CN109917497A - A kind of high definition eyeglass of Abbe number 45 - Google Patents
A kind of high definition eyeglass of Abbe number 45 Download PDFInfo
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- CN109917497A CN109917497A CN201910378045.5A CN201910378045A CN109917497A CN 109917497 A CN109917497 A CN 109917497A CN 201910378045 A CN201910378045 A CN 201910378045A CN 109917497 A CN109917497 A CN 109917497A
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- abbe number
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- basal layer
- high definition
- phenyl
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Abstract
The invention discloses a kind of high definition eyeglasses of Abbe number 45, it include basal layer, its material of basal layer composition includes 15-35% silica, the niobium oxide of 10-40%, the zirconium oxide and oxidation lithium mixture of 5-20%, also it is added with micro barium monoxide, calcium oxide, the refractive index of the basal layer is 1.75 or less, film is covered in the substrate surface, Abbe number additive is coated on the film, the Abbe number additive can ensure that the Abbe number of film 45 or more, the Abbe number additive is with 9, 9- diaryl vinyl fluoride is the compound of skeleton.
Description
Technical field
The invention mainly relates to eyeglass technical fields, more particularly to a kind of high definition eyeglass of Abbe number 45.
Background technique
Abbe number is the physical quantity of roentgen Ernest & Whitney Abbe invention, also referred to as " abbe number ", for measuring
The light degree of dispersion of transparent medium.
Abbe number is exactly the index to indicate transparent medium dispersive power.In general, the refractive index of medium is bigger, color
Scattered more serious, Abbe number is smaller；Conversely, the refractive index of medium is smaller, dispersion is slighter, and Abbe number is bigger.
Abbe number is usually used in eyeglass industry, is that eyeglass chooses one of reference factor.Currently, ophthalmically acceptable optical lens material
Abbe number is generally between 30 to 60.The Abbe number of high definition eyeglass is required 45 or more, the refractive index very little of such medium, but is wanted
Eyeglass is directly processed into 45 or more Abbe number, difficulty of processing is very big, higher cost, is easy to be drawn additionally, due to lens surface
Wound, this makes the cost of upkeep of eyeglass also very big.
Summary of the invention
In view of the deficienciess of the prior art, the present invention is intended to provide a kind of thin by covering Abbe number 45 in lens surface
Film is to reduce the high definition eyeglass of cost.
To achieve the above object, the present invention provides the following technical solutions:
A kind of high definition eyeglass of Abbe number 45, includes basal layer, its material of basal layer composition includes the two of 15-35%
Silica, the niobium oxide of 10-40%, the zirconium oxide and oxidation lithium mixture of 5-20%, also added with micro barium monoxide, oxidation
Calcium, the refractive index of the basal layer are 1.75 hereinafter, being covered with film in the substrate surface, are coated with Abbe on the film
Number additive, the Abbe number additive can ensure that the Abbe number of film 45 or more, and the Abbe number additive is with 9,9-
Diaryl vinyl fluoride is the compound of skeleton.
As an improvement of the present invention, it is described with 9,9- diaryl vinyl fluoride be skeleton compound include hydroxy phenyl, alkane
Base hydroxy phenyl, aryl hydroxy phenyl, two or trihydroxy phenyl, hydroxynaphenyl, hydroxy alkoxy base phenyl, alkyl hydroxy alkoxy
At least two in phenyl.
As a further improvement of the present invention, it is described with 9,9- diaryl vinyl fluoride be skeleton compound further include having heat
Plastic resin.
As a further improvement of the present invention, the thermoplastic resin is aromatic polycarbonate resin or aromatic polyester tree
Rouge.
Compared with the prior art, the advantages of the present invention are as follows: by covering film in lens substrate layer surface, and in film
Upper smearing Abbe number additive, so that film Abbe number is 45 or more, and basal layer refractive index is very low, and can be protected by film
Shield, even if film surface is scratched, film of tearing is replaced.
Detailed description of the invention
Fig. 1 is the composition figure of Abbe number additive in the embodiment of the present invention.
Specific embodiment
It is described further below in conjunction with high definition eyeglass of the figure embodiment to the Abbe number 45 in the present invention.
The present embodiment is a kind of high definition eyeglass of Abbe number 45, includes basal layer, its material of basal layer composition packet
Containing 15-35% silica, silica is a kind of acidic oxide, it is a kind of for optically coated material, is added
After having added silica, a small amount of clear water is smeared in substrate surface in order to which film described hereinafter is covered on basal layer table
Face, basal layer further include the niobium oxide of 10-40%, and niobium oxide has certain electric conductivity, can be absorbed electrostatic in air from
Son prevents them to be deposited between basal layer and film, in addition, niobium oxide or a kind of catalyst, in the mistake of manufacture basal layer
It can promote the fusion of each component in journey.In basal layer also the zirconium oxide containing 5-20% and oxidation lithium mixture, zirconium oxide and
Niobium oxide have high chemical stability, can be prevented after basal layer quench hardening basal layer again with the acidity or alkalinity in the external world
Particle reacts, and corrodes basal layer, zirconium oxide and lithia also have low viscosity, can prevent the dust impurity in air from inhaling
It is attached to substrate surface, to influence the clarity of eyeglass.Micro barium monoxide, calcium oxide are also added in basal layer, this
A little elements are mainly used for colouring, and barium monoxide, calcium oxide can make eyeglass be rendered as brilliant white, and when needing other colors,
Other microelements can be added, for example addition cobalt oxide, copper oxide, iron oxide and nickel oxide can make eyeglass be rendered as ash
Color, suitable for sunglasses is made, it is dark brown that addition manganese oxide can make eyeglass be rendered as, and have and absorb infrared ray and ultraviolet
The effect of line is generally used for the goggles of production welding personnel.
Basal layer can make the refractive index of basal layer 1.75 hereinafter, i.e. substrate after the element of addition aforementioned proportion
Layer has preferable translucency, but the basal layer of this high light transmittance is often very fragile, therefore covers in substrate surface bonding
Be stamped thin film, Abbe number additive be coated on film, the Abbe number additive can ensure that the Abbe number of film 45 with
On, the Abbe number additive is the compound with 9,9- diaryl vinyl fluoride for skeleton.9,9- diaryl vinyl fluoride is one kind
New photoresponse compound has extraordinary thermal stability and anti-fatigue performance.In light (such as ultraviolet light and can of different wave length
It is light-exposed) under the action of, the transformation of the photo-induced reversible between open loop body and closed loop body can occur for Diarene compound.This open loop body with
Transformation between closed loop body can cause the significant changes of compound colors, while can also cause the various properties of compound, such as reflect
The reversible change of rate, dielectric constant, oxidation-reduction potential, therefore using diaryl vinyl fluoride as skeleton, it can be ensured that Abbe number
Stability.The diaryl vinyl fluoride structural formula is as shown in Figure 1, wherein and ring Z is fragrant hydrocarbon ring, and R<1>and R<2>they are substituent groups,
X is group or amino, and k is 0 to 4 integer, and m is 0 or more integers greater than 0, and p is 1 or more integers greater than 1.
Specifically, it is described with 9,9- diaryl vinyl fluoride be skeleton compound further include hydroxy phenyl, alkyl hydroxy benzene
Base, aryl hydroxy phenyl, two or trihydroxy phenyl, hydroxynaphenyl, hydroxy alkoxy base phenyl, in alkyl hydroxy alkoxyl phenyl
At least two.Described by the compound of skeleton of 9,9- diaryl vinyl fluoride further includes having thermoplastic resin.The thermoplastic resin
For aromatic polycarbonate resin or aromatic polyester resin.
The above makes the preferred embodiment of the present invention, does not depart from this hair for those of ordinary skill in the art
Under the premise of bright principle, several variations and modifications can also be made, these also should be regarded as protection scope of the present invention.
Claims (4)
1. a kind of high definition eyeglass of Abbe number 45, it is characterised in that: include basal layer, its material of basal layer composition includes
There are 15-35% silica, the niobium oxide of 10-40%, the zirconium oxide and oxidation lithium mixture of 5-20%, also added with micro
Barium monoxide, calcium oxide, the refractive index of the basal layer are 1.75 hereinafter, being covered with film, the film in the substrate surface
On be coated with Abbe number additive, the Abbe number additive can ensure that the Abbe number of film 45 or more, and the Abbe number adds
Adding agent is using 9,9- diaryl vinyl fluoride as the compound of skeleton.
2. high definition eyeglass according to claim 1, it is characterised in that: it is described with 9,9- diaryl vinyl fluoride be skeleton change
Closing object includes hydroxy phenyl, alkyl hydroxy phenyl, aryl hydroxy phenyl, two or trihydroxy phenyl, hydroxynaphenyl, hydroxy alkoxy base
At least two in phenyl, alkyl hydroxy alkoxyl phenyl.
3. high definition eyeglass according to claim 2, it is characterised in that: it is described with 9,9- diaryl vinyl fluoride be skeleton change
Closing object further includes having thermoplastic resin.
