CN109929706A - A kind of natural soap lye liquid detergent Performance-System made using green bean oil - Google Patents
A kind of natural soap lye liquid detergent Performance-System made using green bean oil Download PDFInfo
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- CN109929706A CN109929706A CN201910010248.9A CN201910010248A CN109929706A CN 109929706 A CN109929706 A CN 109929706A CN 201910010248 A CN201910010248 A CN 201910010248A CN 109929706 A CN109929706 A CN 109929706A
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Abstract
The invention discloses a kind of Performance-Systems of natural soap lye liquid detergent using the production of green bean oil, belong to natural soap lye liquid detergent and surfactant science and applied technical field.The present invention adds alkali to be adjusted to milky white shape using soybean oil as raw material, and surfactant is then added, and pH is tuned into neutrality, can be prepared by the natural soap lye liquid detergent of soybean oil type.The present invention forms oligomeric structure using the hydrogen bond action between the carboxyl and surfactant of soybean oil, and hydrophobic volume further increases, and is more likely formed long stable foaming properties system.Liquid detergent initial foam volume of the present invention is up to 85ml, and half-life period is up to 120min.The present invention realizes the effective use of soybean oil, can reduce to the dependence of chemical surfactant, capable of greatly saving human cost instantly, with very big economic effect and social benefit.
Description
Technical field
The present invention relates to a kind of Performance-Systems of natural soap lye liquid detergent using the production of green bean oil, belong to natural soap
Liquid liquid detergent and surfactant science and applied technical field.
Background technique
Soybean oil is derived from soya seeds, and soybean oil is the grease that yield is most in the world.There are many type of soybean oil, press and add
Work mode can be divided into squeezing soyabean oil, leach soybean oil；Soy bean oil, genetically engineered soybean oil can be divided by the type of soybean.
The color of soybean oil is deeper, there is special beany flavor；Thermal stability is poor, and when heating can generate more foam.
Soybean oil contains more linolenic acid, is easier to oxidation deterioration and generates " beans stink ".In terms of edible quality, soybean oil is not so good as
Sesame oil, sunflower oil, peanut oil.
In terms of nutritive value, 7-10% containing palmitinic acid in soybean oil, stearic acid 2-5%, arachidic acid 1-3%, oleic acid 22-
30%, linoleic acid 50-60, linolenic acid 5-9%.The Fatty acid compositions of soybean oil are preferable, its linoleic acid rich in has
It is significant to reduce serum cholesterol content, the effect of preventing cardiovascular disease, the also vitamin E containing volume, dimension life in soybean
Plain D and lecithin abundant, it is very useful to human health.In addition, human consumption's absorptivity of soybean oil is up to
98%, so soybean oil is also a kind of very high excellent edible oil of nutritive value.
Soya-bean oil is also brought some non-oil substances into process, is contained in unrefined crude oil in addition to containing fat
The phosphatide of 1%-3%, the sterol substance and the substances such as a small amount of protein and wheat germ phenol of 0.7%-0.8%, easily causes acid
It loses, so soya-bean oil such as removes impurity without aquation, it is unsuitable long-term storage.In addition, purification soya-bean oil is in long term storage, it is oily
Color can gradually be deepened by shallowly, and reason may be related with the autoxidation of grease, therefore, when soya-bean oil darkens, just should not be remake
Long term storage.
Soybean oil raw material is easy to get, and soybean oil is more to be eaten by people, however we expect under social condition instantly
Natural soap lye liquid detergent is made using this Nantural non-toxic harmless material of soybean oil, can reduce to instantly living to chemical surface
The dependence of property agent, can greatly reduce liquid detergent cost, further increase detersive efficiency.
Liquid detergent can bring many conveniences, compared with powder product, liquid product to the daily life of consumer
It is more easier to dissolve, especially at low temperatures, dust in process of production is less, and metering is easy and accurate.From 20 generation
It recorded for the 50's, light dirt type liquid detergent comes into vogue and gradually achieves the considerable market share.Heavy duty liquid laundry detergent,
The development of especially natural soap lye liquid detergent also it is unwilling thereafter.The global natural soap lye liquid detergent of first the heavy scale in 1958
U.S.'s listing.To in the 1970s, phosphorous powder detergent is restricted, so that naturally because legislation issues, which are carried out, prohibits phosphorus
Soap lye liquid detergent is developed opportunity, substantially reduces the market training process of natural soap lye liquid detergent.From washing powder to natural
The transformation of soap lye liquid detergent experienced the development of technical change and corresponding raw material and formula technique.
Surfactant is that a kind of addition minute quantity can reduce significantly the surface tension of solution and be formed in body phase
One substance of orderly molecule aggregate, is made of hydrophobic grouping and hydrophilic radical.Surfactant because of its amphiphilic nature,
Can be adsorbed on interface and be formed in certain density solution foam latex, thus have froth flotation, from
The performances such as sub- flotation, foam flooding, foam fire-fighting.Surfactant in the solution can self-organizing to form various molecular assemblies poly-
Collective, such as spherical foam, rodlike foam, foam, vesica and liquid crystal.Surfactant foam, formation condition and Xiang Guanji
Reason is always the emphasis of surfactant scientific domain concern and research.Wherein foam occupies importantly in research in recent years
Position.Bubble power refer to formation of foam complexity and raw foaming amount number, and stability refers to and generates the lasting of foam
Power, the difficulty or ease of defoaming.That is, the stability of foam just refers to foam, there are the length in service life.Certainly, study carefully its essence and
Speech, foam is a kind of thermodynamic unstable system, it is impossible to be stablized.Exactly because its this unique property, so that it is being steeped
Foam construction material, foamed plastics, bread medicine controlled releasing, bioengineering, cosmetics, etc. fields be widely used.
However dependence cocinic acid, palmitoleic acid and surface work that the natural soap lye liquid detergent of various brands instantly is excessive
Property agent compounding.There is foam stabilities it is poor, high production cost and oil displacement efficiency are low the problems such as become increasingly conspicuous.Therefore, it develops
A kind of liquid detergent low in cost, that foam stability is good, oil displacement efficiency is high is that have very wide prospect.
Summary of the invention
To solve the above-mentioned problems, the present invention is stablized by the way that soybean oil and surfactant compound are successfully prepared foam
Property it is high, wettability is good, natural soap lye liquid detergent that is being stabilized in high/low temperature so that clothing is being immersed in the water more
Greasy dirt easily is driven, washing efficiency is greatly improved, cost of material and human cost is greatly saved.Therefore, by compounding structure
The research of the natural soap lye liquid detergent of soybean oil type is built with theoretical research and practical value.
The first purpose of the invention is to provide a kind of natural soap lye liquid detergent, the preparation method of the liquid detergent includes:
Soybean oil is placed in water, adds alkali to solution that milky white shape is presented, surfactant is then added, pH value of solution is tuned into neutrality, i.e.,
The natural soap lye liquid detergent of soybean oil type can be made.
In one embodiment of the invention, the mass fraction of soybean oil relative solution is 8%-15%.
In one embodiment of the invention, the mass fraction of soybean oil relative solution preferably 10%.
In one embodiment of the invention, the mass fraction of surfactant relative solution is 8%-15%.
In one embodiment of the invention, the mass fraction of surfactant relative solution preferably 10%.
In one embodiment of the invention, surfactant includes anionic surfactant and/or nonionic table
Face activating agent.
In one embodiment of the invention, anionic surfactant includes sodium sulfate of polyethenoxy ether of fatty alcohol
(AES), neopelex (LAS).
In one embodiment of the invention, nonionic surfactant includes the (AEO- of fatty alcohol polyoxyethylene ether -9
9), cocoyl diglycollic amide (6501).
In one embodiment of the invention, when surfactant includes simultaneously anionic surfactant and nonionic
When surfactant, the mass ratio of anionic surfactant and nonionic surfactant is 1:(1-2).
In one embodiment of the invention, the preparation method of the liquid detergent further include: after pH is adjusted to neutrality, add
Enter preservative, essence, pigment.
In one embodiment of the invention, preservative includes Phenoxyethanol.
In one embodiment of the invention, the preparation method of the liquid detergent specifically includes:
The soybean oil that total mass fraction is 10% is placed in water first, excessive potassium hydroxide is added thereto, makes solution
In alkalinity, at this moment soybean oil can be saponified in water, stir evenly solution present it is milky white；Total mass fraction 5% is added thereto
Sodium sulfate of polyethenoxy ether of fatty alcohol (AES), then into solution be added 5% fatty alcohol polyoxyethylene ether -9 of total mass fraction
(AEO-9) it is put into appropriate citric acid after mixing evenly, pH value of solution is tuned into neutrality；Preservative is placed into, essence and color is added
Element, the natural soap lye liquid detergent of soybean oil type can be prepared by stirring evenly.
In one embodiment of the invention, it rocks soybean oil up and down by tool plug graduated cylinder and accounts for total solution mass fraction and be
7%-15%.
In one embodiment of the invention, by tool plug graduated cylinder up and down rock 15-30 time, after will tool fill in graduated cylinder it is quiet
It sets, and observes foam situation of change.
In one embodiment of the invention, foam measurement method is the tool plug graduated cylinder using 100ml, is put into 10ml's
Mass fraction is the natural soap lye liquid detergent of soybean oil type.
A second object of the present invention is to provide a kind of utilization method of soybean oil, the method is prepared using soybean oil
Obtain above-mentioned natural soap lye liquid detergent.Soybean oil raw material is easy to get, and soybean oil is more by people under social condition instantly
It is edible, it will cause many grease type rubbishes from cooking, such as gutter oil etc..The re-using for realizing soybean oil is that have very greatly
Economic effect and social benefit.
Third object of the present invention is to provide a kind of flooding method, the method is done washing using above-mentioned natural soap lye
Liquid carries out the displacement of reservoir oil.
Fourth object of the present invention is to provide a kind of cleaning method, and the method is done washing using above-mentioned natural soap lye
Liquid is cleaned.
5th purpose of the invention is to have expanded the application category of natural soap lye liquid detergent.
In one embodiment of the invention, the application be applied to environmental area, field of textiles, chemical field,
Prepare drug field, industry cleaning link, household chemicals.
In one embodiment of the invention, the application includes: applied to environmental protection, oilfield exploitation, weaving print
Dye, industry cleaning link, household chemicals.
Beneficial effects of the present invention:
(1) the natural soap lye liquid detergent of soybean oil type of the invention, raw material sources are wide, biorenewable, environmentally protective, biology
Degradability is high, enriches the type for the high-performance natural soap lye liquid detergent that renewable resource is raw material, can be widely used in daily use chemicals
In the research of the clean and industrial oil displacement system of greasy dirt.
(2) present invention, which compounds with soybean oil with nonionic surfactant to obtain the natural soap lye liquid detergent of soybean oil type, matches
Side, in existing foam stabilising system, the liquid detergent foam stabilization efficiency of inventive formulation is higher, natural compared to traditional
Soap lye laundry liquid formulation, the present invention does washing, and liquid preparing process is simple, and oil displacement efficiency is high.
(3) soybean oil raw material of the present invention is easy to get, and soybean oil is eaten by people under social condition instantly, can make
At many grease type rubbishes from cooking, such as gutter oil etc., realize that the re-using of soybean oil is that have very big economic effect
With social benefit.The effective use for realizing soybean oil can reduce to instantly to the dependence of chemical surfactant, energy
It is enough greatly to save human cost.Cost is reduced to 3 yuan/kilogram by 5 original yuan/kilogram, and cost reduces by 40%.
(4) the environmentally protective soybean oil type liquid detergent that the present invention constructs compares other brand liquid detergents with higher bubble
Foam amount and foam stability.Pass through the foam stability for the foam volume verifying that tool plug graduated cylinder is measured.Initial foam volume is up to
85ml, half-life period are up to 120min.The present invention is formed using the hydrogen bond action between the carboxyl and surfactant of soybean oil
Oligomeric structure, hydrophobic volume further increase, and are more likely formed long stable foaming properties system.
(5) soybean oil soap lye liquid detergent of the invention can be widely applied to mineral flotation agent, textile fabric softening agent and
The numerous areas such as antistatic agent and pigment dispersing agent.Product is played in the basic research of Surfactant compound system in the present invention
Pole facilitation.
Detailed description of the invention
Fig. 1 is that the soybean oil type of the present invention natural soap lye laundry liquid system foam curve of stability (includes two kinds of feelings of no greasy dirt
Condition)；
Fig. 2 is that the natural soap lye laundry liquid of soybean oil type of the present invention ties up to foam attenuation curve under condition of different temperatures；
Fig. 3 is compound system of the present invention and the foam situation of change ratio of the natural soap lye liquid detergent of certain brand under the same conditions
Compared with.
Specific embodiment
Embodiment 1: the preparation method of the natural soap lye liquid detergent of soybean oil type
Method is as follows: being first placed in water the soybean oil that total mass fraction is 10%, excessive hydroxide is added thereto
Potassium makes solution alkaline, and at this moment soybean oil can be saponified in water, stirs evenly solution and presents milky white, total matter is added thereto
The sodium sulfate of polyethenoxy ether of fatty alcohol (AES) of score 5% is measured, then 5% fatty alcohol polyoxy of total mass fraction is added into solution
Vinethene -9 (AEO-9) is put into appropriate citric acid after mixing evenly, and pH value of solution is tuned into neutrality, places into Phenoxyethanol anti-corrosion
Essence and pigment is added in agent, and the natural soap lye liquid detergent of soybean oil type can be prepared by stirring evenly.
Liquid detergent cost of material of the present invention is 3 yuan/kilogram, and the cost of material of currently used liquid detergent is 5 yuan/kilogram,
Cost reduces 40%.
Embodiment 2: foam stability can measure
By the tool plug graduated cylinder that foam measurement method is using 100ml, it is put into the solution that the mass fraction of 10ml is 15%.
Tool plug graduated cylinder rocks 15-30 time up and down, after will tool plug graduated cylinder standing, and observe foam situation of change.
By taking the phase homogenous quantities present invention to compound natural two parts of soap lye liquid detergent, 0.5g gasoline is added in portion, another is not
Gasoline is added, is placed in identical experimental provision, at identical conditions, natural soap lye liquid detergent more of the invention is in difference
Greasy dirt situation gas release is compared with half-life period, as a result as shown in Figure 1.The present invention is multiple with soybean oil and nonionic surfactant
With obtaining the natural soap lye laundry liquid formulation of soybean oil type, using the hydrogen bond action between the carboxyl and surfactant of soybean oil,
Oligomeric structure is formed, hydrophobic volume further increases, and is more likely formed long stable foaming properties system.The present invention compounds
To liquid detergent initial foam volume be up to 85ml, half-life period is up to 120min.
Fig. 2 is that the laundry liquid of compounding ties up to foam attenuation curve under condition of different temperatures, and as shown in Figure 2, the present invention washes
Clothing liquid system is also preferable in the foam stability of higher temperature (45 DEG C), and initial foam volume is up to 40ml, and half-life period is up to 4.5
It.
Embodiment 3:
Referring to embodiment 1, the dosage of soybean oil is replaced with into 5% or 25%, two kinds of laundry liquids are prepared respectively
System measures foam volume by tool plug graduated cylinder.Wherein the initial foam volume of liquid detergent obtained by the soybean oil of 5% additive amount is 30ml,
Half-life period is no more than 0.5 day；The initial foam volume of liquid detergent obtained by the soybean oil of 25% additive amount is 80ml, and half-life period is equal
No more than 4.5 days.
Embodiment 4: compared with the natural soap lye liquid detergent foam stability of certain brand
The natural soap lye laundry liquid formulation of certain brand: coconut oil, AES, preservative, pigment.
By the natural soap lye liquid detergent of certain brand and the natural soap lye liquid detergent of compound system of the invention that take phase homogenous quantities
It is placed in identical experimental provision, at identical conditions, with natural soap lye liquid detergent gas release of the invention and half-life period ratio
Compared with, from the figure 3, it may be seen that the soybean oil natural soap liquid foam volume of invention is abundant, long half time.
Reference examples 1:
Referring to embodiment 1, soybean oil is replaced with into coconut oil or palm oil, two kinds of laundry liquids are prepared respectively
System measures foam volume by tool plug graduated cylinder, and the initial foam volume of gained liquid detergent is no more than xx ml, and half-life period is no more than
X days.
Above data explanation, under different greasy dirt situations and condition of different temperatures, which has very good
Frostproof froth n amount and stability property.The surfactant is similar with traditional surfactant, and molecule easily forms cylindric knot
Structure is conducive to surfactant and is self-assembly of foam response Performance-System in aqueous solution.
By the way that soybean oil and surfactant compound to be successfully prepared, foam stability is high, wettability is good, in height
The natural soap lye liquid detergent being stabilized in warm situation greatly improves so that clothing is easier to drive greasy dirt being immersed in the water
Washing efficiency has saved cost of material and human cost.Therefore, the natural soap lye liquid detergent of soybean oil type is constructed by compounding
Research is with theoretical research and practical value.Soybean oil and surfactant pass through hydrogen bond action in aqueous solution, are built into
Oligo surfactant structure.The a plurality of hydrophobic long-chain of the surfactant of the structure forms side by side.Lead to natural soap of the invention
Liquid liquid detergent gas release is mentioned than common liquid detergent has changed three times, this property is considerably less in natural soap lye liquid detergent property
See.
Although the present invention has been described by way of example and in terms of the preferred embodiments, it is not intended to limit the invention, any to be familiar with this skill
The people of art can do various change and modification, therefore protection of the invention without departing from the spirit and scope of the present invention
Range should subject to the definition of the claims.
Claims (10)
1. a kind of natural soap lye liquid detergent, which is characterized in that the preparation method of the liquid detergent includes: that soybean oil is placed in water
In, add alkali to solution that milky white shape is presented, surfactant is then added, pH value of solution is tuned into neutrality, can be prepared by soybean oil type
Natural soap lye liquid detergent.
2. liquid detergent according to claim 1, which is characterized in that the mass fraction of soybean oil relative solution is 8%-
15%.
3. liquid detergent according to claim 1, which is characterized in that the mass fraction of surfactant relative solution is 8%-
15%.
4. liquid detergent according to claim 1 to 3, which is characterized in that the mass fraction of soybean oil relative solution is
10%.
5. liquid detergent according to claim 1 to 3, which is characterized in that the mass fraction of surfactant relative solution
It is 10%.
6. liquid detergent according to claim 1, which is characterized in that surfactant include anionic surfactant and/
Or nonionic surfactant.
7. -5 any liquid detergent according to claim 1, which is characterized in that when surfactant includes simultaneously anion table
When face activating agent and nonionic surfactant, the mass ratio of anionic surfactant and nonionic surfactant is 1:
(1-2)。
8. a kind of utilization method of soybean oil, which is characterized in that the method is that claim 1-7 is prepared using soybean oil
Any natural soap lye liquid detergent.
9. a kind of flooding method, which is characterized in that the method is to utilize the carry out displacement of reservoir oil as claimed in claim 1 to 7.
10. a kind of cleaning method, which is characterized in that the method is described clean using as claimed in claim 1 to 7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910010248.9A CN109929706A (en) | 2019-01-07 | 2019-01-07 | A kind of natural soap lye liquid detergent Performance-System made using green bean oil |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910010248.9A CN109929706A (en) | 2019-01-07 | 2019-01-07 | A kind of natural soap lye liquid detergent Performance-System made using green bean oil |
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| CN109929706A true CN109929706A (en) | 2019-06-25 |
Family
ID=66984986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201910010248.9A Pending CN109929706A (en) | 2019-01-07 | 2019-01-07 | A kind of natural soap lye liquid detergent Performance-System made using green bean oil |
Country Status (1)
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60181200A (en) * | 1984-02-28 | 1985-09-14 | ライオン株式会社 | Stable soap composition |
| CN1240228A (en) * | 1999-07-23 | 2000-01-05 | 李志军 | Multi-function soap liquid detergent and productive process thereof |
| CN104946433A (en) * | 2014-03-26 | 2015-09-30 | 南京健安泊生物技术有限公司 | Method for preparing soap with whitening function |
-
2019
- 2019-01-07 CN CN201910010248.9A patent/CN109929706A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60181200A (en) * | 1984-02-28 | 1985-09-14 | ライオン株式会社 | Stable soap composition |
| CN1240228A (en) * | 1999-07-23 | 2000-01-05 | 李志军 | Multi-function soap liquid detergent and productive process thereof |
| CN104946433A (en) * | 2014-03-26 | 2015-09-30 | 南京健安泊生物技术有限公司 | Method for preparing soap with whitening function |
Non-Patent Citations (1)
| Title |
|---|
| 王迪等: "以大豆油和玉米油为原料的‘液体皂’的制备", 《科技创新导报》 * |
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