CN109941962A - A method of being electrically connected high density slope step nano wire - Google Patents

A method of being electrically connected high density slope step nano wire Download PDF

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CN109941962A
CN109941962A CN201910240844.6A CN201910240844A CN109941962A CN 109941962 A CN109941962 A CN 109941962A CN 201910240844 A CN201910240844 A CN 201910240844A CN 109941962 A CN109941962 A CN 109941962A
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layer
nano wire
electrically connected
high density
etching
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CN109941962B (en
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余林蔚
徐顺
吴小祥
王军转
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Nanjing University
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Nanjing University
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Abstract

The invention discloses a kind of methods for being electrically connected high density slope step nano wire, using photoresist in alternately etching technics, it is different that local curvature's difference leads to move back erosion rate, to realize the step surface more much broader than low curvature (or straight) position in step higher curvature (both ends of such as band) position, so be conducive to easily prepare electrode on pace, it realizes and high density nanowire arrays on cliff is electrically connected respectively, the discrete nanowire field-effect device to realize high-density laminated provides great convenience.

Description

A method of being electrically connected high density slope step nano wire
Technical field
The present invention relates to the method that high density slope step is obtained by cycle alternation etching technics more particularly to a kind of electricity The method for learning connection high density slope step nano wire.
Background technique
Crystal silicon or related semiconductor nano wire (Nanowire) be develop of new generation High-performance micro-nano electronic logic, sensing and Show the crucial construction unit of application.In order to preferably mutually compatible with plane electronics technique, and realize that positioning is integrated, the application hair Bright people proposes a kind of plane solid-liquid earliest and consolidates (IP SLS) growth pattern: where using amorphous silicon as presoma, by eutectic Point indium metal, tin nanoparticles absorb amorphous silicon and grow crystal silicon nanowire structure.Meanwhile using mask layer and substrate to quarter The different etching response of gas is lost, multistage slope surface nanometer step can be prepared by the method that cycle alternation etches, with this three-dimensional Step is as guidance, and molten drop is in the case where the amorphous silicon that step edge covers attracts, the step edge that postpones movement, thus by nanometer Line is grown in step edge, realizes high density slope step nano-wire array.
It is difficult to apply in the problems in electronic device however, this high density nanowire arrays are but faced with.In micro-nano electricity In sub- device, for the ease of the needs such as testing, encapsulating, metal electrode its size being electrically connected is realized with nanowire channel often It is micron order, and the spacing for the slope step realized before this only has nanoscale, biggish size disparity often makes metal electrode It cannot substantially and securely be connect with nano wire, this not only brings huge challenge to manufacturing process, while also reducing nanometer Utilization rate of the line as channel, it is difficult to prepare the electronic device of high current, high integration.
Summary of the invention
Goal of the invention: the present invention proposes a kind of method for being electrically connected high density slope step nano wire, by exposure mask The design of layer shape, i.e., short side curvature is larger and long side curvature is smaller, since mask layer etching gas is to the biggish short side of curvature Spacing difference in length-width direction is formed in slope surface for the method for etching faster, thus can use cycle alternation etching and spacing can The solid matter of control guides nanometer step, is so conducive to easily prepare electrode on pace, and high density on cliff is received in realization Nanowire arrays are electrically connected respectively, and the discrete nanowire field-effect device to realize high-density laminated provides great convenience.
Technical solution:
A method of it being electrically connected high density slope step nano wire, comprising steps of
1) insulating medium layer of one layer of 200~1000nm thickness is deposited using PECVD or PVD process on substrate;
2) photoetching, electron-beam direct writing or mask plate technical definition step edge are utilized, keeps its short side curvature larger and grows Side curvature is smaller;The insulating medium layer shape is etched using inductively coupled plasma etching or reactive ion body etching technics At perpendicular steps side wall;Thickness of the etch thicknesses no more than the insulating medium layer;
3) a layer photoresist mask layer is covered at the top of the step, is performed etching by ICP etching technics;It is passed through again SF6、C4F8、CF4Or Ar performs etching the silicon oxide dielectric layer of photoresist mask layer edge exposure;To above-mentioned two Step carries out circulation etching several times, obtains multistage slope surface nanometer step, and the series of step is corresponding to the number of circulation etching;
4) in slope surface nanometer step one end, by photoetching, thermal evaporation process or sputtering technology, part deposits a layer thickness For the band-like catalyzing metal layer of 20~100nm;Temperature to catalyzing metal layer fusing point or more is increased, reducibility gas plasma is passed through Body is handled, and the catalyzing metal layer for being covered on described slope surface nanometer step one end is made to be changed into the metal nanoparticle of separation;
5) temperature is reduced to metal nanoparticle fusing point hereinafter, covering one layer and required life in total surface deposition The long corresponding amorphous semiconductor precursor thin-film layer of nano wire;
6) in vacuum or the environment of inert gas shielding, catalytic metal fusing point or more is raised the temperature to, so that golden Metal nano-particle refuse starts to absorb amorphous silicon layer in its front end, and deposits out the nano wire of crystalline state in rear end;It is described to receive Rice noodles, as guidance channel Parallel Growth, obtain Parallel Growth and receive in the slope surface by the multi-stage stairs on slope surface nanometer step Nano-wire array on meter Tai Jie;
7) remaining amorphous silicon precursor thin-film layer is removed by hydrogen gas plasma, ICP RIE etching technics;
8) at the slope surface nanometer step both ends, pattern is formed using photoetching or electron-beam direct writing, is then steamed using heat Hair or sputtering technology deposit the discrete metal electrode of one layer of 50~200nm thickness, are formed reliably electric respectively to the nano wire Learn connection.
In the step 1), the material of the substrate is crystal silicon, glass, aluminium foil, silicon nitride, silica, silicon carbide, Lan Bao Stone, polyimides or poly terephthalic acid class plastics.
In the step 1), the insulating medium layer is with a thickness of 100~600nm.
In the step 1), the dielectric layer material is silica.
In the step 3), for the height of every grade of step in 1~1000 nanometer range, circulation etching number is 1~10;It is long The spacing spent on direction is 2~3 times of width direction.
The catalytic metal is indium.
The precursor thin-film layer is amorphous silicon a-Si, amorphous germanium a-Ge, amorphous carbon a-C or other amorphous alloy Layer or heterogeneous laminated construction.
On the slope surface nanometer step, every layer of precursor thin-film layer cladding thickness is between 2~500nm.
The utility model has the advantages that 1) respond using mask layer and substrate to the different etching of etching gas, only pass through a photoetching+quarter Etching technique can be etched by cycle alternation and obtain multistage slope surface nanometer step.Guidance nano wire be can be directly used in this slope surface Upper Parallel Growth obtains density three-dimensional slope surface nanowire array structure;2) by the particular design of mask layer shape, using covering Film layer etching gas realizes its higher curvature (both ends of such as band) position ratio to the difference of mask layer both direction etching speed The much broader step surface in low curvature (or straight) position, then grows the nano wire for being parallel to step;3) slope step is long Biggish spacing prepares metal electrode convenient for subsequent process on degree direction, this is the micro-nano electronics for realizing high integration, high current Device provides possibility;4) electrode of discrete form takes full advantage of each nano wire, and the nano wire at one on step is no longer It uses as a whole, since the number that the series of step can be etched by cycle alternation controls, thus this form has Hope the integrated level for greatly improving device.
Detailed description of the invention
Fig. 1 is a kind of preparation flow schematic diagram for being electrically connected high density slope step nano wire provided by the invention.Its In, Fig. 1 a substrate pre-treatment, Fig. 1 b deposits one layer of dielectric layer on substrate, and Fig. 1 c etch media layer forms perpendicular steps and covers Mask layer, Fig. 1 d move back erosion technology and form multistage slope step, and the e step one end Fig. 1 deposits ribbon catalyzing metal layer, Fig. 1 f hydrogen etc. Gas ions processing forms catalytic metal drop, and Fig. 1 g covers noncrystal precursor layer, and Fig. 1 h starts to grow nano wire, Fig. 1 i step two End deposits discrete metal electrode.
Fig. 2 is that one kind provided by the invention is electrically connected high density slope step structure SEM schematic diagram.
Specific embodiment
In the following with reference to the drawings and specific embodiments, the present invention is furture elucidated.
Fig. 1 is a kind of preparation flow schematic diagram for being electrically connected high density slope step nano wire provided by the invention.Such as Shown in Fig. 1, the method for being electrically connected high density slope step nano wire of the invention, step includes:
1) (poly- with crystal silicon, glass, aluminium foil, silicon nitride, silica, silicon carbide, sapphire, PI (polyimides) or PET Terephthaldehyde's acids plastics) it is used as substrate, the dielectric of one layer of 200~1000nm thickness is deposited using PECVD or PVD process Layer;In the present invention, more optimal solution is the dielectric that one layer of 100~600nm thickness is deposited using PECVD or PVD process Layer, the material of the insulating medium layer are silica, such as SiO2, Si3N4Deng;
2) photoetching, electron-beam direct writing or mask plate technical definition step edge are utilized, keeps its short side curvature larger and grows Side curvature is smaller, this is conducive to subsequent step and forms the step appearance needed;Using inductively coupled plasma body (ICP) etching or Person's reactive ion body etches (RIE) technique etch media layer and forms perpendicular steps side wall;Etch thicknesses are situated between no more than silica Matter thickness degree;
3) a layer photoresist mask layer is covered at the top of step is passed through O in ICP etching technics2、Cl2Or and exposure mask The corresponding etching gas of layer forms plasma, also can be in the horizontal direction to inside contracting while photoresist vertical direction is etched It is retracted more into certain distance, and on the biggish short side direction of curvature, then passes to SF6、C4F8、CF4Or Ar is to photoresist The silicon oxide dielectric layer of mask layer edge exposure performs etching;Such two steps cycle alternation carries out, gradually due to mask layer It moves back and moves back erosion rate difference caused by erosion and local curvature's difference, it is larger and wide that length direction top bar spacing may finally be obtained The small-pitch multistage slope surface nanometer step of direction top bar is spent, and the series of step is corresponding to the number of circulation etching;Every grade For the height of step in 1~1000 nanometer range, cycle period can be 1~10;Width direction is spaced about on length direction 2~3 times;
4) in slope surface nanometer step one end, by photoetching, thermal evaporation process or sputtering technology, part deposits a layer thickness For the band-like catalyzing metal layer of 20~100nm;Temperature to catalyzing metal layer fusing point or more is increased, the reduction such as hydrogen, ammonia is passed through Property gaseous plasma is handled, and the metal for making the catalyzing metal layer for being covered on slope surface nanometer step one end be changed into separation is received Rice grain;In the present invention, the catalytic metal is indium;
5) temperature is reduced to metal nanoparticle fusing point hereinafter, total surface deposition covers one layer and required growth The corresponding amorphous semiconductor precursor thin-film layer of nano wire;The precursor thin-film layer is amorphous silicon a-Si, amorphous germanium a-Ge, non- Brilliant carbon a-C or other amorphous alloy layers and heterogeneous lamination (such as a-Ge/a-Si) structure;On slope surface nanometer step, often Layer film cladding thickness is between 2~500nm;
6) in vacuum or the environment of inert gas shielding, catalytic metal fusing point or more is raised the temperature to, so that golden Metal nano-particle refuse starts to absorb amorphous silicon layer in its front end, and deposits out the nano wire of crystalline state in rear end;By slope Multi-stage stairs on face obtain Parallel Growth in the nano-wire array on slope step as guidance channel;
7) remaining amorphous silicon precursor thin-film layer can be removed by hydrogen gas plasma, ICP RIE etching technics;By It is greater than remaining noncrystal membrane precursor layer in slope surface in the nanowire diameter of slope step growth, general diameter is film thickness 2~3 times, and in ICP, RIE etching technics, the etch rate of amorphous layer is usually above the etching to crystalline state nano wire, therefore Amorphous layer on slope step is selectively cleared;
8) at slope surface nanometer step both ends, form pattern using photoetching or electron-beam direct writing, then using thermal evaporation or Person's sputtering technology deposits the discrete metal electrode of one layer of 50~200nm thickness, and formation is reliably electrically connected nano wire respectively.
The preferred embodiment of the present invention has been described above in detail, but during present invention is not limited to the embodiments described above Detail can carry out a variety of equivalents to technical solution of the present invention (in full within the scope of the technical concept of the present invention Amount, shape, position etc.), these equivalents belong to protection of the invention.

Claims (8)

1. a kind of method for being electrically connected high density slope step nano wire, it is characterised in that: comprising steps of
1) insulating medium layer of one layer of 200~1000nm thickness is deposited using PECVD or PVD process on substrate;
2) photoetching, electron-beam direct writing or mask plate technical definition step edge are utilized, makes that its short side curvature is larger and long side is bent Rate is smaller;It is formed using inductively coupled plasma etching or the reactive ion body etching technics etching insulating medium layer vertical Straight mesa sidewall;Thickness of the etch thicknesses no more than the insulating medium layer;
3) a layer photoresist mask layer is covered at the top of the step, is performed etching by ICP etching technics;It is passed through SF again6、 C4F8、CF4Or Ar performs etching the silicon oxide dielectric layer of photoresist mask layer edge exposure;To above-mentioned two stepping Row circulation etching several times, obtains multistage slope surface nanometer step, and the series of step is corresponding to the number of circulation etching;
4) in slope surface nanometer step one end, by photoetching, thermal evaporation process or sputtering technology, it is 20 that part, which deposits a layer thickness, The band-like catalyzing metal layer of~100nm;Increase temperature to catalyzing metal layer fusing point more than, be passed through reducibility gas plasma into Row processing, makes the catalyzing metal layer for being covered on described slope surface nanometer step one end be changed into the metal nanoparticle of separation;
5) temperature metal nanoparticle fusing point is reduced to receive hereinafter, covering one layer in total surface deposition with required growth The corresponding amorphous semiconductor precursor thin-film layer of rice noodles;
6) in vacuum or the environment of inert gas shielding, catalytic metal fusing point or more is raised the temperature to, so that metal is received Rice grain refuse starts to absorb amorphous silicon layer in its front end, and deposits out the nano wire of crystalline state in rear end;The nano wire By the multi-stage stairs on slope surface nanometer step as guidance channel Parallel Growth, Parallel Growth is obtained in the slope surface nanometer platform Nano-wire array on rank;
7) remaining amorphous silicon precursor thin-film layer is removed by hydrogen gas plasma, ICP RIE etching technics;
8) at the slope surface nanometer step both ends, form pattern using photoetching or electron-beam direct writing, then using thermal evaporation or Person's sputtering technology deposits the discrete metal electrode of one layer of 50~200nm thickness, is formed and reliably distinguishes the nano wire electricity company It connects.
2. the method according to claim 1 for being electrically connected high density slope step nano wire, it is characterised in that: the step It is rapid 1) in, the material of the substrate be crystal silicon, glass, aluminium foil, silicon nitride, silica, silicon carbide, sapphire, polyimides or Person's poly terephthalic acid class plastics.
3. the method according to claim 1 for being electrically connected high density slope step nano wire, it is characterised in that: the step It is rapid 1) in, the insulating medium layer is with a thickness of 100~600nm.
4. the method according to claim 1 for being electrically connected high density slope step nano wire, it is characterised in that: the step It is rapid 1) in, the dielectric layer material be silica.
5. the method according to claim 1 for being electrically connected high density slope step nano wire, it is characterised in that: the step It is rapid 3) in, the height of every grade of step in 1~1000 nanometer range, circulation etching number be 1~10;Spacing on length direction It is 2~3 times of width direction.
6. the method according to claim 1 for being electrically connected high density slope step nano wire, it is characterised in that: described to urge Change metal is indium.
7. the method according to claim 1 for being electrically connected high density slope step nano wire, it is characterised in that: before described Drive thin-film layers are amorphous silicon a-Si, amorphous germanium a-Ge, amorphous carbon a-C or other amorphous alloy layers or heterogeneous lamination knot Structure.
8. the method according to claim 1 for being electrically connected high density slope step nano wire, it is characterised in that: described On slope surface nanometer step, every layer of precursor thin-film layer cladding thickness is between 2~500nm.
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CN113247860A (en) * 2020-06-24 2021-08-13 南京大学 Preparation method of embedded cross-surface growth three-dimensional nanowire spiral structure
CN113428832A (en) * 2021-06-25 2021-09-24 杭州电子科技大学温州研究院有限公司 High-density multi-modal neural microelectrode array and preparation and integration method thereof
CN113968571A (en) * 2021-10-21 2022-01-25 南京大学 Preparation method of anti-crosstalk self-limiting ultrafine close-packed crystal silicon nanowires

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