CN109913061A - A kind of imitative copper ring water conservation paint and preparation method thereof - Google Patents
A kind of imitative copper ring water conservation paint and preparation method thereof Download PDFInfo
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- CN109913061A CN109913061A CN201910025398.7A CN201910025398A CN109913061A CN 109913061 A CN109913061 A CN 109913061A CN 201910025398 A CN201910025398 A CN 201910025398A CN 109913061 A CN109913061 A CN 109913061A
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- copper ring
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- water conservation
- imitative copper
- ring water
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Abstract
The imitative copper ring water conservation paint and preparation method thereof that the present invention provides a kind of suitable for sculpture, model, craftwork, wall, part modification etc..The imitative copper ring water conservation paint is one-component product, imitates copper paint by pickling or using multicomponent solvent type compared to tradition to make for imitative copper effect, is more advantageous to construction, can greatly improve worker's production efficiency, save construction cost.The preparation method devises a set of dedicated technological process of production according to the physicochemical properties of different material, use the preparation method, the performance of each component can be performed to preferable level, finally obtained with excellent adhesive force, the imitative copper ring water conservation paint of hardness and impact resistance.
Description
Technical field
The invention belongs to technical field of paint preparation, and in particular to a kind of imitative copper ring water conservation paint and preparation method thereof.
Background technique
Imitative copper effect is that the effect of the pig copper is imitated by special processing mode, is very suitable to be made in sculpture, model, technique
The positions such as product, wall, part modification.Traditional production imitates copper effect and generally uses pickling or use multi-component solvent type
Coating had not only polluted environment but also had been unfavorable for constructing.It develops a with excellent adhesive force, the imitative copper ring guarantor of hardness and impact resistance
Sealing wax can reduce industry for the pollution of environment but also improve production efficiency.
Summary of the invention
Of the existing technology in order to solve the problems, such as, the present invention provides one kind to be suitable for sculpture, model, craftwork, back
Imitative copper ring water conservation paint of view wall, part modification etc. and preparation method thereof.
The object of the present invention is to provide a kind of imitative copper ring water conservation paints.
Another object of the present invention is to provide a kind of preparation method of imitative copper ring water conservation paint.
Imitative copper ring water conservation paint according to the present invention, the raw material including following parts by weight: water-based acrylic resin 50-60
Part, 0.3-0.5 parts of neutralizer, 0.8-1.2 parts of dispersing agent, 0.1-0.2 parts of defoaming agent, 0.3-0.5 parts of levelling agent, thickener 0.3-
0.6 part, 0.1-0.2 parts of carbon black, 6-10 parts of iron oxide yellow, 10-20 parts of Cu-Zn alloy powder, 0.5-1 parts of anti-settling agent and deionized water 20-
30 parts.
Imitative copper ring water conservation paint according to the present invention, wherein the neutralizer is dimethylethanolamine.
Imitative copper ring water conservation paint according to the present invention, wherein the dispersing agent is water paint high molecular weight wetting and dispersing
Agent.
Imitative copper ring water conservation paint according to the present invention, wherein the defoaming agent is that hydrophobic solid and brokenly bubble polysiloxanes exist
Mixture in polyglycols.
Imitative copper ring water conservation paint according to the present invention, wherein the levelling agent is the polyacrylate for being adsorbed in silica.
Imitative copper ring water conservation paint according to the present invention, wherein the thickener is polyurethane thickener.
Imitative copper ring water conservation paint according to the present invention, wherein the anti-settling agent is organobentonite.
Imitative copper ring water conservation paint according to the present invention, wherein the imitative copper ring water conservation paint further includes butanol etherification amino resins
4-8 parts, 0.1-0.3 parts and butyl acetate 0.3-0.5 parts of butyl glycol ether.
The preparation method of copper ring water conservation paint is imitated according to the present invention, and the preparation method comprises the following steps:
A, according to the raw material proportioning, deionized water and neutralizer are mixed, revolving speed 500-800r/min stirring is being stirred
Dispersing agent, defoaming agent, carbon black, iron oxide yellow, Cu-Zn alloy powder and anti-settling agent are sequentially added in the process, after the completion of addition, revolving speed 900-
1100r/min disperses 20-40 minutes, then grinds to fineness≤30 micron, obtains slurry；
B, water-based acrylic resin is stirred at revolving speed 500-800r/min, step A is added in whipping process and obtains
Slurry, stirring sequentially adds levelling agent and thickener after 5-15 minute, stirs 20-40 minutes then to get to the imitative copper
Environmentally friendly sealing wax.
