CN109895420A - A kind of integral composite material sleeper and its manufacturing method - Google Patents

A kind of integral composite material sleeper and its manufacturing method Download PDF

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Publication number
CN109895420A
CN109895420A CN201910218894.4A CN201910218894A CN109895420A CN 109895420 A CN109895420 A CN 109895420A CN 201910218894 A CN201910218894 A CN 201910218894A CN 109895420 A CN109895420 A CN 109895420A
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China
Prior art keywords
fiber
composite material
sleeper
material sleeper
density
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CN201910218894.4A
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Chinese (zh)
Inventor
侯学杰
刘振
谢文蓓
刘振兴
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Luoyang Kebo Si New Mstar Technology Ltd
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Luoyang Kebo Si New Mstar Technology Ltd
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Priority to CN201910218894.4A priority Critical patent/CN109895420A/en
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Abstract

A kind of integral composite material sleeper and its manufacturing method.Contain fiber in the composite material sleeper, the density of the composite material sleeper increases from inside to outside in the radial direction the composite material sleeper, and the increase of the density of the composite material sleeper is by realizing the fiber content of the fiber in the composite material sleeper in increasing from inside to outside in the radial direction for the composite material sleeper.The surface strength of the integral composite material sleeper of the application is high, and the concentrfated load on sleeper surface can effectively be dispersed, to avoid the problem that surface layer is intact, internal injury, extends the service life of sleeper.

Description

A kind of integral composite material sleeper and its manufacturing method
Technical field
This application involves but be not limited to Transit Equipment technical field, it is compound to be particularly, but not limited to a kind of integral type Material sleeper and its manufacturing method.
Background technique
In the railway system, sleeper is to transmit one of load, important component of firm track.The technical level and quality of sleeper Superiority and inferiority directly affects the design and operational safety of railroad track.
Currently, the common sleeper of Railway Design is wooden sleeper and concrete sleeper.These two types of sleepers there are many deficiencies, Such as wooden sleeper is perishable, the service life is short, raw material resources are in short supply;Concrete sleeper weight is big, easy fragmentation, damping difference etc.. In face of traditional material there are the problem of, novel composite material composite sleeper is by development and application, wherein being using one kind outstanding Fibre-reinforced high molecular foamed composite composite sleeper.Composite sleeper made of the type composite material has density low, strong Many advantages, such as degree is high, do not absorb water, ageing-resistant corrosion, it is important that there is the processing performance for being equal to timber, set convenient for engineering Meter, site operation and applicating maintenance.
Application No. is the Chinese patents of CN200810140888.3 to disclose the formula of a kind of synthesis wooden sleeper and continuously shaped Technique.In the application, often there is the phenomenon that being crushed by fastener to this type composite sleeper in upper surface, lower surface also often have by railway ballast or The impaired problem of other hard object extrusions, leads to the sleeper lost of life.The reason of problems occur is that sleeper density is lower, is kept Light-weight advantage, but when bearing uniformly distributed concentrfated load, easily damaged destruction.If improving sleeper density, sleeper weight meeting Increase, is unfavorable for products application.It is reported that protective layer, but such protective layer multi-pass mistake can be increased on composite sleeper surface Sleeper surface is arranged in the mode of secondary bonding, there are the problems in stress collection, there is the risk to fall off.In addition, increased protection Layer is obvious with sleeper body density variation, when concentrfated load is transmitted to sleeper body, still has the phenomenon that stress concentration, leads to table Sleeper long-time service cannot be completely secured in the problem of layer intact, internal injury.Therefore, there is the composite sleeper of protective layer also not Seeing has practical application.
Summary of the invention
This application provides a kind of integral composite material sleeper and its manufacturing methods, solve composite sleeper surface strength The problem of difference, easy damaged.
Specifically, this application provides a kind of integral composite material sleeper, contain fiber in the composite material sleeper, The density of the composite material sleeper increases from inside to outside in the radial direction the composite material sleeper, and described compound The increase of the density of material sleeper is by making the fiber content of the fiber in the composite material sleeper in the composite material rail Pillow increases from inside to outside to realize in the radial direction.
In the embodiment of the present application, the composite material sleeper may include transition zone, and the fiber in the transition zone exists The composite material sleeper can increase to the second fiber content by by the first fiber content from inside to outside in the radial direction Formal distribution.
In the embodiment of the present application, the fiber in the transition zone is in the composite material sleeper in the radial direction from interior To it is outer can be by the formal distribution for being linearly increasing to the second fiber content by the first fiber content.
In the embodiment of the present application, first fiber content can be linearly increasing to second fiber according to formula I Content, formula I are as follows:
y1=k1x+b1
In formula, y1For the fiber content of tested point, unit %;
X is the distance between tested point and the inward flange of transition zone, unit m;
k1It is nonnegative number, unit 1/m for fiber content growth rate;
b1Within the scope of 2%-25%.
