CN109920869A - Contain silane coupling agent photovoltaic module back side performance protective film and preparation method thereof - Google Patents

Contain silane coupling agent photovoltaic module back side performance protective film and preparation method thereof Download PDF

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Publication number
CN109920869A
CN109920869A CN201910148400.XA CN201910148400A CN109920869A CN 109920869 A CN109920869 A CN 109920869A CN 201910148400 A CN201910148400 A CN 201910148400A CN 109920869 A CN109920869 A CN 109920869A
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protective film
photovoltaic module
film
module back
back side
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CN201910148400.XA
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CN109920869B (en
Inventor
汪惠琴
马万升
谢桂枝
代荣
程鹏飞
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Mount Huangshan Tianma New Mstar Technology Ltd
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Mount Huangshan Tianma New Mstar Technology Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Processes Of Treating Macromolecular Substances (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The invention discloses contain silane coupling agent photovoltaic module back side performance protective film and preparation method thereof; the raw material of the protective film includes: natural rubber 85%-95%, polyolefin plastomers resin 3%-5%, ethylene-vinyl acetate copolymer 5%-8% and polyethylene 2%-5% by weight; S1, first confirm that whether workshop condition, raw material, raw material pot, molten liquid whisking machines and high-low pressure inflation film manufacturing machine are clean; it is whether all qualified without residue and personal hygiene and protection facility;The present invention relates to performance protective film technical fields.Silane coupling agent photovoltaic module back side performance protective film and preparation method thereof should be contained; it is shorter to solve existing photovoltaic module back protection film service life; and it is prone to wear; preferably photovoltaic module cannot be protected when use; due to long-time sunshine and high temperature; photovoltaic module back protection film can be damaged, tissue occurs, and generate gas bag when existing back protection film use, use inconvenient problem.

