CN109890353A - Cosmetic composition - Google Patents

Cosmetic composition Download PDF

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Publication number
CN109890353A
CN109890353A CN201780068500.0A CN201780068500A CN109890353A CN 109890353 A CN109890353 A CN 109890353A CN 201780068500 A CN201780068500 A CN 201780068500A CN 109890353 A CN109890353 A CN 109890353A
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acid
cosmetic composition
mass
mentioned
powder
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CN109890353B (en
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仓岛巧
清水秀树
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Shiseido Co Ltd
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Shiseido Co Ltd
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87—Polyurethanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/48—Thickener, Thickening system

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

The present invention provides cosmetic composition, contains unbodied SiO 2 powder and associative thickeners.

Description

Cosmetic composition
Association request
The present invention is based on Japanese patent applications: the claim of priority of Patent 2016-217920 (application on November 8th, 2016), Whole contents of this application are included in by reference and are recorded in this specification (this book).
Technical field
This disclosure relates to cosmetic composition.For example, this disclosure relates to the composition for the material that can be applied to haircut.
Background technique
Such as the cosmetics containing silica are disclosed in Patent Documents 1 to 3.
The emulsification cosmetic recorded in patent document 1 contains: (a) 1.0~2.0 mass % are indicated with specific structural formula Hydrophobically modified polyether urethane, (b) pass through it is broken by with gelation can the gel that constitutes of hydrophilic compounds Obtained microgel and (c) the preparing spherical SiO 2 powder of 0.5~2.0 mass %.
The gel hair styling agent composition recorded in patent document 2 contain (A) silicic acid anhydride and/or hydrophobization silicic acid anhydride, (B) smectite clays mineral and (C) water form.The non-emulsified type hair styling agent composition recorded in patent document 3 contains (A) silicic acid anhydride and/or hydrophobization silicic acid anhydride, (B) polyalcohol and (C) polysaccharide system thickener form.
Existing technical literature
Patent document
Patent document 1: special open 2014-40385 bulletin；
Patent document 2: special open 2012-102056 bulletin；
Patent document 3: special open 2012-102058 bulletin.
Summary of the invention
Problems to be solved by the invention
Using the material of haircuting for the emulsification cosmetic recorded in the patent document 1 containing preparing spherical SiO 2 powder, for being shaped to Power of haircuting with the hair style of hair stream naturally is low, just also low using the power of haircuting after starting and for remaking hair style again Power of haircuting is also low.
It is used as the clay mineral and polysaccharide of thickener in the hair styling agent composition recorded in patent document 2 and 3, causes User may feel that tacky, while can generate friction (I body, squeak) when in use.
Then, haircuting property and haircuting property, and the change that use feeling is good again after being desired to have high haircuting property, just smearing Cosmetic compositions.
Means for solving the problems
According to the 1st viewpoint of the disclosure, it is possible to provide the cosmetics containing unbodied SiO 2 powder and associative thickeners Composition.
Invention effect
According to the cosmetic composition of the disclosure, available high haircuting property, just using after starting high haircuting property and High haircuting property again.In addition, tacky and friction generation can be inhibited according to the cosmetic composition of the disclosure.It uses as a result, The available suitable use feeling of person.
Specific embodiment
According to the preferred embodiment of above-mentioned 1st viewpoint, SiO 2 powder has 50m2The BET specific surface area of/g or more (is removed Outer interior surface area).
According to the preferred embodiment of above-mentioned 1st viewpoint, relative to the quality of cosmetic composition, the content of SiO 2 powder For 0.1 mass of mass %~3 %.
According to the preferred embodiment of above-mentioned 1st viewpoint, associative thickeners be hydrophobic modified polyether urethane and/or Taurine ester system synthesizes macromolecule.
According to the preferred embodiment of above-mentioned 1st viewpoint, hydrophobic modified polyether urethane has structural formula below (I):
In formula (I),
R1、R2And R4Respectively stand alone as the alkyl of carbon atom number 2~4；
R3For that can have the alkyl of the carbon atom number 1~10 of urethane bond；
R5For the alkyl of carbon atom number 8~36；
The number that m is 2 or more；
The number that h is 1 or more；
The number that k is 1~500；
The number that n is 1~200.
According to the preferred embodiment of above-mentioned 1st viewpoint, hydrophobic modified polyether urethane is (PEG-240/ decyl - 20/ hexamethylene diisocyanate of alcohol polyethers) copolymer.
According to the preferred embodiment of above-mentioned 1st viewpoint, it is with 2- acrylamide the third sulphur of -2- that taurine ester system, which synthesizes macromolecule, The polymer and/or copolymer (including cross-linked polymer) of acid or its salt as structural unit.
According to the preferred embodiment of above-mentioned 1st viewpoint, it is (acryloyl dimethyl tauric acid that taurine ester system, which synthesizes macromolecule, - 25 methacrylate of ammonium/behenyl alcohol polyethers) cross-linked polymer.
According to the preferred embodiment of above-mentioned 1st viewpoint, relative to the quality of cosmetic composition, the content of associative thickeners For 0.3 mass of mass %~3 %.
According to the preferred embodiment of above-mentioned 1st viewpoint, relative to the quality of cosmetic composition, cosmetic composition is further Carboxyl vinyl polymer containing 0.1 mass of mass %~0.5 %.
According to the preferred embodiment of above-mentioned 1st viewpoint, the content of oil components is less than 2 mass %.
According to the preferred embodiment of above-mentioned 1st viewpoint, viscosity 1,000mPa s~100,000mPa s.
In the following description, in the bracket after the abbreviation that POE is polyoxyethylene, POP is polyoxypropylene, POE or POP The digital representation compound in POE base or POP base average addition molal quantity.
Cosmetic composition involved in the 1st embodiment for the disclosure is illustrated.The cosmetics group of the disclosure Object is closed, such as can be applied to material of haircuting.In the case where the composition of the disclosure includes oil components, preferably oil-in-water Type.
The cosmetic composition of the disclosure contains unbodied SiO 2 powder and associative thickeners.
[SiO 2 powder]
Silica (silica) is also referred to as silica (silicon dioxide), silicic acid anhydride etc..As silicon dioxide powder Fumed silica powder (Fumed silica powder) can be used for example in end.Silica surface is preferably hydrophilic Property.
It is amorphous to refer to, such as in general each particle in powder is not spherical shape.The BET specific surface of SiO 2 powder Product, except interior surface area (as non-porous plastid), preferably 50m2/ g or more, more preferably 100m2/ g or more, further Preferably 150m2/ g or more.The average primary particle diameter of SiO 2 powder is preferably 1μM or less.By the external table for making powder Area becomes larger, and haircuting property and again haircuting property can be improved.As the commercially available product of SiO 2 powder, can be used for example AEROSIL (registered trademark) series 90,130,150,200,300,380, OX50, TT600, R972, R974, R9200, RY200 etc. (EVONIK company).
Relative to the quality of composition, the content of SiO 2 powder is preferably 0.1 mass % or more, more preferably 0.2 Quality % or more, more preferably 0.4 mass % or more, more preferably 0.5 mass % or more, further preferably 0.8 mass % More than.If the content of SiO 2 powder is less than 0.1 mass %, whole after being unable to get sufficient haircuting property, just smearing Hair property and again haircuting property.In addition, the quality relative to composition, the content of SiO 2 powder is preferably 3 mass % or less, more Preferably 2.5 mass % or less, further preferably 2 mass % or less.If the content of SiO 2 powder is more than 3 mass %, Then tacky or friction can deteriorate.
The cosmetic composition of the disclosure can also contain preparing spherical SiO 2 in the range of not interfering disclosure effect Powder.
[associative thickeners]
Associative thickeners usually has hydrophobic portion and hydrophilic portion.Associative thickeners preferably has hydrophobic portion at both ends.Separately Outside, associative thickeners preferably has hydrophilic portion between the hydrophobic portion at both ends.Such as, it is believed that a certain associative thickeners is logical It crosses hydrophobic portion to associate each other and form network (eyed structure), and shows thickening power.
As associative thickeners, hydrophobic modified polyether urethane and/or taurine ester system can be used for example Synthesize macromolecule.It should be noted that even if the thickening mechanism for the thickener being exemplified below is without associativity, also not by the thickener It is excluded from the thickener that can be applied to disclosure composition.
As hydrophobic modified polyether urethane, the macromolecule with structure formula (I) below can be used for example.
In structure formula (I), R1、R2And R4The respectively alkyl of independent preferably carbon atom number 2~4, more preferably carbon atom number 2~4 alkylidene.R3Can preferably have the alkyl of the carbon atom number 1~10 of urethane bond.R5Preferably carbon atom number 8 ~36 alkyl, the more preferably alkyl of carbon atom number 12~24.For example, R1It can be ethylidene.For example, R2It can be sub- second Base.For example, R3It can be the alkylidene of carbon atom number 4~8.For example, R4It can be ethylidene.For example, R5It can be for branch Carbon number 16~32 alkyl.
In structure formula (I), m is preferably 2 or more number.H be preferably 1 or more number, more preferably 1.K is preferably 1~500 Number, more preferably 100~300.N be preferably 1~200 number, more preferably 10~100.
Hydrophobic modified polyether urethane represented by above-mentioned formula (I), for example, can be by making R1[(OR2)kOH]m Represented one kind or two or more polyether polyol, R3(NCO)H+1Represented one kind or two or more polyisocyanate and HO(R4O)nR5Represented one kind or two or more polyether mono alcohol reaction obtains.At this point, being originated from the isocyanic acid of polyisocyanate The ratio between ester group and the hydroxyl for being originated from the pure and mild polyether mono alcohol of polyether polyols preferably NCO:OH=0.8:1~1.4:1.
Above-mentioned formula R1[(OR2)kOH]mRepresented polyether polyols, can be by by ethylene oxide, epoxy third The polyalcohol of the alkylene oxide (alkylene oxide) of alkane, epoxy butane, epoxychloropropane etc., styrene oxide etc. and m valence into Row addition polymerization and obtain.R1It is determined according to the polyalcohol of m valence.R2It is determined according to alkylene oxide, styrene oxide etc.. R1[(OR2)kOH]mMolecular weight be preferably 500~100,000, more preferably 1000~50,000.
