CN109921062A - A kind of fuel cell gas-liquid separator - Google Patents

A kind of fuel cell gas-liquid separator Download PDF

Info

Publication number
CN109921062A
CN109921062A CN201711325748.9A CN201711325748A CN109921062A CN 109921062 A CN109921062 A CN 109921062A CN 201711325748 A CN201711325748 A CN 201711325748A CN 109921062 A CN109921062 A CN 109921062A
Authority
CN
China
Prior art keywords
gas
chamber
liquid
mixed media
liquid mixed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201711325748.9A
Other languages
Chinese (zh)
Other versions
CN109921062B (en
Inventor
孙海
张盟
孙公权
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dalian Institute of Chemical Physics of CAS
Original Assignee
Dalian Institute of Chemical Physics of CAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dalian Institute of Chemical Physics of CAS filed Critical Dalian Institute of Chemical Physics of CAS
Priority to CN201711325748.9A priority Critical patent/CN109921062B/en
Publication of CN109921062A publication Critical patent/CN109921062A/en
Application granted granted Critical
Publication of CN109921062B publication Critical patent/CN109921062B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Fuel Cell (AREA)

Abstract

The present invention is a kind of small-sized gas-liquid separator of fuel cell, and centrifuge separation principle of the invention, water droplet moves in a circle in mosquito-repellent incense coil pipe, generates the sedimentation acceleration of big 400 times of principle of force of gravity sedimentation, and gas-liquid separation effect is good.Gas-liquid mixed media cooling gas passes through snakelike chamber, hits wall surface at the serpentine channel place of turning back, effectively deposits, improve water recovery efficiency.

