CN110041661A - A kind of high-ductility abrasion-proof CABLE MATERIALS - Google Patents

A kind of high-ductility abrasion-proof CABLE MATERIALS Download PDF

Info

Publication number
CN110041661A
CN110041661A CN201910326182.4A CN201910326182A CN110041661A CN 110041661 A CN110041661 A CN 110041661A CN 201910326182 A CN201910326182 A CN 201910326182A CN 110041661 A CN110041661 A CN 110041661A
Authority
CN
China
Prior art keywords
mass ratio
mixing
liquid
parts
takes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910326182.4A
Other languages
Chinese (zh)
Inventor
赵玲玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Zhongke Huijing Energy Storage Materials Technology Co Ltd
Original Assignee
Beijing Zhongke Huijing Energy Storage Materials Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Zhongke Huijing Energy Storage Materials Technology Co Ltd filed Critical Beijing Zhongke Huijing Energy Storage Materials Technology Co Ltd
Priority to CN201910326182.4A priority Critical patent/CN110041661A/en
Publication of CN110041661A publication Critical patent/CN110041661A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/40—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of high-ductility abrasion-proof CABLE MATERIALSs, belong to technical field of electric wires and cables.The present invention is first handled biogas slurry, and then prawn shell carries out mixed fermentation processing, so that differentiation degradation occurs for chitin, is generated active constituent, is reinforced crosslinked action, improves overall wear resistance energy.Fanglun slurry cake has fluff structures, there can be very large access area with resin component, interactively between raising system internal composition, improve shock resistance, promote toughness, the degree of orientation is improved, so that the degree of roughness on surface to improve with the compatibility of modified resin ingredient, it is common to promote toughness and wear-resisting property.The oscillation intensity that the addition of castor oil can reduce covalent bond in resin component combines so that tensile strength effectively improves with composite modified resin ingredient, can form the strong three-dimensional network mutually wound, improves internal mechanical performance.The problem of it is poor that the present invention solves current common CABLE MATERIALS wear-resisting property, and tensile strength is low, and toughness is weak, is not easy to processing.