In the embodiment of the present application, the density of the transition zone can be linearly increasing according to formula II, formula II are as follows:
y2=k2x+b2
In formula, y2For the density of tested point, unit kg/m3
X is the distance between tested point and the inward flange of transition zone, unit m;
k2It is nonnegative number, unit kg/m for the density increase rate of transition zone4
b2Within the scope of 100-1200, unit kg/m3
In the embodiment of the present application, the composite material sleeper can also include the first density layer and/or the second density layer, The side close to the composite material sleeper center of the transition zone, second density layer is arranged in first density layer The side far from the composite material sleeper center of the transition zone is set, and the fiber in first density layer is pressed First fiber content is evenly distributed, and the fiber in second density layer is evenly distributed by the second fiber content.
In the embodiment of the present application, the composite material sleeper can successively include from inside to outside in radial directions described First density layer and the transition zone.The thickness of first density layer can be the 1/ of the height of the composite material sleeper , remaining as the transition zone.
In the embodiment of the present application, the composite material sleeper can successively include from inside to outside in radial directions described Transition zone and second density layer.The thickness of the transition zone can be the 6/50-49/ of the height of the composite material sleeper 50, remaining as second density layer.
In the embodiment of the present application, the composite material sleeper can successively include institute on radial direction from inside to outside State the first density layer, the transition zone and second density layer.The thickness of first density layer can be the composite wood Expect the 1/10-9/10 of the height of sleeper, the thickness of the transition zone can be the 1/100- of the height of the composite material sleeper 22/50, remaining as second density layer.
In the embodiment of the present application, the composite material sleeper can successively include first from inside to outside in radial directions Density layer, transition zone and the second density layer, the fiber in first density layer is evenly distributed by the first fiber content, described Fiber in second density layer is evenly distributed by the second fiber content, and the fiber in the transition zone is equal by third fiber content It is distributed evenly, the second fiber content described in third fiber content < described in the first fiber content <.
In the embodiment of the present application, first fiber content can be 2%-25%, and second fiber content can be with For 17%-60%.
In the embodiment of the present application, the density of first density layer can be 100kg/m3-1200kg/m3, described second The density of density layer can be 500kg/m3-1900kg/m3
Present invention also provides the manufacturing methods of integral composite material sleeper as described above, which comprises
According to the density of desired composite material sleeper, fibre of the fiber in the composite material sleeper is calculated Dimension hplc, and convert and obtain fiber content of the fiber on fiber architecture frame;
Fiber is passed through by fiber architecture on fiber architecture frame according to fiber content of the fiber on fiber architecture frame It arranges yarn plate and carries out pre- distribution row yarn;
The fiber for passing through row's yarn plate is drawn to impregnating equipment, and reisn base material is made to impregnate the fiber;And
The fiber for being impregnated with reisn base material is formed, the integral composite material sleeper is obtained.
In the embodiment of the present application, described to may include: on fiber architecture frame by fiber architecture
Optionally, the fiber for forming the first density layer is equably arranged on the fiber architecture frame;
In the periphery for the fiber for forming first density layer, the fiber architecture of transition zone will be formed in the fiber architecture On frame;
Optionally, in the periphery for the fiber for forming the transition zone, the fiber for forming the second density layer is equably arranged On the fiber architecture frame.
The composite material sleeper of the application uses specific fiber architecture mode --- makes fine in the composite material sleeper The fiber content of dimension increases from inside to outside in the radial direction the composite material sleeper, so that the composite material sleeper Density is gradually increased to the high density on surface layer by internal low-density, is not only increased the intensity on surface layer, is also made the concentration on surface Load has obtained effective dispersion, to avoid the problem that surface layer is intact, internal injury, extends the service life of sleeper.
The composite material sleeper of the application manufactures to obtain using integrally formed mode, belongs to the sleeper of integral type, avoids Fall off risk existing for sleeper secondary bonding.
Other features and advantage will illustrate in the following description, also, partly become from specification It obtains it is clear that being understood and implementing the application.The purpose of the application and other advantages can be by specifications, right Specifically noted structure is achieved and obtained in claim and attached drawing.
Detailed description of the invention
Attached drawing is used to provide to further understand technical scheme, and constitutes part of specification, with this The embodiment of application is used to explain the technical solution of the application together, does not constitute the limitation to technical scheme.
Fig. 1 is the cross-sectional view of the composite material sleeper of the embodiment of the present application.
Fig. 2 is the schematic diagram of the manufacturing process of the composite material sleeper of the embodiment of the present application.
Fig. 3 is the structural schematic diagram for applying for primary fiber row's yarn plate of embodiment.
Fig. 4 is the structural schematic diagram for applying for secondary stock row's yarn plate of embodiment.
