CN109868109A - A kind of aqueous silicon PU glue and its production method suitable for paving sports field - Google Patents

A kind of aqueous silicon PU glue and its production method suitable for paving sports field Download PDF

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Publication number
CN109868109A
CN109868109A CN201910223641.6A CN201910223641A CN109868109A CN 109868109 A CN109868109 A CN 109868109A CN 201910223641 A CN201910223641 A CN 201910223641A CN 109868109 A CN109868109 A CN 109868109A
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China
Prior art keywords
parts
aqueous silicon
glue
sports field
powder
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Pending
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CN201910223641.6A
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Chinese (zh)
Inventor
胡忠明
马维宏
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Gansu Spotted Sports Equipment Co Ltd
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Gansu Spotted Sports Equipment Co Ltd
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Priority to CN201910223641.6A priority Critical patent/CN109868109A/en
Publication of CN109868109A publication Critical patent/CN109868109A/en
Pending legal-status Critical Current

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Abstract

The present invention relates to field of material technology, are related to materials'use and its paving sports field preparation method.Specially a kind of aqueous silicon PU glue and its production method suitable for paving sports field.Material prescription of the invention is reasonable, and product reaches GB/14833-2011 " synthetic material runway cover " standard prescribed requirement.Impact absorbing, vertical deformation, antiskid value project and index request, compression recovery rate, rebound value performance all exceed standard requirements in performance indicator.There is good cushioning effect on the runway cushion performance of material-paving of the present invention, faces sport injury caused by the reaction force of ankle, joint, ligament with effectively extenuating.Using long-time dehydration, content of volatile organic compound is greatly reduced, the volatile hazardous substances content such as benzene class, formaldehyde is lower than state-set standard, and the sun reaches really tasteless harmless under being exposed to the sun.