When containing butanol etherification amino resins, butyl glycol ether and butyl acetate in raw material, the imitative copper ring water conservation paint
Preparation method the following steps are included:
A, according to the raw material proportioning, deionized water and neutralizer are mixed, revolving speed 500-800r/min stirring is being stirred
Dispersing agent, defoaming agent, carbon black, iron oxide yellow, Cu-Zn alloy powder and anti-settling agent are sequentially added in the process, after the completion of addition, revolving speed 900-
1100r/min disperses 20-40 minutes, then grinds to fineness≤30 micron, obtains slurry；
B, water-based acrylic resin is stirred at revolving speed 500-800r/min, step A is added in whipping process and obtains
Slurry, stirring 5-15 minutes after sequentially add levelling agent, thickener, butanol etherification amino resins, butyl glycol ether and acetic acid
Then butyl ester is stirred 20-40 minutes and is painted to get to the imitative copper ring water conservation.
The invention has the benefit that
1, the present invention provides a kind of imitative copper ring water conservation paints, and the imitative copper ring water conservation paint is one-component product, compared to biography
System imitates copper paint by pickling or using multicomponent solvent type to make for imitative copper effect, is more advantageous to construction, can be significantly
Worker's production efficiency is improved, construction cost is saved.
2, the imitative copper ring water conservation paint, based on water-based acrylic resin, is aided with dimethylethanolamine, butanol etherification
The components such as amino resins, butyl glycol ether and butyl acetate, various ingredients cooperate with each other, and obtained imitative copper ring water conservation paint has excellent
Different adhesive force, hardness and impact resistance have very high use and economic value.
3, the imitative copper ring water conservation paint, using carbon black, iron oxide yellow and a variety of pigment combinations of Cu-Zn alloy powder, while according to pigment
Color, with the compatibility and dispersibility of other components, emphasis deployed the ratio of pigment, obtained imitative copper ring water conservation paint color
It is true true to nature, there is excellent decorative effect.
4, the present invention also provides the preparation methods of the imitative copper ring water conservation paint, according to the physical chemistry of different material
Matter devises a set of dedicated technological process of production, using the preparation method, can perform to the performance of each component preferably
Level, finally obtain with excellent adhesive force, the imitative copper ring of hardness and impact resistance is retained paint.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, technical solution of the present invention will be carried out below
Detailed description.Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Base
Embodiment in the present invention, those of ordinary skill in the art are obtained all without making creative work
Other embodiment belongs to the range that the present invention is protected.
Need to illustrate when, in embodiment of the invention below, the raw material that uses specifically:
The water-based acrylic resin is 5345 resins with Dehua work；
The neutralizer is dimethylethanolamine；
The dispersing agent is the BYK194 dispersing agent of BYK company, Germany；
The defoaming agent is the BYK028 defoaming agent of BYK company, Germany；
The levelling agent is the BYK346 levelling agent of BYK company, Germany；
The thickener is the RM-8W thickener of Dow company；
The anti-settling agent is this organobentonite of hamming EW.
Embodiment 1
A kind of imitative copper ring water conservation paint, the raw material including following parts by weight: 50 parts of water-based acrylic resin, neutralizer 0.5
Part, 0.8 part of dispersing agent, 0.2 part of defoaming agent, 0.3 part of levelling agent, 0.6 part of thickener, 0.1 part of carbon black, 10 parts of iron oxide yellow, copper
10 parts of bronze, 1 part of anti-settling agent and 20 parts of deionized water.
The preparation method of the imitative copper ring water conservation paint comprises the steps of:
A, according to the raw material proportioning, deionized water and neutralizer are mixed, revolving speed 800r/min stirring, in whipping process
In sequentially add dispersing agent, defoaming agent, carbon black, iron oxide yellow, Cu-Zn alloy powder and anti-settling agent, after the completion of addition, revolving speed 900r/min
Dispersion 40 minutes, then grinds to fineness≤30 micron, obtains slurry；
B, water-based acrylic resin is stirred at revolving speed 500r/min, the slurry that step A is obtained is added in whipping process
Material, stirring sequentially added levelling agent and thickener after 15 minutes, then stirred 20 minutes and were retained paint to get to the imitative copper ring.
Embodiment 2
A kind of imitative copper ring water conservation paint, the raw material including following parts by weight: 60 parts of water-based acrylic resin, neutralizer 0.3
Part, 1.2 parts of dispersing agent, 0.1 part of defoaming agent, 0.5 part of levelling agent, 0.3 part of thickener, 0.2 part of carbon black, 6 parts of iron oxide yellow, copper gold
20 parts of powder, 0.5 part of anti-settling agent and 30 parts of deionized water.
The preparation method of the imitative copper ring water conservation paint comprises the steps of:
A, according to the raw material proportioning, deionized water and neutralizer are mixed, revolving speed 500r/min stirring, in whipping process
In sequentially add dispersing agent, defoaming agent, carbon black, iron oxide yellow, Cu-Zn alloy powder and anti-settling agent, after the completion of addition, revolving speed 1100r/min
Dispersion 20 minutes, then grinds to fineness≤30 micron, obtains slurry；
B, water-based acrylic resin is stirred at revolving speed 800r/min, the slurry that step A is obtained is added in whipping process
Material, stirring sequentially add levelling agent and thickener after five minutes, then stir 40 minutes and are retained paint to get to the imitative copper ring.
Embodiment 3
A kind of imitative copper ring water conservation paint, the raw material including following parts by weight: 55 parts of water-based acrylic resin, neutralizer 0.4
Part, 1 part of dispersing agent, 0.15 part of defoaming agent, 0.4 part of levelling agent, 0.45 part of thickener, 0.15 part of carbon black, 8 parts of iron oxide yellow, copper
15 parts of bronze, 0.75 part of anti-settling agent and 25 parts of deionized water.
The preparation method of the imitative copper ring water conservation paint comprises the steps of:
A, according to the raw material proportioning, deionized water and neutralizer are mixed, revolving speed 650r/min stirring, in whipping process
In sequentially add dispersing agent, defoaming agent, carbon black, iron oxide yellow, Cu-Zn alloy powder and anti-settling agent, after the completion of addition, revolving speed 1000r/min
Dispersion 30 minutes, then grinds to fineness≤30 micron, obtains slurry；
B, water-based acrylic resin is stirred at revolving speed 650r/min, the slurry that step A is obtained is added in whipping process
Material, stirring sequentially add levelling agent and thickener after ten minutes, then stir 30 minutes and are retained paint to get to the imitative copper ring.
Embodiment 4
A kind of imitative copper ring water conservation paint, the raw material including following parts by weight: 50 parts of water-based acrylic resin, neutralizer 0.5
Part, 0.8 part of dispersing agent, 0.2 part of defoaming agent, 0.3 part of levelling agent, 0.6 part of thickener, 0.1 part of carbon black, 10 parts of iron oxide yellow, copper
10 parts of bronze, 1 part of anti-settling agent, 4 parts of butanol etherification amino resins, 0.3 part of butyl glycol ether, 0.3 part of butyl acetate and deionization
30 parts of water.
The preparation method of the imitative copper ring water conservation paint comprises the steps of:
A, according to the raw material proportioning, deionized water and neutralizer are mixed, revolving speed 500r/min stirring, in whipping process
In sequentially add dispersing agent, defoaming agent, carbon black, iron oxide yellow, Cu-Zn alloy powder and anti-settling agent, after the completion of addition, revolving speed 1100r/min
Dispersion 20 minutes, then grinds to fineness≤30 micron, obtains slurry；
B, water-based acrylic resin is stirred at revolving speed 800r/min, the slurry that step A is obtained is added in whipping process
Material, stirring sequentially add levelling agent, thickener, butanol etherification amino resins, butyl glycol ether and butyl acetate after five minutes, so
It stirs 40 minutes and is painted to get to the imitative copper ring water conservation afterwards.
Embodiment 5
A kind of imitative copper ring water conservation paint, the raw material including following parts by weight: 60 parts of water-based acrylic resin, neutralizer 0.3
Part, 1.2 parts of dispersing agent, 0.1 part of defoaming agent, 0.5 part of levelling agent, 0.3 part of thickener, 0.2 part of carbon black, 6 parts of iron oxide yellow, copper gold
20 parts of powder, 0.5 part of anti-settling agent, 8 parts of butanol etherification amino resins, 0.1 part of butyl glycol ether, 0.5 part of butyl acetate and deionization
20 parts of water.
The preparation method of the imitative copper ring water conservation paint comprises the steps of:
A, according to the raw material proportioning, deionized water and neutralizer are mixed, revolving speed 800r/min stirring, in whipping process
In sequentially add dispersing agent, defoaming agent, carbon black, iron oxide yellow, Cu-Zn alloy powder and anti-settling agent, after the completion of addition, revolving speed 900r/min
Dispersion 40 minutes, then grinds to fineness≤30 micron, obtains slurry；
B, water-based acrylic resin is stirred at revolving speed 500r/min, the slurry that step A is obtained is added in whipping process
Material, stirring sequentially added levelling agent, thickener, butanol etherification amino resins, butyl glycol ether and butyl acetate after 15 minutes, so
It stirs 20 minutes and is painted to get to the imitative copper ring water conservation afterwards.
Embodiment 6
A kind of imitative copper ring water conservation paint, the raw material including following parts by weight: 55 parts of water-based acrylic resin, neutralizer 0.4
Part, 1 part of dispersing agent, 0.15 part of defoaming agent, 0.4 part of levelling agent, 0.45 part of thickener, 0.15 part of carbon black, 8 parts of iron oxide yellow, copper
15 parts of bronze, 0.75 part of anti-settling agent, 6 parts of butanol etherification amino resins, 0.2 part of butyl glycol ether, 0.4 part of butyl acetate and go from
25 parts of sub- water.
The preparation method of the imitative copper ring water conservation paint comprises the steps of:
A, according to the raw material proportioning, deionized water and neutralizer are mixed, revolving speed 650r/min stirring, in whipping process
In sequentially add dispersing agent, defoaming agent, carbon black, iron oxide yellow, Cu-Zn alloy powder and anti-settling agent, after the completion of addition, revolving speed 1000r/min
Dispersion 30 minutes, then grinds to fineness≤30 micron, obtains slurry；
B, water-based acrylic resin is stirred at revolving speed 650r/min, the slurry that step A is obtained is added in whipping process
Material, stirring sequentially add levelling agent, thickener, butanol etherification amino resins, butyl glycol ether and butyl acetate after ten minutes, so
It stirs 30 minutes and is painted to get to the imitative copper ring water conservation afterwards.
To the imitative copper ring water conservation Qi Jinhang test that embodiment 1,3,5 and 6 obtains, test result is as shown in table 1
Table 1: experimental result table
From table 1, it can be seen that imitative copper ring provided by the invention water conservation paint, there is excellent dicoration, adhesive force, hardness and
Impact resistance has very high technology and commercial value.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
Those familiar with the art in the technical scope disclosed by the present invention, can easily think of the change or the replacement, and should all contain
Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.
Claims (10)
1. a kind of imitative copper ring water conservation paint, which is characterized in that the imitative copper ring water conservation enamel-cover includes the raw material of following parts by weight: aqueous
50-60 parts of acrylic resin, 0.3-0.5 parts of neutralizer, 0.8-1.2 parts of dispersing agent, 0.1-0.2 parts of defoaming agent, levelling agent 0.3-
0.5 part, 0.3-0.6 parts of thickener, 0.1-0.2 parts of carbon black, 6-10 parts of iron oxide yellow, 10-20 parts of Cu-Zn alloy powder, anti-settling agent 0.5-1
Part and 20-30 parts of deionized water.
2. imitative copper ring water conservation paint according to claim 1, which is characterized in that the neutralizer is dimethylethanolamine.
3. imitative copper ring water conservation paint according to claim 1, which is characterized in that the dispersing agent is water paint macromolecule
Measure wetting dispersing agent.
4. imitative copper ring water conservation paint according to claim 1, which is characterized in that the defoaming agent is hydrophobic solid and brokenly bubble
Mixture of the polysiloxanes in polyglycols.
5. imitative copper ring water conservation paint according to claim 1, which is characterized in that the levelling agent is to be adsorbed in silica
Polyacrylate.
6. imitative copper ring water conservation paint according to claim 1, which is characterized in that the thickener is polyurethane thickener.
7. imitative copper ring water conservation paint according to claim 1, which is characterized in that the anti-settling agent is organobentonite.
8. -7 any imitative copper rings are retained paint according to claim 1, which is characterized in that the imitative copper ring water conservation, which is painted, further includes
4-8 parts of butanol etherification amino resins, 0.1-0.3 parts and butyl acetate 0.3-0.5 parts of butyl glycol ether.
9. a kind of preparation method of any imitative copper ring water conservation paint of claim 1-7, which is characterized in that the preparation method packet
Include following steps:
A, according to the raw material proportioning, deionized water and neutralizer are mixed, revolving speed 500-800r/min stirring, in whipping process
In sequentially add dispersing agent, defoaming agent, carbon black, iron oxide yellow, Cu-Zn alloy powder and anti-settling agent, after the completion of addition, revolving speed 900-
1100r/min disperses 20-40 minutes, then grinds to fineness≤30 micron, obtains slurry；
B, water-based acrylic resin is stirred at revolving speed 500-800r/min, the slurry that step A is obtained is added in whipping process
Material, stirring sequentially added levelling agent and thickener after 5-15 minutes, then stirred 20-40 minutes and protected to get to the imitative copper ring
Sealing wax.
10. described in a kind of claim 8 imitate copper ring water conservation paint preparation method, which is characterized in that the preparation method include with
Lower step:
A, according to the raw material proportioning, deionized water and neutralizer are mixed, revolving speed 500-800r/min stirring, in whipping process
In sequentially add dispersing agent, defoaming agent, carbon black, iron oxide yellow, Cu-Zn alloy powder and anti-settling agent, after the completion of addition, revolving speed 900-
1100r/min disperses 20-40 minutes, then grinds to fineness≤30 micron, obtains slurry；
B, water-based acrylic resin is stirred at revolving speed 500-800r/min, the slurry that step A is obtained is added in whipping process
Material, stirring sequentially added levelling agent, thickener, butanol etherification amino resins, butyl glycol ether and butyl acetate after 5-15 minutes,
Then it stirs 20-40 minutes and is painted to get to the imitative copper ring water conservation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910025398.7A CN109913061A (en) | 2019-01-11 | 2019-01-11 | A kind of imitative copper ring water conservation paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910025398.7A CN109913061A (en) | 2019-01-11 | 2019-01-11 | A kind of imitative copper ring water conservation paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN109913061A true CN109913061A (en) | 2019-06-21 |
Family
ID=66960236
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910025398.7A Pending CN109913061A (en) | 2019-01-11 | 2019-01-11 | A kind of imitative copper ring water conservation paint and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022088118A1 (en) * | 2020-10-30 | 2022-05-05 | 河北比尔尼克新材料科技股份有限公司 | Brushed copper-imitation water-based paint, preparation method therefor and use thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1626587A (en) * | 2003-12-10 | 2005-06-15 | 中国科学院成都有机化学有限公司 | Water born paint of imitating metal in use for plastic painting dressing |
| CN101962508A (en) * | 2010-07-12 | 2011-02-02 | 深圳市天健涂料科技开发有限公司 | Imitation copper paint and preparation method and construction technology thereof |
| WO2012013663A2 (en) * | 2010-07-28 | 2012-02-02 | Basf Se | Use of perlite based effect pigments for finishes with antique, or patina appearance |
| CN102850862A (en) * | 2012-08-31 | 2013-01-02 | 芜湖县双宝建材有限公司 | Golden color paint and preparation process thereof |
-
2019
- 2019-01-11 CN CN201910025398.7A patent/CN109913061A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1626587A (en) * | 2003-12-10 | 2005-06-15 | 中国科学院成都有机化学有限公司 | Water born paint of imitating metal in use for plastic painting dressing |
| CN101962508A (en) * | 2010-07-12 | 2011-02-02 | 深圳市天健涂料科技开发有限公司 | Imitation copper paint and preparation method and construction technology thereof |
| WO2012013663A2 (en) * | 2010-07-28 | 2012-02-02 | Basf Se | Use of perlite based effect pigments for finishes with antique, or patina appearance |
| CN102850862A (en) * | 2012-08-31 | 2013-01-02 | 芜湖县双宝建材有限公司 | Golden color paint and preparation process thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022088118A1 (en) * | 2020-10-30 | 2022-05-05 | 河北比尔尼克新材料科技股份有限公司 | Brushed copper-imitation water-based paint, preparation method therefor and use thereof |
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Application publication date: 20190621 |