Description

A kind of fuel cell gas-liquid separator
Technical field
The invention belongs to the innovative technologies of fuel cell component.Specifically, belong to methanol fuel cell gas-liquid separator Innovative technology.
Background technique
Currently, many advantages, such as methanol fuel cell is high, pollution-free with its energy conversion efficiency, low noise becomes New Energy Source research hotspot.Methanol fuel cell because its can be used for field encamp, vehicle power supply and off-network power generation etc. functions, market prospects can It sees.
Volume minimization is the target of fuel cell system optimization always, in addition to efficiently using space, internal system component Miniaturization be Mobile fuel battery " weight reducing " basic solution route.Currently, methanol fuel cell gas more than hectowatt grade Liquid/gas separator volume is big, and reason is that it, by Gravity Separation principle, needs longer droplet settling distance.Gas-liquid separator is The indispensable important component of methanol fuel cell water management, but it is excellent by the gas-liquid separator volume of Gravity Separation principle Change limited potential, hinders the further compression volume of methanol fuel cell mobile power station.
Gas-liquid separator by Gravity Separation principle is to have had both gas-liquid separation and water two kinds of functions of recycling, and the present invention will The two is decomposed, and two parts are formed, and front end uses centrifugal gas-liquid separation principle, not only the gas-liquid separator of force of gravity separation principle It reduces space and enhances gas-liquid separating function, form an entirety with rear end water recovery section, reduce system integration body Product, breaches system bulk specific power bottleneck.Heated base is arranged in water recycling box bottom end in the present invention, and it is fast to realize fuel cell Fast startup function.
Summary of the invention
The purpose of the present invention is to provide a kind of small-sized gas-liquid separators of use for methanol fuel cells, and the separator volume is small, Gas-liquid separation effect is preferable;Be installed on Proton Exchange Membrane Fuel Cells, can effective recycle-water, improve fuel cell water management energy Power.
The present invention is realized by following proposal.Separator main body structure is with polyetherimide or other resistance to first The engineering plastics of alcohol corrosion are raw material, are realized using engraving technology and technique for sticking, and water recycling box upper layer is gas-liquid mixed media Chamber, inner wall paste polydimethylsiloxanefilm film or the hydrophobic material of other resistance to 80 degree of high temperature.
Structure of the invention is as follows:
A kind of small-sized gas-liquid separator of fuel cell, including water recycling box are an airtight chamber, set in water recycling box There are a lateral partitions, for lateral partitions by water recycling box respectively at upper and lower two airtight chamber, upper chamber is gas-liquid mixed media Chamber, lower chamber are solution cavity;
It is equipped with the import of gas-liquid mixed media chamber and gas vent in the side wall surface of gas-liquid mixed media chamber, in gas-liquid mixed It is equipped between import and gas vent in dielectric cavity and increases gas-liquid mixed media from import to the vertical of gas vent flow channel length Plate;
It is equipped with through-hole in lateral partitions, the down going channel as solution cavity;
Solution outlet is equipped in solution cavity;Solution cavity top and gas-liquid mixed media chamber top pass through pipeline connection.
Further include a mosquito-repellent incense coil pipe, is by a center of circle by a round tube in disk annular in shape from inside to outside in same plane Around or round tube coil in the shape of a spiral from bottom to top along an axis;The import of gas-liquid mixed media chamber is leaned on coiling round tube annular in shape The round tube port of nearly the center point or the round tube lower port coiled in the shape of a spiral are connected.
Vertical plate is 2 or more, vertical plate upper surface with gas-liquid mixed media chamber upper wall surface is closed amplexiforms or connect, Vertical plate lower end surface with lateral partitions upper surface is closed amplexiforms or connect, one side end face of vertical plate and gas-liquid mixed media One side surface of chamber side wall surface or another vertical plate is closed to be amplexiformed or connects, and labyrinth type serpentine channel is formed.
It is equipped with heated base in solution cavity bottom, is equipped with electrical heating elements in heated base.
1. mosquito-repellent incense coil pipe import of the present invention connects with fuel cell heat sink outlet, gas-liquid mixed media is logical in mosquito-repellent incense coil pipe Road makes rotating motion, and the sinking speed of water droplet isAnd gravity settling velocity isThe sedimentation acceleration of water droplet isGravitational settling acceleration is g, the sedimentation of water droplet in mosquito-repellent incense coil pipe Speed is more order of magnitude greater than gravity settling velocity, and the sedimentation acceleration ratio gravitational settling acceleration of water droplet is big by two in mosquito-repellent incense coil pipe A order of magnitude, therefore the separative efficiency of mosquito-repellent incense coil pipe is higher, required settlement space is smaller.
