CN109860725A - A kind of cylindrical lithium ion battery and preparation method with internal heat dissipating and tab fixed structure - Google Patents

A kind of cylindrical lithium ion battery and preparation method with internal heat dissipating and tab fixed structure Download PDF

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Publication number
CN109860725A
CN109860725A CN201811585752.3A CN201811585752A CN109860725A CN 109860725 A CN109860725 A CN 109860725A CN 201811585752 A CN201811585752 A CN 201811585752A CN 109860725 A CN109860725 A CN 109860725A
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CN
China
Prior art keywords
battery
tab
lithium ion
heat dissipating
internal heat
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Pending
Application number
CN201811585752.3A
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Chinese (zh)
Inventor
李涛
王勇
周会
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Shandong Goldencell Electronics Technology Co Ltd
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Shandong Goldencell Electronics Technology Co Ltd
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Priority to CN201811585752.3A priority Critical patent/CN109860725A/en
Publication of CN109860725A publication Critical patent/CN109860725A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

A kind of cylindrical lithium ion battery and preparation method with internal heat dissipating and tab fixed structure, it is characterized in that, battery structure includes: steel shell (1), nut cap (2), positive plate (3), diaphragm (4), negative electrode tab (5), electrolyte (6), insulating layer (7), conductive layer (9).Cell cathode ear pole (8) forms pad (10) after connecing by point back welding.The contact that tab with shell bottom can be significantly improved by the fixed tab of conducting resinl, improves withstanding current capability, is suitble to high-power applications battery.It can solve the risk for causing tab to fall off because of high vibration by the fixation of conducting resinl.By insulating layer and conductive layer, the heat that battery can be made to generate in heavy-current discharge quickly sheds.

