CN100386294C - Porous mixed ammonium nitrate explosive - Google Patents
Porous mixed ammonium nitrate explosive Download PDFInfo
- Publication number
- CN100386294C CN100386294C CNB2006100395389A CN200610039538A CN100386294C CN 100386294 C CN100386294 C CN 100386294C CN B2006100395389 A CNB2006100395389 A CN B2006100395389A CN 200610039538 A CN200610039538 A CN 200610039538A CN 100386294 C CN100386294 C CN 100386294C
- Authority
- CN
- China
- Prior art keywords
- ammonium nitrate
- explosive
- porous
- present
- emulsion explosive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn - After Issue
Links
- 239000002360 explosive Substances 0.000 title claims abstract description 58
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- 208000000655 Distemper Diseases 0.000 claims description 12
- 239000003995 emulsifying agent Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 8
- 229920002521 macromolecule Polymers 0.000 claims description 6
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims description 4
- 239000001993 wax Substances 0.000 claims description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- 229920002367 Polyisobutene Polymers 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- 239000013078 crystal Substances 0.000 claims description 2
- 239000004200 microcrystalline wax Substances 0.000 claims description 2
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 229960002317 succinimide Drugs 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 238000005422 blasting Methods 0.000 abstract description 6
- 238000005474 detonation Methods 0.000 abstract description 6
- 239000003921 oil Substances 0.000 description 16
- 230000001804 emulsifying effect Effects 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 8
- 238000004880 explosion Methods 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- XGSVQGOPJUAOQH-UHFFFAOYSA-N aluminum;2-methyl-1,3,5-trinitrobenzene Chemical compound [Al+3].CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O XGSVQGOPJUAOQH-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Abstract
The present invention discloses a porous mixed ammonium nitrate explosive which is prepared by combining porous ammonium nitrate and a high-oil powdery emulsion explosive. The present invention is composed of 10 to 50 wt% of porous ammonium nitrate and 50 to 90 wt% of high-oil powdery emulsion explosive. The porous mixed ammonium nitrate explosive of the present invention has the characteristics of simple production process and high producing energy, and the water-resisting properties and the high detonation velocity of the powdery emulsion explosive are kept. Detonation performance is better than that of a porous granular ammonium nitrate explosive, and cost is lower than that of a powdery emulsion explosive. The present invention can be used for surface blasting, can also be used for small-bore blasting, and can be used in wet blast holes.
Description
Technical field
The present invention relates to a kind of industrial ammonium nitrate pyrotechnic composition, particularly relate to the porous mixed ammonium nitrate explosive that the quick-fried industry of the people is used.
Background technology
The explosive that the quick-fried industry of the people is used mainly contains ammonium nitrate-fuel oil mixture, emulsion explosive, an-tnt explosive.The an-tnt explosive blast performance is better, but toxic substance is harmful, and the cost height.Porous grain ammonium nitrate-fuel oil mixture is a kind of industrial explosive that is widely used in the surface mine explosion, because it is with low cost, production technique is simple, favored by the user.But it also exist not anti-water, explosion velocity low, do not fit into weak points such as aperture explosion and hard rock blasting.
Powdery emulsifying explosive is a kind of high performance industrial explosive, and certain water resisting property is arranged, and applicable to the various engineering explosion, but powdery emulsifying explosive exists production cost height, the limited deficiency of throughput.
Summary of the invention
Purpose of the present invention is exactly at the above-mentioned problems in the prior art, a kind of production technique is simple, detonation property is better than the porous and granular ammoniumnitrate explosives and provide, cost is lower than powdery emulsifying explosive, applicable to the porous mixed ammonium nitrate explosive of various engineering blasting operation condition.
For realizing the present invention's purpose, porous mixed ammonium nitrate explosive of the present invention is achieved through the following technical solutions.
Porous mixed ammonium nitrate explosive of the present invention is to be constituted by porous grain ammonium nitrate, high oil-bound distemper shape emulsion explosive, and the each component content range is:
Porous grain ammonium nitrate 10%～50% (weight);
High oil-bound distemper shape emulsion explosive 50%～90% (weight).
The component concentration (weight) of described high oil-bound distemper shape emulsion explosive is: organic oil phase material 4.5%～8.7%, emulsifying agent 1.2%～2.2%, water 1.8～3.5%, ammonium nitrate 88%～92.5%.
Described organic oil phase material is: 2～5 kinds of mixtures in stearic acid, slack wax, mixed crystal wax, paraffin, Microcrystalline Wax, the rosin.
Described emulsifying agent is a polyisobutene succinimide family macromolecule emulsifying agent.
Principle of the present invention is: porous grain ammonium nitrate is a kind of oxygenant, and oxygen balance is 0.2, mixes with normal powdery emulsifying explosive, and it is unnecessary oxygen supply to occur in the explosive, the combustible agent deficiency.In order to guarantee that explosive charge reacts completely, oxygen balance will be near zero, so the suitable oil phase ratio that improves when producing powdery emulsifying explosive guarantees that enough flammable compositions are the main points of this porous mixed ammonium nitrate explosive of preparation.
The present invention compares with existing explosive, and its distinguishing feature is:
1. pyrotechnic composition have kept the characteristics of powdery emulsifying explosive water resisting property, high explosion velocity.Compare with powdery emulsifying explosive, cost has reduced by 15%; Compare with porous grain ammonium nitrate-fuel oil mixture, detonation property and water resisting property improve greatly; Compare with industrial powdered an-tnt explosive, do not contain tritonal, the detonation index is higher than industrial powdered an-tnt explosive, and cost also is lower than industrial powdered an-tnt explosive.
2. enlarge the scope of application, not only can be used for surface blasting but also can be used for the small-bore explosion, in moist big gun hole, used, also had blasting effect preferably.
3. production technique is simple, and quality product guarantees easily, for the producer that powder emulsified production line is arranged, only needs investment seldom.
4. can significantly improve the explosive production capacity, throughput has improved 80%, rate of return on investment height, remarkable in economical benefits.
Embodiment
For further describing the present invention, porous mixed ammonium nitrate explosive of the present invention is further described below in conjunction with embodiment.
According to table 1 preparation porous mixed ammonium nitrate explosive 100kg.
Table 1 porous mixed ammonium nitrate explosive prescription (kg)
| Embodiment | Porous grain ammonium nitrate | High oil-bound distemper shape emulsion explosive | Remarks |
| 1 | 10 | 90 | |
| 2 | 20 | 80 | |
| 3 | 30 | 70 | |
| 4 | 40 | 60 | |
| 5 | 50 | 50 | |
| 6 | 35 | 65 | |
| 7 | 35 | 65 |
Wherein:
The high oil-bound distemper shape preparation of emulsifying explosive that uses among the embodiment 1 is (weight): ammonium nitrate 92.5%, water 1.8%, organic oil phase material 4.5%, macromolecule emulsifier 1.2%.
The high oil-bound distemper shape preparation of emulsifying explosive that uses among the embodiment 2-5 is (weight): ammonium nitrate 89.8%, water 3%, organic oil phase material 5%, macromolecule emulsifier 2.2%.
The high oil-bound distemper shape preparation of emulsifying explosive that uses among the embodiment 6 is (weight): ammonium nitrate 88%, water 2.0%, organic oil phase material 8.7%, macromolecule emulsifier 1.3%.
High oil-bound distemper shape preparation of emulsifying explosive among the embodiment 7 is (weight): ammonium nitrate 90%, water 3.5%, organic oil phase material 4.5%, macromolecule emulsifier 2.0%.
The preparation method of porous mixed ammonium nitrate explosive of the present invention is: respectively common porous grain ammonium nitrate, high oil-bound distemper shape emulsion explosive are carried out machinery by quantitative helical feed to continuous mixer and puddle evenly and get final product.
According to the porous mixed ammonium nitrate explosive of embodiment of the invention formulation, its blast performance is as shown in table 2 after tested.
The blast performance of the porous mixed ammonium nitrate explosive of table 2 preparation
| Prescription | Explosion velocity (m/s) | Induced detonation (cm) | Brisance (mm) |
| 1 | 3980 | 13 | 16.00 |
| 2 | 3788 | 12 | 15.30 |
| 3 | 3623 | 9 | 14.51 |
| 4 | 3571 | 8 | 13.96 |
| 5 | 3289 | 6 | 12.65 |
| 6 | 3598 | 8 | 14.25 |
| 7 | 3615 | 8 | 14.20 |
The result of embodiment shows, all reaches GB12437 according to the explosive property of the formulation of 7 embodiment---2000 industrial powdered an-tnt explosive standards can replace powdery ammonium ladder detonator to use fully.The sample shelf lives all surpasses six months.
Claims (3)
1. porous mixed ammonium nitrate explosive, it is characterized in that: it is to be constituted by porous grain ammonium nitrate, high oil-bound distemper shape emulsion explosive, and its component content range is:
Porous grain ammonium nitrate 10%～50% (weight),
High oil-bound distemper shape emulsion explosive 50%～90% (weight);
The component concentration (weight) of described high oil-bound distemper shape emulsion explosive is: organic oil phase material 4.5%～8.7%, emulsifying agent 1.2%～2.2%, water 1.8～3.5%, ammonium nitrate 88%～92.5%.
2. porous mixed ammonium nitrate explosive as claimed in claim 1 is characterized in that: described organic oil phase material is: 2～5 kinds of mixtures in stearic acid, slack wax, mixed crystal wax, paraffin, Microcrystalline Wax, the rosin.
3. porous mixed ammonium nitrate explosive as claimed in claim 1 or 2 is characterized in that: described emulsifying agent is a polyisobutene succinimide family macromolecule emulsifying agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100395389A CN100386294C (en) | 2006-04-14 | 2006-04-14 | Porous mixed ammonium nitrate explosive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100395389A CN100386294C (en) | 2006-04-14 | 2006-04-14 | Porous mixed ammonium nitrate explosive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1837166A CN1837166A (en) | 2006-09-27 |
| CN100386294C true CN100386294C (en) | 2008-05-07 |
Family
ID=37014698
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100395389A Withdrawn - After Issue CN100386294C (en) | 2006-04-14 | 2006-04-14 | Porous mixed ammonium nitrate explosive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100386294C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103896695B (en) * | 2012-12-30 | 2016-04-20 | 南京理工大学 | Many micropores spherulitic ammonium nitrate and method for making thereof |
| CN110627591B (en) * | 2019-09-11 | 2021-12-28 | 石家庄成功机电有限公司 | Industrial explosive and preparation method thereof |
| CN112209787A (en) * | 2020-10-12 | 2021-01-12 | 北京奥信化工科技发展有限责任公司 | Water-resistant porous granular ammonium nitrate fuel oil explosive and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1059886C (en) * | 1993-03-10 | 2000-12-27 | 北京矿冶研究总院 | Ammonium nitrate emulsified mine explosive |
-
2006
- 2006-04-14 CN CNB2006100395389A patent/CN100386294C/en not_active Withdrawn - After Issue
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1059886C (en) * | 1993-03-10 | 2000-12-27 | 北京矿冶研究总院 | Ammonium nitrate emulsified mine explosive |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1837166A (en) | 2006-09-27 |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Anhui Dun'an Civil Blasting Equipment Co., Ltd. Assignor: Anhui Dun'an Chemical Industry Group Co., Ltd. Contract fulfillment period: 2008.5.20 to 2014.5.19 Contract record no.: 2009340000141 Denomination of invention: Porous mixed ammonium nitrate explosive Granted publication date: 20080507 License type: Exclusive license Record date: 20090728 |
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| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.5.20 TO 2014.5.19; CHANGE OF CONTRACT Name of requester: ANHUI DUNAN EXPLOSIVE MATERIALS EQUIPMENT CO., LTD Effective date: 20090728 |
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| EC01 | Cancellation of recordation of patent licensing contract |
Assignee: Anhui Dun'an Civil Blasting Equipment Co., Ltd. Assignor: Anhui Dun'an Chemical Industry Group Co., Ltd. Contract record no.: 2009340000141 Date of cancellation: 20161020 |
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| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161227 Address after: 242310 Ningguo, Anhui City, the town of Victoria demarcation Patentee after: Anhui Jiangnan Chemical Industry Co., Ltd. Address before: 243100 Anhui province Dangtu County Department provided Road No. 10 Patentee before: Anhui Dun'an Chemical Industry Group Co., Ltd. |
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| AV01 | Patent right actively abandoned |
Granted publication date: 20080507 Effective date of abandoning: 20211213 |
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| AV01 | Patent right actively abandoned |
Granted publication date: 20080507 Effective date of abandoning: 20211213 |
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| AV01 | Patent right actively abandoned | ||
| AV01 | Patent right actively abandoned |