Description

A kind of aqueous silicon PU glue and its production method suitable for paving sports field
Technical field
The present invention relates to field of material technology, are related to materials'use and its paving sports field preparation method.Specially one Kind is suitable for the aqueous silicon PU glue and its production method of paving sports field.
Background technique
Plastic cement race track is also known as round-the-clock athletics tracks, and plastic cement race track is with flatness is good, compression strength is high, hardness bullet Property appropriate, stable physical property characteristic, be conducive to the performance for improving sporter's speed and technology, effectively improve and move into Achievement.It is also beneficial to reduce the tumble injury rate of sporter, protection sporter's safety.Existing plastic cement race track can go out after a period of use Existing performance decline, local damage, stability reduce.
In addition, common silicon PU material is deposited as environmental-protecting performance requirement of the market to sports field material product is higher and higher In certain volatility.Especially easily there is the problem of pernicious gas persistently volatilizees under solar exposure high temperature, seriously affects human body Health.
Summary of the invention
The present invention solves that prior art deficiency provides that a kind of service life is long, performance is stable and safety and environmental protection is suitable for sports ground The aqueous silicon PU glue and its production method that ground is laid with.
The technical solution adopted by the present invention to solve the technical problems are as follows:
A kind of aqueous silicon PU glue suitable for paving sports field, raw material include: by weight 40-60 parts of polyether polyol, MDI30-40 parts of isocyanates, 10-15 parts of plasticizer, 5-10 parts of talcum powder, 15-20 parts of kaolin, 5-10 parts of magnesium powder, the green powder of iron 10-15 parts.
Its raw material includes: 15 parts of polyether polyol N220,35 parts of polyether polyol N330, isocyanates by weight 30 parts of MDI50,10 parts of plasticizer, 5 parts of talcum powder, 15 parts of kaolin, 5 parts of magnesium powder, 15 parts of the green powder of iron.
Its raw material includes: 15 parts of polyether polyol N220,35 parts of polyether polyol N330, isocyanates by weight 30 parts of MDI50,10 parts of plasticizer, 5 parts of talcum powder, 15 parts of kaolin, 5 parts of magnesium powder, 15 parts of the green powder of iron.
A kind of production method of the aqueous silicon PU glue suitable for paving sports field, includes the following steps:
A, polyether polyol, talcum powder, kaolin, magnesium powder and the green powder of iron are mixed, heat temperature raising in mixing;
B, in mixing 100-110 DEG C dehydration 120 minutes or more;
C, it is cooled to 90-95 degree and plasticizer and isocyanates MDI is added;
D, 80-90 DEG C stirring insulation reaction 120 minutes or more;
E, 75 degree of material cooling or less metering packings;
F, packaging material and water are mixed and made into aqueous silicon PU glue.
In being mixed in the step B 100-110 DEG C dehydration 120 minutes or more, dehydration is negative in vacuum Pressure carries out, pressure 0.08Mpa or more.
The step F material mixes under 30 DEG C of environment temperature with water, and it is mixed that every 50 kilograms of materials add 250-300 grams of water Aqueous silicon PU glue is made in conjunction.
The invention has the benefit that
1, material prescription of the invention is reasonable, and product, which reaches GB/14833-2011 " synthetic material runway cover " standard regulation, to be wanted It asks.Impact absorbing, vertical deformation, antiskid value project and index request, compression recovery rate, rebound value performance are all super in performance indicator Standard requirements out.Have good cushioning effect on the runway cushion performance of material-paving of the present invention, effectively extenuate in face of ankle, Joint, ligament reaction force caused by sport injury.
2, using long-time dehydration, content of volatile organic compound is greatly reduced, the volatility such as benzene class, formaldehyde have Evil content of material is lower than state-set standard, and the sun reaches really tasteless harmless under being exposed to the sun.
3, aqueous silicon PU glue of the invention forms aqueous covercoat after being laid with, and can guarantee the permanent stabilization of surface structure feature not Become, wear-resisting property meets long-term high-frequency use.And surface layer is tough and tensile, closely knit, is not easy to be scratched by sole or other hard objects, leads to Crossing easy rinse can keep for a long time court sparkling clean.
Specific embodiment
A kind of aqueous silicon PU glue suitable for paving sports field, raw material includes: polyether polyol 40-60 by weight Part, MDI30-40 parts of isocyanates, 10-15 parts of plasticizer, 5-10 parts of talcum powder, 15-20 parts of kaolin, 5-10 parts of magnesium powder, iron Green powder 10-15 parts.