4. high definition eyeglass according to claim 3, it is characterised in that: the thermoplastic resin is aromatic polycarbonate resin
Or aromatic polyester resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910378045.5A CN109917497A (en) | 2019-05-08 | 2019-05-08 | A kind of high definition eyeglass of Abbe number 45 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910378045.5A CN109917497A (en) | 2019-05-08 | 2019-05-08 | A kind of high definition eyeglass of Abbe number 45 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109917497A true CN109917497A (en) | 2019-06-21 |
Family
ID=66979113
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910378045.5A Pending CN109917497A (en) | 2019-05-08 | 2019-05-08 | A kind of high definition eyeglass of Abbe number 45 |
Country Status (1)
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| CN (1) | CN109917497A (en) |
Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1112526A (en) * | 1994-03-11 | 1995-11-29 | 德国特殊玻璃公开股份有限公司 | High-refractive index phototropic glass |
| JPH0848940A (en) * | 1994-04-21 | 1996-02-20 | Seiko Epson Corp | Film-forming coating fluid and synthetic resin lens |
| US5789476A (en) * | 1995-03-03 | 1998-08-04 | Seiko Epson Corporation | Film-forming coating solution and synthetic resin lens |
| CN101010400A (en) * | 2004-09-01 | 2007-08-01 | 触媒化成工业株式会社 | Coating liquid for forming transparent coating film and base with transparent coating film |
| CN101117267A (en) * | 2006-08-01 | 2008-02-06 | 湖北华光新材料有限公司 | High-refractivity spectacle glass |
| JP4630393B2 (en) * | 2008-12-26 | 2011-02-09 | パナソニック株式会社 | Diffraction lens and imaging apparatus using the same |
| CN102666677A (en) * | 2009-11-19 | 2012-09-12 | 三菱化学株式会社 | Polycarbonate resin film, transparent film, and process for producing same |
| CN103080162A (en) * | 2011-06-13 | 2013-05-01 | Dic株式会社 | Radically polymerizable composition, cured product, and plastic lens |
| TW201408718A (en) * | 2012-08-31 | 2014-03-01 | Fujifilm Corp | Low refractive index film, curing composition for forming low refractive index film, optical member and solid-state imaging element using the same, method for producing optical member set and method for producing curing composition |
| JP2014205734A (en) * | 2013-04-10 | 2014-10-30 | 大阪瓦斯株式会社 | Abbe number improver |
| CN104386911A (en) * | 2014-11-11 | 2015-03-04 | 湖北新华光信息材料有限公司 | Optical glass |
| CN105264406A (en) * | 2013-05-07 | 2016-01-20 | 埃西勒国际通用光学公司 | Optical article comprising acrylic substrate coated with specific hard-coat |
| CN106415330A (en) * | 2014-02-04 | 2017-02-15 | 东海光学株式会社 | Optical product, glasses lens and glasses |
| CN107429033A (en) * | 2015-03-13 | 2017-12-01 | 大阪燃气化学有限公司 | Resin combination and optical lens |
| CN209784571U (en) * | 2019-05-08 | 2019-12-13 | 河南达人视界眼镜有限公司 | High-definition lens with Abbe number of 45 |
-
2019
- 2019-05-08 CN CN201910378045.5A patent/CN109917497A/en active Pending
Patent Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1112526A (en) * | 1994-03-11 | 1995-11-29 | 德国特殊玻璃公开股份有限公司 | High-refractive index phototropic glass |
| JPH0848940A (en) * | 1994-04-21 | 1996-02-20 | Seiko Epson Corp | Film-forming coating fluid and synthetic resin lens |
| US5789476A (en) * | 1995-03-03 | 1998-08-04 | Seiko Epson Corporation | Film-forming coating solution and synthetic resin lens |
| CN101010400A (en) * | 2004-09-01 | 2007-08-01 | 触媒化成工业株式会社 | Coating liquid for forming transparent coating film and base with transparent coating film |
| CN101117267A (en) * | 2006-08-01 | 2008-02-06 | 湖北华光新材料有限公司 | High-refractivity spectacle glass |
| JP4630393B2 (en) * | 2008-12-26 | 2011-02-09 | パナソニック株式会社 | Diffraction lens and imaging apparatus using the same |
| CN102666677A (en) * | 2009-11-19 | 2012-09-12 | 三菱化学株式会社 | Polycarbonate resin film, transparent film, and process for producing same |
| CN103080162A (en) * | 2011-06-13 | 2013-05-01 | Dic株式会社 | Radically polymerizable composition, cured product, and plastic lens |
| TW201408718A (en) * | 2012-08-31 | 2014-03-01 | Fujifilm Corp | Low refractive index film, curing composition for forming low refractive index film, optical member and solid-state imaging element using the same, method for producing optical member set and method for producing curing composition |
| JP2014205734A (en) * | 2013-04-10 | 2014-10-30 | 大阪瓦斯株式会社 | Abbe number improver |
| CN105264406A (en) * | 2013-05-07 | 2016-01-20 | 埃西勒国际通用光学公司 | Optical article comprising acrylic substrate coated with specific hard-coat |
| CN106415330A (en) * | 2014-02-04 | 2017-02-15 | 东海光学株式会社 | Optical product, glasses lens and glasses |
| CN104386911A (en) * | 2014-11-11 | 2015-03-04 | 湖北新华光信息材料有限公司 | Optical glass |
| CN107429033A (en) * | 2015-03-13 | 2017-12-01 | 大阪燃气化学有限公司 | Resin combination and optical lens |
| CN209784571U (en) * | 2019-05-08 | 2019-12-13 | 河南达人视界眼镜有限公司 | High-definition lens with Abbe number of 45 |
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