2. mosquito-repellent incense coil outlets are that the import of gas-liquid mixed media chamber connects with the water recycling box upper layer of rear end, gas-liquid is entered The drop particle diameter of blending agent chamber is larger, and droplet collision labyrinth type serpentine channel is turned back place, is slipped to along wall surface towards solution cavity Down going channel, realize effective recycling of water.
3. water recycling box upper layer is that gas-liquid mixed media cavity wall pastes polydimethylsiloxanefilm film or other resistance to 80 degree The hydrophobic material of high temperature, this is conducive to water droplet and slides along wall surface, improves water recovery efficiency.Separator main body structure is with polyethers acyl Imines or the engineering plastics of other methanol tolerants corrosion are raw material, guarantee the durability and reliability that water segregator uses.
4. the methanol solution of pile anode export is passed through lower layer's solution cavity, Way in is parallel to solution cavity plane, avoids Impact for liquid level of solution, setting export pipeline extend to minimum liquid level or less and solution are sucked out.
5. gas-liquid mixed media chamber height is unsuitable too low, otherwise sectional area is too small can make gas flow rate too fast, be unfavorable for liquid The sedimentation of drop;Methanol solution chamber height is unsuitable too low, and otherwise methanol solution chamber air pressure fluctuation easily causes methanol solution to overflow in gas-liquid Blending agent chamber.
6. air pressure connection interface is arranged in gas-liquid mixed media chamber and solution cavity, for balancing pressure.Gas-liquid mixed media chamber It will cause solution with solution cavity pressure imbalance to overflow in gas-liquid mixed media chamber.
7. heated base is arranged in water recycling box bottom end, it is used for heating methanol solution, heating function to be switched in fuel cell When use, realize fuel cell quick start function.
Beneficial effects of the present invention are as follows:
1. separating effect of the invention have passed through the simulation analysis verifying of Fluid Mechanics Computation method, water droplet is in mosquito-repellent incense coil pipe Inside move in a circle, generate force of gravity and settle big 400 times of principle of sedimentation acceleration, analog result as shown in figure 4, liquid water by In the outer diameter zone flowing for acting on pipeline of centrifugal force, gas-liquid separation effect is good.
2. the emulation that the motion state of water recycling box gas-liquid mixed media of the invention have passed through Fluid Mechanics Computation method Analysis verifying, such as Fig. 5, gas-liquid mixed media cooling gas pass through snakelike chamber, hit wall surface, speed at the serpentine channel place of turning back It reduces, water droplet enters down going channel along wall surface, and extends water droplet in the residence time of water recycling box, improves water recovery efficiency.
3. heated base is arranged in water recycling box bottom end, fuel cell quick start function is realized, through test 10 minutes Within, complete the start-up course of fuel cell.
Detailed description of the invention
Fig. 1 water segregator overall diagram
Fig. 2 water segregator lateral sectional view
Fig. 3 water segregator gas-liquid mixed media chamber top cross-sectional view
Fig. 4 mosquito repellent coil disc intraluminal fluid phase distribution map
Fig. 5 gas-liquid mixed media chamber velocity contour
Appended drawing reference in Fig. 1,2 and 3 are as follows: 1. mosquito-repellent incense coil pipes;2. water recycling box;3. gas-liquid mixed media chamber;4. solution Chamber;5. labyrinth type serpentine channel;6. the down going channel of solution cavity;7. gas-liquid mixed media chamber import;8. heated base.
Specific embodiment
Embodiment
1. separator main body structure using polyetherimide as raw material, is completed using engraving technology and technique for sticking, water recycling Box upper layer is that gas-liquid mixed media cavity wall pastes polydimethylsiloxanefilm film, water recycling box bottom end heated base stainless steel 316L material.
2. cyclone separator arrangement is divided into two parts, gas-liquid mixed media passes through centrifugation mosquito-repellent incense coil pipe (1) channel in front end, in rear end By water recycling box (2);It is import that mosquito-repellent incense coil pipe (1) most outer ring, which extends mouth, is connected with fuel cell heat sink outlet, innermost ring Extending mouth is that outlet connects with water recycling box (2) import of rear end, and 5mm was arranged in caliber, around 5 weeks;Water recycling box (2) point is up and down Two layers of chamber, upper layer are gas-liquid mixed media chamber (3), and lower layer is solution cavity (4);It is snakelike that labyrinth type is arranged in gas-liquid mixed media chamber 4 partitions are arranged in channel (5), and at the serpentine channel place of turning back, setting is passed through the down going channel (6) of solution cavity, gas-liquid mixed media Chamber import (7) is oriented parallel to gas-liquid mixed media chamber (3) plane;The methanol solution of pile anode export is passed through lower layer's solution cavity (4), solution cavity Way in is parallel to solution cavity (4) plane, and solution cavity export direction is perpendicular to solution cavity plane, setting outlet Solution is sucked out in pipeline at low liquid level;Air pressure connection interface is arranged in gas-liquid mixed media chamber (3) and solution cavity (4), for balancing Pressure.Heated base (8) are set in water recycling box bottom end, pedestal makes of Stainless steel 316 L, and 5 heating rod pipelines are arranged.

Claims (4)

1. a kind of fuel cell gas-liquid separator, it is characterised in that: including water recycling box, be an airtight chamber, recycled in water A lateral partitions are equipped in box, for lateral partitions by water recycling box respectively at upper and lower two airtight chamber, upper chamber is mixed for gas-liquid Dielectric cavity is closed, lower chamber is solution cavity;
It is equipped with the import of gas-liquid mixed media chamber and gas vent in the side wall surface of gas-liquid mixed media chamber, in gas-liquid mixed media The vertical plate for increasing gas-liquid mixed media from import to gas vent flow channel length is equipped between intracavitary import and gas vent;
It is equipped with through-hole in lateral partitions, the down going channel as solution cavity;
Solution outlet is equipped in solution cavity;Solution cavity top and gas-liquid mixed media chamber top pass through pipeline connection.
2. according to gas-liquid separator described in claim 1, it is characterised in that: further include a mosquito-repellent incense coil pipe, be by a round tube by One center of circle is in coiling annular in shape or round tube are coiled along an axis in the shape of a spiral from bottom to top from inside to outside in same plane;Gas Liquid blending agent chamber import and coiling round tube annular in shape are close to the round tube port of the center point or in the shape of a spiral under the round tube that coils Port is connected.
3. according to gas-liquid separator described in claim 1, it is characterised in that: the vertical plate is 2 or more, on vertical plate End face with gas-liquid mixed media chamber upper wall surface is closed amplexiforms or connect, vertical plate lower end surface and the closed patch in lateral partitions upper surface It connects or connects, one side end face of vertical plate and a side surface of gas-liquid mixed media chamber side wall surface or another vertical plate are closed It amplexiforms or connects, form labyrinth type serpentine channel.
4. according to gas-liquid separator described in claim 1, it is characterised in that: be equipped with heated base in solution cavity bottom, heat bottom Electrical heating elements are equipped in seat.
CN201711325748.9A 2017-12-13 2017-12-13 Gas-liquid separator for fuel cell Active CN109921062B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711325748.9A CN109921062B (en) 2017-12-13 2017-12-13 Gas-liquid separator for fuel cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711325748.9A CN109921062B (en) 2017-12-13 2017-12-13 Gas-liquid separator for fuel cell

Publications (2)

Publication Number Publication Date
CN109921062A true CN109921062A (en) 2019-06-21
CN109921062B CN109921062B (en) 2021-07-06

Family

ID=66958331

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711325748.9A Active CN109921062B (en) 2017-12-13 2017-12-13 Gas-liquid separator for fuel cell

Country Status (1)

Country Link
CN (1) CN109921062B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113161583A (en) * 2021-03-30 2021-07-23 中通客车股份有限公司 Method and system for evaluating performance of fuel cell steam-water separator
CN114497628A (en) * 2022-01-25 2022-05-13 中山大洋电机股份有限公司 Fuel cell system

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100092818A1 (en) * 2008-10-15 2010-04-15 Samsung Electro-Mechanics Co., Ltd. Gas-liquid separator, hydrogen generating apparatus, and fuel cell generation system having the same
CN101997127A (en) * 2009-08-21 2011-03-30 中国科学院大连化学物理研究所 Gas-liquid separator used for directly liquid feeding fuel battery system
CN103240188A (en) * 2012-02-13 2013-08-14 巴莱诺斯清洁能源控股公司 Inertial separator for gas liquid separation
CN103657313A (en) * 2013-11-30 2014-03-26 成都科盛石油科技有限公司 Gas-liquid separator
CN103894019A (en) * 2012-12-26 2014-07-02 现代摩比斯株式会社 Gas-liquid separation device used for fuel battery and fuel battery system
CN104667584A (en) * 2015-02-12 2015-06-03 浙江大学 Spiral type gas-liquid separator under micro-gravity based on porous material
DE102014016963A1 (en) * 2014-11-18 2016-05-19 Daimler Ag Water separator in centrifugal design
CN105642453A (en) * 2016-03-23 2016-06-08 北京航天动力研究所 High-pressure high-flow microgravity centrifugal gas and liquid separation device
CN106898801A (en) * 2015-12-18 2017-06-27 中国科学院大连化学物理研究所 A kind of gas-liquid separator for direct liquid feed fuel cell system
CN106898800A (en) * 2015-12-21 2017-06-27 中国科学院大连化学物理研究所 A kind of minitype radiator and fuel cell system with gas-liquid separating function

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100092818A1 (en) * 2008-10-15 2010-04-15 Samsung Electro-Mechanics Co., Ltd. Gas-liquid separator, hydrogen generating apparatus, and fuel cell generation system having the same
CN101997127A (en) * 2009-08-21 2011-03-30 中国科学院大连化学物理研究所 Gas-liquid separator used for directly liquid feeding fuel battery system
CN103240188A (en) * 2012-02-13 2013-08-14 巴莱诺斯清洁能源控股公司 Inertial separator for gas liquid separation
CN103894019A (en) * 2012-12-26 2014-07-02 现代摩比斯株式会社 Gas-liquid separation device used for fuel battery and fuel battery system
CN103657313A (en) * 2013-11-30 2014-03-26 成都科盛石油科技有限公司 Gas-liquid separator
DE102014016963A1 (en) * 2014-11-18 2016-05-19 Daimler Ag Water separator in centrifugal design
CN104667584A (en) * 2015-02-12 2015-06-03 浙江大学 Spiral type gas-liquid separator under micro-gravity based on porous material
CN106898801A (en) * 2015-12-18 2017-06-27 中国科学院大连化学物理研究所 A kind of gas-liquid separator for direct liquid feed fuel cell system
CN106898800A (en) * 2015-12-21 2017-06-27 中国科学院大连化学物理研究所 A kind of minitype radiator and fuel cell system with gas-liquid separating function
CN105642453A (en) * 2016-03-23 2016-06-08 北京航天动力研究所 High-pressure high-flow microgravity centrifugal gas and liquid separation device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113161583A (en) * 2021-03-30 2021-07-23 中通客车股份有限公司 Method and system for evaluating performance of fuel cell steam-water separator
CN114497628A (en) * 2022-01-25 2022-05-13 中山大洋电机股份有限公司 Fuel cell system
CN114497628B (en) * 2022-01-25 2024-01-05 中山大洋电机股份有限公司 Fuel cell system

Also Published As

Publication number Publication date
CN109921062B (en) 2021-07-06

Similar Documents

Publication Publication Date Title
CN103566698B (en) Gas-liquid-solid three-phase separator
CN203577481U (en) Separator
CN109921062A (en) A kind of fuel cell gas-liquid separator
CN103894004B (en) Mass dryness fraction distributor and the methods such as a kind of novel gas-liquid two-phase fluid
CN102967095A (en) Variable volume high-efficiency vertical oil separator for refrigeration compressor testing device
CN201363134Y (en) Oil and gas separation integrated device
CN102671502A (en) Gas-liquid inertia separation and distribution coupling unit and separator adopting same
CN109622251A (en) A kind of pipe separator
CN106898800B (en) A kind of minitype radiator and fuel cell system with gas-liquid separating function
CN202427267U (en) Gas-liquid separating device
CN102463006A (en) Oil-gas separator
CN202250025U (en) Spiral gas anchor
CN203400581U (en) Gas-liquid separator used for cooling system of vehicle
CN207116557U (en) A kind of battery modules shell of high safety performance
CN205592049U (en) Novel electricity spouts filter
CN104324528B (en) A kind of fountain moisture separator
CN202438213U (en) Spherical steam-water separator
CN211896038U (en) System for generating ozone by utilizing liquid oxygen and liquefying and separating
CN102872657B (en) Gas-liquid separating device
CN207499861U (en) A kind of gs-oil separator of secondary separation
CN107670338B (en) Outward flow type air eliminator
CN204193572U (en) A kind of fountain moisture separator
CN103736325B (en) Collision type moist steam vehicle repair major is separated pretreating device
CN220238044U (en) Steam-water separator for hydrogen fuel cell and fuel cell system
CN220939618U (en) Hydrogen tail gas steam-water separator of centrifugal hydrogen-oxygen fuel cell

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant