CN109914156A - Tender sensitive skin paper of a kind of children and preparation method thereof - Google Patents
Tender sensitive skin paper of a kind of children and preparation method thereof Download PDFInfo
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- CN109914156A CN109914156A CN201711326351.1A CN201711326351A CN109914156A CN 109914156 A CN109914156 A CN 109914156A CN 201711326351 A CN201711326351 A CN 201711326351A CN 109914156 A CN109914156 A CN 109914156A
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Abstract
The present invention relates to tender sensitive skin paper of a kind of children and preparation method thereof, the technique for disclosing prescriptions worth thousand gold dregs of a decoction papermaking includes Microwave Pretreatment, fermentation, washing, papermaking, extracts the techniques such as effective component and paper modification.The present invention is using the prescriptions worth thousand gold dregs of a decoction as preparation staple fiber, and in conjunction with the long fibre characteristic of cotton fiber, the tender sensitive skin paper of the children of preparation has extraordinary tensile property, while being applied by plasm-glue-blending and surface, has significant wet strength.The present invention uses microwave irradiation and bioanalysis, and whole process does not introduce harmful chemicals, it is ensured that the hygienic characteristic of paper, and the pliability of paper is good.The also initiative extraction pharmacological property ingredient from slurrying filtrate, and be applied to paper itself, microorganism infection can be prevented, to skin and mucosa without any irritation and side effect, the tender sensitive skin crowd of children is suitble to use.
Description
Technical field
The invention belongs to pulp and paper technology fields, and in particular, to a kind of tender sensitive skin paper of children and its preparation side
Method.
Background technique
Paper industry is one of important foundation industry of Chinese national economy.Since a large amount of dirt can be generated in paper-making process
Water and solid waste, therefore, paper industry is also resource, energy consumption intensity is high, pollutant yield is big, environment influences sternly
The processing and manufacturing industry of weight.As the sector scale is gradually expanded, environment brought by these sewage and solid waste influences
Also it becomes increasingly conspicuous.
Now commonly used pulping and papermaking method energy consumption is high, and various paper making raw materials are decomposed with the method for biological decomposition
In lignin, substituted chemistry method pulping, realize papermaking overall process water zero-emission, from paper industry is prevented at all to environment
Pollution.But since lignin is amorphous macromolecular structure, stability is very strong, and could only be degraded wood with a small amount of fungi in microorganism
Element as whiterot fungi can only degrade sawdust lignin, and needs high temperature and pressure, so causing added cost it is difficult to ensure that temperature is uniform；
Simultaneously because being easy secretion melanocyte in antimicrobial treatment process, pulp brightness is caused to reduce.
In order to increase the whiteness of bioanalysis slurrying, researchers, which are usually added in the Biological Pretreatment stage, inhibits melanocyte shape
At chemicals or be added chemical bleaching preparation.Although such methods can promote pulp brightness to a certain extent, by
In introducing chemicals in pulping process, it is unfavorable for the hygienic characteristic of fiber, so that the subsequent applications of fiber are restricted.
Summary of the invention
It is insufficient that the technical problem to be solved by the present invention is to bioanalysis pulping techniques, provides a kind of tender sensitive skin paper of children
Preparation method.The method is not only able to solve the problems, such as that lignin macromolecule structure removing difficulty is big, moreover it is possible to paper pulp be effectively reduced
Whiteness, the bleached pulp of preparation have the characteristics that whiteness is high, Kappa number is low, and performance is good, and the tender sensitive skin paper of children obtained is soft
Softness is good.
Another object of the present invention is to provide a kind of tender sensitivities of children of the preparation method preparation of the tender sensitive skin paper of children
Skin paper.
The present invention is achieved by the following technical solutions:
A kind of preparation method of the tender sensitive skin paper of children, comprising the following steps:
S1. it pre-processes: the prescriptions worth thousand gold dregs of a decoction that water content is 25%~45% is subjected to Micro-wave pretreatment, microwave power
For 400~700W, the microwave time is 20~40min, for use；
S2. ferment: the prescriptions worth thousand gold dregs of a decoction deionized water that step S1 is obtained is impregnated and washing, in washing water is
Property, it is dehydrated, dispersed, then placed it in fermentation vat, biological complex enzyme is added, after mixing evenly, under aerobic conditions,
It is handled again using microwave radiation, microwave power is 1000~1500W, and the microwave time is 60~200min, to prescriptions worth thousand gold
Dregs of a decoction material carries out fermentation process, is filtered after fermentation, obtains filtrate and filtrate；
S3. it washs: the filtrate in step S2 is impregnated repeatedly, disperses and washed with water, in washing water is
Property after, be dehydrated, sealing, obtain dreg fibers after dry；
S4. the extraction of effective component: concentration is evaporated to the filtrate in step S2, obtaining has effective component solution；
S5. papermaking: fiber made from step S3 is manufactured paper with pulp, body paper is obtained；
S6. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
Effective component solution in basic medical fluid and step S4 is mixed to get medical fluid；
By the body paper surface of medicine liquid spray and step S5, obtaining after dry has the tender sensitive skin paper of the children of pharmacological property.
Preferably, the prescriptions worth thousand gold dregs of a decoction are very heavy group, cherokee rose root, Caulis Spatholobi, single side needle, leatherleaf mahonia, Herba Andrographitis, Radix Angelicae Sinensis
With Radix Codonopsis after water or ethyl alcohol extract the remaining dregs of a decoction.
Preferably, the preparation method of the prescriptions worth thousand gold dregs of a decoction is prepared with reference to the method for following patent notes: (1)
ZL99115682.X, a kind of manufacture craft of ' Qianjin ' capsule to treat ganopathy；(2) a kind of manufacture of ' Qianjin ' capsule to treat ganopathy of ZL99115683.8
Method；(3) preparation method of ZL98112696.0 compound Chinese medicinal preparation FUKE QIANJIN PIAN.
Preferably, the partial size of the prescriptions worth thousand gold dregs of a decoction is less than 3cm.
Preferably, the water content of the prescriptions worth thousand gold dregs of a decoction is 30%~35% in step S1, and the power of the microwave radiation is 600
~700W, time are 20~30min.
Preferably, biological complex enzyme described in step S2 is prepared by the raw material of following weight percent: whiterot fungi 6~
12%, Ficus virens 12~20%, zytase 24~30% and laccase 10~20%.
Preferably, in step S2, the biological complex enzyme additional amount is 1~2 kg/ton of material.
The present invention uses the biological complex enzyme being made of whiterot fungi, Ficus virens, zytase and laccase, benefit
With reasonable compatibility between each strain and enzyme, jointly the effect coordinated, in the effectively degradation dregs of a decoction while a variety of lignins, additionally it is possible to
It persistently plays a role in the subsequent bleaching process of dregs of a decoction slurry.
Preferably, the power of microwave radiation described in step S3 is 1200~1500W, and the time is 120~200min.
The present invention pre-processes the prescriptions worth thousand gold dregs of a decoction using microwave irradiation, not but not to the main of the prescriptions worth thousand gold dregs of a decoction
Composition fiber element has an impact, and the also very advantageous lignin components in the dregs of a decoction are separated, and generates plant cell wall tissue
Microcellular structure is more advantageous to the chemical reaction of subsequent delignification, meanwhile, the dregs of a decoction are pre-processed using microwave irradiation, also
The substance with bonding or glue blending function can be generated, these substances play the role of reinforcing fibre crosslinking, so that at the physics of paper
Performance is reinforced.
Preferably, the water content of the body paper is 91%~93%.
Preferably, evaporating temperature is 100~110 DEG C in step S4.
Preferably, fiber made from S3 being beaten in step S5, beating degree is 35~45oSR, then manufactures paper with pulp,
Using starch as Cypres, body paper is obtained after dry.The present invention, as sizing agent, can improve paper using starch
Physical property also remains the health of paper, and chemicals bring is avoided to endanger.
Preferably, in step S6, by the effective component spray solution in S4 in the body paper surface of S5, had after dry
It is the 20%~30% of original paper quality that the tender sensitive skin of the children of pharmacological property, which has the fountain height of effective component solution with paper, in 60~65
Obtaining after drying at DEG C has the tender sensitive skin paper of the children of pharmacological property.
A kind of tender sensitive skin paper of children of the above-mentioned method preparation that fiber is prepared using the prescriptions worth thousand gold dregs of a decoction.The tender sensitivity of the children
Skin paper is preparing the application in amenities or medical supplies.
The present invention directly prepares bleached pulp using the dregs of a decoction as plant material, using microwave irradiation technology, simplifies the process of slurrying,
Any harmful substance will not be not only generated to environment during the reaction, but also its special treatment process makes the dregs of a decoction in de- wood
It is with the obvious advantage in element reaction.
Compared with prior art, the preparation method of the tender sensitive skin paper of children provided by the invention has the advantage that
The present invention carries out bioanalysis slurrying by raw material of the prescriptions worth thousand gold dregs of a decoction for the first time, exists simultaneously draft according to the prescriptions worth thousand gold dregs of a decoction
Plant and broadleaf plant material this characteristic, using whiterot fungi, Ficus virens, zytase and laccase composition
Biological complex enzyme, the effect coordinated using reasonable compatibility between each strain and enzyme, jointly, a variety of lignins in the effectively degradation dregs of a decoction
While, additionally it is possible to the chromophoric group in paper pulp is removed, the whiteness of bleached pulp is effectively promoted.
The present invention directly prepares bleached pulp using the dregs of a decoction as plant material, using microwave irradiation technology, isolates from the dregs of a decoction
Lignin components make plant cell wall tissue generate microcellular structure, promote the decomposition of lignin macromolecule structure and the fracture of chemical bond,
It is more advantageous to the chemical reaction of subsequent delignification, can preferably dissolve out lignin in paper pulp, residual lignin content is low, bleaching efficiency
Height obtains whiteness height, the lower slurry of Kappa number.
The method provided by the invention for preparing fiber using the prescriptions worth thousand gold dregs of a decoction, pulp preparing process is simple, is not only reacting
Any harmful substance will not be generated to environment in the process, easy to operate, the time is short.
In conclusion the present invention solves the problems, such as that existing microwave irradiation technology pulping process is complicated；And focus on solving life
The object legal system slurry situation that treatment effeciency is low, effect is poor.Using the coarse particles of the method for the present invention preparation are low with Kappa number, intensity is good
The characteristics of, whiteness is up to 80% or more, and Kappa number is respectively less than 10, and pliability is in 160mN or less.
The present invention uses bioanalysis slurrying, and pulping process does not introduce harmful chemicals, it is ensured that the hygienic characteristic of fiber.
Extract pharmacological property ingredient in the also initiative slave pulping waste liquor of the present invention, and be applied to body paper itself, children obtained is tender
Sensitive skin has good anti-inflammatory, antibiotic effect with paper, has high functional characteristic and added value.
Specific embodiment
The present invention is further illustrated combined with specific embodiments below.Unless stated otherwise, it is used in the embodiment of the present invention
Raw material and method are the raw material of this field regular market purchase and conventional use of method, used equipment are that this field is routinely set
It is standby.
The preparation method of basic medical fluid:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
First by Herba Andrographitis and the Radix Angelicae Sinensis effective ingredient that with 85% concentration the heated circumfluence method of ethyl alcohol both is extracted, filter
The filtrate that ethyl alcohol is solvent is obtained after de- slag, recovered ethyl alcohol obtains filtrate.
Secondly respectively by leatherleaf mahonia, single side needle and very heavy group, cherokee rose root, Caulis Spatholobi, Radix Codonopsis distinguish boiling, it is extracted,
It filters de- slag and obtains corresponding filtrate；It will wherein leave after very heavy group, cherokee rose root, Caulis Spatholobi, Radix Codonopsis boiling and extracted again；It should
Extracting solution merges with first time extracting solution.
Embodiment 1
The present embodiment provides a kind of preparation methods of the tender sensitive skin paper of children, specific steps are as follows:
S1. it pre-processes: the prescriptions worth thousand gold dregs of a decoction that water content is 25% being subjected to Micro-wave pretreatment, microwave power is
400W, microwave time are 40min, for use；
S2. ferment: the prescriptions worth thousand gold dregs of a decoction deionized water that step S1 is obtained is impregnated and washing, in washing water is
Property, it is dehydrated, dispersed, then placed it in fermentation vat, 1 kg/ton of biological complex enzyme material is added, after mixing evenly,
It under aerobic conditions, is handled again using microwave radiation, microwave power 1500W, the microwave time is 60min, to prescriptions worth thousand gold
Dregs of a decoction material carries out fermentation process, is filtered after fermentation, obtains filtrate and filtrate；
S3. it washs: the filtrate in step S2 is impregnated repeatedly, disperses and washed with water, in washing water is
Property after, be dehydrated, sealing, obtain dreg fibers after dry；
S4. the extraction of effective component: being evaporated concentration to the filtrate in step S2, and evaporating temperature is 100 DEG C, is had
There is effective component solution；
S5. papermaking: fiber made from step S3 is beaten, beating degree 35oThen SR manufactures paper with pulp, using shallow lake
Powder obtains body paper after dry as Cypres.The water content of body paper is 91%.Cypres concentration is 8%, coating weight
For 1g/m2。
S6. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
Effective component solution in basic medical fluid and step S4 is mixed to get medical fluid；
By medicine liquid spray in the body paper surface of step S5, obtaining after dry, there is the tender sensitive skin of the children of pharmacological property to have with paper
The fountain height of effective component solution is the 20% of original paper quality, and obtaining after dry at 65 DEG C has the tender sensitive skin of the children of pharmacological property
Use paper.
The preparation method of the prescriptions worth thousand gold dregs of a decoction is referred to patent ZL99115682.X, a kind of production work of ' Qianjin ' capsule to treat ganopathy
Skill, the prescriptions worth thousand gold dregs of a decoction are very heavy group, cherokee rose root, Caulis Spatholobi, single side needle, leatherleaf mahonia, Herba Andrographitis, Radix Angelicae Sinensis and Radix Codonopsis pass through water or second
Dregs of a decoction mixing after alcohol extracting.The partial size of the prescriptions worth thousand gold dregs of a decoction is less than 3cm.
Wherein, biological complex enzyme is prepared by the raw material of following weight percent: whiterot fungi 6%, yellow archespore Mao Pingcao
Bacterium 20%, zytase 24% and laccase 20%.
Embodiment 2
The present embodiment provides a kind of preparation methods of the tender sensitive skin paper of children, specific steps are as follows:
S1. it pre-processes: the prescriptions worth thousand gold dregs of a decoction that water content is 45% being subjected to Micro-wave pretreatment, microwave power is
700W, microwave time are 20min, for use；
S2. ferment: the prescriptions worth thousand gold dregs of a decoction deionized water that step S1 is obtained is impregnated and washing, in washing water is
Property, it is dehydrated, dispersed, then placed it in fermentation vat, 1.5 kg/ton of biological complex enzyme material are added, after mixing evenly,
It under aerobic conditions, is handled again using microwave radiation, microwave power 1000W, the microwave time is 200min, to a thousand pieces of gold
Recipe slag material carries out fermentation process, is filtered after fermentation, obtains filtrate and filtrate；
S3. it washs: the filtrate in step S2 is impregnated repeatedly, disperses and washed with water, in washing water is
Property after, be dehydrated, sealing, obtain dreg fibers after dry；
S4. the extraction of effective component: being evaporated concentration to the filtrate in step S2, and evaporating temperature is 110 DEG C, is had
There is effective component solution；
S5. papermaking: fiber made from step S3 is beaten, beating degree 45oThen SR manufactures paper with pulp, using shallow lake
Powder obtains body paper after dry as Cypres.The water content of body paper is 93%.Cypres concentration is 10%, coating
Amount is 0.7g/m2。
S6. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
Effective component solution in basic medical fluid and step S4 is mixed to get medical fluid；
By medicine liquid spray in the body paper surface of step S5, obtaining after dry, there is the tender sensitive skin of the children of pharmacological property to have with paper
The fountain height of effective component solution is the 30% of original paper quality, and obtaining after dry at 60 DEG C has the tender sensitive skin of the children of pharmacological property
Use paper.
The preparation method of the prescriptions worth thousand gold dregs of a decoction refers to matching with patent ZL98112696.0 compound Chinese medicinal preparation FUKE QIANJIN PIAN
Method processed, the prescriptions worth thousand gold dregs of a decoction are very heavy group, cherokee rose root, Caulis Spatholobi, single side needle, leatherleaf mahonia, Herba Andrographitis, Radix Angelicae Sinensis and Radix Codonopsis pass through water
Or the dregs of a decoction mixing after ethyl alcohol extraction.The partial size of the prescriptions worth thousand gold dregs of a decoction is less than 2cm.
Wherein, biological complex enzyme is prepared by the raw material of following weight percent: whiterot fungi 12%, yellow archespore Mao Pingcao
Bacterium 12%, zytase 30% and laccase 10%.
Embodiment 3
The present embodiment provides a kind of preparation methods of the tender sensitive skin paper of children, specific steps are as follows:
S1. it pre-processes: the prescriptions worth thousand gold dregs of a decoction that water content is 30% being subjected to Micro-wave pretreatment, microwave power is
600W, microwave time are 30min, for use；
S2. ferment: the prescriptions worth thousand gold dregs of a decoction deionized water that step S1 is obtained is impregnated and washing, in washing water is
Property, it is dehydrated, dispersed, then placed it in fermentation vat, 1 kg/ton of biological complex enzyme material is added, after mixing evenly,
It under aerobic conditions, is handled again using microwave radiation, microwave power 1200W, the microwave time is 120min, to prescriptions worth thousand gold
Dregs of a decoction material carries out fermentation process, is filtered after fermentation, obtains filtrate and filtrate；
S3. it washs: the filtrate in step S2 is impregnated repeatedly, disperses and washed with water, in washing water is
Property after, be dehydrated, sealing, obtain dreg fibers after dry；
S4. the extraction of effective component: being evaporated concentration for the filtrate in step S2, and evaporating temperature is 105 DEG C, is had
There is effective component solution；
S5. papermaking: fiber made from step S3 is beaten, beating degree 40oThen SR manufactures paper with pulp, using shallow lake
Powder obtains body paper after dry as Cypres.The water content of body paper is 92%.Cypres concentration is 9%, coating weight
For 0.8g/m2。
S6. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
Effective component solution in basic medical fluid and S4 is mixed to get medical fluid；
By the body paper surface of medicine liquid spray and step S5, obtaining after dry, there is the tender sensitive skin of the children of pharmacological property to have with paper
The fountain height of effective component solution is the 25% of original paper quality, and obtaining after dry at 60 DEG C has the tender sensitive skin of the children of pharmacological property
Use paper.
The preparation method of the prescriptions worth thousand gold dregs of a decoction is referred to a kind of manufacturing method of ' Qianjin ' capsule to treat ganopathy of patent ZL99115683.8,
The prescriptions worth thousand gold dregs of a decoction are very heavy group, cherokee rose root, Caulis Spatholobi, single side needle, leatherleaf mahonia, Herba Andrographitis, Radix Angelicae Sinensis and Radix Codonopsis pass through water or ethyl alcohol
Dregs of a decoction mixing after extraction.The partial size of the prescriptions worth thousand gold dregs of a decoction is less than 2.5cm.
Biological complex enzyme is prepared by the raw material of following weight percent: whiterot fungi 10%, Ficus virens
15%, zytase 24% and laccase 15%.
Embodiment 4
The present embodiment provides a kind of preparation methods of the tender sensitive skin paper of children, specific steps are as follows:
S1. it pre-processes: the prescriptions worth thousand gold dregs of a decoction that water content is 35% being subjected to Micro-wave pretreatment, microwave power is
500W, microwave time are 35min, for use；
S2. ferment: the prescriptions worth thousand gold dregs of a decoction deionized water that step S1 is obtained is impregnated and washing, in washing water is
Property, it is dehydrated, dispersed, then placed it in fermentation vat, 2 kg/ton of biological complex enzyme material are added, after mixing evenly,
It under aerobic conditions, is handled again using microwave radiation, microwave power 1400W, the microwave time is 100min, to prescriptions worth thousand gold
Dregs of a decoction material carries out fermentation process, is filtered after fermentation, obtains filtrate and filtrate；
S3. it washs: the filtrate in step S2 is impregnated repeatedly, disperses and washed with water, in washing water is
Property after, be dehydrated, sealing, obtain dreg fibers after dry；
S4. the extraction of effective component: being evaporated concentration to the filtrate in step S2, and evaporating temperature is 105 DEG C, is had
There is effective component solution；
S5. papermaking: fiber made from step S3 is beaten, beating degree 38oThen SR manufactures paper with pulp, using shallow lake
Powder obtains body paper after dry as Cypres.The water content of body paper is 92%.Cypres concentration is 9%, coating weight
For 0.9g/m2。
S6. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
Effective component solution in basic medical fluid and step S4 is mixed to get medical fluid；
By medicine liquid spray in the body paper surface of step S5, obtaining after dry, there is the tender sensitive skin of the children of pharmacological property to have with paper
The fountain height of effective component solution is the 25% of original paper quality, and obtaining after dry at 65 DEG C has the tender sensitive skin of the children of pharmacological property
Use paper.
The preparation method of the prescriptions worth thousand gold dregs of a decoction is referred to a kind of manufacturing method of ' Qianjin ' capsule to treat ganopathy of patent ZL99115683.8,
The prescriptions worth thousand gold dregs of a decoction are very heavy group, cherokee rose root, Caulis Spatholobi, single side needle, leatherleaf mahonia, Herba Andrographitis, Radix Angelicae Sinensis and Radix Codonopsis pass through water or ethyl alcohol
Dregs of a decoction mixing after extraction.The partial size of the prescriptions worth thousand gold dregs of a decoction is less than 3cm.
Biological complex enzyme is prepared by the raw material of following weight percent: whiterot fungi 8%, Ficus virens
18%, zytase 26% and laccase 18%.
Comparative example 1
The present embodiment provides a kind of preparation methods of the tender sensitive skin paper of children, specific steps are as follows:
S1. it ferments: by the prescriptions worth thousand gold dregs of a decoction deionized water immersion and washing, until washing water is neutrality, being dehydrated, divided
It dissipates, then places it in fermentation vat, 1 kg/ton of biological complex enzyme material is added, after mixing evenly, under aerobic conditions, again
It is handled using microwave radiation, microwave power 1200W, the microwave time is 120min, is sent out prescriptions worth thousand gold dregs of a decoction material
Ferment processing, is filtered after fermentation, obtains filtrate and filtrate；
S2. it washs: the filtrate in step S1 is impregnated repeatedly, disperses and washed with water, in washing water is
Property after, be dehydrated, sealing, obtain dreg fibers after dry；
S3. the extraction of effective component: being evaporated concentration for the filtrate in step S1, and evaporating temperature is 105 DEG C, is had
There is effective component solution；
S4. papermaking: fiber made from step S2 is beaten, beating degree 40oThen SR manufactures paper with pulp, using shallow lake
Powder obtains body paper after dry as Cypres.The water content of body paper is 92%.Cypres concentration is 9%, coating weight
For 0.8g/m2。
S5. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
Effective component solution in basic medical fluid and step S4 is mixed to get medical fluid；
By medicine liquid spray in the body paper surface of step S4, obtaining after dry, there is the tender sensitive skin of the children of pharmacological property to have with paper
The fountain height of effective component solution is the 25% of original paper quality, and obtaining after dry at 60 DEG C has the tender sensitive skin of the children of pharmacological property
Use paper.
Comparative example 2
The present embodiment provides a kind of preparation methods of the tender sensitive skin paper of children, specific steps are as follows:
S1. it pre-processes: the prescriptions worth thousand gold dregs of a decoction that water content is 30% being subjected to Micro-wave pretreatment, microwave power is
600W, microwave time are 30min, for use；
S2. ferment: the prescriptions worth thousand gold dregs of a decoction deionized water that step S1 is obtained is impregnated and washing, in washing water is
Property, it is dehydrated, dispersed, then placed it in fermentation vat, 1 kg/ton of biological complex enzyme material is added, after mixing evenly,
It under aerobic conditions, is handled again using microwave radiation, microwave power 1200W, the microwave time is 120min, to prescriptions worth thousand gold
Dregs of a decoction material carries out fermentation process, is filtered after fermentation, obtains filtrate and filtrate；
S3. it washs: the filtrate in step S2 is impregnated repeatedly, disperses and washed with water, in washing water is
Property after, dehydration, sealing obtain dreg fibers after dry；
S4. papermaking: fiber made from step S3 is beaten, beating degree 40oThen SR manufactures paper with pulp, using shallow lake
Powder obtains body paper after dry as Cypres.The water content of body paper is 92%.Cypres concentration is 9%, coating weight
For 0.8g/m2。
Comparative example 3~6
The process conditions of comparative example 3~6 are similar to Example 3, the difference is that following technique is respectively adopted in step S1
Condition:
| Prescriptions worth thousand gold dregs of a decoction water content, % | Microwave power, w | Microwave time, min | |
| Comparative example 3 | 24 | 350 | 40 |
| Comparative example 4 | 24 | 600 | 30 |
| Comparative example 5 | 46 | 850 | 20 |
| Comparative example 6 | 30 | 350 | 40 |
Comparative example 7~9
The process conditions of comparative example 7~9 are similar to Example 3, the difference is that following technique is respectively adopted in step S2
Condition:
| Microwave power, w | Microwave time, min | |
| Comparative example 7 | 850 | 40 |
| Comparative example 8 | 1200 | 100 |
| Comparative example 9 | 850 | 240 |
Comparative example 10~13
The process conditions of comparative example 10~13 are similar to Example 3, the difference is that following work is respectively adopted in step S2
Skill condition:
| Whiterot fungi, % | Ficus virens, % | Zytase, % | Laccase, % | |
| Comparative example 10 | 4 | 20 | 24 | 10 |
| Comparative example 11 | 12 | 8 | 24 | 20 |
| Comparative example 12 | 10 | 12 | 18 | 15 |
| Comparative example 13 | 6 | 15 | 30 | 6 |
Comparative example 14~15
The process conditions of comparative example 14~15 are similar to Example 3, the difference is that following work is respectively adopted in step S4
Skill condition:
| The temperature of concentration, DEG C | |
| Comparative example 14 | 95 |
| Comparative example 15 | 115 |
Comparative example 16~18
The process conditions of comparative example 16~18 are similar to Example 3, the difference is that following work is respectively adopted in step S6
Skill condition:
| Fountain height, % | Drying temperature, DEG C | |
| Comparative example 16 | 30 | 60 |
| Comparative example 17 | 28 | 60 |
| Comparative example 18 | 30 | 67 |
Comparative example 19~21
The process conditions of comparative example 19~21 are similar to Example 3, the difference is that following work is respectively adopted in step S5
Skill condition:
Kappa number and measuring brightness are carried out to the fiber that the preparation method of Examples 1 to 4 and comparative example 1~21 obtains,
In, Kappa number is measured according to standard GB/T/T 1546-2004, and whiteness is according to standard GB/T/T 8940.2-1988
It is measured, paper strength, pliability is measured, wherein pliability is carried out according to standard GB/T/T 8942-1988
Measurement, paper strength are measured according to standard GB/T/T20808-2006.It the results are shown in Table 1.
Table 1
It is found that the present invention is using the dregs of a decoction as plant material, using microwave irradiation to prescriptions worth thousand gold compared with comparative example 1 and 3~6
The dregs of a decoction are pre-processed, and the lignin components being very beneficial in the dregs of a decoction are separated, and plant cell wall tissue is made to generate micropore knot
Structure is more advantageous to the chemical reaction of subsequent delignification, is prepared using bioanalysis dregs of a decoction pulping process provided by the invention
Paper pulp, residual lignin content is low, and Kappa number is respectively less than 10, and paper pliability is good.
It is found that extracting effective component in the slave waste liquid of present invention initiative compared with comparative example 2, and it is applied to fiber
On, medical value is effectively raised, the fiber product of acquisition is to shigella dysenteriae, Escherichia coli, S. aureus L-forms, streptococcus and Ah meter
Bar protozoon plays the role of effectively inhibiting to kill.
It is found that invention utilizes microwave radiation using the dregs of a decoction as plant material compared with comparative example 7~9 and comparative example 10~13
Technology directly prepares bleached pulp, in conjunction with the synergistic effect between strain each in biological complex enzyme and enzyme, is not only able to the degradation dregs of a decoction
In a variety of lignins, additionally it is possible to remove the chromophoric group in paper pulp, improve bleaching efficiency；The present invention from environmental protection angle in a creative way
Solve the problems, such as that existing bioanalysis slurrying processing whiteness is low, whiteness can reach 80% or more.
It is found that influence of the technique to effective component for extracting effective component in waste liquid is very big compared with comparative example 14~15,
Especially influence of the temperature to the viscosity of waste liquid etc., so that the volatility of effective component is changed.
It is found that the spray processing of effective component can be in the Adsorption Effect drug effect to effective component compared with comparative example 16~18
Ingredient volatilization and the drying and adsorption capacity of fiber.
It is found that being resisted using its beating degree of fiber made of the dregs of a decoction and coating process to paper compared with comparative example 19~21
The features such as extensional can have a significant impact, and dreg fibers are short more with heteroproteose cell there are this fibre length.
Microbiological indicator test
Microbial indicators detected, microorganism are carried out with paper to the tender sensitive skin of children that the preparation method of Examples 1 to 4 obtains
Index is measured according to standard GB/T/T 26174-2010.It the results are shown in Table 2.
Table 2
Skin irritation test
By taking the tender sensitive skin paper of children prepared by the method for Examples 1 to 4 as an example, the tender sensitive skin paper of observation children is to skin
The irritation and allergic reaction of skin provide reference to evaluate its safety.
(1) skin irritation test is carried out using rabbit, divides intact skin group and damage skin group, for 24 hours by rabbit before test
Back backbone diamond wool shaves off, and after being kept in contact 1d, continuous 7d with the tender sensitive skin paper of children and rabbit skin and mucosa respectively, sees
Examining skin, whether there is or not the stimulate the reactions such as erythema, oedema.
(2) skin allergy experiment is carried out using cavy, is kept with the tender sensitive skin paper of children and guinea pig skin mucous membrane weekly
Contact 2 times contacts 4h or more every time, and continuous 3 weeks, whether there is or not the allergic reactions such as erythema, oedema for observation skin.
Experimental result:
The intact skin and damaged skin of rabbit, remove after being intended for single use or be used for multiple times for 24 hours, respectively at 1,24,48,
72h observation, is showed no erythema and oedema, and stimulate the reaction mean scores are < 0.5, nonirritant.
In guinea pig skin allergic experiment, does not occur the cutaneous anaphylaxises such as the obvious erythema of skin, oedema and other are systemic
Allergic reaction.
Therefore, the tender sensitive skin paper of children of the invention will not cause irritation anti-rabbit intact skin and damage skin
It answers, to guinea pig skin without allergic reaction, there is good cutaneous safety.
Clinical trial
Using the tender sensitive skin paper of the children of embodiment 1 and 4 as experimental material, with it is commercially available commonly with paper as a control group, choosing
Selecting the children that the age is 4~8 years old, totally 90 people, age-based layer are randomly divided into 3 groups, and every group of 30 people, after 1 week, detection is of the invention
The tender sensitive skin paper of the children of offer counts the stimulation implementations of skin and mucosa to its experimental result.It the results are shown in Table
3。
Table 3
As the result is shown: thering are 10 children (to account for total number of persons using there is irritative response after the product of control group in control group
66.7%), irritative response does not occur in embodiment 1 and embodiment 4.As it can be seen that the tender sensitive skin of children provided by the invention
With paper to skin and mucosa without any irritation and side effect.
Detailed process equipment and processing step of the invention that the present invention is explained by the above embodiments, those skilled in the art
Member is not it should be appreciated that the present invention is limited by above-described embodiment, and the above embodiments and description only describe the present invention
Principle, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, this is to this field
It is it will be apparent that these changes and improvements all fall within the protetion scope of the claimed invention for technical staff.
Claims (10)
1. a kind of preparation method of the tender sensitive skin paper of children, which comprises the following steps:
S1. pre-process: by water content be 25% ~ 45% the prescriptions worth thousand gold dregs of a decoction carry out Micro-wave pretreatment, microwave power be 400 ~
700W, microwave time are 20 ~ 40 min, for use；
S2. ferment: the prescriptions worth thousand gold dregs of a decoction deionized water that step S1 is obtained is impregnated and washing, until washing water is neutrality, into
Row dehydration, dispersion, then place it in fermentation vat, biological complex enzyme are added, after mixing evenly, under aerobic conditions, again
It is handled using microwave radiation, microwave power is 1000 ~ 1500 W, and the microwave time is 60 ~ 200 min, to the prescriptions worth thousand gold dregs of a decoction
Material carries out fermentation process, is filtered after fermentation, obtains filtrate and filtrate；
S3. it washs: the filtrate in step S2 is impregnated repeatedly, disperses and washed with water, until after washing water is neutral,
Dehydration, sealing obtain dreg fibers after dry；
S4. the extraction of effective component: concentration is evaporated to the filtrate in step S2, obtaining has effective component solution；
S5. papermaking: fiber made from step S3 is manufactured paper with pulp, body paper is obtained；
S6. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: Radix Angelicae Sinensis, Radix Codonopsis, the incorporation of Herba Andrographitis and single side needle are each
It is the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；It will be basic
Effective component solution in medical fluid and step S4 is mixed to get medical fluid；
By the body paper surface of medicine liquid spray and step S5, obtaining after dry has the tender sensitive skin paper of the children of pharmacological property.
2. the preparation method of young tender sensitive skin paper according to claim 1, which is characterized in that the prescriptions worth thousand gold dregs of a decoction are
Very heavy group, cherokee rose root, Caulis Spatholobi, single side needle, leatherleaf mahonia, Herba Andrographitis, Radix Angelicae Sinensis and Radix Codonopsis are remaining after water or ethyl alcohol extract
The dregs of a decoction.
3. the preparation method of young tender sensitive skin paper according to claim 1, which is characterized in that prescriptions worth thousand gold in step S1
The water content of the dregs of a decoction is 30% ~ 35%, and the power of the microwave radiation is 600 ~ 700 W, and the time is 20 ~ 30 min.
4. the preparation method of young tender sensitive skin paper according to claim 1, which is characterized in that biology described in step S2
Complex enzyme is prepared by the raw material of following weight percent: whiterot fungi 6 ~ 12%, Ficus virens 12 ~ 20%, xylan
Enzyme 24 ~ 30% and laccase 10 ~ 20%.
5. the preparation method of young tender sensitive skin paper according to claim 1, which is characterized in that micro- described in step S2
The power of wave radiation is 1200 ~ 1500 W, and the time is 120 ~ 200 min.
6. the preparation method of young tender sensitive skin paper according to claim 1, which is characterized in that evaporating temperature in step S4
It is 100 ~ 110 DEG C.
7. the preparation method of young tender sensitive skin paper according to claim 1, which is characterized in that S3 is made in step S5
Fiber be beaten, beating degree be 35 ~ 45oThen SR manufactures paper with pulp, using starch as Cypres, obtain after dry
To body paper.
8. the preparation method of young tender sensitive skin paper according to claim 1, which is characterized in that in step S6, by step
For effective component spray solution in S4 in the body paper surface of step S5, obtaining after dry has the tender sensitive skin paper of the children of pharmacological property
Fountain height with effective component solution is the 20% ~ 30% of original paper quality, obtains the children with pharmacological property after dry at 60 ~ 65 DEG C
Tender sensitivity skin paper.
9. a kind of tender sensitive skin of children of the preparation method preparation by the tender sensitive skin paper of any one of claim 1 ~ 8 children
Use paper.
10. a kind of tender sensitive skin paper of children described in claim 9 is preparing the application in amenities or medical supplies.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099827A (en) * | 1994-07-01 | 1995-03-08 | 黄庆文 | Toilet paper with traditional Chinese medicine and making method |
| CN1251763A (en) * | 1998-10-21 | 2000-05-03 | 株洲千金药业股份公司 | Process for preparing Chinese medicine 'Qianjin tablets' for treating gynopathy |
| CN104005247A (en) * | 2014-05-15 | 2014-08-27 | 昆明理工大学 | Microwave-assisted preparation method of bagasse bleached pulp |
| CN104179055A (en) * | 2014-07-18 | 2014-12-03 | 刘秀平 | Grass fiber bio-separation compound preparation and application method thereof |
| CN106269818A (en) * | 2016-11-11 | 2017-01-04 | 无限极（中国）有限公司 | The processing method of a kind of Chinese medicine dreg and application |
-
2017
- 2017-12-12 CN CN201711326351.1A patent/CN109914156A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099827A (en) * | 1994-07-01 | 1995-03-08 | 黄庆文 | Toilet paper with traditional Chinese medicine and making method |
| CN1251763A (en) * | 1998-10-21 | 2000-05-03 | 株洲千金药业股份公司 | Process for preparing Chinese medicine 'Qianjin tablets' for treating gynopathy |
| CN104005247A (en) * | 2014-05-15 | 2014-08-27 | 昆明理工大学 | Microwave-assisted preparation method of bagasse bleached pulp |
| CN104179055A (en) * | 2014-07-18 | 2014-12-03 | 刘秀平 | Grass fiber bio-separation compound preparation and application method thereof |
| CN106269818A (en) * | 2016-11-11 | 2017-01-04 | 无限极（中国）有限公司 | The processing method of a kind of Chinese medicine dreg and application |
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Application publication date: 20190621 |