CN109884076A - A method of analysis reverse osmosis membrane salt rejection rate performance - Google Patents

A method of analysis reverse osmosis membrane salt rejection rate performance Download PDF

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Publication number
CN109884076A
CN109884076A CN201910265443.6A CN201910265443A CN109884076A CN 109884076 A CN109884076 A CN 109884076A CN 201910265443 A CN201910265443 A CN 201910265443A CN 109884076 A CN109884076 A CN 109884076A
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China
Prior art keywords
osmosis membrane
reverse osmosis
rejection rate
salt rejection
diaphragm
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CN201910265443.6A
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Chinese (zh)
Inventor
小勇
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Ji'an Gallon Film Environmental Protection Technology Co Ltd
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Ji'an Gallon Film Environmental Protection Technology Co Ltd
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Priority to CN201910265443.6A priority Critical patent/CN109884076A/en
Publication of CN109884076A publication Critical patent/CN109884076A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of methods for analyzing reverse osmosis membrane salt rejection rate performance, comprising the following steps: the reverse osmosis membrane component that (a) is analysed to is attached to the reverse osmosis membrane machine for test analysis;(b) water flowing is carried out to reverse osmosis membrane component to be analyzed and tests its salt rejection rate;(c) when salt rejection rate exceeds range of normal value, determine that salt rejection rate is abnormal, carry out step (d);Otherwise, test terminates;(d) water flowing dyeing test is carried out to reverse osmosis membrane component to be analyzed using the liquid medicine that coloring agent is added again;(e) the film bag for dismantling reverse osmosis membrane component, checks diaphragm colored state;(f) it is analyzed according to diaphragm colored state and determines abnormal cause.It the composite can be widely applied to reverse osmosis membrane manufacturing field.