Its preferred raw material includes: 15 parts of polyether polyol N220,35 parts of polyether polyol N330, isocyanide by weight 30 parts of acid esters MDI50,10 parts of plasticizer, 5 parts of talcum powder, 15 parts of kaolin, 5 parts of magnesium powder, 15 parts of the green powder of iron.Kaolin is added Volatile organic compounds is substituted, volatile hazardous substances content is reduced, kaolin promotes stability of strutting system.
Its preferred raw material includes: 15 parts of polyether polyol N220,35 parts of polyether polyol N330, isocyanide by weight 30 parts of acid esters MDI50,10 parts of plasticizer, 5 parts of talcum powder, 15 parts of kaolin, 5 parts of magnesium powder, 15 parts of the green powder of iron.
A kind of production method of the aqueous silicon PU glue suitable for paving sports field, includes the following steps:
A, polyether polyol, talcum powder, kaolin, magnesium powder and the green powder of iron are mixed, heat temperature raising in mixing;
B, in mixing 100-110 DEG C dehydration 120 minutes or more;
C, it is cooled to 90-95 degree and plasticizer and isocyanates MDI is added;
D, 80-90 DEG C stirring insulation reaction 120 minutes or more;
E, 75 degree of material cooling or less metering packings;
F, packaging material and water are mixed and made into aqueous silicon PU glue.
In being mixed in the step B 100-110 DEG C dehydration 120 minutes or more, dehydration is negative in vacuum Pressure carries out, pressure 0.08Mpa or more.
The step F material mixes under 30 DEG C of environment temperature with water, and it is mixed that every 50 kilograms of materials add 250-300 grams of water Aqueous silicon PU glue is made in conjunction.
Embodiment 1
A kind of aqueous silicon PU glue suitable for paving sports field, raw material include: 40 parts of polyether polyol, isocyanide by weight MDI30 parts of acid esters, 10 parts of plasticizer, 5 parts of talcum powder, 15 parts of kaolin, 5 parts of magnesium powder, 10 parts of the green powder of iron.
A kind of production method of the aqueous silicon PU glue suitable for paving sports field, includes the following steps:
A, polyether polyol, talcum powder, kaolin, magnesium powder and the green powder of iron are mixed, heat temperature raising in mixing;
B, in mixing 100 DEG C dehydration 180 minutes;
C, 90 degree of addition plasticizer and isocyanates MDI are cooled to;
D, 80 DEG C stirring insulation reaction 180 minutes;
E, 75 degree of material cooling or less metering packings;
F, packaging material and water are mixed and made into aqueous silicon PU glue.
Embodiment 2
A kind of aqueous silicon PU glue suitable for paving sports field, raw material include: 60 parts of polyether polyol, isocyanide by weight MDI40 parts of acid esters, 15 parts of plasticizer, 10 parts of talcum powder, 20 parts of kaolin, 10 parts of magnesium powder, 15 parts of the green powder of iron.
A kind of production method of the aqueous silicon PU glue suitable for paving sports field, includes the following steps:
A, polyether polyol, talcum powder, kaolin, magnesium powder and the green powder of iron are mixed, heat temperature raising in mixing;
B, in mixing 110 DEG C dehydration 120 minutes;
C, 95 degree of addition plasticizer and isocyanates MDI are cooled to;
D, 90 DEG C stirring insulation reaction 120 minutes;
E, 75 degree of material cooling or less metering packings;
F, packaging material and water are mixed and made into aqueous silicon PU glue.
Embodiment 3
A kind of aqueous silicon PU glue suitable for paving sports field, raw material includes: polyether polyol N220 15 by weight Part, 35 parts of polyether polyol N330,30 parts of isocyanates MDI50,10 parts of plasticizer, 5 parts of talcum powder, 15 parts of kaolin, magnesium 15 parts of the green powder of 5 parts of powder, iron.
A kind of production method of the aqueous silicon PU glue suitable for paving sports field, includes the following steps:
A, polyether polyol, talcum powder, kaolin, magnesium powder and the green powder of iron are mixed, heat temperature raising in mixing;
B, in mixing 110 DEG C dehydration 240 minutes;Dehydration carries out under negative pressure of vacuum, pressure 0.08Mpa with On;
C, 95 degree of addition plasticizer and isocyanates MDI are cooled to;
D, 90 DEG C stirring insulation reaction 240 minutes;
E, 75 degree of material cooling or less metering packings;
F, packaging material and water are mixed and made into aqueous silicon PU glue.
In embodiment 1-3 compared with the material of the prior art, impact absorbing rate is in 36-50%;Vertical direction deformation range exists 0.6-2.5mm;Antiskid value >=47 are measured at 20 DEG C of room temperature;Tensile strength >=0.5 Mpa;Elongation at break >=40%;Anti-flammability It is 1 grade.Kaolin is added and substitutes volatile organic compounds, reduces volatile hazardous substances content, it is steady that kaolin promotes support It is qualitative.Kaolin additive amount needs strict control, and excessive addition, which can reduce the service life, runway cracking easily occurs.Dehydration is true Idling pressure carries out, and pressure 0.08Mpa or more, pretreatment reduces volatile organic compounds later period volatility, is more suitable Primary school, child use, more safe and healthy.

Claims (6)

1. a kind of aqueous silicon PU glue suitable for paving sports field, it is characterised in that its raw material includes: that polyethers is more by weight First alcohol 40-60 parts, MDI30-40 parts of isocyanates 10-15 parts of plasticizer, 5-10 parts of talcum powder, 15-20 parts of kaolin, magnesium powder 5-10 parts, green powder 10-15 parts of iron.
2. a kind of aqueous silicon PU glue suitable for paving sports field according to claim 1, it is characterised in that its raw material It by weight include: 15 parts of polyether polyol N220,35 parts of polyether polyol N330,30 parts of isocyanates MDI50, plasticising 10 parts of agent, 5 parts of talcum powder, 15 parts of kaolin, 5 parts of magnesium powder, 15 parts of the green powder of iron.
3. a kind of aqueous silicon PU glue suitable for paving sports field according to claim 1, it is characterised in that its raw material It by weight include: 15 parts of polyether polyol N220,35 parts of polyether polyol N330,30 parts of isocyanates MDI50, plasticising 10 parts of agent, 5 parts of talcum powder, 15 parts of kaolin, 5 parts of magnesium powder, 15 parts of the green powder of iron.
4. a kind of producer of aqueous silicon PU glue suitable for paving sports field according to any one of claims 1 to 3 Method, it is characterised in that include the following steps:
A, polyether polyol, talcum powder, kaolin, magnesium powder and the green powder of iron are mixed, heat temperature raising in mixing;
B, in mixing 100-110 DEG C dehydration 120 minutes or more;
C, it is cooled to 90-95 degree and plasticizer and isocyanates MDI is added;
D, 80-90 DEG C stirring insulation reaction 120 minutes or more;
E, 75 degree of material cooling or less metering packings;
F, packaging material and water are mixed and made into aqueous silicon PU glue.
5. a kind of production method of aqueous silicon PU glue suitable for paving sports field according to claim 4, feature In being to be mixed in the step B 100-110 DEG C dehydration 120 minutes or more, dehydration is under negative pressure of vacuum It carries out, pressure 0.08Mpa or more.
6. a kind of production method of aqueous silicon PU glue suitable for paving sports field according to claim 4, feature It is that the step F material mixes under 30 DEG C of environment temperature with water, every 50 kilograms of materials add 250-300 grams of water mixing system At aqueous silicon PU glue.
CN201910223641.6A 2019-03-22 2019-03-22 A kind of aqueous silicon PU glue and its production method suitable for paving sports field Pending CN109868109A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110643012A (en) * 2019-10-16 2020-01-03 济南固丰建材科技有限公司 Silicon PU and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003055627A (en) * 2001-08-10 2003-02-26 Denki Kagaku Kogyo Kk Water-base adhesive composition and bonded structure
CN1673305A (en) * 2005-03-25 2005-09-28 师建华 Water solution treatment process of polyurethane elastomer to make plastic track
CN104910694A (en) * 2015-06-29 2015-09-16 山东一诺威聚氨酯股份有限公司 Single-component water-curable polyurethane surface spraying color paste as well as preparation method and application method thereof
CN108314767A (en) * 2017-12-15 2018-07-24 广州市恒辉体育设施有限公司 A kind of preparation method of the elastic material on athletic ground

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003055627A (en) * 2001-08-10 2003-02-26 Denki Kagaku Kogyo Kk Water-base adhesive composition and bonded structure
CN1673305A (en) * 2005-03-25 2005-09-28 师建华 Water solution treatment process of polyurethane elastomer to make plastic track
CN104910694A (en) * 2015-06-29 2015-09-16 山东一诺威聚氨酯股份有限公司 Single-component water-curable polyurethane surface spraying color paste as well as preparation method and application method thereof
CN108314767A (en) * 2017-12-15 2018-07-24 广州市恒辉体育设施有限公司 A kind of preparation method of the elastic material on athletic ground

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110643012A (en) * 2019-10-16 2020-01-03 济南固丰建材科技有限公司 Silicon PU and preparation method thereof

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Application publication date: 20190611