CN110041656A - A kind of flame retardant type high-concentration color masterbatch - Google Patents
A kind of flame retardant type high-concentration color masterbatch Download PDFInfo
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- CN110041656A CN110041656A CN201910398179.3A CN201910398179A CN110041656A CN 110041656 A CN110041656 A CN 110041656A CN 201910398179 A CN201910398179 A CN 201910398179A CN 110041656 A CN110041656 A CN 110041656A
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2455/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2423/00 - C08J2453/00
- C08J2455/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K2003/026—Phosphorus
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K3/2279—Oxides; Hydroxides of metals of antimony
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
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Abstract
The present invention relates to a kind of flame retardant type high-concentration color masterbatch, include following components according to mass fraction meter: 6-11 parts of titanium dioxides；3-8 parts of dispersing agents；6-15 parts of fire retardants: the fire retardant includes 40% organic fire-retardant, 60% inorganic fire retardants；Wherein, mass percent 40% is organic phosphorus, organic fire-retardant of 60% nitrogen silicon fire retardant；The inorganic fire retardants of 20% borate of mass percent, 10% organosilicon oxide, 20% molybdenum trioxide, 30% antimony oxide, 20% red phosphorus；5-12 parts of pigment；Carrier: 4-10 parts of PE resins, 8-20 parts of ABS resins.It is simple and convenient to be processed into material, reaches V-1 grades of fire protection flame retarding requirements, it is tough and tensile, weather resistance is good, good stability of the dimension, molding shrinkage are small.
Description
Technical field
The present invention relates to Masterbatch technical fields, and in particular to a kind of flame retardant type high-concentration color masterbatch.
Background technique
Color masterbatch be the pigment of super quantity is uniformly attached among resin prepared by aggregation.Color masterbatch also known as color kind, color
Mother is a kind of novel high polymer material special coloring agent, also known as pigment preparation matter.It is mainly by pigment, carrier and three kinds of additive
Fundamental is formed, and is aggregation obtained from the pigment of super quantity is equably attached among resin, pigment can be claimed dense
Contracting object, so his tinting strength, tinting power is higher than pigment itself.
Summary of the invention
It is an object of the present invention to provide a kind of flame retardant type high-concentration color masterbatch, it is simple and convenient to be processed into material, reaches V-1 grades of fire prevention
Flame-retardancy requirements, it is tough and tensile, weather resistance is good, good stability of the dimension, molding shrinkage are small.
In order to achieve the goal above, the technical solution adopted by the present invention are as follows: a kind of flame retardant type high-concentration color masterbatch, according to matter
Measuring number meter includes following components: 6-11 parts of titanium dioxides；3-8 parts of dispersing agents；
6-15 parts of fire retardants: the fire retardant includes 40% organic fire-retardant, 60% inorganic fire retardants；Wherein, quality
Percentage 40% is organic phosphorus, 60% nitrogen silicon fire retardant organic fire-retardant；20% borate of mass percent, 10% organosilicon oxygen
The inorganic fire retardants of compound, 20% molybdenum trioxide, 30% antimony oxide, 20% red phosphorus；
5-12 parts of pigment；
Carrier: 4-10 parts of PE resins, 8-20 parts of ABS resins.
Preferably, a kind of flame retardant type high-concentration color masterbatch, includes following components according to mass fraction meter: 7 parts of titanium dioxides；4
Part dispersing agent；9 parts of fire retardants；7 parts of pigment；
Carrier: 7 parts of PE resins, 16 parts of ABS resins.
Further, the dispersing agent is EVA wax.
Further, the titanium dioxide is anatase thpe white powder, 65% rutile titanium dioxide of mass percent 35%
Powder.
The technical effects of the invention are that: the present invention may include organic pigment and inorganic pigment, organic pigment using pigment
It include: red phthalocyanine, phthalocyanine blue, phthalocyanine green, everbright fast red, macromolecular is red, macromolecular is yellow, permanent yellow, permanent violet.Inorganic pigment packet
It includes: cadmium red, cadmium yellow, titanium dioxide, carbon black, iron oxide red, iron oxide yellow.Carrier is the matrix of Masterbatch.The present invention uses PE tree
Rouge, ABS resin are as carrier, and the compatibility of the two is good, while the good fluidity of carrier, PE resin, ABS resin as carrier,
PE resin can be adapted for the coloring of ABS resin, simple and convenient at expecting.Dispersing agent promotes pigment is evenly dispersed not re-unite,
The present invention using polyethylene low-molecular-weight wax, stearate as dispersing agent, fusing point ratio PE resin, ABS resin are low, with PE resin,
ABS resin has good compatibility and pigment to have preferable affinity.
Material of the present invention reaches V-1 grades of fire protection flame retarding requirements.And the application uses additive flame retardant, that is, is added fire-retardant
Agent reduces material polymerization thermal cracking flammable product generated, the present invention is using organic to change the thermal degradation mode of material
Additive flame retardant and inorganic additive flame retardant mixing fire retardant, wherein organic additive flame retardant using organic phosphorus, nitrogen,
Silicon fire retardant.Additive amount using these small organic molecule fire retardants is few, the inorganic addition used while flame retardant effect is obvious
Type fire retardant borate, organosilicon oxide, red phosphorus, molybdenum trioxide, antimony oxide reach fire protection flame retarding requirement and in products
It is not easy to decompose in processing and forming temperature course, and acrylonitrile-butadiene-styrene copolymer (ABS) Masterbatch is due to ABS
The effect cooperation PE resin of resin is as carrier, and material hardness is high, tough and tensile, weather resistance is good, creep resistant is good, dimensional stability
Well, molding shrinkage is small.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
The present invention may include organic pigment and inorganic pigment using pigment, and organic pigment includes: red phthalocyanine, phthalocyanine blue, phthalein
Cyanines are green, everbright fast red, macromolecular is red, macromolecular is yellow, permanent yellow, permanent violet.Inorganic pigment include: cadmium red, cadmium yellow, titanium dioxide,
Carbon black, iron oxide red, iron oxide yellow.Carrier is the matrix of Masterbatch.The present invention using PE resin, ABS resin as carrier, two
The compatibility of person is good, while the good fluidity of carrier, and as carrier, PE resin can be adapted for ABS tree for PE resin, ABS resin
The coloring of rouge, it is simple and convenient at expecting.Dispersing agent promotes pigment is evenly dispersed not re-unite, and the present invention uses polyethylene low molecule
As dispersing agent, fusing point ratio PE resin, ABS resin are low for wax, stearate, have good compatibility with PE resin, ABS resin,
There is preferable affinity with pigment.
Material of the present invention reaches V-1 grades of fire protection flame retarding requirements.And the application uses additive flame retardant, that is, is added fire-retardant
Agent reduces material polymerization thermal cracking flammable product generated, the present invention is using organic to change the thermal degradation mode of material
Additive flame retardant and inorganic additive flame retardant mixing fire retardant, wherein organic additive flame retardant using organic phosphorus, nitrogen,
Silicon fire retardant.Additive amount using these small organic molecule fire retardants is few, the inorganic addition used while flame retardant effect is obvious
Type fire retardant borate, organosilicon oxide, red phosphorus, molybdenum trioxide, antimony oxide reach fire protection flame retarding requirement and in products
It is not easy to decompose in processing and forming temperature course, and acrylonitrile-butadiene-styrene copolymer (ABS) Masterbatch is due to ABS
The effect cooperation PE resin of resin is as carrier, and material hardness is high, tough and tensile, weather resistance is good, creep resistant is good, dimensional stability
Well, molding shrinkage is small.
Furthermore material covering not only can be improved using two kinds of anatase titanium dioxide, rutile-type titanium dioxide mixing in titanium dioxide of the present invention
Power, and improve material weatherability, fade resistance.
Embodiment 1: a kind of flame retardant type high-concentration color masterbatch, includes following components according to mass fraction meter: 7 parts of titanium dioxides；4
Part dispersing agent；9 parts of fire retardants；7 parts of pigment；
Carrier: 7 parts of PE resins, 16 parts of ABS resins；
6-15 parts of fire retardants: the fire retardant includes 40% organic fire-retardant, 60% inorganic fire retardants；Wherein, quality
Percentage 40% is organic phosphorus, 60% nitrogen silicon fire retardant organic fire-retardant；20% borate of mass percent, 10% organosilicon oxygen
The inorganic fire retardants of compound, 20% molybdenum trioxide, 30% antimony oxide, 20% red phosphorus.
Preferably, a kind of flame retardant type high-concentration color masterbatch, includes following components according to mass fraction meter:
Further, the dispersing agent is EVA wax.
Further, the titanium dioxide is anatase thpe white powder, 65% rutile titanium dioxide of mass percent 35%
Powder.
20 are extracted, average tensile strength reaches 37.8Mpa, and fire protection flame retarding requires to reach V-1 grades.
