CN110042011A - A kind of glasses liquid and its application with lasting guarantor's Xiang Gong energy - Google Patents
A kind of glasses liquid and its application with lasting guarantor's Xiang Gong energy Download PDFInfo
- Publication number
- CN110042011A CN110042011A CN201910463716.8A CN201910463716A CN110042011A CN 110042011 A CN110042011 A CN 110042011A CN 201910463716 A CN201910463716 A CN 201910463716A CN 110042011 A CN110042011 A CN 110042011A
- Authority
- CN
- China
- Prior art keywords
- glasses
- glasses liquid
- liquid
- xiang gong
- gong energy
- Prior art date
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- Granted
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- 239000011521 glass Substances 0.000 title claims abstract description 52
- 239000007788 liquid Substances 0.000 title claims abstract description 46
- 230000002045 lasting effect Effects 0.000 title claims abstract description 7
- 239000003094 microcapsule Substances 0.000 claims abstract description 28
- HDBWAWNLGGMZRQ-UHFFFAOYSA-N p-Vinylbiphenyl Chemical group C1=CC(C=C)=CC=C1C1=CC=CC=C1 HDBWAWNLGGMZRQ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000004140 cleaning Methods 0.000 claims abstract description 6
- 239000000178 monomer Substances 0.000 claims abstract description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 239000006210 lotion Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 239000012065 filter cake Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- -1 olefin sulfonate Chemical class 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- 239000003242 anti bacterial agent Substances 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 19
- 239000003205 fragrance Substances 0.000 abstract description 17
- 230000000694 effects Effects 0.000 abstract description 8
- 206010011732 Cyst Diseases 0.000 abstract description 2
- 208000031513 cyst Diseases 0.000 abstract description 2
- 238000012423 maintenance Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 26
- 239000004417 polycarbonate Substances 0.000 description 17
- 238000007654 immersion Methods 0.000 description 10
- 239000012530 fluid Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 4
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- XIRPMPKSZHNMST-UHFFFAOYSA-N 1-ethenyl-2-phenylbenzene Chemical group C=CC1=CC=CC=C1C1=CC=CC=C1 XIRPMPKSZHNMST-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 230000003578 releasing effect Effects 0.000 description 2
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 2
- 235000010262 sodium metabisulphite Nutrition 0.000 description 2
- 238000013268 sustained release Methods 0.000 description 2
- 239000012730 sustained-release form Substances 0.000 description 2
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 125000000373 fatty alcohol group Chemical group 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000008236 heating water Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical group [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003335 steric effect Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0078—Compositions for cleaning contact lenses, spectacles or lenses
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Eyeglasses (AREA)
Abstract
The invention belongs to eyeglass to clean maintenance technical field, in particular to a kind of glasses liquid and its application with lasting guarantor's Xiang Gong energy, first essence microcapsule is prepared using dimethacrylate diol-lipid monomer, 4- vinyl biphenyl as cyst material polymerized monomer, glasses liquid is configured to having the substances such as the surfactant for cleaning dirt-removing functions again, after handling using the glasses liquid PC eyeglass, the effect that eyeglass distributes cool feeling fragrance can be significantly improved.
Description
Technical field
The invention belongs to eyeglass to clean maintenance technical field, in particular to a kind of with the lasting glasses for protecting Xiang Gong energy
Liquid and its application.
Background technique
Glasses are all a kind of necessity lived, worked, either spectacles, presbyopic for present many people
Glasses or sunglasses require to clean at any time, just can ensure that the visual effect of cleaning.It in addition to this, can also be in glasses
Some essence are added in liquid, the fragrance that essence gives out can not only improve the nasal receptor of wearer, also have and refresh the mind
Effect, facilitate wearer and keep a cool head.
But it needs again to wear glasses after blotting the glasses liquid of lens surface after on the one hand cleaning eyeglass using glasses liquid
On, the essence in glasses liquid can largely be siphoned away together with glasses liquid, the essence itself being left attached on lens surface
Just few, another aspect essence is volatile, leads to not long lasting for releasing fragrance.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of glasses liquid with lasting guarantor's Xiang Gong energy, by weight
Number calculates, including
Wherein, essence microcapsule the preparation method comprises the following steps:
(1) the deionized water dispersion liquid for preparing the emulsifier that mass concentration is 1.0%~5.0%, as water phase；
(2) essence, dimethacrylate diol-lipid monomer, 4- vinyl biphenyl monomer are mixed sufficiently, as oily phase；
(3) oil that the water phase and step (2) that step (1) obtains obtain through high speed shear forms lotion after mixing；
(4) initiator and catalyst are added into lotion obtained in step (3), is filtered after being stirred to react, to filter cake into
Row drying；
Anionic surfactant includes neopelex, lauryl sodium sulfate, fatty alcohol polyoxyethylene ether
Sodium sulphate (AES), α-sodium olefin sulfonate (AOS) etc.,
Nonionic surfactant is fatty alcohol polyoxyethylene ether (AEO-9) etc.,
Antibacterial agent is sodium benzoate etc..