Description

A kind of cylindrical lithium ion battery and system with internal heat dissipating and tab fixed structure Preparation Method
Technical field
The invention belongs to technical field of lithium ion, are related to a kind of cylinder with internal heat dissipating and tab fixed structure Type lithium ion battery and preparation method.
Background technique
Since lithium ion battery has many advantages, such as that energy density is high, self discharge is small, cycle performance is superior, lithium ion battery is wide It is general be applied to backup power source, energy storage device, electric car, electric bicycle, in electric tool.Lithium battery mainly has positive, negative Pole, diaphragm, electrolyte and 5 part of shell composition.According to shell mode, it is divided into cylindrical battery, rectangular cell and soft-package battery.Circle Column battery only forms one or two solder joint, will appear when battery is large current discharge in negative lug welding process The larger situation of local heat production.It is unfavorable for being large current discharge additionally, due to solder joint area is smaller, and solder joint is in strong vibrator bar There is the risk to fall off under part.Therefore need to solve the problems, such as that negative lug welding position is thermally conductive and conductive poor.
Patent name: a kind of lithium battery and radiator, number of patent application: 201820115630.7, patent publication No.: 207834495U discloses a kind of lithium battery and radiator, including lithium battery casing, explosion-proof cap, core, steel needle and graphite Alkene radiator, wherein lithium battery casing is in hollow structure, and lithium battery casing includes bulge-structure and cylindrical structure, is prevented Quick-fried nut cap is set to inside the bulge-structure and mechanical seal.The patent the utility model has the advantages that by the periphery of the core The graphene radiator being arranged continuously can pass through the cooling fin by the continual heat for generating lithium battery interior It is transmitted to inside the graphene heat-dissipating pipe, and is discharged into heat inside the bulge-structure by the cooling ring, and pass through Heat is excluded the inside of lithium battery by the gas vent.The patent is by graphene radiator, when the patent of invention of application It by conducting resinl and casting glue, is fixed by pole ear, plays the role of heat dissipation, improves a point back welding and fix and electric conductivity.The two There is apparent difference.
Number of patent application: 201621273440.5, patent publication No.: 206293500U, patent name: a kind of heat dissipation of collection plus The electrostrictive polymer core power battery module of hot one, it is disclosed that a kind of electrostrictive polymer core power electricity of collection heat dissipation heating one Pond module, including battery core bracket, battery core and aluminum hull clamping plate, battery core bracket are cuboid internal cavities, and more than two battery cores are put It sets in battery core bracket, aluminum hull clamping plate is close in the outermost two sides of battery core, and tab connection sheet or aluminium sheet are connect with the positive and negative tab of battery core, electricity The one side of core pastes and pastes silica gel piece at green special cotton and cell polar ear;Two or more pastes the battery core of green special cotton and silica gel piece, Heat conductive graphite piece is pasted on green special cotton face the same face with pasting in a wherein battery core again, heating sheet be placed on two battery cores it Between and heating sheet two sides mutually pasted with green special cotton face respectively;Temperature sensor is connect with heat conductive graphite piece.It is provided simultaneously with heat dissipation And heating function, but the patent belongs to the heat radiation structure design outside battery core, is suitble to battery Pack.With the patent of invention of application, There is basic difference on radiator structure.
Summary of the invention
The present invention provides a kind of cylindrical lithium ion battery and preparation method with internal heat dissipating and tab fixed structure, It is controlled by structure design and processes.It can effectively solve the problems, such as that negative lug welding position is thermally conductive and conductive poor.
To achieve the above object, the technical solution adopted by the present invention is that:
A kind of cylindrical lithium ion battery with internal heat dissipating and tab fixed structure, including steel shell are provided with lid on steel shell Cap, characterized in that battery roll core is provided in steel shell, battery roll core includes that positive plate, diaphragm, negative electrode tab are successively mutually rolled up, Be additionally provided with electrolyte in steel shell, battery roll core bottom is provided with cell cathode ear pole, cell cathode ear pole by conductive layer into Row is wrapped up and is fixed, and conductive layer covers a layer insulating, and cell cathode ear pole forms pad after connecing by a point back welding.
, acetone 20 ~ 200 carries out cathode point back welding after inside battery core winding into shell and connects to form pad;It is then injected into epoxy Resin conductive glue forms conductive layer after solidification;Epoxy resin embedding adhesive is finally injected, forms insulating layer after solidification.200~ 650, butanediol diglycidyl ether 3 ~ 15, conducting particles conductive layer is formed by curing by epoxide resin conductive adhesive, formulation weight Than are as follows: epoxy resin 80 ~ 110, triethanolamine 12 ~ 20
, acetone 50 ~ 300.The curing process of the epoxy resin embedding adhesive is 6 ~ 24 hours at 50 ~ 70 DEG C.100, polyamide 170 ~ 180, conducting particles described in liquid butyronitrile 5 ~ 20 is silver powder, copper powder, aluminium powder, iron powder, nickel powder, electrically conductive graphite, carbon nanometer One of pipe is a variety of compound.The curing process of the epoxide resin conductive adhesive is 4 ~ 24 hours at 60 ~ 80 DEG C.It is described exhausted Edge layer is formed by curing for epoxy resin embedding adhesive, formulation weight ratio are as follows: 4,4- dihydroxydiphenylsulisomer epoxy resin
The method have the benefit that:
1, the contact that tab with shell bottom can be significantly improved by the fixed tab of conducting resinl, improves withstanding current capability, is suitble to big Power application battery.
2, the risk for causing tab to fall off because of high vibration can solve by the fixation of conducting resinl.
3, by insulating layer and conductive layer, the heat that battery can be made to generate in heavy-current discharge quickly sheds.
4, the patent of invention applied is that the contact of tab with shell bottom can be significantly improved by the fixed tab of conducting resinl, is improved Withstanding current capability is suitble to high-power applications batteries.It can solve by the fixation of conducting resinl because high vibration leads to tab The risk to fall off.It can solve the risk for causing tab to fall off because of high vibration by the fixation of conducting resinl.Pass through insulating layer And conductive layer, the heat that battery can be made to generate in heavy-current discharge quickly shed.By with existing patent, apply for a patent category In innovation.
Detailed description of the invention
Fig. 1: outside batteries structure chart
Fig. 2: inside battery structure chart and bottom partial enlargement structure chart;
Fig. 3: Fig. 2 partial enlarged view.
In attached drawing, 1, steel shell;2, nut cap;3, positive plate;4, diaphragm;5, negative electrode tab;6, electrolyte;7, insulating layer;8, electric Pond negative lug;9, conductive layer;10, pad.
Specific embodiment
Embodiment 1
A kind of cylindrical lithium ion battery and preparation method with internal heat dissipating and tab fixed structure, with 26650-3Ah- For 3.2V size battery, structure includes: steel shell (1), nut cap (2), positive plate (3), diaphragm (4), cathode as shown in Figure 1 and Figure 2 Piece (5), electrolyte (6), insulating layer (7), conductive layer (9).Cell cathode ear pole (8) forms pad after connecing by point back welding (10).
Tab (8) is wrapped up and is fixed by conductive layer (9), and conductive layer (9) covers a layer insulating (7) above.
Cathode point back welding is carried out after inside battery core winding into shell to connect to form pad (10).
5, acetone 70., triethanolamine 15, copper powder 400, butanediol diglycidyl ether injection epoxide resin conductive adhesive, Conductive layer (9) are formed after solidification, conductive layer (9) is formed by curing by epoxide resin conductive adhesive, is formulated (weight ratio) are as follows: epoxy resin 100
The curing process of epoxide resin conductive adhesive is 14 hours at 70 DEG C.
, liquid butyronitrile 10, acetone 100.Glue forms insulating layer (7) after solidification, and insulating layer (7) is epoxy resin embedding adhesive It is formed by curing.It is formulated (weight ratio) are as follows: 4,4- dihydroxydiphenylsulisomer epoxy resin 100, polyamide 180 inject epoxy resin and fill Envelope
The curing process of epoxy resin embedding adhesive is 6 hours at 70 DEG C.
It is compared before battery is large current discharge and is improved, tests bottom end temperature.As shown in the table, it can be seen that Under same electric current, the battery bottom end temperature after change is substantially reduced 4 ~ 7 DEG C or so.

