CN109847555A - A kind of device and method based on multiple gases in hydrate recycling catalysis drying gas - Google Patents
A kind of device and method based on multiple gases in hydrate recycling catalysis drying gas Download PDFInfo
- Publication number
- CN109847555A CN109847555A CN201910107744.6A CN201910107744A CN109847555A CN 109847555 A CN109847555 A CN 109847555A CN 201910107744 A CN201910107744 A CN 201910107744A CN 109847555 A CN109847555 A CN 109847555A
- Authority
- CN
- China
- Prior art keywords
- hydrate
- gas
- tower
- reaction tower
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Abstract
The invention belongs to chemical field more particularly to a kind of device and methods based on multiple gases in hydrate recycling catalysis drying gas.Hydrogen can not only be recycled using hydration method object method, and wherein more valuable C can be recycled2Component (ethane and ethylene), while being also able to achieve CH4、N2Separation and recovery.Gas hydrate is formed and is separately occurred in reaction tower and decomposer respectively with decomposition reaction, the formation and decomposition, the separation of admixture of gas and the purification of gas component and recycling of gas hydrate are realized simultaneously, while having recycled multiple gases and gas recovery concentration height.Theoretical basis is provided to further realize hydrate industrial separation gaseous mixture, is had important practical significance for the popularization and application of hydration separation technology.
Description
Technical field
The invention belongs to chemical field more particularly to a kind of dresses based on multiple gases in hydrate recycling catalysis drying gas
It sets and method.
Background technique
Catalysis drying gas is that refinery is the most generally also that a kind of yield (raw material oil quality 5% or so) maximum hydrogen-containing gas is mixed
Object is closed, its main feature is that not only containing a certain amount of hydrogen (volume fraction 15%~40%), but also higher containing economic value
The C such as ethylene, ethane2Component (volume fraction 20%~30% or so), if can be by hydrogen therein and C2Component recycles,
Objective economic benefit can will be brought (it is estimated that the total amount of contained ethylene is super in annual the produced catalysis drying gas in the whole nation to refinery
1,000,000 tons are crossed, and total content and the comparable ethane of ethylene are then the raw materials of best cracking ethylene preparation).For a long time, catalysis is dry
Gas is not utilized well mostly, but is burnt up as device in Gas.Reason is its complicated composition, hydrogen and C2Component
Respective concentration is all less high, although there are many technology of refinery gas comprehensive utilization at present, there is also some limitations, such as deep cooling
The cryogenic conditions of partition method need just to be able to achieve by cascade refrigeration, and energy consumption is higher, and circularly cooling process is also more complicated, dress
It is big to set investment;The equipment that adsorption technology is used is more, and technique and process control are complicated, needs frequent switching, equipment investment is big;Film point
It is usually less high from the rate of recovery of method and product purity, and to membrane material requirement with higher, the service life of film is short,
Higher cost, gas are easy loss.In addition, the operating pressure of membrane separation process is generally 3~15MPa, low pressure refinery gas is carried out
Compression boosting need to be carried out when recycling, and energy consumption is caused to increase.
Hydrate separation technology is as a kind of emerging isolation technics, increasingly by attention both domestic and external, with refinery gas
Existing processing technique, which is compared, has unique advantage.Compared with cold separation technology, the condition ratio of hydrate separation technology needs
Relatively mild (pressure is 2~6MPa, and temperature is 0~10 DEG C), can carry out separating-purifying, moderate pressure to gaseous mixture at 0 DEG C or more
Significantly reduce energy consumption;Secondly, compared with adsorption separation technology and membrane separation technique, the scope of application of hydrate separation technology
It is wider, if PSA method and membrane separation process apply in general to the higher unstripped gas of density of hydrogen, the unstripped gas of low concentration is then recycled
Rate is too low, and hydrate separation technology in unstripped gas density of hydrogen it is of less demanding, can generally reach 90% or more return
Yield, and have the pressure loss small, the high advantage of separative efficiency;In addition, hydrate separation technology also have process flow it is short,
The low feature of continuously-running, equipment investment.Hydrate separation technology and traditional absorption, rectifying and adsorption technology also there are many
Single-stage or multistage balance point can be used according to the requirement of separation accuracy in similarity, such as difference that balances each other based on different component
From etc..Therefore hydrate separation technology has good application prospect in terms of the comprehensive utilization of refinery gas.
The existing method or apparatus using hydration method recycling multiple gases is varied, in place of Shortcomings, such as water
It closes object method and other traditional handicrafts combines low separation efficiency;It is excessively single to separate gas;Complex process etc..
Therefore, a kind of device and method based on multiple gases in hydrate recycling catalysis drying gas is needed.
Summary of the invention
Catalysis drying gas is separated the object of the present invention is to provide the utilization hydrate of a kind of simple process, economical and efficient and is returned
Receive H2、CH4、CO2、N2And C2The device and method of component (ethane and ethylene).
The method for recycling multiple gases in catalysis drying gas, the specific steps are as follows:
(1) it is generated in decomposition unit first, the catalysis drying gas in head tank (24) is sent into the first hydrate reaction tower,
Two plumes are obtained after reaction, one enters hydrogen rich gas collector by the gaseous stream that hydrogen forms by reaction tower Base top contact
(25), high concentration hydrogen is recycled;Another stock is the slurries that remaining hydrate and unreacted aqueous solution are formed in reaction unit,
Dissolve device (19) into the first hydrate, is dissolved under conditions of heating decompression, release CH4、CO2、N2And C2Component
And aqueous solution;
(2) it is generated in decomposition unit second, the CH that step (1) obtains4、CO2、N2And C2Gas enters the second hydration
The lower part of object reaction tower, during going on it, with the water containing dynamics promotor for coming from the first wet tank (5) downlink
Solution inversely contacts step by step, C2Component generates hydrate in the second hydrate reaction tower, by the CH in gas4、CO2、N2With C2
Component separation;C2Component is converted into hydrate and is mixed into solidliquid mixture into the second hydrate neutralizing device (19) with aqueous solution
In, dissolved under conditions of heating decompression, releases C2Component and aqueous solution, C2Component enters C2Collector (26) carries out
Recycling;And aqueous solution returns to the first wet tank (5) and recycles;The CH isolated4、CO2、N2From the second hydrate reaction tower
Top is discharged into third hydrate reaction tower;
(3) it is generated in decomposition unit in third, into the other of third hydrate reaction tower, during going on it, with
It is inversely contacted step by step from the aqueous solution of second liquid storage tank (5) containing dynamics promotor and generates hydrate;In gas easily
Generate the CH of hydrate4And CO2It is converted into hydrate and is mixed into solidliquid mixture, remaining N with aqueous solution2It is hydrated from third
Discharge at the top of object reaction tower, into nitrogen collector (28);Hydrate in third hydrate reaction tower and unreacted water-soluble
The slurries that liquid is formed dissolve device (19) into third hydrate, release CH by decompression4Gas and CO2Hydrate and aqueous solution
Mixed serum;Obtained gas is sent into methane collection device (29);And slurries then enter tetrahydrate neutralizing device (19), into
Row CO2The neutralizing of hydrate separates;The CO that tetrahydrate neutralizing device (19) releases2Into CO2Collector, and aqueous solution into
Enter second liquid storage tank (5), recycles.
Wherein, the dynamics promotor in the first wet tank (5) is lauryl sodium sulfate (SDS), and concentration is
300mg/L;Compound accelerator in second liquid storage tank (5) is graphite powder (NGP)+SDBS, concentration of aqueous solution 0.8%+
0.08%.
First hydrate dissolves the reaction pressure control of heating neutralizing in device (19) in 0.1~0.5MPa, and temperature control exists
0.5~1 DEG C;Second hydrate dissolves the reaction pressure control of heating neutralizing in device (19) in 0.1~0.5MPa, and temperature control exists
4℃;Third hydrate dissolves the reaction pressure control of heating neutralizing in device (19) in 3.0MPa, and temperature is controlled at 4 DEG C;4th water
The reaction pressure control of heating neutralizing in materialization solution device (19) is closed in 0.1~0.5MPa, temperature is controlled at 4 DEG C.
The present invention also provides a kind of using hydrate separation catalysis drying gas and recycles H2、CH4、CO2、N2And C2Component
The device of (ethane and ethylene), which includes the first generation decomposition unit, and for separating and recovering hydrogen, second generates decomposition list
Member, for separating and recovering C2Component, third generates decomposition unit, for separating and recovering N2、CH4、CO2And cooling system, wherein
First generation decomposition unit, the second generation decomposition unit, third generate decomposition unit and successively connect from front to back according to process sequence
Logical, the first generation decomposition unit is connected to cooling system.
Described first, which generates decomposition unit, includes the first hydrate reaction tower, head tank (24), hydrogen rich gas collector (25)
Dissolve device (19) with the first hydrate, the import of the first hydrate reaction tower is connected to head tank (24), in the first hydration
Gas pressure regulating valve (10) and gas flowmeter (16) are disposed on the route that object reaction tower is connected to head tank;First hydration
The top exit of object reaction tower is connected to hydrogen rich gas collector (25);It is connected in the first hydrate reaction tower with hydrogen rich gas collector
Route on be disposed with pressure gauge (17), counterbalance valve (18), gas flowmeter (16) and gas pressure regulating valve (10);First water
Close the outlet at bottom of object reaction tower and the inlet communication of the first hydrate neutralizing device (19);First hydrate dissolves the top of device (19)
Portion outlet is connected to the second hydrate reaction tower;The outlet at bottom of first hydrate neutralizing device (19) is connected to cooling system.
Described second, which generates decomposition unit, includes the first wet tank (5), the second hydrate reaction tower, the second hydration materialization
Solve device (19) and C2Collector (26);The second hydrate reaction top of tower import is connected to the first wet tank (5), and second
The outlet of hydrate reaction top of tower is connected to third hydrate reaction tower;In the second hydrate reaction tower and third hydrate reaction
Pressure gauge (17), counterbalance valve (18), gas flowmeter (16) and gas pressure regulating valve (10) are disposed on the route of tower connection;
The outlet at bottom of second hydrate reaction tower and the second hydrate dissolve device (19) inlet communication, and the second hydrate dissolves device (19)
Outlet at bottom is connected to the first wet tank (5), and the second hydrate dissolves device (19) top exit and C2Collector (26) connection,
Dissolve device and C in the second hydrate2Counterbalance valve (18) and gas flowmeter (16) are disposed on the route of collector connection.
It includes second liquid storage tank (5), third hydrate reaction tower, third hydration materialization that the third, which generates decomposition unit,
Solve device (19), tetrahydrate dissolves device (19), methane collection device (27), N2Gas collector (28) and Carbon dioxide collector
(29);The third hydrate reaction tower entrance is connected to second liquid storage tank (5), third hydrate reaction top of tower outlet with
N2Gas collector (28) connection, in third hydrate reaction tower and N2Pressure is disposed on the route of gas collector (28) connection
Power table (17), counterbalance valve (18), gas flowmeter (16) and gas pressure regulating valve (10);Third hydrate reaction tower bottom outlet with
Third hydrate dissolves the connection of device (19) entrance, and third hydrate dissolves device (19) upper outlet and methane collection device (27) even
It is logical;Third hydrate is dissolved device (19) outlet at bottom and is connected to tetrahydrate neutralizing device (19) entrance, tetrahydrate neutralizing
Device (19) upper outlet is connected to Carbon dioxide collector (29), and tetrahydrate dissolves device (19) lower part outlet and second liquid
Storage tank (5) connection;In third hydrate neutralizing device and methane collection device and tetrahydrate neutralizing device and carbon dioxide collection
Counterbalance valve (18) and gas flowmeter (16) are disposed on the route of device connection.
The hydrate reaction tower includes high-pressure tower (7) and highly pressurised liquid circulating pump (14), the inside of the high-pressure tower (7)
Top be equipped with spray head (11), middle part be equipped with high pressure hydration reactor (12), the inside of the high-pressure tower (7) is additionally provided with refrigeration
System (6), the periphery of the high-pressure tower are provided with insulating layer (8) and cooling coil (9);The highly pressurised liquid circulating pump (14) with
Connection inside high-pressure tower (7);
The wet tank (5) is sequentially communicated with pressure liquid pump (3), temperature sensor (1), safety valve (4), the storage
Stirring motor (2) refrigeration system (6) and cooling coil (9) are equipped with inside tank (5).
The cooling system includes cold flow container (20), wherein the entrance of cold flow container (20) and the first hydrate dissolve device
(19) outlet is disposed with refrigeration system on the route that cold flow container (20) is connected to hydrate neutralizing device (19)
(6), temperature sensor (1), liquid pressure regulator valve (15);What the outlet of cold flow container (20) was connected to the first hydrate reaction tower entrance
Liquid boosted flow pump (21), fluid flowmeter (22), check (non-return) valve (23) and liquid pressure regulator valve (15) are disposed on route;
The outside of the cold flow container (20) is additionally provided with liquid level meter (13).
The medicine have the advantages that
1) working pressure range of use the technique of the present invention is 0.1~15MPa, temperature range for 273.15~
277.65K;Due to bleed pressure height, without pressurization, it is only necessary to be hydrated tower and decomposer, investment is little, to production industry without shadow
It rings.
2) separation method of the present invention and process flow be simple, convenience and high-efficiency, and promotor is environment friendly and pollution-free, will not make to equipment
At corrosion, quickly, high production efficiency, low energy consumption and obtained separation gas concentration is high (concentration is more than 90%) for reaction rate;.
3) present invention can not only recycle hydrogen using hydration method, and can recycle wherein more valuable C2Component (ethane
And ethylene), while being also able to achieve CH4、N2Separation and recovery.By gas hydrate formed with decomposition reaction respectively in reaction tower and
Separately occur in decomposer, while realizing the formation and decomposition, the separation of admixture of gas and gas component of gas hydrate
Purification and recycling, while having recycled multiple gases and gas recovery concentration is high.To further realize hydrate industry point
Theoretical basis is provided from gaseous mixture, is had important practical significance for the popularization and application of hydration separation technology.
Detailed description of the invention
The recyclable device schematic diagram of multiple gases in Fig. 1 hydrate recycling catalysis drying gas of the present invention;
Description of symbols:
1- temperature sensor, 2- stirring motor, 3- pressure liquid pump, 4- safety valve, 5- wet tank, 6- refrigeration system,
7- high-pressure tower, 8- insulating layer, 9- cooling coil, 10- gas pressure regulating valve, 11- spray head, 12- high pressure hydration reactor, 13- liquid level
Meter, 14- highly pressurised liquid circulating pump, 15- liquid pressure regulator valve, 16- gas flowmeter, 17- pressure gauge, 18- counterbalance valve, 19- hydration
Materialization solution device, the cold flow container of 20-, 21- liquid boosted flow pump, 22- fluid flowmeter, 23- check (non-return) valve, 24- head tank, 25- are rich
Hydrogen collecting apparatus, 26-C2 collector, 27- methane collection device, 28- nitrogen collector, 29- Carbon dioxide collector.
Specific embodiment
Embodiment 1
(1) catalysis drying gas enters the first hydrate reaction using gas pressure regulating valve (10) by gas flowmeter (16)
Tower reacts to obtain two plumes through the first hydrate reaction tower, one by reaction tower Base top contact the gaseous state being made of hydrogen
Logistics, the gaseous stream is by pressure gauge (17), counterbalance valve (18), gas flowmeter (16) using gas pressure regulating valve (10) into
Enter hydrogen rich gas collector (25), recycles high concentration hydrogen (gas concentration about 95%);Remaining water and gas hydrate synthesis slurries lead to
Liquid pressure regulator valve (15) are crossed into the first hydrate neutralizing device (19), are dissolved (pressure control under conditions of heating decompression
In 0.1~0.5MPa, temperature is controlled at 0.5~1 DEG C), release CH4、CO2、N2And C2Component and aqueous solution;
(2) CH that step (1) obtains4、CO2、N2And C2Gas enters the second hydrate reaction tower lower part, goes on it
In the process, (SDS concentration is 300mg/L, pressure with the dynamics promotor that contains from the first wet tank (5) downlink
4.0MPa, 4.5 DEG C of temperature) aqueous solution inversely contact step by step, C2Component generates hydrate in hydrate reaction tower, by gas
In CH4、CO2、N2With C2Component separation;C2Component is converted into hydrate and is mixed into solidliquid mixture into second with aqueous solution
Hydrate is dissolved in device (19), dissolved under conditions of heating decompression (pressure control in 0.1~0.5MPa, temperature control
At 4 DEG C), release C2Component and aqueous solution, C2Component (concentration 98.98%) enters C2Collector (26) is recycled;And it is water-soluble
Liquid returns to the first wet tank (5) and recycles;The CH isolated4、CO2、N2It is discharged from the second hydrate reaction top of tower, according to
It is secondary by counterbalance valve (18), gas flowmeter (16) enters third hydrate reaction tower using gas pressure regulating valve (10).
(3) gas enters third hydrate reaction tower from lower part, on it go during, with come from second liquid storage tank
(5) (graphite powder NGP+SDBS, concentration of aqueous solution 0.8%+0.08%, pressure 7.5MPa, temperature containing dynamics promotor
4 DEG C) aqueous solution inversely contacts step by step and generates hydrate (compared to pure aquatic system, 116.3%) efficiency is increased to;In gas easily
Generate the component (CH of hydrate4、CO2Component) it is converted into hydrate and is mixed into solidliquid mixture, remaining gas with aqueous solution
(N2) be discharged from third hydrate reaction top of tower, into nitrogen collector (28);Hydrate in third hydrate reaction tower
The slurries formed with unreacted aqueous solution, liquid enter third hydrate neutralizing device (19), dissolve with heating in the neutralizing device
(reaction pressure control is controlled in 3.0MPa, temperature at 4 DEG C), releases CH4Gas and CO2The mixing slurry of hydrate and aqueous solution
Liquid;Obtained gas is sent into methane (concentration 91%) collector (27);And slurries then enter tetrahydrate neutralizing device (19),
Carry out CO2The neutralizing separation of hydrate (pressure control is controlled in 0.1~0.5MPa, temperature at 4 DEG C);Tetrahydrate dissolves device
(19) CO released2By pressure gauge (17), counterbalance valve (18), gas flowmeter (16) using gas pressure regulating valve (10) into
Enter CO2(concentration 60%, if carrying out the second-order separation, concentration is up to 96%), and aqueous solution returns to second liquid for collector (29)
Storage tank (5) recycles.
Claims (10)
1. a kind of method of multiple gases in recycling catalysis drying gas, it is characterised in that: specific step is as follows for the method:
(1) it is generated in decomposition unit first, the catalysis drying gas in head tank (24) is sent into the first hydrate reaction tower, reaction
After obtain two plumes, one enters hydrogen rich gas collector by the gaseous stream that hydrogen forms by reaction tower Base top contact
(25), high concentration hydrogen is recycled;Another stock is the slurries that remaining hydrate and unreacted aqueous solution are formed in reaction unit,
Dissolve device (19) into the first hydrate, is dissolved under conditions of heating decompression, release CH4、CO2、N2And C2Component
And aqueous solution;
(2) it is generated in decomposition unit second, the CH that step (1) obtains4、CO2、N2And C2Gas enters the second hydrate reaction
The lower part of tower, on it go during, with from the first wet tank (5) downlink the aqueous solution containing dynamics promotor by
The reverse contact of grade, C2Component generates hydrate in the second hydrate reaction tower, by the CH in gas4、CO2、N2With C2Component point
From;C2Component is converted into hydrate and is mixed into solidliquid mixture with aqueous solution to be dissolved in device (19) into the second hydrate,
Dissolved under conditions of heating decompression, releases C2Component and aqueous solution, C2Component enters C2Collector (26) is recycled;
And aqueous solution returns to the first wet tank (5) and recycles;The CH isolated4、CO2、N2It is arranged from the second hydrate reaction top of tower
Enter third hydrate reaction tower out;
(3) it generates in decomposition unit in third, into the gas of third hydrate reaction tower, during going on it, and comes from
The aqueous solution of second liquid storage tank (5) containing dynamics promotor inversely contacts step by step and generates hydrate;It is easily generated in gas
The CH of hydrate4And CO2It is converted into hydrate and is mixed into solidliquid mixture, remaining N with aqueous solution2It is anti-from third hydrate
Top of tower is answered to be discharged, into nitrogen collector (28);Hydrate and unreacted aqueous solution shape in third hydrate reaction tower
At slurries, into third hydrate dissolve device (19), release CH by decompression4Gas and CO2Hydrate and aqueous solution it is mixed
Close slurries;Obtained gas is sent into methane collection device (29);And slurries then enter tetrahydrate neutralizing device (19), carry out
CO2The neutralizing of hydrate separates;The CO that tetrahydrate neutralizing device (19) releases2Into CO2Collector, and aqueous solution enters
Second liquid storage tank (5), recycles.
2. the method for recycling catalysis drying gas according to claim 1, which is characterized in that dynamic in the first wet tank (5)
Mechanics promotor is lauryl sodium sulfate (SDS), concentration of aqueous solution 300mg/L;Compounding in second liquid storage tank (5) promotees
It is graphite powder (NGP)+SDBS, concentration of aqueous solution 0.8%+0.08% into agent.
3. the method for recycling catalysis drying gas according to claim 1, which is characterized in that the first hydrate is dissolved in device (19)
In 0.1~0.5MPa, temperature is controlled at 0.5~1 DEG C for the reaction pressure control of heating neutralizing;Second hydrate is dissolved in device (19)
In 0.1~0.5MPa, temperature is controlled at 4 DEG C for the reaction pressure control of heating neutralizing;Third hydrate dissolves heating in device (19)
In 3.0MPa, temperature is controlled at 4 DEG C for the reaction pressure control of neutralizing;Tetrahydrate dissolves the reaction of heating neutralizing in device (19)
Pressure control is controlled in 0.1~0.5MPa, temperature at 4 DEG C.
4. a kind of device based on multiple gases in hydrate recycling catalysis drying gas, which is characterized in that described device includes the
All one's life, for separating and recovering hydrogen, second generated decomposition unit, for separating and recovering C at decomposition unit2Component, third generate
Decomposition unit, for separating and recovering N2、CH4、CO2And cooling system, wherein first generates decomposition unit, the second generation is decomposed
Unit, third generate decomposition unit and are sequentially communicated from front to back according to process sequence, and first generates decomposition unit and cooling system
Connection.
5. the device according to claim 4 based on multiple gases in hydrate recycling catalysis drying gas, which is characterized in that
Described first, which generates decomposition unit, includes the first hydrate reaction tower, head tank (24), hydrogen rich gas collector (25) and the first water
It closes materialization solution device (19), the import of the first hydrate reaction tower is connected to head tank (24);First hydrate reaction tower
Top exit is connected to hydrogen rich gas collector (25);The outlet at bottom of first hydrate reaction tower and the first hydrate dissolve device
(19) inlet communication;The top exit of first hydrate neutralizing device (19) is connected to the second hydrate reaction tower;First hydration
The outlet at bottom of materialization solution device (19) is connected to cooling system.
6. the device according to claim 4 based on multiple gases in hydrate recycling catalysis drying gas, which is characterized in that
Described second, which generates decomposition unit, includes the first wet tank (5), the second hydrate reaction tower, the second hydrate neutralizing device (19)
And C2Collector (26);The second hydrate reaction top of tower entrance is connected to the first wet tank (5), and the second hydrate is anti-
Top of tower outlet is answered to be connected to third hydrate reaction tower;The outlet at bottom of second hydrate reaction tower and the second hydrate are dissolved
Device (19) inlet communication, the second hydrate neutralizing device (19) outlet at bottom are connected to the first wet tank (5), the second hydration materialization
Solve device (19) top exit and C2Collector (26) connection.
7. the device according to claim 4 based on multiple gases in hydrate recycling catalysis drying gas, which is characterized in that
It includes second liquid storage tank (5), third hydrate reaction tower, third hydrate neutralizing device that the third, which generates decomposition unit,
(19), tetrahydrate dissolves device (19), methane collection device (27), N2Gas collector (28) and Carbon dioxide collector (29);
The third hydrate reaction tower entrance is connected to second liquid storage tank (5), the outlet of third hydrate reaction top of tower and N2Gas
Collector (28) connection;The outlet of third hydrate reaction tower bottom is connected to third hydrate neutralizing device (19) entrance, third water
Materialization solution device (19) upper outlet is closed to be connected to methane collection device (27);Third hydrate dissolves device (19) outlet at bottom and the 4th
Hydrate dissolves the connection of device (19) entrance, and tetrahydrate dissolves device (19) upper outlet and Carbon dioxide collector (29) even
Logical, tetrahydrate neutralizing device (19) lower part outlet is connected to second liquid storage tank (5).
8. according to the described in any item devices based on multiple gases in hydrate recycling catalysis drying gas of claim 5-7,
Be characterized in that, the hydrate reaction tower includes high-pressure tower (7) and highly pressurised liquid circulating pump (14), the high-pressure tower (7) it is interior
The top in portion is equipped with spray head (11), and middle part is equipped with high pressure hydration reactor (12), and the inside of the high-pressure tower (7) is additionally provided with system
Cooling system (6), the periphery of the high-pressure tower are provided with insulating layer (8) and cooling coil (9);The highly pressurised liquid circulating pump (14)
It is connected to high-pressure tower (7) inside.
9. the device according to claim 6 or 7 based on multiple gases in hydrate recycling catalysis drying gas, feature exist
In the wet tank (5) is sequentially communicated with pressure liquid pump (3), temperature sensor (1), safety valve (4), the storage tank (5)
Inside is equipped with stirring motor (2), refrigeration system (6) and cooling coil (9).
10. the device according to claim 4 based on multiple gases in hydrate recycling catalysis drying gas, feature exist
In the cooling system includes cold flow container (20), wherein the entrance of cold flow container (20) and the first hydrate dissolve going out for device (19)
Mouth connection is disposed with refrigeration system (6) on the route that cold flow container (20) is connected to hydrate neutralizing device (19), temperature passes
Sensor (1), liquid pressure regulator valve (15);On the route that the outlet of cold flow container (20) is connected to the first hydrate reaction tower entrance successively
It is provided with liquid boosted flow pump (21), fluid flowmeter (22), check (non-return) valve (23) and liquid pressure regulator valve (15);The cold flow container
(20) outside is additionally provided with liquid level meter (13).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910107744.6A CN109847555B (en) | 2019-02-01 | 2019-02-01 | Device and method for recovering multiple gases in catalytic dry gas based on hydrate method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910107744.6A CN109847555B (en) | 2019-02-01 | 2019-02-01 | Device and method for recovering multiple gases in catalytic dry gas based on hydrate method |
Publications (2)
Publication Number | Publication Date |
---|---|
CN109847555A true CN109847555A (en) | 2019-06-07 |
CN109847555B CN109847555B (en) | 2021-07-27 |
Family
ID=66897541
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201910107744.6A Active CN109847555B (en) | 2019-02-01 | 2019-02-01 | Device and method for recovering multiple gases in catalytic dry gas based on hydrate method |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109847555B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110577851A (en) * | 2019-09-12 | 2019-12-17 | 华南理工大学 | device and method for quickly and continuously hydrating and separating coal bed gas |
Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1272618A (en) * | 2000-01-13 | 2000-11-08 | 石油大学(北京) | Method for extracting concentrated hydrogen gas by utilizing separation of aqua compound |
JP3433288B2 (en) * | 1999-07-29 | 2003-08-04 | 独立行政法人産業技術総合研究所 | Mixed gas separation device and mixed gas separation method |
JP2005263986A (en) * | 2004-03-18 | 2005-09-29 | Mitsui Eng & Shipbuild Co Ltd | System and method for producing dry gas hydrate |
CN1706920A (en) * | 2004-06-11 | 2005-12-14 | 中国石油天然气股份有限公司 | Combined process for separating and recovering hydrogen, ethylene and ethane from refinery dry gas or separating ethylene cracking gas |
CN1724115A (en) * | 2005-07-07 | 2006-01-25 | 中国石油大学(北京) | Process of absorption-hydration coupling for separating multicomponent gas mixture |
CN1873285A (en) * | 2005-06-02 | 2006-12-06 | 中国科学院过程工程研究所 | Method and equipment for enriching and storing and transporting coalbed gas by using hydrate |
CN102295967A (en) * | 2011-06-28 | 2011-12-28 | 华南理工大学 | Apparatus for continuously separating carbon dioxide from natural gas through hydrate method, and method thereof |
CN103030494A (en) * | 2012-12-21 | 2013-04-10 | 天津大学 | Absorption and hydration coupling device and method for separating ethylene and ethane in catalytic cracking dry gas or ethylene pyrolysis gas |
CN104289083A (en) * | 2014-09-12 | 2015-01-21 | 中国科学院广州能源研究所 | Method for separating mixed gas by hydrate process |
US20150107826A1 (en) * | 2013-10-22 | 2015-04-23 | Korea Advanced Institute Of Science And Technology | Method for Recovering Methane Gas from Natural Gas Hydrate by Injecting CO2 and Air Mixed Gas |
CN105087093A (en) * | 2014-05-08 | 2015-11-25 | 罗显平 | Method and device for continuous separation of methane, carbon dioxide and hydrogen sulfide from biogas by hydrate method |
WO2018118623A1 (en) * | 2016-12-22 | 2018-06-28 | Exxonmobil Research And Engineering Company | Separation of methane from gas mixtures |
CN108525473A (en) * | 2018-06-14 | 2018-09-14 | 河南理工大学 | Phase transformation ionic liquid hydration method trapping separation CO2/CH4/N2System and device |
-
2019
- 2019-02-01 CN CN201910107744.6A patent/CN109847555B/en active Active
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3433288B2 (en) * | 1999-07-29 | 2003-08-04 | 独立行政法人産業技術総合研究所 | Mixed gas separation device and mixed gas separation method |
CN1272618A (en) * | 2000-01-13 | 2000-11-08 | 石油大学(北京) | Method for extracting concentrated hydrogen gas by utilizing separation of aqua compound |
JP2005263986A (en) * | 2004-03-18 | 2005-09-29 | Mitsui Eng & Shipbuild Co Ltd | System and method for producing dry gas hydrate |
CN1706920A (en) * | 2004-06-11 | 2005-12-14 | 中国石油天然气股份有限公司 | Combined process for separating and recovering hydrogen, ethylene and ethane from refinery dry gas or separating ethylene cracking gas |
CN1873285A (en) * | 2005-06-02 | 2006-12-06 | 中国科学院过程工程研究所 | Method and equipment for enriching and storing and transporting coalbed gas by using hydrate |
CN1724115A (en) * | 2005-07-07 | 2006-01-25 | 中国石油大学(北京) | Process of absorption-hydration coupling for separating multicomponent gas mixture |
CN102295967A (en) * | 2011-06-28 | 2011-12-28 | 华南理工大学 | Apparatus for continuously separating carbon dioxide from natural gas through hydrate method, and method thereof |
CN103030494A (en) * | 2012-12-21 | 2013-04-10 | 天津大学 | Absorption and hydration coupling device and method for separating ethylene and ethane in catalytic cracking dry gas or ethylene pyrolysis gas |
US20150107826A1 (en) * | 2013-10-22 | 2015-04-23 | Korea Advanced Institute Of Science And Technology | Method for Recovering Methane Gas from Natural Gas Hydrate by Injecting CO2 and Air Mixed Gas |
CN105087093A (en) * | 2014-05-08 | 2015-11-25 | 罗显平 | Method and device for continuous separation of methane, carbon dioxide and hydrogen sulfide from biogas by hydrate method |
CN104289083A (en) * | 2014-09-12 | 2015-01-21 | 中国科学院广州能源研究所 | Method for separating mixed gas by hydrate process |
WO2018118623A1 (en) * | 2016-12-22 | 2018-06-28 | Exxonmobil Research And Engineering Company | Separation of methane from gas mixtures |
CN108525473A (en) * | 2018-06-14 | 2018-09-14 | 河南理工大学 | Phase transformation ionic liquid hydration method trapping separation CO2/CH4/N2System and device |
Non-Patent Citations (4)
Title |
---|
LEGOIX LUDOVIC NICOLAS等: ""Experimental Study of Mixed Gas Hydrates from Gas Feed Containing CH4, CO2 and N-2: Phase Equilibrium in the Presence of Excess Water and Gas Exchange"", 《ENERGIES》 * |
周诗岽等: ""水合物法分离CO2+N2混合气体效果研究"", 《天然气化工(C1化学与化工)》 * |
周锡堂等: ""水合物法分离回收石油化工厂火炬气工艺研究"", 《现代化工》 * |
孟凡飞等: ""可用于炼厂气综合利用的水合物分离技术研究进展"", 《石油化工》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110577851A (en) * | 2019-09-12 | 2019-12-17 | 华南理工大学 | device and method for quickly and continuously hydrating and separating coal bed gas |
Also Published As
Publication number | Publication date |
---|---|
CN109847555B (en) | 2021-07-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100406375C (en) | Method for preparing hydrogen by reforming methanol with high recovery rate | |
CN102617282B (en) | Methanol production process and system | |
CN102585951A (en) | Novel process for co-production of liquefied synthesis gas, pure hydrogen and methanol from coke-oven gas | |
CN103194286A (en) | Methanation method for synthesizing substitute natural gas by using industrial hydrocarbon exhaust gas | |
CN107880960A (en) | Device in Gas alkane hydrate method of purification and system | |
CN104709877B (en) | One kind reclaims nitrogen and hydrogen device and method in synthesis ammonia relief gas | |
CN109847555A (en) | A kind of device and method based on multiple gases in hydrate recycling catalysis drying gas | |
CN107446635B (en) | Novel coke oven gas utilization method | |
CN102041019A (en) | Method for coproducing substitute natural gas through coal liquefaction | |
CN105294604A (en) | Propylene oxide production device | |
WO2021232663A1 (en) | System and method for producing hydrogen from biogas in sewage treatment plant | |
CA1076778A (en) | Apparatus and method for manufacturing deuterium enriched water | |
CA1201576A (en) | Method and plant for obtaining deuterium-enriched water | |
CN205740823U (en) | A kind of MTP device | |
TWI434822B (en) | A manufacture method of methanol and its device thereof | |
CN113117503B (en) | System and method for separating mixed gas by energy-saving hydrate method | |
CN211005248U (en) | Device for directly preparing gasoline by carbon dioxide hydrogenation | |
CN108707064B (en) | Production method for co-producing dimethyl ether by using blast furnace gas | |
CN113860991A (en) | Ammonia and alcohol co-production method for realizing low-carbon emission by combining photocatalysis with coal gas production | |
CN1111708C (en) | Method for extracting concentrated hydrogen gas by utilizing separation of aqua compound | |
CN113117504A (en) | System and method for separating mixed gas by energy recovery type hydrate method | |
CN204550489U (en) | A kind of gas employing methanation of coke oven LNG device with spraying cycle device | |
CN220149230U (en) | Green electricity system green ammonia coproduction nitric acid closed circulation system | |
CN1094481C (en) | Method and device for separating and reclaiming ethylene from catalytic cracked dry gas | |
CN114534653B (en) | Propane dehydrogenation and synthesis ammonia coupling system and process |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |