CN109997848A - A kind of production method of energy-saving and environmental protection granular pesticide - Google Patents
A kind of production method of energy-saving and environmental protection granular pesticide Download PDFInfo
- Publication number
- CN109997848A CN109997848A CN201910359795.8A CN201910359795A CN109997848A CN 109997848 A CN109997848 A CN 109997848A CN 201910359795 A CN201910359795 A CN 201910359795A CN 109997848 A CN109997848 A CN 109997848A
- Authority
- CN
- China
- Prior art keywords
- energy
- production method
- saving
- environmental protection
- pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
Abstract
The present invention provides a kind of production methods of energy-saving and environmental protection granular pesticide, and mother liquor is made in pesticide active ingredient and auxiliary agent, and the mother liquor mixes in proportion after spray atomization with carrier, obtains the granular pesticide.A kind of energy conservation of the invention, the production method of environment-protection pesticide granule, using the production method of environmental-protection adsorption technological improvement granule, aqueous emulsion is made by shearing to be sanded that suspension is made or shears in pesticide active ingredient, it is uniformly mixed again with attapulgite, both finished dosage form is obtained, products obtained therefrom is without drying, not only reduce production energy consumption, and entire production link is without dust, safety, high production efficiency, production process is easy, production energy consumption is small, product quality is more stable, the granule also has slow-release function simultaneously, effective component gradually discharges, extend the lasting period, reduce spraying times, reduce persticide residue, improve pesticide utilization rate.
Description
Technical field
The invention belongs to pesticide production technology field more particularly to a kind of production methods of energy-saving and environmental protection granular pesticide.
Background technique
Currently, the production method of granular pesticide mainly uses extrusion granulation method and coating method.But extrusion granulation method
Process is tedious, and entire production process dust is more.And coating method is divided into dry-method coating and wet process is coated two kinds, dry-method coating does not add
Add any solvent, coating material is directly passed through into the packaging technique that electrostatic or dry binder form a film in surface of material, but pesticide has
Imitate phenomena such as ingredient is easy to fall off or uneven in the presence of cladding；Wet process coating is to be dispersed in surface of material by solvent appropriate, molten
Coatings are formed after agent is dry, product needs to dry, and increases production energy consumption.
Summary of the invention
In view of the problems of the above-mentioned prior art, the object of the present invention is to provide a kind of energy-saving and environmental protection granular pesticides
Production method.
The present invention is achieved through the following technical solutions above-mentioned purpose:
Mother liquor, the mother is made in pesticide active ingredient and auxiliary agent by a kind of production method of energy-saving and environmental protection granular pesticide
Liquid mixes in proportion after spray atomization with carrier, obtains the granular pesticide.
Further, the mass ratio of the pesticide active ingredient and auxiliary agent is 10-50:1-20.
Further, the mass ratio of the mother liquor and carrier is 10-20:90-80.
Further, the pesticide active ingredient is imidacloprid, avermectin, Diacloden, Biphenthrin, clothianidin, fluorine
Worm nitrile, chlopyrifos, Buprofezin, carbosulfan, thiodicarb, triazolone, diflubenzuron, Mobucin, carbofuran, bensulfuron-methyl, first
Sulphur is grand, one of pyrazosulfuron, butachlor, pretilachlor, cyhalofop-butyl, Thidiazuron, bentazone or a variety of.
Further, the auxiliary agent includes wetting agent, dispersing agent and solvent naphtha.
Further, the wetting agent is Morwet EFW, polyphosphate sodium salt, lauryl sodium sulfate or Nekal BX
In any one.
Further, the dispersing agent be lignin sulfonic acid sodium salt, naphthalenesulfonic acid-formaldehyde condensate, Morwet D-425,
In polycarboxylate, alkyl phenol polyoxyethylene ether, fatty acid ethylene oxide condensate, lignin sulfonic acid calcium salt or dispersing agent NNO
Any one.
Further, the solvent naphtha is any one in 150# solvent naphtha or 200# solvent naphtha.
Further, the mother liquor is agricultural-chemical suspension liquid or pesticide aqueous emulsion；The agricultural-chemical suspension liquid be pesticide effectively at
Divide, wetting agent, dispersing agent and water addition sand mill, clipped sand milling are made；The pesticide aqueous emulsion is pesticide active ingredient, molten
Agent oil, emulsifier and water, heated shearing are made.
Further, the carrier is attapulgite.
Compared with prior art, the beneficial effects of the present invention are: a kind of life of energy-saving and environmental protection granular pesticide of the invention
Production method, using the production method of environmental-protection adsorption technological improvement granule, by pesticide active ingredient by shear be sanded be made it is outstanding
Aqueous emulsion is made in supernatant liquid or shearing, then is uniformly mixed with attapulgite, both obtains finished dosage form, products obtained therefrom is without drying, not only
Production energy consumption is reduced, and entire production link, without dust, safety, high production efficiency, production process is easy, and production energy consumption is small,
Product quality is more stable, while the granule also has slow-release function, and effective component gradually discharges, and extends the lasting period, and reduction is applied
Medicine number reduces persticide residue, improves pesticide utilization rate.
Specific embodiment
Below just in conjunction with the embodiments, the embodiment of the present invention is described in further detail, so that the technology of the present invention
Scheme is more readily understood, grasps, but the present invention is not limited thereto.Experimental method described in following embodiments, such as without special theory
It is bright, it is conventional method；The reagent and material commercially obtain unless otherwise specified.
The preparation of embodiment 1:5% Abamectin
Preparation step is as follows:
The preparation of 50% avermectin suspension of step 1)
By mass percentage, by 50% the former medicine of AVM, 2% polycarboxylate, 0.5% polyphosphate sodium salt, more than water
Amount sufficiently enters sand mill after shearing and grinds, can obtain 50% avermectin suspension.
The preparation of 5% Abamectin of step 2)
50% avermectin suspension and attapulgite are added in batch mixer in the ratio of 1:9, mix well to get
5% avermectin granular preparation.
Embodiment 2:2% diflubenzuron granule preparation
Preparation step is as follows:
The preparation of 40% diflubenzuron suspension of step 1)
By percentage composition, by 40% diflubenzuron raw medicine, 3%Morwet D-425,1%Morwet EFW, water surplus, sufficiently
Sand mill grinding is added after shearing, 40% diflubenzuron suspension can be obtained.
2% diflubenzuron granule preparation of step 2)
40% diflubenzuron suspension is diluted with water as 20% diflubenzuron mother liquor, by 20% diflubenzuron mother liquor and attapulgite
It is added in batch mixer, is mixed well to get 2% diflubenzuron granular preparation in the ratio of 1:9.
Embodiment 3:1% imidacloprid granule preparation
Preparation step is as follows:
The preparation of 20% imidacloprid suspension of step 1)
By percentage composition, by 20% imidacloprid raw medicine, 2% dispersing agent NNO, 0.5% lauryl sodium sulfate, water surplus,
Sand mill grinding is sufficiently added after shearing, 20% imidacloprid suspension can be obtained.
1% imidacloprid granule preparation of step 2)
20% imidacloprid suspension is diluted with water as 10% imidacloprid mother liquor, by 10% imidacloprid mother liquor and attapulgite
It is added in batch mixer, is mixed well to get 1% imidacloprid granular preparation in the ratio of 1:9.
Embodiment 4:10% chlopyrifos granule preparation
Preparation step is as follows:
The preparation of 50% chlopyrifos aqueous emulsion of step 1)
By percentage composition, by 50% chlopyrifos raw medicine, 10%150# solvent naphtha, 9% alkyl phenol polyoxyethylene ether, more than water
Amount, heating, sufficiently shearing, can obtain 50% chlopyrifos aqueous emulsion.
10% chlopyrifos granule preparation of step 2)
50% chlopyrifos aqueous emulsion and attapulgite are added in batch mixer in the ratio of 2:8, mixed well to get 10%
Chlopyrifos granular preparation.
Above-described is only some embodiments of the present invention.For those of ordinary skill in the art, not
Under the premise of being detached from the invention design, various modifications and improvements can be made, these belong to protection model of the invention
It encloses.
Claims (10)
1. a kind of production method of energy-saving and environmental protection granular pesticide, it is characterised in that: mother is made in pesticide active ingredient and auxiliary agent
Liquid, the mother liquor mix in proportion after spray atomization with carrier, obtain the granular pesticide.
2. a kind of production method of energy-saving and environmental protection granular pesticide according to claim 1, it is characterised in that: the agriculture
The mass ratio of pharmaceutically active ingredient and auxiliary agent is 10-50:1-20.
3. a kind of production method of energy-saving and environmental protection granular pesticide according to claim 1, it is characterised in that: the mother
The mass ratio of liquid and carrier is 10-20:90-80.
4. a kind of production method of energy-saving and environmental protection granular pesticide according to claim 1, it is characterised in that: the agriculture
Pharmaceutically active ingredient is imidacloprid, avermectin, Diacloden, Biphenthrin, clothianidin, Fipronil, chlopyrifos, Buprofezin, fourth sulphur
Carbofuran, thiodicarb, triazolone, diflubenzuron, Mobucin, carbofuran, bensulfuron-methyl, metsulfuron-methyl, pyrazosulfuron, butachlor, third
One of careless amine, cyhalofop-butyl, Thidiazuron, bentazone are a variety of.
5. a kind of production method of energy-saving and environmental protection granular pesticide according to claim 1, it is characterised in that: described to help
Agent includes wetting agent, dispersing agent and solvent naphtha.
6. a kind of production method of energy-saving and environmental protection granular pesticide according to claim 1, it is characterised in that: the profit
Humectant is any one in Morwet EFW, polyphosphate sodium salt, lauryl sodium sulfate or Nekal BX.
7. a kind of production method of energy-saving and environmental protection granular pesticide according to claim 1, it is characterised in that: described point
Powder is lignin sulfonic acid sodium salt, naphthalenesulfonic acid-formaldehyde condensate, Morwet D-425, polycarboxylate, alkylphenol-polyethenoxy
Any one in ether, fatty acid ethylene oxide condensate, lignin sulfonic acid calcium salt or dispersing agent NNO.
8. a kind of production method of energy-saving and environmental protection granular pesticide according to claim 1, it is characterised in that: described molten
Agent oil is any one in 150# solvent naphtha or 200# solvent naphtha.
9. a kind of production method of energy-saving and environmental protection granular pesticide according to claim 1, it is characterised in that: the mother
Liquid is agricultural-chemical suspension liquid or pesticide aqueous emulsion；The agricultural-chemical suspension liquid is that pesticide active ingredient, wetting agent, dispersing agent and water are added
Sand mill, clipped sand milling are made；The pesticide aqueous emulsion is pesticide active ingredient, solvent naphtha, emulsifier and water, heated to cut
It cuts into.
10. a kind of production method of energy-saving and environmental protection granular pesticide according to claim 1, it is characterised in that: the load
Body is attapulgite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910359795.8A CN109997848A (en) | 2019-04-30 | 2019-04-30 | A kind of production method of energy-saving and environmental protection granular pesticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910359795.8A CN109997848A (en) | 2019-04-30 | 2019-04-30 | A kind of production method of energy-saving and environmental protection granular pesticide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109997848A true CN109997848A (en) | 2019-07-12 |
Family
ID=67175247
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910359795.8A Pending CN109997848A (en) | 2019-04-30 | 2019-04-30 | A kind of production method of energy-saving and environmental protection granular pesticide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109997848A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87104564A (en) * | 1986-07-02 | 1988-02-03 | 明治制药株式会社 | A kind of preparation method who contains the granular composition of agricultural chemical compound |
| WO2007030885A1 (en) * | 2005-09-16 | 2007-03-22 | Nufarm Australia Limited | Agrochemical emulsifiable concentrate |
| CN101073324A (en) * | 2006-05-15 | 2007-11-21 | 中国科学院生态环境研究中心 | Synergistic insect-killing composition |
| CN101248800A (en) * | 2007-11-20 | 2008-08-27 | 江门市植保有限公司 | Agricultural chemical composition containing fipronil and bacillus thuringiensis |
| CN102100229A (en) * | 2009-12-16 | 2011-06-22 | 联合国南通农药剂型开发中心 | Pesticide micro-capsule granules and preparation method thereof |
| CN102775241A (en) * | 2011-05-09 | 2012-11-14 | 深圳诺普信农化股份有限公司 | Granular pesticide fertilizer, and preparation method and application thereof |
-
2019
- 2019-04-30 CN CN201910359795.8A patent/CN109997848A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87104564A (en) * | 1986-07-02 | 1988-02-03 | 明治制药株式会社 | A kind of preparation method who contains the granular composition of agricultural chemical compound |
| WO2007030885A1 (en) * | 2005-09-16 | 2007-03-22 | Nufarm Australia Limited | Agrochemical emulsifiable concentrate |
| CN101073324A (en) * | 2006-05-15 | 2007-11-21 | 中国科学院生态环境研究中心 | Synergistic insect-killing composition |
| CN101248800A (en) * | 2007-11-20 | 2008-08-27 | 江门市植保有限公司 | Agricultural chemical composition containing fipronil and bacillus thuringiensis |
| CN102100229A (en) * | 2009-12-16 | 2011-06-22 | 联合国南通农药剂型开发中心 | Pesticide micro-capsule granules and preparation method thereof |
| CN102775241A (en) * | 2011-05-09 | 2012-11-14 | 深圳诺普信农化股份有限公司 | Granular pesticide fertilizer, and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108294043B (en) | Special suspending agent for flight control | |
| CN101870607B (en) | Full-biodegradable anti-caking agent for compound fertilizer/blended fertilizer and preparation method thereof | |
| CN110959614A (en) | Plant growth regulator and preparation method and application thereof | |
| CN101209940B (en) | Loss control nitrogenous fertilizer and producing method thereof | |
| CN106993625B (en) | One plant growth regulators | |
| CN104945170A (en) | Liquid foliar fertilizer special for flue-cured tobacco | |
| CN103740490A (en) | Multifunctional laundry paper and preparation method thereof | |
| CN105265430A (en) | Chitosan oligosaccharide used for relieving tebuconazole seed coating phytotoxicity | |
| CN103271025B (en) | Anilofos and pyrazosulfuron water surface diffusant and preparation method thereof | |
| CN109997848A (en) | A kind of production method of energy-saving and environmental protection granular pesticide | |
| CN110839647B (en) | Bactericidal composition containing pyraclostrobin and metiram and preparation method thereof | |
| CN108684689A (en) | A kind of emamectin-benzoate water dispersible granules and preparation method thereof | |
| CN100348107C (en) | Bordeaux mixture as nutrient protecting agent | |
| CN102217638B (en) | Pesticide composition for preventing and treating plant virus diseases | |
| CN111466374A (en) | Pesticide soluble granule and preparation method thereof | |
| CN106719637A (en) | A kind of microcapsule suspension suspending agent containing fenoxanil and Prochloraz and preparation method thereof | |
| CN102388717A (en) | Planting method capable of increasing yields and sugar contents of sugarcanes and nutrition regulator used in same | |
| CN107739661A (en) | A kind of pipe-dredging agent and preparation method | |
| JPH02279611A (en) | Preparation of bordeaux mixture | |
| CN105104395B (en) | A kind of Mancozeb microcapsule formulations and preparation method thereof | |
| CN111517857A (en) | High-tower continuous cropping-preventing urea-based fertilizer and preparation method thereof | |
| CN103449888A (en) | Foliar fertilizer having leaf blade cleaning effect | |
| CN108794223A (en) | High dissolubility siliceous fertilizer prepared by a kind of ultrafine dust using processing wollastonite recycling（Soil conditioner）And preparation method thereof | |
| CN105831115A (en) | Water-dispersible granule and clean production method thereof | |
| CN107573144A (en) | A kind of organic fertilizer drier and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: No.58 shuangxiang Road, Hongshan Fine Chemical Industry Park, Liuhe District, Nanjing, Jiangsu Province, 211500 Applicant after: Jiangsu Aijin crop Technology Group Co., Ltd Address before: No.58 shuangxiang Road, Hongshan Fine Chemical Industry Park, Liuhe District, Nanjing, Jiangsu Province, 211500 Applicant before: JIANGSU ESSENCE AGROCHEMICAL Co.,Ltd. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190712 |