CN110028875A - A kind of wear-resistant daub - Google Patents

A kind of wear-resistant daub Download PDF

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Publication number
CN110028875A
CN110028875A CN201910421053.3A CN201910421053A CN110028875A CN 110028875 A CN110028875 A CN 110028875A CN 201910421053 A CN201910421053 A CN 201910421053A CN 110028875 A CN110028875 A CN 110028875A
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CN
China
Prior art keywords
epoxy resin
silicon carbide
wear
graphite powder
curing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910421053.3A
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Chinese (zh)
Inventor
刘坐镇
周建涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HENAN HUACHANG HIGH-TECH Co Ltd
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HENAN HUACHANG HIGH-TECH Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to CN201910421053.3A priority Critical patent/CN110028875A/en
Publication of CN110028875A publication Critical patent/CN110028875A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)

Abstract

The invention is related to a kind of wear-resistant daub, it is composed of the following components: epoxy resin, curing agent, nanometer silicon carbide, graphite powder, benzene sulfonyl chloride, promotor, non-metallic elastic material, the parts by weight of each component are as follows: epoxy resin 40~80%, curing agent 1~10%, nanometer silicon carbide 1~20%, graphite powder 1~5%, benzene sulfonyl chloride 1~10%, promotor 1~10%, non-metallic elastic material 1~10%, the parts by weight of each component are as follows: epoxy resin 62%, curing agent 6%, nanometer silicon carbide 15%, graphite powder 3%, benzene sulfonyl chloride 5%, promotor 6%, non-metallic elastic material 3%, the parts by weight of each component are as follows: epoxy resin 45%, curing agent 10%, nanometer silicon carbide 20%, graphite powder 5%, benzene sulfonyl chloride 5%, promote Agent 10%, non-metallic elastic material 5%;Therefore, the present invention has the advantages that high temperature resistant, easy to make, cure cycle is short and wearability is good.

Description

A kind of wear-resistant daub
Technical field
The invention belongs to the technical fields of clay, and in particular to a kind of wear-resistant daub.
Background technique
Currently, in the whipping process of industrial chemicals, due to the corrosivity of raw material, often to agitator tank, stirrer paddle And agitating shaft generates corrosion reaction, seriously affects the service life of mixing plant, for the service life for extending equipment, the prior art In have by using stainless steel material corrosion-resistant, also have using clay come corrosion-resistant, shortcoming in the prior art is solidification The deficiencies of phase length, non-refractory, cohesive force weak easy to fall off, complex process;For these shortcomings, it is necessary to develop a kind of resistance to High temperature, the wear-resistant daub that easy to make, cure cycle is short and wearability is good;Therefore, a kind of high temperature resistant, easy to make, solid is developed The change period is short and the good wear-resistant daub of wearability has a very important significance.
Summary of the invention
The purpose of the invention is to overcome the deficiencies in the prior art, and provide a kind of high temperature resistant, easy to make, solidification week Phase is short and the good wear-resistant daub of wearability.
The object of the present invention is achieved like this: a kind of wear-resistant daub, composed of the following components: epoxy resin, curing agent, Nanometer silicon carbide, graphite powder, benzene sulfonyl chloride, promotor, non-metallic elastic material.
The parts by weight of each component are as follows: the parts by weight of each component are as follows: epoxy resin 40~80%, curing agent 1~10%, nanometer silicon carbide 1~20%, graphite powder 1~5%, benzene sulfonyl chloride 1~10%, promotor 1~10%, nonmetallic bullet Property material 1~10%.
The parts by weight of each component are as follows: epoxy resin 62%, curing agent 6%, nanometer silicon carbide 15%, graphite powder 3%, benzene sulfonyl chloride 5%, promotor 6%, non-metallic elastic material 3%.
The parts by weight of each component are as follows: epoxy resin 45%, curing agent 10%, nanometer silicon carbide 20%, graphite powder 5%, benzene sulfonyl chloride 5%, promotor 10%, non-metallic elastic material 5%.
The parts by weight of each component are as follows: epoxy resin 61%, curing agent 8%, nanometer silicon carbide 15%, graphite powder 3%, benzene sulfonyl chloride 3%, promotor 7%, non-metallic elastic material 3%.
The parts by weight of each component are as follows: epoxy resin 63%, curing agent 7%, nanometer silicon carbide 15%, graphite powder 3%, benzene sulfonyl chloride 2%, promotor 8%, non-metallic elastic material 2%.
Manufacturing method includes that following step is poly-: (1), by epoxy resin and curing agent, weighing according to the ratio and be added to reactor In, it is heated to 160 DEG C under stiring, so that it is carried out addition reaction, and keep the temperature 50min, is then transferred in another container.
(2), in above-mentioned reaction solution, a certain amount of non-metallic elastic material, promotor and graphite powder is added, and stir extremely In homogeneous black paste.
(3), it before use, a certain amount of nanometer silicon carbide, benzene sulfonyl chloride is added, and stirs to being in uniform black cream Shape object.
(4), the uniform paste of mix, using finishing in 50 minutes.
Beneficial effects of the present invention: it is an advantage of the invention that wearability is good, it is environmentally protective, it is durable, it is not easily to fall off;Through Ji uses, cheap, long service life;Product solves emergency maintenance and the abrasion of large number of equipment, etching problem, can be with Eradicate run, drip, leak problem.Only needed at problem with glue easily a little can carefree no trouble, be suitble to urgent repairing to be used;It is grinding In system and production, added with efficient rubber accelerator (2- benzothiazolyl mercaptan), it is made to carry out condensation reaction with epoxy resin, Thus improve the performance of clay;And physical structure is mainly by one kind by high molecular polymer and corundum, silicon carbide The two-component synthetic material being formulated etc. a variety of composite superfine powder fillers and chemical addition agent.When clay is painted on equipment matrix After upper, the high molecular polymer in clay forms that very strong molecule connecting key is Nian Jie with the matrix of equipment, makes clay and equipment Coating surface solidification is integral, and a variety of composite micro-powders such as corundum, silicon carbide and Ultramicro-powder filler impart equipment and be coated surface Property, i.e. high-wearing feature;High molecular polymer itself has Anticorrosive Character simultaneously, so that the equipment after coating be made to have Wear-and corrosion-resistant performance.Under operating condition of the same race, the erosive wear resistant performance of wear-and corrosion-resistant clay is 6-8 times of 20# steel;Therefore, originally Invention has the advantages that high temperature resistant, easy to make, cure cycle is short and wearability is good.
Specific embodiment
Embodiment 1
A kind of wear-resistant daub, it is composed of the following components: epoxy resin, curing agent, nanometer silicon carbide, graphite powder, benzene sulfonyl chloride, rush Into agent, non-metallic elastic material, the parts by weight of each component are as follows: the parts by weight of each component are as follows: epoxy resin 40 ~80%, curing agent 1~10%, nanometer silicon carbide 1~20%, graphite powder 1~5%, benzene sulfonyl chloride 1~10%, promotor 1~ 10%, non-metallic elastic material 1~10%;Manufacturing method includes that following step is poly-: (1), by epoxy resin and curing agent, according to the ratio It weighs and is added in reactor, be heated to 160 DEG C under stiring, so that it is carried out addition reaction, and keep the temperature 50min, then turn Enter in another container;(2), in above-mentioned reaction solution, a certain amount of non-metallic elastic material, promotor and graphite powder is added, and Stirring is in homogeneous black paste;(3), it before use, a certain amount of nanometer silicon carbide, benzene sulfonyl chloride is added, and stirs extremely In uniform black paste;(4), the uniform paste of mix, using finishing in 50 minutes.
Control group is the wear-resistant daub of recipe ingredient commonly used in the prior art production, the present embodiment group phase in the present embodiment Have the advantages that good wearability, long service life, high temperature resistant and cure cycle are short to the prior art.
Embodiment 2
The parts by weight of each component are as follows: epoxy resin 62%, curing agent 6%, nanometer silicon carbide 15%, graphite powder 3%, benzene Sulfonic acid chloride 5%, promotor 6%, non-metallic elastic material 3%;Manufacturing method includes that following step is poly-: (1), by epoxy resin and solid Agent is weighed according to the ratio and is added in reactor, is heated to 160 DEG C under stiring, so that it is carried out addition reaction, and keep the temperature Then 50min is transferred in another container;(2), in above-mentioned reaction solution, a certain amount of non-metallic elastic material, promotor is added And graphite powder, and stir in homogeneous black paste;(3), before use, a certain amount of nanometer silicon carbide, benzene sulfonyl is added Chlorine, and stir in uniform black paste;(4), the uniform paste of mix, using finishing in 50 minutes.
Control group is the wear-resistant daub of recipe ingredient commonly used in the prior art production, the present embodiment group phase in the present embodiment Have the advantages that good wearability, long service life, high temperature resistant and cure cycle are short to the prior art.
Embodiment 3
The parts by weight of each component are as follows: epoxy resin 45%, curing agent 10%, nanometer silicon carbide 20%, graphite powder 5%, Benzene sulfonyl chloride 5%, promotor 10%, non-metallic elastic material 5%;Manufacturing method includes that following step is poly-: (1), by epoxy resin And curing agent, it weighs and is added in reactor according to the ratio, be heated to 160 DEG C under stiring, it is made to carry out addition reaction, and 50min is kept the temperature, is then transferred in another container;(2), in above-mentioned reaction solution, a certain amount of non-metallic elastic material is added, promotees Into agent and graphite powder, and stir in homogeneous black paste;(3), before use, a certain amount of nanometer silicon carbide, benzene is added Sulfonic acid chloride, and stir in uniform black paste;(4), the uniform paste of mix, using finishing in 50 minutes.
Control group is the wear-resistant daub of recipe ingredient commonly used in the prior art production, the present embodiment group phase in the present embodiment Have the advantages that good wearability, long service life, high temperature resistant and cure cycle are short to the prior art.
Embodiment 4
The parts by weight of each component are as follows: epoxy resin 61%, curing agent 8%, nanometer silicon carbide 15%, graphite powder 3%, benzene Sulfonic acid chloride 3%, promotor 7%, non-metallic elastic material 3%;Manufacturing method includes that following step is poly-: (1), by epoxy resin and solid Agent is weighed according to the ratio and is added in reactor, is heated to 160 DEG C under stiring, so that it is carried out addition reaction, and keep the temperature Then 50min is transferred in another container;(2), in above-mentioned reaction solution, a certain amount of non-metallic elastic material, promotor is added And graphite powder, and stir in homogeneous black paste;(3), before use, a certain amount of nanometer silicon carbide, benzene sulfonyl is added Chlorine, and stir in uniform black paste;(4), the uniform paste of mix, using finishing in 50 minutes.
Control group is the wear-resistant daub of recipe ingredient commonly used in the prior art production, the present embodiment group phase in the present embodiment Have the advantages that good wearability, long service life, high temperature resistant and cure cycle are short to the prior art.
Embodiment 5
The parts by weight of each component are as follows: epoxy resin 63%, curing agent 7%, nanometer silicon carbide 15%, graphite powder 3%, benzene Sulfonic acid chloride 2%, promotor 8%, non-metallic elastic material 2%;Manufacturing method includes that following step is poly-: (1), by epoxy resin and solid Agent is weighed according to the ratio and is added in reactor, is heated to 160 DEG C under stiring, so that it is carried out addition reaction, and keep the temperature Then 50min is transferred in another container;(2), in above-mentioned reaction solution, a certain amount of non-metallic elastic material, promotor is added And graphite powder, and stir in homogeneous black paste;(3), before use, a certain amount of nanometer silicon carbide, benzene sulfonyl is added Chlorine, and stir in uniform black paste;(4), the uniform paste of mix, using finishing in 50 minutes.
Control group is the wear-resistant daub of recipe ingredient commonly used in the prior art production in the present embodiment, and the present embodiment group is relatively existing Have the advantages that technology has good wearability, long service life, high temperature resistant and cure cycle short.
Epoxy resin has high bond strength and good chemical performance, can be obtained by by being modified and various fillers being added The wear and corrosion behavior and other performance of various needs;This patent is exactly added on the basis of common epoxy resin wear-resisting resistance to Rotten filler forms bi-component glue gunk, especially by be added modifying agent make its have with matrix high adhesive strength and Good erosive wear resistant and corrosion resistance.
The service life that abrasion-proof corrosion-proof clay substantially increases dimension body is smeared, not only saves a large amount of people to each overhaul Power working hour, while also saving a large amount of steel plate materials.In addition, all elbow and cone all can be applied in maintenance it is wear-resisting resistance to Rotten clay, wear-resistant daub is also used in other similar operating conditions, including all kinds of elbows and volute of blower, to increase these components Service life and reduce maintenance load.
Specific embodiment is to further explanation of the invention rather than limits, and is existed for those of ordinary skills Further transformation is done to structure in the case where not departing from substantive content of the present invention, and all these transformation all should belong to institute of the present invention Attached scope of protection of the claims.

Claims (7)

1. a kind of wear-resistant daub, it is characterised in that: composed of the following components: epoxy resin, curing agent, nanometer silicon carbide, graphite Powder, benzene sulfonyl chloride, promotor, non-metallic elastic material.
2. a kind of wear-resistant daub according to claim 1, it is characterised in that: the parts by weight of each component are as follows: epoxy Resin 40~80%, nanometer silicon carbide 1~20%, graphite powder 1~5%, benzene sulfonyl chloride 1~10%, promotees curing agent 1~10% Into agent 1~10%, non-metallic elastic material 1~10%.
3. a kind of wear-resistant daub according to claim 1, it is characterised in that: the parts by weight of each component are as follows: epoxy Resin 62%, curing agent 6%, nanometer silicon carbide 15%, graphite powder 3%, benzene sulfonyl chloride 5%, promotor 6%, non-metal elastic Material 3%.
4. a kind of wear-resistant daub according to claim 1, it is characterised in that: the parts by weight of each component are as follows: epoxy Resin 45%, curing agent 10%, nanometer silicon carbide 20%, graphite powder 5%, benzene sulfonyl chloride 5%, promotor 10%, nonmetallic bullet Property material 5%.
5. a kind of wear-resistant daub according to claim 1, it is characterised in that: the parts by weight of each component are as follows: epoxy Resin 61%, curing agent 8%, nanometer silicon carbide 15%, graphite powder 3%, benzene sulfonyl chloride 3%, promotor 7%, non-metal elastic Material 3%.
6. a kind of wear-resistant daub according to claim 1, it is characterised in that: the parts by weight of each component are as follows: epoxy Resin 63%, curing agent 7%, nanometer silicon carbide 15%, graphite powder 3%, benzene sulfonyl chloride 2%, promotor 8%, non-metal elastic Material 2%.
7. a kind of wear-resistant daub described in -6 according to claim 1, manufacturing method includes that following step is poly-: (1), by epoxy resin and Curing agent is weighed according to the ratio and is added in reactor, is heated to 160 DEG C under stiring, so that it is carried out addition reaction, and protect Then warm 50min is transferred in another container;
(2), in above-mentioned reaction solution, a certain amount of non-metallic elastic material, promotor and graphite powder is added, and stirs in equal Even black paste;
(3), it before use, a certain amount of nanometer silicon carbide, benzene sulfonyl chloride is added, and stirs to being in uniform black paste;
(4), the uniform paste of mix, using finishing in 50 minutes.
CN201910421053.3A 2019-05-21 2019-05-21 A kind of wear-resistant daub Pending CN110028875A (en)

Priority Applications (1)

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CN201910421053.3A CN110028875A (en) 2019-05-21 2019-05-21 A kind of wear-resistant daub

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Application Number Priority Date Filing Date Title
CN201910421053.3A CN110028875A (en) 2019-05-21 2019-05-21 A kind of wear-resistant daub

Publications (1)

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CN110028875A true CN110028875A (en) 2019-07-19

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111331762A (en) * 2020-02-24 2020-06-26 沈阳中航迈瑞特工业有限公司 Preparation process of epoxy resin daub mould

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1339546A (en) * 2000-08-25 2002-03-13 栗德发 Wear resistant daub and its producing method
CN105713485A (en) * 2016-04-27 2016-06-29 邹海明 Wear-resistant anticorrosive cement
CN107540393A (en) * 2017-08-24 2018-01-05 浙江科屹耐火材料有限公司 A kind of refractory mortar

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1339546A (en) * 2000-08-25 2002-03-13 栗德发 Wear resistant daub and its producing method
CN105713485A (en) * 2016-04-27 2016-06-29 邹海明 Wear-resistant anticorrosive cement
CN107540393A (en) * 2017-08-24 2018-01-05 浙江科屹耐火材料有限公司 A kind of refractory mortar

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111331762A (en) * 2020-02-24 2020-06-26 沈阳中航迈瑞特工业有限公司 Preparation process of epoxy resin daub mould

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Application publication date: 20190719

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