Description

Contain silane coupling agent photovoltaic module back side performance protective film and preparation method thereof
Technical field
The present invention relates to performance protective film technical fields, specially contain silane coupling agent photovoltaic module back side high-performance Protective film and preparation method thereof.
Background technique
Protective film can be divided into protective film for digital product, protection film for automobile, household protective film, food fresh keeping guarantor according to purposes Cuticula etc..As the digital products such as mobile phone are in the universal of China, a kind of system as screen protecting film of protective film slowly Claim, and its function in screen protecting film field is also multifarious.AR material of the material from earliest PP material to popular Matter, centre experienced development more than 5 years, being received by vast mobile phone group slowly.Protective film functionally say be will be to me A tunic is put outside claimed physical item.Have AR T-coating, AG frosted anti-reflective film, Mobile phone mirror in present society Sub- film, peep-proof film, the functional forms protective film such as high definition preventing from scraping film.When main screen backlight extinguishes, protective film plays the role of mirror. Writings and image can normally be shown by film when back light is opened.Film is divided into 5~6 layers, and has carried out aluminium to wherein one layer Vapor deposition treatment.Extraneous light, Lai Shixian mirror function are reflected using this layer.Protective film by application range point, can be applicable to Under some fields: metal product surface, coating metal product surface, plastic product surface, automobile product surface, electronic product table Face, label product surface, product forms surface and other product surfaces.
Existing photovoltaic module back protection film service life is shorter, and is prone to wear, cannot be preferably right when use Photovoltaic module is protected, and due to long-time sunshine and high temperature, can damage photovoltaic module back protection film and tissue, Er Qiexian occurs Gas bag is generated when some back protection film uses, uses inconvenience.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides contain silane coupling agent photovoltaic module back side performance protective film And preparation method thereof, it is shorter to solve existing photovoltaic module back protection film service life, and be prone to wear, when use not Preferably photovoltaic module can be protected, due to long-time sunshine and high temperature, the generation of photovoltaic module back protection film can be damaged Tissue, and gas bag is generated when existing back protection film use, use inconvenient problem.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs: containing silane coupling agent photovoltaic module Back side performance protective film, including protective film and photovoltaic panel are fixedly connected with protective film, the protection at the top of the photovoltaic panel The raw material of film includes: natural rubber 85%-95%, polyolefin plastomers resin 3%-5%, ethyl vinyl acetate second by weight Alkene copolymer 5%-8% and polyethylene 2%-5%.
Preferably, the raw material includes: natural rubber 85%, polyolefin plastomers resin 3%, ethylene-vinegar by weight Sour ethylene copolymer 7% and polyethylene 5%.
Preferably, the raw material includes: natural rubber 87%, polyolefin plastomers resin 4%, ethylene-vinegar by weight Sour ethylene copolymer 7% and polyethylene 5%.
Preferably, the raw material includes: natural rubber 86%, polyolefin plastomers resin 4%, ethylene-vinegar by weight Sour ethylene copolymer 6% and polyethylene 4%.
Preferably, the raw material includes: natural rubber 90%, polyolefin plastomers resin 3%, ethylene-vinegar by weight Sour ethylene copolymer 5% and polyethylene 2%.
Preferably, the natural rubber is guayule, be made after being solidified, being dried by guayule when use, and And it is ground into graininess.
Preferably, the ethylene-vinyl acetate copolymer and polyethylene are granular material, when being processed, are needed Carry out anaerobic thawing after carry out again using.
The invention also discloses the preparation methods containing silane coupling agent photovoltaic module back side performance protective film, specific to wrap Include following steps:
S1, first confirm that whether workshop condition, raw material, raw material pot, molten liquid whisking machines and high-low pressure inflation film manufacturing machine are clean, It is whether all qualified without residue and personal hygiene and protection facility;
S2, raw material accurately then weighed up according to the weight of each formula to be chosen, and posts label, Marked Weight, Title and code;
S3, then staff can put at normal temperature natural rubber particle in the raw material pot got ready, start blender It is stirred under the revolving speed of 40-60r/min, and remains unchanged mixing speed, sequentially add polyolefin plastomers resin, ethylene- Acetate ethylene copolymer, polyethylene, suitable OPP stir 10-15min;
S4, it discharges later, by discharging investment molten liquid whisking machines, carries out anaerobic melting, temperature control is existed 400 DEG C -600 DEG C, mixing speed 60r-100r/min;
After the completion of S5, melting, molten liquid is flowed in high-low pressure inflation film manufacturing machine by diversion pipe, carries out blown film;
When S6, blown film, initial survey is carried out, first is detected by the protective film of high-low pressure inflation film manufacturing machine produced, Then determine whether to continue blown film;
After S7, initial survey complete qualification, continual production is carried out, the protective film of production is crispaturaed by film rolling mechanism On reel, the product inspection after packaging is put in storage.
(3) beneficial effect
The present invention provides contain silane coupling agent photovoltaic module back side performance protective film and preparation method thereof.With it is existing Technology compared to have it is following the utility model has the advantages that
(1), the protection should be passed through containing silane coupling agent photovoltaic module back side performance protective film and preparation method thereof The raw material of film includes: natural rubber 85%-95%, polyolefin plastomers resin 3%-5%, ethyl vinyl acetate second by weight Alkene copolymer 5%-8% and polyethylene 2%-5%, S1, workshop condition, raw material, raw material pot, molten liquid whisking machines are first confirmd that Whether clean with high-low pressure inflation film manufacturing machine, whether no residue and personal hygiene and protection facility are all qualified;S2, then basis The weight of each formula to be chosen accurately weighs up raw material, and posts label, Marked Weight, title and code;S3, then work Making personnel can put at normal temperature natural rubber particle in the raw material pot got ready, revolving speed of the starting blender in 40-60r/min Lower stirring, and mixing speed is remained unchanged, sequentially add polyolefin plastomers resin, ethylene-vinyl acetate copolymer, poly- second Alkene, suitable OPP stir 10-15min;S4, it discharges later, by discharging investment molten liquid whisking machines, carries out anaerobic Melting, by temperature control at 400 DEG C -600 DEG C, mixing speed 60r-100r/min;After the completion of S5, melting, molten liquid is led to It crosses diversion pipe to flow in high-low pressure inflation film manufacturing machine, carries out blown film;When S6, blown film, initial survey is carried out, by first by high-low pressure inflation film manufacturing machine The protective film produced detected, then determine whether to continue blown film;After S7, initial survey complete qualification, continued not Disconnected production is crispaturaed the protective film of production on reel by film rolling mechanism, and the product inspection after packaging is put in storage, is solved Existing photovoltaic module back protection film service life is shorter, and is prone to wear, and when use cannot be preferably to photovoltaic module It is protected, due to long-time sunshine and high temperature, photovoltaic module back protection film can be damaged, tissue, and the existing back side occurs Gas bag is generated when protective film use, uses inconvenient problem.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention.
In figure, 1- protective film, 2- photovoltaic panel.
Specific embodiment
Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is only It is a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, ordinary skill people Member's every other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
Referring to Fig. 1, the embodiment of the present invention provides five kinds of technical solutions: containing the high property in the silane coupling agent photovoltaic module back side Energy protective film, including protective film 1 and photovoltaic panel 2, the top of photovoltaic panel 2 are fixedly connected with protective film 1, and the raw material of protective film 1 is pressed Weight part ratio includes: natural rubber 85%-95%, polyolefin plastomers resin 3%-5%, ethylene-vinyl acetate copolymer It is shorter to solve existing photovoltaic module back protection film service life, and is easy mill by 5%-8% and polyethylene 2%-5% Damage, when use, cannot preferably protect photovoltaic module, due to long-time sunshine and high temperature, can damage the photovoltaic module back side Tissue occurs for protective film, and generates gas bag when existing back protection film use, uses inconvenient problem.
The invention also discloses the preparation methods containing silane coupling agent photovoltaic module back side performance protective film, specific to wrap Include following embodiment:
Embodiment 1
S1, first confirm that whether workshop condition, raw material, raw material pot, molten liquid whisking machines and high-low pressure inflation film manufacturing machine are clean, It is whether all qualified without residue and personal hygiene and protection facility;
S2, raw material accurately then weighed up according to the weight of each formula to be chosen, and posts label, Marked Weight, Title and code;
S3, then staff can put at normal temperature natural rubber particle in the raw material pot got ready, start blender It is stirred under the revolving speed of 40r/min, and remains unchanged mixing speed, sequentially add polyolefin plastomers resin, ethyl vinyl acetate Ethylene copolymer, polyethylene, suitable OPP stir 11min;
S4, it discharges later, by discharging investment molten liquid whisking machines, carries out anaerobic melting, temperature control is existed 400 DEG C, mixing speed 60r/min;
After the completion of S5, melting, molten liquid is flowed in high-low pressure inflation film manufacturing machine by diversion pipe, carries out blown film;
When S6, blown film, initial survey is carried out, first is detected by the protective film of high-low pressure inflation film manufacturing machine produced, Then determine whether to continue blown film;
After S7, initial survey complete qualification, continual production is carried out, the protective film of production is crispaturaed by film rolling mechanism On reel, the product inspection after packaging is put in storage.
Embodiment 2
S1, first confirm that whether workshop condition, raw material, raw material pot, molten liquid whisking machines and high-low pressure inflation film manufacturing machine are clean, It is whether all qualified without residue and personal hygiene and protection facility;
S2, raw material accurately then weighed up according to the weight of each formula to be chosen, and posts label, Marked Weight, Title and code;
S3, then staff can put at normal temperature natural rubber particle in the raw material pot got ready, start blender It is stirred under the revolving speed of 40r/min, and remains unchanged mixing speed, sequentially add polyolefin plastomers resin, ethyl vinyl acetate Ethylene copolymer, polyethylene, suitable OPP stir 12min;
S4, it discharges later, by discharging investment molten liquid whisking machines, carries out anaerobic melting, temperature control is existed 450 DEG C, mixing speed 70r/min;
After the completion of S5, melting, molten liquid is flowed in high-low pressure inflation film manufacturing machine by diversion pipe, carries out blown film;
When S6, blown film, initial survey is carried out, first is detected by the protective film of high-low pressure inflation film manufacturing machine produced, Then determine whether to continue blown film;
After S7, initial survey complete qualification, continual production is carried out, the protective film of production is crispaturaed by film rolling mechanism On reel, the product inspection after packaging is put in storage.
Embodiment 3
S1, first confirm that whether workshop condition, raw material, raw material pot, molten liquid whisking machines and high-low pressure inflation film manufacturing machine are clean, It is whether all qualified without residue and personal hygiene and protection facility;
S2, raw material accurately then weighed up according to the weight of each formula to be chosen, and posts label, Marked Weight, Title and code;
S3, then staff can put at normal temperature natural rubber particle in the raw material pot got ready, start blender It is stirred under the revolving speed of 40r/min, and remains unchanged mixing speed, sequentially add polyolefin plastomers resin, ethyl vinyl acetate Ethylene copolymer, polyethylene, suitable OPP stir 13min;
S4, it discharges later, by discharging investment molten liquid whisking machines, carries out anaerobic melting, temperature control is existed 500 DEG C, mixing speed 80r/min;
After the completion of S5, melting, molten liquid is flowed in high-low pressure inflation film manufacturing machine by diversion pipe, carries out blown film;
When S6, blown film, initial survey is carried out, first is detected by the protective film of high-low pressure inflation film manufacturing machine produced, Then determine whether to continue blown film;
After S7, initial survey complete qualification, continual production is carried out, the protective film of production is crispaturaed by film rolling mechanism On reel, the product inspection after packaging is put in storage.
Embodiment 4
S1, first confirm that whether workshop condition, raw material, raw material pot, molten liquid whisking machines and high-low pressure inflation film manufacturing machine are clean, It is whether all qualified without residue and personal hygiene and protection facility;
S2, raw material accurately then weighed up according to the weight of each formula to be chosen, and posts label, Marked Weight, Title and code;
S3, then staff can put at normal temperature natural rubber particle in the raw material pot got ready, start blender It is stirred under the revolving speed of 40r/min, and remains unchanged mixing speed, sequentially add polyolefin plastomers resin, ethyl vinyl acetate Ethylene copolymer, polyethylene, suitable OPP stir 14min;
S4, it discharges later, by discharging investment molten liquid whisking machines, carries out anaerobic melting, temperature control is existed 550 DEG C, mixing speed 90r/min;
After the completion of S5, melting, molten liquid is flowed in high-low pressure inflation film manufacturing machine by diversion pipe, carries out blown film;
When S6, blown film, initial survey is carried out, first is detected by the protective film of high-low pressure inflation film manufacturing machine produced, Then determine whether to continue blown film;
After S7, initial survey complete qualification, continual production is carried out, the protective film of production is crispaturaed by film rolling mechanism On reel, the product inspection after packaging is put in storage.
Embodiment 5
S1, first confirm that whether workshop condition, raw material, raw material pot, molten liquid whisking machines and high-low pressure inflation film manufacturing machine are clean, It is whether all qualified without residue and personal hygiene and protection facility;
S2, raw material accurately then weighed up according to the weight of each formula to be chosen, and posts label, Marked Weight, Title and code;
S3, then staff can put at normal temperature natural rubber particle in the raw material pot got ready, start blender It is stirred under the revolving speed of 40r/min, and remains unchanged mixing speed, sequentially add polyolefin plastomers resin, ethyl vinyl acetate Ethylene copolymer, polyethylene, suitable OPP stir 15min;
S4, it discharges later, by discharging investment molten liquid whisking machines, carries out anaerobic melting, temperature control is existed 600 DEG C, mixing speed 100r/min;
After the completion of S5, melting, molten liquid is flowed in high-low pressure inflation film manufacturing machine by diversion pipe, carries out blown film;
When S6, blown film, initial survey is carried out, first is detected by the protective film of high-low pressure inflation film manufacturing machine produced, Then determine whether to continue blown film;
After S7, initial survey complete qualification, continual production is carried out, the protective film of production is crispaturaed by film rolling mechanism On reel, the product inspection after packaging is put in storage.
In conclusion by high containing the silane coupling agent photovoltaic module back side made by technique S1-S7 in embodiment 1-5 Performance protective film solves long-time sunshine and high temperature in use, can obviously can preferably protect to photovoltaic module, The problem of tissue occurs for photovoltaic module back protection film can be damaged, it is more convenient to use.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment Intrinsic element.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (8)

1. containing silane coupling agent photovoltaic module back side performance protective film, including protective film (1) and photovoltaic panel (2), the light Protective film (1) is fixedly connected at the top of volt plate (2), it is characterised in that: the raw material of the protective film (1) wraps by weight It includes: natural rubber 85%-95%, polyolefin plastomers resin 3%-5%, ethylene-vinyl acetate copolymer 5%-8% and poly- second Alkene 2%-5%.
2. according to claim 1 contain silane coupling agent photovoltaic module back side performance protective film, it is characterised in that: day Right rubber 85%, polyolefin plastomers resin 3%, ethylene-vinyl acetate copolymer 7% and polyethylene 5%.
3. according to claim 1 contain silane coupling agent photovoltaic module back side performance protective film, it is characterised in that: day Right rubber 87%, polyolefin plastomers resin 4%, ethylene-vinyl acetate copolymer 7% and polyethylene 5%.
4. according to claim 1 contain silane coupling agent photovoltaic module back side performance protective film, it is characterised in that: day Right rubber 86%, polyolefin plastomers resin 4%, ethylene-vinyl acetate copolymer 6% and polyethylene 4%.
5. according to claim 1 contain silane coupling agent photovoltaic module back side performance protective film, it is characterised in that: day Right rubber 90%, polyolefin plastomers resin 3%, ethylene-vinyl acetate copolymer 5% and polyethylene 2%.
6. contain silane coupling agent photovoltaic module back side performance protective film described in -5 any one according to claim 1, Be characterized in that: the natural rubber is guayule, be made after being solidified, being dried by guayule when use, and crush At graininess.
7. contain silane coupling agent photovoltaic module back side performance protective film described in -6 any one according to claim 1, Be characterized in that: the ethylene-vinyl acetate copolymer and polyethylene are granular material, when being processed, need to carry out nothing Oxygen melt after carry out again using.
8. contain silane coupling agent photovoltaic module back side performance protective film described in -7 any one according to claim 1, Be characterized in that: preparation method specifically includes the following steps:
S1, first confirm that whether workshop condition, raw material, raw material pot, molten liquid whisking machines and high-low pressure inflation film manufacturing machine are clean, nothing left Stay object and personal hygiene and protection facility whether all qualified;
S2, raw material accurately then weighed up according to the weight of each formula to be chosen, and posts label, Marked Weight, title And code;
S3, then staff can put at normal temperature natural rubber particle in the raw material pot got ready, start blender in 40- It is stirred under the revolving speed of 60r/min, and remains unchanged mixing speed, sequentially add polyolefin plastomers resin, ethyl vinyl acetate second Alkene copolymer, polyethylene, suitable OPP stir 10-15min;
S4, it discharges later, by discharging investment molten liquid whisking machines, carries out anaerobic melting, temperature is controlled 400 DEG C -600 DEG C, mixing speed 60r-100r/min;
After the completion of S5, melting, molten liquid is flowed in high-low pressure inflation film manufacturing machine by diversion pipe, carries out blown film;
When S6, blown film, initial survey is carried out, first is detected by the protective film (1) of high-low pressure inflation film manufacturing machine produced, so After determine whether to continue blown film;
After S7, initial survey complete qualification, continual production is carried out, the protective film (1) of production is crispaturaed by film rolling mechanism On reel, the product inspection after packaging is put in storage.
CN201910148400.XA 2019-02-27 2019-02-27 Photovoltaic module back high-performance protective film containing silane coupling agent and preparation method thereof Active CN109920869B (en)

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CN102432963A (en) * 2011-08-17 2012-05-02 常州荣晟新材料科技有限公司 Fluorinated weather-resistant film for solar photovoltaic battery back plate and preparation method of fluorinated weather-resistant film
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CN103336321A (en) * 2012-12-24 2013-10-02 湖北慧狮塑业股份有限公司 Polypropylene type optical protective film
CN104040730A (en) * 2012-01-13 2014-09-10 三菱树脂株式会社 Solar cell module having excellent appearance and method for manufacturing same
CN104112785A (en) * 2014-07-31 2014-10-22 明冠新材料股份有限公司 Film used for synergistic type solar cell back plate and preparation method thereof
CN105609575A (en) * 2015-12-31 2016-05-25 杭州福斯特光伏材料股份有限公司 High-reflectivity backplate material of photovoltaic module
CN108034140A (en) * 2018-01-09 2018-05-15 浙江中聚材料有限公司 Excellent polyolefin complex of a kind of weather resistance and preparation method thereof
CN108749248A (en) * 2018-06-27 2018-11-06 来安县瑞傲源新材料有限公司 A kind of solar cell backboard material of high intensity and preparation method thereof
CN109355037A (en) * 2018-10-18 2019-02-19 杭州福斯特应用材料股份有限公司 A kind of ultraviolet light solidification packaging adhesive film and solar cell module

