CN109856302B - Gas detection device for benzene series and operation method thereof - Google Patents

Abstract

The invention provides a gas detection device for benzene series, which comprises a box body, wherein the box body is provided with a gas sample introduction unit, and a gas separation unit, a detection unit, a data acquisition and processing unit, a control unit and a carrier gas unit are arranged in the box body; the gas separation unit is arranged in a separate separation tank. The gas separation unit includes a ten-way valve disposed inside the separation tank. In addition, the invention also provides an operation method of the gas detection device for the benzene series. The gas detection device adopts the chromatographic columns with specific combination, is matched with the ten-way valve with special structure and connection relation, is particularly suitable for detecting benzene series in the atmosphere, can continuously detect and clean the benzene series without shutdown, can repeatedly detect the benzene series in a short time, avoids system errors caused by external state changes, and has more reliable detection result and higher precision.

Description

Gas detection device for benzene series and operation method thereof

Technical Field

The application claims priority of a chinese prior patent application No. 2018100419954, applied on 17/1/2018.

The invention relates to a gas detection and analysis technology in the field of environmental protection, in particular to a detection device for detecting gas components, and particularly relates to a gas detection device for benzene series and an operation method thereof.

Background

The environmental protection field often needs to detect and analyze various gases, and a gas chromatograph is generally used. The gas chromatograph is a device for analyzing and detecting a mixed sample, and generally comprises a gas path system, a sample introduction system, a separation system, a circuit control system, a detection system, a data acquisition and processing system and the like. However, the existing gas chromatograph is generally installed in a laboratory, the whole volume is very large, complicated airflow pipelines and various power supply and control cables and the like need to be connected among systems, the connection reliability of the whole device is very unstable, the calibration needs to be checked again when the system is changed slightly, and the possibility of carrying conveniently does not exist basically.

CN 106841483 a discloses a chromatographic sample feeding separation device, which is combined by an eight-way valve and a ten-way valve to improve the analysis efficiency. However, the two sets of valves are only half the time to utilize half of the gas paths, and the two sets of gas paths are not related to each other. As a result, systematic errors are easily caused by the difference between the two sets of air passages, for example, the volume difference of the two quantitative pipes inevitably exists, so that the inevitable systematic errors exist. And more gas circuit pipelines need a large amount of connecting pipelines, the more pipelines, the larger the error brought by the volume of the gas circuit, and the larger the adsorption influence of pipeline materials on components in the gas. In addition, the more pipes, the more easily the joints are subjected to connection failure, the time for calibrating and troubleshooting is greatly increased, and the reliability of the system is deteriorated. The use of the two sets of valves brings the problem of synchronism, the control conversion of the system is complex, the volume occupied by the two sets of valves is larger, and the two sets of valves are difficult to be used for portable emergency sampling analysis.

CN 104374860 a discloses a portable gas analyzer, which adopts a single ten-way valve in cooperation with two chromatographic columns to perform post-separation analysis on gas. However, the introduction of the whole frame of the portable gas analyzer in the prior art is very crude, and only the description includes a box body, an automatic sampling and sampling mechanism, a sample gas separation mechanism and a chromatographic detection mechanism are arranged in the box body, the automatic sampling and sampling mechanism includes a ten-way valve and a sampling ring, the mixed gas separation mechanism mainly includes a coarse chromatographic column, a fine chromatographic column, an auxiliary pipeline and heat insulation cotton, and the mixed gas detection mechanism mainly includes a fuel cell and an auxiliary pipeline. No description is given as to the delivery of gas, calibration of the apparatus, control of the apparatus, etc., and the person skilled in the art cannot imagine the overall structure of the portable gas analyzer of the prior art. In addition, this prior art adopts two chromatographic columns mode of ally oneself with to carry out the separation of gas, gets rid of the influence of impurity through the mode of establishing ties, and two chromatographic columns keep the continuity to establish ties during the use, and a state sampling adds the washing pipeline, and a state advances a kind analysis. However, the dual chromatographic columns of the prior art are continuously used in series, and only the species of the target section can be selectively highlighted according to two columns, so that the rest sections are omitted, but the prior art cannot remove interfering substances, cannot pull and amplify the peak patterns of different components in trace gas, the peak patterns of the species of the target section are not sufficiently subdivided, and the accuracy of the analysis result is still to be improved.

Disclosure of Invention

The present invention provides a gas detecting device for benzene series and an operation method thereof, so as to reduce or avoid the aforementioned problems.

Specifically, the invention provides a gas detection device for benzene series, which can effectively reduce system errors, improve system reliability and detection precision, and is more practical and portable.

In order to solve the technical problem, the invention provides a gas detection device for benzene series, which comprises a box body, wherein the box body is provided with a gas sampling unit, and a gas separation unit, a detection unit, a data acquisition and processing unit, a control unit and a carrier gas unit are arranged in the box body; the gas separation unit is arranged in an independent separation box, and the separation box is provided with three gas inlet pipes and three gas outlet pipes communicated with the interior of the separation box; the three gas inlet pipes are respectively a first gas inlet pipe and a second gas inlet pipe which are communicated with the carrier gas unit, and a third gas inlet pipe which is communicated with the gas sampling unit; the three exhaust pipes are respectively a first exhaust pipe and a second exhaust pipe for emptying and a third exhaust pipe communicated with the detection unit, and a sampling pump is arranged in the second exhaust pipe; the gas separation unit includes a ten-way valve provided inside the separation tank, the ten-way valve having first to tenth connection ports numbered in order of adjoining positions; the first connecting port is communicated with the eighth connecting port through a pipeline provided with a first chromatographic column; the second connecting port is communicated with the third exhaust pipe, and the third exhaust pipe is provided with a second chromatographic column positioned between the second connecting port and the detection unit; the third connecting port is communicated with the second air inlet pipe; the fourth connecting port is communicated with the seventh connecting port through a pipeline provided with a quantitative pipe; the fifth connecting port is communicated with the second exhaust pipe; the sixth connecting port is communicated with the third air inlet pipe; the ninth connecting port is communicated with the first exhaust pipe; the tenth connecting port is communicated with the first air inlet pipe; the first chromatographic column adopts a chromatographic column with model number of 125-1334DB-624 of Agilent company in America; the second column was a 19095N-126I HP-INNOWAX, Agilent, USA column.

Preferably, the data acquisition and processing unit is connected with the detection unit through a circuit, and the data acquisition and processing unit is provided with a display screen for displaying the detection result and at least one data output interface.

Preferably, the carrier gas unit comprises a carrier gas steel cylinder which is arranged in the box body, and the carrier gas steel cylinder provides the first path of carrier gas and the second path of carrier gas through the first gas inlet pipe and the second gas inlet pipe respectively.

Preferably, the ten-way valve has a first state in which the first connection port communicates with the tenth connection port, the second connection port communicates with the third connection port, the fourth connection port communicates with the fifth connection port, the sixth connection port communicates with the seventh connection port, and the eighth connection port communicates with the ninth connection port.

Preferably, the ten-way valve has a second state in which the first connection port communicates with the second connection port, the third connection port communicates with the fourth connection port, the fifth connection port communicates with the sixth connection port, the seventh connection port communicates with the eighth connection port, and the ninth connection port communicates with the tenth connection port.

The invention also provides an operation method of the gas detection device for the benzene series, which comprises the following steps:

the ten-way valve is adjusted to a first state through the control unit, and in the first state, the first connecting port is communicated with the tenth connecting port, the second connecting port is communicated with the third connecting port, the fourth connecting port is communicated with the fifth connecting port, the sixth connecting port is communicated with the seventh connecting port, and the eighth connecting port is communicated with the ninth connecting port;

starting the sampling pump, collecting sample gas through the gas sampling unit, enabling the sample gas to be continuously introduced into the third gas inlet pipe, then entering the sixth connecting port and entering the quantitative pipe from the seventh connecting port, and exhausting gas flowing out of the quantitative pipe after entering the fourth connecting port and the fifth connecting port through the second gas exhaust pipe;

meanwhile, the control unit enables the first path of carrier gas provided by the carrier gas unit to be continuously introduced into the tenth connecting port and the first connecting port through the first gas inlet pipe, then the first path of carrier gas flows through the first chromatographic column, and the gas flowing out of the first chromatographic column enters the eighth connecting port and the ninth connecting port and is exhausted through the first exhaust pipe;

meanwhile, the control unit enables a second path of carrier gas provided by the carrier gas unit to be introduced into the third connecting port and the second connecting port through the second gas inlet pipe, then the second path of carrier gas flows through the second chromatographic column through the third gas outlet pipe, and then the gas flowing out of the second chromatographic column enters the detection unit and is exhausted.

Preferably, the operating method further comprises the steps of:

adjusting the ten-way valve from a first state to a second state through the control unit, wherein in the second state, the first connecting port is communicated with the second connecting port, the third connecting port is communicated with the fourth connecting port, the fifth connecting port is communicated with the sixth connecting port, the seventh connecting port is communicated with the eighth connecting port, and the ninth connecting port is communicated with the tenth connecting port;

at the moment, the collected sample gas is continuously introduced into the third gas inlet pipe through the sampling pump and the gas sample introduction unit, then enters the sixth connecting port and the fifth connecting port and is exhausted from the second exhaust pipe;

meanwhile, the control unit enables the first path of carrier gas provided by the carrier gas unit to be continuously introduced into the tenth connecting port and the ninth connecting port through the first air inlet pipe and then exhausted through the first exhaust pipe;

meanwhile, a second path of carrier gas provided by the carrier gas unit is led into the third connector and the fourth connector through the second gas inlet pipe through the control unit, then the second path of carrier gas enters the quantitative tube through back flushing to push the sample gas stored in the quantitative tube in the first state out of the quantitative tube, then the sample gas flows into the seventh connector and the eighth connector, the second path of carrier gas enters the first chromatographic column through back flushing, different gas components are analyzed and discharged at different speeds under the action of the first chromatographic column, the gas to be detected analyzed firstly is led into the first connector and the second connector, then flows into the second chromatographic column through the third exhaust pipe, and the gas to be detected enters the detection unit for detection after being separated by the second chromatographic column.

Preferably, the operating method further comprises the steps of:

after the first chromatographic column analyzes and separates the sample gas for a preset time, the ten-way valve is adjusted from the second state to the first state through the control unit;

continuously introducing the collected sample gas into the third gas inlet pipe through the sampling pump and the gas sample introduction unit, then entering the sixth connecting port and entering the quantitative pipe from the seventh connecting port, and evacuating the gas flowing out of the quantitative pipe through the second gas exhaust pipe after entering the fourth connecting port and the fifth connecting port; thereby discharging all the gas in the second state for storing the sample gas for the next analysis in the quantitative tube;

meanwhile, the control unit enables the first path of carrier gas provided by the carrier gas unit to be continuously introduced into the tenth connecting port and the first connecting port through the first gas inlet pipe, then the carrier gas enters the first chromatographic column in a back blowing mode, all original gas in the first chromatographic column is pushed out in a reverse direction, and then the carrier gas enters the eighth connecting port and the ninth connecting port and is exhausted through the first exhaust pipe;

meanwhile, a second path of carrier gas provided by the carrier gas unit is continuously introduced into the third connector and the second connector through the second gas inlet pipe by the control unit, then flows into the third exhaust pipe, continuously pushes the residual gas to be detected in the third exhaust pipe to the second chromatographic column, continuously analyzes and discharges components in the gas to be detected at different speeds by the second chromatographic column, and then the gas flowing out of the second chromatographic column enters the detection unit for detection and then is exhausted; thereby completing a cycle of gas analysis in said first state; and the analysis result obtained by the detection unit is further transmitted to the data acquisition and processing unit through a circuit.

The gas detection device for the benzene series provides an integral structure which is internally and integrally arranged in the box body, all the structures are stably connected into a whole in the box body, the structure is compact, the carrying and the transportation are convenient, and the gas detection device is suitable for the emergency gas analysis and detection in various field environments. And the gas separation unit with an independent structure can conveniently form a highly integrated gas analyzer which can be conveniently exchanged, and the number of connecting pipelines and the number of control valves are reduced, so that the system error can be effectively reduced, and the reliability and the detection precision of the system are improved. In addition, the gas separation unit of the invention intercepts and back blows the later resolved miscellaneous peak gas through the first chromatographic column, which is beneficial to improving the detection precision of the gas to be detected, and then the second chromatographic column pulls the peak distance of each component apart, thereby improving the detection degree of different components, especially trace components, and improving the detection precision.

In addition, the chromatographic column with a specific combination is adopted by the gas detection device, and the ten-way valve with a special structure and a special connection relation is matched, so that the gas detection device is particularly suitable for detecting benzene series in the atmosphere, can continuously detect and clean the benzene series without stopping the machine, can repeatedly detect in a short time, avoids system errors caused by external state changes, and is more reliable in detection result and higher in precision.

Drawings

The drawings are only for purposes of illustrating and explaining the present invention and are not to be construed as limiting the scope of the present invention. Wherein,

FIG. 1 is a schematic diagram showing a gas detecting apparatus for benzene series according to an embodiment of the present invention;

FIG. 2 is a schematic view showing a connection structure of a gas sensor for benzene series according to another embodiment of the present invention;

FIG. 3 shows a schematic diagram of a first state of a gas separation unit of a gas detection apparatus for benzenes in accordance with yet another embodiment of the present invention;

FIG. 4 is a schematic diagram of a second state of the gas separation unit of FIG. 3;

FIG. 5 is a graph showing an exemplary test result of the gas detecting apparatus of the present invention;

FIGS. 6a to 6e are standard graphs showing different benzene series, respectively.

Detailed Description

In order to more clearly understand the technical features, objects, and effects of the present invention, embodiments of the present invention will now be described with reference to the accompanying drawings. Wherein like parts are given like reference numerals.

As described in the background section, the conventional gas analyzing apparatus, such as a gas chromatograph, has a complicated structure and many connecting pipes, power supply cables, control cables, etc., which results in poor stability and inconvenience in carrying. Therefore, the invention provides a gas detection device for benzene series, which integrates necessary structures as much as possible by simplifying the structure, reduces the number of connecting pipelines and the number of control valves by reducing the number of components of a separation system as much as possible, thereby effectively reducing the system error, improving the reliability and the detection precision of a gas analyzer and obtaining a more practical gas detection device for the benzene series.

Specifically, referring to fig. 1, which is a schematic structural diagram illustrating a gas detection apparatus for benzene series according to an embodiment of the present invention, the gas detection apparatus for benzene series according to the present invention includes a box 100, the box 100 is provided with a gas injection unit 11, and the box 100 is internally provided with a gas separation unit 12, a detection unit 13, a data acquisition and processing unit 14, a control unit 15, a carrier gas unit 16 and a calibration unit 17; in addition, the gas detection device for benzene series according to the present invention may further include a sampling pump 18 controlled by the control unit 15 in the tank 100, as required by the pressure condition of the sampling gas source. The outer side of the box 100 may also be provided with a terminal for an external power line, or the terminal of the external power source may be replaced with a USB power supply connector (not shown in the figure) for connecting to a vehicle-mounted power source, which is also an alternative feasible solution. Of course, in a particularly compact and portable configuration, a battery may also be built into the case 100 for emergency testing.

In addition, in the specific structure of the present invention, as shown in fig. 2, which is a schematic view showing a connection structure of a gas detection apparatus for benzene series according to another specific embodiment of the present invention, referring to fig. 1-2, various structures such as cables, electromagnetic valves, etc. connected to the data acquisition and processing unit 14 and the control unit 15, and correspondingly, structures such as gas pipelines, etc. connected to the gas sampling unit 11, the gas separation unit 12, the detection unit 13, the carrier gas unit 16 and the calibration unit 17 are further provided in the box 100.

The gas detection apparatus for benzene-based compounds according to the present invention further includes a gas separation unit 12 having an independent structure, which is provided in a single independent separation tank 120, and the separation tank 120 is provided with three gas inlet pipes 121, 122, 123 and three gas outlet pipes 124, 125, 126 communicating with the inside thereof. That is, the gas separation unit 12 disposed in the box 100 is designed as an independent structure, there are only six pipes connecting the inside and the outside of the separation box 120, namely, three inlet pipes 121, 122, 123 and three outlet pipes 124, 125, 126, and the inside of the separation box 120 is integrated with a gas phase separation column suitable for separating a specific kind of gas, for example, for the separation detection of aromatic hydrocarbon compounds, such as

A combination of a metal capillary column and a CP-Sil 43 CB type gas phase separation column; or for separate detection of halogenated compounds, for example

Metal capillary column and gas phase separation column of type ae.ov-1301. Of course, the same principle of separation and detection of gas components can be realized by replacing different groups of chromatographic columns according to the type and the quantity of the detected target species. Wherein

The series of metal capillary columns, CP-Sil 43 CB and AE.OV-1301 are commercially availableThe gas analysis performance of the gas phase separation column of the common type can be obtained by inquiring various product manuals. In addition, a constant temperature control mechanism can be further arranged in the separation box 120 to avoid the interference of the room temperature fluctuation with the analysis result.

The gas separation unit 12 with an independent structure can form a highly integrated and conveniently interchangeable gas analyzer, that is, for the detection of the separation of gases of different types, the gas separation boxes 120 of various specifications can be prefabricated, when a certain type of gas needs to be analyzed, the gas separation boxes 120 of corresponding types can be installed in the box body 100, and the gas analyzer of one type can be correspondingly formed only by six pipelines which are communicated with the internal pipeline of the box body 100 and are communicated with the gas separation boxes 120. In fact, in the embodiment shown in fig. 2, the six pipes of the gas separation box 120, in fact, with the two evacuation pipes 124 and 126 for emptying, are directly discharged outside the box 100, i.e. the two pipes 124 and 126 are integrated in the gas separation box 120, and when being installed in the box 100, there is no need for any joints at all, so that only four pipe joints are needed for replacing one gas separation box 120.

Correspondingly, at a suitable position of the box 100, an air inlet pipe of the gas sample injection unit 11 and a channel for exhausting air from the three air outlet pipes 124, 125, 126 may be provided. In addition, according to the specific situation of the sampled gas, in order to facilitate gas analysis, a filter joint 111 for preliminary dehumidification and dust removal may be disposed on the gas inlet pipe of the gas sampling unit 11; of course, in an environment where the gas source is dry and dust-free, the gas may be directly filtered by the dust removing structure built in the gas sampling unit 11 without the filter joint 111.

That is, as can be seen from fig. 1-2, the gas detection device for benzene series substances of the present invention can provide an integral structure which is all built in and integrated in the box body, and the structures are stably connected into a whole in the box body, so that the structure is compact, and the device is convenient to carry and transport, and is suitable for the emergency gas analysis and detection in various field environments. And the gas separation unit with an independent structure can conveniently form a highly integrated gas analyzer which can be conveniently exchanged, and the number of connecting pipelines and the number of control valves are reduced, so that the system error can be effectively reduced, and the reliability and the detection precision of the system are improved.

Further, the data collecting and processing unit 14 shown in fig. 1-2 is electrically connected to the detecting unit 13, and the data collecting and processing unit 14 has a display screen 141 for displaying the detection result and at least one data output interface 142. Three USB-type data output interfaces 142 are shown in detail in fig. 1, wherein one data output interface 142 may also be provided in the form of a card reader adapted to mount a memory card. The display 141 may be a liquid crystal display (lcd) embedded in one side of the casing 100, or may be only a video output interface, and may be connected to an external display by means of a video cable. Or, in another embodiment, according to the state of the art, the display screen 141 and the data output interface 142 may be combined into a unified and independent interface, such as a USB Type-C interface, through which an external notebook computer may be connected to receive the detection data and/or the video signal, which has better scalability.

In addition, as shown in fig. 2, the three gas inlet pipes 121, 122, 123 are a first gas inlet pipe 121 and a second gas inlet pipe 122 respectively communicated with the carrier gas unit 16, and a third gas inlet pipe 123 communicated with the gas sampling unit 11 and the calibration unit 17.

In addition, the three exhaust pipes 124, 125, 126 are a first exhaust pipe 124 and a second exhaust pipe 125 for evacuation, respectively, and a third exhaust pipe 126 communicating with the detection unit 13.

Further, the carrier gas unit 16 may include a carrier gas cylinder 161 disposed in the box 100, and the carrier gas cylinder 161 provides the first carrier gas and the second carrier gas through the first inlet pipe 121 and the second inlet pipe 122, respectively. That is, in the present embodiment, the carrier gas cylinder 161 is built in, so that the trouble of connecting gas cylinders on site can be reduced, the system error is reduced, the redundant calibration process after temporary connection is avoided, and the method is particularly suitable for gas analysis and detection in emergency situations, such as toxic gas leakage situations. In addition, two paths of carrier gas are provided by a single carrier gas steel cylinder 161, so that system errors such as flow and components of different gas sources are avoided, and the detection precision is improved. Of course, in view of portability, the amount of carrier gas in the built-in carrier gas cylinder 161 is limited, and the housing 100 may be provided with an interface connected in parallel with the carrier gas cylinder 161 for externally connecting another high-ballast gas cylinder during a long-time field test. Since the flow rate and the type selection of the carrier gas have a great influence on the result, the external carrier gas source needs to be replaced and calibration needs to be performed again, and the calibration process will be further described below.

Further, the calibration unit 17 includes a calibration steel cylinder 171 and a dynamic calibration instrument 172 built in the housing 100, and the third gas inlet pipe 123 communicates the calibration steel cylinder 171 and the dynamic calibration instrument 172 through a three-way valve. Similarly, the calibration steel cylinder 171 is arranged in the gas cylinder calibration device, so that the trouble of connecting the gas cylinder on site can be reduced, and the system error is reduced. With the calibration cylinder 171, a quick calibration can be performed, that is, by collecting a standard mixed gas with a known concentration in the calibration cylinder 171 into the quantitative tube 203, performing a normal separation detection procedure to obtain the component peaks of each component, and comparing the quantitative data such as the peak height and the peak area with a standard curve of a laboratory to determine whether the system state meets formal measurement.

In addition, the dynamic calibration instrument 172 in the calibration unit 17 may perform a multi-point dynamic calibration process. That is, the dynamic calibration instrument 172 is a multi-point calibration instrument, and after the dynamic calibration instrument 172 is used to prepare mixed gas with different known concentrations and detect the mixed gas to obtain an analysis result, a plurality of points are obtained by plotting the concentrations of the different gases and quantitative values (peak heights or peak areas), and a standard curve can be obtained from the points. Typically, when taken out of the field for testing, the dynamic calibration apparatus 172 may not be connected to the housing, but the calibration cylinder 171 may remain continuously connected, i.e., built into the housing. If the detection time is too long, a high-pressure gas cylinder with large capacity of standard gas can be externally connected. The calibration cylinder 171 is only of fixed concentration, i.e. only corresponds to a point on the standard curve obtained by the dynamic calibration instrument 172, and the operating state of the instrument can be known from the deviation of the point from the curve, so that the calibration is called fast calibration or also called fast verification. This fast calibration system can be performed at the beginning or near the end of a field test, or it can be programmed to perform 1-2 fast calibrations periodically by the control system 15 each day.

In one embodiment, a sampling pump 18 may be disposed in the second exhaust pipe 125 for providing a certain flow pressure, which facilitates gas sampling under normal pressure conditions, and improves the efficiency controllability of sampling analysis. In this embodiment, sampling pump 18 has set up the terminal position at the gas circuit, and the gas circuit that sampling pump 18 itself probably brought connects and the material adsorbs scheduling problem, for setting up in the front end of gas circuit, its influence greatly reduced to detecting the precision, therefore this embodiment is preferred to be rearmounted sampling pump 18, is about to sampling pump 18 sets up in second blast pipe 125, can reduce the interference that sampling pump 18 itself brought, is favorable to detecting the improvement of precision.

The specific structure of the separation unit of the gas sensor for benzene series according to the present invention will be further described with reference to fig. 3 to 4, in which fig. 3 is a schematic view showing a first state of the gas separation unit of the gas sensor for benzene series according to still another embodiment of the present invention; fig. 4 shows a schematic view of a second state of the gas separation unit of fig. 3.

It is shown that the separation unit of the gas detecting apparatus for benzene series according to the present invention comprises a ten-way valve 20 disposed inside a separation tank 120, the ten-way valve 20 having first to tenth connection ports numbered in order of adjacent positions. Since the ten-way valve 20 has many connecting ports, the connecting ports are labeled with specific reference numerals one by one, and for better understanding, in fig. 3 and 4 of the present invention, each connecting port is numbered with arabic numerals in sequence according to adjacent positions, and each arabic numeral corresponds to a connecting port with the same number in chinese serial number, for example, the connecting port corresponding to arabic numeral 1 is shown in the following description as the first connecting port, the connecting port corresponding to arabic numeral 2 is shown in the following description as the second connecting port, and so on.

The ten-way valve 20 of the separation unit 12 of the gas detection device for benzene series according to the present invention is shown in the figure, and the first connection port and the eighth connection port are communicated through a pipe provided with a first chromatographic column 201; the second connection port communicates with a third exhaust pipe 126, and the third exhaust pipe 126 is provided with a second chromatography column 202 located between the second connection port and the detection unit 13; the third connection port communicates with the second intake pipe 122; the fourth connecting port is communicated with the seventh connecting port through a pipeline provided with a quantitative pipe 203; the fifth connection port is communicated with the second exhaust pipe 125; the sixth connection port is communicated with the third air inlet pipe 123; the ninth connection port communicates with the first exhaust pipe 124; the tenth connection port communicates with the first intake pipe 121.

The operation method of the gas sensor for benzene series according to the present invention will be described in detail with reference to FIGS. 1 to 4, and the function and effect of the connection structure of the separation unit 12 according to the present invention can be more clearly understood by operating the process of gas analysis.

As shown in fig. 1 to 4, the operation method of the gas detection apparatus for benzene series according to the present invention includes the steps of:

referring first to fig. 1 and 3, the ten-way valve 20 is adjusted by the control unit 15 to a first state, that is, the ten-way valve 20 has a first state in which the first connection port is communicated with the tenth connection port, the second connection port is communicated with the third connection port, the fourth connection port is communicated with the fifth connection port, the sixth connection port is communicated with the seventh connection port, and the eighth connection port is communicated with the ninth connection port.

Then, the sampling pump 18 is started, the sample gas is collected by the gas sampling unit 11, the sample gas is continuously introduced into the third gas inlet pipe 123, then enters the sixth connecting port and enters the quantitative tube 203 from the seventh connecting port, and the gas flowing out of the quantitative tube 203 enters the fourth connecting port and the fifth connecting port and then is exhausted through the second gas outlet pipe 125. By the continuous flow of the sample gas, a desired predetermined amount of the sample gas is stored in the quantitative tube 203, facilitating the next analytical detection.

Meanwhile, the control unit 15 makes the first path of carrier gas provided by the carrier gas unit 16 continuously pass through the first gas inlet pipe 121 and enter the tenth connection port and the first connection port, then flow through the first chromatographic column 201, and the gas flowing out of the first chromatographic column 201 enters the eighth connection port and the ninth connection port, and then is exhausted through the first exhaust pipe 124.

Meanwhile, the control unit 15 makes the second path of carrier gas provided by the carrier gas unit 16 pass through the second gas inlet pipe 122, enter the third connection port and the second connection port, flow through the second chromatographic column 202 through the third gas outlet pipe 126, and then the gas flowing out of the second chromatographic column 202 enters the detection unit 13 and is exhausted.

The first chromatographic column 201 and the corresponding connectors and pipelines are cleaned in sequence by using the first path of carrier gas, and the second path of carrier gas is used for emptying the second chromatographic column 202 and the detection unit 13 after being cleaned in sequence, so that the system can be cleaned by using the same gas source, the gas source is stable, the efficiency is higher, and more accurate detection results can be obtained subsequently. And after the cleaning is stable, the system reaches a preset state which can be analyzed and detected in the next step.

Then, when the system reaches a predetermined stable state, the control unit 15 may adjust the ten-way valve 20 from the first state shown in fig. 3 to the second state shown in fig. 4, that is, the ten-way valve 20 has a second state in which the first connection port communicates with the second connection port, the third connection port communicates with the fourth connection port, the fifth connection port communicates with the sixth connection port, the seventh connection port communicates with the eighth connection port, and the ninth connection port communicates with the tenth connection port in the second state shown in fig. 4.

At this time, the sampled sample gas is continuously introduced into the third gas inlet pipe 123 through the sampling pump 18 and the gas sampling unit 11, and then enters the sixth connection port and the fifth connection port and is evacuated from the second gas exhaust pipe 125. This process is arranged in keeping the gaseous flow of sample in the pipeline, and the air current interruption can not appear in the sampling of the next circulation of being convenient for to this continuity of guaranteeing continuous on-line analysis avoids appearing data jump and influences the detection precision, guarantees simultaneously that the malleation gas that lasts flows and can avoid the outside air to get into the gas circuit and cause the pollution, guarantees that the gas circuit is stable clean, thereby has further guaranteed the accuracy nature of analysis result.

Meanwhile, the control unit 15 makes the first path of carrier gas provided by the carrier gas unit 16 continuously pass through the first gas inlet pipe 121 to the tenth connection port and the ninth connection port, and then is exhausted through the first exhaust pipe 124. Therefore, the pipeline is continuously cleaned by the carrier gas, pollution is avoided, and next gas analysis is prepared.

Meanwhile, the control unit 15 makes the second path of carrier gas provided by the carrier gas unit 16 pass through the second gas inlet tube 122 and enter the third connector and the fourth connector, then the carrier gas enters the quantitative tube 203 by back flushing to push the sample gas stored in the quantitative tube 203 in the first state out of the quantitative tube 203, then the sample gas flows into the seventh connector and the eighth connector, and similarly the sample gas enters the first chromatographic column 201 by back flushing, under the action of the first chromatographic column 201, different gas components are analyzed and discharged at different speeds, the analyzed gas firstly passes through the first connector and the second connector, then flows into the second chromatographic column 202 through the third gas outlet tube 126, and enters the detection unit 13 for detection after being separated by the second chromatographic column 202.

The second state shown in fig. 4 appears superficially similar to the separation detection with the first column 201 and the second column 202 connected in series, and then the operation steps of the present invention are not simple series separation, but need to be switched to the first state immediately after the first column 201 has resolved the sample gas for a predetermined time.

That is, the time for the first resolved gas to completely empty through the first chromatography column 201 into the third exhaust pipe 126 may be calculated or obtained experimentally according to the characteristics of the first chromatography column 201, and when the time for the first resolved gas to empty is reached, the control unit 15 automatically starts the state transition, that is, the ten-way valve 20 is adjusted from the second state to the first state by the control unit 15.

At this time, the gas resolved first enters the third exhaust pipe 126 completely, and a part of the gas resolved first may reach the second chromatographic column 202 and even the detection unit 13 (this may be flexibly set by the volume of the third exhaust pipe 126 between the second connection port and the second chromatographic column 202, and depends on the width range of the target species zone). After that, the control unit 15 immediately switches from the second state to the first state, and the gas desorbed from the rear section of the first chromatographic column 201 is suddenly cut off and does not enter the third exhaust pipe 126 again. That is, in this step of the present invention, the gas component in the sample gas that is first resolved from the first chromatographic column 201 is required as the gas to be measured, and the gas component that is resolved from the first chromatographic column 201 is useless impurity gas, so that the impurity peak generated after the gas enters the detection unit 13 is prevented from degrading the curve accuracy of the gas to be measured.

After the state is switched to the first state, as shown in fig. 3, the collected sample gas is continuously introduced into the third gas inlet pipe 123 through the sampling pump 18 and the gas sampling unit 11, then enters the sixth connection port and enters the quantitative tube 203 from the seventh connection port, and the gas flowing out of the quantitative tube 203 enters the fourth connection port and the fifth connection port and is then evacuated through the second gas outlet pipe 125; thereby discharging the gas in the second state entirely for storing the sample gas for the next analysis in the quantitative tube 203.

Meanwhile, the control unit 15 makes the first path of carrier gas provided by the carrier gas unit 16 continuously enter the tenth connection port and the first connection port through the first gas inlet pipe 121, and then enters the first chromatographic column 201 through back flushing. The first column 201 originally retains the rear stage analysis gas which has not yet flowed out, and the waste gas is trapped when the second state is switched to the first state because of its slow passing speed. At this time, through the back-blowing action of the first path of carrier gas, the part of gas originally remaining in the first chromatographic column 201 can be easily pushed out of the first chromatographic column 201 by the first path of carrier gas through the back-blowing manner. With the continuous entering of the first path of carrier gas, all the original gas in the first chromatographic column 201 can be pushed out reversely, and then enters the eighth connecting port and the ninth connecting port, and is exhausted through the first exhaust pipe 124. That is, in this step, through switching to the first state, can blow the waste gas in first chromatographic column 201 in the reverse direction through the carrier gas of the first way clean, because the speed that the waste gas passes through first chromatographic column 201 is just very slow originally, if forward sweep efficiency can be very low, and through reverse sweep, can clean first chromatographic column 201 and relevant pipeline interface etc. faster, clean efficiency is higher, the time that needs is shorter, sweep the abluent effect also than forward sweep the effect far better, also avoided in the forward sweep analysis time overlength species that are difficult to sweep out get into the detecting element 13 of next analysis, thereby more reduced impurity interference, improved the accuracy nature of analysis result.

At the same time, the second path of carrier gas provided by the carrier gas unit 16 is continuously introduced into the third connection port and the second connection port through the second gas inlet pipe 121 by the control unit 15, and then flows into the third gas outlet pipe 126. The remaining gas to be detected, which is just the just intercepted previous stage and is analyzed first, in the third exhaust pipe 126 is switched to the first state, then the remaining gas to be detected is just pushed to the second chromatographic column 202 by the relay flow of the second path of carrier gas flowing into the third exhaust pipe 126, then the components in the gas to be detected are continuously analyzed and discharged at different speeds by the second chromatographic column 202 normally, and then the gas flowing out of the second chromatographic column 202 enters the detection unit 13 for detection and is exhausted; thus completing a cycle of gas analysis in the first state; the analysis result obtained by the detection unit 13 is further transmitted to the data acquisition and processing unit 14 through a circuit.