Description

A kind of high-ductility abrasion-proof CABLE MATERIALS
Technical field
The invention belongs to technical field of electric wires and cables, and in particular to a kind of high-ductility abrasion-proof CABLE MATERIALS.
Background technique
Power supply has become world economy and develops rapidly indispensable a part, and wire and cable is as power supply Carrier spread all trades and professions.Since the insulating polymeric material that wire and cable uses belongs to combustible material, in transmission electric energy mistake Cable fire is often caused by internal cause (cable self-heating, short circuit etc.) and external cause (fire etc.) in journey, lives and properties are made At damage.Traditional flame retardant cable mainly uses halogen containing polymers (such as PVC) and halogen containing flame-retardant (containing chlorine or brominated chemical combination Object) by being kneaded acquisition good flame-retardance energy, but fire can still cause the burning of cable, and cable is in combustion Asphyxia, poisoning can be made one by generating a large amount of poison gas, corrosive gas, not only be caused greatly to survivor and rescue personnel Harm and pollution environment.
Wire and cable plastics mainly include polyvinyl chloride (PVC), polyolefin (such as polyethylene, polypropylene), fluoroplastics. Polyvinyl chloride cable and some other halogen cable materials are endangered due to releasing a large amount of corrosive gas and dense smoke when burning And the life security of people, so low smoke, zero halogen cable is widely used in recent years.Therefore seek the substitute of PVC, Promoting interior of building city electrical wiring (220/240V), Telephone Cable data cable non-halogen, oneself is extremely urgent.2001 Year, FROOC (Fire Retardant Olefinic Cable Compounds) association has been set up in Europe, it is therefore intended that is pushed away The development of line cable industry of the dynamic collaboration based on halogen-free polyolefin CABLE MATERIALS.
Wire cable insulating and sheath are commonly called as CABLE MATERIALS with plastics, and existing vehicle wire cable material uses halogen fire-retardant Agent can discharge a large amount of toxic and harmful gas, generate harm to health after human body sucking, be unfavorable for vehicle fire when in combustion state Calamity escape and environmental requirement；And since biggish vibration, wire and cable meeting during routine use can be generated when vehicle operation There is frequent friction, thus CABLE MATERIALS is required to have preferable wear-resisting property.Have a plurality of types of low smoke and zero halogen electricity in the prior art Cable material product.The hardness of 125 DEG C of low-smoke zero-halogen cable materials of conventional commercial is low, and loading is high, electric wire made from it Cable finished product can lead to the short-circuit and on fire of route due to insulation and the abrasion of sheath in long-time use process, generate safety Hidden danger.
Wire and cable is resin dedicated including cable insulating material and cable jacket material, raw materials used mainly to have polyethylene and polychlorostyrene Ethylene.Now, 6kV grades or more power cable is all using polyethylene crosslinking Insulation Material；1kV low-voltage cable below is then with poly- Based on vinyl chloride insulation and pvc sheath, but since polyvinyl chloride stability and electrical insulating property are poor, more come The more replaced by polyethylene；Communication cable generally does insulating layer with high density polyethylene (HDPE), is protected with linear low density polyethylene Jacket layer；Optical cable is then mainly with high density polyethylene (HDPE) and medium density polyethylene as protective cover material.However, cable is in the process used In, it being usually erected in the air, carries out the conveying of electric power, the skyborne cable of this sample rack usually will receive the erosion of ultraviolet light, So that the premature cracking of cable, influences the cable transfer of cable, so that the normal life of people is affected, electricity is substantially reduced The service life of cable, and some special trades are needed to use on heavy-duty machinery, and need that equipment is followed constantly to move, It is constantly contacted with objects such as ground, walls, normal cable is not able to satisfy its wear-resisting requirement then.
Summary of the invention
The technical problems to be solved by the invention: it is poor for common CABLE MATERIALS wear-resisting property at present, and tensile strength is low, it is tough Property it is weak, be not easy to processing the problem of, a kind of high-ductility abrasion-proof CABLE MATERIALS is provided.
In order to solve the above technical problems, the present invention is using technical solution as described below:
A kind of high-ductility abrasion-proof CABLE MATERIALS, including following component: 4 ~ 8 parts of Corvics, 2 ~ 5 parts of nitrile rubbers, 0.1 ~ 0.3 part Nano-TiO2, 1 ~ 4 part of tert-butylhydroquinone, 2 ~ 5 parts of plasticizer, 5 ~ 8 parts of talcum powder, 12 ~ 20 parts of composite cable auxiliary materials, 20 ~ 35 parts of composite modified resin ingredients.
The preparation method of the composite cable auxiliary material, includes the following steps:
(1) 5:1:3:0.1:50 ~ 85 take shrimp shell meal, Grape Skin, yeast extract, casein, water to be mixed in mass ratio, stand, add Enter the pretreatment biogas slurry of shrimp shell meal quality 3 ~ 7%, stir, sealing and standing fermentation discharges, and filtering is collected fermentation liquid sterilizing, obtained Sterilized solution takes sterilized solution in 75 ~ 85 DEG C of concentrated by rotary evaporations, obtains concentrate, and 1:12 ~ 20 in mass ratio take concentrate, reagent A mixing to stir It mixes, obtains compound liquid；
(2) according to parts by weight, 20 ~ 30 parts of glucose, 2 ~ 5 parts of potassium dihydrogen phosphates, 8 ~ 15 portions of linseed oil, 2 ~ 15 portions of castor-oil plants are taken Oil, 100 ~ 150 parts of ethanol solutions first take glucose, potassium dihydrogen phosphate, ethanol solution mixing, and room temperature is stirred, and are added sub- Sesame oil and castor oil mixing, in 55 ~ 65 DEG C, high-speed stirred obtains mixed liquid, takes mixed liquid 3:7 ~ 12:1:0.1 in mass ratio that compound is added Liquid, crosslinked action liquid, auxiliary agent are mixed, and in 60 ~ 80 DEG C of rotary evaporations, microwave treatment, discharging is to get composite cable auxiliary Material.
Pretreatment biogas slurry in the step (1): take biogas slurry 1:7 ~ 10:2 in mass ratio that HCl solution, sodium citrate is added It is mixed, is stored at room temperature, filter, take filtrate that the meal wheat stone mixing of filtrate quality 3 ~ 7% is added, stand, shake, filter, collect Filtered fluid, as pretreatment biogas slurry.
Reagent A in the step (1): 7 ~ 10:1 in mass ratio takes poly-vinyl alcohol solution, polypyrrole mixing to get reagent A。
Auxiliary agent in the step (2): 1:2 ~ 5 take OP-10, neopelex mixing to get helping in mass ratio Agent.
Crosslinked action liquid in the step (2): 2 ~ 5:1:25 in mass ratio takes glutaraldehyde, terephthalaldehyde, anhydrous second Alcohol mixes to get crosslinked action liquid.