As polyalcohol, the preferably polyalcohol of 2~8 valences.Such as it can be enumerated as polyalcohol: ethylene glycol, propylene glycol, fourth two The dihydric alcohol of alcohol, six methylene glycol, neopentyl glycol etc.；Glycerol, trihydroxy iso-butane, 1,2,3- butane triol, 1,2,3- penta 3 Alcohol, 2- methyl-1,2,3- propane triol, 2- methyl -2,3,4- butane triol, 2- ethyl -1,2,3- butane triol, 2,3,4- penta Alkane triol, 2,3,4- hexane triol, 4- propyl -3,4,5- heptane triol, 2,4- dimethyl -2,3,4- pentane triol, pentamethyl The ternary of glycerol, five glycerol, 1,2,4- butane triol, 1,2,4- pentane triol, trimethylolethane, trimethylolpropane etc. Alcohol；Pentaerythrite, 1,2,3,4- pentane tetrol, 2,3,4,5- hexane tetrol, 1,2,4,5- pentane tetrol, 1,3,4,5- hexane four The tetrahydroxylic alcohol of alcohol etc.；The pentabasis alcohol of adonite, arabite, xylitol etc.；Dipentaerythritol, D-sorbite (ソ Le ビ ッ ト), the hexahydroxylic alcohols of mannitol, iditol etc.；Eight yuan of alcohol of sucrose etc. etc..
In addition, alkylene oxide, styrene oxide etc. through addition, excellent in order to be particularly easy to obtain and play excellent effect It is selected as the alkylene oxide or styrene oxide of carbon atom number 2~4.Alkylene oxide, styrene oxide etc. can be homopolymerization, be also 2 kinds with On atactic polymerization or block polymerization.The method of addition can be usual way.Degree of polymerization k is preferably 0~1000, is more preferably It 1~500, is more preferably 10~200.Relative to whole R2, ethylidene is in R2In shared ratio be preferably 50~100 matter Measure %.
Above-mentioned formula R3(NCO)H+1As long as represented polyisocyanate is in the molecule with 2 or more isocyanate group , it is not particularly limited.For example, can be enumerated as polyisocyanate: aliphatic diisocyanate, aromatic diisocyanates Ester, alicyclic diisocyanate, the diisocyanate of biphenyl diisocyanate and phenylmethane, triisocyanate and four are different Cyanate etc..
As aliphatic diisocyanate, such as can enumerate: methylene diisocyanate, dimethylene diisocyanate, Trimethylene diisocyanate, tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, Dipropyl ether diisocyanate, 2,2- dimethylpentane diisocyanate, 3- methoxyhexane diisocyanate, eight methylene two are different Cyanate, 2,2,4- trimethylpentane diisocyanate, nine methylene diisocyanates, decamethylene diisocyanate, 3- fourth Oxygroup hexane diisocyanate, 1,4- butanediol dipropyl ether diisocyanate, thio dihexyl diisocyanate, xyxylene Diisocyanate, terephthaldehyde's group diisocyanate, tetramethyl xylylene diisocyanate etc..
It as aromatic diisocyanate, such as can enumerate: m-benzene diisocyanate (metaphenylene diisocyanate), right Phenylene diisocyanate (to phenylene vulcabond), 2,4 toluene diisocyanate, 2,6- toluene di-isocyanate(TDI), dimethyl Phenylene diisocyanate, ethyl phenylene diisocyanate, cumene diisocyanate, tolidine diisocyanate, 1,4- naphthalene two Isocyanates, 1,5- naphthalene diisocyanate, 2,6- naphthalene diisocyanate, 2,7- naphthalene diisocyanate etc..
It as alicyclic diisocyanate, such as can enumerate: hydrogenated xylylene diisocyanate, two isocyanide of isophorone Acid esters etc..
It as biphenyl diisocyanate, such as can enumerate: biphenyl diisocyanate, 3,3 '-dimethyl diphenyl diisocyanates Ester, 3,3 '-dimethoxy-biphenyl diisocyanate etc..
It as the diisocyanate of phenylmethane, such as can enumerate: 4,4 '-diisocyanate of diphenyl methane-, 2,2 '- Dimethyl diphenylmethane -4,4 '-diisocyanate, diphenyldimethyhnethane -4,4 '-diisocyanate, 2,5,2 ', 5 ' - Bis- (4- isocyanatophenyl) methane of tetramethyl diphenyl methane -4,4 '-diisocyanate, cyclohexyl (シ Network ロ ヘ キ シ Le ビ ス (4- イ ソ シ オ Application ト Off ェ ニ Le) メ タ Application), 3,3 '-dimethoxydiphenyl methane -4,4 '-diisocyanate Ester, 4,4 '-dimethoxydiphenyl methane -3,3 '-diisocyanate, 4,4 '-diethoxy diphenyl methanes -3,3 '-two are different Cyanate, 2,2 '-dimethyl -5,5 '-dimethoxydiphenyl methane -4,4 '-diisocyanate, 3,3 '-dichlorophenyls two Methylmethane -4,4 '-diisocyanate, benzophenone-3,3 '-diisocyanate etc..
It as the triisocyanate of phenylmethane, such as can enumerate: 1- methylbenzene -2,4,6- triisocyanate, 1,3,5- Trimethylbenzene -2,4,6- triisocyanate, 1,3,7- naphthalene triisocyanate, biphenyl -2,4,4 '-triisocyanate, diphenylmethyl Alkane -2,4,4 '-triisocyanate, 3- Dimethyl diphenylmethane -4,6,4 '-triisocyanate, triphenyl methane -4,4 ', 4 ' ' - Triisocyanate, 1,6,11- hendecane triisocyanate, 1,8- diisocyanate ester group -4- isocyanatomethyl octane, 1,3, 6- hexa-methylene triisocyanate, bicycloheptane triisocyanate, three (isocyanatophenyl) thiophosphates etc..
In addition, polyisocyanate also can be used as the dimer of these polyisocyanate compounds, trimer (cyamelide Ester bond) it uses, in addition, can also react with amine and be used as biuret.
And, it is possible to use these polyisocyanate compounds and with the urethane bond with polyol reaction Polyisocyanate.As polyalcohol, the preferably polyalcohol of 2~8 valences, polyalcohol preferably above-mentioned.It should be noted that As R3(NCO)H+1In the case where using polyisocyanate more than trivalent, preferably with the polyisocyanate of the urethane bond Ester.
Above-mentioned formula HO (R4O)nR5As long as the polyethers of represented polyether mono alcohol monohydric alcohol can be not particularly limited.It is poly- Ether single methanol can be by by the alkylene oxide of ethylene oxide, propylene oxide, epoxy butane, epoxychloropropane etc., styrene oxide etc. Addition polymerization is carried out with monohydric alcohol and is obtained.
Monohydric alcohol described herein, such as can be indicated by following formula (II)s, (III) and (IV).
R5It can be the alkyl of removing hydroxyl in above-mentioned formula (II)~(IV).As R5, preferably as R6、R7、R8、R10 And R11, such as can enumerate: alkyl, alkenyl, alkylaryl, naphthenic base, cycloalkenyl etc..R5Carbon atom number be preferably 8~36, more Preferably 12~24.
It as alkyl, such as can enumerate: methyl, ethyl, propyl, isopropyl, butyl, isobutyl group, tert-butyl, amyl, different Amyl, neopentyl, tertiary pentyl, hexyl, heptyl, octyl, 2- ethylhexyl, nonyl, decyl, undecyl, dodecyl, 13 Alkyl, isotridecyl, myristyl, palmityl, stearyl, iso stearyl, eicosyl, docosyl, lignocerane Base, melissyl, 2- octyldodecyl, 2- dodecyl cetyl, 2- myristyl octadecyl, it is mono methyl branching- Iso stearyl etc..
It as alkenyl, such as can enumerate: vinyl, allyl, acrylic, isopropenyl, cyclobutenyl, pentenyl, isoamyl Alkenyl, hexenyl, heptenyl, octenyl, nonenyl, decene base, hendecene base, laurylene base, tetradecene base, oleyl etc..
It as alkylaryl, can enumerate: phenyl, tolyl, xylyl, cumenyl, mesitylene base, benzyl, benzene Ethyl, styryl, cinnamyl, benzhydryl, trityl, ethylphenyl, propyl phenyl, butyl phenyl, amyl phenyl, oneself Base phenyl, heptyl phenyl, octyl phenyl, nonyl phenyl,αNaphthalene,βNaphthalene etc..
It as naphthenic base and cycloalkenyl, such as can enumerate: cyclopenta, cyclohexyl, suberyl, methylcyclopentyl, methyl ring Hexyl, methylcycloheptyl, cyclopentenyl, cyclohexenyl group, cycloheptenyl, methyl cyclopentene base, methyl cyclohexane alkenyl, methyl cycloheptyl Alkenyl etc..
In above-mentioned formula (III), R9Preferably alkyl, more preferably for example alkylidene, alkenylene, alkyl arylene, ring are sub- Alkyl, ring alkenylene etc..
In addition, alkylene oxide, styrene oxide etc. through addition can be homopolymerization, it can also be atactic polymerization of more than two kinds or embedding Duan Juhe.The method of addition can be usual way.Polymerization degree n is preferably 0~1000, is more preferably 1~200, is further excellent It is selected as 10~200.In addition, ethylidene is in R4In shared ratio, preferably whole R450 weight of mass %~100 %, more excellent It is selected as 65 weight of mass %~100 %.
As the method for manufacturing copolymer represented by above-mentioned formula (I), common polyethers and isocyanates can use Reaction, such as polyethers can be heated 1~3 hour at 80~90 DEG C with isocyanates and be allowed to react.
In addition, making (A) R1[(OR2)kOH]mRepresented polyether polyol and (B) R3(NCO)H+1Represented is poly- Isocyanates and (C) HO (R4O)nR5In the case where represented polyether mono alcohol reaction, the copolymerization of the structure of formula (I) can be generated By-product other than object.For example, in the case where using diisocyanate, as principal product, C-B- represented by formula (I) can be generated The copolymer of A-B-C type, in addition, also secondary C-B-C type, C-B- (A-B) can be generatedxThe compound of-A-B-C type etc..At this point it is possible to Especially the copolymer of formula (I) type is not separated, and with the state of the mixture of the copolymer comprising formula (I) type for the present invention.
