CN109943227A - A kind of solid buoyancy material matrix surface low-density anti-pollution paint - Google Patents
A kind of solid buoyancy material matrix surface low-density anti-pollution paint Download PDFInfo
- Publication number
- CN109943227A CN109943227A CN201910170734.7A CN201910170734A CN109943227A CN 109943227 A CN109943227 A CN 109943227A CN 201910170734 A CN201910170734 A CN 201910170734A CN 109943227 A CN109943227 A CN 109943227A
- Authority
- CN
- China
- Prior art keywords
- parts
- pollution
- raw material
- weight proportion
- pollution paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention relates to anti-pollution paint technical fields, and disclose a kind of solid buoyancy material matrix surface low-density anti-pollution paint, the raw material including following parts by weight proportion: 30.2-39.4 parts of anti-pollution components, 10.7 parts of filling components, 12-14 parts of adhesion components；Wherein, anti-pollution component includes the raw material of following parts by weight proportion: 20-30 parts of octamethylcy-clotetrasiloxanes；Filling components include the raw material of following parts by weight proportion: 4 parts of methacrylonitriles, 4 parts of methacrylic acids；Adhesion component includes the raw material of following parts by weight proportion: 3-5 parts of E03 trade mark bisphenol A type epoxy resins, 1-2 parts of isophorone diamine.The present invention solves solid buoyancy material matrix surface anti-pollution paint in the prior art, is effectively prevented marine organisms while equipment surface is grown nonparasitically upon another plant in realization, cannot achieve the technical issues of its own weight is effectively reduced.
Description
Technical field
The present invention relates to anti-pollution paint technical field, specially a kind of solid buoyancy material matrix surface low-density anti-pollution
Coating.
Background technique
It is extra large that solid buoyancy material has been widely used in latent device of oceanographic buoy, oil exploitation marine riser and underwater operation etc.
Equipment is used in ocean exploitation.However, existing solid buoyancy material, during long-time service, marine attaching organism can gradually grow
It is attached to the surface of the equipment such as oceanographic buoy, oil exploitation marine riser, at leisure increases the weight of material, so that it be made to lose
Buoyancy.
Marine attaching organism in order to prevent, currently used method are to coat one layer of anti-ocean on above equipment surface to adhere to
The coating of biology, as the ZL patent No. 99816367.8 discloses the composition and/or coating of a kind of marine antifouling, the composition
It and/or not only comprising the mixture of hydrolase, microorganism or hydrolase and microorganism in coating, but also include for enhancing water
Solve inorganic salts (NaCl, CaCl of enzymatic hydrolysis2、MgSO4), it is effectively prevented although above-mentioned composition and/or coating are able to achieve
The technical effect that marine organisms grow nonparasitically upon another plant in equipment surface, but the biggish nothing of density is added in above-mentioned composition and/or coating
Machine salt component, the biggish component of inorganic salts of density significantly increases the weight of above-mentioned composition and/or coating, if by said combination
Object and/or coating are coated in the surface of the ocean development equipment using buoyant material production, then the buoyancy of the equipment will
It can be obviously reduced.
The present invention provides a kind of solid buoyancy material matrix surface low-density anti-pollution paint, it is intended to solve in the prior art
Solid buoyancy material matrix surface anti-pollution paint is effectively prevented marine organisms while equipment surface is grown nonparasitically upon another plant in realization,
It cannot achieve the technical issues of its own weight is effectively reduced.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of solid buoyancy material matrix surface low-density anti-pollutions to apply
Material, solves solid buoyancy material matrix surface anti-pollution paint in the prior art, is effectively prevented marine organisms in realization and exists
While equipment surface is grown nonparasitically upon another plant, the technical issues of its own weight is effectively reduced cannot achieve.
(2) technical solution
To achieve the above object, the invention provides the following technical scheme:
A kind of solid buoyancy material matrix surface low-density anti-pollution paint, the raw material including following parts by weight proportion:
30.2-39.4 parts of anti-pollution components, 10.7 parts of filling components, 12-14 parts of adhesion components；
Wherein, anti-pollution component includes the raw material of following parts by weight proportion: 20-30 parts of octamethylcy-clotetrasiloxanes；Filling
Component includes the raw material of following parts by weight proportion: 4 parts of methacrylonitriles, 4 parts of methacrylic acids；Adhesion component includes following heavy
Measure the raw material of number proportion: 3-5 parts of E03 trade mark bisphenol A type epoxy resins, 1-2 parts of isophorone diamine.
Preferably, the anti-pollution component includes the raw material of following parts by weight proportion: 20g octamethylcy-clotetrasiloxane,
0.1g sodium hydroxide, 1mLN, dinethylformamide, 1mL hexamethyldisiloxane, 4mL gamma-aminopropyl-triethoxy-silane,
2mL propionic acid, 3mL acetate butyl.
Preferably, the filling components include the raw material of following parts by weight proportion: 5mL methacrylonitrile, 4mL methyl-prop
Olefin(e) acid, 0.1g dibenzoyl peroxide, 2mL isobutanol, 1mL allyl methacrylate.
Preferably, the adhesion component includes the raw material of following parts by weight proportion: 3gE03 trade mark bisphenol type epoxy tree
Rouge, 10mL butanone, 1mL isophorone diamine.
Preferably, the anti-pollution paint preparation method the following steps are included:
S1. using octamethylcy-clotetrasiloxane as primary raw material, anti-pollution component is prepared；
S2. using methacrylonitrile, methacrylic acid as primary raw material, preparation obtains filling components；
S3., anti-pollution component in step S1 and the filling components in step S2 are injected to the mold of sealing after mixing
In, it is placed in 50-70 DEG C of water-bath, constant temperature polymerization reaction for 24 hours, demoulds later, and copolymer is placed at 180-230 DEG C and is foamed instead
1h is answered, is cooled down later, anti-staining agent is prepared；
S4. using E03 trade mark bisphenol A type epoxy resin, butanone, isophorone diamine as raw material, adhesion component is prepared；
S5. the anti-staining agent in step S3 is added in the adhesion component in step S4, stirs evenly, is placed in vacuum oven
30min is steeped in interior middle vacuum evacuation, and anti-pollution paint is prepared.
Preferably, in the step S3, after polymer foaming reaction, it is cooled to 120-150 DEG C, it is anti-at 120-150 DEG C
Answer 3h.
(3) beneficial technical effect
Compared with prior art, the present invention has following beneficial technical effect:
The anti-pollution paint that the present invention prepares is coated in solid buoyancy material surface, is prepared into anti-pollution layer, conserves 7 days,
Contact angle after contact angle after the anti-pollution layer is stable in water is 102.4 ° -110.3 °, stablizes in diiodomethane is
98.4 ° -105.8 °, its density be 0.22-0.28g/cm3；
With contact angle 91.5 ° of the anti-pollution layer in comparative example after stable in water, stablize in diiodomethane after connecing
69.2 ° of feeler, density 0.68g/cm3It compares, the present invention not only significantly improves anti-pollution layer connecing in water and diiodomethane
Feeler, and it is significant alleviate the density of anti-pollution layer itself, to be effectively prevented marine organisms in equipment list in realization
While face is grown nonparasitically upon another plant, the technical effect that its own weight is effectively reduced is achieved.