The preparation method of the composite modified resin ingredient, includes the following steps:
S1. the extracting epoxy resin of 2:1:7 in mass ratio ~ 13, phenolic resin, butanone are mixed, and adjust pH, obtain resin liquid, take tree The aniline of resin liquid quality 6 ~ 10%, the mixing of 2 ~ 4 times of resin liquid quality of acetone is added in rouge liquid, and ultrasonic oscillation obtains dispersion liquid, It takes dispersion liquid 12 ~ 20:1 in mass ratio that reagent B is added to be mixed, obtains modified resin,
S2. it takes stalk to pulverize and sieve, takes sieving particle Steam explosion treatment, obtain bursting charge, take bursting charge 1:15 ~ 25 in mass ratio NaOH solution is added to be mixed, stands, filtering takes filter cake to wash, and is freeze-dried, material must be lyophilized, and takes freeze-drying material in mass ratio 3:1:0.2:16 is added Fanglun slurry cake, additive, acetone and is mixed, and refrigerates, filtering, collects filter residue 1:5 ~ 8 in mass ratio: 0.01 is added modified resin, cobalt naphthenate mixing, mixed in 70 ~ 85 DEG C of heat, cools down to get composite modified resin ingredient.
Reagent B in the step S1: take sodium peroxydisulfate 2:1:10 in mass ratio ~ 15 that sodium hydrogensulfite, hydrochloric acid is added molten Liquid mixes to get reagent B.
Additive in the step S2: 1:3 ~ 6:0.3 in mass ratio be added carbon black, stearic acid, zinc oxide mixing to get Additive.
The plasticizer: 2 ~ 5:1:0.1 in mass ratio takes triethyl citrate, dioctyl phthalate, chlorinated paraffin Mixing is to get plasticizer.
The present invention is compared with other methods, and advantageous effects are:
(1) present invention is first handled biogas slurry, is acidified and is complexed processing and remove part heavy metal ion therein, utilizes meal wheat Stone adjusts the concentration and activity of its internal bacterium, and then prawn shell carries out mixed fermentation processing, so that chitin occurs to a certain degree Differentiation degradation so that the groups such as the active amino wherein contained, hydroxyl exposure, thus be conducive to in system it is other at Distribute going on smoothly for raw cross-linking reaction, in addition, addition has the terephthaldehyde of benzene ring structure in added crosslinked action liquid Aldehyde, molecular structure is larger for glutaraldehyde, can also effectively widen the hole between each macromolecular chain of cross-linked network, And the filling of phenyl ring this rigid structure, it also can effectively improve the mechanical property of cross-linked network, further increase wear-resisting property；
(2) Fanglun slurry cake used in the present invention has fluff structures, and fento is grown thickly, and has very big specific surface area, can be with resin Ingredient has very large access area, and can crush in cooperation stalk, the micro fiber that Steam explosion treatment generates, with resin component shape At physics engagement, very strong surface binding force is generated, intertwineing with each other between the fento of Fanglun slurry cake is can avoid and easily leads to It disperses unevenly, to improve its dispersibility, to provide good physical associations basis inside this system, can also cooperate subsequentization Bonding action is learned, polynary cross-linked network is cooperatively formed, constitutes energy-absorbing buffering structure, the effect improved between system internal composition is closed System improves shock resistance, promotes toughness, reduces fento rotation angle to the modification of fiber, the degree of orientation is improved, so that surface Degree of roughness make and the compatibility of modified resin ingredient improves, it is common to promote toughness and wear-resisting property；
(3) linseed oil that the present invention adds is glycerol and linoleic acid reaction gained glyceride, and there are three double for tool in molecular structure Key can carry out addition reaction to phenol structure under acid effect and introduce long flexible chain molecule, and the introducing of backbone can effectively change The flexibility and impact resistance of kind resin component, play filling effect to fiber material, and be mixed into outer toughening effect The ingredients such as nitrile rubber can form the three-dimensional crosslinked network structure of high tenacity inside system of the present invention, further promote product Mechanical performance, the addition of castor oil can reduce the oscillation intensity of covalent bond in resin component, and lipophilic group can have increase surface Contact angle and reduces swelling index and so that tensile strength effectively improves can effectively avoid brittleness in processing and use process Excessively high to be broken, the bacterial fibers that have in made fermented ingredient, plant fiber are combined with composite modified resin ingredient, The strong three-dimensional network mutually wound can also be formed, internal mechanical performance is improved.
Specific embodiment
Reagent A: 7 ~ 10:1 in mass ratio takes the poly-vinyl alcohol solution that mass fraction is 10%, polypyrrole to mix to get reagent A。
Reagent B: the hydrochloric acid solution that sodium hydrogensulfite is added in sodium peroxydisulfate 2:1:10 in mass ratio ~ 15, pH is 2.1 ~ 3.2 is taken Mixing is to get reagent B.
Additive: carbon black, stearic acid, zinc oxide mixing is added to get additive in 1:3 ~ 6:0.3 in mass ratio.
Auxiliary agent: 1:2 ~ 5 take OP-10, neopelex mixing to get auxiliary agent in mass ratio.
Crosslinked action liquid: 2 ~ 5:1:25 in mass ratio takes glutaraldehyde, terephthalaldehyde, dehydrated alcohol mixing to get crosslinked action Liquid.
Pretreatment biogas slurry: take biogas slurry 1:7 ~ 10:2 in mass ratio that HCl solution, the sodium citrate that mass fraction is 20% is added It is mixed, is stored at room temperature 2 ~ 4h, filter, take filtrate that the meal wheat stone mixing of filtrate quality 3 ~ 7% is added, stand, with 200 ~ 250r/min shakes 1 ~ 3h, and filtered fluid is collected in filtering, as pretreatment biogas slurry.
Plasticizer: 2 ~ 5:1:0.1 in mass ratio takes triethyl citrate, dioctyl phthalate, chlorinated paraffin mixing, Up to plasticizer.
The preparation method of composite cable auxiliary material, includes the following steps:
(1) 5:1:3:0.1:50 ~ 85 take the shrimp shell meal sieved with 100 mesh sieve, Grape Skin, yeast extract, casein, water in fermentation in mass ratio Tank mixing is stirred 15 ~ 30min with 400 ~ 550r/min, stands 2 ~ 4h, the pretreatment natural pond of shrimp shell meal quality 3 ~ 7% is added Liquid, after 350 ~ 550r/min magnetic agitation, 20 ~ 45min, sealing and standing is fermented 3 ~ 5 days, is discharged, filtering, is collected fermentation liquid and is turned Enter high-pressure sterilizing pot, 12 ~ 18min of insulated sterilizing, obtains sterilized solution under the conditions of 121 DEG C, takes sterilized solution in Rotary Evaporators, in 75 ~ 85 DEG C, 40 ~ 60min of concentrated by rotary evaporation, concentrate is obtained, 1:12 ~ 20 in mass ratio take concentrate, reagent A mixing, with 500 ~ 800r/ Min 40 ~ 60min of magnetic agitation, obtains compound liquid；
(2) according to parts by weight, 20 ~ 30 parts of glucose, 2 ~ 5 parts of potassium dihydrogen phosphates, 8 ~ 15 portions of linseed oil, 2 ~ 15 parts of castors are successively taken The ethanol solution that sesame oil, 100 ~ 150 parts of volume fractions are 70%, first takes glucose, potassium dihydrogen phosphate, ethanol solution in batch mixer Mixing is stirred 3 ~ 5h under room temperature with 350 ~ 550r/min, linseed oil and castor oil mixing is added, in 55 ~ 65 DEG C, with 1200 ~ 1600r/min, 40 ~ 60min of high-speed stirred, mixed liquid is obtained, takes mixed liquid 3:7 ~ 12:1:0.1 in mass ratio that compound is added Liquid, crosslinked action liquid, auxiliary agent mixing, with 500 ~ 800r/min, 40 ~ 60min of magnetic agitation, in 60 ~ 80 DEG C of rotary evaporations 30 ~ After 55min, micro-wave oven is moved to 400W power microwave and handles 8 ~ 13min, is discharged to get composite cable auxiliary material.
The preparation method of composite modified resin ingredient, includes the following steps:
S1. the extracting epoxy resin of 2:1:7 in mass ratio ~ 13, phenolic resin, the butanone that mass fraction is 12% mix, with 500 ~ 800r/min 40 ~ 60min of magnetic agitation adjusts pH to 1.3 ~ 1.7 with the HCl solution that mass fraction is 20%, obtains resin liquid, take Resin liquid be added resin liquid quality 6 ~ 10% aniline, 2 ~ 4 times of resin liquid quality acetone mixing, move to ultrasonic oscillation instrument in 20 ~ 35min of ultrasonic oscillation, obtains dispersion liquid under 50 ~ 65kHz frequency, takes dispersion liquid 12 ~ 20:1 in mass ratio that reagent B is added mixed It closes, with 500 ~ 800r/min, 40 ~ 60min of magnetic agitation, obtains modified resin,
S2. it takes stalk to crushed 80 meshes in pulverizer, takes sieving particle in steam blasting machine, 15 ~ 25 DEG C of Yu Wendu, press water material Under 4 ~ 8:1 of mass ratio, 4.1 ~ 5.3MPa of pressure, 4 ~ 8min of Steam explosion treatment obtains bursting charge, takes bursting charge 1:15 in mass ratio ~ 25, which are added the NaOH solution that mass fraction is 15%, is mixed, and stands 3 ~ 5h, filters, after taking filter cake to be rinsed with water 2 ~ 4 times, In the dry 4 ~ 8h of -20 DEG C of freeze drying box, material must be lyophilized, take freeze-drying material 3:1:0.2:16 in mass ratio that Fanglun slurry cake is added, adds Add agent, acetone mixing, after 700 ~ 1000r/min magnetic agitation, 40 ~ 60min, move to refrigerator in 2 ~ 5 DEG C of 3 ~ 5h of refrigeration, filter, It collects filter residue 1:5 ~ 8:0.01 in mass ratio and modified resin, cobalt naphthenate mixing is added, mix 1 ~ 3h in 70 ~ 85 DEG C of heat, drop naturally It warms to room temperature to get composite modified resin ingredient.
A kind of high-ductility abrasion-proof CABLE MATERIALS, according to the mass fraction, including following component: 4 ~ 8 parts of Corvics, 2 ~ 5 parts Nitrile rubber, 0.1 ~ 0.3 part of nano-TiO2, 1 ~ 4 part of tert-butylhydroquinone, 2 ~ 5 parts of plasticizer, 5 ~ 8 parts of talcum powder, 12 ~ 20 Part composite cable auxiliary material, 20 ~ 35 parts of composite modified resin ingredients.
A kind of preparation method of high-ductility abrasion-proof CABLE MATERIALS, includes the following steps:
(1) according to the mass fraction, 4 ~ 8 parts of Corvics, 2 ~ 5 parts of nitrile rubbers, 0.1 ~ 0.3 part of nano-TiO are taken2, 1 ~ 4 part Tert-butylhydroquinone, 2 ~ 5 parts of plasticizer, 5 ~ 8 parts of talcum powder, 12 ~ 20 parts of composite cable auxiliary materials, 20 ~ 35 parts it is composite modified Resin component；
(2) prior to 30 ~ 45 DEG C, Corvic, nitrile rubber, nano-TiO are taken2, plasticizer, talcum powder, composite cable it is auxiliary It helps material to mix in batch mixer, with 600 ~ 1000r/min, 40 ~ 60min of magnetic agitation, adds composite modified resin ingredient, special fourth Base hydroquinone mixing, with 1200 ~ 1800r/min, 25 ~ 45min of high-speed stirred, move to mixer, in 60 ~ 80 DEG C be kneaded 30 ~ 60min, is warming up to 110 ~ 120 DEG C, and after 25 ~ 45min of mixing, investment twin screw extruder is granulated, and melts in 160 ~ 180 DEG C It squeezes out, plastotype, it is cooling to get high-ductility abrasion-proof CABLE MATERIALS.
Reagent A: 7:1 in mass ratio takes the poly-vinyl alcohol solution that mass fraction is 10%, polypyrrole to mix to get reagent A.
Reagent B: the hydrochloric acid solution that sodium hydrogensulfite is added in sodium peroxydisulfate 2:1:10 in mass ratio, pH is 2.1 is taken to mix, i.e., Obtain reagent B.
Additive: carbon black, stearic acid, zinc oxide mixing is added to get additive in 1:3:0.3 in mass ratio.
Auxiliary agent: 1:2 in mass ratio takes OP-10, neopelex mixing to get auxiliary agent.
Crosslinked action liquid: 2:1:25 in mass ratio takes glutaraldehyde, terephthalaldehyde, dehydrated alcohol mixing to get crosslinked action liquid.
Pretreatment biogas slurry: take biogas slurry 1:7:2 in mass ratio that the HCl solution that mass fraction is 20%, sodium citrate mixing is added Stirring, is stored at room temperature 2h, filters, and takes filtrate that the meal wheat stone mixing of filtrate quality 3% is added, stands, shakes 1h with 200r/min, Filtered fluid is collected in filtering, as pretreatment biogas slurry.
Plasticizer: 2:1:0.1 in mass ratio takes triethyl citrate, dioctyl phthalate, chlorinated paraffin mixing, i.e., Obtain plasticizer.
The preparation method of composite cable auxiliary material, includes the following steps:
(1) 5:1:3:0.1:50 in mass ratio takes the shrimp shell meal sieved with 100 mesh sieve, Grape Skin, yeast extract, casein, water in fermentor Mixing is stirred 15min with 400r/min, stands 2h, the pretreatment biogas slurry of shrimp shell meal quality 3% is added, with 350r/min After magnetic agitation 20min, sealing and standing is fermented 3 days, is discharged, filtering, is collected fermentation liquid and is transferred to high-pressure sterilizing pot, in 121 DEG C of items Insulated sterilizing 12min under part, obtains sterilized solution, takes sterilized solution in Rotary Evaporators, in 75 DEG C, concentrated by rotary evaporation 40min must be concentrated Liquid, in mass ratio 1:12 take concentrate, reagent A mixing, with 500r/min magnetic agitation 40min, obtain compound liquid；
(2) according to parts by weight, 20 parts of glucose, 2 parts of potassium dihydrogen phosphates, 8 portions of linseed oil, 2 parts of castor oil, 100 parts are successively taken The ethanol solution that volume fraction is 70% first takes glucose, potassium dihydrogen phosphate, ethanol solution to mix in batch mixer, in room temperature condition Under, 3h is stirred with 350r/min, linseed oil and castor oil mixing is added, in 55 DEG C, with 1200r/min high-speed stirred 40min obtains mixed liquid, takes mixed liquid 3:7:1:0.1 in mass ratio that compound liquid, crosslinked action liquid, auxiliary agent mixing is added, with 500r/min Magnetic agitation 40min moves to micro-wave oven with 400W power microwave and handles 8min, discharge, i.e., after 60 DEG C of rotary evaporation 30min Obtain composite cable auxiliary material.
The preparation method of composite modified resin ingredient, includes the following steps:
S1. 2:1:7 extracting epoxy resin, phenolic resin, the butanone that mass fraction is 12% mix in mass ratio, with 500r/min magnetic Power stirs 40min, adjusts pH to 1.3 with the HCl solution that mass fraction is 20%, obtains resin liquid, take resin liquid that resin liquid matter is added The aniline of amount 6%, the mixing of 2 times of resin liquid quality of acetone, move to ultrasonic oscillation instrument ultrasonic oscillation under 50kHz frequency 20min obtains dispersion liquid, takes dispersion liquid 12:1 in mass ratio that reagent B mixing is added, with 500r/min magnetic agitation 40min, must change Property resin,
S2. it takes stalk to crushed 80 meshes in pulverizer, takes sieving particle in steam blasting machine, 15 DEG C of Yu Wendu, press water material matter Amount takes bursting charge 1:15 in mass ratio that quality point is added than under 4:1, pressure 4.1MPa, Steam explosion treatment 4min obtains bursting charge Number is mixed for 15% NaOH solution, stands 3h, and filtering is dry in -20 DEG C of freeze drying box after taking filter cake to be rinsed with water 2 times Material must be lyophilized in dry 4h, take freeze-drying material 3:1:0.2:16 in mass ratio that Fanglun slurry cake, additive, acetone mixing is added, with 700r/ After min magnetic agitation 40min, refrigerator is moved in 2 DEG C of refrigeration 3h, filtering collects filter residue 1:5:0.01 in mass ratio and modification is added Resin, cobalt naphthenate mixing, mix 1h in 70 DEG C of heat, are naturally cooling to room temperature to get composite modified resin ingredient.
A kind of high-ductility abrasion-proof CABLE MATERIALS, according to the mass fraction, including following component: 4 parts of Corvics, 2 parts of butyronitrile Rubber, 0.1 part of nano-TiO2, 1 part of tert-butylhydroquinone, 2 parts of plasticizer, 5 parts of talcum powder, 12 parts of composite cable auxiliary materials, 20 parts of composite modified resin ingredients.
A kind of preparation method of high-ductility abrasion-proof CABLE MATERIALS, includes the following steps:
(1) according to the mass fraction, 4 parts of Corvics, 2 parts of nitrile rubbers, 0.1 part of nano-TiO are taken2, 1 part of tertiary butyl be to benzene Diphenol, 2 parts of plasticizer, 5 parts of talcum powder, 12 parts of composite cable auxiliary materials, 20 parts of composite modified resin ingredients；
(2) prior to 30 DEG C, Corvic, nitrile rubber, nano-TiO are taken2, plasticizer, talcum powder, composite cable auxiliary material It is mixed in batch mixer, with 600r/min magnetic agitation 40min, it is mixed to add composite modified resin ingredient, tert-butylhydroquinone It closes, with 1200r/min high-speed stirred 25min, moves to mixer, in 60 DEG C of mixing 30min, be warming up to 110 DEG C, mixing 25min Afterwards, investment twin screw extruder is granulated, and in 160 DEG C of melting extrusions, plastotype is cooling to get high-ductility abrasion-proof CABLE MATERIALS.
Reagent A: 8:1 in mass ratio takes the poly-vinyl alcohol solution that mass fraction is 10%, polypyrrole to mix to get reagent A.
Reagent B: the hydrochloric acid solution that sodium hydrogensulfite is added in sodium peroxydisulfate 2:1:12 in mass ratio, pH is 2.6 is taken to mix, i.e., Obtain reagent B.
Additive: carbon black, stearic acid, zinc oxide mixing is added to get additive in 1:5:0.3 in mass ratio.
Auxiliary agent: 1:3 in mass ratio takes OP-10, neopelex mixing to get auxiliary agent.
Crosslinked action liquid: 4:1:25 in mass ratio takes glutaraldehyde, terephthalaldehyde, dehydrated alcohol mixing to get crosslinked action liquid.
Pretreatment biogas slurry: take biogas slurry 1:9:2 in mass ratio that the HCl solution that mass fraction is 20%, sodium citrate mixing is added Stirring, is stored at room temperature 3h, filters, and takes filtrate that the meal wheat stone mixing of filtrate quality 5% is added, stands, shakes 2h with 225r/min, Filtered fluid is collected in filtering, as pretreatment biogas slurry.
Plasticizer: 3:1:0.1 in mass ratio takes triethyl citrate, dioctyl phthalate, chlorinated paraffin mixing, i.e., Obtain plasticizer.
The preparation method of composite cable auxiliary material, includes the following steps:
(1) 5:1:3:0.1:65 in mass ratio takes the shrimp shell meal sieved with 100 mesh sieve, Grape Skin, yeast extract, casein, water in fermentor Mixing is stirred 22min with 475r/min, stands 3h, the pretreatment biogas slurry of shrimp shell meal quality 5% is added, with 450r/min After magnetic agitation 30min, sealing and standing is fermented 4 days, is discharged, filtering, is collected fermentation liquid and is transferred to high-pressure sterilizing pot, in 121 DEG C of items Insulated sterilizing 16min under part, obtains sterilized solution, takes sterilized solution in Rotary Evaporators, in 80 DEG C, concentrated by rotary evaporation 50min must be concentrated Liquid, in mass ratio 1:16 take concentrate, reagent A mixing, with 650r/min magnetic agitation 50min, obtain compound liquid；
(2) according to parts by weight, 25 parts of glucose, 3 parts of potassium dihydrogen phosphates, 11 portions of linseed oil, 8 parts of castor oil, 125 parts are successively taken The ethanol solution that volume fraction is 70% first takes glucose, potassium dihydrogen phosphate, ethanol solution to mix in batch mixer, in room temperature condition Under, 4h is stirred with 450r/min, linseed oil and castor oil mixing is added, in 60 DEG C, with 1400r/min high-speed stirred 50min obtains mixed liquid, takes mixed liquid 3:10:1:0.1 in mass ratio that compound liquid, crosslinked action liquid, auxiliary agent mixing is added, with 650r/ Min magnetic agitation 50min moves to micro-wave oven with 400W power microwave and handles 10min, out after 70 DEG C of rotary evaporation 40min Material is to get composite cable auxiliary material.
The preparation method of composite modified resin ingredient, includes the following steps:
S1. 2:1:10 extracting epoxy resin, phenolic resin, the butanone that mass fraction is 12% mix in mass ratio, with 650r/min magnetic Power stirs 50min, adjusts pH to 1.5 with the HCl solution that mass fraction is 20%, obtains resin liquid, take resin liquid that resin liquid matter is added The aniline of amount 8%, the mixing of 3 times of resin liquid quality of acetone, move to ultrasonic oscillation instrument ultrasonic oscillation under 55kHz frequency 30min obtains dispersion liquid, takes dispersion liquid 16:1 in mass ratio that reagent B mixing is added, with 650r/min magnetic agitation 50min, must change Property resin,
S2. it takes stalk to crushed 80 meshes in pulverizer, takes sieving particle in steam blasting machine, 20 DEG C of Yu Wendu, press water material matter Amount takes bursting charge 1:20 in mass ratio that quality point is added than under 6:1, pressure 4.7MPa, Steam explosion treatment 6min obtains bursting charge Number is mixed for 15% NaOH solution, stands 4h, and filtering is dry in -20 DEG C of freeze drying box after taking filter cake to be rinsed with water 3 times Material must be lyophilized in dry 6h, take freeze-drying material 3:1:0.2:16 in mass ratio that Fanglun slurry cake, additive, acetone mixing is added, with 850r/ After min magnetic agitation 50min, refrigerator is moved in 3 DEG C of refrigeration 4h, filtering collects filter residue 1:6:0.01 in mass ratio and modification is added Resin, cobalt naphthenate mixing, mix 2h in 80 DEG C of heat, are naturally cooling to room temperature to get composite modified resin ingredient.
A kind of high-ductility abrasion-proof CABLE MATERIALS, according to the mass fraction, including following component: 6 parts of Corvics, 4 parts of butyronitrile Rubber, 0.2 part of nano-TiO2, 3 parts of tert-butylhydroquinones, 3 parts of plasticizer, 7 parts of talcum powder, 16 parts of composite cable auxiliary materials, 30 parts of composite modified resin ingredients.
A kind of preparation method of high-ductility abrasion-proof CABLE MATERIALS, includes the following steps:
(1) according to the mass fraction, 6 parts of Corvics, 3 parts of nitrile rubbers, 0.2 part of nano-TiO are taken2, 3 parts of tertiary butyls are to benzene Diphenol, 3 parts of plasticizer, 7 parts of talcum powder, 16 parts of composite cable auxiliary materials, 30 parts of composite modified resin ingredients；
(2) prior to 40 DEG C, Corvic, nitrile rubber, nano-TiO are taken2, plasticizer, talcum powder, composite cable auxiliary material It is mixed in batch mixer, with 800r/min magnetic agitation 50min, it is mixed to add composite modified resin ingredient, tert-butylhydroquinone It closes, with 1500r/min high-speed stirred 35min, moves to mixer, in 70 DEG C of mixing 45min, be warming up to 115 DEG C, mixing 35min Afterwards, investment twin screw extruder is granulated, and in 170 DEG C of melting extrusions, plastotype is cooling to get high-ductility abrasion-proof CABLE MATERIALS.
Reagent A: 10:1 in mass ratio takes the poly-vinyl alcohol solution that mass fraction is 10%, polypyrrole to mix to get reagent A.
Reagent B: the hydrochloric acid solution that sodium hydrogensulfite is added in sodium peroxydisulfate 2:1:15 in mass ratio, pH is 3.2 is taken to mix, i.e., Obtain reagent B.
Additive: carbon black, stearic acid, zinc oxide mixing is added to get additive in 1:6:0.3 in mass ratio.
Auxiliary agent: 1:5 in mass ratio takes OP-10, neopelex mixing to get auxiliary agent.
Crosslinked action liquid: 5:1:25 in mass ratio takes glutaraldehyde, terephthalaldehyde, dehydrated alcohol mixing to get crosslinked action liquid.
Pretreatment biogas slurry: take biogas slurry 1:10:2 in mass ratio that HCl solution, sodium citrate that mass fraction is 20% is added mixed Stirring is closed, 4h is stored at room temperature, is filtered, takes filtrate that the meal wheat stone mixing of filtrate quality 7% is added, stands, shaken with 250r/min Filtered fluid is collected in 3h, filtering, as pretreatment biogas slurry.
Plasticizer: 5:1:0.1 in mass ratio takes triethyl citrate, dioctyl phthalate, chlorinated paraffin mixing, i.e., Obtain plasticizer.
The preparation method of composite cable auxiliary material, includes the following steps:
(1) 5:1:3:0.1:85 in mass ratio takes the shrimp shell meal sieved with 100 mesh sieve, Grape Skin, yeast extract, casein, water in fermentor Mixing is stirred 30min with 550r/min, stands 4h, the pretreatment biogas slurry of shrimp shell meal quality 7% is added, with 550r/min After magnetic agitation 45min, sealing and standing is fermented 5 days, is discharged, filtering, is collected fermentation liquid and is transferred to high-pressure sterilizing pot, in 121 DEG C of items Insulated sterilizing 18min under part, obtains sterilized solution, takes sterilized solution in Rotary Evaporators, in 85 DEG C, concentrated by rotary evaporation 60min must be concentrated Liquid, in mass ratio 1:20 take concentrate, reagent A mixing, with 800r/min magnetic agitation 60min, obtain compound liquid；
(2) according to parts by weight, 30 parts of glucose, 5 parts of potassium dihydrogen phosphates, 15 portions of linseed oil, 15 parts of castor oil, 150 are successively taken The ethanol solution that part volume fraction is 70% first takes glucose, potassium dihydrogen phosphate, ethanol solution to mix in batch mixer, in room temperature item Under part, 5h is stirred with 550r/min, linseed oil and castor oil mixing is added, in 65 DEG C, with 1600r/min high-speed stirred 60min obtains mixed liquid, takes mixed liquid 3:12:1:0.1 in mass ratio that compound liquid, crosslinked action liquid, auxiliary agent mixing is added, with 800r/ Min magnetic agitation 60min moves to micro-wave oven with 400W power microwave and handles 13min, out after 80 DEG C of rotary evaporation 55min Material is to get composite cable auxiliary material.
The preparation method of composite modified resin ingredient, includes the following steps:
S1. 2:1:13 extracting epoxy resin, phenolic resin, the butanone that mass fraction is 12% mix in mass ratio, with 800r/min magnetic Power stirs 60min, adjusts pH to 1.7 with the HCl solution that mass fraction is 20%, obtains resin liquid, take resin liquid that resin liquid matter is added The aniline of amount 10%, the mixing of 4 times of resin liquid quality of acetone, move to ultrasonic oscillation instrument ultrasonic oscillation under 65kHz frequency 35min obtains dispersion liquid, takes dispersion liquid 20:1 in mass ratio that reagent B mixing is added, with 800r/min magnetic agitation 60min, must change Property resin,
S2. it takes stalk to crushed 80 meshes in pulverizer, takes sieving particle in steam blasting machine, 25 DEG C of Yu Wendu, press water material matter Amount takes bursting charge 1:25 in mass ratio that quality point is added than under 8:1, pressure 5.3MPa, Steam explosion treatment 8min obtains bursting charge Number is mixed for 15% NaOH solution, stands 5h, and filtering is dry in -20 DEG C of freeze drying box after taking filter cake to be rinsed with water 4 times Material must be lyophilized in dry 8h, take freeze-drying material 3:1:0.2:16 in mass ratio that Fanglun slurry cake, additive, acetone mixing is added, with 1000r/ After min magnetic agitation 60min, refrigerator is moved in 5 DEG C of refrigeration 5h, filtering collects filter residue 1:8:0.01 in mass ratio and modification is added Resin, cobalt naphthenate mixing, mix 3h in 85 DEG C of heat, are naturally cooling to room temperature to get composite modified resin ingredient.
A kind of high-ductility abrasion-proof CABLE MATERIALS, according to the mass fraction, including following component: 8 parts of Corvics, 5 parts of butyronitrile Rubber, 0.3 part of nano-TiO2, 4 parts of tert-butylhydroquinones, 5 parts of plasticizer, 8 parts of talcum powder, 20 parts of composite cable auxiliary materials, 35 parts of composite modified resin ingredients.
A kind of preparation method of high-ductility abrasion-proof CABLE MATERIALS, includes the following steps:
(1) according to the mass fraction, 8 parts of Corvics, 5 parts of nitrile rubbers, 0.3 part of nano-TiO are taken2, 4 parts of tertiary butyls are to benzene Diphenol, 5 parts of plasticizer, 8 parts of talcum powder, 20 parts of composite cable auxiliary materials, 35 parts of composite modified resin ingredients；
(2) prior to 45 DEG C, Corvic, nitrile rubber, nano-TiO are taken2, plasticizer, talcum powder, composite cable auxiliary material It is mixed in batch mixer, with 1000r/min magnetic agitation 60min, it is mixed to add composite modified resin ingredient, tert-butylhydroquinone It closes, with 1800r/min high-speed stirred 45min, moves to mixer, in 80 DEG C of mixing 60min, be warming up to 120 DEG C, mixing 45min Afterwards, investment twin screw extruder is granulated, and in 180 DEG C of melting extrusions, plastotype is cooling to get high-ductility abrasion-proof CABLE MATERIALS.
Comparative example 1: it is essentially identical with the preparation method of embodiment 1, it has only the difference is that lacking composite cable auxiliary material.
Comparative example 2: it is essentially identical with the preparation method of embodiment 1, it has only the difference is that lacking composite modified resin ingredient.
Comparative example 3: the high-ductility abrasion-proof CABLE MATERIALS of Nanjing company production.
By high-ductility abrasion-proof CABLE MATERIALS obtained by embodiment and comparative example according to GB/T32129-2015, GB/T1040-2006 into Row test, test result are as shown in table 1:
Table 1:
Test item Embodiment 1 Embodiment 2 Embodiment 3 Comparative example 1 Comparative example 2 Comparative example 3
Tensile strength (MPa) 30 28 29 25 26 15
Elongation at break (%) 445 440 435 426 415 385
Wearability Preferably Preferably Preferably Preferably Generally It is poor
In summary, the resulting high-ductility abrasion-proof CABLE MATERIALS toughness of the present invention is preferable and wear-resisting, more preferable compared to commercial product effect, It is worth promoting.
The foregoing is merely preferred modes of the invention, are not intended to limit the invention, all in spirit and original of the invention Within then, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of high-ductility abrasion-proof CABLE MATERIALS, according to the mass fraction, including following component: 4 ~ 8 parts of Corvics, 2 ~ 5 parts of fourths Nitrile rubber, 0.1 ~ 0.3 part of nano-TiO2, 1 ~ 4 part of tert-butylhydroquinone, 2 ~ 5 parts of plasticizer, 5 ~ 8 parts of talcum powder, feature exists In, further includes: 12 ~ 20 parts of composite cable auxiliary materials, 20 ~ 35 parts of composite modified resin ingredients.
2. a kind of high-ductility abrasion-proof CABLE MATERIALS according to claim 1, which is characterized in that the preparation of the composite cable auxiliary material Method includes the following steps:
(1) 5:1:3:0.1:50 ~ 85 take shrimp shell meal, Grape Skin, yeast extract, casein, water to be mixed in mass ratio, stand, add Enter the pretreatment biogas slurry of shrimp shell meal quality 3 ~ 7%, stir, sealing and standing fermentation discharges, and filtering is collected fermentation liquid sterilizing, obtained Sterilized solution takes sterilized solution in 75 ~ 85 DEG C of concentrated by rotary evaporations, obtains concentrate, and 1:12 ~ 20 in mass ratio take concentrate, reagent A mixing to stir It mixes, obtains compound liquid；
(2) according to parts by weight, 20 ~ 30 parts of glucose, 2 ~ 5 parts of potassium dihydrogen phosphates, 8 ~ 15 portions of linseed oil, 2 ~ 15 portions of castor-oil plants are taken Oil, 100 ~ 150 parts of ethanol solutions first take glucose, potassium dihydrogen phosphate, ethanol solution mixing, and room temperature is stirred, and are added sub- Sesame oil and castor oil mixing, in 55 ~ 65 DEG C, high-speed stirred obtains mixed liquid, takes mixed liquid 3:7 ~ 12:1:0.1 in mass ratio that compound is added Liquid, crosslinked action liquid, auxiliary agent are mixed, and in 60 ~ 80 DEG C of rotary evaporations, microwave treatment, discharging is to get composite cable auxiliary Material.
3. a kind of high-ductility abrasion-proof CABLE MATERIALS according to claim 2, which is characterized in that the pretreatment natural pond in the step (1) Liquid: it takes biogas slurry 1:7 ~ 10:2 in mass ratio that HCl solution, sodium citrate mixing is added, is stored at room temperature, filters, filtrate is taken to add The meal wheat stone mixing for entering filtrate quality 3 ~ 7%, stands, shakes, and filtered fluid is collected in filtering, as pretreatment biogas slurry.
4. a kind of high-ductility abrasion-proof CABLE MATERIALS according to claim 2, which is characterized in that the reagent A in the step (1): press 7 ~ 10:1 of mass ratio takes poly-vinyl alcohol solution, polypyrrole mixing to get reagent A.
5. a kind of high-ductility abrasion-proof CABLE MATERIALS according to claim 2, which is characterized in that the auxiliary agent in the step (2): pressing matter Amount takes OP-10, neopelex mixing to get auxiliary agent than 1:2 ~ 5.
6. a kind of high-ductility abrasion-proof CABLE MATERIALS according to claim 2, which is characterized in that the crosslinked action in the step (2) Liquid: 2 ~ 5:1:25 in mass ratio takes glutaraldehyde, terephthalaldehyde, dehydrated alcohol mixing to get crosslinked action liquid.
7. a kind of high-ductility abrasion-proof CABLE MATERIALS according to claim 1, which is characterized in that the system of the composite modified resin ingredient Preparation Method includes the following steps:
S1. the extracting epoxy resin of 2:1:7 in mass ratio ~ 13, phenolic resin, butanone are mixed, and adjust pH, obtain resin liquid, take tree The aniline of resin liquid quality 6 ~ 10%, the mixing of 2 ~ 4 times of resin liquid quality of acetone is added in rouge liquid, and ultrasonic oscillation obtains dispersion liquid, It takes dispersion liquid 12 ~ 20:1 in mass ratio that reagent B is added to be mixed, obtains modified resin,
S2. it takes stalk to pulverize and sieve, takes sieving particle Steam explosion treatment, obtain bursting charge, take bursting charge 1:15 ~ 25 in mass ratio NaOH solution is added to be mixed, stands, filtering takes filter cake to wash, and is freeze-dried, material must be lyophilized, and takes freeze-drying material in mass ratio 3:1:0.2:16 is added Fanglun slurry cake, additive, acetone and is mixed, and refrigerates, filtering, collects filter residue 1:5 ~ 8 in mass ratio: 0.01 is added modified resin, cobalt naphthenate mixing, mixed in 70 ~ 85 DEG C of heat, cools down to get composite modified resin ingredient.
8. a kind of high-ductility abrasion-proof CABLE MATERIALS according to claim 7, which is characterized in that the reagent B in the step S1: took Sodium hydrogensulfite, hydrochloric acid solution mixing is added to get reagent B in sodium sulphate 2:1:10 in mass ratio ~ 15.
9. a kind of high-ductility abrasion-proof CABLE MATERIALS according to claim 7, which is characterized in that the additive in the step S2: press Carbon black, stearic acid, zinc oxide mixing is added to get additive in mass ratio 1:3 ~ 6:0.3.
10. a kind of high-ductility abrasion-proof CABLE MATERIALS according to claim 1, which is characterized in that the plasticizer: in mass ratio 2 ~ 5: 1:0.1 takes triethyl citrate, dioctyl phthalate, chlorinated paraffin mixing to get plasticizer.
CN201910326182.4A 2019-04-23 2019-04-23 A kind of high-ductility abrasion-proof CABLE MATERIALS Pending CN110041661A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910326182.4A CN110041661A (en) 2019-04-23 2019-04-23 A kind of high-ductility abrasion-proof CABLE MATERIALS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910326182.4A CN110041661A (en) 2019-04-23 2019-04-23 A kind of high-ductility abrasion-proof CABLE MATERIALS