In this step, since the impurity gas with a longer resolving time is intercepted by the first chromatographic column 201 before and does not enter the third exhaust pipe 126, the gas component which is really required to be analyzed and detected is pushed to the second chromatographic column 202 through the second path of carrier gas, the gas to be detected with different components is resolved and discharged at different speeds by the second chromatographic column 202, the intervals of the curve wave crests of different gas components are opened, the mutual masking interference of adjacent wave crests is avoided, the detection degree of different components, especially trace components, is improved, and the detection precision is improved.

In the invention, the sample gas is not directly subjected to series analysis and detection through the first chromatographic column 201 and the second chromatographic column 202, but the first chromatographic column 201 is subjected to an interception operation before detection, the first chromatographic column 201 is utilized to pre-separate the sample gas, the gas to be detected analyzed firstly is guided to the second chromatographic column, the rear section of waste gas is intercepted in the first chromatographic column 201 through state switching, and then the waste gas is subjected to back flushing to prepare for next detection. The control unit 15 can set an appropriate time for the state transition according to the characteristics of the first chromatographic column 201, and can intercept the rear-stage exhaust gas other than the gas to be detected to be analyzed, and analyze only the front-stage gas to be detected.

Example 1

The characteristics and technical effects of the present invention will be further described below by taking the detection of benzene series in the atmosphere as an example.

The benzene series can be widely detected in human living and living environments due to pollution in production and life. And has strong harm to blood, nerve and reproductive system of human body. The concentration of benzene series in the atmosphere is taken as one of the contents of the conventional monitoring of the atmospheric environment, and strict indoor and outdoor air quality standards are stipulated. The Benzene series in general terms mainly includes Benzene, Toluene, Ethylbenzene, Xylene, trimethylbenzene, styrene, phenol, aniline, chlorobenzene, nitrobenzene, and the like, wherein Benzene (Benzene), Toluene (Toluene), Ethylbenzene (Ethylbenzene), and Xylene (Xylene) are representative substances, and BTEX is also called Benzene series for short. Benzene series have serious negative effects on the area, especially the urban atmospheric environment. Since most benzene series (such as benzene and toluene) have strong volatility, they are easily volatilized into gas at room temperature to form Volatile Organic gases (VOCs), which can cause VOCs gas pollution. For example, BTEX is widely used in the industries of paint, degreasing, dry cleaning, printing, textile, synthetic rubber, etc., as an organic solvent frequently used in the industry. The air pollution is caused by volatilization in the processes of production, storage and transportation and use of BTEX. BTEX has higher photochemical reaction activity in the atmosphere and has a considerable effect on the formation of photo-oxidants (such as ozone, peroxyacetyl nitrate and the like) and secondary organic aerosol in the atmosphere.

Therefore, the following will further describe the detection of benzene compounds in the atmosphere as an example.

The experimental conditions are as follows:

the first chromatographic column 201 adopts a chromatographic column with the model number of 125-1334DB-624 of Agilent of America; the second column 202 was a 19095N-126I HP-INNOWAX, Agilent, USA column.

Wherein, the related parameters of the Agilent 125-1334DB-624 are as follows: the length is 30m, the diameter is 0.530mm, the film thickness is 3.00mm, and the temperature range is-20 ℃ to 260 ℃. The relevant parameters of Agilent 19095N-126I HP-INNOWAX are as follows: the length is 60m, the diameter is 0.530mm, the film thickness is 1.00mm, and the temperature range is 40-240 ℃.

The flow rate of carrier gas is 45ml/min, the temperature of a column box is 40 ℃, the sampling time is 300s, and the sample injection time is 3600 s.

Fig. 5 is a graph showing an exemplary detection result of the gas detection apparatus of the present invention, in which the data of the sample obtained by the detection unit 13 is processed by the data collection and processing unit 14 according to the variation of the sample injection time.

Among them, the peak P1 in the graph shown in fig. 5 is a hetero peak and should be excluded. The process of judging the peak as a hetero-peak is as follows: when the test is carried out by introducing a standard gas with a certain concentration (for example, 20ppb), six peaks appear in the spectrogram, and one peak appears when introducing a standard gas with 0ppb, which indicates that the peak appearing at 0ppb is not the peak of the benzene series and is a hetero-peak. In addition, when the calibration is carried out by introducing benzene series substances with different concentrations, such as 10ppb, 20ppb and 30ppb, the peak areas and the peak heights of other substances are changed according to a proportional relation, and the area and the peak height of the first peak P1 are not changed along with the concentration, so that the peak is further proved to be not a benzene series substance peak and is a hetero-peak. There are many ways to determine the peak P1 as a hetero peak, which can be easily determined by those skilled in the art according to the common general knowledge in the art, and it is not intended to be the scope of the present invention, and the description is only briefly made here to facilitate the understanding of the contents of the present invention.

In addition, the peaks P2, P3, P4, P5, P6 and the like shown in FIG. 5 can be easily judged to correspond to benzene, toluene, ethylbenzene, m-xylene and o-xylene respectively by calibrating various single-component benzene series and based on the principle that the retention time of the same substance peak is the same under the same condition. In the embodiment shown in FIG. 5, the retention time of benzene represented by peak P2 was 10.03 minutes, the retention time of toluene represented by peak P3 was 15.52 minutes, the retention time of ethylbenzene represented by peak P4 was 26.84 minutes, the retention time of m-P-xylene represented by peak P5 was 28.47 minutes, and the retention time of o-xylene represented by peak P6 was 34.48 minutes.

FIGS. 6a to 6e show standard graphs of different benzene series (wherein, the concentration gradient of the sample is 5, 10, 15, 20, 25, 30 and 40ppb respectively). Wherein, fig. 6a is a standard curve chart of peak areas and peak heights of benzene with different concentrations obtained by calibration of the gas detection device of the present invention, and similar fig. 6b to 6e are respectively a standard curve chart of peak areas and peak heights of toluene, ethylbenzene, m-p-xylene and o-xylene. The results of experiments according to the concentration gradient show that the linear correlation is better for the peak areas corresponding to the peaks and the variance of the standard curve of the peak height > 0.99.

It will be understood by those skilled in the art that since the standard curves of FIGS. 6a-6e of the present invention show that the correlation between the peak area and peak height and the concentration of the substance is very good, after the test results similar to FIG. 5 are obtained, the concentration value of the corresponding benzene series can be obtained by using the peak height of each substance peak in FIG. 5 corresponding to the peak height in the standard curve. Of course, the concentration value of the corresponding benzene-based compound can also be obtained by using the peak area obtained by integrating the peaks of the respective substances in fig. 5 corresponding to the peak area in the calibration curve. It should be noted that the concentration values of the actually detected benzene series can be obtained by using the standard curves of the peak height and the peak area, and in the present invention, since the standard variance values of most peak areas are closer to 1 with respect to the peak height in fig. 6a to 6e, the concentration values calculated by the standard curves of the peak areas are used in the actual detection process of the present invention.

Further, due to the special structure of the gas detection device of the present invention, it can be beneficial to the first chromatographic column 201 to remove interference, and at the same time, the retention time of each substance can be extended, and then the retention time of each component of the benzene series to be detected is further extended by the second chromatographic column 202, so that it can obtain the peaks P2-P6 of the benzene series in the separation state shown in fig. 5, which not only has good separation effect, but also has large distance between each peak, good stability of the retention time range, and can greatly improve the efficiency of obtaining peak area by calculation. For example, when the existing curve integrates the area, usually the inflection point is determined point by point along the curve and then the curve is fitted for integration, which easily integrates some fluctuations not belonging to the peak of the substance into the peak area, not only the calculation time is long, but also the addition of the fluctuation area reduces the detection accuracy. In the invention, due to the special structure of the gas detection device, the stable retention time range of the substance peak can be obtained, so that when the peak area is integrated, only a curve in a specific time range can be intercepted for integration, the area outside the substance peak range is automatically excluded, and the integration efficiency of the peak area is greatly improved. Meanwhile, due to the existence of various different substances in the atmosphere, the curve obtained by detection cannot be only a standard curve pattern containing 6 substance peaks, and other fluctuating peaks of the interferent which are not removed by the first chromatographic column 201 may exist outside the retention time range of the standard 5 substance peaks besides the 5 substance peaks of the benzene series, so that the special structure of the invention can remove the area outside the retention range of the standard 5 substance peaks from the peak area integration, thereby removing the interference area of the interferent in the peak area integration algorithm, and greatly improving the accuracy of the gas detection device in the detection of the benzene series.

Further, in the following Table 1, the results of the repetitive experiments obtained by the gas detecting apparatus of the present invention are specifically given by taking the concentration of 20ppb as an example

Table 1: repeatability test results

And (4) conclusion: the relative standard deviation is calculated for all analysis results, and the retention time, the peak area and the relative standard deviation of the peak height obtained by repeated tests are lower, which shows that the gas detection device and the operation method thereof have good repeatability.

Wherein, the 1 st data of each peak in table 1 refers to 20ppb concentration blind data prepared from five components, 6 peaks are detected under standard operating conditions, the 1 st peak is removed, and the integrated peak areas of the other 5 peaks are shown in the first data of table 1. The concentrations of the species P2 to P6, obtained by converting the peak areas of the first set of data in the table into concentration values using a standard curve, are: 20.9, 19.96, 19.87, 19.69, 20.17 ppb. The actual concentration of the blind sample for examination is 20ppb, and the measured concentration is within the allowable range of error, so that the gas detection device and the operation method thereof are proved to be effective.

Furthermore, according to the detection standard of the atmospheric pollutants, only the concentration of benzene and toluene in the atmosphere is required to be detected, so that the gas detection device provided by the invention is switched from the second state to the first state only after the detection of the benzene and toluene is completed, the flow of the gas to be detected is intercepted, the residual gas is blown out reversely by the carrier gas, the required detection concentration of the benzene and toluene can be obtained efficiently, and the detection efficiency can be further improved.

For example, in the graph of the test results shown in FIG. 5, the retention time of benzene and toluene ends at about 16 minutes, while the retention time of ethylbenzene is after about 25 minutes, so that the trapping operation can be performed at about 20 minutes to switch from the second state to the first state. That is, the gas detection device of the invention can carry out interception blowback operation at any time as required under the condition of not interrupting the operation by the ten-way valve structure with a special structure, not only can obtain the concentration result of the required benzene series, but also can keep the carrier gas cleaning process of the system in the clearance of the interception operation, can repeat a plurality of groups of detection operations in a shorter time, and can eliminate the detection error by a plurality of groups of detection results obtained efficiently. In a word, the gas detection device of the invention adopts the design mode of interception and back flushing, can carry out interception operation according to the requirement, is beneficial to efficiently detecting the components to be detected, can stop detection at will according to the requirement, can not generate any interference on the detected result due to interception and back flushing, and can greatly improve the detection efficiency. For example, if the concentration of benzene, toluene and ethylbenzene is detected, the interception switching is only required to be carried out within about 30 minutes, the operation is simple and reliable, and a large amount of purging operation time can be saved.

In addition, it should be noted that, since different detection states have great influence on the detection result, multiple sets of data are obtained efficiently in as short a time as possible, and the detection accuracy can be greatly improved. The detection device in the prior art, which is simply connected in series, lacks the ten-way valve capable of efficiently intercepting and converting, the detection of the ten-way valve needs a large amount of time for carrying out carrier gas cleaning, the time consumption is very long, the time interval for obtaining a plurality of groups of data is also very long, the equipment state difference of each detection data is very large, the reliability of the detection result is very poor, and the accurate detection result is difficult to obtain. The detection and cleaning structure which is operated without stopping the machine can carry out repeated detection in a shorter time, which is a particularly outstanding advantage of the invention compared with the prior art, and the obtained detection result is more reliable and has higher precision.

It should be appreciated by those of skill in the art that while the present invention has been described in terms of several embodiments, not every embodiment includes only a single embodiment. The description is given for clearness of understanding only, and it is to be understood that all matters in the embodiments are to be interpreted as including technical equivalents which are related to the embodiments and which are combined with each other to illustrate the scope of the present invention.

The above description is only an exemplary embodiment of the present invention, and is not intended to limit the scope of the present invention. Any equivalent alterations, modifications and combinations can be made by those skilled in the art without departing from the spirit and principles of the invention.

Claims (6)

1. A gas detection device for benzene series substances comprises a box body (100), and is characterized in that the box body (100) is provided with a gas sampling unit (11), and a gas separation unit (12), a detection unit (13), a data acquisition and processing unit (14), a control unit (15) and a carrier gas unit (16) are arranged in the box body (100); wherein the gas separation unit (12) is arranged in an independent separation box (120), and the separation box (120) is provided with three air inlet pipes (121, 122, 123) and three air outlet pipes (124, 125, 126) communicated with the interior of the separation box; the three gas inlet pipes (121, 122, 123) are respectively a first gas inlet pipe (121) and a second gas inlet pipe (122) which are communicated with the carrier gas unit (16), and a third gas inlet pipe (123) which is communicated with the gas sampling unit (11); the three exhaust pipes (124, 125, 126) are respectively a first exhaust pipe (124) and a second exhaust pipe (125) for emptying, and a third exhaust pipe (126) communicated with the detection unit (13), and a sampling pump (18) is arranged in the second exhaust pipe (125);

the gas separation unit (12) includes a ten-way valve (20) disposed inside the separation tank (120), the ten-way valve (20) having first to tenth connection ports numbered in order of adjoining positions; the first connecting port is communicated with the eighth connecting port through a pipeline provided with a first chromatographic column (201); the second connecting port is communicated with the third exhaust pipe (126), and the third exhaust pipe (126) is provided with a second chromatographic column (202) positioned between the second connecting port and the detection unit (13); the third connecting port is communicated with the second air inlet pipe (122); the fourth connecting port is communicated with the seventh connecting port through a pipeline provided with a quantitative pipe (203); the fifth connecting port is communicated with the second exhaust pipe (125); the sixth connecting port is communicated with the third air inlet pipe (123); the ninth connection port is communicated with the first exhaust pipe (124); the tenth connecting port is communicated with the first air inlet pipe (121);

the first chromatographic column (201) adopts a chromatographic column with the model number of 125-1334DB-624 of Agilent company in America; the second chromatographic column (202) adopts a model 19095N-126I HP-INNOWAX chromatographic column of Agilent company;

the carrier gas unit (16) comprises a carrier gas steel cylinder (161) which is arranged in the box body (100), and the carrier gas steel cylinder (161) provides a first path of carrier gas and a second path of carrier gas through the first gas inlet pipe (121) and the second gas inlet pipe (122) respectively.

2. The gas detection apparatus according to claim 1, wherein the ten-way valve (20) has a first state in which the first connection port communicates with the tenth connection port, the second connection port communicates with the third connection port, the fourth connection port communicates with the fifth connection port, the sixth connection port communicates with the seventh connection port, and the eighth connection port communicates with the ninth connection port.

3. The gas detection apparatus according to claim 1, wherein the ten-way valve (20) has a second state in which the first connection port communicates with the second connection port, the third connection port communicates with the fourth connection port, the fifth connection port communicates with the sixth connection port, the seventh connection port communicates with the eighth connection port, and the ninth connection port communicates with the tenth connection port.

4. A method of operating the benzene-based gas sensor apparatus according to claim 1, comprising the steps of:

adjusting the ten-way valve (20) to a first state by the control unit (15), in which the first connection port communicates with the tenth connection port, the second connection port communicates with the third connection port, the fourth connection port communicates with the fifth connection port, the sixth connection port communicates with the seventh connection port, and the eighth connection port communicates with the ninth connection port;

the sampling pump (18) is started, sample gas is collected through the gas sampling unit (11), the sample gas is continuously introduced into the third gas inlet pipe (123), then enters the sixth connecting port and enters the quantitative pipe (203) from the seventh connecting port, and gas flowing out of the quantitative pipe (203) enters the fourth connecting port and the fifth connecting port and then is exhausted through the second gas exhaust pipe (125);

meanwhile, the control unit (15) enables the first path of carrier gas provided by the carrier gas unit (16) to continuously enter the tenth connecting port and the first connecting port through the first gas inlet pipe (121), then the first path of carrier gas flows through the first chromatographic column (201), and the gas flowing out of the first chromatographic column (201) enters the eighth connecting port and the ninth connecting port and then is exhausted through the first exhaust pipe (124);

meanwhile, a second path of carrier gas provided by the carrier gas unit (16) is led into the third connecting port and the second connecting port through the second gas inlet pipe (122) by the control unit (15), then flows through the second chromatographic column (202) through the third gas outlet pipe (126), and then flows out of the second chromatographic column (202) to enter the detection unit (13) and is exhausted.

5. The method of operation of claim 4, further comprising the steps of:

adjusting the ten-way valve (20) from a first state to a second state by the control unit (15), in the second state, the first connection port communicates with the second connection port, the third connection port communicates with the fourth connection port, the fifth connection port communicates with the sixth connection port, the seventh connection port communicates with the eighth connection port, and the ninth connection port communicates with the tenth connection port;

at the moment, the collected sample gas is continuously introduced into the third gas inlet pipe (123) through the sampling pump (18) and the gas sampling unit (11), then enters the sixth connecting port and the fifth connecting port and is exhausted from the second exhaust pipe (125);

meanwhile, the control unit (15) enables the first path of carrier gas provided by the carrier gas unit (16) to continuously enter the tenth connecting port and the ninth connecting port through the first gas inlet pipe (121), and then the first path of carrier gas is exhausted through the first exhaust pipe (124);

meanwhile, a second path of carrier gas provided by the carrier gas unit (16) is introduced into the third connector and the fourth connector through the second gas inlet pipe (122) through the control unit (15), then enters the quantitative tube (203) in a back flushing manner to push the sample gas stored in the quantitative tube (203) in the first state out of the quantitative tube (203), then the sample gas flows into the seventh connector and the eighth connector, enters the first chromatographic column (201) in a back flushing manner, different gas components are analyzed and discharged at different speeds under the action of the first chromatographic column (201), the gas to be detected analyzed is introduced into the first connector and the second connector, then flows to the second chromatographic column (202) through the third gas outlet pipe (126), and enters the detection unit (13) for detection after being separated by the second chromatographic column (202).

6. The method of operation of claim 5, further comprising the steps of:

after the first chromatographic column (201) performs analytical separation on the sample gas for a preset time, the ten-way valve (20) is adjusted from the second state to the first state through the control unit (15);

continuously introducing the collected sample gas into the third gas inlet pipe (123) through the sampling pump (18) and the gas sampling unit (11), then entering the sixth connecting port and entering the quantitative pipe (203) from the seventh connecting port, and exhausting the gas flowing out of the quantitative pipe (203) after entering the fourth connecting port and the fifth connecting port through the second gas exhaust pipe (125); thereby discharging the gas in the second state entirely for storing the sample gas for the next analysis in the quantitative tube (203);

meanwhile, the control unit (15) enables the first path of carrier gas provided by the carrier gas unit (16) to continuously enter the tenth connecting port and the first connecting port through the first gas inlet pipe (121), then the first path of carrier gas enters the first chromatographic column (201) in a back blowing mode, all original gas in the first chromatographic column (201) is reversely pushed out, and then the first path of carrier gas enters the eighth connecting port and the ninth connecting port and is exhausted through the first exhaust pipe (124);

meanwhile, a second path of carrier gas provided by the carrier gas unit (16) is continuously introduced into the third connecting port and the second connecting port through the second gas inlet pipe (121) by the control unit (15), then flows into the third exhaust pipe (126), the residual gas to be detected in the third exhaust pipe (126) is continuously pushed to the second chromatographic column (202), then the components in the gas to be detected are continuously analyzed and discharged at different speeds through the second chromatographic column (202), and then the gas flowing out of the second chromatographic column (202) enters the detection unit (13) for detection and then is exhausted; thereby completing a cycle of gas analysis in said first state; the analysis result obtained by the detection unit (13) is further transmitted to the data acquisition and processing unit (14) through a circuit.

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