As associative thickeners, -20/ hexamethyl diisocyanate of PEG-240/ decyl tetradecyl alcohol polyethers can be used for example Ester) copolymer (copolymer shown in above-mentioned formula (I), R1、R2And R4Respectively ethylidene, R3For hexa-methylene, R5For 2- 12 Alkyl dodecyl, h 1, m 2, k 120, n 20) (ADEKANOL (registered trademark) GT-700, ADEKA company).
As associative thickeners, such as can enumerate: taurine ester system synthesizes macromolecule and/or acrylic ester synthesis is high Molecule.For example, can be used as taurine ester system macromolecular thickener with 2- acrylamide -2- propane sulfonic acid (acryloyl Base dimethyltaurine) or its salt (AMPS structure) as structural unit polymer and/or copolymer (include cross-linked polymeric Object).It as such thickener, such as can enumerate: (- 25 metering system of acryloyl dimethyl tauric acid ammonium/behenyl alcohol polyethers Acid esters) cross-linked polymer (Aristoflex (registered trademark) HMB, Clariant Japan company).
If attempting only to thicken cosmetic composition with clay mineral system or polysaccharide system thickener, it can become and use Person (user) feels tacky or friction composition.However, if can inhibit tacky using associative thickeners or rub The generation of wiping, while thicken cosmetic composition.
In addition, use feeling can be improved if carboxyl vinyl polymer (carbomer) is used for cosmetic composition.So And in the case where associative thickeners is not present, if attempting to be made with carboxyl vinyl polymer containing SiO 2 powder Composition thickening, then SiO 2 powder can be aggregated.However, by addition associative thickeners, even if in carboxy vinyl In the presence of based polyalcohol, the agglutination of SiO 2 powder can also be inhibited.Thus, it is possible to good use feeling is maintained, It can inhibit the agglutination of SiO 2 powder, and cosmetic composition can be made to thicken.
Relative to the quality of composition, the content of the associative thickeners in composition is preferably 0.3 mass % or more, more Preferably 0.4 mass % or more, more preferably 0.5 mass % or more, more preferably 0.8 mass % or more, further preferably 1 Quality % or more.If the content of associative thickeners is to be unable to get sufficient thickening effect less than 0.3 mass %.Relatively The content of associative thickeners in the quality of composition, composition is preferably 3 mass % or less, more preferably 2.5 matter Measure % or less, further preferably 2 mass % or less.If the content of associative thickeners is more than 3 mass %, viscosity became Height, and to the Packing character of container, smear when spreadability, the compatibility of He Yumao Hairdresser deteriorate.
In the composition of the disclosure, in the range of not interfering disclosure effect, other thickeners can also be added.Make It for other thickeners, such as can enumerate: gum arabic, carrageenan, karaya gum, bassora gum, tragon, Wen Quince Seed (marmelo), casein, dextrin, gelatin, pectic acid sodium, sodium alginate, methylcellulose, ethyl cellulose, carboxymethyl are fine Tie up element (CMC), hydroxyethyl cellulose, hydroxypropyl cellulose, polyvinyl alcohol (PVA), polyvinyl methyl ether (PVM), PVP (polyethylene Base pyrrolidones), Sodium Polyacrylate, carboxyl vinyl polymer, locust bean gum, guar gum, tamarind gum, dialkyl dimethyl Ammonium sulfate cellulose, xanthan gum, aluminum magnesium silicate, bentonite, hectorite, silicic acid A1Mg (Veegum), sodium metasilicate magnesium (laponite), silicic acid anhydride etc..
As the thickener combined with associative thickeners, it is preferable to use carboxyl vinyl polymer.By using carboxyl The use feeling of cosmetic composition can be improved in polyvinyl.For example, power of haircuting and warp after just use can be improved When stability.Relative to the quality of composition, the content of carboxyl vinyl polymer be preferably 0.08 mass % or more, more preferably For 0.1 mass % or more.If the content of carboxyl vinyl polymer is to be unable to improve use feeling less than 0.08 mass %.Phase For the quality of composition, the content of carboxyl vinyl polymer is preferably 0.5 mass % or less, more preferably 0.3 mass % Below.If the content of carboxyl vinyl polymer is more than 0.5 mass %, viscosity becomes excessively high, and to the Packing character of container, painting The compatibility of spreadability, He Yumao Hairdresser when smearing deteriorates.
In the case where adding carboxyl vinyl polymer in cosmetic composition, cosmetic composition preferably further contains There is the neutralizer of alkali compounds of additive amount corresponding to carboxyl vinyl polymer etc..As neutralizer, such as can enumerate: Potassium hydroxide, sodium hydroxide etc..
As the thickener combined with associative thickeners, can be used sodium metasilicate magnesium etc. mineral system thickener and/or The polysaccharide system thickener of xanthan gum etc..By making associative thickeners and mineral system thickener and/or polysaccharide system thickener Combination can inhibit adjoint tacky of mineral system and polysaccharide system and friction, and after improving haircuting property and just smearing Haircuting property.Relative to the quality of composition, the content of mineral system thickener is preferably 0.5 mass % or more, more preferably 0.8 matter Measure % or more.If the content of mineral system thickener is that can not adjust the viscosity of preparation less than 0.5 mass % or can not improve whole It has an effect.Relative to the quality of composition, the content of mineral system thickener is preferably 2 mass % or less, more preferably 1.5 mass % Below.If the content of mineral system thickener is more than 2 mass %, tacky or friction can be generated.It is more relative to the quality of composition The content of carbohydrate system thickener is preferably 0.05 mass % or more, more preferably 0.08 mass % or more.If polysaccharide system thickens The content of agent is that can not then adjust the viscosity of preparation less than 0.05 mass % or can not improve power of haircuting.In addition, relative to combination The quality of object, the content of mineral system thickener are preferably 1.5 mass % or less, more preferably 1 mass % or less.If polysaccharide system The content of thickener is more than 1.5 mass %, then can generate tacky or friction.
[powder other than SiO 2 powder]
The cosmetic composition of the disclosure can further contain silicon dioxide powder in the range of not interfering disclosure effect Powder other than end.
As powder, can be used for example: inorganic powder is (for example, talcum, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, rubellan, biotite, lepidolite, calcining mica, calcination of talc, leech Stone, magnesium carbonate, calcium carbonate, alumina silicate, barium silicate, calcium silicates, magnesium silicate, strontium silicate, metal salt, magnesium, silica, boiling Stone, glass, barium sulfate, calcined calcium sulfate hemihydrate (bassanite), calcium phosphate, fluor-apatite, hydroxyapatite, ceramic powder, metallic soap (example Such as, Zinc tetradecanoate, calcium palmitate, aluminum stearate), boron nitride etc.)；Organic dust is (for example, polyamide resin powders (nylon Powder), polyethylene powders, poly-methyl methacrylate base ester powder, Polystyrene powder, styrene and acrylic acid copolymer resin Cosmetics end, benzoguanamine resin powder, polytetrafluorethylepowder powder, cellulose powder, silicone resin powder, Silk Powder, sheep Hair powder, carbamate powder etc.)；Inorganic white pigment (for example, titanium dioxide, zinc oxide etc.)；Inorganic red system's pigment (for example, iron oxide (iron oxide red), iron titanate etc.)；Inorganic brown pigment (γIron oxide etc.), inorganic yellow pigment (yellow iron oxide, loess etc.), inorganic black system pigment (black iron oxide, carbon black, titanium suboxide etc.), inorganic violet face Expect (for example, manganese violet, cobalt violet etc.)；Inorganic green pigment (for example, chromium oxide, chromium hydroxide, cobalt titanate etc.)；Inorganic blue series Pigment (for example, ultramarine, dark purple etc.)；Pearlescent pigment is (for example, aoxidize titanium coated mica, the titanium coated bismuth oxychloride of oxidation, titanium oxide Coating talcum, coloring aoxidize titanium coated mica, bismuth oxychloride, guanin etc.)；Metallic powdery pigment is (for example, aluminium powder, copper powder End etc.)；Zirconium, barium or aluminum lake etc. organic pigment (for example, red No. 201, it is No. 202 red, No. 204 red, No. 205 red, No. 220 red, No. 226 red, No. 228 red, red No. 405, No. 203 orange, No. 204 orange, yellow 205, yellow 401 Number and the equal organic pigments of blue 404, it is No. 3 red, No. 104 red, No. 106 red, No. 227 red, No. 230 red, red Color 401, No. 505 red, No. 205 orange, yellow 4, Sunset Yellow FCF, yellow 202, yellow 203, green 3 and blue No. 1 etc.)；Natural pigment (for example, chlorophyll,βCarrotene etc.) etc..
[other]
The cosmetic composition of the disclosure in the range of not interfering disclosure effect, can according to need suitably containing other at Point, such as: it is aqueous solvent, oil components, anionic surfactant, cationic surfactant, amphoteric surfactant, non- Ionic surface active agent, water soluble polymer, film agent, ultraviolet absorbing agent, metal ion block agent, amino acid, has powder Machine amine, macromolecule emulsion, pH adjusting agent, skin-nourishing agent, vitamin, antioxidant, anti-oxidant auxiliary agent, fragrance etc..
Hereinafter, the example for enumerating the other compositions that can be blended.At least one of following compositions can be added to the disclosure Composition in.
It as aqueous solvent, such as can enumerate: water, alcohol or their mixture.
As water, the water that can be used in cosmetics, quasi drug etc. can be used, can be used for example: Purified Water, ion are handed over Change water, tap water etc..Water phase can contain water-soluble alcohol according to purpose and further.
As water-soluble alcohol, such as can enumerate selected from following at least one: lower alcohol, polyalcohol, polyhydric alcohol polymer, The alcohol alkyl ether of binary, dihydric alcohol alkyl ether, diatomic alcohol ether acid ester, glycerol monoalkyl ether, sugar alcohol, monosaccharide, oligosaccharides, polysaccharide and Their derivative etc..
It as lower alcohol, such as can enumerate: ethyl alcohol, propyl alcohol, isopropanol, isobutanol, tert-butyl alcohol etc..
As polyalcohol, such as can enumerate: dihydric alcohol is (for example, ethylene glycol, propylene glycol, trimethylene, 1,2- fourth two It is alcohol, 1,3 butylene glycol, tetramethylene glycol, 2,3- butanediol, pentamethylene glycol, 2- butylene-1,4-diol, hexylene glycol, pungent Glycol etc.)；Trihydroxylic alcohol (for example, glycerol, trimethylolpropane etc.)；Tetrahydroxylic alcohol is (for example, the pentaerythrite of 1,2,6- hexanetriol etc. Deng)；Pentabasis alcohol (for example, xylitol etc.)；Hexahydroxylic alcohols (for example, D-sorbite (ソ Le ビ ト ー Le), mannitol etc.)；It is polynary Alkoxide polymer is (for example, diethylene glycol (DEG), dipropylene glycol, triethylene glycol, polypropylene glycol, tetraethylene glycol, two glycerol, polyethylene glycol, three sweet Oil, four glycerol, polyglycereol etc.)；The alcohol alkyl ether of binary is (for example, ethylene glycol single methyl ether, ethylene glycol monomethyl ether, second two Alcohol single-butyl ether, ethylene glycol list phenyl ether, ethylene glycol mono hexyl ether, ethylene glycol list 2- methylhexyl ether, ethylene glycol isoamyl ether, Ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol Anaesthetie Ether, ethylene glycol dibutyl ethers etc.)； Dihydric alcohol alkyl ether is (for example, diethylene glycol monomethyl ether, carbiphene, diethylene glycol monobutyl ehter, diethylene glycol dimethyl base Ether, diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol (DEG) methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl Ether, propylene glycol monomethyl ether, propylene glycol monoethyl, glycol monobutyl ether, propylene glycol isopropyl ether, dipropylene glycol first Base ether, dipropylene glycol ethylether, dipropylene glycol butyl ether etc.)；Diatomic alcohol ether acid ester is (for example, ethylene glycol single methyl ether Acetic acid esters, ethylene glycol monomethyl ether acetate, ethylene glycol monobutyl ether acetic acid esters, ethylene glycol list phenyl ether acetate, ethylene glycol Two adipate esters, 3,6-Dioxa-1,2,7,8-octantetracarbonsaeure ester, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ehter acetic acid esters, propylene glycol Monomethyl ether acetate, propylene glycol monoethyl acetic acid esters, propylene glycol monopropyl ether acetic acid esters, propylene glycol list phenyl ether acetate Deng)；Glycerol monoalkyl ether (for example, chimyl alcohol (キ シ Le ア ル コ ー Le), selachyl alcohol, batyl alcohol etc.)；Sugar alcohol is (for example, mountain Pears sugar alcohol, maltitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, starch decompose sugar, malt Sugar, xylitol (キ シ リ ト ー ス), starch decompose sugar and go back carbinol etc.)；Glysolid(グリソリッド)；Tetrahydrofurfuryl alcohol；POE- tetra- Hydrogen furfuryl alcohol；POP- butyl ether；POP POE- butyl ether；Three polypropylene glycerol aethers；POP- glycerin ether；POP- glycerol ether phosphoric acid Ester；POP POE- pentaerythrite ether, polyglycereol etc..
As monosaccharide, such as can enumerate selected from following at least one: triose is (for example, D- glyceraldehyde, dihydroxyacetone (DHA) Deng)；Tetrose (for example, D- erythrose, D- erythrulose, D- threose, antierythrite etc.)；Pentose is (for example, L- is Arabic Sugar, D- xylose, L- lyxose, D-arabinose, D-ribose, D- ribulose, D- xylulose, L- xylulose etc.)；Hexose (example Such as, D-Glucose, D- talose, D-Psicose, D- galactolipin, D-Fructose, L- galactolipin, L- mannose, D-Tag Deng)；Seven carbon sugar (for example, aldoheptose, ketoheptose (ヘ プ ロ-ス) etc.)；Eight carbon sugar (for example, octulose etc.)；Desoxysugar (example Such as, 2-deoxy-D-ribose, L-fucose, 6-deoxy-L-mannose etc.)；Amino sugar is (for example, d-glucosamine, D- half Lactose amine, sialic acid, amino uronic acid, muramic acid etc.)；Uronic acid is (for example, D- glucuronic acid, D-MANNOSE aldehydic acid, L- Gu sieve Uronic acid, D- galacturonic acid, L- iduronic acid etc.) etc..
It as oligosaccharides, such as can enumerate selected from following at least one: sucrose, gentianose, umbelliferose, lactose, Chinese herbaceous peony Sugar, isolychnose class,α,αTrehalose, raffinose, LychnisFlos-Cuculi carbohydrate, umbilicin (ウ Application ビ リ シ Application), stachyose, hair Stamen flower carbohydrate etc..
As polysaccharide, such as can enumerate selected from following at least one: cellulose, Wen Quince seed, chondroitin sulfate, starch, Galactan, dermatan sulfate, glycogen, gum arabic, heparin sulfate, hyaluronic acid, bassora gum, keratan sulfate (keratan sulfate), chondroitin, xanthan gum, mucoitinsulfuric acid, guar gum, glucan, keratosulfate (keratosulfate), locust bean gum, succinoglucan, peaceful acid in Carlow (カ ロ ニ Application acid) etc..
It as other polyalcohols, such as can enumerate selected from following at least one: Glucam E-10 (Glucam E-10), PP 25 (Glucam P-10) etc..
As anionic surfactant, can be used for example: fatty acid soaps are (for example, sodium laurate, sodium palmitate Deng)；High alkyl sulfate salt (for example, NaLS, lauryl potassium sulfate etc.)；Alkyl ether sulphate salts (for example, POE- triethanolamine lauryl sulfate, POE- NaLS etc.)；N- acyl group sarcosine is (for example, sodium N-lauroyl sarcosinate Deng)；Higher fatty acid amides sulfonate is (for example, N- stearyl-N methyl taurine sodium, N- myristoyl-N- methyl ox Sodium sulfonate, coconut oil fat acid methyl taurine sodium, lauryl methyl sodium taurocholate etc.)；Phosphate ester salt (POE- oil base ether phosphoric acid Sodium, POE- stearyl ether phosphoric acid etc.)；Sulfosuccinate is (for example, two (2- ethylhexyl) sodium sulfosuccinates, single lauroyl Base single ethanol amide polyoxyethylene sodium sulfosuccinate, lauryl polypropylene glycol sodium sulfosuccinate etc.)；Alkylbenzene sulfonate (for example, linear alkyl benzene sulphonate, linear dodecylbenzene sulfonic acid triethanolamine, linear dodecylbenzene sulfonic acid etc.)； High-grade aliphatic ester sulfuric acid (for example, hydrogenated coconut oil fatty acid glycerine sodium sulphate etc.)；N- acyl glutamate (for example, N- lauroyl glutamate list sodium, N- stearyl disodium glutamate, N- myristoyl-Pidolidone list sodium etc.)；Sulphation Oil (for example, turkey red oil (ロ ー ト oil) etc.)；POE- alkyl ether carboxylic acid；POE- polyoxyethylene base ether carboxylate；αAlkene sulphur Hydrochlorate；Higher fatty acids sulfonated ester；Secondary alcohol sulphates salt；Higher fatty acid alkanol amide sulfuric acid；Lauroyl list second Alkylolamides sodium succinate；N- palmityl two-triethanolamine of aspartic acid；Casein (acid) sodium etc..
As cationic surfactant, such as can enumerate: alkyl trimethyl ammonium salt is (for example, chlorination stearyl trimethyl Ammonium, Trimethyllaurylammonium chloride etc.)；Fixanol (for example, cetylpyridinium chloride etc.)；Chlorination distearyl two Methyl ammonium dialkyl dimethyl ammonium salt；Chlorination is more (N, N'- dimethyl -3,5- methylenepiperidines)；Alkyl quaternary ammonium salts；Alkyl two Methylbenzylammonium salt；Alkyl isoquinolinium salt；Dialkylmorpholinum salts；POE- alkylamine；Alkylamine salt；Polyamines fatty acid is derivative Object；Amylalcohol aliphatic ester derivatives；Benzalkonium chloride；Benzethonium chloride etc..
As amphoteric surfactant, such as can enumerate: imidazoline system amphoteric surfactant is (for example, 2- undecyl- N, N, N- (hydroxyethyl-carboxymethyl) -2- imidazoline sodium, 2- cocoyl -2- imidazoline hydroxide -1- Carboxyethoxy two Sodium salt etc.)；Betaine series surfactants are (for example, 2- heptadecyl-N- carboxymethyl-N- hydroxyethyl imidazole quinoline glycine betaine, the moon Osmanthus base dimethylaminoethyl acid glycine betaine, alkyl betaine, amide betaine, sulfobetaines etc.) etc..
As lipophilic nonionic surfactant, such as can enumerate: sorbitan fatty acid esters are (for example, dehydration Sorbitol monooleate, sorbitan list isostearate, sorbitan monolaurate, sorbitan Monopalmitate, sorbitan monostearate, NOFABLE SO-992, three oleic acid of sorbitan Ester, five -2 ethyl hexanoic acid of sorbitan, two glyceride, four -2 ethyl hexanoic acid of sorbitan, two glyceride etc.)；It is poly- Glycerin fatty acid glyceride is (for example, single cottonseed oil fatty acid glyceride, single erucic acid glyceride, sesquialter olein, single tristearin Acid glyceride,α,α'-oleic acid pyroglutamic acid glyceride, glycerol malic acid monostearate etc.)；Fatty acid propylene glycol ester (for example, Propylene glycolmonostearate etc.)；Rilanit special derivative；Glycerol alkyl ether etc..
As hydrophilic non-ionic surfactant, such as can enumerate: POE- sorbitan fatty acid esters (for example, POE- dehydrated sorbitol mono-fatty acid ester, POE- sorbitan monostearate, POE- dehydrated sorbitol mono-fatty acid ester, Four oleate of POE- sorbitan etc.)；POE- sorbitan fatty acid ester (for example, POE- D-sorbite monolaurate, POE- sorbitol monooleate, five oleate of POE- D-sorbite, POE- sorbitan monostearate etc.)；POE- glycerol Aliphatic ester is (for example, POE- glyceryl monostearate, POE- glycerol monoisostearate, POE- glyceryl triisostearate etc. POE- monoleate etc.)；POE- aliphatic ester is (for example, the mono- dioleate of POE- distearate, POE-, distearyl acid second two Alcohol ester etc.)；POE- alkyl ether (for example, POE- lauryl ether, POE- oleyl ether, POE- stearyl ether, POE- Shan Yu base ether, POE-2- octyldodecyl ether, POE- cholestane alcohol ether etc.)；Pluronic type (for example, Pluronic etc.)；POE/POP- alkane Base ether is (for example, POE/POP- cetyl ether, POE/POP-2- decyl alkyl ether, POE/POP- single-butyl ether, POE/POP- Hydrogenated lanolin, POE/POP- glycerin ether etc.)；Four POE/, tetra- POP- ethylenediamine condensation product (for example, Tetronic etc.)；POE- castor Sesame oil rilanit special derivative is (for example, POE- castor oil, POE- rilanit special, POE- rilanit special list isostearic acid Ester, three isostearate of POE- rilanit special, POE- rilanit special list pyroglutamic acid list isostearic acid diester, POE- hydrogenation Castor oil maleate etc.)；POE- beeswax/lanolin derivative (for example, POE- D-sorbite beeswax etc.)；Alkanolamide (example Such as, cocoanut fatty acid diethanolamide, lauric monoethanolamide, fatty acid isopropanol amide etc.)；POE- propylene glycol fatty Acid esters；POE- alkylamine；POE- fatty acid amide；Sucrose fatty ester；Alkyl ethoxy dimethyl amine；Three oleyl alcohol phosphoric acid Ester etc..
It as moisturizer, such as can enumerate: polyethylene glycol, propylene glycol, glycerol, 1,3-BDO, xylitol, sorbose Alcohol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitinsulfuric acid, Carlow peaceful acid, Atelocollagen, 12- hydroxy stearic acid Cholesterol ester, sodium lactate, bile salt, dl- pyrrolidone carboxylic acid salt, alkylene oxide derivative (Alkylene oxide Derivative), short chain soluble collagen, two glycerol (EO) PO addition product, Fructus Rosae Normalis extract, Yarrow extract, vegetation Sweet-scented osmanthus extract etc..
As natural water soluble polymer, such as can enumerate: department of botany's macromolecule is (for example, gum arabic, yellow alpine yarrow Glue, galactan, guar gum, tragon, karaya gum, carrageenan, pectin, Qiong Zhi, Wen Quince seed (marmelo), algae Class colloid (brown alga extract), starch (rice, corn, potato, wheat), glycyrrhizic acid)；Department of microbiology macromolecule is (for example, yellow Virgin rubber, glucan, succinoglucan, pullulan etc.)；Animal system macromolecule is (for example, collagen, casein, albumin, bright Glue etc.) etc..
As semi-synthetic water soluble polymer, such as can enumerate: starch-series macromolecule is (for example, carboxymethyl starch, methyl Hydroxypropul starch etc.)；(methylcellulose, ethyl cellulose, methylhydroxypropylcellulose, ethoxy are fine for cellulose polymer Tie up element, cellulose sodium sulfate, hydroxypropyl cellulose, carboxymethyl cellulose, sodium carboxymethylcellulose, avicel cellulose, cellulose Powder etc.)；Alginic acid system macromolecule (for example, sodium alginate, propylene glycol alginate etc.) etc..
As the water soluble polymer of synthesis, such as can enumerate: vinyl polymer is (for example, polyvinyl alcohol, polyethylene Ylmethyl ether, polyvinylpyrrolidone, carboxy vinyl polymer etc.)；Polyoxyethylene system macromolecule (for example, polyethylene glycol 20, 000,40,000,60,000 poloxalkol etc.)；Acrylic acid series macromolecule (for example, Sodium Polyacrylate, Polyacrylic acid ethyl ester, polyacrylamide etc.)；Polyethyleneimine；Cationic polymer etc..
As film agent, such as can enumerate: anionic property film agent is (for example, (methyl) acrylic acid/(methyl) acrylate Copolymer, methyl vinyl ether/maleic anhydride high polymer etc.), cationic film agent is (for example, cationized cellulose, diformazan Base diallyl ammonium chloride polymer, dimethyl diallyl ammonium chloride/acrylamide copolymer etc.), nonionic film agent (for example, polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl acetate, polyacrylate copolymer, (methyl) acrylamide, The macromolecule organic silicon, organic siliconresin, trimethylsiloxysilicate etc.).
As ultraviolet absorbing agent, such as can enumerate: benzoic acid system ultraviolet absorbing agent (for example, p-aminobenzoic acid (with Under be abbreviated as PABA), PABA monoglyceride, N, N- dipropoxy PABA ethyl ester, N, N- diethoxy PABA ethyl ester, N, N- Dimethyl PABA ethyl ester, N, N- dimethyl PABA butyl ester, N, N- dimethyl PABA ethyl ester etc.)；Anthranilic acid system ultraviolet light Absorbent (for example, high menthyl ester of N- acetyl group anthranilic acid etc.)；Salicylic acid system ultraviolet absorbing agent (for example, salicylic acid amyl ester, Menthyl salicylate, high menthyl salicylate, Neo Heliopan OS, phenyl salicylate, salicylic acid benzyl ester, salicylic acid are to different Propyl alcohol phenylester etc.)；Cinnamic acid system ultraviolet absorbing agent is (for example, octyl methoxycinnamate, 4- isopropyl cinnamic acid ethyl Ester, 2,5- diisopropyl cinnamic acid methyl ester, 2,4- diisopropyl cinnamic acid ethyl ester, 2,4- diisopropyl cinnamic acid methyl Ester, p-methoxycinnamic acid propyl diester, p-methoxycinnamic acid isopropyl esters, Neo Heliopan E1000, to methoxy Base cinnamic acid octyl ester (Neo Heliopan AV), p-methoxycinnamic acid 2- ethoxyethyl group ester, to methoxy Base cyclohexyl cinnamate,αCyano-βPhenyl-cinnamic acid ethyl ester,αCyano-βPhenyl-cinnamic acid 2- ethylhexyl, mono- 2- Ethyl hexyl-di-p-methoxy cortex cinnamomi acid glyceride etc.)；Benzophenone series ultraviolet absorbing agent is (for example, 2,4- dihydroxy two Benzophenone, 2,2'- dihydroxy -4- methoxy benzophenone, 2,2' dihydroxy 4,4' dimethoxy benzophenone, 2,2', 4, 4'- tetrahydroxybenzophenone, ESCALOL 567,2- hydroxyl -4- methoxyl group -4'- methyl benzophenone, 2- Hydroxyl -4- methoxy benzophenone -5- sulfonate, 4- phenyl benzophenone, 4'- phenyl-benzophenone -2- formic acid 2- ethyl hexyl Ester, 2-hydroxy-4-n-octoxybenzophenone, 4- hydroxyl -3- carboxyl benzophenone etc.)；3- (4'- methylbenzilidene)-d, l- Camphor, 3- benzal-d, l- camphor；2- phenyl -5- methylbenzoxazole；2,2'- hydroxy-5-methyl base phenyl benzotriazole；2- (2'- hydroxyl -5'- t-octyl phenyl) benzotriazole；2- (2'- hydroxyl -5'- aminomethyl phenyl benzotriazole；Dibenzyl hydrazine；Two fennels Ether methane；4- methoxyl group -4'- tert butyidibenzoylmethane；5- (Asia 3,3- dimethyl -2- norborny) -3- pentane -2- Ketone, dimorpholino pyridazinone (ジ モ Le ホ リ ノ ピ リ ダ ジ ノ)；2- ethylhexyl -2- cyano -3,3- diphenylacrylate ester； 2,4- is bis--{ [4- (2- ethylhexyl oxygroup) -2- hydroxyl]-phenyl } -6- (4- methoxyphenyl)-(1,3,5)-triazine etc..
Agent is blocked as metal ion, such as can be enumerated: 1- hydroxyl ethane -1,1- di 2 ethylhexyl phosphonic acid, 1- hydroxyl ethane -1,1- bis- Phosphonic acids tetrasodium salt, natrium adetate, edetate trisodium, sequestrene Na4, sodium citrate, polyphosphate sodium, sodium metaphosphate, glucose Acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid(EDTA), ethylenediamine hydroxyethyl triacetic acid trisodium etc..
It as amino acid, such as can enumerate: neutral amino acid (for example, threonine, cysteine etc.)；Basic amino acid (for example, oxylysine etc.) etc..In addition, as amino acid derivativges, such as can enumerate: sarcosinate (lauroyl Sodium sarcosinate), acyl glutamate, acyl groupβSodium L-alaninate, glutathione, 2-pyrrolidone-5-carboxylic acid etc..
It as organic amine, such as can enumerate: monoethanolamine, diethanol amine, triethanolamine, morpholine, triisopropanolamine, 2- ammonia Base -2- methyl-1,3-propanediol, 2-amino-2-methyl-1-propanol etc..
It as macromolecule emulsion, such as can enumerate: acrylic resin emulsion, polyacrylic acid ethyl ester emulsion, acrylic acid tree Lipoprotein solution, polyalkyl acrylate emulsion, vinylite emulsion, caoutchouc latex etc..
It as pH adjusting agent, such as can enumerate: lactic acid-sodium lactate, citric acid-sodium citrate, succinic acid-sodium succinate etc. Buffer etc..
It as vitamins, such as can enumerate: vitamin A, B1, B2, B6, C, E and its derivative, pantothenic acid and its derivative Object, biotin etc..
It as antioxidant, such as can enumerate: tocopherols, dibutyl hydroxy toluene, butylated hydroxy anisole, galla turcica Esters of gallic acid etc..
As anti-oxidant auxiliary agent, such as can enumerate: phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, Fumaric acid, cephalin, hexametaphosphate (ester), phytic acid, ethylenediamine tetra-acetic acid etc..
It as the ingredient that others can blend, such as can enumerate: preservative (ethyl-para-hydroxybenzoate, para hydroxybenzene first Acid butyl ester, Chlorphenesin, Phenoxyethanol etc.)；Antiphlogistic is (for example, glycyrrhizin derivative, Enoxolone derivative, salicylic acid spread out Biology, chamenol, zinc oxide, allantoin etc.)；Whitening agent (for example, intacellin, Herba Saxifragae extract, arbutin etc.)；Respectively Kind of extract (for example, Cortex Phellodendri, the coptis, Asian puccoon, Chinese herbaceous peony, when medicine, birch (birch), Salvia japonica, loquat, ginseng, aloe, brocade Certain herbaceous plants with big flowers, orris, grape, semen coicis, sponge gourd, lily, safflower, Rhizoma Chuanxiong, the pinecone, hypericum erectum, rest-harrow, garlic, capsicum, dried orange peel, Radix Angelicae Sinensis, seaweed etc.)；Activator (activating agent) (for example, royal jelly, photosensitive element, cholesterol derivative etc.)；Blood circulation accelerant (for example, Vanillyl pelargonic amide (ノ ニ Le acid ワ レ ニ Le ア ミ De), nicotinic acid benzyl ester, niacinβButoxyethyl, capsaicine, ginger Oily ketone, spot sting tincture, ammonium ichthosulfonate, tannic acid,αBorneol (αBorneol,α- borneol), tocopheryl nicotinate, hexanicotinate, Cyclandelate (cyclandelate), cinnarizine (cinnarizine), tolazoline (tolazoline), acetylcholine (acetylcholine), Verapamil (verapamil), cepharanthine (cepharanthine), gamma oryzanol etc.)；It is anti-grease Bleeding (for example, Sulfur, mesulfen etc.)；Anti-inflammatory agent (for example, tranexamic acid, thiolaurine, hypotaurine etc.) etc..
Moreover, the composition of the disclosure can also suitably contain: caffeine, tannin, Verapamil, tranexamic acid and its spreading out Various extracts from crude drugs, the tocopherol acetate, enoxolone (グ リ of biology, Radix Glycyrrhizae, oblonga (カ リ Application), pyrola japonicaKlenze ex Alef etc. チ Le レ ジ Application acid), the medicament of glycyrrhizic acid (グ リ チ Le リ チ Application acid) and its derivative or its salt etc., vitamin C, ascorbic acid The amino acid and its derivative of whitening agent, arginine, the lysine of magnesium phosphate, ascorbic acid glucoside, arbutin, kojic acid etc. etc. Object.
[oil components]
In the cosmetic composition of the disclosure, the content of oil components is preferably less than 2 mass %, more preferably 1 mass % It below, is more preferably 0 mass %.If the content of oil components is 2 mass % or more, generate tacky, there is obstruction powder Effect of haircuting tendency.In addition, the use feeling of smooth degree etc. can be promoted by making oil components amount less than 2 mass %, And improve apparent transparency.
As oil components, can be used for example: liquid fat, solid grease, wax, hydrocarbon, higher fatty acids, higher alcohol, Synthesize ester oil, silicone oil etc..
As liquid fat, such as can enumerate: avocado oil, camellia oil, turtle oil, macadimia nut oil, corn oil, ermine oil, Olive oil, rapeseed oil, egg oil, sesame oil, persic oil (apricot kernel oil), wheat-germ oil, camellia caul-fat, castor oil, linseed Oil, safflower oil, cottonseed oil, perilla oil, soybean oil, peanut oil, tea-seed oil, Chinese torreyanut oil, rice bran oil, chinese wood oil, Japanese paulownia Oil, jojoba oil, embryo oil, triglycerin etc..
It as solid grease, such as can enumerate: cocoa butter, coconut oil, house oil, hydrogenated coconut oil, palm oil, butter, sheep Oil, h-tallow, palm-kernel oil, lard, ox bone rouge (oil), haze tallow kernel oil, hydrogenated oil and fat, ox foot rouge (oil), haze tallow, hydrogenated castor Oil etc..
As wax class, such as can enumerate: beeswax, candelila wax, cotton wax, Brazil wax, bayberry wax, insect wax (Chinese wax), Spermaceti, lignite wax, rice bran wax, lanolin, kapok wax, acetic acid lanolin, liquid lanolin, sugarcane wax, lanolin fatty acid are different Propyl diester, lauric acid hexyl ester, reduction lanolin, Jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE wool Lipidol acetic acid esters, POE cholesterol ethers, lanolin fatty acid macrogol ester, POE hydrogenated lanolin alcohol ether etc..
It as hydrocarbon ils, such as can enumerate: atoleine, ceresine, saualane, pristane, paraffin, ceresin, squalene, all Intellectual circle, microwax etc..
As higher fatty acids, such as can enumerate: lauric acid, myristic acid, palmitinic acid, stearic acid, behenic acid, oleic acid, Undecenoic acid, Carvedilol acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA) etc..
As higher alcohol, can be used for example: straight chain alcohol is (for example, laruyl alcohol, cetanol, stearyl alcohol, behenyl alcohol, Pork and beans Cool alcohol, oleyl alcohol, cetostearyl alcohol etc.)；Branched-chain alcoho is (for example, single stearyl glycerin ether (batyl alcohol), 2- decyl alkanol, sheep Hair lipidol, cholesterol, phytosterol, hexyl dodecanol, isooctadecanol, octyldodecanol etc.) etc..
As synthesis ester oil, can enumerate: isopropyl myristate, Octanoic acid, hexadecyl ester, myristic acid octyldodecyl Ester, isopropyl myristate, stearic acid butyl ester, lauric acid hexyl ester, myristyl myristate, decyl oleate, diformazan Base octanoic acid hexyl decyl ester, cetyl lactate, Tetradecyl lactate, acetic acid lanolin, Standamul 7061, isostearic acid are different Cetyl, 12- hydroxy stearic acid cholesterol ester, two -2 ethyl hexanoic acid of ethylene glycol ester, dipentaerythritol aliphatic ester, N- alkyl Glycol list isostearate, neopentyl glycol dicaprate, the different stearyl ester of malic acid two, two (2- heptylundecanoic acid) glyceride, Three (2 ethyl hexanoic acid) trimethylolpropanes, three isostearic acid trimethylolpropanes, four (2 ethyl hexanoic acid) pentaerythritol esters, three (2 ethyl hexanoic acid) glyceride, tricaprylin, three different tripalmitins, three isostearic acid trimethylolpropanes, 2- second Base caproic acid cetyl, palmitinic acid 2- ethylhexyl, myristin, three (2- heptylundecanoic acid) glyceride, castor Sesame oil fatty acid methyl ester, oleyl oleate, aceto-glyceride, palmitinic acid 2- heptylundecanoic base ester, adipic acid diisobutyl ester, N- lauroyl-Pidolidone -2- octyldodecyl, adipic acid two (2- heptylundecanoic base) ester, lauric acid ethyl ester, Decanedioic acid two (2- ethylhexyl) ester, myristic acid 2- hexyl decyl ester, palmitinic acid 2- hexyl decyl ester, the adipic acid 2- hexyl last of the ten Heavenly stems Base ester, diisopropyl sebacate, succinic acid 2- ethylhexyl, citric acid triethyl group ester etc..
It as silicone oil, can enumerate: dimethyl polysiloxane, methylhydrogenpolysi,oxane, methyl phenyl silicone, stearic oxygen Ylmethyl polysiloxanes, polyether-modified organopolysiloxane, fluoroalkyl/polyoxyalkylene are total to modified organopolysiloxane, alkane Base modified organopolysiloxane, end modified organopolysiloxane, fluorine richness organopolysiloxane, amino modified organic poly- silicon oxygen Alkane, Silica hydrogel, acrylic acid organosilicon (acrylic polysiloxane, ア Network リ Le シ リ コ ー Application), trimethylsiloxy silicic acid The organo-silicon compound etc. of ester, organosilicon RTV rubber etc..
[resin of haircuting]
The composition of the disclosure can be further containing resin of haircuting.The composition of the disclosure is being used as the case where expecting of haircuting Under, resin of haircuting is the polymer for further increasing power of haircuting.For example, resin of haircuting can be the polymer with film forming.
As resin of haircuting, ionic polymers and/or nonionic polymeric can be used for example.Ionic polymers It can be at least one of anionic polymer, cation property copolymer and amphoteric polymer.As resin of haircuting, do not have There is restriction, can be exemplified polymer below.
(1) the glycine betaine system yin of methacryloxyethyl carboxybetaine/methacrylate copolymer etc. Ionic polymers (Yukaformer (registered trademark) 301 of Mitsubishi Chemical Ind etc.),
(2) ethenyl pyrrolidone of polyvinylpyrrolidone or polyvinylpyrrolidone-vinyl acetate copolymer etc. Ketone system high-molecular compound (Luviskol K-90, VA73 of BASF AG etc.),
(3) vinyl alcohol system high-molecular compound (the synthesis chemical company, Japan of polyvinyl alcohol or polyvinyl butyral etc. Gohsenol (registered trademark), the Denka Poval (registered trademark) of Denki Kagaku Kogyo kabushiki etc.),
(4) acidic vinyl ether system high-molecular compound (Osaka organic chemistry of vinyl methyl ether/maleic acid butyl ester etc. Aniale BEM-42S, Gauntlets ES-225 of ISP company of company etc.),
(5) alkyl acrylate/alkyl methacrylate/diacetone acrylamide/methacrylic acid copolymer, acrylic acid The acrylic acid series high-molecular compound of alkyl ester copolymer, acrylic acid/acrylic acid amides/acrylic acid ethyl ester copolymer etc. (the Luvimer 100P of BASF AG, Ultrahold Strong, Mitsubishi Chemical Ind Diahold (registered trademark) HR- 200, Plascize (registered trademark) L-53P etc. of mutual induction chemical company),
(6) N- methacryloxyethyl-N, N- dimethyl ammonium-α- N- methyl carboxybetaine/alkyl methacrylate The both sexes third of copolymer, acrylic acid octyl amide/hydroxyethyl methacrylate/methacrylic acid Butylaminoethyl ester copolymer etc. Olefin(e) acid system high-molecular compound (Yukaformer (registered trademark) AM-75 of Mitsubishi Chemical Ind, NSC company, Japan Amphomer 28-4910 etc.),
(7) hydroxyethyl cellulose dimethyl diallyl ammonium chloride copolymer, hydroxyethyl cellulose Hydroxyproyl Trimethyl chlorination Ammonium, vinyl pyrrolidone/N, N'- dimethyl amino ethyl methacrylate copolymer diethyl sulfide acid salt solution, diformazan The cationic nitrogenous of homopolymer, the dimethyl diallyl ammonium chloride/acrylamide copolymer of base diallyl ammonium chloride etc. High-molecular compound (Leoguard (registered trademark) GP, the Japan NSC of polymer JR-125, Lion company of Amacor company Celquat L-200 of company, the Gafquat 734 of ISP company, Osaka organic chemistry company H.C. polymer 1N, Nalco Merquat 550 of company etc.).
Relative to the quality of composition, the content for resin of haircuting is preferably 0.1 mass % or more, more preferably 0.3 matter Measure % or more, further preferably 0.5 mass % or more.If being unable to get sufficient power of haircuting less than 0.1 mass %. In addition, the quality relative to composition, the content for resin of haircuting be preferably 8 mass % or less, more preferably 5 mass % or less, Further preferably 3 mass % or less.If adding the resin of haircuting more than 8 mass %, can cause tacky.
Among above-mentioned resin of haircuting, about anionic polymer and amphoteric polymer, with its original state be insoluble in In the case where water, part or all of functional group can be neutralized as needed with inorganic or organic alkaline agent, be allowed to change For water solubility.
The alkaline agent used for the purpose of above-mentioned neutralization can be enumerated as inorganic alkaline agent: sodium hydroxide, potassium hydroxide Deng alkali metal hydroxide.In addition it can enumerate: the volatility alkaline agent of ammonia, morpholine etc.；Triethanolamine, diethanol amine, isopropyl The alkane of hydramine, monoethanolamine, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, 2- amino-2-methyl -1,3- propylene glycol etc. Alcamines；The amino acids etc. of L-arginine, lysine etc..
The viscosity of the cosmetic composition of the disclosure be preferably 1,000mPa s or more, more preferably 10,000mPa s with On.If 000mPa s, then the manual operation easiness of composition reduces less than 1.The viscosity of the composition of the disclosure is preferably 100,000mPa s or less.If more than 100,000mPa s, then to the Packing character of container, smear when spreadability, He Yumao Hairdresser Compatibility deteriorate.Viscosity can be at 30 DEG C with Brookfield type viscosimeter (spindle number is 6 or 7, revolution 10rpm) It is measured.
According to the cosmetic composition of the disclosure, high haircuting property may be implemented.Especially being easy production has fluffy (ボ リ The sense of ュ ー system) hair style.In addition, the hair style that can be improved in moulding is destroyed it according to the cosmetic composition of the disclosure The haircuting property again of repeat style hair style again afterwards.In addition, user can be inhibited to be felt according to the cosmetic composition of the disclosure That feels is tacky.In addition, the generation of friction can be inhibited according to the cosmetic composition of the disclosure.In addition, according to the disclosure Cosmetic composition can improve viscosity by thickener, while can also inhibit the agglutination of SiO 2 powder.
The manufacturing method of the cosmetic composition of the disclosure is illustrated.The cosmetic composition of the disclosure is not limited to Specific method can be made by generally well-known method.For example, making makeup by mixing above-mentioned each ingredient Product composition.
Embodiment
For the cosmetic composition of the disclosure, citing is illustrated below.However, the cosmetic composition of the disclosure is not It is limited to example below.In addition, below in an example, for the cosmetic composition of each test example is applied to material of haircuting Example be illustrated, but the composition of the disclosure is not limited to material of haircuting.The unit of content shown in each table is quality %.
Viscosity is determined for each composition.In addition, for each composition, for stability, haircuting property, just smear after Haircuting property, again haircuting property, evaluated without tacky (べ つ I な さ) and without friction (I body な さ).Each table The evaluation of middle each assessment item of display.
[stability] has rated the dispersing uniformity of the ingredient in composition by visual observation.
A: ingredient is uniformly dispersed or does not observe agglutinator etc..
B: evaluation does not use
C: the dispersion of ingredient is obvious uneven or observes apparent agglutinator etc..
For haircuting property, just smear after haircuting property, again haircuting property, evaluate without tacky and friction free, 3 valuation officers Composition involved in each test example is used as material of haircuting by (syndic), is provided score according to benchmark below, is calculated average mark. The evaluation criteria of each assessment item is as described below.
Whether [haircuting property] has rated can be shaped to the hair style of hair stream naturally by hair and maintain the hair style.
[haircuting property after just smearing], which has rated, to extend on hand by composition and is being after being just applied on hair It is no hair style to be subjected to moulding.
Whether [haircuting property again] has rated can make hair style again behind from being applied on hair composition 1 hour Type.
Composition is applied to valuation officer by [no tacky] with hand haircuted on hair during felt without it is tacky into Evaluation is gone.
Composition is applied to valuation officer by [no friction] with hand haircuted on hair during felt without rub into Evaluation is gone.No friction refers to, smoothness when hair is rubbing against one another and when hair and hand rub.
[evaluation criteria]
5 points: very good
4 points: good
3 points: common
2 points: poor
1 point: excessively poor
[evaluation (average mark)]
A:4 points or more
B:3 points
C:2 points
D:1 points
[embodiment 1 and comparative example 1~2]
The composition of composition involved in embodiment 1 and comparative example 1~2 and evaluation are shown in Table 1.Involved in embodiment 1 Composition includes to have 200 ± 25m of BET specific surface area2The fused silica powder of amorphous/non-porous matter of/g (Directory Value) End and associative thickeners.On the other hand, composition involved in comparative example 1 is free of SiO 2 powder.Involved by comparative example 2 Composition replace amorphous silica powder and include with specific surface area 300m2Spherical shape/Porous of/g (Directory Value) SiO 2 powder.SiO 2 powder in comparative example 2 is porosity, and the specific surface area of catalogue is also considered as and includes The value of interior surface area.It is therefore contemplated that the external surface area of SiO 2 powder used in comparative example 2 is less than in embodiment 1 The SiO 2 powder used.Oil components are free of in embodiment 1.
In composition involved in comparative example 1 and comparative example 2, haircuting property, just smear after haircuting property and haircuting property again It is lower.Comparative example 1 and comparative example 2 are compared, by adding SiO 2 powder, also do not observe haircuting property, just Haircuting property and the improvement of haircuting property again after smearing.However, the group according to involved in the embodiment 1 for using amorphous silica Close object, haircuting property after improving haircuting property significantly compared with comparative example 1 and 2, just smear and again haircuting property.Thus recognize For, in the small SiO 2 powder of external surface area, haircuting property after haircuting property can not be improved, just smeared and again haircuting property. Think the big unbodied silica of external surface area to haircuting property, just smear after haircuting property and haircuting property is effective again.
The viscosity of composition involved in embodiment 1 is 5,600mPa s.
[table 1]
[embodiment 2~5]
The composition of composition involved in embodiment 2~5 and evaluation are shown in Table 2.In embodiment 2, for the group of embodiment 1 It closes object and further adds the ingredient (5) as resin of haircuting.In embodiment 3~5, adding for amorphous silica powder is changed Dosage.
Observation embodiment 2 by addition it is found that haircuted resin, compared with Example 1, haircuting property and haircuting property obtains again Improve.It follows that the combination of amorphous silica powder and resin of haircuting is to haircuting property and again, haircuting property is effective.
In embodiment 3 and 4, although the amount of amorphous silica powder is reduced, but still obtained sufficient haircuting property, Haircuting property after just smearing and again haircuting property.It is thus regarded that the amount of amorphous silica powder be preferably 0.1 mass % with Upper, more preferably 0.4 mass % or more.
In embodiment 5, even if the amount of amorphous silica powder increases, use feeling is not also reduced, and improves and haircut Property, just smear after haircuting property and haircuting property again.It is thus regarded that the amount of amorphous silica powder can be at least added to Until 2.5 mass %.
In embodiment 2~5, embodiment 2 can farthest inhibit tacky.It is thus regarded that in order to inhibit tacky, without fixed The amount of shape SiO 2 powder is preferably 0.5 mass of mass %~1.5 %.
The viscosity of composition involved in embodiment 2~4 is 4,000mPa s~4,500mPa s.Involved by embodiment 5 Composition viscosity be 7,000mPa s.
[table 2]
[embodiment 6~7]
The composition of composition involved in embodiment 6~7 and evaluation are shown in Table 3.In embodiment 6~7, associativity is changed The additive amount of thickener.
In embodiment 6, although the amount of associative thickeners is reduced, but still obtain and Examples 1 to 5 is same comments Valence.It is thus regarded that the amount of associative thickeners is preferably 0.3 mass % or more, more preferably 0.5 mass % or more.
In embodiment 7, even if the amount of associative thickeners increases, the evaluation same with Examples 1 to 5 has also been obtained.By This thinks, until the amount of associative thickeners can at least be added to 2.5 mass %.
[table 3]
[embodiment 8~11 and comparative example 3~5]
The composition of composition involved in embodiment 8~11 and comparative example 3~5 and evaluation are shown in table 4 and table 5.Embodiment 8 In, use the associative thickeners different from associative thickeners used in Examples 1 to 7 (ingredient (4)).Embodiment 9 In, carboxyl vinyl polymer and its neutralizer are further added into the composition of embodiment 7.In embodiment 10 and 11, The thickener that thickening mechanism is different from associative thickeners is applied in combination with associative thickeners.In embodiment 10, by conduct The ingredient (6) of mineral system thickener and ingredient (7) as polysaccharide system thickener are combined with associative thickeners.Embodiment 11 In, it combines ingredient (7) with associative thickeners.The thickening mechanism of ingredient (6) is to form paper room shape (cardhouse) structure. The thickening mechanism of ingredient (7) is high molecular winding.On the other hand, in comparative example 3~5, it is not added with associative thickeners.Compare In example 3, for the composition for removing associative thickeners from the composition of embodiment 7.In comparative example 4, ingredient (6) conduct is used only Thickener.In comparative example 5, ingredient (7) are used only as thickener.
Even if also having been obtained and embodiment 1 in the embodiment 8 using the associative thickeners different from Examples 1 to 7 ~7 same evaluations.Result, it is believed that in order to ensure good use feeling, while also obtaining the excellent of amorphous silica powder Point, associative thickeners are effective.
In the comparative example 4 and 5 for being not added with associative thickeners, tacky and friction is generated, does not obtain good use feeling. It is thought that the influence due to caused by mineral system and polysaccharide system thickener.In addition, also observing the drop of haircuting property in comparative example 5 It is low.In contrast, combination has in the embodiment 10 and 11 of associative thickeners, it is suppressed that tacky and friction.Moreover, embodiment 10 In 11, haircuting property and the haircuting property after just smearing also get a promotion.It is thus regarded that by by associative thickeners and mineral System and/or polysaccharide system thickening agent combination can inhibit tacky due to caused by mineral system and polysaccharide system thickener and friction Generation, while the haircuting property after can also be improved haircuting property and just smearing.
According to embodiment 10 and 11, it is believed that the content of mineral system thickener can be 0.5 mass % or more, preferably 0.8 Quality % or more.Additionally, it is believed that the content of mineral system thickener can be 2 mass % or less, preferably 1.5 mass % or less. The content for thinking polysaccharide system thickener can be 0.05 mass % or more, preferably 0.08 mass % or more.Additionally, it is believed that mine The content of object system thickener can be 1.5 mass % or less, preferably 1 mass % or less.
In comparative example 3 of the carboxyl vinyl polymer as thickener is used only, SiO 2 powder is aggregated, not Obtain stable composition.It is thought that due to caused by the electrostatic interaction of carboxyl vinyl polymer.However, having association in combination In the embodiment 9 of property thickener and carboxyl vinyl polymer, even if in the presence of carboxyl vinyl polymer, it can also To inhibit the agglutination of SiO 2 powder, stable composition has been obtained.Moreover, by addition carboxyl vinyl polymer, with Embodiment 2 compares, and improves the haircuting property after just smearing.It follows that even if using SiO 2 powder being made to be aggregated Thickener in the case where, by adding associative thickeners together, also obtained that SiO 2 powder advantage can be obtained Stable composition.In addition, the viscosity sense of composition increases by addition carboxyl vinyl polymer, improves and just smear Usability and ageing stability afterwards.
According to embodiment 9, it is believed that the content of carboxyl vinyl polymer can be 0.08 mass % or more, preferably 0.1 Quality % or more.Additionally, it is believed that the content of carboxyl vinyl polymer can be 0.5 mass % or less, preferably 0.3 mass % Below.
The viscosity of composition involved in embodiment 8~11 is 20,000mPa s~45,000mPa s.
[table 4]
[table 5]
According to the above-described embodiment and examples, cosmetic composition of the invention is illustrated, but be not limited to above embodiment And embodiment, it may include within the scope of the invention and basic fundamental according to the present invention design is to each open element (packet Containing element documented by claims, the description and the appended drawings) carry out various modifications and changes and improvement.In addition, in the present invention Claims in the range of, various combinations, substitution or the selection of each open element can be carried out.
Further problem, purpose and mode (including changing mode) of the invention is also by including claims All open items of the invention and be illustrated.
The numberical range recorded in this manual is closed, even if should also be construed in the case where no especially record The arbitrary several value or ranges for being included within the scope of this are specifically recorded in this manual.
Industrial availability
The cosmetic composition of the disclosure can be suitable as material of haircuting.In addition, the composition of the disclosure can be used for smearing Or cosmetics, skin preparations for extenal use in erasing to skin.

Claims (12)

1. cosmetic composition contains unbodied SiO 2 powder and associative thickeners.
2. cosmetic composition described in claim 1, wherein above-mentioned SiO 2 powder has 50m2The BET of/g or more compares table Area (except interior surface area).
3. cosmetic composition of any of claims 1 or 2, wherein relative to the quality of above-mentioned cosmetic composition, above-mentioned two The content of silicon oxide powder is 0.1 mass of mass %~3 %.
4. cosmetic composition according to any one of claims 1 to 3, wherein above-mentioned associative thickeners changes for hydrophobicity Property polyether urethane and/or taurine ester system synthesize macromolecule.
5. composition as claimed in claim 4, wherein above-mentioned hydrophobic modified polyether urethane has structural formula below (I):
In formula (I),
R1、R2And R4Respectively stand alone as the alkyl of carbon atom number 2~4；
R3For that can have the alkyl of the carbon atom number 1~10 of urethane bond；
R5For the alkyl of carbon atom number 8~36；
The number that m is 2 or more；
The number that h is 1 or more；
The number that k is 1~500；
The number that n is 1~200.
6. cosmetic composition described in claim 4 or 5, wherein above-mentioned hydrophobic modified polyether urethane is (PEG- - 20/ hexamethylene diisocyanate of 240/ decyl tetradecyl alcohol polyethers) copolymer.
7. cosmetic composition as claimed in claim 4, wherein it is with 2- acryloyl that above-mentioned taurine ester system, which synthesizes macromolecule, The polymer and/or copolymer (including cross-linked polymer) of amine -2- propane sulfonic acid or its salt as structural unit.
8. cosmetic composition described in claim 4 or 7, wherein it is (acryloyl group that above-mentioned taurine ester system, which synthesizes macromolecule, - 25 methacrylate of dimethyltaurine ammonium/behenyl alcohol polyethers) cross-linked polymer.
9. cosmetic composition according to any one of claims 1 to 8, wherein the matter relative to above-mentioned cosmetic composition Amount, the content of above-mentioned associative thickeners are 0.3 mass of mass %~3 %.
10. cosmetic composition according to any one of claims 1 to 9, wherein the matter relative to above-mentioned cosmetic composition Amount, the carboxyl vinyl polymer further containing 0.1 mass of mass %~0.5 %.
11. cosmetic composition according to any one of claims 1 to 10, wherein the content of oil components is less than 2 matter Measure %.
12. cosmetic composition described in any one of claim 1~11, wherein viscosity 1, s~100 000mPa, 000mPa・s。
CN201780068500.0A 2016-11-08 2017-11-02 Cosmetic composition Active CN109890353B (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003342130A (en) * 2002-05-30 2003-12-03 Shiseido Co Ltd Hair cosmetic
FR2870724A1 (en) * 2004-05-28 2005-12-02 Oreal Composition, useful for the treatment (e.g. discoloration) of human keratinous material, comprises a compound (ethylenediamine-N,N'-disuccinic acid), pearling agent and/or opacifying agent
JP2006062996A (en) * 2004-08-25 2006-03-09 Shiseido Co Ltd Hair cosmetic
CN1784214A (en) * 2003-05-09 2006-06-07 宝洁公司 Wet skin treatment compositions comprising gel-networks
CN1921824A (en) * 2004-02-18 2007-02-28 威娜股份有限公司 Hair-treatment agent comprising terpolymer from vinyl pyrrolidone, methacrylamide and vinyl imidazole and active ingredients and additives
CN101795661A (en) * 2007-08-30 2010-08-04 宝洁公司 Leave-in hair styling product with particles for improving hair volume
WO2010126090A1 (en) * 2009-04-28 2010-11-04 株式会社資生堂 Hair-dressing cosmetic
JP2014058467A (en) * 2012-09-18 2014-04-03 Shiseido Co Ltd Hair cosmetic

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009022444A1 (en) * 2009-05-23 2010-01-07 Clariant International Limited Liquid composition, useful to preserve e.g. cream, comprises sorbitan monocaprylate and antimicrobial agent comprising organic acid and its salts, formaldehyde donor, isothiazolinone, paraben ester and its salts and pyridone and its salts
JP5823115B2 (en) 2010-11-11 2015-11-25 株式会社マンダム Non-emulsifying hair styling composition
JP5823114B2 (en) 2010-11-11 2015-11-25 株式会社マンダム Gel hair styling composition
JP6041471B2 (en) * 2011-09-16 2016-12-07 株式会社マンダム Emulsion composition for hairdressing agent
JP2014040385A (en) 2012-08-21 2014-03-06 Shiseido Co Ltd Emulsified cosmetic
JP6092365B2 (en) 2013-03-29 2017-03-08 株式会社マンダム Hairdressing composition

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003342130A (en) * 2002-05-30 2003-12-03 Shiseido Co Ltd Hair cosmetic
CN1784214A (en) * 2003-05-09 2006-06-07 宝洁公司 Wet skin treatment compositions comprising gel-networks
CN1921824A (en) * 2004-02-18 2007-02-28 威娜股份有限公司 Hair-treatment agent comprising terpolymer from vinyl pyrrolidone, methacrylamide and vinyl imidazole and active ingredients and additives
FR2870724A1 (en) * 2004-05-28 2005-12-02 Oreal Composition, useful for the treatment (e.g. discoloration) of human keratinous material, comprises a compound (ethylenediamine-N,N'-disuccinic acid), pearling agent and/or opacifying agent
JP2006062996A (en) * 2004-08-25 2006-03-09 Shiseido Co Ltd Hair cosmetic
CN101795661A (en) * 2007-08-30 2010-08-04 宝洁公司 Leave-in hair styling product with particles for improving hair volume
WO2010126090A1 (en) * 2009-04-28 2010-11-04 株式会社資生堂 Hair-dressing cosmetic
CN102413811A (en) * 2009-04-28 2012-04-11 株式会社资生堂 Hair-dressing cosmetic
JP2014058467A (en) * 2012-09-18 2014-04-03 Shiseido Co Ltd Hair cosmetic

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
郑艳红: "复合材料增强增韧的实验研究", 《复合材料学报》 *

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