Description

A method of analysis reverse osmosis membrane salt rejection rate performance
Technical field
The present invention relates to a kind of methods for analyzing reverse osmosis membrane salt rejection rate performance.
Background technique
Reverse osmosis membrane component is common component in water purifier.In order to save space and easy to install and use, traditional is anti- Infiltration membrane element is all using single film bag by the way of the water producing pipe spiral winding of center, to be ultimately formed to the close film bag of multilayer Layer is constituted cylindric, and central tube is as collector pipe, the collector pipe of the multilayer pure water collection of film bag to the heart in the component.Mesh Before, during the manufacturing of reverse-osmosis membrane element, salt rejection rate detection is that one after ro components batch production is important Detection process.It after salt rejection rate exception is tested in water flowing, needs to dismantle reverse osmosis membrane component, carries out anomaly analysis, it is different to find out Normal reason mostlys come from diaphragm itself or leakproofness extremely, but many abnormal, is visually difficult to observe and accurately determine, Therefore the prior art can not quick and precisely determine that generating bad reason changes so that product is difficult to avoid that secondary injury subsequent It is difficult to avoid that the batch problem such as film deficient purchase occur in good, be easy to cause biggish loss.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies of the prior art and provide, one kind is simple and easy to do, result is quasi- Really, the method for analysis reverse osmosis membrane salt rejection rate performance high-efficient, at low cost.
Technical solution used by the method for analysis reverse osmosis membrane salt rejection rate performance of the invention is: the following steps are included:
(a) the reverse osmosis membrane component being analysed to is attached to the reverse osmosis membrane machine for test analysis;
(b) water flowing is carried out to reverse osmosis membrane component to be analyzed and tests its salt rejection rate;
(c) when salt rejection rate exceeds range of normal value, determine that salt rejection rate is abnormal, carry out step (d);Otherwise, test terminates;
(d) water flowing dyeing test is carried out to reverse osmosis membrane component to be analyzed using the liquid medicine that coloring agent is added again;
(e) the film bag for dismantling reverse osmosis membrane component, checks diaphragm colored state;
(f) it is analyzed according to diaphragm colored state and determines abnormal cause.
Further, further include following steps before step (a):
(a0) negative pressure ventilation detection is carried out to reverse osmosis membrane bag, checks its vacuum degree, when vacuum degree exceeds range of normal value When, it carries out step (a);Otherwise, test terminates.
Further, the coloring agent is rhodamine or rhodamine B.
Further, in step (f), if uneven smooth distributed area occurs in diaphragm colored state, the area Ze Gai diaphragm is different Often.
Further, if discrete striped occurs in diaphragm dyeing, exception scratch or impression caused by being determined as manually.
Further, if spot occurs in diaphragm dyeing, it is determined as that diaphragm supplied materials itself is abnormal.
Further, if netted striped occurs in diaphragm, it is determined as damage caused by runner cloth or filter extruding.
Further, if there is dyeing unevenly on diaphragm periphery, it is judged to sealing exception.
The beneficial effects of the present invention are: the method that the present invention uses staining analysis, to find reverse osmosis membrane component salt rejection rate Where abnormal problem, using the normal water principle processed of reverse osmosis membrane, raw water is replaced with and the liquid medicine of coloring agent is added tests, Reverse osmosis membrane water hole can retain 0.0001 micron of substance, and normal film coloring agent can not penetrate, only diaphragm or sealing Property deposit when abnormal, region can penetrate coloring agent, dyed color is deeper, salt rejection rate influence it is bigger, tentatively discovery reverse osmosis After defective products occurs in membrane element, the liquid medicine dyeing by the way that coloring agent is added realizes what analysis reverse osmosis membrane salt rejection rate generated extremely Reason is added the liquid medicine of coloring agent by that can leave a trace when reverse-osmosis membrane element, darkens, showed not when trace is heavier When uniform ground is distributed, the reason of causing defective products, can determine that by diaphragm colored state, such as artificial finger touches or runner Cloth, filter extruding cause reverse osmosis membrane is damaged and supplied materials is abnormal etc., and " can develop " many meat by means of the present invention The exception that eye can't see, exception and glue sealing sexual abnormality including desalination layer etc., therefore the present invention is a kind of simple and easy to do, result Accurately, the method for analysis reverse osmosis membrane salt rejection rate performance high-efficient, at low cost.
Detailed description of the invention
Fig. 1 is the flow diagram of the method for the analysis reverse osmosis membrane salt rejection rate performance of the embodiment of the present invention;
Fig. 2~Fig. 4 is several in step (f) in the method for the analysis reverse osmosis membrane salt rejection rate performance of the embodiment of the present invention The schematic diagram of typical diaphragm colored state.
Specific embodiment
As shown in Figure 1, the present embodiment analysis reverse osmosis membrane salt rejection rate performance method the following steps are included:
(a0) negative pressure ventilation detection is carried out to reverse osmosis membrane bag, checks its vacuum degree, when vacuum degree exceeds range of normal value When, it carries out step (a);Otherwise, test terminates;This step is preliminary investigation, can tentatively be judged in the case where not having to whole water inspections It is abnormal, and baking step when water examines normal is eliminated, it greatly improves the efficiency, reduces costs;
(a) the reverse osmosis membrane component being analysed to is attached to the reverse osmosis membrane machine for test analysis;
(b) water flowing is carried out to reverse osmosis membrane component to be analyzed and tests its salt rejection rate;
(c) when salt rejection rate exceeds range of normal value, determine that salt rejection rate is abnormal, carry out step (d);Otherwise, test terminates;
(d) water flowing dyeing test is carried out to reverse osmosis membrane component to be analyzed using the liquid medicine that coloring agent is added again, In, the coloring agent is rhodamine or rhodamine B;
(e) the film bag for dismantling reverse osmosis membrane component, checks diaphragm colored state;
(f) it is analyzed according to diaphragm colored state and determines abnormal cause, if the appearance of diaphragm colored state is uneven smooth Distributed area, the area Ze Gai diaphragm is abnormal, and several typical case's abnormalities are as follows: as shown in Figure 1, if discrete item occurs in diaphragm dyeing Line, then exception scratch or impression caused by being determined as manually;As shown in Fig. 2, being determined as film if spot occurs in diaphragm dyeing Piece supplied materials itself is abnormal, and there are flaws;As shown in figure 3, being determined as that runner cloth or filter squeeze if netted striped occurs in diaphragm It is damaged caused by pressure;If there is dyeing unevenly on diaphragm periphery, it is judged to sealing exception.
The method that the present invention uses staining analysis is utilized with finding the problem place of reverse osmosis membrane component salt rejection rate exception Raw water is replaced with and the liquid medicine of coloring agent is added tests by the normal water principle processed of reverse osmosis membrane, and reverse osmosis membrane water hole can be cut 0.0001 micron of substance is stayed, normal film coloring agent can not penetrate, and only diaphragm or leakproofness are deposited when abnormal, location Domain can penetrate coloring agent, and dyed color is deeper, and salt rejection rate influence is bigger, defective products occur in tentatively discovery reverse-osmosis membrane element Afterwards, analysis reverse osmosis membrane salt rejection rate exception Producing reason is realized by the way that the liquid medicine dyeing of coloring agent is added, coloring agent is added Liquid medicine can leave a trace when passing through reverse-osmosis membrane element, darken when trace is heavier, when showing uneven smooth distribution, lead to Crossing diaphragm colored state can determine that the reason of causing defective products, and such as artificial finger touches or runner cloth, filter extruding cause instead Diaphragm damage and supplied materials exception etc. are permeated, " can develop " exception being much invisible to the naked eye by means of the present invention, packet Include exception and the glue sealing sexual abnormality etc. of desalination layer, thus the present invention be it is a kind of it is simple and easy to do, result is accurate, it is high-efficient, at The method of this low analysis reverse osmosis membrane salt rejection rate performance.
It the composite can be widely applied to reverse osmosis membrane manufacturing field.

Claims (8)

1. a kind of method for analyzing reverse osmosis membrane salt rejection rate performance, it is characterised in that: the following steps are included:
(a) the reverse osmosis membrane component being analysed to is attached to the reverse osmosis membrane machine for test analysis;
(b) water flowing is carried out to reverse osmosis membrane component to be analyzed and tests its salt rejection rate;
(c) when salt rejection rate exceeds range of normal value, determine that salt rejection rate is abnormal, carry out step (d);Otherwise, test terminates;
(d) water flowing dyeing test is carried out to reverse osmosis membrane component to be analyzed using the liquid medicine that coloring agent is added again;
(e) the film bag for dismantling reverse osmosis membrane component, checks diaphragm colored state;
(f) it is analyzed according to diaphragm colored state and determines abnormal cause.
2. the method for analysis reverse osmosis membrane salt rejection rate performance according to claim 1, it is characterised in that: before step (a), Further include following steps:
(a0) negative pressure ventilation detection is carried out to reverse osmosis membrane bag, checks its vacuum degree, when vacuum degree exceeds range of normal value, into Row step (a);Otherwise, test terminates.
3. the method for analysis reverse osmosis membrane salt rejection rate performance according to claim 1 or 2, it is characterised in that: the dyeing Agent is rhodamine or rhodamine B.
4. the method for analysis reverse osmosis membrane salt rejection rate performance according to claim 1 or 2, it is characterised in that: step (f) In, if uneven smooth distributed area occurs in diaphragm colored state, the area Ze Gai diaphragm is abnormal.
5. the method for analysis reverse osmosis membrane salt rejection rate performance according to claim 4, it is characterised in that: if diaphragm dyes There is discrete striped, then exception scratch or impression caused by being determined as manually.
6. the method for analysis reverse osmosis membrane salt rejection rate performance according to claim 4, it is characterised in that: if diaphragm dyes There is spot, is then determined as that diaphragm supplied materials itself is abnormal.
7. the method for analysis reverse osmosis membrane salt rejection rate performance according to claim 4, it is characterised in that: if diaphragm occurs Netted striped is then determined as damage caused by runner cloth or filter extruding.
8. the method for analysis reverse osmosis membrane salt rejection rate performance according to claim 4, it is characterised in that: if in diaphragm week There is dyeing unevenly in side, then is judged to sealing exception.
CN201910265443.6A 2019-04-03 2019-04-03 A method of analysis reverse osmosis membrane salt rejection rate performance Pending CN109884076A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115414788A (en) * 2022-08-03 2022-12-02 佛山市麦克罗美的滤芯设备制造有限公司 Reverse osmosis membrane detection device and reverse osmosis membrane detection method

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CN104399374A (en) * 2014-11-25 2015-03-11 贵阳时代沃顿科技有限公司 Method and device for detecting integrity of composite reverse osmosis membrane desalting layer
CN204241295U (en) * 2014-12-12 2015-04-01 湖南沁森环保高科技有限公司 A kind of reverse osmosis membrane pressure dyeing proving installation
CN205953606U (en) * 2016-08-03 2017-02-15 深圳加仑膜技术有限公司 A reverse osmosis membrane for in water purifier
CN107583467A (en) * 2017-08-15 2018-01-16 深圳安吉尔饮水产业集团有限公司 A kind of method and device for testing reverse osmosis membrane

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Publication number Priority date Publication date Assignee Title
CN103551045A (en) * 2013-11-11 2014-02-05 国家电网公司 Dye determination method for oxidization condition of reverse osmosis membrane
CN104399374A (en) * 2014-11-25 2015-03-11 贵阳时代沃顿科技有限公司 Method and device for detecting integrity of composite reverse osmosis membrane desalting layer
CN204241295U (en) * 2014-12-12 2015-04-01 湖南沁森环保高科技有限公司 A kind of reverse osmosis membrane pressure dyeing proving installation
CN205953606U (en) * 2016-08-03 2017-02-15 深圳加仑膜技术有限公司 A reverse osmosis membrane for in water purifier
CN107583467A (en) * 2017-08-15 2018-01-16 深圳安吉尔饮水产业集团有限公司 A kind of method and device for testing reverse osmosis membrane

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115414788A (en) * 2022-08-03 2022-12-02 佛山市麦克罗美的滤芯设备制造有限公司 Reverse osmosis membrane detection device and reverse osmosis membrane detection method
CN115414788B (en) * 2022-08-03 2024-04-26 佛山市麦克罗美的滤芯设备制造有限公司 Reverse osmosis membrane detection device and reverse osmosis membrane detection method

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Application publication date: 20190614