CN110041812A - A kind of projection screen preparation aqueous polymer emulsion composition and its application - Google Patents

A kind of projection screen preparation aqueous polymer emulsion composition and its application Download PDF

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Publication number
CN110041812A
CN110041812A CN201910183248.9A CN201910183248A CN110041812A CN 110041812 A CN110041812 A CN 110041812A CN 201910183248 A CN201910183248 A CN 201910183248A CN 110041812 A CN110041812 A CN 110041812A
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CN
China
Prior art keywords
polymer emulsion
aqueous polymer
nano
emulsion composition
projection
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CN201910183248.9A
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Chinese (zh)
Inventor
梁永日
崔林杰
郑京男
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Beijing Institute of Petrochemical Technology
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Beijing Institute of Petrochemical Technology
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Publication of CN110041812A publication Critical patent/CN110041812A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04Homopolymers or copolymers of ethene
    • C09D123/08Copolymers of ethene
    • C09D123/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09D123/0853Vinylacetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03BAPPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
    • G03B21/00Projectors or projection-type viewers; Accessories therefor
    • G03B21/54Accessories
    • G03B21/56Projection screens
    • G03B21/60Projection screens characterised by the nature of the surface
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2231Oxides; Hydroxides of metals of tin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2248Oxides; Hydroxides of metals of copper
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Abstract

The present invention provides a kind of projection screen preparation aqueous polymer emulsion composition, it is characterised in that includes aqueous polymer emulsion, inorganic nanoparticles and auxiliary agent., can be in arbitrary site using aqueous polymer emulsion composition of the invention, field-applied forms the projection film of high definition and environmental protection on any suitable substrate, without in addition setting screen cloth, is very easy to be projected.Aqueous polymer emulsion composition of the invention can form projection film on the transparent substrates such as glass, for back projection imaging, angle of visibility up to 170 degree, environment resistant light ability it is strong, compared with the prior art, construction is easy, the size of projection screen is not affected by other factors, only determined according to the size of transparent substrate, the environment-friendly type projection screen of formation is influenced very little by ambient light, even if under bright light, beautiful in colour, lifelike image picture can also be formed, and can watch clearly image in the two sides of screen.Due to being back projection imaging, projector can be hidden completely, and demonstrator does not have shade, and projector's light will not generate glare effects, is still the state of substrate in the state of not using, therefore do not influence the original function of substrate.

Description

A kind of projection screen preparation aqueous polymer emulsion composition and its application
Technical field
The present invention relates to a kind of projection screen preparation aqueous polymer emulsion composition and its application, in particular to a kind of rings Guarantor field new material.
Background technique
Currently, optical projection system is widely used in the occasions such as commercial exhibition, multimedia conferencing room, classroom, stadiums, adopted Projection pattern mainly has positive throwing and rear-projection.Correspondingly, projection screen can also be divided into front projection screen from projection pattern Curtain (reflective) and back projection screens (transmission-type).The so-called positive installation site for being exactly projector and spectators of throwing is in projection screen It is ipsilateral, projector issue light project projection screen, form image on the projection screen, then light is re-reflected into people Eyes.Similarly, so-called rear-projection is exactly that the installation site of projector is located at the two sides of projection screen, projector's hair with spectators For light out from the side direct projection of projection screen to projection screen, light enters spectators' eyes through projection screen.Front projection screen It is not limited by size, but need to control environment light can just obtain good viewing effect, it is good in ambient light and illumination It will cause the degradation of picture contrast under environment.And rear projection screen picture entirety sense is stronger, picture color is gorgeous, and image is forced Very, and control environment light is not needed, is suitable for ambient light and illuminates good environment, but rear projection screen is dimensionally not so good as It is positive to throw, and enough back spaces are needed, to ensure projector distance.Also, just throwing and rear-projection can not to be used for simultaneously at present Screen.
Summary of the invention
The purpose of the present invention is to provide a kind of projection screen preparation aqueous polymer emulsion compositions, it is characterised in that packet Property of water-bearing polymer emulsion, inorganic nanoparticles and auxiliary agent.
In the present invention, the aqueous polymer emulsion include aqueous polyurethane emulsion, water polyacrylic acid lotion, EVA lotion or two or more aqueous polymer emulsions.
In the present invention, the inorganic nanoparticles are selected from nano silica, nano-stannic oxide, nanometer titanium dioxide Zinc, nano-titanium dioxide, nano aluminium oxide, one or more kinds of mixtures in nano zircite, the nano particle mixing The mass content of object in the composition is 3-10%.
In the present invention, toning nanofiller can also be included.Preferably, the toning receives filler as selected from nano-silica Change copper, nanometer di-iron trioxide, nano-manganese dioxide, one or more kinds of mixtures in nano carbon black, in the composition Mass content be 0.01-2%.
In the present invention, the auxiliary agent is made of defoaming agent, dispersing agent and film forming agent, mass content in the composition For 1-10%.
The second aspect of the present invention provides a kind of biplane projection screen, which is characterized in that using above-mentioned waterborne polymeric cream Liquid composition is coated on substrate and forms projection film, and the use of projection film combination projector forms image.
The third aspect of the present invention provides a kind of aqueous polymer emulsion composition of the present invention and prepares in projection screen In purposes.
Projection screen preparation of the invention is at low cost, environmentally friendly with aqueous polymer emulsion composition and construction is easy, and adopts , can be coated and dried at normal temperatures and pressures with modes such as conventional spraying, roller coating, organic solvent taste is not generated, to environment without dirt Dye, rate of drying is fast at normal temperatures and pressures, and construction is easy, therefore can be made, and further reduced the cost of projection screen, Feature is that the coating of aqueous polymer emulsion composition coating material is not necessarily to the professional training of professional, sharp at normal temperatures and pressures It is coated directly on required cleaning substrate with simple spraying or method of roll coating, spontaneously dries film forming.
It, can be existing on any suitable substrate in arbitrary site using aqueous polymer emulsion composition of the invention The projection film that field coating forms high definition and environmental protection is very easy to be projected it is not necessary that screen cloth is in addition arranged.Of the invention is aqueous Polymeric emulsion composition can form projection film on the transparent substrates such as glass, be used for back projection imaging, angle of visibility up to 170 degree, Environment resistant light ability is strong, and compared with the prior art, construction is easy, the size of projection screen is not affected by other factors, basis The size of transparent substrate is determined, and the environment-friendly type projection screen of formation influenced very little by ambient light, even if under bright light, Beautiful in colour, lifelike image picture can also be formed, and can watch clearly image in the two sides of screen.Work as room When the glass or substrate of interior window prepare projection film as the above-mentioned waterborne polymeric mixture of substrate painting, indoor and outdoor can see throwing Shadow imaging, and influence of the projection film to indoor shading value is smaller when not projecting.Projection membrane removal is easier to, and is held after being steeped with clear water Easy-clear does not stay the trace of film.
Aqueous polymer emulsion composition of the invention can also be coated in existing non-woven fabrics, white curtain or wall On, the projection film of high definition and environmental protection is formed, which overcomes even if that can also form clearly picture under bright light Existing white curtain needs the shortcomings that using in the dark.Environment-friendly type projection screen of the invention can be used for outdoor advertising, room In internal and external ornament finishing, display and demonstration, office realm etc..
Specific embodiment
In the following, a detailed description of the technical solution in the embodiment of the present invention is provided, it is clear that described embodiment is only It is a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, ordinary skill people Member's every other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
It should be noted that, in this document, the terms "include", "comprise" or its any other variant are intended to non-row His property includes, so that the process, method, article or equipment for including a series of elements not only includes those elements, and And further include other elements that are not explicitly listed, or further include for this process, method, article or equipment institute it is intrinsic Element.
A kind of projection screen preparation aqueous polymer emulsion composition, includes aqueous polymer emulsion, inorganic nanoparticles And auxiliary agent.
