CN110003608A - A kind of dedicated high glaze self-lubricating high molecular material of cosmetic pencil packaging - Google Patents
A kind of dedicated high glaze self-lubricating high molecular material of cosmetic pencil packaging Download PDFInfo
- Publication number
- CN110003608A CN110003608A CN201910339694.4A CN201910339694A CN110003608A CN 110003608 A CN110003608 A CN 110003608A CN 201910339694 A CN201910339694 A CN 201910339694A CN 110003608 A CN110003608 A CN 110003608A
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- CN
- China
- Prior art keywords
- parts
- cosmetic pencil
- molecular material
- high molecular
- lubricating
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Abstract
The invention discloses a kind of cosmetic pencils to pack dedicated high glaze self-lubricating high molecular material, according to parts by weight includes following component: 75 ~ 95 parts of acrylonitrile-butadiene-styrene (ABS) plastics, 5 ~ 15 parts of polymethyl methacrylate, 0.1 ~ 2 part of liquid dispersant, 1 ~ 5 part of compatilizer, 0.1 ~ 5 part of solid dispersion, 5 ~ 10 parts of lubricant.The present invention is effectively during long-acting static friction and dynamic friction; form the safeguard measure to cosmetic pencil; accomplish the features such as product static friction is stable, kinetic force of friction is uniform, product does not wear, is unlikely to deform; the diversification requirement of product simultaneously; there are more requirements that superior mechanical property is needed to support the structure of pen; better surface-active is used for gold stamping, printing of product surface spray painting etc., and better colorability allows material itself to be conducive to dyestuff dispersion and reach good color effect.
Description
Technical field
The present invention relates to technical field of polymer materials, more particularly to a kind of cosmetic pencil pack dedicated high glaze from
Lubricate high molecular material.
Background technique
There is the lotion, packaging structure and design of different component with the development and progress of industry in cosmetic pencil,
In main body with environmental protection, high glaze, multicolour, feel lubrication, be used for a long time it is ageing-resistant with regard to long-acting feel.The general material mesh in market
It is preceding to have feature request mainly in Gao Zedu, for example 718 materials are exactly the cosmetic pencil material of black high-brightness, there is no jails of painting
Soundness, also the lubrication of feel and cosmetic pencil do not repeat uniform for contact engaging and separating force in plug use process and product engaging portion
The special wear-resisting requirement divided.Cosmetic pencil be plug-in, this is static friction, a cosmetic pencil be it is revolving, this
It is dynamic friction.
Existing cosmetic pencil is packaged in that product static friction during long-acting static friction and dynamic friction is unstable, kinetic force of friction
Unevenly, product is prone to wear, is easily deformed, simultaneously because the diversification of product requires, it is higher for the structural requirement of pen: 1,
Superior mechanical property is needed to support;2, better surface-active is needed to be used for product surface spray painting, gold stamping, printing etc.;
3, better colorability is needed, allows material itself to be conducive to dyestuff dispersion and reaches good color effect.
Summary of the invention
In view of the deficienciess of the prior art, the object of the invention is that providing a kind of dedicated height of cosmetic pencil packaging
Gloss self-lubricating high molecular material forms the safeguard measure to cosmetic pencil effectively during long-acting static friction and dynamic friction,
Accomplish the features such as product static friction is stable, kinetic force of friction is uniform, product does not wear, is unlikely to deform, while the diversification of product is wanted
It asks, has more requirements that superior mechanical property is needed to support the structure of pen, better surface-active is used for product
Gold stamping, printing of surface lacquer etc., better colorability allow material itself to be conducive to dyestuff dispersion and reach good color effect.
To achieve the goals above, the technical solution adopted by the present invention is that such: a kind of dedicated height of cosmetic pencil packaging
Gloss self-lubricating high molecular material includes following component: acrylonitrile-butadiene-styrene (ABS) plastics 75 ~ 95 according to parts by weight
Part, 5 ~ 15 parts of polymethyl methacrylate, 0.1 ~ 2 part of liquid dispersant, 1 ~ 5 part of compatilizer, 0.1 ~ 5 part of solid dispersion, profit
5 ~ 10 parts of lubrication prescription.
As a preferred embodiment, the liquid dispersant is organic silicone oil.
As a preferred embodiment, the compatilizer is Methacrylate-butadiene-styrene.
As a preferred embodiment, the solid dispersion is wax-like ethylene bis stearic acid amide.
As a preferred embodiment, the lubricant includes one or both of silicone powder, polytetrafluoroethylene (PTFE).
As a preferred embodiment, the silicone powder, polytetrafluoroethylene (PTFE) are calculated by weight as 2.5 ~ 5 parts of silicone powder, gather
2.5 ~ 5 parts of tetrafluoroethene.
