CN109897468A - A kind of glass fire-retardant heat insulation decorating film and its preparation method and application - Google Patents
A kind of glass fire-retardant heat insulation decorating film and its preparation method and application Download PDFInfo
- Publication number
- CN109897468A CN109897468A CN201910240492.4A CN201910240492A CN109897468A CN 109897468 A CN109897468 A CN 109897468A CN 201910240492 A CN201910240492 A CN 201910240492A CN 109897468 A CN109897468 A CN 109897468A
- Authority
- CN
- China
- Prior art keywords
- parts
- decorating film
- fire
- heat insulation
- room temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention discloses a kind of glass fire-retardant heat insulation decorating films, it include following components according to mass fraction: 60-80 parts of Corvic, 20-30 parts of polylactone diol, 15-30 parts of polyether-tribasic alcohol, 15-25 parts of dihydromethyl propionic acid, 60-80 parts of hexamethylene diisocyanate, 10-30 parts of polycaprolactone glycol, 5-10 parts of methyl diphenylene diisocyanate, 30-60 parts of toluene, 10-20 parts of butanone, 10-20 parts of isopropanol, 5-10 parts of dimethylformamide, 15-30 parts of triethanolamine, 20-40 parts of dihexyl adipate, 5-8 parts of butyl acetate, 15-20 parts of fire retardant, 3-6 parts of catalyst, 1-5 parts of additive.Decorating film proposed by the present invention is attached at the inner surface of simple glass, can obstruct solar thermal energy, can greatly reduce the refrigeration cost of summer air-conditioning；Winter, controllable indoor heat scattered and disappeared through window, will not only indoor occupant be made not feel good, but also reduce unnecessary energy consumption cost.Decorating film proposed by the present invention has good safety, stability and permeability.
Description
Technical field
The invention belongs to technology field of membrane materials, in particular to a kind of glass fire-retardant heat insulation decorating film and preparation method thereof
And application.
Background technique
Decorating film be with high molecular polymer (PVC) be raw material, add various auxiliary agents, through calendering, it is compound prepared by one
Kind new decorative material, can be combined multipurpose ornament materials with substrates such as timber, plastic plate, aluminium sheet, iron plates, be widely applied
In household electrical appliance, sound equipment incrustation, interior decoration, aircraft, steamer, train interior trim.Further, it is also possible to be used for billboard
Deng.
Decorating film has characteristics that 1, heat-proof quality: can be quantified using advanced science and technology control product heat-insulated rate, it is heat-insulated
Rate up to 79%, room summer after pad pasting than the room temperature of non-pad pasting reduce 3-6 degree or more (form family size and
Depending on) it effectively controls sunlight and is exposed to the sun, it reduces fee for air conditioning usage and uses.It is healthy comfortable.Curtain, parasols, sunshade: tradition
Shading product heat-insulated rate can not quantify, and be many times sunshade and do not accomplish heat-insulated.2, keep warm: the decorative adhesive film of this series is in the winter
Season can play insulation effect, by vacuum magnetron sputtering coating film, indoor heat source (far infrared) can be reflected back interior, from
And play the role of heat preservation.3, every ultraviolet light: because having filled ultraviolet absorbing agent in film layer, thus can isolate 99%
Ultraviolet light, protection skin preserve from, and family's living furniture, floor, fabrics are not faded.4, private: the window patch of metallized processing
Film forms " mirror surface " effect on glass.The eyes that other people pry through effectively are blocked on daytime, and are not influenced from indoor clear
Outdoor landscape.5, safety anti-explosive, antitheft, shellproof: glass encounter external impacts it is broken when, the fragment to splash is easily hurted sb.'s feelings.
Decorating film is loaded on glass pane inner surface, can effectively promote the safety anti-explosive performance of glass；Protect the safety of household.Safety is anti-
It steals, anti-riot, shellproof, real invisible anti-theft network, substitutes anti-theft iron fence.6, decorative: decorative performance is that decorating film is most important
One effect.Having except multi-functional decorating film basis, is still having one is pure decorating film, not the work of heat isolation explosion proof
With reaching beautiful and economic finishing mode mainly in changing indoor environment and design.Especially in glass wall
More working environment.
Summary of the invention
In order to solve technical problem of the existing technology, the present invention provides a kind of glass fire-retardant heat insulation decorating film and
Preparation method and application.