Preferably, the aqueous polymer emulsion includes aqueous polyurethane emulsion, water polyacrylic acid lotion or it is mixed Close object.
Preferably, the inorganic nanoparticles be selected from nano silica, nano-stannic oxide, Nano zinc dioxide impact-resistant, Nano-titanium dioxide, nano aluminium oxide, one or more mixtures in nano zircite, the mixture of nanoparticles are combining Mass content in object is 3-10%.
Preferably, light modulation nanofiller can also be included.Preferably, the light modulation receives filler as selected from nanometer titanium dioxide Copper, nanometer di-iron trioxide, nano-manganese dioxide, one or more mixtures in nano carbon black, quality in the composition Content is 0.01-2%.
In the present invention, the auxiliary agent is made of defoaming agent, dispersing agent and film forming agent, mass content in the composition For 1-10%.
A kind of environment-friendly type projection screen preparation aqueous polymer emulsion composition coating material of the invention.Of the invention Aqueous polymer emulsion composition coating material is suitable for making on transparent glass or transparent polymer film substrate and non-woven fabrics It is standby just carry on the back prepared on dual-purpose projection screen or opaque substrate orthographic projection curtain, be particularly suitable for meeting the transparent of existing structure Windowpane or display board be transformed into just, the demand of rear projection screen.The present invention relates to curtain coating material have anti-light line ability it is strong, Construction is simple, low cost and environment-friendly type feature.
The second aspect of the present invention provides a kind of biplane projection screen, which is characterized in that using above-mentioned waterborne polymeric cream Liquid composition is coated on substrate and forms projection film, and the use of projection film combination projector forms image.
The third aspect of the present invention provides a kind of aqueous polymer emulsion composition of the present invention and prepares in projection screen In purposes.
In the present invention, the aqueous polymer emulsion is carrier material, and commercially available waterborne polyester material, aqueous poly- can be used Urethane, water-and acrylate, aqueous EVA lotion etc., range of solid content is preferably to contain in the composition between 25-45% Amount is 65-85%.
In the present invention, inorganic nano-filler be chosen as nano silica, nano-stannic oxide, Nano zinc dioxide impact-resistant, Or mixtures thereof nano-titanium dioxide, nano aluminium oxide, nano zircite etc., content in the composition are 3-10%.
In the present invention, light modulation nano material is chosen as nanometer titanium dioxide copper, nanometer di-iron trioxide, nanometer titanium dioxide Or mixtures thereof manganese, nano carbon black etc., content in the composition are 0.01-2%.
In the present invention, auxiliary agent is made of defoaming agent, dispersing agent and film forming agent, and content in the composition is 1- 10%.
The substrate includes transparent substrate, opaque substrate, the transparent glass window of existing structure or display board etc..This hair Construction is simple and environmentally friendly feature described in bright are the coatings of aqueous polymer emulsion composition coating material without professional Professional training, be coated directly on required cleaning substrate using simple spraying or method of roll coating at normal temperatures and pressures, from Right drying and forming-film, drying process do not bring organic solvent taste.
Aqueous polymer emulsion composition coating material of the invention is applicable to the interior/exterior decoration dress of existing building Repair, in display and demonstration and outdoor advertisement screen, can site operation, easy construction, drying time are short, save cost and time, anti-ring Border light ability is high, in time to can also be seen that clearly picture under the conditions of daytime strong light.
Embodiment
Embodiment 1
In the aqueous polyurethane of 100 mass parts, the silica of 8 mass parts is added;The nano-stannic oxide of 2 mass parts and The water of 2 mass parts is mixed, solid content 45%.Then the aqueous of embodiment 1 is obtained after sixty minutes using ultrasonic wavelength-division Polymer composition 1.Aqueous polymeric composition 1 is packed into spray gun, is to be coated on vertical direction by locating in advance with ground It is sprayed on the glass substrate of reason, natural drying obtains linen coated film, and surface drying time is 10~15.Coat polymerizable aqueous The glass of object 1 can be used as projection screen use, and angle of visibility 170, coating two sides can be imaged.Coat side is towards projector In use, rear-projection effect is preferable.
Embodiment 2
In the aqueous polyurethane of 100 mass parts, the silica of 14 mass parts is added;The nano dioxy of 7 mass parts Change titanium;It is mixed in the water of 2 mass parts, solid content 63%.Then embodiment 2 is obtained after sixty minutes using ultrasonic wavelength-division Transmit coating compositions 2;Transmission coating compositions 2 are packed into spray gun, are to be coated on vertical direction by pretreated with ground It is sprayed on glass substrate, natural drying obtains linen coated film, and surface drying time is 10~15.Coat waterborne polymeric 1 Glass can be used as projection screen use, angle of visibility 170, coating two sides can be imaged.Coat side makes towards projector Used time, rear-projection effect are preferable.
Embodiment 3
In the aqueous polyurethane of 100 mass parts, the silica of 8 mass parts is added;The nano-stannic oxide of 2 mass parts; 0.05 part of copper dioxide, mixes in the water of 2 mass parts, solid content 47%.Then it is obtained after sixty minutes using ultrasonic wavelength-division To the transmission coating compositions 3 of embodiment 3;Will transmission coating compositions 3 be packed into spray gun, with ground be vertical direction on be coated to through It crosses on pretreated glass substrate and sprays, natural drying obtains the coated film of grey black, and surface drying time is 10~15.Coat water Property polymer 1 glass can be used as projection screen use, angle of visibility 170, coating two sides can be imaged.Coat side court Projector is in use, rear-projection effect is preferable.
Embodiment 4
In the water-and acrylate and aqueous polyurethane of 100 mass parts in mixture (3: 7), the dioxy of 14 mass parts is added SiClx;The nano-stannic oxide of 7 mass parts;It is mixed in the water of 2 mass parts, solid content 63.Then using ultrasonic wavelength-division The transmission coating compositions 4 of embodiment 4 are obtained after sixty minutes;Transmission coating compositions 4 are packed into spray gun, are vertical direction with ground On be coated to by being sprayed on pretreated glass substrate, natural drying obtains linen coated film, surface drying time 10 ~15.The glass for coating waterborne polymeric 1 can be used as projection screen use, and angle of visibility 170, coating two sides can be obtained into Picture.Coat side is towards projector in use, rear-projection effect is preferable.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention Range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.