The present invention also provides a kind of above-mentioned applications with the glasses liquid for persistently protecting Xiang Gong energy: using the glasses liquid to PC
Eyeglass carries out cleaning treatment, this can not only go the cleaning of eyeglass based on the realization of the substances such as surfactant in glasses liquid
It is dirty, moreover it is possible to which that the essence based on microcapsule coated makes spectacle lens have the function of sustained release fragrance, and the sustained release time is obviously big
In 12 hours.
Specific embodiment
Embodiment 1
The preparation of essence microcapsule:
(1) PVA-1788 is well-dispersed in and is configured to the dispersion liquid that PVA-1788 mass concentration is 4% in deionized water,
As water phase；
(2) by the peppermint oil dementholized of 950 parts by weight, the 4- of the ethylene glycol dimethacrylate of 198 parts by weight, 45 parts by weight
Vinyl biphenyl mixing is abundant, as oily phase；
(3) water phase that 200g step (1) obtains and the oil that 100g step (2) obtains are mixed, through high-shear homogenizer
High speed shear 7 minutes, obtains lotion under 4500rpm is acted on；
(4) aqueous solution that 100g sodium peroxydisulfate is added into whole lotion obtained in step (3) (is dissolved with sodium peroxydisulfate
5.5g) with the aqueous solution of 100g sodium pyrosulfite (being dissolved with sodium pyrosulfite 4.5g), stirred under room temperature (25 DEG C, similarly hereinafter) anti-
After answering 1.5 hours, (heating water bath) continues to be stirred to react 6 hours (stirring rate is 120rpm) under conditions of 45 DEG C,
Filtering, gained filter cake is dry sufficiently to get arriving essence microcapsule at 50 DEG C.
In parts by weight, will
The pH value of resulting mixed system sufficiently, using piece alkali/citric acid is adjusted to 7 to get lasting to having by mixing
Protect the glasses liquid of Xiang Gong energy.
Using:
Glasses liquid 20g obtained in the present embodiment is taken, thereto plus deionized water is to 300mL, by PC after stirring sufficiently
Eyeglass (Jiangsu Dong Bao Optical Co., Ltd, spectacle lens concave surface keep PC material towards the one side of wearer's face when wearing,
Functional coating is not applied, this also complies with state of the spectacle lens when actual wear uses) it is immersed in wherein, it is taken out after 15 minutes,
The water on PC spectacle lens is blotted using clean glasses cloth, spectacle lens restore dry and Clear & Transparent.
Comparative example 11
When will prepare essence microcapsule, " 4- vinyl biphenyl " is replaced with into equimolar " ethylene glycol dimethacrylate
Ester ", remaining operation are constant:
(1) with embodiment 1；
(2) ethylene glycol dimethacrylate of the peppermint oil dementholized of 950 parts by weight, 247.5 parts by weight is mixed sufficiently, is made
For oily phase；
(3) with embodiment 1；
(4) with embodiment 1.
Glasses liquid is prepared based on essence microcapsule prepared by comparative example 11, other compositions of glasses liquid are the same as embodiment 1.
Using:
The glasses liquid obtained using comparative example 11 carries out immersion treatment, tool to spectacle lens in the same manner as in Example 1
Gymnastics is made with embodiment 1.
Comparative example 12
When will prepare essence microcapsule, " 4- vinyl biphenyl " is replaced with into equimolar " styrene ", remaining operation is not
Become:
(1) with embodiment 1；
(2) by the peppermint oil dementholized of 950 parts by weight, the 4- of the ethylene glycol dimethacrylate of 198 parts by weight, 26 parts by weight
Vinyl biphenyl mixing is abundant, as oily phase；
(3) with embodiment 1；
(4) with embodiment 1.
Glasses liquid is prepared based on essence microcapsule prepared by comparative example 12, other compositions of glasses liquid are the same as embodiment 1.
Using:
The glasses liquid obtained using comparative example 12 carries out immersion treatment, tool to spectacle lens in the same manner as in Example 1
Gymnastics is made with embodiment 1.