Embodiment 2: a kind of flame retardant type high-concentration color masterbatch, includes following components according to mass fraction meter: 6 parts of titanium dioxides；3
Part dispersing agent；
6 parts of fire retardants: the fire retardant includes 40% organic fire-retardant, 60% inorganic fire retardants；Wherein, quality percentage
More organic phosphorus than 40%, 60% nitrogen silicon fire retardant organic fire-retardant；20% borate of mass percent, the oxidation of 10% organosilicon
The inorganic fire retardants of object, 20% molybdenum trioxide, 30% antimony oxide, 20% red phosphorus；
5 parts of pigment；
Carrier: 4 parts of PE resins, 8 parts of ABS resins.
Further, the dispersing agent is EVA wax.
Further, the titanium dioxide is anatase thpe white powder, 65% rutile titanium dioxide of mass percent 35%
Powder.
20 are extracted, average tensile strength reaches 37.0Mpa, and fire protection flame retarding requires to reach V-1 grades.
Embodiment 3: a kind of flame retardant type high-concentration color masterbatch, includes following components according to mass fraction meter: 11 parts of titanium dioxides；
8 parts of dispersing agents；
15 parts of fire retardants: the fire retardant includes 40% organic fire-retardant, 60% inorganic fire retardants；Wherein, quality hundred
Divide more organic phosphorus than 40%, 60% nitrogen silicon fire retardant organic fire-retardant；20% borate of mass percent, the oxidation of 10% organosilicon
The inorganic fire retardants of object, 20% molybdenum trioxide, 30% antimony oxide, 20% red phosphorus；
12 parts of pigment；
Carrier: 10 parts of PE resins, 20 parts of ABS resins.
Further, the dispersing agent is EVA wax.
Further, the titanium dioxide is anatase thpe white powder, 65% rutile titanium dioxide of mass percent 35%
Powder.
20 are extracted, average tensile strength reaches 37.2Mpa, and fire protection flame retarding requires to reach V-1 grades.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.
Claims (4)
1. a kind of flame retardant type high-concentration color masterbatch, which is characterized in that according to mass fraction meter include following components: 6-11 parts of titanium whites
Powder；3-8 parts of dispersing agents；
6-15 parts of fire retardants: the fire retardant includes 40% organic fire-retardant, 60% inorganic fire retardants；Wherein, quality percentage
More organic phosphorus than 40%, 60% nitrogen silicon fire retardant organic fire-retardant；20% borate of mass percent, the oxidation of 10% organosilicon
The inorganic fire retardants of object, 20% molybdenum trioxide, 30% antimony oxide, 20% red phosphorus；
5-12 parts of pigment；
Carrier: 4-10 parts of PE resins, 8-20 parts of ABS resins.
2. a kind of flame retardant type high-concentration color masterbatch according to claim 1, which is characterized in that include according to mass fraction meter
Following components: 7 parts of titanium dioxides；4 parts of dispersing agents；9 parts of fire retardants；7 parts of pigment；
Carrier: 7 parts of PE resins, 16 parts of ABS resins.
3. a kind of flame retardant type high-concentration color masterbatch according to claim 1 or 2, which is characterized in that the dispersing agent is
EVA wax.
4. a kind of flame retardant type high-concentration color masterbatch according to claim 1 or 2, which is characterized in that the titanium dioxide is
The anatase thpe white powder of mass percent 35%, 65% rutile type titanium white.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910398179.3A CN110041656A (en) | 2019-05-14 | 2019-05-14 | A kind of flame retardant type high-concentration color masterbatch |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910398179.3A CN110041656A (en) | 2019-05-14 | 2019-05-14 | A kind of flame retardant type high-concentration color masterbatch |
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| CN110041656A true CN110041656A (en) | 2019-07-23 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110938277A (en) * | 2019-12-07 | 2020-03-31 | 绍兴市上虞鸿越塑业有限公司 | Production process of flame-retardant color master batch |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106750835A (en) * | 2017-03-28 | 2017-05-31 | 东莞市志和色母科技有限公司 | A kind of fire-retardant uvioresistant color masterbatch and preparation method thereof |
| CN107033442A (en) * | 2017-06-27 | 2017-08-11 | 天津毅兴彩科技有限公司 | A kind of ABS color master batch |
-
2019
- 2019-05-14 CN CN201910398179.3A patent/CN110041656A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106750835A (en) * | 2017-03-28 | 2017-05-31 | 东莞市志和色母科技有限公司 | A kind of fire-retardant uvioresistant color masterbatch and preparation method thereof |
| CN107033442A (en) * | 2017-06-27 | 2017-08-11 | 天津毅兴彩科技有限公司 | A kind of ABS color master batch |
Non-Patent Citations (1)
| Title |
|---|
| 童佳民等编: "《高效建筑消防-上卷》", 31 January 2012 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110938277A (en) * | 2019-12-07 | 2020-03-31 | 绍兴市上虞鸿越塑业有限公司 | Production process of flame-retardant color master batch |
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