CN109943165A - A kind of antibacterial waterproof anti-corrosion exterior coating and preparation method thereof - Google Patents

A kind of antibacterial waterproof anti-corrosion exterior coating and preparation method thereof Download PDF

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Publication number
CN109943165A
CN109943165A CN201711389612.4A CN201711389612A CN109943165A CN 109943165 A CN109943165 A CN 109943165A CN 201711389612 A CN201711389612 A CN 201711389612A CN 109943165 A CN109943165 A CN 109943165A
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parts
agent
preparation
waterproof anti
exterior coating
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CN201711389612.4A
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张亮
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Clivia Coating (tianjin) Co Ltd
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Clivia Coating (tianjin) Co Ltd
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Abstract

The invention discloses a kind of antibacterial waterproof anti-corrosion exterior coatings and preparation method thereof, it includes the raw material of following parts by weight: 90-120 parts of water, 15-25 parts of epoxy resin, 25-35 parts of perfluor silicone resin, 50-65 parts of acrylic emulsion, 10-15 parts of hydroxyethyl cellulose, 8-10 parts of polyvinylpyrrolidone dispersing agent, 10-15 parts of propylene glycol antifreezing agent, 25-35 parts of kaolin, 12 10-15 parts of coalescing agent alcohol ester, 5-10 parts of defoaming agent, 5-8 parts of isothiazolinone disinfecting agent, 15-25 parts of ultrafine mica powder, 45-65 parts of nano-titanium dioxide, 5-8 parts of aqueous wetting agent, 6-10 parts of thickener, such preparation method improves the waterproofness and contaminated resistance of coating, isothiazolinone disinfecting agent improves the antibacterial of coating Property, by the rational proportion of raw material, the corrosion resistance and thermal insulation of coating are improved, the addition of nano-titanium dioxide improves the anti-ultraviolet property and anti-aging property of coating, and such preparation method for coating simple process and low cost is suitble to large-scale production.

Description

A kind of antibacterial waterproof anti-corrosion exterior coating and preparation method thereof
Technical field
The present invention relates to technical field of aqueous paint, specially a kind of antibacterial waterproof anti-corrosion exterior coating and its preparation side Method.
Background technique
Coating is widely used in industry and lives each mainly for the protection of the article for needing to coat with decoration Field.In recent years, with the fast development of real estate industry, China, the demand of exterior coating is increasing, and people are for building The requirement for building appearance is also constantly being promoted.Since China different regions environmental condition differs greatly, for some heavy industry, mine The city of industry prosperity can make easily to stain coating and lose original decoration effect since dust in atmosphere and other suspended materials are more Fruit.Exterior coating decorative cover easy mildew in wet environment, it is desirable that coating has the function of inhibiting mould and algae reproduction growth.Separately Outside, exterior coating facing is exposed to the atmosphere, and can be often subject to rainwash, and exterior coating coating should have preferable water-fast Property and corrosion resistance.In the prior art, the functionality of coating is relatively simple, is not able to satisfy the requirement of various Composite.Therefore, I Propose a kind of antibacterial waterproof anti-corrosion exterior coating and preparation method thereof.
Summary of the invention
To make up the deficiencies in the prior art, a kind of antibacterial waterproof anti-corrosion exterior coating and preparation method thereof is provided.
The present invention adopts the following technical scheme: a kind of raw material system of stable type environmental protection effect water paint by following parts by weight At: 90-120 parts of water, 15-25 parts of epoxy resin, 25-35 parts of perfluor silicone resin, 50-65 parts of acrylic emulsion, ethoxy 10-15 parts of cellulose, 8-10 parts of polyvinylpyrrolidone dispersing agent, 10-15 parts of propylene glycol antifreezing agent, 25-35 parts of kaolin, at 10-15 parts of film auxiliary agent alcohol ester 12,5-8 parts of isothiazolinone disinfecting agent, 15-25 parts of ultrafine mica powder, is received 5-10 parts of defoaming agent Rice 45-65 parts of titanium dioxide, 5-8 parts of aqueous wetting agent, 6-10 parts of thickener.
The antibacterial waterproof anti-corrosion exterior coating the preparation method comprises the following steps:
S1 is by 90-120 parts of water, 15-25 parts of epoxy resin, 25-35 parts of perfluor silicone resin, acrylic emulsion 50-65 10-15 parts of part, hydroxyethyl cellulose mixing are added in stirred tanks, at normal temperature, with the stirring of 300r/min speed, 40min, until complete Full mixing, synthesizes base-material;
8-10 parts of polyvinylpyrrolidone dispersing agent, 5-10 parts of defoaming agent and water is added in gained base-material in above-mentioned S1 in S2 Property 5-8 parts of wetting agent, 30min is stirred with the revolving speed of 800-1000r/min, temperature controls between 70 DEG C to 80 DEG C, stirring knot Shu Hou, cooling keep the temperature at 45 DEG C, keep the temperature 2h, obtain reaction lotion;
S3 reacts ultrafine mica powder 15-25 parts, 45-65 parts of nano-titanium dioxide, kaolin of addition in lotion obtained by S2 25-35 parts, 60min is stirred with the revolving speed of 1200-1500r/min, room temperature is cooled the temperature to, obtains mixed emulsion;
10-15 parts of propylene glycol antifreezing agent, 12 10-15 of coalescing agent alcohol ester is added in gained mixed emulsion in S3 in S4 Part, 5-8 parts of isothiazolinone disinfecting agent, 6-10 parts of thickener stir 2h with the revolving speed of 600-800r/min, and temperature keeps normal Temperature stands 30min and obtains antibacterial waterproof anti-corrosion exterior coating.
Further, the defoaming agent is polydimethylsiloxanes;
Further, the nano-titanium dioxide is wherein the one of anatase titanium dioxide or rutile titanium dioxide Kind;
Further, the aqueous wetting agent is simple function group and oleoyl alkylene oxide block copolymer;
Further, the thickener is polyurethanes thickener.
The present invention improves painting by mixing and base-material being made epoxy resin, perfluor silicone resin, acrylic emulsion The waterproofness and contaminated resistance of material, isothiazolinone disinfecting agent improve the antibiotic property of coating, by the rational proportion of raw material, The corrosion resistance and thermal insulation of coating are improved, the addition of nano-titanium dioxide improves the anti-ultraviolet property of coating, simultaneously The anti-aging property of coating is also improved, such preparation method for coating simple process and low cost is suitble to large-scale production.
Specific embodiment
Combined with specific embodiments below to technical solution of the present invention further instruction, but the present invention is not in any form It is limited to embodiment content.Experimental method described in embodiment is conventional method unless otherwise specified, unless otherwise specified, The chemical reagent and material, commercially obtain.
Embodiment 1
Stable type environmental protection effect water paint is prepared from the following raw materials in parts by weight: 120 parts of water, 25 parts of epoxy resin, complete 35 parts of fluorosilicone resin, 50 parts of acrylic emulsion, 15 parts of hydroxyethyl cellulose, 10 parts of polyvinylpyrrolidone dispersing agent, third 15 parts of glycol antifreezing agent, 35 parts of kaolin, 12 parts of coalescing agent alcohol ester, 10 parts of polydimethylsiloxanes, isothiazolinone are killed 5 parts of microbial inoculum, 15 parts of ultrafine mica powder, 45 parts of anatase titanium dioxide, 8 parts of aqueous wetting agent, 10 parts of thickener.
The antibacterial waterproof anti-corrosion exterior coating the preparation method comprises the following steps:
S1 is by 120 parts of water, 25 parts of epoxy resin, 35 parts of perfluor silicone resin, 50 parts of acrylic emulsion, hydroxy ethyl fiber 15 parts of mixing of element are added in stirred tank, at normal temperature, with the stirring of 300r/min speed, 40min, until being thoroughly mixed, synthesize base-material;
S2 in above-mentioned S1 gained base-material in be added 10 parts of polyvinylpyrrolidone dispersing agent, 10 parts of polydimethylsiloxanes and 8 parts of aqueous wetting agent, 30min is stirred with the revolving speed of 1000r/min, temperature is controlled at 75 DEG C, and after stirring, cooling will be warm Degree is maintained at 45 DEG C, keeps the temperature 2h, obtains reaction lotion;
S3 reacts addition 15 parts of ultrafine mica powder, 45 parts of nano-titanium dioxide, 35 parts of kaolin in lotion obtained by S2, with The revolving speed of 1500r/min stirs 60min, cools the temperature to room temperature, obtains mixed emulsion;
15 parts of propylene glycol antifreezing agent, 12 parts of coalescing agent alcohol ester, different thiophene is added in gained mixed emulsion in S3 in S4 5 parts of oxazoline ketone fungicide, 10 parts of thickener stir 2h with the revolving speed of 800r/min, and the temperature remains within the normal range for temperature, stand 30min and obtain Antibacterial waterproof anti-corrosion exterior coating.
Embodiment 2
Stable type environmental protection effect water paint is prepared from the following raw materials in parts by weight: 90 parts of water, 15 parts of epoxy resin, perfluor 25 parts of silicone resin, 50 parts of acrylic emulsion, 10 parts of hydroxyethyl cellulose, 8 parts of polyvinylpyrrolidone dispersing agent, propylene glycol 10 parts of antifreezing agent, 25 parts of kaolin, 12 parts of coalescing agent alcohol ester, 5 parts of polydimethylsiloxanes, isothiazolinone disinfecting agent 5 Part, 15 parts of ultrafine mica powder, 45 parts of anatase titanium dioxide, 5 parts of aqueous wetting agent, 6 parts of thickener.
The antibacterial waterproof anti-corrosion exterior coating the preparation method comprises the following steps:
S1 is by 90 parts of water, 15 parts of epoxy resin, 25 parts of perfluor silicone resin, 50 parts of acrylic emulsion, hydroxy ethyl fiber 10 parts of mixing of element are added in stirred tank, at normal temperature, with the stirring of 300r/min speed, 40min, until being thoroughly mixed, synthesize base-material;
8-10 parts of polyvinylpyrrolidone dispersing agent, 5 and of polydimethylsiloxanes is added in gained base-material in above-mentioned S1 in S2 5 parts of aqueous wetting agent, 30min is stirred with the revolving speed of 800r/min, temperature is controlled at 70 DEG C, after stirring, cooling, by temperature 45 DEG C are maintained at, 2h is kept the temperature, obtains reaction lotion;
S3 reacts addition 15 parts of ultrafine mica powder, 45 parts of anatase titanium dioxide, 25 parts of kaolin in lotion obtained by S2, 60min is stirred with the revolving speed of 1200r/min, room temperature is cooled the temperature to, obtains mixed emulsion;
10 parts of propylene glycol antifreezing agent, 12 parts of coalescing agent alcohol ester, different thiophene is added in gained mixed emulsion in S3 in S4 5 parts of oxazoline ketone fungicide, 6 parts of thickener stir 2h with the revolving speed of 600r/min, and the temperature remains within the normal range for temperature, stand 30min and are resisted Bacterium waterproof anti-corrosion exterior coating.
Embodiment 3
Stable type environmental protection effect water paint is prepared from the following raw materials in parts by weight: 100 parts of water, 20 parts of epoxy resin, complete 30 parts of fluorosilicone resin, 55 parts of acrylic emulsion, 12 parts of hydroxyethyl cellulose, 9 parts of polyvinylpyrrolidone dispersing agent, the third two 12 parts of alcohol antifreezing agent, 30 parts of kaolin, 12 parts of coalescing agent alcohol ester, 8 parts of polydimethylsiloxanes, isothiazolinone disinfecting agent 7 parts, 20 parts of ultra-fine mica, 50 parts of rutile titanium dioxide, 7 parts of aqueous wetting agent, 8 parts of thickener.
The antibacterial waterproof anti-corrosion exterior coating the preparation method comprises the following steps:
S1 is by 100 parts of water, 20 parts of epoxy resin, 30 parts of perfluor silicone resin, 55 parts of acrylic emulsion, hydroxy ethyl fiber 12 parts of mixing of element are added in stirred tank, at normal temperature, with the stirring of 300r/min speed, 40min, until being thoroughly mixed, synthesize base-material;
9 parts of polyvinylpyrrolidone dispersing agent, 8 parts of polydimethylsiloxanes and water is added in gained base-material in above-mentioned S1 in S2 Property 7 parts of wetting agent, 30min is stirred with the revolving speed of 900r/min, temperature is controlled at 78 DEG C, and after stirring, temperature is protected in cooling It holds at 45 DEG C, keeps the temperature 2h, obtain reaction lotion;
S3 reacts addition 20 parts of ultrafine mica powder, 50 parts of rutile titanium dioxide, kaolin 30 in lotion obtained by S2 Part, 60min is stirred with the revolving speed of 1400r/min, room temperature is cooled the temperature to, obtains mixed emulsion;
12 parts of propylene glycol antifreezing agent, 12 parts of coalescing agent alcohol ester, different thiophene is added in gained mixed emulsion in S3 in S4 7 parts of oxazoline ketone fungicide, 8 parts of thickener stir 2h with the revolving speed of 700r/min, and the temperature remains within the normal range for temperature, stand 30min and are resisted Bacterium waterproof anti-corrosion exterior coating.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (5)

1. a kind of antibacterial waterproof anti-corrosion exterior coating and preparation method thereof, which is characterized in that antibacterial waterproof anti-corrosion exterior wall applies Material is prepared from the following raw materials in parts by weight: 90-120 parts of water, 15-25 parts of epoxy resin, 25-35 parts of perfluor silicone resin, 50-65 parts of acrylic emulsion, 10-15 parts of hydroxyethyl cellulose, 8-10 parts of polyvinylpyrrolidone dispersing agent, propylene glycol antifreezing agent 10-15 parts, 25-35 parts of kaolin, 12 10-15 parts of coalescing agent alcohol ester, 5-10 parts of defoaming agent, isothiazolinone disinfecting agent 5- 8 parts, 15-25 parts of ultrafine mica powder, 45-65 parts of nano-titanium dioxide, 5-8 parts of aqueous wetting agent, 6-10 parts of thickener;
Antibacterial waterproof anti-corrosion exterior coating the preparation method comprises the following steps: S1 by 90-120 parts of water, 15-25 parts of epoxy resin, perfluor silicon 10-15 parts of 25-35 parts of oxygen alkane resin, 50-65 parts of acrylic emulsion, hydroxyethyl cellulose mixing are added in stirred tank, in room temperature Under, with the stirring of 300r/min speed, 40min, until being thoroughly mixed, synthesize base-material;S2 is added poly- in above-mentioned S1 in gained base-material 8-10 parts of vinylpyrrolidone dispersing agent, 5-10 parts of defoaming agent and 5-8 parts of aqueous wetting agent, with the revolving speed of 800-1000r/min 30min is stirred, temperature controls between 70 DEG C to 80 DEG C, and after stirring, cooling keeps the temperature at 45 DEG C, keeps the temperature 2h, obtains To reaction lotion;S3 reacts ultrafine mica powder 15-25 parts, 45-65 parts of nano-titanium dioxide, kaolinite of addition in lotion obtained by S2 It is 25-35 parts native, 60min is stirred with the revolving speed of 1200-1500r/min, room temperature is cooled the temperature to, obtains mixed emulsion;S4 is in S3 10-15 parts of propylene glycol antifreezing agent, 12 10-15 parts of coalescing agent alcohol ester, isothiazolinone are added in middle gained mixed emulsion to kill 5-8 parts of microbial inoculum, 6-10 parts of thickener stir 2h with the revolving speed of 600-800r/min, and the temperature remains within the normal range for temperature, stand 30min and obtain Antibacterial waterproof anti-corrosion exterior coating.
2. a kind of antibacterial waterproof anti-corrosion exterior coating according to claim 1 and preparation method thereof, which is characterized in that institute Stating defoaming agent is polydimethylsiloxanes.
3. a kind of antibacterial waterproof anti-corrosion exterior coating according to claim 1 and preparation method thereof, which is characterized in that institute State the one of which that the nano-titanium dioxide is anatase titanium dioxide or rutile titanium dioxide.
4. a kind of antibacterial waterproof anti-corrosion exterior coating according to claim 1 and preparation method thereof, which is characterized in that institute Stating the aqueous wetting agent is simple function group and oleoyl alkylene oxide block copolymer.
5. a kind of antibacterial waterproof anti-corrosion exterior coating according to claim 1 and preparation method thereof, which is characterized in that institute Stating thickener is polyurethanes thickener.
CN201711389612.4A 2017-12-21 2017-12-21 A kind of antibacterial waterproof anti-corrosion exterior coating and preparation method thereof Pending CN109943165A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110396340A (en) * 2019-08-27 2019-11-01 惠州市鸿泰建筑工程有限公司 A kind of uvioresistant exterior coating of wet-heat resisting and preparation method thereof
CN111826046A (en) * 2020-07-30 2020-10-27 马鞍山市金韩防水保温工程有限责任公司 Environment-friendly water-based paint for buildings and preparation method thereof
CN113637364A (en) * 2021-08-16 2021-11-12 中国科学技术大学先进技术研究院 Waterproof primer and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004176040A (en) * 2002-10-01 2004-06-24 Sk Kaken Co Ltd Primary conditioning coating material and method for coating wall surface of building
CN102604498A (en) * 2012-02-29 2012-07-25 中山蓝海洋水性涂料有限公司 High-pollution-resistant high weatherproof water-based external wall emulsion paint and preparation method thereof
CN102676014A (en) * 2012-05-30 2012-09-19 浙江好途程新型建材有限公司 Staining-resistant heat-insulationcoating and preparation method thereof
CN102993869A (en) * 2012-11-28 2013-03-27 天长市开林化工有限公司 Coating for renovating exterior wall tiles of building

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004176040A (en) * 2002-10-01 2004-06-24 Sk Kaken Co Ltd Primary conditioning coating material and method for coating wall surface of building
CN102604498A (en) * 2012-02-29 2012-07-25 中山蓝海洋水性涂料有限公司 High-pollution-resistant high weatherproof water-based external wall emulsion paint and preparation method thereof
CN102676014A (en) * 2012-05-30 2012-09-19 浙江好途程新型建材有限公司 Staining-resistant heat-insulationcoating and preparation method thereof
CN102993869A (en) * 2012-11-28 2013-03-27 天长市开林化工有限公司 Coating for renovating exterior wall tiles of building

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110396340A (en) * 2019-08-27 2019-11-01 惠州市鸿泰建筑工程有限公司 A kind of uvioresistant exterior coating of wet-heat resisting and preparation method thereof
CN111826046A (en) * 2020-07-30 2020-10-27 马鞍山市金韩防水保温工程有限责任公司 Environment-friendly water-based paint for buildings and preparation method thereof
CN113637364A (en) * 2021-08-16 2021-11-12 中国科学技术大学先进技术研究院 Waterproof primer and preparation method thereof

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