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1047324A (en) * 1989-05-16 1990-11-28 罗姆和哈斯公司 The propylene ester adhesive composition that contains linking agent and impact modifying agent
CN102939665A (en) * 2010-06-14 2013-02-20 三菱化学株式会社 Solar cell module
CN102304329A (en) * 2011-07-25 2012-01-04 俞明高 Self-adhesive protective film and initial adhesion regulating method of self-adhesive protective film
CN102432963A (en) * 2011-08-17 2012-05-02 常州荣晟新材料科技有限公司 Fluorinated weather-resistant film for solar photovoltaic battery back plate and preparation method of fluorinated weather-resistant film
CN104040730A (en) * 2012-01-13 2014-09-10 三菱树脂株式会社 Solar cell module having excellent appearance and method for manufacturing same
CN103336321A (en) * 2012-12-24 2013-10-02 湖北慧狮塑业股份有限公司 Polypropylene type optical protective film
CN104112785A (en) * 2014-07-31 2014-10-22 明冠新材料股份有限公司 Film used for synergistic type solar cell back plate and preparation method thereof
CN105609575A (en) * 2015-12-31 2016-05-25 杭州福斯特光伏材料股份有限公司 High-reflectivity backplate material of photovoltaic module
CN108034140A (en) * 2018-01-09 2018-05-15 浙江中聚材料有限公司 Excellent polyolefin complex of a kind of weather resistance and preparation method thereof
CN108749248A (en) * 2018-06-27 2018-11-06 来安县瑞傲源新材料有限公司 A kind of solar cell backboard material of high intensity and preparation method thereof
CN109355037A (en) * 2018-10-18 2019-02-19 杭州福斯特应用材料股份有限公司 A kind of ultraviolet light solidification packaging adhesive film and solar cell module

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Denomination of invention: High performance protective film on the back of photovoltaic module containing silane coupling agent and its preparation method

Effective date of registration: 20221222

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Pledgee: Tunxi Mount Huangshan rural commercial bank Limited by Share Ltd.

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Registration number: Y2022980028777