Claims (6)

1. a kind of cylindrical lithium ion battery with internal heat dissipating and tab fixed structure, including steel shell (1), on steel shell (1) Be provided with nut cap (2), characterized in that be provided with battery roll core in steel shell (1), battery roll core include positive plate (3), diaphragm (4), Negative electrode tab (5) is successively mutually rolled up, and is additionally provided with electrolyte (6) in steel shell (1), battery roll core bottom is provided with battery cathode pole Ear (8), cell cathode ear pole (8) are wrapped up and are fixed by conductive layer (9), and conductive layer (9) covers a layer insulating above (7), cell cathode ear pole (8) forms pad (10) after connecing by point back welding.
2. a kind of preparation method of the cylindrical lithium ion battery with internal heat dissipating and tab fixed structure as described in power 1, It is characterized in that conductive layer (9) is formed by curing by epoxide resin conductive adhesive, it is formulated (weight ratio) are as follows: epoxy resin 80 ~ 110, three second Hydramine 12 ~ 20, conducting particles 200~650,3 ~ 15 acetone 20 ~ 200 of butanediol diglycidyl ether, inside battery core winding into shell Cathode point back welding is carried out afterwards to connect to form pad (10);It is then injected into epoxide resin conductive adhesive, forms conductive layer (9) after solidification; Epoxy resin embedding adhesive is finally injected, forms insulating layer (7) after solidification.
3. a kind of system of cylindrical lithium ion battery with internal heat dissipating and tab fixed structure according to claim 2 Preparation Method, characterized in that the conducting particles is silver powder, in copper powder, aluminium powder, iron powder, nickel powder, electrically conductive graphite, carbon nanotube It is one or more compound.
4. a kind of cylindrical lithium ion battery and preparation with internal heat dissipating and tab fixed structure according to claim 2 Method, which is characterized in that the curing process of affiliated epoxide resin conductive adhesive is 4 ~ 24 hours at 60 ~ 80 DEG C.
5. a kind of cylindrical lithium ion battery and preparation with internal heat dissipating and tab fixed structure according to claim 2 Method, it is characterised in that the insulating layer (7) is formed by curing for epoxy resin embedding adhesive, is formulated (weight ratio) are as follows: 4,4- dihydroxies Base diphenyl sulphone (DPS) epoxy resin 100, polyamide 170 ~ 180, liquid butyronitrile 5 ~ 20, acetone 50 ~ 300.
6. a kind of cylindrical lithium ion battery and preparation with internal heat dissipating and tab fixed structure according to claim 2 Method, which is characterized in that the curing process of affiliated epoxy resin embedding adhesive is 6 ~ 24 hours at 50 ~ 70 DEG C.
CN201811585752.3A 2018-12-25 2018-12-25 A kind of cylindrical lithium ion battery and preparation method with internal heat dissipating and tab fixed structure Pending CN109860725A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111211377A (en) * 2020-01-15 2020-05-29 天能帅福得能源股份有限公司 System and method for monitoring temperature of cylindrical lithium ion battery
CN111354915A (en) * 2020-04-24 2020-06-30 福建南平延平区南孚新能源科技有限公司 Button battery pole shell and electrode lug traceless welding method, welding structure and product
CN113937428A (en) * 2021-09-30 2022-01-14 广东微电新能源有限公司 Battery, battery preparation method, battery detection method and electronic equipment

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CN203617380U (en) * 2013-12-18 2014-05-28 山东精工电子科技有限公司 Cylindrical shock-resistant lithium ion battery
CN104577192A (en) * 2015-01-05 2015-04-29 国家电网公司 High-rate lithium ion power battery and manufacturing method thereof
CN107732287A (en) * 2017-06-20 2018-02-23 东莞市创明电池技术有限公司 Column lithium ion battery

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CN203617380U (en) * 2013-12-18 2014-05-28 山东精工电子科技有限公司 Cylindrical shock-resistant lithium ion battery
CN104577192A (en) * 2015-01-05 2015-04-29 国家电网公司 High-rate lithium ion power battery and manufacturing method thereof
CN107732287A (en) * 2017-06-20 2018-02-23 东莞市创明电池技术有限公司 Column lithium ion battery

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111211377A (en) * 2020-01-15 2020-05-29 天能帅福得能源股份有限公司 System and method for monitoring temperature of cylindrical lithium ion battery
CN111211377B (en) * 2020-01-15 2021-06-01 天能帅福得能源股份有限公司 System and method for monitoring temperature of cylindrical lithium ion battery
CN111354915A (en) * 2020-04-24 2020-06-30 福建南平延平区南孚新能源科技有限公司 Button battery pole shell and electrode lug traceless welding method, welding structure and product
CN111354915B (en) * 2020-04-24 2023-06-23 福建南平延平区南孚新能源科技有限公司 Button cell electrode shell and electrode lug traceless welding method, welding structure and product
CN113937428A (en) * 2021-09-30 2022-01-14 广东微电新能源有限公司 Battery, battery preparation method, battery detection method and electronic equipment

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Application publication date: 20190607

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