Appended drawing reference in figure are as follows:
10- composite material sleeper the first density layer of 11-
12- transition zone the second density layer of 13-
14- fiber 15- resin
21- fiber architecture frame 22- fabric frame
23- fiber arranges yarn plate 231- primary fiber and arranges yarn plate
2311- once arranges yarn plate row yarn hole 2312- and once arranges yarn board mount
232- secondary stock arranges bis- row's yarn plates of yarn plate 2321- and arranges yarn hole
Bis- row's yarn board mount 24- impregnating equipments of 2322-
25- molding equipment 26- sawing device
Specific embodiment
For the purposes, technical schemes and advantages of the application are more clearly understood, below in conjunction with attached drawing to the application Embodiment be described in detail.It should be noted that in the absence of conflict, in the embodiment and embodiment in the application Feature can mutual any combination.
This application provides a kind of integral composite material sleeper, fiber is contained in the composite material sleeper, it is described multiple The density of condensation material sleeper increases from inside to outside in the radial direction the composite material sleeper, and the composite material rail The increase of the density of pillow is by making the fiber content of the fiber in the composite material sleeper in the diameter of the composite material sleeper Increase from inside to outside to realize on direction.
In this application, term " composite material sleeper " is defined as synthesizing rail by what fiber and reisn base material were formed Pillow.
In this application, term " radial direction of sleeper " is defined as in the cross section of the length direction perpendicular to sleeper On, from the center of cross section, (i.e. cornerwise intersection point) of square cross section is directed toward the direction at the edge of cross section.
It should be appreciated that in this application, " density of sleeper " refers to the density of local sleeper, can pass through local sleeper Quality/part sleeper volume be calculated, therefore " density of sleeper " can be in the radial direction side of the composite material sleeper Increase from inside to outside upwards.
In this application, the volume for the fiber that term " fiber content " is defined as in sleeper unit volume accounts for sleeper unit bodies Long-pending percentage.
In this application, the density and fiber content of the sleeper changed are all based on 1mm3-1cm3Unit volume and Speech.
In the embodiment of the present application, the composite material sleeper may include transition zone, and the fiber in the transition zone exists The composite material sleeper can increase to the second fiber content by by the first fiber content from inside to outside in the radial direction Formal distribution.
In the embodiment of the present application, the fiber in the transition zone is in the composite material sleeper in the radial direction from interior To it is outer can be by the formal distribution for being linearly increasing to the second fiber content by the first fiber content.
It can be with it should be appreciated that in addition to linearly increasing mode, when increasing to the second fiber content from the first fiber content Other modes are used, for example, index increases, logarithm increases, increases according to the part being gradually increasing in parabola or according to hyperbolic Part increasing being gradually increasing in line etc..
In the embodiment of the present application, first fiber content can be linearly increasing to second fiber according to formula I Content, formula I are as follows:
y1=k1x+b1
In formula, y1For the fiber content of tested point, unit %;
X is the distance between tested point and the inward flange of transition zone, unit m;
k1It is nonnegative number, unit 1/m for fiber content growth rate;
b1Within the scope of 2%-25%.
When composite material sleeper includes the first density layer, the inward flange of the transition zone is located at transition zone and the first density The intersection of layer;When composite material sleeper does not include the first density layer, the inward flange of the transition zone is composite material sleeper Center.
In the embodiment of the present application, the density of the transition zone can be linearly increasing according to formula II, formula II are as follows:
y2=k2x+b2
In formula, y2For the density of tested point, unit kg/m3
X is the distance between tested point and the inward flange of transition zone, unit m;
k2It is nonnegative number, unit kg/m for the density increase rate of transition zone4
b2Within the scope of 100-1200, unit kg/m3
In the embodiment of the present application, the composite material sleeper can also include the first density layer and/or the second density layer, The side close to the composite material sleeper center of the transition zone, second density layer is arranged in first density layer The side far from the composite material sleeper center of the transition zone is set, and the fiber in first density layer is pressed First fiber content is evenly distributed, and the fiber in second density layer is evenly distributed by the second fiber content.
In the embodiment of the present application, the composite material sleeper can successively include from inside to outside in radial directions described First density layer and the transition zone.The thickness of first density layer can be the 1/ of the height of the composite material sleeper , remaining as the transition zone.
In the embodiment of the present application, the composite material sleeper can successively include from inside to outside in radial directions described Transition zone and second density layer.The thickness of the transition zone can be the 6/50-49/ of the height of the composite material sleeper 50, remaining as second density layer.
In the embodiment of the present application, as shown in Figure 1, the composite material sleeper 10 in radial directions from inside to outside can be with It successively include first density layer 11, the transition zone 12 and second density layer 13.The thickness of first density layer 11 Degree can be the 1/10-9/10 of the height of the composite material sleeper 10, and the thickness of the transition zone 12 can be described compound The 1/100-22/50 of the height of material sleeper 10, remaining as second density layer 13.In the present embodiment, the transition zone 12 and second density layer 13 be successively centered around 11 surrounding of the first density layer, at this point, the transition zone 12 and described In a ring, the thickness of the transition zone 12 refers to being centered around 11 side of the first density layer for the cross section of two density layers 13 The thickness of transition zone 12.In other embodiments, the thickness of cross section transition zone in a ring and the second density layer with herein It defines identical.
In the Shi Lizhong of the application, the composite material sleeper can successively include first from inside to outside in radial directions Density layer, transition zone and the second density layer, the fiber in first density layer is evenly distributed by the first fiber content, described Fiber in second density layer is evenly distributed by the second fiber content, and the fiber in the transition zone is equal by third fiber content It is distributed evenly, the second fiber content described in third fiber content < described in the first fiber content <.First density layer Thickness can for the composite material sleeper height 1/10-9/10, the thickness of the transition zone can be described compound The thickness of the 1/50-44/50 of the height of material sleeper, second density layer can be the height of the composite material sleeper 1/50-40/50。
In the embodiment of the present application, the density of first density layer can be 100kg/m3-1200kg/m3(it can pass through The quality of first density layer/first density layer volume is calculated), the density of second density layer can be 500kg/m3-1900kg/m3(can be calculated by quality/second density layer volume of second density layer).
The embodiment of the present application also provides the manufacturing methods of composite material sleeper as described above, which comprises
According to the density of desired composite material sleeper, fibre of the fiber in the composite material sleeper is calculated Dimension hplc, and convert and obtain fiber content of the fiber on fiber architecture frame;
Fiber is passed through by fiber architecture on fiber architecture frame according to fiber content of the fiber on fiber architecture frame It arranges yarn plate and carries out pre- distribution row yarn;
The fiber for passing through row's yarn plate is drawn to impregnating equipment, and reisn base material is made to impregnate the fiber;And
The fiber for being impregnated with reisn base material is formed, the composite material sleeper is obtained.
The composite material sleeper manufacturing method of the embodiment of the present application uses integrally formed mode, and it is secondary viscous to avoid sleeper Connect the existing risk that falls off.
In the embodiment of the present application, as shown in Fig. 2, the method may include:
According to the density of desired composite material sleeper, fiber 14 is calculated in the composite material sleeper Fiber content, and convert and obtain fiber content of the fiber on fiber architecture frame;
The fiber 14 for forming transition zone is arranged on fiber architecture frame 21, so that fiber 14 is passed through row's yarn plate 23 and is divided in advance Arrange yarn;
The fiber 14 for passing through row's yarn plate 23 is drawn to impregnating equipment 24, and reisn base material 15 is made to impregnate the fibre Dimension 14;With
The fiber 14 for being impregnated with reisn base material 15 feeding molding equipment 25 is foamed and solidified, molding is completed;
Sleeper semi-finished product after molding are cut by desired size using sawing device 26, obtain composite material sleeper 10。
In the embodiment of the present application, the method can also include: to be arranged in by the fiber 14 for forming the transition zone Before on fiber architecture frame 21, the fiber 14 for forming the first density layer is equably arranged on the fiber architecture frame 21, so Afterwards in the periphery for the fiber 14 for forming first density layer, the fiber 14 for forming the transition zone is arranged in the fiber and is arranged On cloth holder 21.
In the embodiment of the present application, the method can also include: to be arranged in by the fiber 14 for forming the transition zone After on fiber architecture frame 21, before making fiber 14 carry out pre- distribution row yarn across row's yarn plate 23, in the fibre of the transition zone The periphery of dimension 14, the fiber 14 for forming second density layer is equably arranged on the fiber architecture frame 21.
On row's yarn plate 23, fibre bundle can carry out pre- distribution row yarn according to the Density Distribution situation of sleeper.Arrange 23 phase of yarn plate When in the sleeper cross section that a size is amplified, the pore size distribution for arranging yarn plate 23 is identical as the distribution of fiber in sleeper.Unlike, Yarn is arranged for the ease of fibre bundle in manufacturing process, arranges reality of the distance between the fiber holes than fibre bundle in sleeper on yarn plate 23 Border distance is big.According to the difference of production line, the distance between fiber holes about fibre bundle is in sleeper on general row's yarn plate 23 5-20 times of actual range.If the distance between adjacent two fibre bundle is 3mm in sleeper, the corresponding fiber on row's yarn plate The distance between hole is 15mm-60mm (being obtained by 3mm × (5-20 times)).When production, when the first fiber content, the second fiber contain It, can be according to the distance between fiber holes and fibre bundle on row's yarn plate 23 in sleeper after amount (and third fiber content) determines Fiber content of the fiber on row's yarn plate 23 and fiber architecture frame 21 is calculated, then according to calculating in the multiple of actual range As a result by fiber architecture on fiber architecture frame 21.
As shown in Figures 3 and 4, row yarn plate 23 include primary fiber row yarn plate 231 (including once arrange yarn plate row 2311 He of yarn hole Primary row's yarn board mount 2312) and secondary stock row yarn plate 232 (including secondary row's yarn plate row yarn hole 2321 and secondary row's yarn plate branch Frame 2322).The distance between the size of secondary stock row's yarn plate 232 and fiber holes thereon are respectively less than primary fiber and arrange yarn plate 231, for example, the distance between the fiber holes on secondary stock row's yarn plate 232 can be actual range of the fibre bundle in sleeper 2-10 times.But the secondary stock arrange on yarn plate 232 actual range of the distance between fiber holes and fibre bundle in sleeper it Between multiple be it is certain, primary fiber arrange the distance between fiber holes and fibre bundle on yarn plate 231 in sleeper it is practical away from Multiple between be also it is certain, so can just obtain designed sleeper density.
In other embodiments, row's yarn plate 23 can not include secondary stock row's yarn plate 232, or arrange including secondary stock Yarn plate 232 and three times fiber row yarn plate, four fiber row's yarn plates etc..Secondary stock arranges yarn plate 232, three times fiber row yarn plate and four Secondary fiber row yarn plate etc. can be set to be arranged between yarn plate 231 and impregnating equipment 24 in primary fiber.
In the embodiment of the present application, the reisn base material may include polyether polyol A, polyether polyol B, polyethers Polyalcohol C, coupling agent, catalyst, foam stabiliser, foaming agent, fire retardant, antioxidant, light stabilizer and isocyanates, it is described The weight ratio of each component of reisn base material and the fiber can be with are as follows:
In the embodiment of the present application, the degree of functionality of the polyether polyol A can be 4-6, and its hydroxyl value can be 200- 800;
The degree of functionality of the polyether polyol B can be 2-4, and its hydroxyl value can be 50-800;
The degree of functionality of the polyether polyol C can be 2-3, and its hydroxyl value can be 50-500.
In the embodiment of the present application, the degree of functionality of the coupling agent can be 1-4.
In the embodiment of the present application, the polyether polyol A, polyether polyol B and polyether polyol C, each independently Can by using sorbierite, sucrose, xylitol, 1,2-PD, ethylene glycol, diethylene glycol (DEG), 1,4-butanediol, neopentyl glycol, Glycerine, trimethylolpropane, ethanol amine, diethanol amine, triethanolamine, ethylenediamine, toluenediamine, methylene dianiline (MDA) and season One of penta tetrol or a variety of combinations are obtained as initiator, and with Polymerization of Propylene Oxide, or with propylene oxide and epoxy Ethane is copolymerized to obtain (wherein, the content that the content of propylene oxide is greater than ethylene oxide).
In the embodiment of the present application, the coupling agent can be amino-containing silane coupling agent, the silane idol containing epoxy group Join one of agent, the silane coupling agent containing thin base and silane coupling agent containing isocyanate group or a variety of;It is described amino-containing Silane coupling agent can be gamma-aminopropyl-triethoxy-silane (KH-550), three oxygen methyl-monosilane (KH-540) of γ-aminopropyl, N- (β-aminoethyl)-γ-aminopropyltrimethoxysilane (KH-792) or N- (β-aminoethyl)-gamma-aminopropyl-triethoxy silicon Alkane (KH-552) etc.;The silane coupling agent containing epoxy group can be γ-glycidyl ether oxygen propyl trimethoxy silicane (KH560), β-(3,4- epoxycyclohexyl) ethyl trimethoxy silane (KH-566) or three second of γ-glycidyl ether oxygen propyl Oxysilane (KH-561) etc.;The silane coupling agent containing thin base can be γ-and dredge base propyl trimethoxy silicane (KH- 590) or γ-dredges base propyl-triethoxysilicane (KH-580) etc.;The silane coupling agent containing isocyanate group can be γ-isocyanate propyl trimethoxysilane (Siquest A-Link 35) or γ-isocyanate propyl triethoxysilane (Siquest A-Link 25) etc..
In the embodiment of the present application, the catalyst can be one of tertiary amine catalyst and organo-metallic catalyst etc. Or it is a variety of;The tertiary amine catalyst can be triethylenediamine, the closed triethylenediamine of acid, trimethyl-N-2- hydroxypropyl Base caproic acid (TMR), the closed TMR (such as TMR-2, TMR-3, TMR-4) of acid, N, N- dimethyl cyclohexyl amine or N- methyl bicyclic Hexylamine etc.;The organo-metallic catalyst can be dibutyl tin dilaurate or isooctyl acid potassium etc..
In the embodiment of the present application, the foam stabiliser can be organo-silicon compound, and the organo-silicon compound can Think one of B8404, B8407, B8409, B8423 and B8433 or a variety of.
In the embodiment of the present application, the foaming agent can be physical blowing agent or chemical foaming agent, the physical blowing Agent can be 141b, pentamethylene, pentane, pentafluoropropane (245fa) or 1,1,1,3,3-pentafluorobutane (365mfc) etc.;It is described Chemical foaming agent is that water makees foaming agent.
In the embodiment of the present application, the fire retardant can add for halogenated phosphate additive flame retardant, phosphoric acid ester One of type fire retardant and halogenated hydrocarbons and other halogen plain additive flame retardants are a variety of;The halogenated phosphate addition type Fire retardant can be three (2- chloroethyl) phosphates (TCEP), three (2- chloropropyl) phosphate TCPP or three (two chloropropyls) phosphorus Acid esters TDCP etc.;The phosphoric acid ester additive flame retardant can be dimethyl methyl phosphonate (DMMP), diethyl ethylphosphate (DEEP) or dimethyl propyl phosphonate ester (DMPP) etc.;The halogenated hydrocarbons and other halogen plain additive flame retardants can be ten Dibromodiphenyl ether (DE-83R) or decabromodiphenylethane etc..
In the embodiment of the present application, the antioxidant can be hindered phenol antioxygen, aromatic amine kind antioxidant and Asia One of phosphoric acid ester antioxidant etc. is a variety of;The hindered phenol antioxygen can-[3-3 (tert-butyl -4 hydroxyl double for triethylene glycol Base -5- aminomethyl phenyl) propionic ester] (245), four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] (1010), thio two Asia Ethyl bis- [3- (- 4 hydroxy benzenes of 3,5- di-t-butyl) propionic ester] (1035), the different monooctyl esters of 3,5- di-t-butyl -4- hydroxy phenylpropionic acid (1135) or butyl octyl diphenylamines (5057) etc..
In the embodiment of the present application, the light stabilizer can be ultraviolet absorbing agent, hindered amine light stabilizer and ammonia One of anti-yellow agent of synthetic fibre is a variety of;The ultraviolet absorber can be N- (carboethoxyphenyl)-N'- methyl-N'- phenyl Carbonamidine (UV-1), 2- (2'- hydroxyl -3'- dodecyl -5'- aminomethyl phenyl) benzotriazole (UV-571) or hydroxyl phenol benzo Triazole type ultraviolet absorber (UV-1130) etc.;The hindered amine light stabilizer can be 292 etc.;The Spandex anti-yellowing agent can Think bis- (N, N- dimethyl-hydrazine amino 4- phenyl) methane (HN-150) or 4,4'- hexamethylene bis (1,1- dimethylamino Urea) (HN-130) etc..
In the embodiment of the present application, the isocyanates can be PAPI (polyaryl polymethylene isocyanates) or modified PAPI can be selected from one of PM-200 and PM-100 etc. or a variety of.
In the embodiment of the present application, the fiber can be selected from glass fibre, aramid fiber, basalt fibre and carbon fiber In any one or more.Also, the fiber can be continuous fiber, and can use long fibre, staple fiber or fiber Powder etc. carries out auxiliary enhancing.Arragement direction of the fiber in sleeper can be along length of sleeper direction, perpendicular to length of sleeper direction Or multidirectional random arrangement.
In the embodiment of the present application, the molding equipment 25 can be continuous mould pressing molding equipment.
The density and fiber content of the sleeper changed involved in following embodiment are all based on 1mm3Unit bodies For product.
Embodiment 1
The composite material sleeper of the present embodiment is in radial directions from inside to outside (i.e. along from the side of sleeper center-to-face dimension layer To) it successively include the first density layer 11, transition zone 12 and the second density layer 13.Fiber 14 in first density layer 11 is by the One fiber content is evenly distributed, and the fiber 14 in second density layer 13 is evenly distributed by the second fiber content, described Fiber 14 in transition zone 12 is in the composite material sleeper 10 in the radial direction from inside to outside by by the first fiber content line Property increases to the formal distribution of the second fiber content, and first fiber content linearly increases according to formula y=0.02x+0.1 Second fiber content is added to, so that the density of the transition zone 12 is in the composite material sleeper in the radial direction from interior To the density for increasing to second density layer by the density linear of first density layer according to formula y=100x+500 outside.
The length of the composite material sleeper of the present embodiment is 4.5m, width 230mm, is highly 140mm, wherein described The width of first density layer 11 is 100mm, with a thickness of 60mm;Second density layer 13 it is close with a thickness of 20mm, described first Spending between layer 11 and second density layer 13 is the transition zone 12.
First fiber content is 10%, and second fiber content is 22%.The density of first density layer is 500kg/m3, the density of second density layer is 1100kg/m3
The raw material for manufacturing the composite material sleeper of the present embodiment is as shown in the table:
Temperature when molding is 40 DEG C.
Embodiment 2
The composite material sleeper of the present embodiment is in radial directions from inside to outside (i.e. along from the side of sleeper center-to-face dimension layer To) it successively include the first density layer 11, transition zone 12 and the second density layer 13.Fiber 14 in first density layer 11 is by the One fiber content is evenly distributed, and the fiber 14 in second density layer 13 is evenly distributed by the second fiber content, described Fiber 14 in transition zone 12 is in the composite material sleeper 10 in the radial direction from inside to outside by by the first fiber content line Property increases to the formal distribution of the second fiber content, and first fiber content is linear according to formula y=0.017x+0.12 Increase to second fiber content so that the transition zone 12 density the composite material sleeper in the radial direction The close of second density layer is increased to by the density linear of first density layer according to formula y=75x+600 from inside to outside Degree.
The length of the composite material sleeper of the present embodiment is 3m, width 260mm, is highly 260mm, wherein described the The width of one density layer 11 is 150mm, with a thickness of 150mm;Second density layer 13 with a thickness of 30mm, first density It is the transition zone 12 between layer 11 and second density layer 13.
First fiber content is 12%, and second fiber content is 25%.The density of first density layer is 600kg/m3, the density of second density layer is 1200kg/m3
The raw material for manufacturing the composite material sleeper of the present embodiment is as shown in the table:
Temperature when molding is 40 DEG C.
Embodiment 3
The composite material sleeper of the present embodiment is in radial directions from inside to outside (i.e. along from the side of sleeper center-to-face dimension layer To) it successively include transition zone 12 and the second density layer 13.Fiber 14 in second density layer 13 is equal by the second fiber content It is distributed evenly, the fiber 14 in the transition zone 12 is in the composite material sleeper 10 in the radial direction from inside to outside by by the One fiber content is linearly increasing to the formal distribution of the second fiber content, and first fiber content is according to formula y= 0.043x+0.1 is linearly increasing to second fiber content, so that the density of the transition zone 12 is in the composite material sleeper According to formula y=140x+500 by the minimum density of transition zone to be linearly increasing to described second from inside to outside in the radial direction close Spend the density of layer.
The length of the composite material sleeper of the present embodiment is 3m, width 240mm, is highly 240mm, wherein the mistake Cross layer 12 with a thickness of 200mm, second density layer 13 with a thickness of 20mm.
First fiber content is 10%, and second fiber content is 53%.The minimum density of the transition zone is 500kg/m3, the density of second density layer is 1900kg/m3
The raw material for manufacturing the composite material sleeper of the present embodiment is same as Example 1.
Temperature when molding is 45 DEG C.
Embodiment 4
The composite material sleeper of the present embodiment successively includes the first density layer 11, transition zone along the direction from center to surface layer 12 and second density layer 13.Fiber 14 in first density layer 11 is evenly distributed by the first fiber content, and described second Fiber 14 in density layer 13 is evenly distributed by the second fiber content, and the fiber 14 in the transition zone 12 is contained by third fiber Amount is evenly distributed.
The length of the composite material sleeper of the present embodiment is 6m, width 230mm, is highly 160mm, wherein described the The width of one density layer 11 is 130mm, with a thickness of 60mm;Second density layer 13 with a thickness of 10mm, first density It is the transition zone 12 between layer 11 and second density layer 13.
First fiber content is 12%, and second fiber content is 25%, and the third fiber content is 18%. The density of first density layer is 600kg/m3, the density of second density layer is 1200kg/m3, the transition zone it is close Degree is 800kg/m3
The raw material for manufacturing the composite material sleeper of the present embodiment is same as Example 1.
Temperature when molding is 50 DEG C.
Performance test
According to the performance of the sleeper of CJ/T 399-2012 (polyurethane foam composite sleeper) test above-described embodiment manufacture. Test result is see following table.
As can be seen that the anti-fatigue performance of the composite material sleeper of the embodiment of the present application is substantially better than existing composite sleeper, Illustrate that the surface strength of the composite material sleeper of the embodiment of the present application is significantly higher, and the concentrfated load on sleeper surface obtains Effectively dispersion;In addition, the composite material sleeper of the embodiment of the present application also has the railway spike resistance to plucking for being substantially better than existing composite sleeper Power.
Although embodiment disclosed by the application is as above, the content only for ease of understanding the application and use Embodiment is not limited to the application.Technical staff in any the application fields, is taken off not departing from the application Under the premise of the spirit and scope of dew, any modification and variation, but the application can be carried out in the form and details of implementation Scope of patent protection, still should be subject to the scope of the claims as defined in the appended claims.

Claims (12)

1. a kind of integral composite material sleeper, contain fiber in the composite material sleeper, which is characterized in that the composite wood Density the increasing from inside to outside in the radial direction in the composite material sleeper of material sleeper, and the composite material sleeper The increase of density is by making the fiber content of the fiber in the composite material sleeper in the radial direction side of the composite material sleeper Increase from inside to outside to realize upwards.
2. integral composite material sleeper according to claim 1, wherein the composite material sleeper includes transition zone, Fiber increasing from inside to outside by by the first fiber content in the radial direction in the composite material sleeper in the transition zone To the formal distribution of the second fiber content.
3. integral composite material sleeper according to claim 2, wherein the fiber in the transition zone is described compound Material sleeper in the radial direction from inside to outside by the formal distribution for being linearly increasing to the second fiber content by the first fiber content.
4. integral composite material sleeper according to claim 3, wherein first fiber content is according to formula I line Property increases to second fiber content, formula I are as follows:
y1=k1x+b1
In formula, y1For the fiber content of tested point, unit %;
X is the distance between tested point and the inward flange of transition zone, unit m;
k1It is nonnegative number, unit 1/m for fiber content growth rate;
b1Within the scope of 2%-25%.
5. integral composite material sleeper according to claim 4, wherein the density of the transition zone is according to formula II line Property increase, formula II are as follows:
y2=k2x+b2
In formula, y2For the density of tested point, unit kg/m3
X is the distance between tested point and the inward flange of transition zone, unit m;
k2It is nonnegative number, unit kg/m for the density increase rate of transition zone4
b2Within the scope of 100-1200, unit kg/m3
6. integral composite material sleeper according to claim 2, the composite material sleeper further includes the first density layer And/or second density layer, first density layer be arranged in the transition zone close to the one of the composite material sleeper center The side far from the composite material sleeper center of the transition zone, and described the is arranged in side, second density layer Fiber in one density layer is evenly distributed by the first fiber content, and the fiber in second density layer presses the second fiber content It is evenly distributed.
7. integral composite material sleeper according to claim 6, wherein
The composite material sleeper successively includes first density layer and the transition zone, institute from inside to outside in radial directions State the 1/10-9/10 of the height with a thickness of the composite material sleeper of the first density layer;Or
The composite material sleeper successively includes the transition zone and second density layer, institute from inside to outside in radial directions State the 6/50-49/50 of the height with a thickness of the composite material sleeper of transition zone;Alternatively,
The composite material sleeper successively include from inside to outside on radial direction first density layer, the transition zone and Second density layer, the 1/10-9/10 of the height with a thickness of the composite material sleeper of first density layer, the mistake Cross the 1/100-22/50 of the height with a thickness of the composite material sleeper of layer.
8. integral composite material sleeper according to claim 1, wherein the composite material sleeper is in radial directions It from inside to outside successively include the first density layer, transition zone and the second density layer, the fiber in first density layer is fine by first Dimension hplc is evenly distributed, and the fiber in second density layer is evenly distributed by the second fiber content, in the transition zone Fiber be evenly distributed by third fiber content, second is fine described in third fiber content < described in the first fiber content < Dimension hplc.
9. the integral composite material sleeper according to any one of claim 2-8, wherein first fiber content is 2%-25%, second fiber content are 17%-60%.
10. integral composite material sleeper a method according to any one of claims 6-8, wherein first density layer Density is 100kg/m3-1200kg/m3, the density of second density layer is 500kg/m3-1900kg/m3
11. the manufacturing method of integral composite material sleeper according to claim 1 to 10, which is characterized in that The described method includes:
According to the density of desired composite material sleeper, fiber of the fiber in the composite material sleeper is calculated and contains Amount, and convert and obtain fiber content of the fiber on fiber architecture frame;
According to fiber content of the fiber on fiber architecture frame, by fiber architecture on fiber architecture frame, fiber is made to pass through row's yarn Plate carries out pre- distribution row yarn;
The fiber for passing through row's yarn plate is drawn to impregnating equipment, and reisn base material is made to impregnate the fiber;And
The fiber for being impregnated with reisn base material is formed, the integral composite material sleeper is obtained.
12. the manufacturing method of composite material sleeper according to claim 11, wherein described to arrange fiber architecture in fiber Include: on cloth holder
Optionally, the fiber for forming the first density layer is equably arranged on the fiber architecture frame;
In the periphery for the fiber for forming first density layer, the fiber architecture of transition zone will be formed in the fiber architecture frame On;
Optionally, in the periphery for the fiber for forming the transition zone, the fiber for forming the second density layer is equably arranged in institute It states on fiber architecture frame.
CN201910218894.4A 2019-03-21 2019-03-21 A kind of integral composite material sleeper and its manufacturing method Pending CN109895420A (en)

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