A kind of miniature 5G communication base station antenna
Technical field
The present invention relates to a kind of miniature 5G communication base station antennas.
Background technique
With ever-increasing mobile subscriber and terminal quantity, business demand amount also rapid growth, the biography currently disposed
System macro base station can not meet the needs of communication service.The construction of one side macro base station needs a large amount of capital investment, construction
Period is very long, and site resource is limited and addressing requires height.On the other hand, if disposing excessive macro base station, can also to run
The burden of quotient's network optimization and operation greatly improves, or even the possibility for having the network coverage excessive.Conventional macro base station is usually indoors
Ability is weaker in terms of the network coverage, and recently as the continuous improvement of user demand, indoor and outdoor shared by house data flow is whole
But in continuous rise, indoor floating resources seem in such a case more lacks the ratio that body flow uses.In addition, due to
Network terminal user distribution over time and space is simultaneously uneven, this results in telephone traffic flowing indoors and the crowd is dense
Region can cause tidal effect, while propose more stern challenge to conventional macro base station.
Low-power consumption, the small base station easily disposed (Small Cell) just come into being in this case, become improvement hot spot
Network, the effective means for improving network capacity and indoor network coverage.It is easy that small base station mainly has compared to the advantage of macro base station
It disposes, safeguard the advantage low with lower deployment cost simple, small in size, and can easily be changed according to the demand of specific service environment
Become its overlay area.These features make small base station have better network carrying ability.Small base station deployment is covered in macro base station
Lid blind area and hot spot region have the function of improving the network coverage, so that the growing data traffic demand of user obtains
Meet.In addition, small base station shows the characteristics of plug-and-play the small base station being deployed in indoor environment is easily used to terminal
Family provides the network insertion of higher speed, this just largely solves the problems, such as macro base station, and network signal is poor indoors.
Small base station market is emerged in 3G, has been developed rapidly since appearance, present deployment total amount surmounts comprehensively
Macro base station.In in September, 2007, commercialization is realized in the U.S. in small base station first, and henceforth, Britain, Qatar, Spain, meaning are big
Multiple countries such as benefit are also dedicated to the research of small base station and the deployment of small base station are included in planning, by 2009 in multiple countries
It comes into operation with area.Quantity in June, 2011, the interior small base station 3G disposed of global range reaches 2,300,000, has far surpassed and has worked as
When 3G macro base station Quantity (1,600,000).Ended for the end of the year 2012, the deployment quantity of the small base station in the whole world alreadys exceed 6,400,000,
Wherein Sprint communication common carrier in the U.S. has been built in the world more than 900,000, AT&T group's construction more than 600,000,
Japanese Ruan Yin group has also built about 130,000.It is shown, is ended according to the small base station construction in the whole world in 2016 and project report
In October, 2015, the deployment amount of small base station in the world have reached 13,300,000.External associated mechanisms statistics cut-off before this
To the end of the year 2017, the deployment total amount of small base station reaches 91,000,000 in world wide.
Our times various regions are very high for the research and development temperature of 5G technology, and domestic and international each mainstream standard mechanism has all recognized
The urgency developed to 5G technology at this stage, and formulated relevant 5G research and development plan.From 4G to 5G, user demand is constantly mentioned
Height, indoor and outdoor data service are significantly expanded, and carrier frequency also will be promoted significantly, and conventional macro base station seems more and more powerless and answers
Right, in following 5G epoch, small base station will necessarily become mainstream on a large scale.Have in the key technology of 5G one be called it is highly dense
The purpose of technology of networking, its exploitation is exactly to prepare for any wide-area deployment of following 5G epoch small base station, therefore 5G epoch
Arrival can truly drive the explosion type of small base station to dispose.
Small base station distribution closeness is proportional to flow of the people, and the more local number of base stations of flow of the people will be more, adjacent
The distance between base station is smaller.On the wall of building, on electric pole, automobile platform all may become small base station deployment station
Point, therefore how to ensure that the durability of small base station and service life just seem especially important.This requires we study base station,
Not only to have to the basic function for sending the information such as real-time power consumption from the background, also to have good durability and use
In the service life, this is that the following small base station institute is prerequisite.
Chinese patent CN106917085B discloses a kind of communication base station with automatically cleaning and anti-corrosion effects, including base
It stands ontology, which includes substrate and the hydrophobic erosion resistant coating set on substrate surface, which is to pass through cold spraying
Stuff and other stuff is sprayed to substrate surface formation by technology;The base station ontology has good hydrophobic effect, shows as good
Automatically cleaning and antiseptic property.
Chinese patent CN102174234B is disclosed outside a kind of used in base station antenna PVC profile with clean surfaces function
Cover, which not only improves its mechanical performance, and ultraviolet-resistant performance is greatly improved, prior
Be the profile shapes surface can nonpolar moiety significantly improve, cause profile shapes surface water contact angle to significantly improve, hydrophobicity increase
By force, reaching has the function of clean surfaces.Antenna for base station PVC profile outer cover with clean surfaces function of the invention is
Be made of the raw material of following quality proportioning: PVC100 parts, 1~3 part of organic tin stabilizer, polyacrylate toughener 5~
10 parts, 1~3 part of polyacrylate processing aid, 5~10 parts of titanium dioxide, 0~5 part of calcium carbonate, 3~5 parts of calcium stearate,
0.3~1 part of polyethylene wax, 0.2~1.2 part of silicone oil, 0.3~1.2 part of fluorosilicon oil, 0.2~1 part of organic fluoride.
However, above-mentioned patent, which is still unable to satisfy 5G technology, develops the requirement self-cleaning to base station.
Summary of the invention
It is unable to satisfy the 5G technology development requirement self-cleaning to base station in order to solve the prior art, the invention proposes following skills
Art scheme:
A kind of miniature 5G communication base station antenna, comprising: pole, antenna and the upper bracket being separately fixed on the pole and
Lower bracket;The upper bracket is located at the top of the lower bracket;The upper end of the antenna is connect with the upper bracket;The antenna
Lower end connect with the lower bracket;The antenna includes outer cover and the line plate positioned at the outer cover.
The shroud surface is coated with hydrophobic self-cleaning material, and the hydrophobic self-cleaning material includes following component: 100 weights
Part deionized water, 30~40 parts by weight propylene acid resins are measured, 10~20 parts by weight organic materials coat silver/titanium dioxide composite wood
Material, 15~25 parts by weight Emulsifier, the emulsifier is by Sodium Dodecyl Allyl Sulfosuccinate and dodecyl hydroxyl
Sulfobetaines is 1:1 mixing composition by weight.
The preparation process of the organic material coated with silver/composite titania material includes the following steps:
30~40 parts by weight pyrrole monomers and 130~150 parts by weight distilled water are placed in a beaker by S1, sequentially add 5~
10 parts by weight of titanium dioxide, 5~10 parts by weight silver nitrates and 20~30 parts by weight compound A form B mixed liquor;
20~30 parts by weight ferric nitrates, 1~3 parts by weight sodium bromide are dissolved in 130~150 parts by weight distilled water by S2, shape
At C solution;
C solution and B solution are mixed to get solution D by S3, and the solution D is stirred to react 2~3h in 70~80 DEG C;
S3 products therefrom is centrifuged, precipitates by S4, and washing to supernatant is colourless;
Precipitating obtained by S4 is put into vacuum drying oven by S5, dry 12~15h at 60~70 DEG C, ground, calcination process,
Obtain organic material coated with silver/composite titania material.
The structural formula of the compound A is as follows:
The hydrophobic self-cleaning material is fixed in shroud surface by the way of spraying, and spraying process includes following step
It is rapid: hydrophobic self-cleaning material being added in spray gun, is being sprayed at shroud surface 30cm, the outer cover sprayed is placed on completely
Hyperbaric environment under solidify, the pressure of the hyperbaric environment is 0.5MPa.
Technical solution of the present invention has as follows by beneficial effect:
(1) in the hydrophobic self-cleaning material of shroud surface coating of miniature 5G communication base station antenna, hydrophobic self-cleaning material
Containing organic material coated with silver/composite titania material, oneself of outer cover is realized in the photocatalysis that can use composite material
Cleaning.
(2) it can be risen by introducing compound A in organic material coated with silver/composite titania material preparation process
To bridge beam action, polypyrrole can be made more closely to be coated on the surface of silver/titanium dioxide, substantially increase composite material
Hydrophobic performance, finally realize self-cleaning effect.
(3) by introducing Sodium Dodecyl Allyl Sulfosuccinate and dodecyl hydroxyl in hydrophobic self-cleaning material
Base sulfobetaines compound emulsifying agent can greatly improve organic material coated with silver/composite titania material emulsifying effectiveness,
And emulsifying effectiveness is better than the single emulsifier of same amount, can make organic material coated with silver/composite titania material distribution
More uniformly.
(4) outer cover sprayed is placed on to solidification under clean hyperbaric environment can greatly improve hydrophobic self-cleaning material
Solidification effect, and then the whole hydrophobic performance for improving outer cover finally realizes self-cleaning effect.
(5) miniature 5G communication base station antenna self-cleaning effect with higher of the invention can utilize higher hydrophobic material
Material realizes that water droplet is freely rolled in hydrophobic surface, can take away dust and particle during tumbling, can for a long time outdoors
It uses, reduces outer cover significantly and dust is adhered to, it is easy to operate, it is at low cost, it can satisfy the needs of 5G communication.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments and comparative example,
The present invention will be described in further detail.
Embodiment 1
A kind of miniature 5G communication base station antenna, comprising: pole, antenna and the upper bracket being separately fixed on the pole and
Lower bracket;The upper bracket is located at the top of the lower bracket;The upper end of the antenna is connect with the upper bracket;The antenna
Lower end connect with the lower bracket;The antenna includes outer cover and the line plate positioned at the outer cover.
The shroud surface is coated with hydrophobic self-cleaning material, and the hydrophobic self-cleaning material includes following component: 100 weights
Measure part deionized water, 30 parts by weight propylene acid resins, 10 parts by weight organic material coated with silver/composite titania material, 15 weights
Part emulsifier is measured, the emulsifier is pressed by Sodium Dodecyl Allyl Sulfosuccinate and dodecyl hydroxyl sulfo betaine
Weight ratio is 1:1 mixing composition.
The preparation process of the organic material coated with silver/composite titania material includes the following steps:
30 parts by weight pyrrole monomers and 130 parts by weight distilled water are placed in a beaker by S1, sequentially add 5 parts by weight titanium dioxides
Titanium, 5 parts by weight silver nitrates and 20 parts by weight compound A form B mixed liquor;
20 parts by weight ferric nitrates, 1 parts by weight sodium bromide are dissolved in 130 parts by weight distilled water by S2, form C solution;
C solution and B solution are mixed to get solution D by S3, and the solution D is stirred to react 2h in 70 DEG C;
S3 products therefrom is centrifuged, precipitates by S4, and washing to supernatant is colourless;
Precipitating obtained by S4 is put into vacuum drying oven by S5, and dry 12h, ground, calcination process obtain organic at 60 DEG C
Material coated with silver/composite titania material.
The structural formula of the compound A is as follows:
The hydrophobic self-cleaning material is fixed in shroud surface by the way of spraying, and spraying process includes following step
It is rapid: hydrophobic self-cleaning material being added in spray gun, is being sprayed at shroud surface 30cm, the outer cover sprayed is placed on completely
Hyperbaric environment under solidify, the pressure of the hyperbaric environment is 0.5MPa.
Embodiment 2
A kind of miniature 5G communication base station antenna, comprising: pole, antenna and the upper bracket being separately fixed on the pole and
Lower bracket;The upper bracket is located at the top of the lower bracket;The upper end of the antenna is connect with the upper bracket;The antenna
Lower end connect with the lower bracket;The antenna includes outer cover and the line plate positioned at the outer cover.
The shroud surface is coated with hydrophobic self-cleaning material, and the hydrophobic self-cleaning material includes following component: 100 weights
Measure part deionized water, 35 parts by weight propylene acid resins, 15 parts by weight organic material coated with silver/composite titania material, 20 weights
Part emulsifier is measured, the emulsifier is pressed by Sodium Dodecyl Allyl Sulfosuccinate and dodecyl hydroxyl sulfo betaine
Weight ratio is 1:1 mixing composition.
The preparation process of the organic material coated with silver/composite titania material includes the following steps:
35 parts by weight pyrrole monomers and 140 parts by weight distilled water are placed in a beaker by S1, sequentially add 8 parts by weight titanium dioxides
Titanium, 8 parts by weight silver nitrates and 25 parts by weight compound A form B mixed liquor;
25 parts by weight ferric nitrates, 2 parts by weight sodium bromides are dissolved in 140 parts by weight distilled water by S2, form C solution;
C solution and B solution are mixed to get solution D by S3, and the solution D is stirred to react 2.5h in 75 DEG C;
S3 products therefrom is centrifuged, precipitates by S4, and washing to supernatant is colourless;
Precipitating obtained by S4 is put into vacuum drying oven by S5, and dry 13h, ground, calcination process obtain organic at 65 DEG C
Material coated with silver/composite titania material.
The structural formula of the compound A is as follows:
The hydrophobic self-cleaning material is fixed in shroud surface by the way of spraying, and spraying process includes following step
It is rapid: hydrophobic self-cleaning material being added in spray gun, is being sprayed at shroud surface 30cm, the outer cover sprayed is placed on completely
Hyperbaric environment under solidify, the pressure of the hyperbaric environment is 0.5MPa.
Embodiment 3
A kind of miniature 5G communication base station antenna, comprising: pole, antenna and the upper bracket being separately fixed on the pole and
Lower bracket;The upper bracket is located at the top of the lower bracket;The upper end of the antenna is connect with the upper bracket;The antenna
Lower end connect with the lower bracket;The antenna includes outer cover and the line plate positioned at the outer cover.
The shroud surface is coated with hydrophobic self-cleaning material, and the hydrophobic self-cleaning material includes following component: 100 weights
Measure part deionized water, 40 parts by weight propylene acid resins, 20 parts by weight organic material coated with silver/composite titania material, 25 weights
Part emulsifier is measured, the emulsifier is pressed by Sodium Dodecyl Allyl Sulfosuccinate and dodecyl hydroxyl sulfo betaine
Weight ratio is 1:1 mixing composition.
The preparation process of the organic material coated with silver/composite titania material includes the following steps:
40 parts by weight pyrrole monomers and 150 parts by weight distilled water are placed in a beaker by S1, sequentially add 10 parts by weight dioxies
Change titanium, 10 parts by weight silver nitrates and 30 parts by weight compound A, forms B mixed liquor;
30 parts by weight ferric nitrates, 3 parts by weight sodium bromides are dissolved in 150 parts by weight distilled water by S2, form C solution;
C solution and B solution are mixed to get solution D by S3, and the solution D is stirred to react 3h in 80 DEG C;
S3 products therefrom is centrifuged, precipitates by S4, and washing to supernatant is colourless;
Precipitating obtained by S4 is put into vacuum drying oven by S5, and dry 15h, ground, calcination process obtain organic at 70 DEG C
Material coated with silver/composite titania material.
The structural formula of the compound A is as follows:
The hydrophobic self-cleaning material is fixed in shroud surface by the way of spraying, and spraying process includes following step
It is rapid: hydrophobic self-cleaning material being added in spray gun, is being sprayed at shroud surface 30cm, the outer cover sprayed is placed on completely
Hyperbaric environment under solidify, the pressure of the hyperbaric environment is 0.5MPa.
Comparative example 1
Emulsifier is only Sodium Dodecyl Allyl Sulfosuccinate in comparative example 1, and other contents and embodiment 1 are complete
Unanimously.
Comparative example 2
Emulsifier is only dodecyl hydroxyl sulfo betaine in comparative example 2, and other contents and embodiment 1 are completely the same.
Comparative example 3
It is not added with compound A in organic material coated with silver/composite titania material preparation process in comparative example 3,
Its content and embodiment 1 are completely the same.
Comparative example 4
The pressure of 4 mesohigh environment of comparative example is atmospheric pressure environment (i.e. 0.1MPa), other contents and embodiment 1 complete one
It causes.
Characterization result: the outer cover being prepared in embodiment 2 and comparative example 1~4 is subjected to water contact angle detection, detection knot
Fruit is as follows:
The above results show: miniature 5G communication base station antenna self-cleaning effect with higher of the invention, can utilize compared with
High hydrophobic material realizes that water droplet is freely rolled in hydrophobic surface, can take away dust and particle during tumbling, can be with
It uses outdoors for a long time, reduces outer cover significantly and dust is adhered to, it is easy to operate, it is at low cost, it can satisfy the need of 5G communication
It wants.