CN109991383A - A kind of water quality detection system - Google Patents

A kind of water quality detection system Download PDF

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Publication number
CN109991383A
CN109991383A CN201711478807.6A CN201711478807A CN109991383A CN 109991383 A CN109991383 A CN 109991383A CN 201711478807 A CN201711478807 A CN 201711478807A CN 109991383 A CN109991383 A CN 109991383A
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water
electric field
heavy metal
metal ion
outlet
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CN109991383B (en
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陈建华
刘红星
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Ningbo Fotile Kitchen Ware Co Ltd
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Ningbo Fotile Kitchen Ware Co Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water
    • G01N33/1813Specific cations in water, e.g. heavy metals
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water
    • G01N33/1826Organic contamination in water

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The present invention relates to a kind of water quality detection systems, including being located at the organic matter detection sensor for detecting Organic substance in water content;It is characterized by also including can detect in water whether the heavy metal ion detection device containing heavy metal ion.Compared with prior art, the present invention has the advantages that Organic substance in water content can not only be detected, also pass through setting heavy metal ion detection device, cation more different than lotus in water is subjected to separation shunting, compare lotus further according to heavy metal ion, the detection of TDS value is carried out to one of water for shunting subexit, can detect in water whether contain heavy metal ion with accurate and effective.

Description

A kind of water quality detection system
Technical field
The present invention relates to a kind of water quality detection systems.
Background technique
The pollution of water quality at present is concentrated mainly on 2 major parts, and a major class is inorganic concentration of heavy metal ion, another major class It is organic cod concentration.Measurement Organic substance in water content generally passes through organic matter sensor and is detected at present, and to being in water It is no substantially to be judged by TDS value in measurement water mostly containing heavy metal ion, but TDS value cannot accurately show be in water It is no to contain heavy metal ion.
Summary of the invention
The technical problem to be solved by the present invention is to for the above-mentioned prior art provide one kind can not only detect it is organic in water Object content, moreover it is possible to more sensitively judge in water whether the water quality detection system containing heavy metal ion.
The technical scheme of the invention to solve the technical problem is: a kind of water quality detection system, including be located at and use In the organic matter detection sensor of detection Organic substance in water content;Whether it is characterized by also including can detect in water containing weight The heavy metal ion detection device of metal ion, the heavy metal ion detection device include
Separating flow tract, separating flow tract have entrance and exit;
Electric field positive plate is separated, is arranged in separating flow tract, close to the outlet of separating flow tract, just with external stabilized power Pole connection;
Electric field negative electrode tab is separated, is arranged in separating flow tract, it is negative with external stabilized power close to the outlet of separating flow tract Pole connection;
The entrance of separating flow tract is positioned close to the front end of separation electric field negative electrode tab;
The outlet of the separating flow tract is formed between separation electric field positive plate rear end and separation electric field negative electrode tab rear end, And exporting for separating flow tract is equipped with N block and separates the split-flow baffles that electric field positive plate parallel interval is arranged, thus by separating flow tract Outlet be divided into N+1 shunting subexit, the value of N is the natural number more than or equal to 2;Most intermediate shunting will be located at Outlet is filled positioned at the water that any of most intermediate two shuntings subexit shunts subexit outflow as detection of heavy metal ion The first water outlet set;It is mixed the water that subexit flows out is shunted from remaining, second as heavy metal ion detection device Water outlet;
And the TDS sensor for detecting TDS value in the first water outlet, using the detected value of TDS sensor as being in water The no foundation containing heavy metal ion.The distance between N block split-flow baffles can be identical, i.e. N block split-flow baffles are by separating flow tract Outlet be divided into the identical shunting subexit of N+1 size.
The distance between N block split-flow baffles can also be different, preferably, the N=2, wherein first piece of split-flow baffles With separate the distance between electric field positive plate are as follows:Wherein K is less than 1 greater than 0 Constant, voltage of the U between the second external stabilized power positive and negative anodes, l are separation electric field positive plate or separation electric field negative electrode tab Length, v are the water velocity that water flows through separating flow tract, and d is the distance between separation electric field positive plate and separation electric field negative electrode tab;Range be 1/15~1/8;Second piece of split-flow baffles with separate the distance between electric field positive plate are as follows: Range be 1/45~1/40;It will be from first piece of split-flow baffles and second piece First water outlet of the water for shunting subexit outflow formed between split-flow baffles as detection of heavy metal ion separator;It will be from The water that other two shunts subexit outflow is mixed, the second water outlet as detection of heavy metal ion separator;In this way, If in water containing silver ion, cadmium ion, barium ions, mercury ion, lead ion etc. than lotus 1/15~1/8 to 1/45~1/40 it Between metal cation, then by first water outlet TDS value can detect, if TDS value be greater than preset threshold, by first It is discharged the waste water as water purifier, the normal water outlet by the second water outlet as water purifier.
As another preferred embodiment, the N=3, wherein first piece of split-flow baffles with separate the distance between electric field positive plate Are as follows:Wherein K be less than 1 be greater than 0 constant, U be the second external stabilized power just Voltage between cathode, l are the length for separating electric field positive plate or separating electric field negative electrode tab, and v is the water that water flows through separating flow tract Flow velocity degree, d are the distance between separation electric field positive plate and separation electric field negative electrode tab;Range be 1/15~1/8;Second Block split-flow baffles with separate the distance between electric field positive plate are as follows: Range It is 1/28~1/20;Third block split-flow baffles with separate the distance between electric field positive plate are as follows: Range are as follows: 1/45~1/40, will be from second piece of split-flow baffles and third block First water outlet of the water for shunting subexit outflow formed between split-flow baffles as detection of heavy metal ion separator;It will be from The water that its excess-three shunts subexit outflow is mixed, the second water outlet as detection of heavy metal ion separator;This Sample, the metal cation than lotus between 1/28~1/20 to 1/45~1/40 such as mercury ion, lead ion, then go out by first The TDS value of water can detect, if TDS value is greater than preset threshold, waste water by the first water outlet as water purifier, by second It is discharged the normal water outlet as water purifier.
In view of attached collection electric field and separate electric field voltage it is excessive when, the electrolysis of water is easy to cause, in order not to as making water It is electrolysed, the voltage between the external stabilized power positive and negative anodes is less than or equal to 2V.
It is identical as electric field anode leaf length is separated to separate electric field cathode leaf length.
As an improvement, the invention also includes with further include in organic matter detection sensor and heavy metal ion detection device TDS sensor electrical connection display screen.
It improves again, the water inlet of water quality detection system is connected to the entrance of organic matter detection sensor, and organic analyte detection passes The outlet of sensor is connected to the entrance of flowmeter, the entrance of separating flow tract in the outlet of flowmeter and heavy metal ion detection device Connection, flowmeter are also electrically connected with display screen.
It improves again, the 2nd TDS sensor is also connected between the outlet of organic matter detection sensor and the entrance of flowmeter, 2nd TDS sensor is also electrically connected with display screen.
Compared with the prior art, the advantages of the present invention are as follows: Organic substance in water content can not only be detected, setting weight is also passed through Cation more different than lotus in water is carried out separation shunting, further according to heavy metal ion than lotus, to it by metal ion detection device In one shunting subexit water carry out the detection of TDS value, can detect in water whether contain heavy metal ion with accurate and effective.
Detailed description of the invention
Fig. 1 is the schematic diagram of water quality detection system in the embodiment of the present invention one.
Fig. 2 is the schematic diagram of heavy metal ion detection device in the embodiment of the present invention one.
Fig. 3 is the schematic diagram of heavy metal ion detection device in the embodiment of the present invention two.
Fig. 4 is the schematic diagram of heavy metal ion detection device in the embodiment of the present invention three.
Specific embodiment
The present invention will be described in further detail below with reference to the embodiments of the drawings.
Water quality detection system as shown in Figure 1, including being located at organic analyte detection biography for detecting Organic substance in water content Sensor 8, and can detect in water whether the heavy metal ion detection device containing heavy metal ion, with organic matter detection sensor 8 And the display screen 9 that the TDS sensor 7 in heavy metal ion detection device is electrically connected;Wherein the water inlet of water quality detection system with The entrance of organic matter detection sensor is connected to, and the outlet of organic matter detection sensor is connected to the entrance of flowmeter 10, flowmeter 10 outlet is connected to the entrance of separating flow tract in heavy metal ion detection device, and flowmeter 10 is also electrically connected with display screen 9;Have The 2nd TDS sensor 11 can also be connected between the outlet of machine analyte detection sensor and the entrance of flowmeter, the 2nd TDS is passed Sensor 11 is also electrically connected with display screen 9.
The structure of organic matter detection sensor uses prior art conventional structure, uses Patent No. in the present embodiment 201720316550.3 structure described in, and will not be described here in detail.
In the present embodiment, heavy metal ion detection device includes, shown in Figure 2:
Separating flow tract 1, separating flow tract have entrance and exit;
Electric field positive plate 2 is separated, is arranged in separating flow tract, close to the outlet of separating flow tract, with external stabilized power Anode connection;
Electric field negative electrode tab 3 is separated, is arranged in separating flow tract, close to the outlet of separating flow tract, with external stabilized power Cathode connection;It is identical as electric field anode leaf length is separated to separate electric field cathode leaf length;
The entrance of separating flow tract is positioned close to the front end of separation electric field negative electrode tab;
The outlet of the separating flow tract is formed between separation electric field positive plate rear end and separation electric field negative electrode tab rear end, And exporting for separating flow tract is equipped with N block and separates the split-flow baffles 6 that electric field positive plate parallel interval is arranged, thus by separating flow tract Outlet be divided into N+1 shunting subexit, the value of N is the natural number more than or equal to 2;Most intermediate shunting will be located at Outlet shunts the water of subexit outflow as detection of heavy metal ion point positioned at any of most intermediate two shuntings subexit The first water outlet from device;It is mixed the water that subexit flows out is shunted from remaining, separates and fill as detection of heavy metal ion The second water outlet set;
And the TDS sensor 7 for detecting TDS value in the first water outlet, using the detected value of TDS sensor as being in water The no foundation containing heavy metal ion, as long as the detected value non-zero of TDS sensor, shows to contain heavy metal ion in water.
In the present embodiment, N=3 will extremely separate the split-flow baffles between electric field positive plate from separation electric field negative electrode tab successively First piece of split-flow baffles, second piece of split-flow baffles, third block split-flow baffles are denoted as, it will be from second piece of split-flow baffles and third block point First water outlet of the water for shunting subexit outflow formed between stream partition as detection of heavy metal ion separator;Will from its The water that excess-three shunts subexit outflow is mixed, the second water outlet as detection of heavy metal ion separator.
The working principle of detection of heavy metal ion separator are as follows:
Water enters from the entrance of separating flow tract, and under the action of separate electric field, cation in water is to separating electric field cathode Piece is mobile, and the anion in water is in separation electric field positive plate movement.Consider that too high voltages are easy to cause the electrolysis of water, therefore excellent First consider that the separation voltage of electric field of input cannot be excessive, should be typically lower than 2V or less.Identical electric field moves different ions Shifting ability is different, and is mainly determined according to different charged ratios, under identical uniform electric field, drive of the ion in water flow It is lower enter separation electric field, the entrance of separating flow tract be positioned close to separation electric field negative electrode tab front end so that it is all sun from The primary condition of son is consistent, and under the action of separating electric field, the different ions in water can be moved under the action of separating electric field It moves, anion is moved to separation electric field positive plate, and cation can be moved to separation electric field negative electrode tab, since different ions has Different charges and different atomic weight, it is calcium (Ca that main cation is most of in normal water2+ atomic weight be 20), magnesium (Mg2+ ion atoms amount be 20), sodium (Na+ atomic weight be 11), also some other micro cation;But for some In the water of pollution, especially in the water of heavy metal pollution, a large amount of heavy metal ion is contained, such as lead (Pb2+ atomic weight be 82), mercury (Hg2+ atomic weight be 80), silver (Ag2+ atomic weight be 47), barium (Ba2+ atomic weight be 56), cadmium (Cd2+ atomic weight 48) etc. for.Different ions has different ratio lotuses, if calcium ion is 2/20 than lotus, cadmium ion 2/48, and lead ion 2/ 82, therefore the ratio lotus of heavy metal ion is relatively small, especially lead, mercury etc., and cation such as calcium and magnesium common in general water Sodium etc. compares larger than lotus.Therefore, in identical separation electric field, identical initial velocity, the ion of not year-on-year lotus is mobile Distance relation to than lotus, than proportional relationship, that is, the distance moved is related to q/m, under phase same electric field, the cation bigger than lotus Movement speed is fast, and the cationic movement speed smaller than lotus is slow;Especially heavy metal ion is due to, movement speed smaller than lotus Slowly;By the diversion channel of water outlet, water is shunted, so as to be separated to zwitterion different in water, is passed through Using the water for shunting subexit outflow formed between second piece of split-flow baffles and third block split-flow baffles as heavy metal ion Detect the first water outlet of separator;It is mixed the water that subexit flows out is shunted from its excess-three, as heavy metal ion Detect the second water outlet of separator, so that it may by most of separation of heavy metal ions and detected, pass through detection the at this time TDS value in one water outlet, so that it may judge whether contain heavy metal ion in water;It is of course also possible to by by TDS sensor The value of detected value and the 2nd TDS sensor compares, as long as two values are different, may also indicate that and contains heavy metal in water Ion, and shown by display screen.
Embodiment two
What is different from the first embodiment is that three pieces of split-flow baffles are not evenly spaced on, it is shown in Figure 3, wherein
First piece of split-flow baffles with separate the distance between electric field positive plate are as follows:Its Middle K be less than 1 be greater than 0 constant, voltage of the U for the second external stabilized power positive and negative anodes between, l be separate electric field positive plate or The length of electric field negative electrode tab is separated, v is the water velocity that water flows through separating flow tract, and d is separation electric field positive plate and separation electric field The distance between negative electrode tab;Range be 1/15~1/8;In this way, calcium ion, sodium ion etc. are than lotus 0 to 1/15~1/8 Between metal cation can be formed between first piece of split-flow baffles and separating flow tract inner wall shunting subexit outflow;
Second piece of split-flow baffles with separate the distance between electric field positive plate are as follows: Range be 1/28~1/20;In this way, the gold than lotus between 1/15~1/8 to 1/28~1/20 such as silver ion, cadmium ion Belong to the shunting subexit outflow that cation can be formed between first piece of split-flow baffles and second piece of split-flow baffles;
Third block split-flow baffles with separate the distance between electric field positive plate are as follows: Range are as follows: 1/45~1/40;In this way, barium ions, lead ion, mercury ion etc. are than lotus 1/28~1/20 to 1/45~1/ The shunting subexit that metal cation between 40 can be formed between second piece of split-flow baffles and third block split-flow baffles Outflow.
At this point, the water for shunting subexit outflow formed between second piece of split-flow baffles and third block split-flow baffles is made For the first water outlet of detection of heavy metal ion separator, whether heavy metal ion can be contained in more accurate effectively detection water.
Embodiment three
Unlike embodiment two, split-flow baffles are shown in Figure 4 equipped with two pieces, in which:
First piece of split-flow baffles with separate the distance between electric field positive plate are as follows: Wherein K is the constant for being greater than 0 less than 1, and voltage of the U between the second external stabilized power positive and negative anodes, l is separation electric field positive plate Or the length of separation electric field negative electrode tab, v are the water velocity that water flows through separating flow tract, d is separation electric field positive plate and separation electricity The distance between field negative electrode tab;Range be 1/15~1/8;
Second piece of split-flow baffles with separate the distance between electric field positive plate are as follows: Range be 1/45~1/40.
At this point, the water for shunting subexit outflow formed between first piece of split-flow baffles and second piece of split-flow baffles is made For the first water outlet of detection of heavy metal ion separator, also accurately can effectively detect in water whether contain heavy metal ion.

Claims (8)

1. a kind of water quality detection system, including being located at the organic matter detection sensor for detecting Organic substance in water content;It is special Sign is: further include can detect in water whether the heavy metal ion detection device containing heavy metal ion, heavy metal ion inspection Surveying device includes
Separating flow tract, separating flow tract have entrance and exit;
Electric field positive plate is separated, is arranged in separating flow tract, close to the outlet of separating flow tract, is connected with the anode of external stabilized power It connects;
Electric field negative electrode tab is separated, is arranged in separating flow tract, close to the outlet of separating flow tract, is connected with the cathode of external stabilized power It connects;
The entrance of separating flow tract is positioned close to the front end of separation electric field negative electrode tab;
The outlet of the separating flow tract is formed between separation electric field positive plate rear end and separation electric field negative electrode tab rear end, and is divided Outlet from runner is equipped with N block and the split-flow baffles for separating the setting of electric field positive plate parallel interval, thus going out separating flow tract Mouth is divided into N+1 shunting subexit, and the value of N is the natural number more than or equal to 2;A most intermediate shunting subexit will be located at Or the water of subexit outflow is shunted as heavy metal ion detection device positioned at any of most intermediate two shuntings subexit First water outlet;It is mixed the water that subexit flows out is shunted from remaining, the second water outlet as heavy metal ion detection device;
And the TDS sensor for detecting TDS value in the first water outlet, whether contain using the detected value of TDS sensor as in water There is the foundation of heavy metal ion.
2. water quality detection system according to claim 1, it is characterised in that: the N=2, wherein first piece of split-flow baffles With separate the distance between electric field positive plate are as follows:Wherein K is less than 1 greater than 0 Constant, voltage of the U between the second external stabilized power positive and negative anodes, l are separation electric field positive plate or separation electric field negative electrode tab Length, v are the water velocity that water flows through separating flow tract, and d is the distance between separation electric field positive plate and separation electric field negative electrode tab;Range be 1/15~1/8;Second piece of split-flow baffles with separate the distance between electric field positive plate are as follows: Range be 1/45~1/40;It will be from first piece of split-flow baffles and second piece First water outlet of the water for shunting subexit outflow formed between split-flow baffles as heavy metal ion detection device;Will from remaining Two water for shunting subexit outflow are mixed, the second water outlet as heavy metal ion detection device.
3. water quality detection system according to claim 1, it is characterised in that: the N=3, wherein first piece of split-flow baffles With separate the distance between electric field positive plate are as follows:Wherein K is less than 1 greater than 0 Constant, voltage of the U between the second external stabilized power positive and negative anodes, l are separation electric field positive plate or separation electric field negative electrode tab Length, v are the water velocity that water flows through separating flow tract, and d is the distance between separation electric field positive plate and separation electric field negative electrode tab;Range be 1/15~1/8;Second piece of split-flow baffles with separate the distance between electric field positive plate are as follows: Range be 1/28~1/20;Third block split-flow baffles with separating electric field just The distance between pole piece are as follows: Range are as follows: 1/45~1/40, will be from second The water for shunting subexit outflow formed between block split-flow baffles and third block split-flow baffles is as heavy metal ion detection device First water outlet;The water that subexit flows out will be shunted from its excess-three to mix, the as heavy metal ion detection device Two water outlets.
4. water quality detection system according to claim 1, it is characterised in that: between the external stabilized power positive and negative anodes Voltage is less than or equal to 2V.
5. water quality detection system according to claim 1, it is characterised in that: the separation electric field cathode leaf length with separate Electric field anode leaf length is identical.
6. water quality detection system described in claim according to claim 1~any one of 5, it is characterised in that: further include With further include the display screen being electrically connected with the TDS sensor in organic matter detection sensor and heavy metal ion detection device.
7. water quality detection system according to claim 6, it is characterised in that: the water inlet and organic matter of water quality detection system The entrance of detection sensor is connected to, and the outlet of organic matter detection sensor be connected to the entrance of flowmeter, the outlet of flowmeter and The entrance connection of separating flow tract, flowmeter are also electrically connected with display screen in heavy metal ion detection device.
8. water quality detection system according to claim 7, it is characterised in that: the outlet of organic matter detection sensor and flow The 2nd TDS sensor is also connected between the entrance of meter, the 2nd TDS sensor is also electrically connected with display screen.
CN201711478807.6A 2017-12-29 2017-12-29 Water quality detection system Active CN109991383B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR200326013Y1 (en) * 2003-01-23 2003-09-13 곽종운 Electronic field effect apparatus for water treatment
CN101200325A (en) * 2007-12-21 2008-06-18 南开大学 Electro-deionization method and device for synchronously concentrating and purifying heavy metal wastewater
CN103383369A (en) * 2012-05-04 2013-11-06 珠海格力电器股份有限公司 TDS detection device for water purifier and water purifier
CN105253965A (en) * 2015-10-19 2016-01-20 江门市腾飞科技有限公司 Intelligent water purifier for removing heavy metals in water through adsorption by electric field
CN106348397A (en) * 2015-07-13 2017-01-25 张传忠 Electric desalinating device
CN207623327U (en) * 2017-12-29 2018-07-17 宁波方太厨具有限公司 A kind of water quality detection system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR200326013Y1 (en) * 2003-01-23 2003-09-13 곽종운 Electronic field effect apparatus for water treatment
CN101200325A (en) * 2007-12-21 2008-06-18 南开大学 Electro-deionization method and device for synchronously concentrating and purifying heavy metal wastewater
CN103383369A (en) * 2012-05-04 2013-11-06 珠海格力电器股份有限公司 TDS detection device for water purifier and water purifier
CN106348397A (en) * 2015-07-13 2017-01-25 张传忠 Electric desalinating device
CN105253965A (en) * 2015-10-19 2016-01-20 江门市腾飞科技有限公司 Intelligent water purifier for removing heavy metals in water through adsorption by electric field
CN207623327U (en) * 2017-12-29 2018-07-17 宁波方太厨具有限公司 A kind of water quality detection system

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