CN109970500A - It is a kind of without terraced sticky ANFO explosives prill - Google Patents
It is a kind of without terraced sticky ANFO explosives prill Download PDFInfo
- Publication number
- CN109970500A CN109970500A CN201910380129.2A CN201910380129A CN109970500A CN 109970500 A CN109970500 A CN 109970500A CN 201910380129 A CN201910380129 A CN 201910380129A CN 109970500 A CN109970500 A CN 109970500A
- Authority
- CN
- China
- Prior art keywords
- sticky
- ammonium nitrate
- terraced
- sensitizer
- anfo explosives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B31/00—Compositions containing an inorganic nitrogen-oxygen salt
- C06B31/28—Compositions containing an inorganic nitrogen-oxygen salt the salt being ammonium nitrate
- C06B31/30—Compositions containing an inorganic nitrogen-oxygen salt the salt being ammonium nitrate with vegetable matter; with resin; with rubber
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of without terraced sticky ANFO explosives prill, belongs to explosive technical field, is related to ANFO explosives prill.It is a kind of without terraced sticky ANFO explosives prill, be to be grouped as by each group of following parts by weight: porous and granular ammonium nitrate 89-91, diesel oil 4.4-5.5, sticky sensitizer 3-5；Wherein the sticky sensitizer is mixed in proportion using modified ammonium nitrate as sensitizer, using polyethylene pyrrole network alkanone as adhesive.Explosion velocity of the present invention improves 6.5%, and storage time is able to extend 50-80 days, and explosion property is stablized, and permeability rate and propellant return rate are substantially reduced, and toxic gas content significantly reduces after explosion, has effectively prevented harm of the TNT to industry personnel and environment.
Description
Technical field
The invention belongs to explosive technical fields, are related to ANFO explosives prill, and in particular to a kind of without terraced sticky prilled ammonium oil
Explosive.
Background technique
ANFO explosives prill is mostly used in mine back production uphole shooting.ANFO explosives prill includes big containing ladder and without ladder two
Class, wherein containing terraced explosive since toxic, the seriously polluted TNT containing 10~20% makees sensitizer, there are at high cost and be unfavorable for giving birth to
The disadvantage for producing safety, is thoroughly eliminated；And existing viscous granular Non-TNT explosive is low despite the presence of production cost, technique is simple
Single advantage, but that there is also viscosity is poor, returns that medicine is serious, explosion property is poor, easy permeability is rotten, unfavorable a series of defects such as stores.
During carrying out uphole shooting, charge pneumatic machinery is mostly used, generally uses the sticky prilled ammonium oil without ladder
Explosive.The adhesive contained in sticky ANFO explosives prill without ladder makes it have viscosity, can reduce the problems such as returning medicine, this
Glutinous pellet explosive is that adhesive is added in porous and granular ammonium nitrate, and the adhesive being commonly used is using water as dissolution
Liquid is mixed with TNT, polyvinyl lactam etc., therefore inevitably contains a small amount of TNT in adhesive.
In order to overcome drawbacks described above of the existing technology, the present invention has developed a kind of new fried without terraced sticky prilled ammonium
Medicine improves ammonium nitrate-fuel oil mixture performance to reach, while the purpose without ladder in explosive.
Summary of the invention
The object of the present invention is to provide a kind of without terraced sticky ANFO explosives prill.
The present invention is achieved by the following technical solutions:
It is a kind of without terraced sticky ANFO explosives prill, be to be grouped as by each group of following parts by weight:
The sticky sensitizer 3-5 of porous and granular ammonium nitrate 89-91 diesel oil 4.4-5.5；
Wherein the sticky sensitizer be using modified ammonium nitrate as sensitizer, using polyethylene pyrrole network alkanone as adhesive by
What ratio mixed.
Further, it is preferable to what each group of following parts by weight was grouped as:
The sticky sensitizer 4 of 90 diesel oil of porous and granular ammonium nitrate 5.
Further, the sticky sensitizer is divided by modified ammonium nitrate and quality that mass fraction is 10-15%
Number is that the polyethylene pyrrole network alkanone solution of 85-90% mix, wherein it is preferred that the modified ammonium nitrate for being 10% by mass fraction,
What the polyethylene pyrrole network alkanone solution for being 90% with mass fraction mixed.
Oxidant of the present invention using porous and granular ammonium nitrate as ammonium nitrate-fuel oil mixture, at the same ammonium nitrate can play it is anti-
Water, the effect of anti-moisture absorption are that oil is mutually used for ammonium nitrate-fuel oil mixture reducing agent with diesel oil, guarantee sufficient fuel agent, with modified ammonium nitrate
As sensitizer, using polyethylene pyrrole network alkanone as adhesive, obtained finished product is maintained without terraced sticky ANFO explosives prill
The characteristics of powder type explosive water-resistance, high explosion velocity, good detonation performances can not only be widely used in surface blasting, but also can be used for small-bore
It explosion and is used in moist blasthole.
Inspection will be compared without terraced sticky ANFO explosives prill and traditional powder type explosive according to made from inventive formulation
It surveys, testing result is as follows:
The present invention is without terraced sticky ANFO explosives prill
Conventional powdered ammonium nitrate-fuel oil mixture
Testing result shows that explosion velocity of the present invention improves 6.5%, and storage time is able to extend 50-80 days, and explosion property is stablized, permeability
Rate and propellant return rate are substantially reduced, and toxic gas content significantly reduces after explosion, have effectively prevented TNT to industry personnel and ring
The harm in border.
Specific embodiment
Embodiment 1
It is a kind of without terraced sticky ammonium nitrate-fuel oil mixture, accurately weigh porous and granular ammonium nitrate 89Kg, diesel oil 4.4Kg, modified ammonium nitrate 4.5Kg,
Polyethylene pyrrole network alkanone 0.5Kg, when preparation, first mixes porous and granular ammonium nitrate and diesel oil, and modified ammonium nitrate and poly- is then added
Ethylene pyrrole network alkanone, be blended 2-3 minutes to get.
Embodiment 2
It is a kind of without terraced sticky ammonium nitrate-fuel oil mixture, accurately weigh porous and granular ammonium nitrate 90Kg, diesel oil 5Kg, modified ammonium nitrate 3.7Kg, poly-
Porous and granular ammonium nitrate and diesel oil when preparation, are first mixed, modified ammonium nitrate and poly- second are then added by ethylene pyrrole network alkanone 0.3Kg
Alkene pyrrole network alkanone, be blended 2-3 minutes to get.
Embodiment 3
It is a kind of without terraced sticky ammonium nitrate-fuel oil mixture, accurately weigh porous and granular ammonium nitrate 91Kg, diesel oil 5.5Kg, modified ammonium nitrate 2.72Kg,
Polyethylene pyrrole network alkanone 0.28Kg, when preparation, first mixes porous and granular ammonium nitrate and diesel oil, and modified ammonium nitrate and poly- is then added
Ethylene pyrrole network alkanone, be blended 2-3 minutes to get.
Claims (4)
1. a kind of without terraced sticky ANFO explosives prill, which is characterized in that be grouped as by each group of following parts by weight:
The sticky sensitizer 3-5 of porous and granular ammonium nitrate 89-91 diesel oil 4.4-5.5；
Wherein the sticky sensitizer be using modified ammonium nitrate as sensitizer, using polyethylene pyrrole network alkanone as adhesive by
What ratio mixed.
2. according to claim 1 a kind of without terraced sticky ANFO explosives prill, which is characterized in that be by following parts by weight
What each group was grouped as:
The sticky sensitizer 4 of 90 diesel oil of porous and granular ammonium nitrate 5.
3. according to claim 1 or 2 a kind of without terraced sticky ANFO explosives prill, which is characterized in that described is sticky
Sensitizer is the polyethylene pyrrole network alkanone solution for being 85-90% by modified ammonium nitrate and mass fraction that mass fraction is 10-15%
It mixes.
4. according to claim 3 a kind of without terraced sticky ANFO explosives prill, which is characterized in that the sticky sensitizer
Be be 10% by mass fraction modified ammonium nitrate and mass fraction be 90% polyethylene pyrrole network alkanone solution mix.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910380129.2A CN109970500A (en) | 2019-05-08 | 2019-05-08 | It is a kind of without terraced sticky ANFO explosives prill |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910380129.2A CN109970500A (en) | 2019-05-08 | 2019-05-08 | It is a kind of without terraced sticky ANFO explosives prill |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109970500A true CN109970500A (en) | 2019-07-05 |
Family
ID=67073267
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910380129.2A Pending CN109970500A (en) | 2019-05-08 | 2019-05-08 | It is a kind of without terraced sticky ANFO explosives prill |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109970500A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110627591A (en) * | 2019-09-11 | 2019-12-31 | 石家庄成功机电有限公司 | Industrial explosive and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1539657A2 (en) * | 2002-09-12 | 2005-06-15 | Textron Systems Corporation | Multi-stage gas generator and gas generants |
| CN104761419A (en) * | 2015-04-07 | 2015-07-08 | 宏大矿业有限公司 | Explosive compound ammonium nitrate fuel oil mixture and preparation method thereof |
| CN106748596A (en) * | 2016-12-21 | 2017-05-31 | 四川雅化实业集团股份有限公司 | A kind of viscous explosive without single chmical compound explosive and preparation method thereof |
-
2019
- 2019-05-08 CN CN201910380129.2A patent/CN109970500A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1539657A2 (en) * | 2002-09-12 | 2005-06-15 | Textron Systems Corporation | Multi-stage gas generator and gas generants |
| CN104761419A (en) * | 2015-04-07 | 2015-07-08 | 宏大矿业有限公司 | Explosive compound ammonium nitrate fuel oil mixture and preparation method thereof |
| CN106748596A (en) * | 2016-12-21 | 2017-05-31 | 四川雅化实业集团股份有限公司 | A kind of viscous explosive without single chmical compound explosive and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 欧育湘: "《炸药学》", 28 February 2014, 北京理工大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110627591A (en) * | 2019-09-11 | 2019-12-31 | 石家庄成功机电有限公司 | Industrial explosive and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106748596B (en) | A kind of viscous explosive and preparation method thereof of no single chmical compound explosive | |
| AU677634B2 (en) | An explosive composition suitable for cartridging in paper and its method of manufacture | |
| CN109970500A (en) | It is a kind of without terraced sticky ANFO explosives prill | |
| CN108976097A (en) | A kind of fireworks safety and environmental protection colloid gunpowder and preparation method thereof | |
| CN108341732A (en) | A kind of aqueous granular viscous explosive formula and preparation process of Storage period length | |
| US4718954A (en) | Explosive compositions | |
| US3406051A (en) | Aqueous explosive compositions containing a partially nitrated aromatic hydrocarbon dispersed by a monoamide | |
| CN106316724A (en) | Safe and environmentally-friendly firework propellant powder | |
| US20220119323A1 (en) | Plasticized, Adhesive Binary Explosive | |
| US3617402A (en) | Aqueous slurry blasting composition containing an aliphatic amine salt and a water soluble inorganic perchlorate | |
| US2537039A (en) | Gelatinous explosive composition | |
| US3784421A (en) | Slurry explosives cross-linked with a compound of tellurium vi | |
| CN103242115B (en) | Water gel and ammonium nitrate fuel oil explosive and production method thereof | |
| US3409484A (en) | Thickened inorganic oxidizer salt slurried explosive containing an alkylamine nitrate and an air-entrapping material | |
| CN100386294C (en) | Porous mixed ammonium nitrate explosive | |
| US3768410A (en) | Cap sensitive ammonium nitrate-hydrazing-water-explosive | |
| US3713918A (en) | Urea stabilized gelled slurry explosive | |
| CN105541522A (en) | Porous granular ammonium nitrate fuel oil explosive based on up-hole blasting | |
| US3049453A (en) | Plastic explosive and method of making it | |
| US2847291A (en) | Gelatin dynamite explosives containing water | |
| CN104761418A (en) | Low-detonation-velocity explosive for explosive welding and preparation method thereof | |
| CN106518584A (en) | Emulsified ammonium nitrate fuel oil explosive and preparation method thereof | |
| US4764229A (en) | Sensitization of inorganic oxidizer explosives | |
| US2131574A (en) | Explosive | |
| CN108774096A (en) | A kind of micro- pyrotechnic composition of colloid and its preparation process of hardly possible solvent flashing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190705 |
|
| RJ01 | Rejection of invention patent application after publication |