To achieve the above object, the technical solution adopted by the present invention are as follows:
A kind of glass fire-retardant heat insulation decorating film, includes following components according to mass fraction:
60-80 parts of Corvic, 20-30 parts of polylactone diol, 15-30 parts of polyether-tribasic alcohol, dihydromethyl propionic acid 15-25
Part, 60-80 parts of hexamethylene diisocyanate, 10-30 parts of polycaprolactone glycol, 5-10 parts of methyl diphenylene diisocyanate,
30-60 parts of toluene, 10-20 parts of butanone, 10-20 parts of isopropanol, 5-10 parts of dimethylformamide, 15-30 parts of triethanolamine, oneself two
Sour dihexyl 20-40 parts, 5-8 parts of butyl acetate, 15-20 parts of fire retardant, 3-6 parts of catalyst, 1-5 parts of additive.
Preferably, a kind of glass fire-retardant heat insulation decorating film, includes following components according to mass fraction:
70 parts of Corvic, 25 parts of polylactone diol, 20 parts of polyether-tribasic alcohol, 20 parts of dihydromethyl propionic acid, hexa-methylene
It is 70 parts of diisocyanate, 20 parts of polycaprolactone glycol, 8 parts of methyl diphenylene diisocyanate, 50 parts of toluene, 15 parts of butanone, different
15 parts of propyl alcohol, 8 parts of dimethylformamide, 20 parts of triethanolamine, 30 parts of dihexyl adipate, 6 parts of butyl acetate, fire retardant 18
Part, 5 parts of catalyst, 3 parts of additive.
Preferably, the relative molecular mass of the polyether-tribasic alcohol is 750-1500.
Preferably, the catalyst is one of trimethyl benzylamine, 12 tertiary amines or stannous methide.
Preferably, the additive includes one of hydroxymethyl cellulose, soybean oil, antioxidant and foam powder or more
Kind is with the mixture of arbitrary proportion.
Preferably, the toluene, butanone, isopropanol, dimethylformamide mass ratio be 3:1:1:0.5.
Preferably, the fire retardant is ammonium polyphosphate.
A kind of preparation method of glass fire-retardant heat insulation decorating film, comprising the following steps:
Step 1 takes each component according to aforementioned proportion, stirs 1- after toluene, butanone, isopropanol and dimethylformamide are mixed
5min obtains mixed liquor A, and mixed liquor A is equally divided into two parts,
It is step 2, first that Corvic, polylactone diol, polyether-tribasic alcohol, dihydromethyl propionic acid, hexa-methylene two is different
Cyanate, the pure and mild catalyst of polycaprolactone two are added in reaction kettle, with the revolving speed stirring 20-30min of 50-60 turns/min, then to
A part of mixed liquor A is added in reaction kettle, 20-30min is stirred with the revolving speed of 50-60 turns/min, is heated to 50-60 DEG C, is stood
30-50min is cooled to room temperature, water-bath melt methyl diphenylene diisocyanate, then with 30-60 drop/min speed by its
It is added to reaction kettle, 20-30min is stirred with the revolving speed of 50-60 turns/min, is heated to 60-90 DEG C, stand 30-50min, it is cooling
To room temperature, another part mixed liquor A is added, is turned with 50-60/revolving speed of min stirs 20-30min, is heated to 60-90 DEG C, it is quiet
30-50min is set, is cooled to room temperature, triethanolamine, dihexyl adipate and butyl acetate are added, with turning for 50-60 turns/min
Speed stirring 20-30min, is heated to 60-90 DEG C, stands 30-50min, be cooled to room temperature, fire retardant and additive is then added,
It is heated to 90-110 DEG C, 30-50min is stood, is cooled to room temperature, obtains mixed liquid B；
Mixed liquid B is sieved by step 3, removes the impurity not being completely dissolved, and is again heated to 90-110 DEG C, stands 30-50min,
It is cooled to room temperature, obtains uniform mixed liquor C；
Step 4, the coated drying of mixed liquor C are prepared into decorating film.
Preferably, the decorating film with a thickness of 0.5mm- 0.7mm.
A kind of application of glass fire-retardant heat insulation decorating film, decorating film are attached at the inner surface of simple glass.
Compared with prior art, the invention has the following advantages:
Decorating film proposed by the present invention is attached at the inner surface of simple glass, can obstruct solar thermal energy, can greatly reduce the summer
Season air-conditioning refrigeration cost；Winter, controllable indoor heat scattered and disappeared through window, will not only indoor occupant be made not feel good, and
And reduce unnecessary energy consumption cost.The inner surface that decorating film is installed on simple glass can be reduced thermal losses up to 30%, this
Outside, it also added fire retardant in the decorating film, it is nonflammable.Decorating film proposed by the present invention has good safety, stablizes
Property and permeability.
Specific embodiment
Below with reference to embodiment, the present invention will be further explained.
Embodiment 1
A kind of glass fire-retardant heat insulation decorating film, includes following components according to mass fraction:
70 parts of Corvic, 25 parts of polylactone diol, 20 parts of polyether-tribasic alcohol, 20 parts of dihydromethyl propionic acid, hexa-methylene
It is 70 parts of diisocyanate, 20 parts of polycaprolactone glycol, 8 parts of methyl diphenylene diisocyanate, 50 parts of toluene, 15 parts of butanone, different
15 parts of propyl alcohol, 8 parts of dimethylformamide, 20 parts of triethanolamine, 30 parts of dihexyl adipate, 6 parts of butyl acetate, fire retardant 18
Part, 5 parts of catalyst, 3 parts of additive.
The relative molecular mass of the polyether-tribasic alcohol is 1200.
The catalyst is trimethyl benzylamine.
The additive includes hydroxymethyl cellulose.
The toluene, butanone, isopropanol, dimethylformamide mass ratio be 3:1:1:0.5.
The fire retardant is ammonium polyphosphate.
A kind of preparation method of glass fire-retardant heat insulation decorating film, comprising the following steps:
Step 1 takes each component according to aforementioned proportion, stirs after toluene, butanone, isopropanol and dimethylformamide are mixed
3min obtains mixed liquor A, and mixed liquor A is equally divided into two parts,
It is step 2, first that Corvic, polylactone diol, polyether-tribasic alcohol, dihydromethyl propionic acid, hexa-methylene two is different
Cyanate, the pure and mild catalyst of polycaprolactone two are added in reaction kettle, stir 25min with the revolving speed of 55 turns/min, then to reaction kettle
It is middle that a part of mixed liquor A is added, 25min is stirred with the revolving speed of 55 turns/min, is heated to 50-60 DEG C, 35min is stood, is cooled to
Room temperature, water-bath are melted methyl diphenylene diisocyanate, are then added into 50 drops/min speed to reaction kettle, with 55
Turn/revolving speed of min stirs 25min, 80 DEG C are heated to, 35min is stood, is cooled to room temperature, adds another part mixed liquor A,
Stir 25min with the revolving speed of 55 turns/min, be heated to 80 DEG C, stand 35min, be cooled to room temperature, add triethanolamine, oneself two
Sour dihexyl and butyl acetate stir 25min with the revolving speed of 55 turns/min, are heated to 80 DEG C, stand 35min, be cooled to room temperature,
Then fire retardant and additive is added, is heated to 100 DEG C, stands 35min, is cooled to room temperature, obtains mixed liquid B；
Mixed liquid B is sieved by step 3, removes the impurity not being completely dissolved, and is again heated to 100 DEG C, is stood 35min, is cooled to
Room temperature obtains uniform mixed liquor C；
Step 4, the coated drying of mixed liquor C are prepared into the decorating film with a thickness of 0.6mm.
Decorating film made from step 4 is attached to the inner surface of simple glass.
Embodiment 2
A kind of glass fire-retardant heat insulation decorating film, includes following components according to mass fraction:
60 parts of Corvic, 20 parts of polylactone diol, 15 parts of polyether-tribasic alcohol, 15 parts of dihydromethyl propionic acid, hexa-methylene
It is 60 parts of diisocyanate, 10 parts of polycaprolactone glycol, 5 parts of methyl diphenylene diisocyanate, 30 parts of toluene, 10 parts of butanone, different
10 parts of propyl alcohol, 5 parts of dimethylformamide, 15 parts of triethanolamine, 20 parts of dihexyl adipate, 5 parts of butyl acetate, fire retardant 15
Part, 3 parts of catalyst, 1 part of additive.
The relative molecular mass of the polyether-tribasic alcohol is 750.
The catalyst is 12 tertiary amines.
The additive includes soybean oil.
The toluene, butanone, isopropanol, dimethylformamide mass ratio be 3:1:1:0.5.
The fire retardant is ammonium polyphosphate.
A kind of preparation method of glass fire-retardant heat insulation decorating film, comprising the following steps:
Step 1 takes each component according to aforementioned proportion, stirs after toluene, butanone, isopropanol and dimethylformamide are mixed
3min obtains mixed liquor A, and mixed liquor A is equally divided into two parts,
It is step 2, first that Corvic, polylactone diol, polyether-tribasic alcohol, dihydromethyl propionic acid, hexa-methylene two is different
Cyanate, the pure and mild catalyst of polycaprolactone two are added in reaction kettle, stir 20min with the revolving speed of 50 turns/min, then to reaction kettle
It is middle that a part of mixed liquor A is added, 20min is stirred with the revolving speed of 50 turns/min, is heated to 50 DEG C, 30min is stood, is cooled to room
Temperature, water-bath melt methyl diphenylene diisocyanate, be then added into 30 drops/min speed to reaction kettle, with 50 turns/
The revolving speed of min stirs 20min, is heated to 60 DEG C, stands 30min, is cooled to room temperature, another part mixed liquor A is added, with 50
Turn/revolving speed of min stirs 20min, 60 DEG C are heated to, 30min is stood, is cooled to room temperature, adds triethanolamine, adipic acid two
Own ester and butyl acetate stir 20min with the revolving speed of 50 turns/min, are heated to 60 DEG C, stand 30min, be cooled to room temperature, then
Fire retardant and additive is added, is heated to 90 DEG C, stands 30min, is cooled to room temperature, obtains mixed liquid B；
Mixed liquid B is sieved by step 3, removes the impurity not being completely dissolved, and is again heated to 90 DEG C, is stood 30min, is cooled to
Room temperature obtains uniform mixed liquor C；
Step 4, the coated drying of mixed liquor C are prepared into the decorating film with a thickness of 0.7mm.
Decorating film made from step 4 is attached to the inner surface of simple glass.
Embodiment 3
A kind of glass fire-retardant heat insulation decorating film, includes following components according to mass fraction:
80 parts of Corvic, 30 parts of polylactone diol, 30 parts of polyether-tribasic alcohol, 25 parts of dihydromethyl propionic acid, hexa-methylene
It is 80 parts of diisocyanate, 30 parts of polycaprolactone glycol, 10 parts of methyl diphenylene diisocyanate, 60 parts of toluene, 20 parts of butanone, different
20 parts of propyl alcohol, 10 parts of dimethylformamide, 30 parts of triethanolamine, 40 parts of dihexyl adipate, 8 parts of butyl acetate, fire retardant 20
Part, 6 parts of catalyst, 5 parts of additive.
The relative molecular mass of the polyether-tribasic alcohol is 1500.
The catalyst is stannous methide.
The additive includes antioxidant.
The toluene, butanone, isopropanol, dimethylformamide mass ratio be 3:1:1:0.5.
The fire retardant is ammonium polyphosphate.
A kind of preparation method of glass fire-retardant heat insulation decorating film, comprising the following steps:
Step 1 takes each component according to aforementioned proportion, stirs after toluene, butanone, isopropanol and dimethylformamide are mixed
5min obtains mixed liquor A, and mixed liquor A is equally divided into two parts,
It is step 2, first that Corvic, polylactone diol, polyether-tribasic alcohol, dihydromethyl propionic acid, hexa-methylene two is different
Cyanate, the pure and mild catalyst of polycaprolactone two are added in reaction kettle, stir 30min with the revolving speed of 60 turns/min, then to reaction kettle
It is middle that a part of mixed liquor A is added, 30min is stirred with the revolving speed of 60 turns/min, is heated to 60 DEG C, 50min is stood, is cooled to room
Temperature, water-bath melt methyl diphenylene diisocyanate, be then added into 60 drops/min speed to reaction kettle, with 60 turns/
The revolving speed of min stirs 30min, is heated to 90 DEG C, stands 50min, is cooled to room temperature, another part mixed liquor A is added, with 60
Turn/revolving speed of min stirs 30min, 90 DEG C are heated to, 50min is stood, is cooled to room temperature, adds triethanolamine, adipic acid two
Own ester and butyl acetate stir 30min with the revolving speed of 60 turns/min, are heated to 90 DEG C, stand 50min, be cooled to room temperature, then
Fire retardant and additive is added, is heated to 110 DEG C, stands 50min, is cooled to room temperature, obtains mixed liquid B；
Mixed liquid B is sieved by step 3, removes the impurity not being completely dissolved, and is again heated to 110 DEG C, is stood 50min, is cooled to
Room temperature obtains uniform mixed liquor C；
Step 4, the coated drying of mixed liquor C are prepared into the decorating film with a thickness of 0.5mm.
Decorating film made from step 4 is attached to the inner surface of simple glass.
Embodiment 4
A kind of glass fire-retardant heat insulation decorating film, includes following components according to mass fraction:
70 parts of Corvic, 30 parts of polylactone diol, 15 parts of polyether-tribasic alcohol, 18 parts of dihydromethyl propionic acid, hexa-methylene
It is 80 parts of diisocyanate, 15 parts of polycaprolactone glycol, 8 parts of methyl diphenylene diisocyanate, 50 parts of toluene, 15 parts of butanone, different
10 parts of propyl alcohol, 10 parts of dimethylformamide, 18 parts of triethanolamine, 30 parts of dihexyl adipate, 6 parts of butyl acetate, fire retardant 18
Part, 5 parts of catalyst, 3 parts of additive.
The relative molecular mass of the polyether-tribasic alcohol is 1000.
The catalyst is trimethyl benzylamine.
The additive includes foam powder.
The toluene, butanone, isopropanol, dimethylformamide mass ratio be 3:1:1:0.5.
The fire retardant is ammonium polyphosphate.
A kind of preparation method of glass fire-retardant heat insulation decorating film, comprising the following steps:
Step 1 takes each component according to aforementioned proportion, stirs after toluene, butanone, isopropanol and dimethylformamide are mixed
5min obtains mixed liquor A, and mixed liquor A is equally divided into two parts,
It is step 2, first that Corvic, polylactone diol, polyether-tribasic alcohol, dihydromethyl propionic acid, hexa-methylene two is different
Cyanate, the pure and mild catalyst of polycaprolactone two are added in reaction kettle, stir 30min with the revolving speed of 55 turns/min, then to reaction kettle
It is middle that a part of mixed liquor A is added, 25min is stirred with the revolving speed of 55 turns/min, is heated to 50 DEG C, 50min is stood, is cooled to room
Temperature, water-bath melt methyl diphenylene diisocyanate, be then added into 35 drops/min speed to reaction kettle, with 60 turns/
The revolving speed of min stirs 25min, is heated to 70 DEG C, stands 35min, is cooled to room temperature, adds another part mixed liquor A, with
The revolving speed of 50-60 turns/min stirs 25min, is heated to 60-90 DEG C, stands 30-50min, is cooled to room temperature, adds three ethyl alcohol
Amine, dihexyl adipate and butyl acetate stir 30min with the revolving speed of 50 turns/min, are heated to 80 DEG C, stand 50min, cooling
To room temperature, fire retardant and additive is then added, is heated to 110 DEG C, stands 50min, is cooled to room temperature, obtains mixed liquid B；
Mixed liquid B is sieved by step 3, removes the impurity not being completely dissolved, and is again heated to 100 DEG C, is stood 40min, is cooled to
Room temperature obtains uniform mixed liquor C；
Step 4, the coated drying of mixed liquor C are prepared into the decorating film with a thickness of 0.6mm.
Decorating film made from step 4 is attached to the inner surface of simple glass.
Embodiment 5
A kind of glass fire-retardant heat insulation decorating film, includes following components according to mass fraction:
60-80 parts of Corvic, 20-30 parts of polylactone diol, 15-30 parts of polyether-tribasic alcohol, dihydromethyl propionic acid 15-25
Part, 60-80 parts of hexamethylene diisocyanate, 10-30 parts of polycaprolactone glycol, 5-10 parts of methyl diphenylene diisocyanate,
30-60 parts of toluene, 10-20 parts of butanone, 10-20 parts of isopropanol, 5-10 parts of dimethylformamide, 15-30 parts of triethanolamine, oneself two
Sour dihexyl 20-40 parts, 5-8 parts of butyl acetate, 15-20 parts of fire retardant, 3-6 parts of catalyst, 1-5 parts of additive.
The relative molecular mass of the polyether-tribasic alcohol is 750-1500.
The catalyst is one of trimethyl benzylamine, 12 tertiary amines or stannous methide.
The additive includes hydroxymethyl cellulose, soybean oil, antioxidant and foam powder, hydroxymethyl cellulose, soybean
The quality of oil, antioxidant and foam powder is 1:1:1:1.
The toluene, butanone, isopropanol, dimethylformamide mass ratio be 3:1:1:0.5.
The fire retardant is ammonium polyphosphate.
A kind of preparation method of glass fire-retardant heat insulation decorating film, comprising the following steps:
Step 1 takes each component according to aforementioned proportion, stirs after toluene, butanone, isopropanol and dimethylformamide are mixed
5min obtains mixed liquor A, and mixed liquor A is equally divided into two parts,
It is step 2, first that Corvic, polylactone diol, polyether-tribasic alcohol, dihydromethyl propionic acid, hexa-methylene two is different
Cyanate, the pure and mild catalyst of polycaprolactone two are added in reaction kettle, stir 30min with the revolving speed of 55 turns/min, then to reaction kettle
It is middle that a part of mixed liquor A is added, 25min is stirred with the revolving speed of 55 turns/min, is heated to 50 DEG C, 50min is stood, is cooled to room
Temperature, water-bath melt methyl diphenylene diisocyanate, be then added into 35 drops/min speed to reaction kettle, with 60 turns/
The revolving speed of min stirs 25min, is heated to 70 DEG C, stands 35min, is cooled to room temperature, adds another part mixed liquor A, with
The revolving speed of 50-60 turns/min stirs 25min, is heated to 60-90 DEG C, stands 30-50min, is cooled to room temperature, adds three ethyl alcohol
Amine, dihexyl adipate and butyl acetate stir 30min with the revolving speed of 50 turns/min, are heated to 80 DEG C, stand 50min, cooling
To room temperature, fire retardant and additive is then added, is heated to 110 DEG C, stands 50min, is cooled to room temperature, obtains mixed liquid B；
Mixed liquid B is sieved by step 3, removes the impurity not being completely dissolved, and is again heated to 100 DEG C, is stood 40min, is cooled to
Room temperature obtains uniform mixed liquor C；
Step 4, the coated drying of mixed liquor C are prepared into the decorating film with a thickness of 0.6mm.
Decorating film made from step 4 is attached to the inner surface of simple glass.
Decorating film made from step 4 is attached to the inner surface of simple glass.
Embodiment 6
A kind of glass fire-retardant heat insulation decorating film, includes following components according to mass fraction:
60-80 parts of Corvic, 20-30 parts of polylactone diol, 15-30 parts of polyether-tribasic alcohol, dihydromethyl propionic acid 15-25
Part, 60-80 parts of hexamethylene diisocyanate, 10-30 parts of polycaprolactone glycol, 5-10 parts of methyl diphenylene diisocyanate,
30-60 parts of toluene, 10-20 parts of butanone, 10-20 parts of isopropanol, 5-10 parts of dimethylformamide, 15-30 parts of triethanolamine, oneself two
Sour dihexyl 20-40 parts, 5-8 parts of butyl acetate, 15-20 parts of fire retardant, 3-6 parts of catalyst, 1-5 parts of additive.
The relative molecular mass of the polyether-tribasic alcohol is 750-1500.
The catalyst is one of trimethyl benzylamine, 12 tertiary amines or stannous methide.
The additive includes hydroxymethyl cellulose, soybean oil, antioxidant, in which: hydroxymethyl cellulose, soybean oil,
The mass ratio of antioxidant is 3:1:1.
The toluene, butanone, isopropanol, dimethylformamide mass ratio be 3:1:1:0.5.
The fire retardant is ammonium polyphosphate.
A kind of preparation method of glass fire-retardant heat insulation decorating film, comprising the following steps:
Step 1 takes each component according to aforementioned proportion, stirs after toluene, butanone, isopropanol and dimethylformamide are mixed
5min obtains mixed liquor A, and mixed liquor A is equally divided into two parts,
It is step 2, first that Corvic, polylactone diol, polyether-tribasic alcohol, dihydromethyl propionic acid, hexa-methylene two is different
Cyanate, the pure and mild catalyst of polycaprolactone two are added in reaction kettle, stir 30min with the revolving speed of 55 turns/min, then to reaction kettle
It is middle that a part of mixed liquor A is added, 25min is stirred with the revolving speed of 55 turns/min, is heated to 50 DEG C, 50min is stood, is cooled to room
Temperature, water-bath melt methyl diphenylene diisocyanate, be then added into 35 drops/min speed to reaction kettle, with 60 turns/
The revolving speed of min stirs 25min, is heated to 70 DEG C, stands 35min, is cooled to room temperature, adds another part mixed liquor A, with
The revolving speed of 50-60 turns/min stirs 25min, is heated to 60-90 DEG C, stands 30-50min, is cooled to room temperature, adds three ethyl alcohol
Amine, dihexyl adipate and butyl acetate stir 30min with the revolving speed of 50 turns/min, are heated to 80 DEG C, stand 50min, cooling
To room temperature, fire retardant and additive is then added, is heated to 110 DEG C, stands 50min, is cooled to room temperature, obtains mixed liquid B；
Mixed liquid B is sieved by step 3, removes the impurity not being completely dissolved, and is again heated to 100 DEG C, is stood 40min, is cooled to
Room temperature obtains uniform mixed liquor C；
Step 4, the coated drying of mixed liquor C are prepared into the decorating film with a thickness of 0.6mm.
Decorating film made from step 4 is attached to the inner surface of simple glass.
The decorating film of embodiment 1-6 preparation is attached at the inner surface of simple glass, can obstruct solar thermal energy, can drop significantly
The low refrigeration cost of summer air-conditioning；Winter, controllable indoor heat scattered and disappeared through window, will not only indoor occupant be made to feel
Discomfort, and reduce unnecessary energy consumption cost.The inner surface that decorating film is installed on simple glass can be reduced thermal losses to reach
30%, in addition, also added fire retardant in the decorating film, it is nonflammable.Decorating film proposed by the present invention has good safety
Property, stability and permeability.
The above is only a preferred embodiment of the present invention, it should be pointed out that: for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of glass fire-retardant heat insulation decorating film, which is characterized in that according to mass fraction include following components:
60-80 parts of Corvic, 20-30 parts of polylactone diol, 15-30 parts of polyether-tribasic alcohol, dihydromethyl propionic acid 15-25
Part, 60-80 parts of hexamethylene diisocyanate, 10-30 parts of polycaprolactone glycol, 5-10 parts of methyl diphenylene diisocyanate,
30-60 parts of toluene, 10-20 parts of butanone, 10-20 parts of isopropanol, 5-10 parts of dimethylformamide, 15-30 parts of triethanolamine, oneself two
Sour dihexyl 20-40 parts, 5-8 parts of butyl acetate, 15-20 parts of fire retardant, 3-6 parts of catalyst, 1-5 parts of additive.
2. glass according to claim 1 fire-retardant heat insulation decorating film, which is characterized in that according to mass fraction include following
Component:
70 parts of Corvic, 25 parts of polylactone diol, 20 parts of polyether-tribasic alcohol, 20 parts of dihydromethyl propionic acid, hexa-methylene
It is 70 parts of diisocyanate, 20 parts of polycaprolactone glycol, 8 parts of methyl diphenylene diisocyanate, 50 parts of toluene, 15 parts of butanone, different
15 parts of propyl alcohol, 8 parts of dimethylformamide, 20 parts of triethanolamine, 30 parts of dihexyl adipate, 6 parts of butyl acetate, fire retardant 18
Part, 5 parts of catalyst, 3 parts of additive.
3. glass according to claim 1 fire-retardant heat insulation decorating film, which is characterized in that the polyether-tribasic alcohol it is opposite
Molecular mass is 750-1500.
4. glass according to claim 1 fire-retardant heat insulation decorating film, which is characterized in that the catalyst is trimethyl benzyl
One of amine, 12 tertiary amines or stannous methide.
5. glass according to claim 1 fire-retardant heat insulation decorating film, which is characterized in that the additive includes methylol
One of cellulose, soybean oil, antioxidant and foam powder are a variety of.
6. glass according to claim 1 fire-retardant heat insulation decorating film, which is characterized in that the toluene, butanone, isopropyl
Alcohol, dimethylformamide mass ratio be 3:1:1:0.5.
7. glass according to claim 1 fire-retardant heat insulation decorating film, which is characterized in that the fire retardant is polyphosphoric acid
Ammonium.
8. the preparation method of -7 any glass fire-retardant heat insulation decorating films according to claim 1, which is characterized in that including
Following steps:
Step 1 takes each component according to aforementioned proportion, stirs 1- after toluene, butanone, isopropanol and dimethylformamide are mixed
5min obtains mixed liquor A, and mixed liquor A is equally divided into two parts,
It is step 2, first that Corvic, polylactone diol, polyether-tribasic alcohol, dihydromethyl propionic acid, hexa-methylene two is different
Cyanate, the pure and mild catalyst of polycaprolactone two are added in reaction kettle, with the revolving speed stirring 20-30min of 50-60 turns/min, then to
A part of mixed liquor A is added in reaction kettle, 20-30min is stirred with the revolving speed of 50-60 turns/min, is heated to 50-60 DEG C, is stood
30-50min is cooled to room temperature, water-bath melt methyl diphenylene diisocyanate, then with 30-60 drop/min speed by its
It is added to reaction kettle, 20-30min is stirred with the revolving speed of 50-60 turns/min, is heated to 60-90 DEG C, stand 30-50min, it is cooling
To room temperature, another part mixed liquor A is added, is turned with 50-60/revolving speed of min stirs 20-30min, is heated to 60-90 DEG C, it is quiet
30-50min is set, is cooled to room temperature, triethanolamine, dihexyl adipate and butyl acetate are added, with turning for 50-60 turns/min
Speed stirring 20-30min, is heated to 60-90 DEG C, stands 30-50min, be cooled to room temperature, fire retardant and additive is then added,
It is heated to 90-110 DEG C, 30-50min is stood, is cooled to room temperature, obtains mixed liquid B；
Mixed liquid B is sieved by step 3, removes the impurity not being completely dissolved, and is again heated to 90-110 DEG C, stands 30-50min,
It is cooled to room temperature, obtains uniform mixed liquor C；
Step 4, the coated drying of mixed liquor C are prepared into decorating film.
9. the glass according to claim 8 preparation method of fire-retardant heat insulation decorating film, which is characterized in that the decorating film
With a thickness of 0.5mm- 0.7mm.
10. the application of decorating film made from preparation method according to claim 8, which is characterized in that decorating film is attached at
The inner surface of simple glass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910240492.4A CN109897468A (en) | 2019-03-28 | 2019-03-28 | A kind of glass fire-retardant heat insulation decorating film and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910240492.4A CN109897468A (en) | 2019-03-28 | 2019-03-28 | A kind of glass fire-retardant heat insulation decorating film and its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109897468A true CN109897468A (en) | 2019-06-18 |
Family
ID=66953587
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910240492.4A Pending CN109897468A (en) | 2019-03-28 | 2019-03-28 | A kind of glass fire-retardant heat insulation decorating film and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109897468A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103820015A (en) * | 2014-02-26 | 2014-05-28 | 浙江天翔科技有限公司 | PU decorative film surface treating agent and method for treating PU decorative film by using same |
| CN106221194A (en) * | 2016-08-18 | 2016-12-14 | 付竹兰 | A kind of preparation method of laminated glass-use decorating film |
-
2019
- 2019-03-28 CN CN201910240492.4A patent/CN109897468A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103820015A (en) * | 2014-02-26 | 2014-05-28 | 浙江天翔科技有限公司 | PU decorative film surface treating agent and method for treating PU decorative film by using same |
| CN106221194A (en) * | 2016-08-18 | 2016-12-14 | 付竹兰 | A kind of preparation method of laminated glass-use decorating film |
Non-Patent Citations (1)
| Title |
|---|
| 柴春鹏等: "《高分子合成材料学》", 31 January 2019, 北京理工大学出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN206106496U (en) | Three -dimensional decorating plate with fluorescent effect | |
| CN109897468A (en) | A kind of glass fire-retardant heat insulation decorating film and its preparation method and application | |
| CN206438704U (en) | A kind of aluminum veneer sprayed with polyester | |
| CN107629228A (en) | A kind of dip coated formula PC decorating films of textile surface | |
| CN104693946A (en) | Selectivity light-transmitting and heat-insulating coating and preparing method thereof | |
| CN108440905A (en) | A kind of wear resistant heat preserving fire prevention resistance vitaglass protective film and preparation method thereof | |
| CN106065084A (en) | A kind of dip coated formula PE decorating film of plastic substrate surface | |
| WO1983000356A1 (en) | Insulation material | |
| CN107629694A (en) | A kind of blade coating formula polyurethane decoration film of metal substrate surface | |
| CN107619491A (en) | A kind of vacuum evaporation cloth of coating-type polyurethane decoration film of metal substrate surface | |
| CN107474286A (en) | A kind of vacuum evaporation cloth of coating-type PVC decorative Film on ceramic bases surface | |
| CN107630189A (en) | A kind of vacuum evaporation cloth of coating-type PP decorating films on painted substrate surface | |
| CN107474280A (en) | A kind of vacuum evaporation cloth of coating-type PC decorating films of textile surface | |
| CN107629233A (en) | A kind of vacuum evaporation cloth of coating-type PE decorating films of plastic substrate surface | |
| CN106046406A (en) | Spray coating type decorative polyurethane film for surface of metal substrate | |
| CN107470114A (en) | A kind of blade coating formula PC decorating films of textile surface | |
| CN107626545A (en) | A kind of roller coat formula PC decorating films of textile surface | |
| CN107629230A (en) | A kind of airblade coating formula PC decorating films of textile surface | |
| CN106084267A (en) | A kind of extrusion formula PC decorating film of textile surface | |
| CN107470113A (en) | A kind of extrusion formula PP decorating films on painted substrate surface | |
| CN107618308A (en) | A kind of spraying coating formula PC decorating films of textile surface | |
| CN107474283A (en) | A kind of spraying coating formula PP decorating films on painted substrate surface | |
| CN107470103A (en) | A kind of flow coat formula PC decorating films of textile surface | |
| CN107470109A (en) | A kind of blade coating formula PP decorating films on painted substrate surface | |
| CN107474279A (en) | A kind of extrusion formula PVC decorative Film on ceramic bases surface |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190618 |