Specific embodiment
Embodiment one:
Low-density anti-pollution paint includes following raw material: 30.2g anti-pollution component, 10.7g filling components, 12g adhesion component；
Wherein, anti-pollution component is made of following raw material, specifically: 20g octamethylcy-clotetrasiloxane, 0.1g sodium hydroxide,
1mLN, dinethylformamide (ρ 0.945g/cm3), 1mL hexamethyldisiloxane (ρ 0.762g/cm3), 4mL γ-ammonia third
Ethyl triethoxy silicane alkane (ρ 0.942g/cm3), 2mL propionic acid (ρ 0.99g/cm3), 3mL acetate butyl (ρ 0.88g/cm3)；
Filling components are made of following raw material, specifically: 5mL methacrylonitrile (ρ 0.8g/cm3), 4mL metering system
Acid (ρ 1.015g/cm3), 0.1g dibenzoyl peroxide, 2mL isobutanol (ρ 0.802g/cm3), 1mL methacrylic acid alkene
Propyl ester (ρ 0.94g/cm3)；
Adhesion component is made of following raw material, specifically: (ρ is for 3gE03 trade mark bisphenol A type epoxy resin, 10mL butanone
0.805g/cm3), 1mL isophorone diamine (ρ 0.924g/cm3)；
The preparation method of above-mentioned anti-pollution paint the following steps are included:
S1. by 20g octamethylcy-clotetrasiloxane, 0.1g sodium hydroxide, 1mLN, dinethylformamide, 1mL hexamethyl two
Siloxanes, 4mL gamma-aminopropyl-triethoxy-silane, are stirred to react 10h at 100 DEG C, and 2mL propionic acid is added later, react 1h,
130 DEG C of reaction 3h are warming up to, 3mL acetate butyl is eventually adding, anti-pollution component is prepared；
S2. 5mL methacrylonitrile, 4mL methacrylic acid, 0.1g dibenzoyl peroxide, 2mL isobutanol, 1mL methyl are taken
Allyl acrylate, preparation obtain filling components；
S3., anti-pollution component in step S1 and the filling components in step S2 are injected to the mold of sealing after mixing
In, it is placed in 60 DEG C of water-bath, constant temperature polymerization reaction for 24 hours, demoulds later, and copolymer is placed in the baking that preheating temperature is 100 DEG C
In case, with the heating rate of 4 DEG C/min, 180 DEG C are warming up to, the foamable reaction 1h at 180 DEG C is cooled to 120 DEG C later, in
3h is reacted at 120 DEG C, is cooled to room temperature, anti-staining agent is prepared；
S4. first 3gE03 trade mark bisphenol A type epoxy resin is dissolved in 10mL butanone, adds 1mL isophorone two
Amine stirs evenly, and adhesion component is prepared；
S5. the anti-staining agent in step S3 is added in the adhesion component in step S4, stirs evenly, is placed in vacuum oven
30min is steeped in interior middle vacuum evacuation, and anti-pollution paint is prepared；
S6. the anti-pollution paint in step S5 is coated in solid buoyancy material surface, is prepared into coating, conserved 7 days, the painting
Contact angle after layer is stable in water and diiodomethane respectively is 102.4 ° and 98.9 °, density 0.23g/cm3。
Embodiment two:
Low-density anti-pollution paint includes following raw material: 39.4g anti-pollution component, 10.7g filling components, 12.9g adhesion component；
Wherein, anti-pollution component is made of following raw material, specifically: 30g octamethylcy-clotetrasiloxane, 0.2g sodium hydroxide,
1mLN, dinethylformamide, 1mL hexamethyldisiloxane, 3mL gamma-aminopropyl-triethoxy-silane, 2mL propionic acid, 3mL vinegar
Sour fourth rouge；
Filling components are made of following raw material, specifically: 5mL methacrylonitrile, 4mL methacrylic acid, 0.1g peroxidating
Dibenzoyl, 2mL isobutanol, 1mL allyl methacrylate；
Adhesion component is made of following raw material, specifically: 3gE03 trade mark bisphenol A type epoxy resin, 10mL butanone, 2mL are different
Isophoronediamine；
The preparation method of above-mentioned anti-pollution paint the following steps are included:
S1. by 30g octamethylcy-clotetrasiloxane, 0.2g sodium hydroxide, 1mLN, dinethylformamide, 1mL hexamethyl two
Siloxanes, 3mL gamma-aminopropyl-triethoxy-silane, are stirred to react 10h at 100 DEG C, and 2mL propionic acid is added later, react 1h,
100 DEG C of reaction 3h are warming up to, 3mL acetate butyl is eventually adding, anti-pollution component is prepared；
S2. 5mL methacrylonitrile, 4mL methacrylic acid, 0.1g dibenzoyl peroxide, 2mL isobutanol, 1mL methyl are taken
Allyl acrylate, preparation obtain filling components；
S3., anti-pollution component in step S1 and the filling components in step S2 are injected to the mold of sealing after mixing
In, it is placed in 50 DEG C of water-bath, constant temperature polymerization reaction for 24 hours, demoulds later, and copolymer is placed in the baking that preheating temperature is 100 DEG C
In case, with the heating rate of 4 DEG C/min, 230 DEG C are warming up to, the foamable reaction 1h at 230 DEG C is cooled to 150 DEG C later, in
3h is reacted at 150 DEG C, is cooled to room temperature, anti-staining agent is prepared；
S4. first 3gE03 trade mark bisphenol A type epoxy resin is dissolved in 10mL butanone, adds 2mL isophorone two
Amine stirs evenly, and adhesion component is prepared；
S5. the anti-staining agent in step S3 is added in the adhesion component in step S4, stirs evenly, is placed in vacuum oven
30min is steeped in interior middle vacuum evacuation, and anti-pollution paint is prepared；
S6. the anti-pollution paint in step S5 is coated in solid buoyancy material surface, is prepared into coating, conserved 7 days, the painting
Contact angle after layer is stable in water and diiodomethane respectively is 110.3 ° and 105.8 °, density 0.22g/cm3。
Embodiment three:
Low-density anti-pollution paint includes following raw material: 33.2g anti-pollution component, 10.7g filling components, 14g adhesion component；
Wherein, anti-pollution component is made of following raw material, specifically: 23g octamethylcy-clotetrasiloxane, 0.1g sodium hydroxide,
1mLN, dinethylformamide, 1mL hexamethyldisiloxane, 4mL gamma-aminopropyl-triethoxy-silane, 2mL propionic acid, 3mL vinegar
Sour fourth rouge；
Filling components are made of following raw material, specifically: 5mL methacrylonitrile, 4mL methacrylic acid, 0.1g peroxidating
Dibenzoyl, 2mL isobutanol, 1mL allyl methacrylate；
Adhesion component is made of following raw material, specifically: 5gE03 trade mark bisphenol A type epoxy resin, 10mL butanone, 1mL are different
Isophoronediamine；
The preparation method of above-mentioned anti-pollution paint the following steps are included:
S1. by 23g octamethylcy-clotetrasiloxane, 0.1g sodium hydroxide, 1mLN, dinethylformamide, 1mL hexamethyl two
Siloxanes, 4mL gamma-aminopropyl-triethoxy-silane, are stirred to react 8h at 120 DEG C, and 2mL propionic acid is added later, react 1h, rise
Temperature is eventually adding 3mL acetate butyl, anti-pollution component is prepared to 150 DEG C of reaction 3h；
S2. 5mL methacrylonitrile, 4mL methacrylic acid, 0.1g dibenzoyl peroxide, 2mL isobutanol, 1mL methyl are taken
Allyl acrylate, preparation obtain filling components；
S3., anti-pollution component in step S1 and the filling components in step S2 are injected to the mold of sealing after mixing
In, it is placed in 70 DEG C of water-bath, constant temperature polymerization reaction for 24 hours, demoulds later, and copolymer is placed in the baking that preheating temperature is 100 DEG C
In case, with the heating rate of 4 DEG C/min, 200 DEG C are warming up to, the foamable reaction 1h at 200 DEG C is cooled to 130 DEG C later, in
3h is reacted at 130 DEG C, is cooled to room temperature, anti-staining agent is prepared；
S4. first 5gE03 trade mark bisphenol A type epoxy resin is dissolved in 10mL butanone, adds 1mL isophorone two
Amine stirs evenly, and adhesion component is prepared；
S5. the anti-staining agent in step S3 is added in the adhesion component in step S4, stirs evenly, is placed in vacuum oven
30min is steeped in interior middle vacuum evacuation, and anti-pollution paint is prepared；
S6. the anti-pollution paint in step S5 is coated in solid buoyancy material surface, is prepared into coating, conserved 7 days, the painting
Contact angle after layer is stable in water and diiodomethane respectively is 108.4 ° and 98.4.6 °, density 0.28g/cm3。
Comparative example:
Low-density anti-pollution paint includes following raw material: 30.2g anti-pollution component, 12g adhesion component；
Wherein, anti-pollution component is made of following raw material, specifically: 20g octamethylcy-clotetrasiloxane, 0.1g sodium hydroxide,
1mLN, dinethylformamide, 1mL hexamethyldisiloxane, 4mL gamma-aminopropyl-triethoxy-silane, 2mL propionic acid, 3mL vinegar
Sour fourth rouge；
Adhesion component is made of following raw material, specifically: 3gE03 trade mark bisphenol A type epoxy resin, 10mL butanone, 1mL are different
Isophoronediamine；
The preparation method of above-mentioned anti-pollution paint the following steps are included:
S1. by 20g octamethylcy-clotetrasiloxane, 0.1g sodium hydroxide, 1mLN, dinethylformamide, 1mL hexamethyl two
Siloxanes, 4mL gamma-aminopropyl-triethoxy-silane, are stirred to react 10h at 100 DEG C, and 2mL propionic acid is added later, react 1h,
130 DEG C of reaction 3h are warming up to, 3mL acetate butyl is eventually adding, anti-pollution component is prepared；
S2. it by the mold of the anti-pollution component injection sealing in step S1, is placed in 60 DEG C of water-bath, constant temperature polymerization reaction
For 24 hours, it demoulds later, copolymer is placed in the baking oven that preheating temperature is 100 DEG C, with the heating rate of 4 DEG C/min, is warming up to
180 DEG C, the foamable reaction 1h at 180 DEG C is cooled to 120 DEG C later, reacts 3h at 120 DEG C, be cooled to room temperature, be prepared
Anti-staining agent；
S3. first 3gE03 trade mark bisphenol A type epoxy resin is dissolved in 10mL butanone, adds 1mL isophorone two
Amine stirs evenly, and adhesion component is prepared；
S4. the anti-staining agent in step S2 is added in the adhesion component in step S3, stirs evenly, is placed in vacuum oven
30min is steeped in interior middle vacuum evacuation, and anti-pollution paint is prepared；
S5. the anti-pollution paint in step S4 is coated in solid buoyancy material surface, is prepared into coating, conserved 7 days, the painting
Contact angle after layer is stable in water and diiodomethane respectively is 91.5 ° and 69.2 °, density 0.68g/cm3。
Claims (6)
1. a kind of solid buoyancy material matrix surface low-density anti-pollution paint, which is characterized in that match including following parts by weight
The raw material of ratio: 30.2-39.4 parts of anti-pollution components, 10.7 parts of filling components, 12-14 parts of adhesion components；
Wherein, anti-pollution component includes the raw material of following parts by weight proportion: 20-30 parts of octamethylcy-clotetrasiloxanes；Filling components
Raw material including following parts by weight proportion: 4 parts of methacrylonitriles, 4 parts of methacrylic acids；Adhesion component includes following parts by weight
The raw material of number proportion: 3-5 parts of E03 trade mark bisphenol A type epoxy resins, 1-2 parts of isophorone diamine.
2. anti-pollution paint according to claim 1, which is characterized in that the anti-pollution component includes following parts by weight proportion
Raw material: 20g octamethylcy-clotetrasiloxane, 0.1g sodium hydroxide, 1mLN, dinethylformamide, two silicon oxygen of 1mL hexamethyl
Alkane, 4mL gamma-aminopropyl-triethoxy-silane, 2mL propionic acid, 3mL acetate butyl.
3. anti-pollution paint according to claim 1, which is characterized in that the filling components include following parts by weight proportion
Raw material: 5mL methacrylonitrile, 4mL methacrylic acid, 0.1g dibenzoyl peroxide, 2mL isobutanol, 1mL methacrylic acid
Allyl ester.
4. anti-pollution paint according to claim 1, which is characterized in that the adhesion component includes following parts by weight proportion
Raw material: 3gE03 trade mark bisphenol A type epoxy resin, 10mL butanone, 1mL isophorone diamine.
5. anti-pollution paint according to claim 1, which is characterized in that the preparation method of the anti-pollution paint includes following step
It is rapid:
S1. using octamethylcy-clotetrasiloxane as primary raw material, anti-pollution component is prepared；
S2. using methacrylonitrile, methacrylic acid as primary raw material, preparation obtains filling components；
S3. the anti-pollution component in step S1 and the filling components in step S2 are injected after mixing in the mold of sealing, is set
In 50-70 DEG C of water-bath, constant temperature polymerization reaction for 24 hours, demoulds later, and copolymer is placed in foamable reaction 1h at 180-230 DEG C,
Cool down later, anti-staining agent is prepared；
S4. using E03 trade mark bisphenol A type epoxy resin, butanone, isophorone diamine as raw material, adhesion component is prepared；
S5. the anti-staining agent in step S3 is added in the adhesion component in step S4, is stirred evenly, is placed in vacuum oven
Vacuum evacuation bubble 30min, is prepared anti-pollution paint.
6. anti-pollution paint according to claim 5, which is characterized in that in the step S3, after polymer foaming reaction, drop
Temperature reacts 3h at 120-150 DEG C to 120-150 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910170734.7A CN109943227B (en) | 2019-03-07 | 2019-03-07 | Low-density anti-fouling coating for surface of solid buoyancy material substrate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910170734.7A CN109943227B (en) | 2019-03-07 | 2019-03-07 | Low-density anti-fouling coating for surface of solid buoyancy material substrate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109943227A true CN109943227A (en) | 2019-06-28 |
| CN109943227B CN109943227B (en) | 2021-03-12 |
Family
ID=67009172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910170734.7A Expired - Fee Related CN109943227B (en) | 2019-03-07 | 2019-03-07 | Low-density anti-fouling coating for surface of solid buoyancy material substrate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109943227B (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100267853A1 (en) * | 2007-11-01 | 2010-10-21 | E.M.A.T. Technologies Ltd. | Polymer-based fire-retarding formulations |
| CN103351777A (en) * | 2013-06-18 | 2013-10-16 | 上海本朴科技发展有限公司 | Nanometer antifouling and antifingerprint coating composition and preparation method thereof |
| US20150273522A1 (en) * | 2012-10-10 | 2015-10-01 | Luxembourg Institute Of Science And Technology (List) | Method For Manufacturing A Superhydrophobic Surface, Surface So Obtained And Use Of It |
| CN105111354A (en) * | 2015-08-04 | 2015-12-02 | 航天材料及工艺研究所 | Acrylonitrile-based polymethacrylimide foam and preparation method therefor |
| CN106883725A (en) * | 2017-02-17 | 2017-06-23 | 中国船舶重工集团公司第七二五研究所 | A kind of double-component propeller antifouling paint |
| CN107312407A (en) * | 2017-08-07 | 2017-11-03 | 江苏理文化工有限公司 | A kind of long-acting self-cleaning coating and preparation method thereof |
| CN107779031A (en) * | 2017-10-16 | 2018-03-09 | 广州大学 | The antifouling smooth coating of low adhesion prepared by the emulsion system without any organic solvent |
| CN108624105A (en) * | 2018-04-26 | 2018-10-09 | 太仓中化环保化工有限公司 | A kind of preparation method of the antifouling anti-graffiti auxiliary agent of water solubility |
-
2019
- 2019-03-07 CN CN201910170734.7A patent/CN109943227B/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100267853A1 (en) * | 2007-11-01 | 2010-10-21 | E.M.A.T. Technologies Ltd. | Polymer-based fire-retarding formulations |
| US20150273522A1 (en) * | 2012-10-10 | 2015-10-01 | Luxembourg Institute Of Science And Technology (List) | Method For Manufacturing A Superhydrophobic Surface, Surface So Obtained And Use Of It |
| CN103351777A (en) * | 2013-06-18 | 2013-10-16 | 上海本朴科技发展有限公司 | Nanometer antifouling and antifingerprint coating composition and preparation method thereof |
| CN105111354A (en) * | 2015-08-04 | 2015-12-02 | 航天材料及工艺研究所 | Acrylonitrile-based polymethacrylimide foam and preparation method therefor |
| CN106883725A (en) * | 2017-02-17 | 2017-06-23 | 中国船舶重工集团公司第七二五研究所 | A kind of double-component propeller antifouling paint |
| CN107312407A (en) * | 2017-08-07 | 2017-11-03 | 江苏理文化工有限公司 | A kind of long-acting self-cleaning coating and preparation method thereof |
| CN107779031A (en) * | 2017-10-16 | 2018-03-09 | 广州大学 | The antifouling smooth coating of low adhesion prepared by the emulsion system without any organic solvent |
| CN108624105A (en) * | 2018-04-26 | 2018-10-09 | 太仓中化环保化工有限公司 | A kind of preparation method of the antifouling anti-graffiti auxiliary agent of water solubility |
Non-Patent Citations (4)
| Title |
|---|
| SU YANLEI等: "Antifouling Property of a Weak Polyelectrolyte Membrane Based on Poly(acrylonitrile) during Protein Ultrafiltration", 《INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH》 * |
| 许康: "氨基硅油改性丙烯酸树脂的制备及其海洋防污应用研究", 《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》 * |
| 陈青香等: "聚甲基丙烯酰亚胺泡沫塑料研究进展", 《工程塑料应用》 * |
| 黄良仙等: "新型氟代有机硅防水整理剂的制备及应用性能", 《印染助剂》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109943227B (en) | 2021-03-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104356287B (en) | A kind of pure acrylic emulsion of stone-like coating and preparation method of the high water-whitening resistance of exterior crosslinked type | |
| CN102732122B (en) | Long-acting self-polishing antifouling coating and preparation method thereof | |
| CN102358804A (en) | Special binder for waterbrone inorganic zinc-rich anti-corrosion coating | |
| CN102382552A (en) | Low temperature cured solvent-free epoxy anticorrosion paint and its preparation method | |
| CN103923560A (en) | Waterborne electro-plating sealant and preparation method thereof | |
| CN108913013A (en) | A kind of high bond strength ocean concrete anti-corrosion material and its preparation process | |
| CN112680014B (en) | Reflective heat insulation sand-in-water coating and preparation method thereof | |
| CN103740217A (en) | Water-based environment-friendly reflective heat-insulating and preserving coating for metal surface | |
| CN105778742B (en) | A kind of low temperature curing type acroleic acid polyurethane coating and manufacturing method | |
| JPWO2017094767A1 (en) | Antifouling composite coating film, antifouling substrate, and method for producing the antifouling substrate | |
| CN106497259A (en) | Aqueous chromium-free Dacroment-fluorubber composite coating and preparation method thereof | |
| CN105237693A (en) | Organic-inorganic hybrid silica modified acrylic resin and coating thereof | |
| CN107603393A (en) | A kind of method for protecting water-borne acrylic coatings adhesive force | |
| CN102286131A (en) | Organic fluorine monomer modified epoxy acrylate emulsion and preparation method thereof as well as antifouling paint containing the emulsion and preparation method thereof | |
| CN109943227A (en) | A kind of solid buoyancy material matrix surface low-density anti-pollution paint | |
| CN104371396A (en) | Scrubbing-resistant interior-wall coating for building | |
| CN101397817B (en) | Coating method of underwater curing anti-corrosive antifouling paint for sea facilities | |
| CN106800853B (en) | A kind of bathroom product coating and the preparation method and application thereof | |
| CN104292895B (en) | A kind of polyvinyl alcohol washable interior wall coating for building | |
| CN108129902A (en) | A kind of preparation method of moisture-proof, antibiotic type putty paste | |
| CN107043590A (en) | A kind of anti-corrosion polyurethane coating | |
| CN107057425A (en) | A kind of building water-proof anticorrosive paint and preparation method | |
| CN105111878B (en) | It is a kind of to make rubber rubber boot surface in water-based coating of dumb light color and luster and preparation method thereof | |
| CN105368260A (en) | Permeable epoxy seal primer and preparing method and using method thereof | |
| CN103937376A (en) | Paint with anti-corrosion property and its preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20210209 Address after: 071000 Fu Village, Liwu Town, Li County, Baoding City, Hebei Province Applicant after: Hebei dingchi road marking Engineering Co.,Ltd. Address before: 410300 No.37 Fangxing Road, Gaoping Township, Liuyang City, Changsha City, Hunan Province Applicant before: Qiu Jiping |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20210312 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |