CN109988885A - Production method of low-carbon killed steel - Google Patents

Production method of low-carbon killed steel Download PDF

Info

Publication number
CN109988885A
CN109988885A CN201910397891.1A CN201910397891A CN109988885A CN 109988885 A CN109988885 A CN 109988885A CN 201910397891 A CN201910397891 A CN 201910397891A CN 109988885 A CN109988885 A CN 109988885A
Authority
CN
China
Prior art keywords
carbon
steel
low
molten steel
deoxidier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910397891.1A
Other languages
Chinese (zh)
Other versions
CN109988885B (en
Inventor
梅雪辉
张晓军
臧绍双
李德军
王宏明
李俊峰
金龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Angang Steel Co Ltd
Original Assignee
Angang Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Angang Steel Co Ltd filed Critical Angang Steel Co Ltd
Priority to CN201910397891.1A priority Critical patent/CN109988885B/en
Publication of CN109988885A publication Critical patent/CN109988885A/en
Application granted granted Critical
Publication of CN109988885B publication Critical patent/CN109988885B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/06Deoxidising, e.g. killing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The invention relates to a production method of low-carbon killed steel, wherein the mass percentage of the upper limit of the carbon content of the low-carbon killed steel is 0.10-0.25%, carbon is left in a converter for boiling tapping, and the mass percentage of the carbon content at the end point is controlled according to that C is more than or equal to 0.05% and less than or equal to-0.03% of the upper limit of the finished product carbon; after molten steel in a boiling state enters an LF furnace treatment position, firstly adding a first batch of slag material to dilute the oxidability of top slag in a molten steel tank, and then adding a carbon deoxidizer; heating the electrode, and deoxidizing the carbide slag at high temperature by using lime, a carbon deoxidizer and an electric arc. The advantages are that: the method is carried out in an LF furnace under normal pressure. The carbon deoxidizer is used to replace partial silicon and aluminum as deoxidizer, so that the cost is reduced. Compared with the silicon deoxidation process and the aluminum deoxidation process which are commonly used at present, the cost per ton of steel can be reduced by 10-20 yuan. Meanwhile, the carbon deoxidation does not leave deoxidation product residues in the molten steel, and is beneficial to improving the cleanliness of the molten steel.

Description

A kind of production method of low-carbon killed steel
Technical field
The invention belongs to mild steel production field more particularly to a kind of production methods of low-carbon killed steel.
Background technique
In conventional method for making steel, especially production low-carbon killed steel, deoxidation mainly rely on silicon, aluminium etc. and oxygen affinity and The power member bigger than iron is usually completed.These elements are acted on the oxygen being dissolved in molten steel, generate the deoxidation products insoluble in molten steel, Due to they emersion and reduce oxygen content.
Carbon deoxidization technique is mainly used under vacuum condition, using vacuum refining devices such as RH, VD, carbon and oxygen occurs anti- It answers.Under vacuum conditions, carbon superfluous in molten steel can be acted on oxygen occurs reaction between carbon and oxygen, and the oxygen in molten steel is made to become CO row It removes, at this moment carbon becomes deoxidier under vacuum conditions, its deoxidizing capacity enhances with the raising of vacuum degree.But use vacuum item Part progress carbon deoxidation is at high cost, is usually used in ultra-low-carbon steel and has the steel grades such as the high-grade pipe line steel of particular/special requirement to gas content.
Under normal pressure, low-carbon killed steel is produced, it is general to be closed using the addition Si system alloy in converter tapping process or aluminium system Golden deoxidation makes to enter refining treatment after molten steel is calm.Also have and a small amount of carburant progress just deoxidation be added in converter tapping process, Then carry out silicon deoxidation or aluminium deoxidation and Alloying Treatment.But such method top slag bubble level is not easy to control, slag risk of overflowing Greatly.And low-carbon killed steel is produced using silicon deoxidation or aluminium deoxidation at present, production cost is also higher.
Summary of the invention
In order to overcome the deficiencies of the prior art, the object of the present invention is to provide a kind of production methods of low-carbon killed steel, use Carbon deoxidization technique under normal pressure produces the finished product carbon content upper limit in 0.10%~0.25% low-carbon killed steel, utilizes carbon deoxidation The high temperature of agent, lime and electrode heating makes carbide slag deoxidation, improves heating efficiency, reduces the consumption of deoxidier, reduce alloy at This, reduces Al2O3Generation, improve Cleanliness of Molten Steel.
To achieve the above object, the invention is realized by the following technical scheme:
A kind of production method of low-carbon killed steel, the mass percent of the carbon content upper limit of the low-carbon killed steel are 0.10%~0.25%, comprising the following steps:
1) it makes steel
A converter stays carbon boil to tap, and endpoint carbon content mass percent presses 0.05%≤C≤finished product carbon upper limit -0.03% Control;
B molten steel tank emptying is controlled in 400mm-600mm;
2) it refines
After molten steel under a fluidized state handles position into LF furnace, first batch of slag charge is added first to dilute the oxygen for pushing up slag in ladle Carbon deoxidier is added in the property changed later;
The heating of b electrode, makes carbide slag deoxidation using the high temperature of lime and carburant and electric arc, two is added in temperature-rise period Slag charge is criticized, the control of the weight ratio of lime and slagging agent is in 4:1~5:1 in two batches of slag charges;Two batches of slag charge amount controls are at 0-6kg/ tons Steel;
After c heating, deoxidier final deoxidizing is added, desulfurization, takes process sample, according to process sample alloying, eventually be tuned into point and on Machine casting.
Slagging agent described in step 2) is fluorite or bauxite or with bauxite slugging material as main component;Carbon is de- Oxygen agent is coke carburant or petroleum coke carburant.
First batch of slag charge and its additional amount described in a are 4~5kg/ of lime tons of steel and 2~2.5kg/ tons of slagging agent in step 2) Steel;Carbon deoxidier additional amount are as follows: molten steel amount × (carbon content -0.01% in the finished product carbon upper limit-molten steel)/carbon deoxidier carbon contains Amount.
When deoxidier described in c is aluminum steel section in step 2), the low-carbon killed steel of production is carbon aluminium-killed steel;Added head The quantity for criticizing aluminum steel section is 1.1~1.9kg/ tons of steel.
When deoxidier described in c is ferrosilicon in step 2), the low-carbon killed steel of production is low-carbon Si killed steel;Institute after heating Add the quantity of first batch of ferrosilicon: molten steel amount × (silicone content in the finished silicon upper limit-molten steel)/ferrosilicon silicone content.
Compared with prior art, the beneficial effects of the present invention are:
1, it is carried out in the LF furnace of carbon deoxygenation mainly under normal pressure in a kind of production method of low-carbon killed steel.It utilizes Carbon deoxidier replaces part silicon, aluminium as deoxidier, cheap, reduces costs.With currently used silicon deoxidization technique It is compared with aluminium deoxidation technique, ton steel cost can reduce 10-20 member.Meanwhile carbon deoxidation remains in molten steel without deoxidation products, has Conducive to raising Cleanliness of Molten Steel.
2, the present invention utilizes existing equipment, enters LF furnace using boiling molten steel, and under fluidized state into molten steel Carbon deoxidier, lime and slagging agent is added, makes carbide slag deoxidation using the high temperature that carbon deoxidier, lime and electrode heat up.
3, the ratio for controlling LF furnace first batch of slag charge lime and slagging agent is conducive to the calcium carbide generated during carbon deoxygenation Slag submerged arc works well, and can be improved electrode heating efficiency.Using electrode heating mode, LF furnace heating rate is by 3-5 DEG C/min It is increased to 4-6 DEG C/min.
4, in LF process, carbon deoxidier is added into boiling molten steel, is easy to appear excessive slag.The present invention is used and is first added Slag charge, to dilute the oxidisability for pushing up slag in ladle, to eliminate the excessive slag risk that carbon deoxidier is added;Make carbon deoxidization technique It can satisfy normal production requirement.
5, the present invention can be improved the accuracy of LF furnace aluminum deoxidation agent for the first time, avoid due to aluminum deoxidation agent for the first time is inaccurate The phenomenon that multiple aluminum deoxidation agent occurred.Quality to guarantee LF furnace after treatment molten steel is stable steady with the production of LF furnace It is fixed.
6, the molten steel in LF furnace treatment process can be reduced using the present invention and returns silicon, it being capable of the steady production finished silicon upper limit 0.03% low Si killed steel.
7, LF furnace operation is affected by LF furnace superintendent experience and into the case where LF furnace molten steel, and the present invention makes the operation mould of LF furnace Formula, the influence for reducing human factor and operating into the case where LF furnace molten steel to LF furnace, is advantageously implemented the intelligent metaplasia of LF furnace It produces.
Specific embodiment
The present invention is described in detail below, it should be noted that implementation of the invention embodiment party not limited to the following Formula.
A kind of production method of low-carbon killed steel, the mass percent of the carbon content upper limit of the low-carbon killed steel are 0.10%~0.25%, comprising the following steps:
1) it makes steel
A converter stays carbon boil to tap, and endpoint carbon content mass percent presses 0.05%≤C≤finished product carbon upper limit -0.03% Control;
B molten steel tank emptying is controlled in 300mm-600mm;
2) it refines
After molten steel under a fluidized state handles position into LF furnace, first batch of slag charge is added first to dilute the oxygen for pushing up slag in ladle Carbon deoxidier is added in the property changed later;
B electrode heats up 5~10 minutes, makes carbide slag deoxidation using the high temperature of lime and carbon deoxidier and electric arc, is rising Two batches of slag charges are added during temperature, the control of the weight ratio of lime and slagging agent is in 4:1~5:1 in two batches of slag charges;Two batches of slag charge amounts Control is in 0-6kg/ tons of steel;
After c heating, deoxidier final deoxidizing is added, desulfurization, takes process sample, according to process sample alloying, eventually be tuned into point and on Machine casting.
Slagging agent described in step 2) is fluorite or bauxite or with bauxite slugging material as main component;Carbon is de- Oxygen agent is coke carburant or petroleum coke carburant.
First batch of slag charge and its additional amount described in a are 4~5kg/ of lime tons of steel and 2~2.5kg/ tons of slagging agent in step 2) Steel;Carbon deoxidier additional amount are as follows: molten steel amount × (carbon content -0.01% in the finished product carbon upper limit-molten steel)/carbon deoxidier carbon contains Amount.
When deoxidier described in c is aluminum steel section in step 2), the low-carbon killed steel of production is carbon aluminium-killed steel;Added head The quantity for criticizing aluminum steel section is 1.1~1.9kg/ tons of steel, and limit for height removes the limit value, the low capping value of the finished product carbon upper limit on finished product carbon.
When deoxidier described in c is ferrosilicon in step 2), the low-carbon killed steel of production is low-carbon Si killed steel;Institute after heating Add the quantity of first batch of ferrosilicon: molten steel amount × (silicone content in the finished silicon upper limit-molten steel)/ferrosilicon silicone content.
Embodiment one
A kind of production method of low-carbon killed steel, the mass percent of the carbon content upper limit of the low-carbon killed steel are 0.10%, comprising the following steps:
1, steel making working procedure
1) endpoint carbon content of converter is 0.05%;
2) boiling tapping, big tank headroom are 400mm.
2, refining procedure
1) it after molten steel handles position into LF furnace, is added slag charge (4kg/ tons of steel limes, the bauxite of 2kg/ tons of steel), it is complete to slag charge Carbon deoxidier is added after running down, carbon deoxidier additional amount is molten steel amount × (carbon content-in the finished product carbon upper limit-molten steel 0.01%)/carbon deoxidier carbon content;.
2) electrode heats up 9 minutes, Argon amount: 200L/min.
3) in temperature-rise period, remaining slag charge is added, in remaining slag charge lime and bauxite be respectively 2kg/ tons of steel and 0.5kg/ tons of steel;
4) additional amount of first batch of aluminum steel section is 1.8kg/ tons of steel after heating up.
5) viscous in time to take slag specimen, when slag specimen discoloration and it is in light green color or transparent glass slag, process sample can be taken, according to process Sample is tuned into point eventually.
6) the aluminium calcium line of 2m/ tons of steel, net Argon 3 minutes upper machines are fed after molten steel alloying.
Embodiment two
A kind of production method of low-carbon killed steel, the mass percent of the carbon content upper limit of the low-carbon killed steel are 0.15%, comprising the following steps:
1, steel making working procedure
1) endpoint carbon content of converter is 0.06%;
2) boiling tapping, big tank headroom are 500mm.
2, refining procedure
1) it after molten steel handles position into LF furnace, is added slag charge (4.5kg/ tons of steel limes, the bauxite of 2.3kg/ tons of steel), to slag Carbon deoxidier is added in material after being completely melt, carbon deoxidier additional amount is molten steel amount × (carbon contains in the finished product carbon upper limit-molten steel Amount -0.01%)/carbon deoxidier carbon content;.
2) electrode heats up 8 minutes, Argon amount: 260L/min.
3) in temperature-rise period, remaining slag charge is added, in remaining slag charge lime and bauxite be respectively 1.5kg/ tons of steel and 0.3kg/ tons of steel;
4) additional amount of first batch of aluminum steel section is 1.5kg/ tons of steel after heating up.
5) viscous in time to take slag specimen, when slag specimen discoloration and it is in light green color or transparent glass slag, process sample can be taken, according to process Sample is tuned into point eventually.
6) the aluminium calcium line of 2.5m/ tons of steel, net Argon 3 minutes upper machines are fed after molten steel alloying.
Embodiment three
A kind of production method of low-carbon killed steel, the mass percent of the carbon content upper limit of the low-carbon killed steel are 0.24%, comprising the following steps:
1, steel making working procedure
1) endpoint carbon content of converter is 0.09%;
2) boiling tapping, big tank headroom are 600mm.
2, refining procedure
1) it after molten steel handles position into LF furnace, is added slag charge (5kg/ tons of steel limes, the bauxite of 2.5kg/ tons of steel), to slag charge Carbon deoxidier is added after being completely melt, carbon deoxidier additional amount is molten steel amount × (carbon content-in the finished product carbon upper limit-molten steel 0.01%)/carbon deoxidier carbon content;.
2) electrode heats up 10 minutes, Argon amount: 300L/min.
3) in temperature-rise period, remaining slag charge is added, in remaining slag charge lime and bauxite be respectively 3kg/ tons of steel and 0.7kg/ tons of steel;
4) additional amount of first batch of aluminum steel section is 1.2kg/ tons of steel after heating up.
5) viscous in time to take slag specimen, when slag specimen discoloration and it is in light green color or transparent glass slag, process sample can be taken, according to process Sample is tuned into point eventually.
6) the aluminium calcium line of 3m/ tons of steel, net Argon 3 minutes upper machines are fed after molten steel alloying.
Example IV
A kind of production method of low-carbon killed steel, the mass percent of the carbon content upper limit of the low-carbon killed steel are 0.12%, comprising the following steps:
1, steel making working procedure
1) endpoint carbon content of converter is 0.06%;
2) boiling tapping, big tank headroom are 500mm.
2, refining procedure
1) it after molten steel handles position into LF furnace, is added slag charge (4kg/ tons of steel limes, the bauxite of 2kg/ tons of steel), it is complete to slag charge Carbon deoxidier is added after running down, carbon deoxidier additional amount is molten steel amount × (carbon content-in the finished product carbon upper limit-molten steel 0.01%)/carbon deoxidier carbon content;.
2) electrode heats up 9 minutes, Argon amount: 230L/min.
3) in temperature-rise period, remaining slag charge is added, in remaining slag charge lime and bauxite be respectively 2kg/ tons of steel and 0.4kg/ tons of steel;
4) ferrosilicon additional amount is molten steel amount × (silicone content in the finished silicon upper limit-molten steel)/ferrosilicon silicone content after heating up.
5) viscous in time to take slag specimen, when slag specimen discoloration and it is in light green color or transparent glass slag, process sample can be taken, according to process Sample is tuned into point eventually.
6) silicon-calcium wire of 2m/ tons of steel, net Argon 3 minutes upper machines are fed after molten steel alloying.
Embodiment five
A kind of production method of low-carbon killed steel, the mass percent of the carbon content upper limit of the low-carbon killed steel are 0.20%, comprising the following steps:
1, steel making working procedure
1) endpoint carbon content of converter is 0.12%;
2) boiling tapping, big tank headroom are 400mm.
2, refining procedure
1) it after molten steel handles position into LF furnace, is added slag charge (4.3kg/ tons of steel limes, the bauxite of 2.2kg/ tons of steel), to slag Carbon deoxidier is added in material after being completely melt, carbon deoxidier additional amount is molten steel amount × (carbon contains in the finished product carbon upper limit-molten steel Amount -0.01%)/carbon deoxidier carbon content;.
2) electrode heats up 8 minutes, Argon amount: 270L/min.
3) in temperature-rise period, remaining slag charge is added, in remaining slag charge lime and bauxite be respectively 2.5kg/ tons of steel and 0.5kg/ tons of steel;
4) ferrosilicon additional amount is molten steel amount × (silicone content in the finished silicon upper limit-molten steel)/ferrosilicon silicone content after heating up.
5) viscous in time to take slag specimen, when slag specimen discoloration and it is in light green color or transparent glass slag, process sample can be taken, according to process Sample is tuned into point eventually.
6) silicon-calcium wire of 1.5m/ tons of steel, net Argon 3 minutes upper machines are fed after molten steel alloying.

Claims (5)

1. a kind of production method of low-carbon killed steel, which is characterized in that the quality hundred of the carbon content upper limit of the low-carbon killed steel Divide than being 0.10%~0.25%, comprising the following steps:
1) it makes steel
A converter stays carbon boil to tap, and endpoint carbon content mass percent is controlled by 0.05%≤C≤finished product carbon upper limit -0.03%;
B molten steel tank emptying is controlled in 400mm-600mm;
2) it refines
After molten steel under a fluidized state handles position into LF furnace, first batch of slag charge is added first to dilute the oxidisability for pushing up slag in ladle, Carbon deoxidier is added later;
The heating of b electrode, makes carbide slag deoxidation using the high temperature of lime and carburant and electric arc, and two batches of slags are added in temperature-rise period Expect, the control of the weight ratio of lime and slagging agent is in 4:1~5:1 in two batches of slag charges;Two batches of slag charge amount controls are in 0-6kg/ tons of steel;
After c heating, deoxidier final deoxidizing is added, desulfurization, takes process sample, according to process sample alloying, is tuned into point eventually and upper machine pours Casting.
2. a kind of production method of low-carbon killed steel according to claim 1, which is characterized in that slugging described in step 2) Agent is fluorite or bauxite or with bauxite slugging material as main component;Carbon deoxidier is coke carburant or petroleum Burnt carburant.
3. a kind of production method of low-carbon killed steel according to claim 1, which is characterized in that in step 2) described in a First batch of slag charge and its additional amount are 2~2.5kg/ tons of steel of 4~5kg/ of lime tons of steel and slagging agent;Carbon deoxidier additional amount are as follows: Molten steel amount × (carbon content -0.01% in the finished product carbon upper limit-molten steel)/carbon deoxidier carbon content.
4. a kind of production method of low-carbon killed steel according to claim 1, which is characterized in that in step 2) described in c When deoxidier is aluminum steel section, the low-carbon killed steel of production is carbon aluminium-killed steel;The quantity of added first batch of aluminum steel section be 1.1~ 1.9kg/ tons of steel.
5. a kind of production method of low-carbon killed steel according to claim 1, which is characterized in that in step 2) described in c When deoxidier is ferrosilicon, the low-carbon killed steel of production is low-carbon Si killed steel;The quantity of added first batch of ferrosilicon after heating: molten steel amount × (silicone content in the finished silicon upper limit-molten steel)/ferrosilicon silicone content.
CN201910397891.1A 2019-05-14 2019-05-14 Production method of low-carbon killed steel Active CN109988885B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910397891.1A CN109988885B (en) 2019-05-14 2019-05-14 Production method of low-carbon killed steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910397891.1A CN109988885B (en) 2019-05-14 2019-05-14 Production method of low-carbon killed steel

Publications (2)

Publication Number Publication Date
CN109988885A true CN109988885A (en) 2019-07-09
CN109988885B CN109988885B (en) 2021-04-02

Family

ID=67136455

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910397891.1A Active CN109988885B (en) 2019-05-14 2019-05-14 Production method of low-carbon killed steel

Country Status (1)

Country Link
CN (1) CN109988885B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113088628A (en) * 2021-03-31 2021-07-09 山东钢铁股份有限公司 LF refining method of low-carbon steel

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0356614A (en) * 1989-07-26 1991-03-12 Kawasaki Steel Corp Production of low-oxygen dead-soft carbon steel
CN102051440A (en) * 2009-11-10 2011-05-11 攀钢集团钢铁钒钛股份有限公司 Molten steel deoxidizing and carbureting method and steelmaking method
CN103014235A (en) * 2013-01-07 2013-04-03 河北钢铁股份有限公司唐山分公司 Deoxidizing process for reducing consumption of aluminum killed steel deoxidizing agent
KR101363927B1 (en) * 2012-08-10 2014-02-20 주식회사 포스코 Refining method of the molten steel
CN103642970A (en) * 2013-12-09 2014-03-19 攀钢集团攀枝花钢铁研究院有限公司 Smelting method of low-carbon aluminum killed steel
CN103741007A (en) * 2013-12-23 2014-04-23 武钢集团昆明钢铁股份有限公司 Production method for reducing gas content in low-carbon aluminum killed steel
CN105855494A (en) * 2015-01-23 2016-08-17 鞍钢股份有限公司 Processing method of small overwater square billet casting machine for low-carbon aluminum steel
CN108998613B (en) * 2018-08-08 2020-06-23 鞍钢股份有限公司 Method for controlling free oxygen in ultra-low carbon low aluminum steel

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0356614A (en) * 1989-07-26 1991-03-12 Kawasaki Steel Corp Production of low-oxygen dead-soft carbon steel
CN102051440A (en) * 2009-11-10 2011-05-11 攀钢集团钢铁钒钛股份有限公司 Molten steel deoxidizing and carbureting method and steelmaking method
KR101363927B1 (en) * 2012-08-10 2014-02-20 주식회사 포스코 Refining method of the molten steel
CN103014235A (en) * 2013-01-07 2013-04-03 河北钢铁股份有限公司唐山分公司 Deoxidizing process for reducing consumption of aluminum killed steel deoxidizing agent
CN103642970A (en) * 2013-12-09 2014-03-19 攀钢集团攀枝花钢铁研究院有限公司 Smelting method of low-carbon aluminum killed steel
CN103741007A (en) * 2013-12-23 2014-04-23 武钢集团昆明钢铁股份有限公司 Production method for reducing gas content in low-carbon aluminum killed steel
CN105855494A (en) * 2015-01-23 2016-08-17 鞍钢股份有限公司 Processing method of small overwater square billet casting machine for low-carbon aluminum steel
CN108998613B (en) * 2018-08-08 2020-06-23 鞍钢股份有限公司 Method for controlling free oxygen in ultra-low carbon low aluminum steel

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
朱学刚等: "超深冲外沸内镇钢试生产 ", 《钢铁研究》 *
梅雪辉等: "LF炉造白渣脱硫工艺实践 ", 《鞍钢技术》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113088628A (en) * 2021-03-31 2021-07-09 山东钢铁股份有限公司 LF refining method of low-carbon steel

Also Published As

Publication number Publication date
CN109988885B (en) 2021-04-02

Similar Documents

Publication Publication Date Title
CN105177215B (en) Efficient production process of high aluminum-alloy-content structure round steel
CN102134628A (en) Smelting method of low-carbon aluminium killed steel with low silicon content
CN104212935B (en) A kind of method with high titanium ferrochrome production high-quality GCr15 bearing steel
CN107236894B (en) A kind of method for making steel of low-sulfur, low titanium Aluminum steel
CN109628697B (en) High-carbon dephosphorization method for smelting medium-high carbon steel grade in converter
CN102021273B (en) Fluidness control method of molten low-silicon aluminized steel of square billet
CN106591708A (en) Production method for producing low-carbon low-silicon and aluminum-containing steel through short process
CN111041148A (en) Process for continuously casting straight-up medium-thin slab of low-sulfur-content medium-carbon structural steel converter
CN110527775A (en) A kind of RH refining furnace chemical heating method suitable for carbon aluminium-killed steel
WO2022236900A1 (en) Low-cost smelting method for polar-use steel using ultra-high phosphorus molten iron
CN111299533A (en) Method for improving castability of ultra-low carbon steel produced by billet continuous casting machine
CN101705327B (en) Production technology of steel used for pipe line steel electrode
CN108913834B (en) Process for producing high-purity pig iron by molten iron blowing, vacuum degassing and electrode heating
CN105063269B (en) The Slag modification method of rail steel
CN104946844B (en) The method of refining of rail steel
CN109439842A (en) The production method of motor pawl machine AISI1006 steel
CN109988885A (en) Production method of low-carbon killed steel
CN101586174B (en) Steel two-slag purifying method for ultra-cleaning welding
CN110004268A (en) Method for producing low-carbon killed steel by carbon deoxidation process under normal pressure
CN108251598B (en) Carbon increasing and nitrogen controlling production method of medium-carbon high-alloy steel
CN109554515B (en) Method for smelting stainless steel by top-blown converter
CN104988282B (en) For the method for deoxidation of converter smelting molten steel
CN110106316A (en) Method for duplex production of low-carbon aluminum killed steel
CN110004269B (en) Production method of aluminum-free medium-high carbon steel
CN112481550A (en) Smelting process of lanthanum-cerium-rare earth alloy die steel

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant