CN109950517A - A kind of graphene lithium battery composite material and preparation method - Google Patents

A kind of graphene lithium battery composite material and preparation method Download PDF

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Publication number
CN109950517A
CN109950517A CN201910330064.0A CN201910330064A CN109950517A CN 109950517 A CN109950517 A CN 109950517A CN 201910330064 A CN201910330064 A CN 201910330064A CN 109950517 A CN109950517 A CN 109950517A
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parts
graphene
composite material
lithium battery
battery composite
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鞠群
胡安佩
渐彬彬
王珂
褚艳
邓毅
庄家庆
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Zaozhuang Institute Of Supervision And Inspection Product Quality
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

The invention discloses a kind of graphene lithium battery composite materials, are related to technical field of lithium batteries, mainly for solving the problems, such as existing graphene lithium battery composite material stability difference and at high cost;The graphene lithium battery composite material, including below according to the raw material of parts by weight: 45~65 parts of positive electrode, 30~50 parts of graphene, 28~36 parts of polyvinyl alcohol, 10~16 parts of polyethylene glycol, 10~14 parts of polyester fiber, 5~9 parts of dimethyl carbonate, 5~25 parts of silica 1,2~6 parts of sodium hydroxide solution, 50~80 parts of dehydrated alcohol, 2~6 parts of acrylamide, 2~6 parts of titanium dioxide, 4~10 parts of trifluoromethanesulfonic acid lithium.The invention also discloses the preparation methods of the graphene lithium battery composite material.Graphene lithium battery composite material prepared by the present invention with high security, it is at low cost, the feature of environmental protection is high the advantages that, have good market value.

Description

A kind of graphene lithium battery composite material and preparation method
Technical field
The present invention relates to a kind of graphene lithium battery, specifically a kind of graphene lithium battery composite material and its preparation side Method.
Background technique
It by lithium metal or lithium alloy is negative electrode material, using the battery of non-aqueous electrolytic solution that " lithium battery ", which is a kind of,.Lithium Battery is broadly divided into two classes: lithium metal battery and lithium ion battery, and lithium ion battery does not contain the lithium of metallic state, and being can With charging, lithium metal battery safety, specific capacity, self-discharge rate and the ratio of performance to price are superior to lithium ion battery.Due to lithium The chemical characteristic of metal is very active, so that the processing of lithium metal, preservation, use, very high to environmental requirement.With scientific skill The development of art, present lithium battery have become mainstream.
Graphene have excellent optics, electricity, mechanical characteristic, materialogy, micro-nano technology, the energy, biomedicine and Drug delivery etc. is with important application prospects, and the characteristic of graphene makes before field of lithium has a wide range of applications Scape, but graphene in use there is it is unstable low with volume energy density the problems such as, limit graphene preferably Play its characteristic.
Summary of the invention
The purpose of the present invention is to provide a kind of graphene lithium battery composite material and preparation methods, solve existing stone Black alkene lithium battery composite material stability difference and problem at high cost.
To achieve the above object, the invention provides the following technical scheme:
A kind of graphene lithium battery composite material, including below according to the raw material of parts by weight: 45~65 parts of positive electrode, graphene 30~50 parts, 28~36 parts of polyvinyl alcohol, 10~16 parts of polyethylene glycol, 10~14 parts of polyester fiber, 5~9 parts of dimethyl carbonate, 5~25 parts of silica 1,2~6 parts of sodium hydroxide solution, 50~80 parts of dehydrated alcohol, 2~6 parts of acrylamide, titanium dioxide 2 ~6 parts, 4~10 parts of trifluoromethanesulfonic acid lithium.
Based on the above technical solution, the present invention also provides following optional technical solutions:
In a kind of optinal plan: including below according to the raw material of parts by weight: 50~60 parts of positive electrode, graphene 34~46 Part, 30~34 parts of polyvinyl alcohol, 12~14 parts of polyethylene glycol, 11~13 parts of polyester fiber, 6~8 parts of dimethyl carbonate, titanium dioxide 17~23 parts of silicon, 3~5 parts of sodium hydroxide solution, 60~70 parts of dehydrated alcohol, 3~5 parts of acrylamide, 3~5 parts of titanium dioxide, 6~8 parts of trifluoromethanesulfonic acid lithium.
In a kind of optinal plan: including below according to the raw material of parts by weight: 55 parts of positive electrode, gathers 40 parts of graphene 32 parts of vinyl alcohol, 13 parts of polyethylene glycol, 12 parts of polyester fiber, 7 parts of dimethyl carbonate, 20 parts of silica, sodium hydroxide solution 4 Part, 65 parts of dehydrated alcohol, 4 parts of acrylamide, 4 parts of titanium dioxide, 7 parts of trifluoromethanesulfonic acid lithium.
In a kind of optinal plan: the positive electrode is one of lithium nickelate, cobalt acid lithium and lithium borate.
The preparation method of the graphene lithium battery composite material, steps are as follows:
Step 1: by positive electrode, graphene, polyvinyl alcohol, polyethylene glycol, silica, titanium dioxide, trifluoromethanesulfonic acid lithium It is put into ultrafine crusher and is crushed, using 50 meshes, obtain mixture A;
Step 2: it is uniform that dimethyl carbonate, sodium hydroxide solution, dehydrated alcohol, acrylamide being put into container for stirring, obtained Mixture B;
Step 3: mixture A and mixture B being stirred evenly, then polyester fiber is internally added, heating water bath is carried out, is mixed Close object C;
Step 4: the temperature of mixture C is cooled to room temperature, then is passed through nitrogen into mixture C and is carried out heating carbonization, heating carbonization Time be 30min, composite material can be obtained after being cooled to room temperature.
In a kind of optinal plan: the mixing time in the step 2 is 5min.
In a kind of optinal plan: the heating water bath time in the step 3 is 15min, and water bath heating temperature is 72 DEG C.
Compared to the prior art, beneficial effects of the present invention are as follows:
1, graphene lithium battery composite material prepared by the present invention, it is at low cost, improve graphene in the stability of use process, So that graphene preferably plays a role;
2, by adding dimethyl carbonate in lithium battery composite material, it can be improved lithium battery in the peace of production and use process Full property and reduce pollution of the lithium battery to environment.
Specific embodiment
Each embodiment cited by the present invention is only to illustrate the present invention, is not used to limit the scope of the present invention.To this Any modification apparent easy to know or change are without departure from spirit and scope of the invention made by invention.
Embodiment 1
A kind of graphene lithium battery composite material, including below according to the raw material of parts by weight: 45 parts of positive electrode, graphene 30 Part, 28 parts of polyvinyl alcohol, 10 parts of polyethylene glycol, 10 parts of polyester fiber, 5 parts of dimethyl carbonate, 5 parts of silica 1, sodium hydroxide 2 parts of solution, 50 parts of dehydrated alcohol, 2 parts of acrylamide, 2 parts of titanium dioxide, 4 parts of trifluoromethanesulfonic acid lithium.
Wherein, the positive electrode is one of lithium nickelate, cobalt acid lithium and lithium borate.
The preparation method of the graphene lithium battery composite material, steps are as follows:
Step 1: by positive electrode, graphene, polyvinyl alcohol, polyethylene glycol, silica, titanium dioxide, trifluoromethanesulfonic acid lithium It is put into ultrafine crusher and is crushed, using 50 meshes, obtain mixture A;
Step 2: it is uniform that dimethyl carbonate, sodium hydroxide solution, dehydrated alcohol, acrylamide being put into container for stirring, obtained Mixture B, the time of stirring are 5min;
Step 3: mixture A and mixture B being stirred evenly, then polyester fiber is internally added, heating water bath is carried out, is mixed Object C, heating water bath 15min are closed, bath temperature is 72 DEG C;
Step 4: the temperature of mixture C is cooled to room temperature, then is passed through nitrogen into mixture C and is carried out heating carbonization, heating carbonization Time be 30min, composite material can be obtained after being cooled to room temperature.
Embodiment 2
A kind of graphene lithium battery composite material, including below according to the raw material of parts by weight: 50 parts of positive electrode, graphene 34 Part, 30 parts of polyvinyl alcohol, 12 parts of polyethylene glycol, 11 parts of polyester fiber, 6 parts of dimethyl carbonate, 7 parts of silica 1, sodium hydroxide 3 parts of solution, 60 parts of dehydrated alcohol, 3 parts of acrylamide, 3 parts of titanium dioxide, 6 parts of trifluoromethanesulfonic acid lithium.
Wherein, the positive electrode is one of lithium nickelate, cobalt acid lithium and lithium borate.
The preparation method of the graphene lithium battery composite material, steps are as follows:
Step 1: by positive electrode, graphene, polyvinyl alcohol, polyethylene glycol, silica, titanium dioxide, trifluoromethanesulfonic acid lithium It is put into ultrafine crusher and is crushed, using 50 meshes, obtain mixture A;
Step 2: it is uniform that dimethyl carbonate, sodium hydroxide solution, dehydrated alcohol, acrylamide being put into container for stirring, obtained Mixture B, the time of stirring are 5min;
Step 3: mixture A and mixture B being stirred evenly, then polyester fiber is internally added, heating water bath is carried out, is mixed Object C, heating water bath 15min are closed, bath temperature is 72 DEG C;
Step 4: the temperature of mixture C is cooled to room temperature, then is passed through nitrogen into mixture C and is carried out heating carbonization, heating carbonization Time be 30min, composite material can be obtained after being cooled to room temperature.
Embodiment 3
A kind of graphene lithium battery composite material, including below according to the raw material of parts by weight: 55 parts of positive electrode, graphene 40 Part, 32 parts of polyvinyl alcohol, 13 parts of polyethylene glycol, 12 parts of polyester fiber, 7 parts of dimethyl carbonate, 20 parts of silica, sodium hydroxide 4 parts of solution, 65 parts of dehydrated alcohol, 4 parts of acrylamide, 4 parts of titanium dioxide, 7 parts of trifluoromethanesulfonic acid lithium.
Wherein, the positive electrode is one of lithium nickelate, cobalt acid lithium and lithium borate.
The preparation method of the graphene lithium battery composite material, steps are as follows:
Step 1: by positive electrode, graphene, polyvinyl alcohol, polyethylene glycol, silica, titanium dioxide, trifluoromethanesulfonic acid lithium It is put into ultrafine crusher and is crushed, using 50 meshes, obtain mixture A;
Step 2: it is uniform that dimethyl carbonate, sodium hydroxide solution, dehydrated alcohol, acrylamide being put into container for stirring, obtained Mixture B, the time of stirring are 5min;
Step 3: mixture A and mixture B being stirred evenly, then polyester fiber is internally added, heating water bath is carried out, is mixed Object C, heating water bath 15min are closed, bath temperature is 72 DEG C;
Step 4: the temperature of mixture C is cooled to room temperature, then is passed through nitrogen into mixture C and is carried out heating carbonization, heating carbonization Time be 30min, composite material can be obtained after being cooled to room temperature.
Embodiment 4
A kind of graphene lithium battery composite material, 60 parts of positive electrode, 46 parts of graphene, 34 parts of polyvinyl alcohol, polyethylene glycol 14 Part, 13 parts of polyester fiber, 8 parts of dimethyl carbonate, 23 parts of silica, 5 parts of sodium hydroxide solution, 70 parts of dehydrated alcohol, propylene 5 parts of amide, 5 parts of titanium dioxide, 8 parts of trifluoromethanesulfonic acid lithium.
Wherein, the positive electrode is one of lithium nickelate, cobalt acid lithium and lithium borate.
The preparation method of the graphene lithium battery composite material, steps are as follows:
Step 1: by positive electrode, graphene, polyvinyl alcohol, polyethylene glycol, silica, titanium dioxide, trifluoromethanesulfonic acid lithium It is put into ultrafine crusher and is crushed, using 50 meshes, obtain mixture A;
Step 2: it is uniform that dimethyl carbonate, sodium hydroxide solution, dehydrated alcohol, acrylamide being put into container for stirring, obtained Mixture B, the time of stirring are 5min;
Step 3: mixture A and mixture B being stirred evenly, then polyester fiber is internally added, heating water bath is carried out, is mixed Object C, heating water bath 15min are closed, bath temperature is 72 DEG C;
Step 4: the temperature of mixture C is cooled to room temperature, then is passed through nitrogen into mixture C and is carried out heating carbonization, heating carbonization Time be 30min, composite material can be obtained after being cooled to room temperature.
Embodiment 5
A kind of graphene lithium battery composite material, 65 parts of positive electrode, 50 parts of graphene, 36 parts of polyvinyl alcohol, polyethylene glycol 16 Part, 14 parts of polyester fiber, 9 parts of dimethyl carbonate, 25 parts of silica, 6 parts of sodium hydroxide solution, 80 parts of dehydrated alcohol, propylene 6 parts of amide, 6 parts of titanium dioxide, 10 parts of trifluoromethanesulfonic acid lithium.
Wherein, the positive electrode is one of lithium nickelate, cobalt acid lithium and lithium borate.
The preparation method of the graphene lithium battery composite material, steps are as follows:
Step 1: by positive electrode, graphene, polyvinyl alcohol, polyethylene glycol, silica, titanium dioxide, trifluoromethanesulfonic acid lithium It is put into ultrafine crusher and is crushed, using 50 meshes, obtain mixture A;
Step 2: it is uniform that dimethyl carbonate, sodium hydroxide solution, dehydrated alcohol, acrylamide being put into container for stirring, obtained Mixture B, the time of stirring are 5min;
Step 3: mixture A and mixture B being stirred evenly, then polyester fiber is internally added, heating water bath is carried out, is mixed Object C, heating water bath 15min are closed, bath temperature is 72 DEG C;
Step 4: the temperature of mixture C is cooled to room temperature, then is passed through nitrogen into mixture C and is carried out heating carbonization, heating carbonization Time be 30min, composite material can be obtained after being cooled to room temperature.
The above, the only specific embodiment of the disclosure, but the protection scope of the disclosure is not limited thereto, it is any Those familiar with the art can easily think of the change or the replacement in the technical scope that the disclosure discloses, and should all contain It covers within the protection scope of the disclosure.Therefore, the protection scope of the disclosure should be subject to the protection scope in claims.

Claims (7)

1. a kind of graphene lithium battery composite material, which is characterized in that including below according to the raw material of parts by weight: positive electrode 45 ~65 parts, 30~50 parts of graphene, 28~36 parts of polyvinyl alcohol, 10~16 parts of polyethylene glycol, 10~14 parts of polyester fiber, carbonic acid 5~9 parts of dimethyl ester, 5~25 parts of silica 1,2~6 parts of sodium hydroxide solution, 50~80 parts of dehydrated alcohol, acrylamide 2~ 6 parts, 2~6 parts of titanium dioxide, 4~10 parts of trifluoromethanesulfonic acid lithium.
2. graphene lithium battery composite material according to claim 1, which is characterized in that including below according to parts by weight Raw material: 50~60 parts of positive electrode, 34~46 parts of graphene, 30~34 parts of polyvinyl alcohol, 12~14 parts of polyethylene glycol, polyester are fine 11~13 parts of dimension, 6~8 parts of dimethyl carbonate, 7~23 parts of silica 1,3~5 parts of sodium hydroxide solution, dehydrated alcohol 60~ 70 parts, 3~5 parts of acrylamide, 3~5 parts of titanium dioxide, 6~8 parts of trifluoromethanesulfonic acid lithium.
3. graphene lithium battery composite material according to claim 2, which is characterized in that including below according to parts by weight Raw material: 55 parts of positive electrode, 40 parts of graphene, 32 parts of polyvinyl alcohol, 13 parts of polyethylene glycol, 12 parts of polyester fiber, carbonic acid diformazan 7 parts of ester, 20 parts of silica, 4 parts of sodium hydroxide solution, 65 parts of dehydrated alcohol, 4 parts of acrylamide, 4 parts of titanium dioxide, trifluoro 7 parts of methanesulfonic acid lithium.
4. graphene lithium battery composite material according to claim 1, which is characterized in that the positive electrode is nickel acid One of lithium, cobalt acid lithium and lithium borate.
5. a kind of preparation method of the graphene lithium battery composite material as described in Claims 1 to 4 is any, which is characterized in that Steps are as follows:
Step 1: by positive electrode, graphene, polyvinyl alcohol, polyethylene glycol, silica, titanium dioxide, trifluoromethanesulfonic acid lithium It is put into ultrafine crusher and is crushed, using 50 meshes, obtain mixture A;
Step 2: it is uniform that dimethyl carbonate, sodium hydroxide solution, dehydrated alcohol, acrylamide being put into container for stirring, obtained Mixture B;
Step 3: mixture A and mixture B being stirred evenly, then polyester fiber is internally added, heating water bath is carried out, is mixed Close object C;
Step 4: the temperature of mixture C is cooled to room temperature, then is passed through nitrogen into mixture C and is carried out heating carbonization, heating carbonization Time be 30min, composite material can be obtained after being cooled to room temperature.
6. the preparation method of graphene lithium battery composite material according to claim 5, which is characterized in that the step 2 In mixing time be 5min.
7. the preparation method of graphene lithium battery composite material according to claim 5, which is characterized in that the step 3 In the heating water bath time be 15min, water bath heating temperature be 72 DEG C.
CN201910330064.0A 2019-04-23 2019-04-23 A kind of graphene lithium battery composite material and preparation method Pending CN109950517A (en)

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CN103296277A (en) * 2012-03-01 2013-09-11 复旦大学 Graphite intercalation compound lithium-ion battery negative electrode material, as well as preparation method and application thereof
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