Claims (8)

1. a kind of projection screen preparation aqueous polymer emulsion composition, it is characterised in that include aqueous polymer emulsion, inorganic Nano particle and auxiliary agent.
2. aqueous polymer emulsion composition according to claim 1, which is characterized in that the aqueous polymer emulsion packet Include aqueous polyurethane emulsion, water polyacrylic acid lotion, EVA lotion or two or more aqueous polymer emulsion mixtures.
3. aqueous polymer emulsion composition according to claim 1, which is characterized in that the inorganic nanoparticles are choosing From in nano silica, nano-stannic oxide, Nano zinc dioxide impact-resistant, nano-titanium dioxide, nano aluminium oxide, nano zircite One or more kinds of mixtures, the mass content of the mixture of nanoparticles in the composition are 3-10%.
4. aqueous polymer emulsion composition according to any one of claim 1 to 3, which is characterized in that can also wrap The nanofiller containing toning.
5. aqueous polymer emulsion composition according to claim 4, which is characterized in that it is described light modulation receive filler be selected from Nanometer titanium dioxide copper, nanometer di-iron trioxide, nano-manganese dioxide, one or more kinds of mixtures in nano carbon black, Mass content in composition is 0.01-2%.
6. aqueous polymer emulsion composition according to any one of claim 1 to 5, which is characterized in that the auxiliary agent It is made of defoaming agent, dispersing agent and film forming agent, mass content in the composition is 1-10%.
7. a kind of biplane projection screen, which is characterized in that use aqueous polymer emulsion described in any one of claims 1 to 6 Composition is coated on substrate and forms projection film, and the use of projection film combination projector forms image.
8. a kind of purposes of aqueous polymer emulsion composition described in claim 1 in projection screen preparation.
CN201910183248.9A 2018-10-23 2019-03-11 A kind of projection screen preparation aqueous polymer emulsion composition and its application Pending CN110041812A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2018112384570 2018-10-23
CN201811238457 2018-10-23

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111607304A (en) * 2020-05-27 2020-09-01 甘肃正书纳米特种涂料科技开发有限公司 Double-side projection nano projection paint and preparation method and use method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106189628A (en) * 2016-08-24 2016-12-07 彭晓中 The making of a kind of aqueous projection screen paint and technique for applying thereof
CN106200243A (en) * 2015-04-17 2016-12-07 金学正 Utilize the light beam projector irradiation display screen of the coating easily removed
CN106590378A (en) * 2015-10-14 2017-04-26 新玉实业股份有限公司 Screen material, sprinkler irrigation device, projection screen device and using method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106200243A (en) * 2015-04-17 2016-12-07 金学正 Utilize the light beam projector irradiation display screen of the coating easily removed
CN106590378A (en) * 2015-10-14 2017-04-26 新玉实业股份有限公司 Screen material, sprinkler irrigation device, projection screen device and using method thereof
CN106189628A (en) * 2016-08-24 2016-12-07 彭晓中 The making of a kind of aqueous projection screen paint and technique for applying thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111607304A (en) * 2020-05-27 2020-09-01 甘肃正书纳米特种涂料科技开发有限公司 Double-side projection nano projection paint and preparation method and use method thereof

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