CN110039883A - A kind of production method of metal alloy composite halftone - Google Patents
A kind of production method of metal alloy composite halftone Download PDFInfo
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- CN110039883A CN110039883A CN201910402195.5A CN201910402195A CN110039883A CN 110039883 A CN110039883 A CN 110039883A CN 201910402195 A CN201910402195 A CN 201910402195A CN 110039883 A CN110039883 A CN 110039883A
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- metal alloy
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C1/00—Forme preparation
- B41C1/14—Forme preparation for stencil-printing or silk-screen printing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C1/00—Forme preparation
- B41C1/14—Forme preparation for stencil-printing or silk-screen printing
- B41C1/145—Forme preparation for stencil-printing or silk-screen printing by perforation using an energetic radiation beam, e.g. a laser
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C1/00—Forme preparation
- B41C1/14—Forme preparation for stencil-printing or silk-screen printing
- B41C1/147—Forme preparation for stencil-printing or silk-screen printing by imagewise deposition of a liquid, e.g. from an ink jet; Chemical perforation by the hardening or solubilizing of the ink impervious coating or sheet
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/04—Printing plates or foils; Materials therefor metallic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/12—Printing plates or foils; Materials therefor non-metallic other than stone, e.g. printing plates or foils comprising inorganic materials in an organic matrix
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/24—Stencils; Stencil materials; Carriers therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/24—Stencils; Stencil materials; Carriers therefor
- B41N1/247—Meshes, gauzes, woven or similar screen materials; Preparation thereof, e.g. by plasma treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N3/00—Preparing for use and conserving printing surfaces
- B41N3/006—Cleaning, washing, rinsing or reclaiming of printing formes other than intaglio formes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N3/00—Preparing for use and conserving printing surfaces
- B41N3/06—Preparing for use and conserving printing surfaces by use of detergents
Abstract
The invention discloses a kind of production methods of metal alloy composite halftone, comprising the following specific steps 1) drawing in the net compound;2) alloy sheet pattern outer profile makes;3) film layer makes;4) adhesion layer is coated with;5) overlay film;6) it dries;7) laser;8) it cleans;9) detection packaging.Through the above way, the production method of metal alloy composite halftone provided by the invention, traditional screen cloth is replaced using metal alloy film, with relatively low elongation percentage, better dimensional stability, printability resistance, it is resistance to puncture, metal alloy film and film layer dual support, the bond strength service life far more than silk screen and film layer can promote 30% or more, under the action of high molecular bonding glue, keep polymer compound layer adhesion strength extremely strong, it is not easily to fall off, plate-making yield greatly improved, save production cost, and printing is good, line style is good, there is the promotion become apparent to cell piece efficiency in this way.
Description
Technical field
The present invention relates to the technical fields of the printed elements such as solar battery sheet, high-accuracy electronic component, more particularly to
A kind of production method of metal alloy composite halftone.
Background technique
With the increasingly increasing of energy demand, energy problem has become restriction the great of international community's economic development and asks
Topic, this promotes people constantly to explore new energy, and wherein the research of solar energy occupies critical role.Solar battery is as too
One of the core technology that sun can be studied, has also obtained quick development, the transformation efficiency for improving solar battery is mesh in recent years
The main study subject of preceding solar battery, in addition to cell substrate material selection and optimization, the improvement of cell piece manufacture craft etc. are wanted
It asks outer, the printing process of suitable high-precision and high-stability is taken to can also be improved the transformation efficiency of solar battery.In the sun
In the printing process of energy battery, the use of printing screen plate has a significant impact to final printing quality.
The conventional solar cell piece printing production method of composite halftone, is typically coated with one on the silk screen to have stretched tight
The emulsion of the photosensitive class of layer, uniform adhesion recycles the shading of film pattern, is exposed on exposure machine on silk screen after drying
The part of light, pattern light leakage solidifies under the action of photosensitizer, and the part of shading does not solidify, and when development, which will rinse out, not to be solidified
Emulsion, the figure just needed on the halftone space of a whole page, to complete the transfer of figure.The halftone of which production has one
Fixed limitation: one, emulsion bad assurance of resolution under the action of light, the flatness of line edge after exposure development
It is bad, it is easy when use to influence the printing quality of lines;Two, the adhesion strength of emulsion and steel wire grenadine is bad, after exposure development very
It is easy to cause space of a whole page emulsion to fall off, to largely effect on plate-making yield;Three, emulsion wearability is bad, is rubbed when printing with substrate
Wiping is prone to wear spillage, influences surface printing quality and service life;Four, lines are influenced by light ray energy stability when exposing
It is larger, it is easy to cause line weight uneven, when batch making influences production yield, and when use influences printing stability;Five, by
The influence of emulsion strike through, printing lines can not narrow down to narrower range, be unable to satisfy the requirement of high-precision hachure printing.
In conjunction with above-mentioned limitation, we constantly make the halftone of printing in the new process of exploration.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of production methods of metal alloy composite halftone, using metal
Alloy sheet replaces traditional screen cloth, has a relatively low elongation percentage, better dimensional stability, printability resistance, it is resistance to puncture, metal closes
Gold plaque and film layer dual support, the bond strength service life far more than silk screen and film layer can promote 30% or more, in high molecular bonding
Under the action of glue, keep polymer compound layer adhesion strength extremely strong, it is not easily to fall off, plate-making yield greatly improved, saving is produced into
This, film layer broken hole not easy to wear, printing service life are enhanced about more than once halftone when in use, and printing later period printing lines will not
It widens, has a clear superiority to cell piece efficiency, the halftone lines strike through of production is more preferable, therefore it is narrow substantially to compress high-precision
The limitation of line width, and print well, line style is good, there is the promotion become apparent to cell piece efficiency in this way.
In order to solve the above technical problems, one technical scheme adopted by the invention is that: it is compound to provide a kind of metal alloy
The production method of halftone, comprising the following specific steps
1) it draws in the net compound: first carrying out polyester webs stretching, polyester grenadine is fixed on screen frame after standing and forms polyester webs, then
Metal alloy film is combined to the recombination region among polyester webs using hot melt adhesive and forms composite metal, under the action of pushing up net machine
Certain tension is obtained, composite metal is fixed on another screen frame, compound white version is obtained;
2) alloy sheet pattern outer profile makes: laser mode is used, in the radium-shine figure needed out of metal alloy on piece
Case outer profile;Alternatively, etching the pattern outer profile of needs in metal alloy on piece using mask etch mode;
3) film layer makes: polymer composite is modulated into the liquid of fixed viscosity, then is coated on PET film,
Film forming layer is made, after film layer is dried under the conditions of 50-100 DEG C in baking oven, then the film layer after drying is cut into correspondingly-sized
Diaphragm completes the production of film layer;
4) adhesion layer is coated with: the high molecular bonding glue modulated being coated uniformly on composite metal using automatic coating machine
Or film surface, form one layer of adhesion layer;
5) it overlay film: takes in the tiling to the composite metal of compound white version of the diaphragm of a correspondingly-sized and film thickness, then will answer
It closes white version to lay flat on heating platform, the area equation of the area of heating platform and compound white version, temperature 100-300 degree, then uses
1-10kg pressure carries out diaphragm and is pressed with composite metal, to form polymer compound layer in compound white version;
6) dry: the compound white version for having attached polymer compound layer be placed into drying in oven, temperature control 200 ±
10 DEG C, time control is taken out in 5-10min, the compound white version that drying is completed, that is, completes the production of polymer compound layer;
7) laser: using laser machine, set corresponding graphic package, set energy and time, then will
Compound white version is placed on the fixed position of equipment, carries out laser, this radium-shine pattern is the just pattern in metal alloy film
In outer profile, the laser probe in laser machine can issue the monochromatic light of fixed wave length, according to the journey for scanning printed pattern
Ordered pair polymer compound layer carries out radium-shine etching, figure layer unwanted in lines is etched away, to form complete hollow out
Figure;
8) it cleans: spraying cleaning solution on the compound white version surface that laser is completed, be rinsed using hydraulic giant, remove line
Remaining foreign matter in item, 40 DEG C of drying in oven 20-30min are placed into after drying can be obtained composite halftone;
9) detection packaging: film thickness, line width, the tension parameters of corresponding composite halftone are detected, reaching prescribed requirement can be normal
Packaging uses.
In a preferred embodiment of the present invention, the metal alloy film and the thickness of film layer are 5-50um.
In a preferred embodiment of the present invention, the pattern outer profile of the metal alloy on piece compares polymer compound layer
The big 0.1-0.3mm of radium-shine pattern cun is gone up, there is " warp " spacing 30um-100um of 10-20um width, and " warp " in outline
Angular range between 20-90 degree or be equal to 90 degree.
In a preferred embodiment of the present invention, the polymer composite passes through automatic coating or automatic curtain coating
Mode be coated on PET film.
In a preferred embodiment of the present invention, the polymer composite includes polyimides, polyurethane, gathers
Ether ether ketone, polyester and dry film.
In a preferred embodiment of the present invention, the high molecular bonding glue is hot-setting adhesive, includes EVA, PE, pu
And epoxy resin.
The beneficial effects of the present invention are: the production method of metal alloy composite halftone of the invention, using metal alloy film
Instead of traditional screen cloth, there is relatively low elongation percentage, better dimensional stability, printability resistance, it is resistance to puncture, metal alloy film with
Film layer dual support, the bond strength service life far more than silk screen and film layer can promote 30% or more, in the work of high molecular bonding glue
Under, keep polymer compound layer adhesion strength extremely strong, it is not easily to fall off, plate-making yield greatly improved, save production cost, halftone
Film layer broken hole not easy to wear when in use, printing service life are enhanced about more than once, and printing later period printing lines will not be widened, to electricity
Pond piece efficiency has a clear superiority, and the halftone lines strike through of production is more preferable, therefore can substantially compress the limit of high-precision narrow linewidth
System, and print well, line style is good, there is the promotion become apparent to cell piece efficiency in this way.
To describe the technical solutions in the embodiments of the present invention more clearly, make required in being described below to embodiment
Attached drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for
For those of ordinary skill in the art, without creative efforts, it can also be obtained according to these attached drawings other
Attached drawing, in which:
Fig. 1 is the structural schematic diagram of a preferred embodiment of metal alloy composite halftone of the present invention;
Fig. 2 is the enlarged drawing for being 90 degree through angle in metal alloy film in Fig. 1;
Fig. 3 is the enlarged drawing in Fig. 1 in metal alloy film through angle for other angles.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's all other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
The embodiment of the present invention includes:
As shown in Figure 1, zero degree halftone includes screen frame 1, through-hole 2, polyester webs 3, recombination region 4, metal alloy film 5, high score
Sub- composite layer 6, pattern area 7 and film layer lines 8.
A kind of production method of metal alloy composite halftone, comprising the following specific steps
1) it draws in the net compound: first carrying out polyester webs stretching, polyester grenadine is fixed on screen frame after standing and forms polyester webs, then
Metal alloy film is combined to the recombination region among polyester webs using hot melt adhesive and forms composite metal, under the action of pushing up net machine
Certain tension is obtained, composite metal is fixed on another screen frame, compound white version is obtained;
2) alloy sheet pattern outer profile makes: laser mode is used, in the radium-shine figure needed out of metal alloy on piece
Case outer profile;Alternatively, etching the pattern outer profile of needs in metal alloy on piece using mask etch mode;
3) film layer makes: polymer composite is modulated into the liquid of fixed viscosity, then is coated on PET film,
Film forming layer is made, after film layer is dried under the conditions of 50-100 DEG C in baking oven, then the film layer after drying is cut into correspondingly-sized
Diaphragm completes the production of film layer;
4) adhesion layer is coated with: the high molecular bonding glue modulated being coated uniformly on composite metal using automatic coating machine
Or film surface, form one layer of adhesion layer;
5) it overlay film: takes in the tiling to the composite metal of compound white version of the diaphragm of a correspondingly-sized and film thickness, then will answer
It closes white version to lay flat on heating platform, the area equation of the area of heating platform and compound white version, temperature 100-300 degree, then uses
1-10kg pressure carries out diaphragm and is pressed with composite metal, to form polymer compound layer in compound white version;
6) dry: the compound white version for having attached polymer compound layer be placed into drying in oven, temperature control 200 ±
10 DEG C, time control is taken out in 5-10min, the compound white version that drying is completed, that is, completes the production of polymer compound layer;
7) laser: using laser machine, set corresponding graphic package, set energy and time, then will
Compound white version is placed on the fixed position of equipment, carries out laser, this radium-shine pattern is the just pattern in metal alloy film
In outer profile, the laser probe in laser machine can issue the monochromatic light of fixed wave length, according to the journey for scanning printed pattern
Ordered pair polymer compound layer carries out radium-shine etching, figure layer unwanted in lines is etched away, to form complete hollow out
Figure;
8) it cleans: spraying cleaning solution on the compound white version surface that laser is completed, be rinsed using hydraulic giant, remove line
Remaining foreign matter in item, 40 DEG C of drying in oven 20-30min are placed into after drying can be obtained composite halftone;
9) detection packaging: film thickness, line width, the tension parameters of corresponding composite halftone are detected, reaching prescribed requirement can be normal
Packaging uses.
Among the above, the metal alloy film and the thickness of film layer are 5-50um, wherein the thickness of film layer can be according to need
Ask random adjustment, and the thickness of film layer very poor can control within the scope of ± 1um.
Further, the metal alloy film with a thickness of 5-50um, by etching or it is radium-shine in the way of by metal alloy
The part that piece needs to do pattern removes the pattern outer profile to form carrying pattern area.As shown in Figures 2 and 3, pass through laser
Or mask etch mode makes the pattern outer profile of needs on metal alloy film 5.Wherein, the pattern outer profile compares high score
The pattern area big 0.1-0.3mm of 7 size in sub- film layer 6, have in outline 10-20um width through 9, through 9 spacing 30um-
100um, and the angular range of " warp " is between 20-90 degree or equal to 90 degree, that is, there are 90 degree through 9, there are also those of other angles
Two kinds of situations.
Further, the polymer composite is coated by way of being cast automatic coating or automatically
On PET film, in the way of being coated with or being cast on a pet film by polymer composite coating, available thickness is equal
One film layer.
Wherein, the polymer composite includes polyimides, polyurethane, polyether-ether-ketone, polyester and dry film.It is dry
Film (Dry film) is with respect to for wet film (Wet film) in coating, and dry film is a kind of high molecular compound.Using
Polymer composite is as film layer, and the material filming is good, and wearability is strong, acid and alkali-resistance, solvent etc..The high molecular bonding
Glue is hot-setting adhesive, includes EVA, PE, pu and epoxy resin.It is relatively strong using being all had with metal alloy film and macromolecule membranous layer
The high molecular bonding glue of adhesion strength has the performances such as high temperature resistant, acid and alkali-resistance, solvent as adhesion layer, the high molecular bonding glue.Benefit
With the effect of high molecular bonding glue, macromolecule membranous layer is uniformly attached to metal alloy film surface, adhesiveness is strong, and associativity is good,
It is not easy to fall off.
The production method of metal alloy composite halftone of the invention is compared and the prior art, has the advantages that
1) elongation percentage of metal alloy film will be much smaller than screen cloth, and working it out product size and having stablized dimensional accuracy can be improved
10%;
2) this product in non-pattern and needs to have sheet metal and film layer dual support in Printing Zone, far more than silk screen and film layer
The bond strength service life can promote 30% or more;
2) outline that laser goes out is clearly smooth, and line width is uniform, very poor to can control within 1um, prints out
Lines plastotype is more preferable, has a clear superiority compared with conventional plates;
2) under the action of high molecular bonding glue, keep polymer compound layer adhesion strength extremely strong, it is not easily to fall off, it greatly improved
Plate-making yield, probably in 50%-60%, which plate-making yield can reach 80%-90%, greatly improved conventional plates yield
Stock utilization saves production cost;
3) polymer compound layer superpower wear-resistant, so that film layer broken hole not easy to wear, printing service life mention halftone when in use
It doubles above, the screen painting service life of the conventional plates average level 50,000 or so, and the screen painting longevity made from which
Life can averagely reach 100,000 or more, even higher, and print later period printing lines and will not widen, and have obviously to cell piece efficiency
Advantage;
4) the halftone lines strike through of which production is more preferable, therefore can substantially compress the limitation of high-precision narrow linewidth,
On the basis of ink of the same race printing, design line thickness can recompress 2-5um, and print well, and line style is good, in this way to battery
Piece efficiency has the promotion become apparent.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (6)
1. a kind of production method of metal alloy composite halftone, which is characterized in that comprising the following specific steps
1) it draws in the net compound: first carrying out polyester webs stretching, polyester grenadine is fixed on screen frame after standing and forms polyester webs, recycle
Metal alloy film is combined to the recombination region among polyester webs and forms composite metal by hot melt adhesive, is obtained under the action of pushing up net machine
Composite metal is fixed on another screen frame, obtains compound white version by certain tension;
2) alloy sheet pattern outer profile makes: laser mode is used, outside the radium-shine pattern needed out of metal alloy on piece
Profile;Alternatively, etching the pattern outer profile of needs in metal alloy on piece using mask etch mode;
3) film layer makes: polymer composite being modulated into the liquid of fixed viscosity, then is coated on PET film, is made
Film layer after drying after drying film layer under the conditions of 50-100 DEG C in baking oven, then is cut into the diaphragm of correspondingly-sized by film forming layer,
Complete the production of film layer;
4) adhesion layer be coated with: using automatic coating machine by the high molecular bonding glue modulated be coated uniformly on composite metal or
Film surface forms one layer of adhesion layer;
5) it overlay film: takes in the tiling to the composite metal of compound white version of the diaphragm of a correspondingly-sized and film thickness, then will be compound white
Version is laid flat on heating platform, the area equation of the area of heating platform and compound white version, temperature 100-300 degree, then uses 1-
10kg pressure carries out diaphragm and is pressed with composite metal, to form polymer compound layer in compound white version;
6) it dries: the compound white version for having attached polymer compound layer being placed into drying in oven, temperature is controlled 200 ± 10
DEG C, time control is taken out in 5-10min, the compound white version that drying is completed, that is, completes the production of polymer compound layer;
7) laser: using laser machine, set corresponding graphic package, set energy and time, then will be compound
White version is placed on the fixed position of equipment, carries out laser, this radium-shine pattern is the just pattern foreign steamer in metal alloy film
In exterior feature, the laser probe in laser machine can issue the monochromatic light of fixed wave length, according to the program pair for scanning printed pattern
Polymer compound layer carries out radium-shine etching, figure layer unwanted in lines is etched away, to form the figure of complete hollow out;
8) it cleans: spraying cleaning solution on the compound white version surface that laser is completed, be rinsed, removed in lines using hydraulic giant
Remaining foreign matter, 40 DEG C of drying in oven 20-30min are placed into after drying can be obtained composite halftone;
9) detection packaging: film thickness, line width, the tension parameters of corresponding composite halftone are detected, reaching prescribed requirement can normally pack
It uses.
2. the production method of metal alloy composite halftone according to claim 1, which is characterized in that the metal alloy
Piece and the thickness of film layer are 5-50um.
3. the production method of metal alloy composite halftone according to claim 1, which is characterized in that the metal alloy
The pattern outer profile of the on piece pattern more radium-shine than on polymer compound layer cun big 0.1-0.3mm has 10-20um wide in outline
" warp " spacing 30um-100um of degree, and the angular range of " warp " is between 20-90 degree or equal to 90 degree.
4. the production method of metal alloy composite halftone according to claim 1, which is characterized in that the macromolecule is multiple
Condensation material is coated on PET film by way of being cast automatic coating or automatically.
5. the production method of metal alloy composite halftone according to claim 4, which is characterized in that the macromolecule is multiple
Condensation material includes polyimides, polyurethane, polyether-ether-ketone, polyester and dry film.
6. the production method of metal alloy composite halftone according to claim 1, which is characterized in that the macromolecule is viscous
Conjunction glue is hot-setting adhesive, includes EVA, PE, pu and epoxy resin.
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