CN109955564A - A kind of composite plate and preparation method thereof of metal-containing layer plastic net cloth - Google Patents
A kind of composite plate and preparation method thereof of metal-containing layer plastic net cloth Download PDFInfo
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- CN109955564A CN109955564A CN201910237743.3A CN201910237743A CN109955564A CN 109955564 A CN109955564 A CN 109955564A CN 201910237743 A CN201910237743 A CN 201910237743A CN 109955564 A CN109955564 A CN 109955564A
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- layer
- metal
- cloth
- doubling
- plastic net
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- 239000004744 fabric Substances 0.000 title claims abstract description 130
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 109
- 239000002184 metal Substances 0.000 title claims abstract description 109
- 239000004033 plastic Substances 0.000 title claims abstract description 108
- 229920003023 plastic Polymers 0.000 title claims abstract description 108
- 239000002131 composite material Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000000758 substrate Substances 0.000 claims abstract description 61
- 239000000565 sealant Substances 0.000 claims abstract description 55
- 238000001465 metallisation Methods 0.000 claims abstract description 51
- 239000010410 layer Substances 0.000 claims abstract description 3
- 239000011521 glass Substances 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 8
- 229920002635 polyurethane Polymers 0.000 claims description 8
- 239000004814 polyurethane Substances 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 238000009941 weaving Methods 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 238000002294 plasma sputter deposition Methods 0.000 claims description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 4
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 4
- 238000004544 sputter deposition Methods 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 3
- 239000005329 float glass Substances 0.000 claims description 3
- 238000000151 deposition Methods 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 claims description 2
- 238000007738 vacuum evaporation Methods 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- -1 silicon oxygen Alkane Chemical class 0.000 claims 1
- 230000001681 protective effect Effects 0.000 abstract description 5
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 239000003086 colorant Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 4
- 238000009954 braiding Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/067—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of fibres or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/028—Net structure, e.g. spaced apart filaments bonded at the crossing points
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
- B32B2037/243—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
- B32B2255/205—Metallic coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
- B32B2307/4023—Coloured on the layer surface, e.g. ink
Abstract
The invention discloses a kind of composite plate and preparation method thereof of metal-containing layer plastic net cloth, the composite plate includes metal mesh layer of cloth, doubling layer and substrate layer, and the one side of the metal mesh layer of cloth or two sides are bonded by doubling layer and substrate layer；The metal mesh layer of cloth is followed successively by pattern layer, sealant, metal deposition layer, latticed plastic wire layer of cloth, metal deposition layer, sealant and pattern layer from top to bottom.The present invention can play fine and close protective effect to metal deposition layer, prevent that the problems such as oxidation, degumming occur for lower metal is used for a long time, and extend the service life of composite board, guarantee the dicoration of composite board；And the setting of sealant can be improved the adhesive fastness of pattern layer, guarantee the stability of decorative pattern.
Description
Technical field:
The present invention relates to decorative composite board material technical field, it is specifically related to a kind of the compound of metal-containing layer plastic net cloth
Plate and preparation method thereof.
Background technique:
In recent years, as the improvement of people's living standards, quality, texture and uniqueness to ornament materials, it is desirable that more next
It is stringenter.Decoration screen cloth is increasingly set as artistic doubling glass decorative intermediate layer due to the diversity of color and lines
Count the welcome of teacher.Metal is then existing since the diversity of intrinsic colour state is also more and more applied on decoration screen cloth
The compound sheetmetal of metal-containing layer plastic net cloth is oxidizable to be caused to change colour, further result in metal and doubling glass or plastics it is de-
It falls, influences decorative effect.
The information disclosed in the background technology section is intended only to increase the understanding to general background of the invention, without answering
When being considered as recognizing or imply that the information constitutes the prior art already known to those of ordinary skill in the art in any form.
Summary of the invention:
The purpose of the present invention is to provide a kind of composite plates and preparation method thereof of metal-containing layer plastic net cloth, to overcome
Above-mentioned defect in the prior art.
To achieve the above object, the present invention provides a kind of composite plates of metal-containing layer plastic net cloth, including Metal screen cloth
Layer, doubling layer and substrate layer, the one side of the metal mesh layer of cloth or two sides are bonded by doubling layer and substrate layer；The metal
Scrim layer is followed successively by pattern layer, sealant, metal deposition layer, latticed plastic wire layer of cloth, metal deposition layer, sealing from top to bottom
Layer and pattern layer.
The string diameter of the plastic wire of the latticed plastic wire layer of cloth is 100-500 μm, preferably 140-350um, plastic wire face
Color is black, grey or other colors, and the area ratio that the range of the mesh accounts for screen cloth is 25-90%, preferably 45-
60%.
The metal deposition layer with a thickness of 100-300nm, preferably 150-250nm, the metal deposition layer is bonded in net
On trellis plastic net cloth.
The sealant with a thickness of 20-100um, preferably 40-60um, the sealant is bonded on metal deposition layer.
The doubling layer with a thickness of 0.76-20mm, preferably 1.52-3.04mm, the doubling layer bonded metal scrim layer
And substrate layer.
The substrate be glass substrate or plastic base, the substrate layer with a thickness of 0.1-15mm, preferably 5-10mm.
A kind of preparation method of the composite plate of metal-containing layer plastic net cloth, comprising the following steps:
1) two sides of the latticed plastic net cloth of Low Temperature Plasma Treating is used, the power of Low Temperature Plasma Treating is
50-100W, preferably 65-75W, pressure are atmospheric pressure environment, and the processing time is 1-10min, preferably 3-6min；
2) on the two sides of latticed plastic net cloth by way of vacuum sputtering, plasma sputtering or vacuum evaporation deposition
Perhaps the face deposited metal layer metal select AI, Cu, Zn, Ag, Ni, Co, Mn, Cr, Ti, AICu one such or
Other suitable metals；
3) Low Temperature Plasma Treating metal deposition layer is used, the power of Low Temperature Plasma Treating is 55-75W, pressure
For atmospheric pressure environment, the processing time is 3-8min；
4) one layer of sealant is sprayed in metal deposit layer surface, the sealant selects the raw material of following weight percent:
Silicone-modified aqueous polyurethane 2-15%, curing agent 1-10%, other be solvent, the silicone-modified aqueous polyurethane
Glass transition temperature is greater than 150 DEG C, toasts 5-10min in 70-100 DEG C of infrared baking oven after spraying, forms the close of densification
Sealing；
5) it is whole to be formed in sealant printout surface pattern layer using digital ink-jet printer for metal mesh layer of cloth；
6) metal mesh layer of cloth, doubling layer and substrate layer are stacked in the following order: substrate layer, doubling layer, metal
Scrim layer, doubling layer, substrate layer, four sides are sticked high temperature gummed tape fixation and are placed into autoclave or doubling furnace after stacking, and take out true
After empty 10-30min, temperature is raised to 120-150 DEG C, constant temperature and pressure 45-180min, cools the temperature to 40 DEG C hereinafter, opening high
Kettle or doubling furnace are pressed, the compound board finished product of metal-containing layer plastic net cloth is taken out.
The latticed plastic net cloth string diameter be 100-500 μm, the plastic wire color be black, grey or other
Color, the area ratio that the range of the mesh accounts for screen cloth is 25-90%, and the weaving manner of the latticed plastic net cloth is flat
Line braiding or twill weave.
The doubling layer is PVB film, EVA film, TPU film or SGP film.
The substrate layer is glass or plastics, and the glass selects float glass, ultra-clear glasses or high borosilicate glass
Glass, the glass with a thickness of 2-15mm, the plastics select PMMA plate, PETG plate, PC plate or PET sheet, the thickness of the plastics
Degree is 0.1-15mm.
Compared with prior art, one aspect of the present invention has the following beneficial effects:
(1) present invention is provided with sealant, sealant using silicone-modified aqueous poly- ammonia in the two sides of metal deposition layer
Ester is that primary raw material can play fine and close protective effect to metal deposition layer, prevents that lower metal generation oxidation, degumming is used for a long time
The problems such as, the service life of composite board can be extended, guarantee the dicoration of composite board；And the setting of sealant can mention
The adhesive fastness of high pattern layer, the stability for guaranteeing decorative pattern；
(2) present invention during the preparation process carries out at low-temperature plasma latticed plastic wire layer of cloth before deposited metal layer
Reason can increase the wetability of latticed plastic net cloth layer surface, improve the bonding between metal and latticed plastic wire layer of cloth
Fastness；Low-temperature plasma processing further is made to metal deposition layer, can be improved the bonding between metal deposition layer and sealant
Property, fine and close protective effect is played to metal deposition layer；Metal mesh layer of cloth, doubling layer and basal layer paste under vacuum high-temperature environment
The bubble that can reduce fitting, the compactness for improving fitting are closed, to enhance the decorative effect of composite board.
Detailed description of the invention:
Fig. 1 is the composite plate structure schematic diagram of the embodiment of the present invention 1, embodiment 3；
Fig. 2 is the composite plate structure schematic diagram of the embodiment of the present invention 2, embodiment 4；
Fig. 3 is the Metal screen cloth schematic diagram of a layer structure of the composite plate of the embodiment of the present invention 1 and embodiment 2；
Fig. 4 is the Metal screen cloth schematic diagram of a layer structure of the composite plate of the embodiment of the present invention 3 and embodiment 4；
Fig. 5 is the preparation flow schematic diagram of the composite board of the embodiment of the present invention 1；
Appended drawing reference: 1- metal mesh layer of cloth, 11- pattern layer, 12- sealant, 13- metal deposition layer, the latticed plastics of 14-
Scrim layer, 2- doubling layer, 3- substrate layer.
Specific embodiment:
Specific embodiments of the present invention will be described in detail below, it is to be understood that protection scope of the present invention is not
It is restricted by specific implementation.
Unless otherwise explicitly stated, otherwise in entire disclosure and claims, term " includes " or its change
Changing such as "comprising" or " including " etc. will be understood to comprise stated element or component, and not exclude other members
Part or other component parts.
Embodiment 1:
As shown in Fig. 1, Fig. 3, Fig. 5, a kind of composite plate of metal-containing layer plastic net cloth, including metal mesh layer of cloth 1, doubling layer
2 and substrate layer 3, the two sides of the metal mesh layer of cloth 1 is bonded by doubling layer 2 and substrate layer 3；The metal mesh layer of cloth 1 is from upper
Pattern layer 11, sealant 12, metal deposition layer 13, latticed plastic wire layer of cloth 14, metal deposition layer 13, sealing are followed successively by under
Layer 12 and pattern layer 11.
The string diameter of the plastic wire of the latticed plastic wire layer of cloth 14 is 250-350um, and plastic wire color is black, grey
Or other colors, the area ratio that the range of the mesh accounts for screen cloth is 45-60%.
The metal deposition layer 13 with a thickness of 150-250nm, the metal deposition layer 13 is bonded in latticed plastic wire
On cloth 14.
The sealant 12 with a thickness of 40-60um, the sealant 12 is bonded on metal deposition layer 13.
The doubling layer 2 with a thickness of 12-18mm, the 2 bonded metal scrim layer 1 of doubling layer and substrate layer 3.
The substrate be glass substrate or plastic base, the substrate layer 3 with a thickness of 5-10mm.
A kind of preparation method of the composite plate of metal-containing layer plastic net cloth, comprising the following steps:
1) two sides of the latticed plastic net cloth 14 of Low Temperature Plasma Treating is used, the power of Low Temperature Plasma Treating is
65-75W, pressure are atmospheric pressure environment, and the processing time is 3-6min；
2) in the two sides deposited metal layer 13 of latticed plastic net cloth 14 by way of vacuum sputtering, the metal is selected
AI, Cu, Zn, Ag, Ni, Co, Mn, Cr, Ti, AICu be one such or other suitable metals；
3) Low Temperature Plasma Treating metal deposition layer 13 is used, the power of Low Temperature Plasma Treating is 55-75W, pressure
Power is atmospheric pressure environment, and the processing time is 3-8min；
4) one layer of sealant 12 is sprayed on 13 surface of metal deposition layer, the sealant 12 selects following weight percent
Raw material: silicone-modified aqueous polyurethane 2-15%, curing agent 1-10%, other be solvent, it is described silicone-modified aqueous poly-
The glass transition temperature of urethane is greater than 150 DEG C, toasts 5-10min after spraying in 70-100 DEG C of infrared baking oven, is formed and is caused
Close sealant 12；
5) it is whole to be formed in 12 printout surface pattern layer 11 of sealant using digital ink-jet printer for metal mesh layer of cloth 1；
6) metal mesh layer of cloth 1, doubling layer 2 and substrate layer 3 are stacked in the following order: substrate layer 3, doubling layer 2,
Metal mesh layer of cloth 1, doubling layer 2, substrate layer 3, four sides stick high temperature gummed tape fixation and place into autoclave or doubling furnace after stacking
In, after vacuumizing 10-30min, temperature is raised to 120-150 DEG C, constant temperature and pressure 45-180min, cool the temperature to 40 DEG C hereinafter,
Autoclave or doubling furnace are opened, the compound board finished product of metal-containing layer plastic net cloth is taken out.
14 string diameter of latticed plastic net cloth is 100-500 μm, and plastic wire color is black, grey or other face
Color, the area ratio that the range of the mesh accounts for screen cloth is 25-90%, and the weaving manner of the latticed plastic net cloth 14 is flat
Line braiding or twill weave.
The doubling layer 2 selects PVB film, film stock thickness 15mm.
The substrate layer 3 selects float glass, with a thickness of 10mm.
Embodiment 2:
As shown in Figure 2 and Figure 3, a kind of composite plate of metal-containing layer plastic net cloth, including metal mesh layer of cloth 1,2 and of doubling layer
The one side of substrate layer 3, the metal mesh layer of cloth 1 is bonded by doubling layer 2 and substrate layer 3；The metal mesh layer of cloth 1 is from top to bottom
It is followed successively by pattern layer 11, sealant 12, metal deposition layer 13, latticed plastic wire layer of cloth 14, metal deposition layer 13, sealant 12
With pattern layer 11.
The string diameter of the plastic wire of the latticed plastic wire layer of cloth 14 is 250-350 μm, and plastic wire color is black, grey
Or other colors, the area ratio that the range of the mesh accounts for screen cloth is 45-60%.
The metal deposition layer 13 with a thickness of 150-250nm, the metal deposition layer 13 is bonded in latticed plastic wire
On cloth 14.
The sealant 12 with a thickness of 40-60um, the sealant 12 is bonded on metal deposition layer 13.
The doubling layer 2 with a thickness of 1.52-18mm, the 2 bonded metal scrim layer 1 of doubling layer and substrate layer 3.
The substrate be glass substrate or plastic base, the substrate layer 3 with a thickness of 5-10mm.
A kind of preparation method of the composite plate of metal-containing layer plastic net cloth, comprising the following steps:
1) two sides of the latticed plastic net cloth 14 of Low Temperature Plasma Treating is used, the power of Low Temperature Plasma Treating is
65-75W, pressure are atmospheric pressure environment, and the processing time is 3-6min；
2) in the one or both sides deposited metal layer 13 of latticed plastic net cloth 14, the gold by way of vacuum sputtering
Belong to and selects AI, Cu, Zn, Ag, Ni, Co, Mn, Cr, Ti, AICu one such or other suitable metals；
3) Low Temperature Plasma Treating metal deposition layer 13 is used, the power of Low Temperature Plasma Treating is 55-75W, pressure
Power is atmospheric pressure environment, and the processing time is 3-8min；
4) one layer of sealant 12 is sprayed on 13 surface of metal deposition layer, the sealant 12 selects following weight percent
Raw material: silicone-modified aqueous polyurethane 2-15%, curing agent 1-10%, other be solvent, it is described silicone-modified aqueous poly-
The glass transition temperature of urethane is greater than 150 DEG C, toasts 5-10min after spraying in 70-100 DEG C of infrared baking oven, is formed and is caused
Close sealant 12；
5) it is whole to be formed in 12 printout surface pattern layer 11 of sealant using digital ink-jet printer for metal mesh layer of cloth 1；
6) metal mesh layer of cloth 1, doubling layer 2 and substrate layer 3 are stacked in the following order: substrate layer 3, doubling layer 2,
Metal mesh layer of cloth 1, four sides are sticked high temperature gummed tape fixation and are placed into autoclave or doubling furnace after stacking, and vacuumize 10-30min
Afterwards, temperature is raised to 120-150 DEG C, constant temperature and pressure 45-180min, cools the temperature to 40 DEG C hereinafter, opening autoclave or folder
Glue furnace takes out the compound board finished product of metal-containing layer plastic net cloth.
It is black, grey or other colors that 14 string diameter of latticed plastic net cloth, which is 100-500um plastic wire color,
The area ratio that the range of the mesh accounts for screen cloth is 35-90%, and the weaving manner of the latticed plastic net cloth 14 is plain weave
Braiding or twill weave.
The doubling layer 2 selects TPU film, film stock thickness 1.52mm.
The substrate layer 3 selects ultra-clear glasses, with a thickness of 10mm.
Embodiment 3
As Figure 1 and Figure 4, a kind of composite plate of metal-containing layer plastic net cloth, including metal mesh layer of cloth 1,2 and of doubling layer
The two sides of substrate layer 3, the metal mesh layer of cloth 1 is bonded by doubling layer 2 and substrate layer 3；The metal mesh layer of cloth 1 is from top to bottom
It is followed successively by pattern layer 11, sealant 12, metal deposition layer 13 and latticed plastic wire layer of cloth 14.
The string diameter of the plastic wire of the latticed plastic wire layer of cloth 14 is 300-320 μm, and plastic wire color is black, grey
Or other colors, the area ratio that the range of the mesh accounts for screen cloth is 50-55%.
The metal deposition layer 13 with a thickness of 200-220nm, the metal deposition layer 13 is bonded in latticed plastic wire
On cloth 14.
The sealant 12 with a thickness of 45-50um, the sealant 12 is bonded on metal deposition layer 13.
The doubling layer 2 with a thickness of 1.52-18mm, the 2 bonded metal scrim layer 1 of doubling layer and substrate layer 3.
The substrate 3 be glass substrate or plastic base, the substrate layer 3 with a thickness of 5-10mm.
A kind of preparation method of the composite plate of metal-containing layer plastic net cloth, comprising the following steps:
1) one side of the latticed plastic net cloth 14 of Low Temperature Plasma Treating is used, the power of Low Temperature Plasma Treating is
65-75W, pressure are atmospheric pressure environment, and the processing time is 3-6min；
2) in a face deposited metal layer 13 of latticed plastic net cloth 14, the metal choosing by way of plasma sputtering
With AI, Cu, Zn, Ag, Ni, Co, Mn, Cr, Ti, AICu be one such or other suitable metals；
3) Low Temperature Plasma Treating metal deposition layer 13 is used, the power of Low Temperature Plasma Treating is 55-75W, pressure
Power is atmospheric pressure environment, and the processing time is 3-8min；
4) one layer of sealant 12 is sprayed on 13 surface of metal deposition layer, the sealant 12 selects following weight percent
Raw material: silicone-modified aqueous polyurethane 2-15%, curing agent 1-10%, other be solvent, it is described silicone-modified aqueous poly-
The glass transition temperature of urethane is greater than 150 DEG C, toasts 5-10min after spraying in 70-100 DEG C of infrared baking oven, is formed and is caused
Close sealant 12；
5) it is whole to be formed in 12 printout surface pattern layer 11 of sealant using digital ink-jet printer for metal mesh layer of cloth 1；
6) metal mesh layer of cloth 1, doubling layer 2 and substrate layer 3 are stacked in the following order: substrate layer 3, doubling layer 2,
Metal mesh layer of cloth 1, doubling layer 2, substrate layer 3, four sides stick high temperature gummed tape fixation and place into autoclave or doubling furnace after stacking
In, after vacuumizing 10-30min, by temperature be raised to the latticed plastic net cloth 14 weaving manner be plain weave or tiltedly
Line braiding.
The doubling layer 2 selects TPU film.
The substrate layer 3 selects PMMA plate, with a thickness of 5-10mm.
Embodiment 4
As shown in Figure 2, Figure 4 shows, a kind of composite plate of metal-containing layer plastic net cloth, including golden 120-150 DEG C, constant temperature and pressure
45-180min cools the temperature to 40 DEG C hereinafter, opening autoclave or doubling furnace, take out the compound of metal-containing layer plastic net cloth
Board finished product.
Belong to scrim layer 1, doubling layer 2 and substrate layer 3, the one side of the metal mesh layer of cloth 1 passes through doubling layer 2 and substrate layer 3
Bonding；The metal mesh layer of cloth 1 is followed successively by pattern layer 11, sealant 12, metal deposition layer 13 and latticed plastics from top to bottom
Scrim layer 14.
The string diameter of the plastic wire of the latticed plastic wire layer of cloth 14 is 300-320 μm, and plastic wire color is black, grey
Or other colors, the area ratio that the range of the mesh accounts for screen cloth is 50-55%.
The metal deposition layer 13 with a thickness of 200-220nm, the metal deposition layer 13 is bonded in latticed plastic wire
On cloth 14.
The sealant 12 with a thickness of 45-50um, the sealant 12 is bonded on metal deposition layer 13.
The doubling layer 2 with a thickness of 15-18mm, the 2 bonded metal scrim layer 1 of doubling layer and substrate layer 3.
The substrate 3 be glass substrate or plastic base, the substrate layer 3 with a thickness of 5-10mm.
A kind of preparation method of the composite plate of metal-containing layer plastic net cloth, comprising the following steps:
1) one side of the latticed plastic net cloth 14 of Low Temperature Plasma Treating is used, the power of Low Temperature Plasma Treating is
65-75W, pressure are atmospheric pressure environment, and the processing time is 3-6min；
2) in a face deposited metal layer 13 of latticed plastic net cloth 14, the metal choosing by way of plasma sputtering
With AI, Cu, Zn, Ag, Ni, Co, Mn, Cr, Ti, AICu be one such or other suitable metals；
3) Low Temperature Plasma Treating metal deposition layer 13 is used, the power of Low Temperature Plasma Treating is 55-75W, pressure
Power is atmospheric pressure environment, and the processing time is 3-8min；
4) one layer of sealant 12 is sprayed on 13 surface of metal deposition layer, the sealant 12 selects following weight percent
Raw material: silicone-modified aqueous polyurethane 2-15%, curing agent 1-10%, other be solvent, it is described silicone-modified aqueous poly-
The glass transition temperature of urethane is greater than 150 DEG C, toasts 5-10min after spraying in 70-100 DEG C of infrared baking oven, is formed and is caused
Close sealant 12；
5) it is whole to be formed in 12 printout surface pattern layer 11 of sealant using digital ink-jet printer for metal mesh layer of cloth 1；
6) metal mesh layer of cloth 1, doubling layer 2 and substrate layer 3 are stacked in the following order: substrate layer 3, doubling layer 2,
Metal mesh layer of cloth 1, four sides are sticked high temperature gummed tape fixation and are placed into autoclave or doubling furnace after stacking, and vacuumize 10-30min
Afterwards, temperature is raised to 120-150 DEG C, constant temperature and pressure 45-180min, cools the temperature to 40 DEG C hereinafter, opening autoclave or folder
Glue furnace takes out the compound board finished product of metal-containing layer plastic net cloth.
The weaving manner of the latticed plastic net cloth 14 is plain weave or twill weave.
The doubling layer 2 selects TPU film.
The substrate layer 3 selects PMMA plate, with a thickness of 5-10mm.
The mode of integrated embodiment 1- embodiment 4: the invention has the following advantages:
(1) present invention is provided with sealant, sealant using silicone-modified aqueous poly- ammonia in the two sides of metal deposition layer
Ester is that primary raw material can play fine and close protective effect to metal deposition layer, prevents that lower metal generation oxidation, degumming is used for a long time
The problems such as, the service life of composite board can be extended, guarantee the dicoration of composite board；And the setting of sealant can mention
The adhesive fastness of high pattern layer, the stability for guaranteeing decorative pattern；
(2) present invention during the preparation process carries out at low-temperature plasma latticed plastic wire layer of cloth before deposited metal layer
Reason can increase the wetability of latticed plastic net cloth layer surface, improve the bonding between metal and latticed plastic wire layer of cloth
Fastness；Low-temperature plasma processing further is made to metal deposition layer, can be improved the bonding between metal deposition layer and sealant
Property, fine and close protective effect is played to metal deposition layer；Metal mesh layer of cloth, doubling layer and basal layer paste under vacuum high-temperature environment
The bubble that can reduce fitting, the compactness for improving fitting are closed, to enhance the decorative effect of composite board.
The aforementioned description to specific exemplary embodiment of the invention is in order to illustrate and illustration purpose.These descriptions
It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to the above instruction, can much be changed
And variation.The purpose of selecting and describing the exemplary embodiment is that explaining specific principle of the invention and its actually answering
With so that those skilled in the art can be realized and utilize a variety of different exemplary implementation schemes of the invention and
Various chooses and changes.
Claims (10)
1. a kind of composite plate of metal-containing layer plastic net cloth, it is characterised in that: including metal mesh layer of cloth, doubling layer and substrate layer,
The one side of the metal mesh layer of cloth or two sides are bonded by doubling layer and substrate layer；The metal mesh layer of cloth is from top to bottom successively
For pattern layer, sealant, metal deposition layer, latticed plastic wire layer of cloth, metal deposition layer, sealant and pattern layer.
2. a kind of composite plate of metal-containing layer plastic net cloth according to claim 1, it is characterised in that: the latticed modeling
The string diameter for expecting the plastic wire of scrim layer is 100-500 μm, and plastic wire color is black, grey, and the range of the mesh accounts for screen cloth
Area ratio be 25-90%.
3. a kind of composite plate of metal-containing layer plastic net cloth according to claim 1, it is characterised in that: the metal deposit
Layer with a thickness of 100-300nm, the metal deposition layer is bonded on latticed plastic net cloth.
4. a kind of composite plate of metal-containing layer plastic net cloth according to claim 1, it is characterised in that: the sealant
With a thickness of 20-100um, the sealant is bonded on metal deposition layer.
5. a kind of composite plate of metal-containing layer plastic net cloth according to claim 1, it is characterised in that: the doubling layer
With a thickness of 0.76-20mm, the doubling layer bonded metal scrim layer and substrate layer.
6. a kind of composite plate of metal-containing layer plastic net cloth according to claim 1, it is characterised in that: the substrate is glass
Glass substrate or plastic base, the substrate layer with a thickness of 0.1-15mm.
7. a kind of preparation method of the composite plate of metal-containing layer plastic net cloth, it is characterised in that: the following steps are included:
1) two sides of the latticed plastic net cloth of Low Temperature Plasma Treating is used, the power of Low Temperature Plasma Treating is 50-
100W, pressure are atmospheric pressure environment, and the processing time is 1-10min；
2) by way of vacuum sputtering, plasma sputtering or vacuum evaporation deposition on the two sides of latticed plastic net cloth or
One face deposited metal layer, the metal select AI, Cu, Zn, Ag, Ni, Co, Mn, Cr, Ti, AICu one such；
3) Low Temperature Plasma Treating metal deposition layer is used, the power of Low Temperature Plasma Treating is 55-75W, and pressure is big
Air pressure environment, processing time are 3-8min；
4) one layer of sealant is sprayed in metal deposit layer surface, the sealant selects the raw material of following weight percent: silicon oxygen
Alkane modified aqueous polyurethane 2-15%, curing agent 1-10%, other be solvent, the glass of the silicone-modified aqueous polyurethane
Change inversion temperature and be greater than 150 DEG C, toast 5-10min in 70-100 DEG C of infrared baking oven after spraying, forms fine and close sealant；
5) it is whole to be formed in sealant printout surface pattern layer using digital ink-jet printer for metal mesh layer of cloth；
6) metal mesh layer of cloth, doubling layer and substrate layer are stacked in the following order: substrate layer, doubling layer, Metal screen cloth
Layer, doubling layer, substrate layer, four sides are sticked high temperature gummed tape fixation and are placed into autoclave or doubling furnace after stacking, and vacuumize 10-
After 30min, temperature is raised to 120-150 DEG C, constant temperature and pressure 45-180min, cool the temperature to 40 DEG C hereinafter, open autoclave or
Person's doubling furnace takes out the compound board finished product of metal-containing layer plastic net cloth.
8. a kind of preparation method of the composite plate of metal-containing layer plastic net cloth according to claim 7, it is characterised in that: institute
Stating latticed plastic net cloth string diameter is 100-500 μm, and plastic wire color is black, grey, and the range of the mesh accounts for screen cloth
Area ratio is 25-90%, and the weaving manner of the latticed plastic net cloth is plain weave or twill weave.
9. a kind of preparation method of the composite plate of metal-containing layer plastic net cloth according to claim 7, it is characterised in that: institute
Stating doubling layer is PVB film, EVA film, TPU film or SGP film.
10. a kind of preparation method of the composite plate of metal-containing layer plastic net cloth according to claim 7, it is characterised in that:
The substrate layer is glass or plastics, and the glass selects float glass, ultra-clear glasses or high-boron-silicon glass, the glass
Glass with a thickness of 2-15mm, the plastics select PMMA plate, PETG plate, PC plate or PET sheet, the plastics with a thickness of 0.1-
15mm。
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN117416113A (en) * | 2023-10-11 | 2024-01-19 | 常州佳尔科仿真器材有限公司 | Lightweight multilayer multiband high-reflection TPU composite material for false target |
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Effective date of registration: 20191203 Address after: 214000 Jingshi Road, Xibei Town, Xishan District, Wuxi City, Jiangsu Province Applicant after: Wuxi Chengyi Stone Technology Co., Ltd. Applicant after: Henrion (Xiamen) import and Export Co., Ltd Address before: 214194 Jingshi Road, Xibei Town, Xishan District, Wuxi City, Jiangsu Province Applicant before: Wuxi Chengyi Stone Technology Co., Ltd. |