Compared with prior art, beneficial effects of the present invention:
(1) polymethyl methacrylate is used to improve the glossiness of material;
(2) mechanical support is provided as main material using acrylonitrile-butadiene-styrene (ABS) plastics, alleviates multicomponent bring
Mechanics decline;
(3) compatilizer is used, ensure that the compatibility and surface brightness of material;
(4) liquid dispersant and solid dispersion are used, guarantees surface-active, dyeing material dynamics and surface can be improved
Paint adhesive force, increases spray painting firmness;
(5) lubricant has been used, condition of molding is improved, the long-term self-lubricating of material molding rear surface is improved using slow release method
Effect;
(6) there is the long-term stability for packing various system type lotions;
(7) there is lower density, material proportion is effectively reduced, reduces costs indirectly.
Specific embodiment
The invention will be further described combined with specific embodiments below.Following embodiment is only used for clearly illustrating
Technical solution of the present invention, and not intended to limit the protection scope of the present invention.
Embodiment 1:
A kind of dedicated high glaze self-lubricating high molecular material of cosmetic pencil packaging, includes following component: propylene according to parts by weight
Nitrile -75 parts of butadiene-styrene plastics, 5 parts of polymethyl methacrylate, 0.1 part of liquid dispersant, 1 part of compatilizer, solid point
0.1 part of powder, 5 parts of lubricant.
The acrylonitrile-butadiene-styrene (ABS) plastics wherein used use plate grade material, provide mechanical support, alleviate more
The decline of component bring mechanics, the specific trade mark are ABS747S;The glossiness of material is promoted using polymethyl methacrylate,
The specific trade mark is CM205.
Specifically, the liquid dispersant is organic silicone oil, the specific trade mark is DOW CORNING organic silicone oil OFX-5043.
Specifically, the solid dispersion is wax-like ethylene bis stearic acid amide, the specific trade mark is Japanese Kao BFF.
Further, using liquid dispersant, solid dispersion guarantee surface-active, can be improved dyeing material dynamics with
And surface lacquer adhesive force, increase spray painting firmness.
Specifically, the compatilizer is Methacrylate-butadiene-styrene, the specific trade mark is Japan Zhong Yuan
M722。
Further, compatilizer uses nucleus type compatilizer, ensure that the compatibility and surface brightness of product.
Specifically, the lubricant includes one or both of silicone powder, polytetrafluoroethylene (PTFE).
More specifically, the silicone powder, polytetrafluoroethylene (PTFE) are calculated by weight as 2.5 parts of silicone powder, polytetrafluoroethylene (PTFE)
2.5 part.
Further, wherein silicone powder improves material and forms the long-term of rear surface as external lubricant by slow release method
Self-lubricating effect, the specific trade mark are DOW CORNING silicone powder RM4-7081;And polytetrafluoroethylene (PTFE) improves molding as in-lubricant
Condition, the specific trade mark are the Japan village Xi Duo PTFE KTL-610.
Embodiment 2:
The difference from embodiment 1 is that present embodiments providing a kind of dedicated high glaze self-lubricating macromolecule of cosmetic pencil packaging
Material includes following component: 83 parts of acrylonitrile-butadiene-styrene (ABS) plastics, polymethyl methacrylate 11 according to parts by weight
Part, 1.1 parts of liquid dispersant, 2 parts of compatilizer, 2.1 parts of solid dispersion, 7.4 parts of lubricant.
More specifically, the silicone powder, polytetrafluoroethylene (PTFE) are calculated by weight as 4.1 parts of silicone powder, polytetrafluoroethylene (PTFE)
3.3 part.
Embodiment 3:
The difference from embodiment 1 is that present embodiments providing a kind of dedicated high glaze self-lubricating macromolecule of cosmetic pencil packaging
Material includes following component: 95 parts of acrylonitrile-butadiene-styrene (ABS) plastics, polymethyl methacrylate 15 according to parts by weight
Part, 2 parts of liquid dispersant, 5 parts of compatilizer, 5 parts of solid dispersion, 10 parts of lubricant.
More specifically, the silicone powder, polytetrafluoroethylene (PTFE) are calculated by weight as 5 parts of silicone powder, polytetrafluoroethylene (PTFE) 5
Part.
Properties of product detection is carried out to the resulting material of embodiment 1 ~ 3, testing result is as shown in table 1.
Table 1
Further, the high molecular material of the embodiment of the present invention 1 ~ 3 and the common solvent of cosmetic pencil are subjected to room temperature, high temperature side
Examination, product has no adverse reaction after test, there is the long-term stability of the various system type lotions of packaging, obtain it is excellent withdraw deposit,
Covering property is extensive.
In conclusion the present invention has lower density relative to market versatile material, product specific gravity is effectively reduced, indirectly
It reduces costs;Meet that cosmetic pencil feel lubrication, plug force value be gentle, rotation force value is for a long time uniformly without the feature of pause and transition in rhythm or melody.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the technical principles of the invention, several improvement and deformations can also be made, these improvement and deformations
Also it should be regarded as protection scope of the present invention.
Claims (6)
1. a kind of cosmetic pencil packs dedicated high glaze self-lubricating high molecular material, which is characterized in that include according to parts by weight
Following component: 75 ~ 95 parts of acrylonitrile-butadiene-styrene (ABS) plastics, 5 ~ 15 parts of polymethyl methacrylate, liquid dispersant 0.1
~ 2 parts, 1 ~ 5 part of compatilizer, 0.1 ~ 5 part of solid dispersion, 5 ~ 10 parts of lubricant.
2. a kind of cosmetic pencil according to claim 1 packs dedicated high glaze self-lubricating high molecular material, feature exists
In: the liquid dispersant is organic silicone oil.
3. a kind of cosmetic pencil according to claim 1 packs dedicated high glaze self-lubricating high molecular material, feature exists
In: the compatilizer is Methacrylate-butadiene-styrene.
4. a kind of cosmetic pencil according to claim 1 packs dedicated high glaze self-lubricating high molecular material, feature exists
In: the solid dispersion is wax-like ethylene bis stearic acid amide.
5. a kind of cosmetic pencil according to claim 1 packs dedicated high glaze self-lubricating high molecular material, feature exists
In: the lubricant includes one or both of silicone powder, polytetrafluoroethylene (PTFE).
6. a kind of cosmetic pencil according to claim 5 packs dedicated high glaze self-lubricating high molecular material, feature exists
In: the silicone powder, polytetrafluoroethylene (PTFE) are calculated by weight as 2.5 ~ 5 parts of silicone powder, 2.5 ~ 5 parts of polytetrafluoroethylene (PTFE).
Priority Applications (1)
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CN201910339694.4A CN110003608A (en) | 2019-04-25 | 2019-04-25 | A kind of dedicated high glaze self-lubricating high molecular material of cosmetic pencil packaging |
Applications Claiming Priority (1)
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CN201910339694.4A CN110003608A (en) | 2019-04-25 | 2019-04-25 | A kind of dedicated high glaze self-lubricating high molecular material of cosmetic pencil packaging |
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CN110003608A true CN110003608A (en) | 2019-07-12 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070167573A1 (en) * | 2003-12-16 | 2007-07-19 | Basf Aktiengesellschaft | Thermoplastic moulding compounds exhibiting improved chemical resistance |
CN102061056A (en) * | 2011-01-13 | 2011-05-18 | 金发科技股份有限公司 | Antistatic ABS (acrylonitrile-butadiene-styrene)/PMMA (polymethyl methacrylate) alloy and preparation method thereof |
CN102775720A (en) * | 2011-05-12 | 2012-11-14 | 黑龙江鑫达企业集团有限公司 | High-impact and high-heat-resistance ABS alloy and its preparation technology |
CN103242619A (en) * | 2013-05-31 | 2013-08-14 | 东莞市国立科技有限公司 | High-gloss, high-hardness and spraying-free ABS (acrylonitrile butadiene styrene) plastic modified material and preparation method thereof |
-
2019
- 2019-04-25 CN CN201910339694.4A patent/CN110003608A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070167573A1 (en) * | 2003-12-16 | 2007-07-19 | Basf Aktiengesellschaft | Thermoplastic moulding compounds exhibiting improved chemical resistance |
CN102061056A (en) * | 2011-01-13 | 2011-05-18 | 金发科技股份有限公司 | Antistatic ABS (acrylonitrile-butadiene-styrene)/PMMA (polymethyl methacrylate) alloy and preparation method thereof |
CN102775720A (en) * | 2011-05-12 | 2012-11-14 | 黑龙江鑫达企业集团有限公司 | High-impact and high-heat-resistance ABS alloy and its preparation technology |
CN103242619A (en) * | 2013-05-31 | 2013-08-14 | 东莞市国立科技有限公司 | High-gloss, high-hardness and spraying-free ABS (acrylonitrile butadiene styrene) plastic modified material and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
周祥兴: "《合成树脂新资料手册》", 31 May 2002, 中国物资出版社 * |
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TA01 | Transfer of patent application right |
Effective date of registration: 20210805 Address after: 239000 Economic Development Zone, Quanjiao County, Chuzhou City, Anhui Province (factory of Chuzhou Xinyi Machinery Co., Ltd.) Applicant after: Anhui weipuda Material Technology Co.,Ltd. Address before: 215000 Building 2, Xinzhong village, Xinzhuang Town, Changshu City, Suzhou City, Jiangsu Province Applicant before: Suzhou Bochi New Materials Co.,Ltd. |
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Application publication date: 20190712 |
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