CN109845759A - A kind of Bordeaux mixture and preparation method, application method of improvement - Google Patents

A kind of Bordeaux mixture and preparation method, application method of improvement Download PDF

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Publication number
CN109845759A
CN109845759A CN201910245963.0A CN201910245963A CN109845759A CN 109845759 A CN109845759 A CN 109845759A CN 201910245963 A CN201910245963 A CN 201910245963A CN 109845759 A CN109845759 A CN 109845759A
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CN
China
Prior art keywords
bordeaux mixture
water
improvement
copper sulfate
basic copper
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Pending
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CN201910245963.0A
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Chinese (zh)
Inventor
丁荔
曹洪建
姜宏浩
曹凌云
吕毅
胡静
陈妮
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Weihai Academy Of Agricultural Sciences
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Weihai Academy Of Agricultural Sciences
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Priority to CN201910245963.0A priority Critical patent/CN109845759A/en
Publication of CN109845759A publication Critical patent/CN109845759A/en
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Abstract

The present invention is a kind of Bordeaux mixture of improvement, including following substance by weight: 1 part of nanometer basic copper sulfate, 1-6 parts of sodium hydroxide, 1-3 parts of calcium chloride, 50-400 parts of water.Can there be good control efficiency to diseases such as the brown spots such as apple, walnut, pears, grape, ring spot, anthracnose, anthrax leaf blight, leaf curl of peach, Bacterial septicaemia syndromes using the Bordeaux mixture of improvement of the invention, and the Bordeaux mixture preparation improved is simple, residue is smaller when use, atomizing sprayer nozzle blocking is not will cause, cost is relatively low.

Description

A kind of Bordeaux mixture and preparation method, application method of improvement
Technical field
The present invention relates to a kind of pesticide, the Bordeaux mixture and preparation method, application method of especially a kind of improvement.
Background technique
Bordeaux mixture is common medicament in the daily production and operation in orchard, and common formula is calculated as copper sulphate 1 Part, 1-3 parts of lime, 60-240 parts of water, charge ratio can according to need appropriate increase and decrease.Bordeaux mixture for apple, walnut, The various diseases such as the brown spots such as pears, grape, ring spot, anthracnose, anthrax leaf blight, leaf curl of peach, Bacterial septicaemia syndrome have Good control efficiency is the common medicament in orchard.
Presently, there are main problem be Bordeaux mixture preparation trouble, meanwhile, when in use Bordeaux mixture due to lime it is residual Slag is more, and atomizing sprayer nozzle is be easy to cause to block, and is not suitable for being sprayed with atomizing sprayer, and Bordeaux mixture surrogate-data technique effect obviously compared with Difference, higher cost.
Suitable atomizing sprayer application can be developed, and main component does not change, it is convenient to prepare, and drug effect is secure can be with The formula for substituting traditional Bordeaux mixture, seems very significant in Modern orchard.
Summary of the invention
For overcome the deficiencies in the prior art, the purpose of the present invention is to provide a kind of Bordeaux mixture of improvement and preparation sides Method, application method, it is intended to which it is convenient to prepare, and meets atomizing sprayer use, effectively prevents orchard disease.
To achieve the goals above, the invention is realized by the following technical scheme:
A kind of Bordeaux mixture of improvement, including following substance by weight: 1 part of nanometer basic copper sulfate, hydroxide 1-6 parts of sodium, 1-3 parts of calcium chloride, 50-400 parts of water.
Preferably, the Bordeaux mixture of the improvement, wherein the nanometer basic copper sulfate is agricultural nanometer alkali formula sulfuric acid Copper, the sodium hydroxide are agricultural sodium hydroxide, and the calcium chloride is agricultural calcium chloride.
Preferably, the Bordeaux mixture of the improvement, wherein partial size≤10nm of the nanometer basic copper sulfate particle.
This case additionally provides a kind of preparation method of the Bordeaux mixture of improvement, comprising:
Step 1) proportionally weighs sodium hydroxide, nanometer basic copper sulfate, calcium chloride and water;
Step 2) is in the stainless steel or plastic containers of 3 cryogenic thermostats, respectively by the weighed sodium hydroxide of institute, chlorination Calcium, nanometer basic copper sulfate add 10-100 parts of water sufficiently to dissolve;
Step 3) mixes sodium hydroxide solution, calcium chloride solution, stirs, and obtains the mixed liquor of the two;
Step 4) pours rapidly the resulting mixed liquor of step 3) in nanometer basic copper sulfate solution, proportionally more than addition Water is sufficiently stirred.
Preferably, the preparation method of the Bordeaux mixture of the improvement, wherein 3 cryogenic thermostats in the step 2) Stainless steel or plastic containers in temperature be maintained at -1 DEG C -0 DEG C.
Preferably, the preparation method of the Bordeaux mixture of the improvement, wherein be proportionally added in the step 4) Yu Shui is specifically included: within the 15S after the resulting mixed liquor of step 3) to be poured rapidly to nanometer basic copper sulfate solution according to than Remaining water is added in example.
This case additionally provides a kind of application method of the Bordeaux mixture of improvement, using the Bordeaux mixture of aforementioned improvement, to change The weight ratio of good Bordeaux mixture and amount of water adds water to be diluted for 1: 50-400, then using the side smeared or sprayed Formula is applied on branches of fruit trees.
Preferably, the application method of the Bordeaux mixture of the improvement, wherein the mode of the sprinkling specifically includes use Atomizing spraying machine is sprayed.
Preferably, the application method of the Bordeaux mixture of the improvement, wherein be when the time being applied on branches of fruit trees Before fruit tree bud, water is added to be diluted for 1: 50-100 with the weight ratio of the Bordeaux mixture of improvement and amount of water.
Preferably, the application method of the Bordeaux mixture of the improvement, wherein be when the time being applied on branches of fruit trees After fruit tree bud, water is added to be diluted for 1: 200-400 with the weight ratio of the Bordeaux mixture of improvement and amount of water.
Advantage of the invention are as follows:
Using the Bordeaux mixture improved of the present invention can to the brown spots such as apple, walnut, pears, grape, ring spot, anthracnose, The diseases such as anthrax leaf tangerine disease, leaf curl of peach, Bacterial septicaemia syndrome have good control efficiency, and the Bordeaux mixture system improved Standby simple, residue is smaller when use, not will cause atomizing sprayer nozzle blocking, cost is relatively low.
Specific embodiment
The present invention will be further described in detail below with reference to the embodiments, to enable those skilled in the art referring to specification Text can be implemented accordingly.
Embodiment one:
A kind of Bordeaux mixture of improvement, including following substance by weight: 1 part of nanometer basic copper sulfate, hydroxide 1-6 parts of sodium, 1-3 parts of calcium chloride, 50-400 parts of water.
Nanometer basic copper sulfate is agricultural nanometer basic copper sulfate, and sodium hydroxide is agricultural sodium hydroxide, and calcium chloride is agriculture With calcium chloride, partial size≤10nm of nanometer basic copper sulfate particle
Embodiment two:
Embodiment two provides a kind of preparation method of the Bordeaux mixture of improvement, comprising:
Step 1) proportionally weighs sodium hydroxide, nanometer basic copper sulfate, calcium chloride and water;
Step 2) is in the stainless steel or plastic containers of 3 cryogenic thermostats, respectively by the weighed sodium hydroxide of institute, chlorination Calcium, nanometer basic copper sulfate add 10-100 parts of water sufficiently to dissolve;
Step 3) mixes sodium hydroxide solution, calcium chloride solution, stirs, and obtains the mixed liquor of the two;
Step 4) pours rapidly the resulting mixed liquor of step 3) in nanometer basic copper sulfate solution, proportionally more than addition Water is sufficiently stirred.
The stainless steel of 3 cryogenic thermostats or the temperature in plastic containers are maintained at -1 DEG C -0 DEG C in step 2).
Remaining water is proportionally added in step 4) to specifically include: the resulting mixed liquor of step 3) is poured into rapidly a nanometer alkali formula Remaining water is proportionally added within 15S after copper-bath.
Embodiment three:
Embodiment three additionally provides a kind of application method of the Bordeaux mixture of improvement, using the Bordeaux mixture of aforementioned improvement, Water is added to be diluted for 1: 50-400 with the weight ratio of the Bordeaux mixture of improvement and amount of water, then using smearing or sprinkling Mode be applied on branches of fruit trees.The mode of sprinkling is specifically included to be sprayed using atomizing spraying machine.When being applied to fruit tree Before time on limb is fruit tree bud, with the weight ratio of the Bordeaux mixture of improvement and amount of water be 1: 50-100 add water into Row dilution.After the time being applied on branches of fruit trees is fruit tree bud, with the parts by weight of the Bordeaux mixture of improvement and amount of water Ratio is 1: 200-400 water to be added to be diluted.
Example IV:
On the basis of above-described embodiment one to three, example IV with nanometer basic copper sulfate, sodium hydroxide, calcium chloride, The weight of water is respectively 1 part, 1 part, 2 parts, 50 parts of ratios produce the Bordeaux mixture of improvement, spray or be applied to branches of fruit trees On, the diseases such as brown spot, ring spot, anthracnose, anthrax leaf blight, leaf curl of peach, Bacterial septicaemia syndrome can be effectively prevented.
Embodiment five:
On the basis of above-described embodiment one to three, embodiment five with nanometer basic copper sulfate, sodium hydroxide, calcium chloride, The weight of water is respectively 1 part, 3 parts, 1.5 parts, 200 parts of ratios produce the Bordeaux mixture of improvement, spray or be applied to fruit tree branch On dry, the diseases such as brown spot, ring spot, anthracnose, anthrax leaf blight, leaf curl of peach, Bacterial septicaemia syndrome can be effectively prevented.
Embodiment six:
On the basis of above-described embodiment one to three, embodiment six with nanometer basic copper sulfate, sodium hydroxide, calcium chloride, The weight of water is respectively 1 part, 6 parts, 3 parts, 400 parts of ratios produce the Bordeaux mixture of improvement, spray or be applied to branches of fruit trees On, the diseases such as brown spot, ring spot, anthracnose, anthrax leaf blight, leaf curl of peach, Bacterial septicaemia syndrome can be effectively prevented.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited In specific details and embodiment shown here.

Claims (10)

1. a kind of Bordeaux mixture of improvement, including following substance by weight: 1 part of nanometer basic copper sulfate, sodium hydroxide 1-6 parts, 1-3 parts of calcium chloride, 50-400 parts of water.
2. the Bordeaux mixture improved as described in claim 1, which is characterized in that the nanometer basic copper sulfate is agricultural nanometer Basic copper sulfate, the sodium hydroxide are agricultural sodium hydroxide, and the calcium chloride is agricultural calcium chloride.
3. the Bordeaux mixture improved as claimed in claim 2, which is characterized in that the agricultural nanometer basic copper sulfate particle Partial size≤10nm.
4. the preparation method of the Bordeaux mixture such as the described in any item improvement of claim 1-2 characterized by comprising
Step 1) proportionally weighs sodium hydroxide, nanometer basic copper sulfate, calcium chloride and water;
Step 2) in the stainless steel or plastic containers of 3 cryogenic thermostats, respectively by the weighed sodium hydroxide of institute, calcium chloride, receive Rice basic copper sulfate adds 10-100 parts of water sufficiently to dissolve;
Step 3) mixes sodium hydroxide solution, calcium chloride solution, stirs, and obtains the mixed liquor of the two;
Step 4) pours rapidly the resulting mixed liquor of step 3) in nanometer basic copper sulfate solution, and remaining water is proportionally added, It is sufficiently stirred.
5. the preparation method for the Bordeaux mixture improved as claimed in claim 4, which is characterized in that in the step 2) 3 it is low The stainless steel of warm constant temperature or the temperature in plastic containers are maintained at -1 DEG C -0 DEG C.
6. the preparation method for the Bordeaux mixture improved as claimed in claim 4, which is characterized in that in the step 4) according to than Example is added remaining water and specifically includes: within the 15S after the resulting mixed liquor of step 3) to be poured rapidly to nanometer basic copper sulfate solution Remaining water is proportionally added.
7. a kind of application method of the Bordeaux mixture of improvement, which is characterized in that use the described in any item improvement of claim 1-2 Bordeaux mixture, be 1: 50-400 water to be added to be diluted with the weight ratio of the Bordeaux mixture of improvement and amount of water, then adopt It is applied on branches of fruit trees with the mode smeared or sprayed.
8. the application method for the Bordeaux mixture improved as claimed in claim 7, which is characterized in that the mode of the sprinkling is specific Including being sprayed using atomizing spraying machine.
9. the application method for the Bordeaux mixture improved as claimed in claim 7, which is characterized in that when being applied on branches of fruit trees Time be fruit tree bud before, with the weight ratio of the Bordeaux mixture of improvement and amount of water be 1: 50-100 add water carry out it is dilute It releases.
10. the application method for the Bordeaux mixture improved as claimed in claim 7, which is characterized in that when being applied to branches of fruit trees On time be fruit tree bud after, be 1: 200-400 water to be added to carry out with the weight ratio of the Bordeaux mixture of improvement and amount of water Dilution.
CN201910245963.0A 2019-03-15 2019-03-15 A kind of Bordeaux mixture and preparation method, application method of improvement Pending CN109845759A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60188304A (en) * 1984-03-08 1985-09-25 Mitsui Toatsu Chem Inc Insecticidal, acaricidal and antimicrobial agent composition
CN101195497A (en) * 2006-12-04 2008-06-11 沈祖达 Process for producing cupric hydroxide or cupric oxide
CN103766401A (en) * 2012-10-23 2014-05-07 大连鹤菲英博科技有限公司 Preparation method of 1% lime equivalent type bordeaux mixture
CN109169707A (en) * 2018-09-22 2019-01-11 杨凌全中有机农业推广中心 A kind of configuration method of Bordeaux mixture

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60188304A (en) * 1984-03-08 1985-09-25 Mitsui Toatsu Chem Inc Insecticidal, acaricidal and antimicrobial agent composition
CN101195497A (en) * 2006-12-04 2008-06-11 沈祖达 Process for producing cupric hydroxide or cupric oxide
CN103766401A (en) * 2012-10-23 2014-05-07 大连鹤菲英博科技有限公司 Preparation method of 1% lime equivalent type bordeaux mixture
CN109169707A (en) * 2018-09-22 2019-01-11 杨凌全中有机农业推广中心 A kind of configuration method of Bordeaux mixture

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
唐仲明 等著: "《果树修剪与管理》", 31 January 2015, 山东科学技术出版社 *
徐爽: "杀菌剂用纳米氢氧化铜的制备及应用性能研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 *
易秋实: "均匀沉淀法制备纳米碱式硫酸铜杀菌剂的研究", 《农药》 *

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Application publication date: 20190607

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