Embodiment 2
Glasses liquid 20g made from Example 1, thereto plus deionized water is to 300mL, by polyurethane eye after stirring sufficiently
(Shanghai Weixing Optical Co., Ltd., spectacle lens concave surface keep polyurethane material towards the one side of wearer's face when wearing to eyeglass
Matter does not apply functional coating) it is immersed in wherein, it is taken out after 15 minutes, it will be on polyurethane spectacle lens using clean glasses cloth
Water blots, and spectacle lens restore dry and Clear & Transparent.
Comparative example 21
The glasses liquid obtained using comparative example 11 carries out immersion treatment, tool to spectacle lens in the same manner as in Example 2
Gymnastics is made with embodiment 2.
Comparative example 22
The glasses liquid obtained using comparative example 12 carries out immersion treatment, tool to spectacle lens in the same manner as in Example 2
Gymnastics is made with embodiment 2.
Embodiment 3
Glasses liquid 20g made from Example 1, thereto plus deionized water is to 300mL, by acrylic eye after stirring sufficiently
(Ke Qiang Optical Co., Ltd, Wenzhou City, spectacle lens concave surface keep acrylic towards the one side of wearer's face when wearing to eyeglass
Material does not apply functional coating) it is immersed in wherein, it is taken out after 15 minutes, it will be on acrylic spectacle lens using clean glasses cloth
Water blot, spectacle lens restore dry simultaneously Clear & Transparent.
Comparative example 31
The glasses liquid obtained using comparative example 11 carries out immersion treatment, tool to spectacle lens in the same manner as in Example 3
Gymnastics is made with embodiment 3.
Comparative example 32
The glasses liquid obtained using comparative example 12 carries out immersion treatment, tool to spectacle lens in the same manner as in Example 3
Gymnastics is made with embodiment 3.
Embodiment 4
Glasses liquid 20g made from Example 1, thereto plus deionized water is to 300mL, by PVC glasses after stirring sufficiently
Piece (spectacle lens concave surface keeps PVC material towards the one side of wearer's face when wearing, do not apply functional coating) is immersed in it
In, it takes out after 15 minutes, is blotted the water on PVC spectacle lens using clean glasses cloth, spectacle lens restore dry and clear saturating
It is bright.
Comparative example 41
The glasses liquid obtained using comparative example 11 carries out immersion treatment, tool to spectacle lens in the same manner as in Example 4
Gymnastics is made with embodiment 4.
Comparative example 42
The glasses liquid obtained using comparative example 12 carries out immersion treatment, tool to spectacle lens in the same manner as in Example 4
Gymnastics is made with embodiment 4.
10 flavors and fragrances professional practitioners as criticism personnel in the various embodiments described above, comparative example handle after
Spectacle lens concave surface aroma strength and persistence carry out evaluation marking, when scoring, by the various embodiments described above, comparative example
In handle and blotted by glasses liquid after spectacle lens be mounted on the frame of same specification immediately, and in calm, clean
Net interior is periodically worn the frame by criticism personnel and experiences the fragrance that spectacle lens are given out, with 0~10
Point make assessment to the intensity of fragrance: fragrance is relatively by force or highly significant 8~10；Fragrance moderate 5~8；Fragrance is thin, but can be obvious
Identification 2~5；Fragrance almost without or very faint 0~2.Score data in following table is that 10 criticism personnel experience itself
The average value that scores of the refrigerant fragrance that gives out of spectacle lens (listed timing node is in table with the various embodiments described above, right
Than the spectacle lens in embodiment after being removed in glasses liquid, the glasses liquid for remaining in spectacle lens surface, which is blotted, starts timing),
As can be seen from the above table, after introducing 4- vinyl biphenyl in essence microcapsule cyst material, will delay containing this
After the spectacle lens treatment fluid processing PC eyeglass of release microcapsules, cool feeling fragrance that eyeglass persistently gives out will obviously strongly (see
Embodiment 1, comparative example 11, the using effect of comparative example 12 compare), and the treatment fluid is used in the eye of other materials
When on eyeglass, it can not but bring this effect (see embodiment 2 to comparative example 42).
In summary each experimental result, applicant think that its reason is possible to be: the material of PC spectacle lens is poly- carbonic acid
Bis- (4- hydroxy phenyl) the propane polycarbonate of ester, i.e. 2,2'-, " 2,2'- bis- (4- hydroxy phenyl) propane " contained on strand
Structure has biggish steric effect, between this two strand for causing PC spectacle lens adjacent side by side in microstructure away from
Defection is larger；And the chain (lower to be known as " double phenyl ring chains ") that 4- vinyl biphenyl is linked to be on molecular structure there are two phenyl ring,
After 4- vinyl biphenyl, which participates in polymerization, forms microcapsule capsule wall material, double phenyl ring chains on a part of 4- vinyl biphenyl refer to
To outside microcapsules, simultaneously because microcapsules are in the biggish suspended state of freedom degree in glasses treatment fluid after dilution, make
The double phenyl ring chains extended outward on microcapsules also have certain activity.In this way, when essence microcapsule is close and touches
When the material face PC being dipped on the eyeglass in treatment fluid, double phenyl ring chains of extension are embedded on PC material face phase side by side on microcapsules
In gap between two adjacent strands, but the space inside PC eyeglass is obviously reduced, in addition double phenyl ring chains itself have
Three-dimensional (two phenyl ring on double phenyl ring chains are not in same plane), thus activity insertion PC material double phenyl ring chains be easy to
It is just stuck in the inside, so that the microcapsule granule being connected with these double phenyl ring chains be made also more steadily to be connected to PC material face
On no longer leave away, be thus significantly increased the microcapsules quantity being attached on spectacle lens concave surface in above-described embodiment 1, this is slightly
Slow release cool feeling fragrance, the cool feeling fragrance for resulting in eyeglass to be distributed naturally are obviously strong together for capsule.
And double phenyl ring chains are introduced in comparative example 11 not on microcapsules, the microcapsules and PC material face in treatment fluid it
Between be only Conventional contact, no further binding force generates, therefore can finally rest on PC material face after immersion treatment
Microcapsules quantity greatly reduced compared to embodiment 1, this just causes to deposit on the releasing effect of cool feeling fragrance with embodiment 1
In so apparent gap；
It is the equal of that double phenyl ring chains are replaced with into single benzene radicals in comparative example 12, this leads to extension on microcapsules
Strand is obviously shortened in length, also changes significantly in structure, and single phenyl ring is single plane structure, no solid
Property, can not be clamped in PC material face, also result in the microcapsules quantity that can finally rest on PC material face compared to
Embodiment 1 significantly reduces.
For embodiment 2 to comparative example 42, after surface of microcapsule whether there is double phenyl ring chains to final process
Eyeglass on distribute the effect of cool feeling fragrance and have no significant effect, let alone castering action.This is possible as at other
In the microstructure of material eyeglass, the spacing gap between two adjacent strands is not enough to that double phenyl ring chains is allowed to be embedded in side by side,
Or even if double phenyl ring chains have been embedded into lens matrix, but the microstructure in lens matrix is not enough to double phenyl ring chain cards
Tightly, it locks, so that more stable connection can not be formed with microcapsule granule, this finally stops after just can not effectively increasing immersion treatment
Stay in the microcapsules quantity on eyeglass material face.
Claims (6)
1. a kind of with the lasting glasses liquid for protecting Xiang Gong energy, it is characterised in that: in parts by weight, the composition of the glasses liquid
Including
2. as described in claim 1 have the glasses liquid for persistently protecting Xiang Gong energy, it is characterised in that: the essence microcapsule
The preparation method comprises the following steps:
(1) the deionized water dispersion liquid for preparing emulsifier, as water phase；
(2) essence, dimethacrylate diol-lipid monomer, 4- vinyl biphenyl monomer are mixed sufficiently, as oily phase；
(3) oil that the water phase and step (2) that step (1) obtains obtain through high speed shear forms lotion after mixing；
(4) initiator and catalyst are added into lotion obtained in step (3), is filtered after being stirred to react, filter cake is done
It is dry.
3. as described in claim 1 have the glasses liquid for persistently protecting Xiang Gong energy, it is characterised in that: the anionic surface is living
Property agent be neopelex, lauryl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol, in α-sodium olefin sulfonate
One or more of combinations.
4. as described in claim 1 have the glasses liquid for persistently protecting Xiang Gong energy, it is characterised in that: the non-ionic surface is living
Property agent be fatty alcohol polyoxyethylene ether.
5. as described in claim 1 have the glasses liquid for persistently protecting Xiang Gong energy, it is characterised in that: the antibacterial agent is benzene first
Sour sodium.
6. a kind of application with the glasses liquid for persistently protecting Xiang Gong energy such as described in any one of claim 1 to 5, feature exist
In: the application is to carry out cleaning treatment to PC eyeglass using the glasses liquid.
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| CN201910463716.8A CN110042011B (en) | 2019-05-30 | 2019-05-30 | Glasses liquid with lasting fragrance-keeping function and application thereof |
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| CN201910463716.8A CN110042011B (en) | 2019-05-30 | 2019-05-30 | Glasses liquid with lasting fragrance-keeping function and application thereof |
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