Publications (1)

Publication Number Publication Date
CN110041661A true CN110041661A (en) 2019-07-23

Family

ID=67278575

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910326182.4A Pending CN110041661A (en) 2019-04-23 2019-04-23 A kind of high-ductility abrasion-proof CABLE MATERIALS

Country Status (1)

Country Link
CN (1) CN110041661A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110649355A (en) * 2019-09-29 2020-01-03 四川天邑康和通信股份有限公司 Radio frequency cable and preparation process thereof
CN114213809A (en) * 2022-01-21 2022-03-22 江西师范大学 Wear-resistant insulating material for computer twisted pair and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103897294A (en) * 2014-03-04 2014-07-02 新泰市东兴橡胶有限公司 Polyvinyl chloride cable material
CN104861397A (en) * 2015-06-02 2015-08-26 珠海汉胜科技股份有限公司 Polyvinyl chloride cable material and preparation method thereof
CN106117824A (en) * 2016-07-25 2016-11-16 安徽德源电缆集团有限公司 A kind of preparation method of ethylene propylene rubber insulated electric cable with silicon rubber sheath material
CN109096691A (en) * 2018-08-17 2018-12-28 佛山朝鸿新材料科技有限公司 A kind of wear-resistant cable sheath material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103897294A (en) * 2014-03-04 2014-07-02 新泰市东兴橡胶有限公司 Polyvinyl chloride cable material
CN104861397A (en) * 2015-06-02 2015-08-26 珠海汉胜科技股份有限公司 Polyvinyl chloride cable material and preparation method thereof
CN106117824A (en) * 2016-07-25 2016-11-16 安徽德源电缆集团有限公司 A kind of preparation method of ethylene propylene rubber insulated electric cable with silicon rubber sheath material
CN109096691A (en) * 2018-08-17 2018-12-28 佛山朝鸿新材料科技有限公司 A kind of wear-resistant cable sheath material

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110649355A (en) * 2019-09-29 2020-01-03 四川天邑康和通信股份有限公司 Radio frequency cable and preparation process thereof
CN110649355B (en) * 2019-09-29 2021-06-25 四川天邑康和通信股份有限公司 Radio frequency cable and preparation process thereof
CN114213809A (en) * 2022-01-21 2022-03-22 江西师范大学 Wear-resistant insulating material for computer twisted pair and preparation method thereof
CN114213809B (en) * 2022-01-21 2024-02-09 广州华速信息技术有限公司 Wear-resistant insulating material for computer twisted pair and preparation method thereof

Similar Documents

Publication Publication Date Title
CN110218401B (en) Flame-retardant smoke-inhibiting soft polyvinyl chloride composite material with good mechanical property and preparation method thereof
CN110041661A (en) A kind of high-ductility abrasion-proof CABLE MATERIALS
CN102643469B (en) LDPE (Low-Density Polyethylene)/EVA (Ethylene Vinyl Acetate Copolymer) anti-flaming material and preparation method thereof
CN102977451B (en) For the low-smoke halogen-free flame-retardant sheath layer of optical cable
CN107400286A (en) The PE materials and its preparation technology of a kind of high barrier
CN108148290A (en) A kind of cable cover(ing)
CN105315399A (en) Highly-transparent flame-retardant modified organic glass and preparation method thereof
CN101056531A (en) Flame-resisting anti-static polythene compound film for shielding wide band electromagnetic wave and its preparing method
CN104559100A (en) Functional cyclodextrin flame-retarding polylactic acid composite material and preparation method thereof
CA2435172A1 (en) Biodegradable polyurethane capsules and manufacturing method thereof
CN110079073A (en) CABLE MATERIALS of high flame resistance and preparation method thereof
CN1155633C (en) Prepn. of maleic anhydride grafted ethylene-alpha-octylene copolymers
CN113845734A (en) Thermoplastic polypropylene cable insulating material for high voltage and preparation method thereof
CN104592710A (en) Heat-resistant flame-retardant wave-absorbing insulating material and preparation method thereof
CN102010537A (en) Modified anti-flaming environmental-friendly insulating material prepared by blending regenerative polyolefin/nano magnesium hydroxide
CN105860474A (en) Heat and solvent resisting lightweight alloy and preparation method thereof
CN108892931A (en) A kind of high pressure resistant cable jacking and preparation method thereof
CN108841069A (en) A kind of door and window is with highstrenghtpiston and preparation method thereof
CN111074373B (en) Flame-retardant antibacterial PTT fiber material and preparation method therefor
CN109880369A (en) A kind of nano-TiO2Composite material and preparation method
CN112143248A (en) High-temperature-resistant degradable environment-friendly insulating material and preparation process thereof
CN103012851A (en) Preparation method of superfine modified brucite flame retardant and application of superfine modified brucite flame-retardant to PVC (Polyvinyl Chloride) cable material
CN113388242A (en) Novel PME plastic
CN114703687B (en) Color cake for coloring artificial leather and preparation method thereof
CN110903544A (en) Lithium ion battery flame-retardant material for energy storage and preparation method and application thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination