A kind of graphene lithium battery composite material and preparation method
Technical field
The present invention relates to a kind of graphene lithium battery, specifically a kind of graphene lithium battery composite material and its preparation side
Method.
Background technique
It by lithium metal or lithium alloy is negative electrode material, using the battery of non-aqueous electrolytic solution that " lithium battery ", which is a kind of,.Lithium
Battery is broadly divided into two classes: lithium metal battery and lithium ion battery, and lithium ion battery does not contain the lithium of metallic state, and being can
With charging, lithium metal battery safety, specific capacity, self-discharge rate and the ratio of performance to price are superior to lithium ion battery.Due to lithium
The chemical characteristic of metal is very active, so that the processing of lithium metal, preservation, use, very high to environmental requirement.With scientific skill
The development of art, present lithium battery have become mainstream.
Graphene have excellent optics, electricity, mechanical characteristic, materialogy, micro-nano technology, the energy, biomedicine and
Drug delivery etc. is with important application prospects, and the characteristic of graphene makes before field of lithium has a wide range of applications
Scape, but graphene in use there is it is unstable low with volume energy density the problems such as, limit graphene preferably
Play its characteristic.
Summary of the invention
The purpose of the present invention is to provide a kind of graphene lithium battery composite material and preparation methods, solve existing stone
Black alkene lithium battery composite material stability difference and problem at high cost.
To achieve the above object, the invention provides the following technical scheme:
A kind of graphene lithium battery composite material, including below according to the raw material of parts by weight: 45~65 parts of positive electrode, graphene
30~50 parts, 28~36 parts of polyvinyl alcohol, 10~16 parts of polyethylene glycol, 10~14 parts of polyester fiber, 5~9 parts of dimethyl carbonate,
5~25 parts of silica 1,2~6 parts of sodium hydroxide solution, 50~80 parts of dehydrated alcohol, 2~6 parts of acrylamide, titanium dioxide 2
~6 parts, 4~10 parts of trifluoromethanesulfonic acid lithium.
Based on the above technical solution, the present invention also provides following optional technical solutions:
In a kind of optinal plan: including below according to the raw material of parts by weight: 50~60 parts of positive electrode, graphene 34~46
Part, 30~34 parts of polyvinyl alcohol, 12~14 parts of polyethylene glycol, 11~13 parts of polyester fiber, 6~8 parts of dimethyl carbonate, titanium dioxide
17~23 parts of silicon, 3~5 parts of sodium hydroxide solution, 60~70 parts of dehydrated alcohol, 3~5 parts of acrylamide, 3~5 parts of titanium dioxide,
6~8 parts of trifluoromethanesulfonic acid lithium.
In a kind of optinal plan: including below according to the raw material of parts by weight: 55 parts of positive electrode, gathers 40 parts of graphene
32 parts of vinyl alcohol, 13 parts of polyethylene glycol, 12 parts of polyester fiber, 7 parts of dimethyl carbonate, 20 parts of silica, sodium hydroxide solution 4
Part, 65 parts of dehydrated alcohol, 4 parts of acrylamide, 4 parts of titanium dioxide, 7 parts of trifluoromethanesulfonic acid lithium.
In a kind of optinal plan: the positive electrode is one of lithium nickelate, cobalt acid lithium and lithium borate.
The preparation method of the graphene lithium battery composite material, steps are as follows:
Step 1: by positive electrode, graphene, polyvinyl alcohol, polyethylene glycol, silica, titanium dioxide, trifluoromethanesulfonic acid lithium
It is put into ultrafine crusher and is crushed, using 50 meshes, obtain mixture A;
Step 2: it is uniform that dimethyl carbonate, sodium hydroxide solution, dehydrated alcohol, acrylamide being put into container for stirring, obtained
Mixture B;
Step 3: mixture A and mixture B being stirred evenly, then polyester fiber is internally added, heating water bath is carried out, is mixed
Close object C;
Step 4: the temperature of mixture C is cooled to room temperature, then is passed through nitrogen into mixture C and is carried out heating carbonization, heating carbonization
Time be 30min, composite material can be obtained after being cooled to room temperature.
In a kind of optinal plan: the mixing time in the step 2 is 5min.
In a kind of optinal plan: the heating water bath time in the step 3 is 15min, and water bath heating temperature is 72 DEG C.
Compared to the prior art, beneficial effects of the present invention are as follows:
1, graphene lithium battery composite material prepared by the present invention, it is at low cost, improve graphene in the stability of use process,
So that graphene preferably plays a role;
2, by adding dimethyl carbonate in lithium battery composite material, it can be improved lithium battery in the peace of production and use process
Full property and reduce pollution of the lithium battery to environment.
Specific embodiment
Each embodiment cited by the present invention is only to illustrate the present invention, is not used to limit the scope of the present invention.To this
Any modification apparent easy to know or change are without departure from spirit and scope of the invention made by invention.
Embodiment 1
A kind of graphene lithium battery composite material, including below according to the raw material of parts by weight: 45 parts of positive electrode, graphene 30
Part, 28 parts of polyvinyl alcohol, 10 parts of polyethylene glycol, 10 parts of polyester fiber, 5 parts of dimethyl carbonate, 5 parts of silica 1, sodium hydroxide
2 parts of solution, 50 parts of dehydrated alcohol, 2 parts of acrylamide, 2 parts of titanium dioxide, 4 parts of trifluoromethanesulfonic acid lithium.
Wherein, the positive electrode is one of lithium nickelate, cobalt acid lithium and lithium borate.
The preparation method of the graphene lithium battery composite material, steps are as follows:
Step 1: by positive electrode, graphene, polyvinyl alcohol, polyethylene glycol, silica, titanium dioxide, trifluoromethanesulfonic acid lithium
It is put into ultrafine crusher and is crushed, using 50 meshes, obtain mixture A;
Step 2: it is uniform that dimethyl carbonate, sodium hydroxide solution, dehydrated alcohol, acrylamide being put into container for stirring, obtained
Mixture B, the time of stirring are 5min;
Step 3: mixture A and mixture B being stirred evenly, then polyester fiber is internally added, heating water bath is carried out, is mixed
Object C, heating water bath 15min are closed, bath temperature is 72 DEG C;
Step 4: the temperature of mixture C is cooled to room temperature, then is passed through nitrogen into mixture C and is carried out heating carbonization, heating carbonization
Time be 30min, composite material can be obtained after being cooled to room temperature.
Embodiment 2
A kind of graphene lithium battery composite material, including below according to the raw material of parts by weight: 50 parts of positive electrode, graphene 34
Part, 30 parts of polyvinyl alcohol, 12 parts of polyethylene glycol, 11 parts of polyester fiber, 6 parts of dimethyl carbonate, 7 parts of silica 1, sodium hydroxide
3 parts of solution, 60 parts of dehydrated alcohol, 3 parts of acrylamide, 3 parts of titanium dioxide, 6 parts of trifluoromethanesulfonic acid lithium.
Wherein, the positive electrode is one of lithium nickelate, cobalt acid lithium and lithium borate.
The preparation method of the graphene lithium battery composite material, steps are as follows:
Step 1: by positive electrode, graphene, polyvinyl alcohol, polyethylene glycol, silica, titanium dioxide, trifluoromethanesulfonic acid lithium
It is put into ultrafine crusher and is crushed, using 50 meshes, obtain mixture A;
Step 2: it is uniform that dimethyl carbonate, sodium hydroxide solution, dehydrated alcohol, acrylamide being put into container for stirring, obtained
Mixture B, the time of stirring are 5min;
Step 3: mixture A and mixture B being stirred evenly, then polyester fiber is internally added, heating water bath is carried out, is mixed
Object C, heating water bath 15min are closed, bath temperature is 72 DEG C;
Step 4: the temperature of mixture C is cooled to room temperature, then is passed through nitrogen into mixture C and is carried out heating carbonization, heating carbonization
Time be 30min, composite material can be obtained after being cooled to room temperature.
Embodiment 3
A kind of graphene lithium battery composite material, including below according to the raw material of parts by weight: 55 parts of positive electrode, graphene 40
Part, 32 parts of polyvinyl alcohol, 13 parts of polyethylene glycol, 12 parts of polyester fiber, 7 parts of dimethyl carbonate, 20 parts of silica, sodium hydroxide
4 parts of solution, 65 parts of dehydrated alcohol, 4 parts of acrylamide, 4 parts of titanium dioxide, 7 parts of trifluoromethanesulfonic acid lithium.
Wherein, the positive electrode is one of lithium nickelate, cobalt acid lithium and lithium borate.
The preparation method of the graphene lithium battery composite material, steps are as follows:
Step 1: by positive electrode, graphene, polyvinyl alcohol, polyethylene glycol, silica, titanium dioxide, trifluoromethanesulfonic acid lithium
It is put into ultrafine crusher and is crushed, using 50 meshes, obtain mixture A;
Step 2: it is uniform that dimethyl carbonate, sodium hydroxide solution, dehydrated alcohol, acrylamide being put into container for stirring, obtained
Mixture B, the time of stirring are 5min;
Step 3: mixture A and mixture B being stirred evenly, then polyester fiber is internally added, heating water bath is carried out, is mixed
Object C, heating water bath 15min are closed, bath temperature is 72 DEG C;
Step 4: the temperature of mixture C is cooled to room temperature, then is passed through nitrogen into mixture C and is carried out heating carbonization, heating carbonization
Time be 30min, composite material can be obtained after being cooled to room temperature.
Embodiment 4
A kind of graphene lithium battery composite material, 60 parts of positive electrode, 46 parts of graphene, 34 parts of polyvinyl alcohol, polyethylene glycol 14
Part, 13 parts of polyester fiber, 8 parts of dimethyl carbonate, 23 parts of silica, 5 parts of sodium hydroxide solution, 70 parts of dehydrated alcohol, propylene
5 parts of amide, 5 parts of titanium dioxide, 8 parts of trifluoromethanesulfonic acid lithium.
Wherein, the positive electrode is one of lithium nickelate, cobalt acid lithium and lithium borate.
The preparation method of the graphene lithium battery composite material, steps are as follows:
Step 1: by positive electrode, graphene, polyvinyl alcohol, polyethylene glycol, silica, titanium dioxide, trifluoromethanesulfonic acid lithium
It is put into ultrafine crusher and is crushed, using 50 meshes, obtain mixture A;
Step 2: it is uniform that dimethyl carbonate, sodium hydroxide solution, dehydrated alcohol, acrylamide being put into container for stirring, obtained
Mixture B, the time of stirring are 5min;
Step 3: mixture A and mixture B being stirred evenly, then polyester fiber is internally added, heating water bath is carried out, is mixed
Object C, heating water bath 15min are closed, bath temperature is 72 DEG C;
Step 4: the temperature of mixture C is cooled to room temperature, then is passed through nitrogen into mixture C and is carried out heating carbonization, heating carbonization
Time be 30min, composite material can be obtained after being cooled to room temperature.
Embodiment 5
A kind of graphene lithium battery composite material, 65 parts of positive electrode, 50 parts of graphene, 36 parts of polyvinyl alcohol, polyethylene glycol 16
Part, 14 parts of polyester fiber, 9 parts of dimethyl carbonate, 25 parts of silica, 6 parts of sodium hydroxide solution, 80 parts of dehydrated alcohol, propylene
6 parts of amide, 6 parts of titanium dioxide, 10 parts of trifluoromethanesulfonic acid lithium.
Wherein, the positive electrode is one of lithium nickelate, cobalt acid lithium and lithium borate.
The preparation method of the graphene lithium battery composite material, steps are as follows:
Step 1: by positive electrode, graphene, polyvinyl alcohol, polyethylene glycol, silica, titanium dioxide, trifluoromethanesulfonic acid lithium
It is put into ultrafine crusher and is crushed, using 50 meshes, obtain mixture A;
Step 2: it is uniform that dimethyl carbonate, sodium hydroxide solution, dehydrated alcohol, acrylamide being put into container for stirring, obtained
Mixture B, the time of stirring are 5min;
Step 3: mixture A and mixture B being stirred evenly, then polyester fiber is internally added, heating water bath is carried out, is mixed
Object C, heating water bath 15min are closed, bath temperature is 72 DEG C;
Step 4: the temperature of mixture C is cooled to room temperature, then is passed through nitrogen into mixture C and is carried out heating carbonization, heating carbonization
Time be 30min, composite material can be obtained after being cooled to room temperature.
The above, the only specific embodiment of the disclosure, but the protection scope of the disclosure is not limited thereto, it is any
Those familiar with the art can easily think of the change or the replacement in the technical scope that the disclosure discloses, and should all contain
It covers within the protection scope of the disclosure.Therefore, the protection scope of the disclosure should be subject to the protection scope in claims.