CN109989727A - A kind of ground-dipping uranium extraction drilling de-plugging anatonosis technique - Google Patents

A kind of ground-dipping uranium extraction drilling de-plugging anatonosis technique Download PDF

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Publication number
CN109989727A
CN109989727A CN201711475704.4A CN201711475704A CN109989727A CN 109989727 A CN109989727 A CN 109989727A CN 201711475704 A CN201711475704 A CN 201711475704A CN 109989727 A CN109989727 A CN 109989727A
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Prior art keywords
hole flushing
bet
ground
injection
reagent
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CN201711475704.4A
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吉宏斌
张青林
李小阳
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XINJIANG CNNC TIANSHAN URANIUM INDUSTRY Co Ltd
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XINJIANG CNNC TIANSHAN URANIUM INDUSTRY Co Ltd
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Priority to CN201711475704.4A priority Critical patent/CN109989727A/en
Publication of CN109989727A publication Critical patent/CN109989727A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/52Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
    • C09K8/528Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning inorganic depositions, e.g. sulfates or carbonates
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B37/00Methods or apparatus for cleaning boreholes or wells
    • E21B37/06Methods or apparatus for cleaning boreholes or wells using chemical means for preventing or limiting, e.g. eliminating, the deposition of paraffins or like substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2208/00Aspects relating to compositions of drilling or well treatment fluids
    • C09K2208/12Swell inhibition, i.e. using additives to drilling or well treatment fluids for inhibiting clay or shale swelling or disintegrating

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention belongs to ground-dipping uranium extraction technical fields, more particularly to a kind of ground-dipping uranium extraction drilling de-plugging anatonosis technique, purpose is by the way that the operation of the series of process such as activator, integrative blockage relieving agent, anti-expansion displacer and state modulator is added to blocking ore bed, it is finally reached the effect of uranium deposit de-plugging anatonosis, thus near wellbore zone and jamming of ore bed problem in the neutral extract technology of very good solution.It is characterized by: it includes the steps that preparation of reagents, injection surfactant, injection integrative blockage relieving agent, the anti-expansion displacer of injection, standing and air compressor machine hole flushing.Using the present invention in the technology for washing well of uranium in Xinjiang mineral deposit, jamming of ore bed is efficiently solved the problems, such as, horizontal 2-3m when water is all larger than normal after hole flushing3/ h, and hold time and reach 130d or more, and stratum can be prevented by secondary injury, it is feasible in technology and reasonable in economy, it is the preferred hole flushing technology of uranium deposit de-plugging anatonosis.

Description

A kind of ground-dipping uranium extraction drilling de-plugging anatonosis technique
Technical field
The invention belongs to ground-dipping uranium extraction technical fields, and in particular to a kind of ground-dipping uranium extraction drilling de-plugging anatonosis technique.
Background technique
Successful application and development with China Yi Li uranium mine ground-dipping uranium extraction technology, in China, other mines are also carried out Ground-dipping uranium extraction technical application can be divided into acid system leaching, alkaline Leaching and neutrality according to different mine ledge core conditions at present Leach etc..Due to ground-dipping uranium extraction be underground carry out, underground water rock chemical reaction is extremely complex, either acid system, alkaline process or CO2+O2Neutrality leaches, and all having one in recovery process cannot be neglected blockage problem, and pumping fluid apertures water is caused due to blocking Amount decline, ground leaching work cannot proceed normally.
Uranium in Xinjiang mineral deposit is that domestic explored large size can one of ground leaching sand uranium deposit.The mineral deposit ore body is in multilayer point Cloth, permeability is low, and hydrogeologic condition is more complex, and carbonate content is high in ore and is unevenly distributed.In view of uranium in Xinjiang mine The geological hydrologies features such as height of bed carbonate hyposmosis, mineral deposit industrialization exploitation use CO2+O2Ground dipping uranium extracting process.CO2+ O2Ground dipping uranium extracting process has many advantages, such as that process is short, effect on environment is small, achieves and is widely applied in the U.S., into several years at me State Xinjiang and Inner Mongol have also carried out exploratory experiment and have studied and achieve initial experience.Since trial production in 2 months 2014, until current Put into 8, exploiting field altogether, with continuing for leaching process, there is the decline of pumping liquid measure in part drilling, in leachate calcium, magnesium etc. from Sub- content increases, and phenomena such as red precipitate occurs on immersible pump, these phenomenons illustrate that drilling near wellbore zone or ore bed occur Electroless Ni-P-C-O plating, by sampling, dry, acid dissolution to tamper, it was demonstrated that tamper is mainly CaCO3, Fe (OH)3、MgCO3 And Al (OH)3, take effect after the modes well-flushing such as conventional air compressor machine poor, be no longer satisfied the needs of steady production, produce Situation is very urgent, therefore, it is necessary to study new pumping and washing process, solves the problems, such as near wellbore zone and jamming of ore bed, improves ore bed and seeps Permeability ensures that production is stablized.
Summary of the invention
The purpose of the present invention is by the way that a systems such as activator, integrative blockage relieving agent, anti-expansion displacer are added to blocking ore bed Column technological operation and state modulator are finally reached the effect of uranium deposit de-plugging anatonosis, thus the neutral leaching work of very good solution Near wellbore zone and jamming of ore bed problem in skill.
The present invention is implemented as follows:
A kind of ground-dipping uranium extraction drilling de-plugging anatonosis technique, specifically comprises the following steps:
Step 1: preparation of reagents;
4 anti-corrosion groove tanks are configured, are respectively intended to prepare clear water, surfactant, integrative blockage relieving suppository and anti-expansion replacement Liquid, each groove tank are interconnected at top and bottom, convey and recycle convenient for liquid;
Step 2: injection surfactant;
In 5m310kg surfactant is added in clear water, after mixing using pipeline pump pressurization bet, bet pressure dimension It holds in 1.5-1.8Mpa, reagent is directly injected by filter segment by hole flushing air hose;
Step 3: injection integrative blockage relieving agent;
In 4m3It is steady that 2000kg HCl, 300kg HF, the high temperature acidified corrosive liquid of 120kg, 120kg iron ion are added in clear water Determine agent, 125kg NH4Cl, after mixing using pipeline pump pressurization bet, bet pressure maintains 1.5-1.8Mpa, by washing Reagent is directly injected into filter segment by hole air hose, when acid solution is into people stratum, CaCO of the main acid first with filter segment deposition3 And MgCO3It reacts, the integrative blockage relieving agent for being mixed with hydrofluoric acid, which can effectively dissolve near wellbore zone common acids, can not dissolve clay Mineral dissolve the clay mineral of chemical precipitation and blocking channel;
Step 4: anti-expansion displacer is injected;
In 5m3250kg NH is added in clear water4Cl, after mixing using pipeline pump pressurization bet, bet pressure is maintained Reagent is directly injected into filter segment by hole flushing air hose, prevents clay swell to the secondary injury on stratum by 1.5-1.8Mpa;
Step 5: it stands;
For the chemical reaction for reinforcing reagent and ore bed, it will thoroughly block the substance in ore bed and remove, after the above reagent injection, It stands for 24 hours;
Step 6: air compressor machine hole flushing;
Hole flushing is carried out using air compressor machine, until hole flushing liquid pH terminates when reaching 6 or more.
Chemical equation in step 3 as described above are as follows:
CaCO3+2HCl→CaCl2+H2O+CO2
Fe(OH)3+3HCl→FeCl3+3H2O
Al2Si2H4O9+18H++l8RF→2H2SiF6+2AlF3+6H2O+18R+
The beneficial effects of the present invention are:
1. injecting surfactant to release ore bed water-blocking effect: a large amount of hole flushing job descriptions are impregnated using single strong acid Hole flushing can not obtain ideal hole flushing effect, and reason is not consider the water-blocking effect of the generation in water-acid-rock mechanism, We pass through a large amount of field tests, and final determine should inject surfactant in de-plugging agent to release ore bed water-blocking effect, improve The contact area of de-plugging agent and tamper.
2. injecting integrative blockage relieving agent dissolution blocking impurity: being prepad fluid using surfactant, HCl is aided with as main acid HF, high-temperature acidification corrosion inhibitor, ferrous stability, NH4The various additives such as Cl, to dissolve calcareous, irony and part of clay mine Object, and can effectively prevent Fe ion secondary precipitation.
3. eliminating the expansion during de-plugging: being added during integrative blockage relieving agent carries out ore bed de-plugging by NH4Cl The anti-expansion displacer prepared with clear water, can prevent clay swell to the secondary injury on stratum.
Specific embodiment
Below with reference to embodiment, the present invention is described further.
Uranium deposit de-plugging anatonosis washing technology implements specific steps:
1. preparation of reagents: configuration 4 anti-corrosion groove tanks, be respectively intended to prepare clear water, surfactant, integrative blockage relieving suppository and Anti- expansion displacement fluid, each groove tank are interconnected at top and bottom, convey and recycle convenient for liquid.
2. injecting surfactant: in 5m310kg surfactant is added in clear water, is added after mixing using pipeline pump Pressure note, bet pressure maintain 1.5-1.8Mpa, reagent are directly injected into filter segment by hole flushing air hose.
3. injecting integrative blockage relieving agent: in 4m32000kg HCl, 300kg HF, the high temperature acidified corrosion of 120kg are added in clear water Liquid, 120kg ferrous stability, 125kg NH4Cl, after mixing using pipeline pump pressurization bet, bet pressure is maintained Reagent is directly injected into filter segment by hole flushing air hose by 1.5-1.8Mpa, when acid solution is into people stratum, main acid first with mistake The CaCO of filter section deposition3And MgCO3It reacts, being mixed with the integrative blockage relieving agent of hydrofluoric acid, can effectively to dissolve near wellbore zone general Logical acid can not dissolve clay mineral, and the clay mineral of chemical precipitation and blocking channel is dissolved.(reaction mechanism: CaCO3+2HCl → CaCl2+H2O+CO2↑、Fe(OH)3+3HCl→FeCl3+3H2O
Al2Si2H4O9+18H++l8RF→2H2SiF6+2AlF3+6H2O+18R+)
4. injecting anti-expansion displacer: in 5m3250kg NH is added in clear water4Cl is pressurizeed using pipeline pump after mixing Bet, bet pressure maintain 1.5-1.8Mpa, reagent are directly injected into filter segment by hole flushing air hose, prevents clay swollen The swollen secondary injury to stratum.
5. standing: for the chemical reaction for reinforcing reagent and ore bed, it will thoroughly block the substance in ore bed and remove, the above reagent After injection, stand for 24 hours.
6. air compressor machine hole flushing: hole flushing is carried out using air compressor machine, until hole flushing liquid pH terminates when reaching 6 or more.
Using the present invention in the technology for washing well of uranium in Xinjiang mineral deposit, jamming of ore bed, water after hole flushing are efficiently solved the problems, such as Amount horizontal 2-3m when being all larger than normal3/ h, and hold time and reach 130d or more, and stratum can be prevented by secondary injury, It is feasible in technology and reasonable in economy, it is the preferred hole flushing technology of uranium deposit de-plugging anatonosis.
Any modifications, equivalent substitutions and improvements made within the spirit and principles of the present invention, should all be in this hair Within bright protection scope.

Claims (2)

  1. The de-plugging anatonosis technique 1. a kind of ground-dipping uranium extraction drills, specifically comprises the following steps:
    Step 1: preparation of reagents;
    4 anti-corrosion groove tanks are configured, are respectively intended to prepare clear water, surfactant, integrative blockage relieving suppository and anti-expansion displacement fluid, respectively Groove tank is interconnected at top and bottom, conveys and recycles convenient for liquid;
    Step 2: injection surfactant;
    In 5m310kg surfactant is added in clear water, after mixing using pipeline pump pressurization bet, bet pressure is maintained Reagent is directly injected into filter segment by hole flushing air hose by 1.5-1.8Mpa;
    Step 3: injection integrative blockage relieving agent;
    In 4m3In clear water be added 2000kg HCl, 300kg HF, the high temperature acidified corrosive liquid of 120kg, 120kg ferrous stability, 125kg NH4Cl, after mixing using pipeline pump pressurization bet, bet pressure maintains 1.5-1.8Mpa, passes through hole flushing wind Reagent is directly injected into filter segment by pipe, when acid solution is into people stratum, CaCO of the main acid first with filter segment deposition3And MgCO3It reacts, the integrative blockage relieving agent for being mixed with hydrofluoric acid, which can effectively dissolve near wellbore zone common acids, can not dissolve clay pit Object dissolves the clay mineral of chemical precipitation and blocking channel;
    Step 4: anti-expansion displacer is injected;
    In 5m3250kg NH is added in clear water4Cl, after mixing using pipeline pump pressurization bet, bet pressure maintains 1.5- Reagent is directly injected into filter segment by hole flushing air hose, prevents clay swell to the secondary injury on stratum by 1.8Mpa;
    Step 5: it stands;
    For the chemical reaction for reinforcing reagent and ore bed, it will thoroughly block the substance in ore bed and remove, after the above reagent injection, stand 24h;
    Step 6: air compressor machine hole flushing;
    Hole flushing is carried out using air compressor machine, until hole flushing liquid pH terminates when reaching 6 or more.
  2. The de-plugging anatonosis technique 2. ground-dipping uranium extraction according to claim 1 drills, it is characterised in that: in the step three Chemical equation are as follows:
    CaCO3+2HCl→CaCl2+H2O+CO2
    Fe(OH)3+3HCl→FeCl3+3H2O
    Al2Si2H4O9+18H++l8RF→2H2SiF6+2AlF3+6H2O+18R+
CN201711475704.4A 2017-12-29 2017-12-29 A kind of ground-dipping uranium extraction drilling de-plugging anatonosis technique Pending CN109989727A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111520107A (en) * 2020-04-24 2020-08-11 核工业北京化工冶金研究院 Well flushing process for in-situ leaching uranium mining production well
CN111878049A (en) * 2020-07-30 2020-11-03 核工业北京化工冶金研究院 High-power ultrasonic blockage removal and infiltration increase device and method for in-situ leaching uranium mine
CN112943129A (en) * 2019-11-26 2021-06-11 中核内蒙古矿业有限公司 Drilling and hole-washing device and method for in-situ leaching uranium mining of large buried depth thick mineral-bearing aquifer
CN114622866A (en) * 2020-12-14 2022-06-14 中核内蒙古矿业有限公司 NaOH well washing process for in-situ leaching mine
CN116004199A (en) * 2022-12-19 2023-04-25 中核通辽铀业有限责任公司 Uranium mining and liquid injection well anti-swelling agent and method for improving liquid injection amount of uranium mining and liquid injection well

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112943129A (en) * 2019-11-26 2021-06-11 中核内蒙古矿业有限公司 Drilling and hole-washing device and method for in-situ leaching uranium mining of large buried depth thick mineral-bearing aquifer
CN111520107A (en) * 2020-04-24 2020-08-11 核工业北京化工冶金研究院 Well flushing process for in-situ leaching uranium mining production well
CN111878049A (en) * 2020-07-30 2020-11-03 核工业北京化工冶金研究院 High-power ultrasonic blockage removal and infiltration increase device and method for in-situ leaching uranium mine
CN114622866A (en) * 2020-12-14 2022-06-14 中核内蒙古矿业有限公司 NaOH well washing process for in-situ leaching mine
CN114622866B (en) * 2020-12-14 2024-03-19 中核内蒙古矿业有限公司 In-situ leaching mine NaOH well washing process
CN116004199A (en) * 2022-12-19 2023-04-25 中核通辽铀业有限责任公司 Uranium mining and liquid injection well anti-swelling agent and method for improving liquid injection amount of uranium mining and liquid injection well
CN116004199B (en) * 2022-12-19 2024-05-07 中核通辽铀业有限责任公司 Uranium mining and liquid injection well anti-swelling agent and method for improving liquid injection amount of uranium mining and liquid injection well

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Application publication date: 20190709