CN109843066A - Pesticide combination - Google Patents

Abstract

The present invention relates to the pesticide combinations comprising a kind of tetrazolium one fungicide and Pesticidal compound II chosen from the followings: N- [the chloro- 3- of 4- [[(phenyl methyl) amino] carbonyl] phenyl] -1- methyl -3- (1, 1, 2, 2, 2- pentafluoroethyl group) -4- (trifluoromethyl) -1H- pyrazoles -5- formamide, [3- (4- chloro- 2, 6- 3,5-dimethylphenyl) -8- methoxyl group -1- methyl -2- oxo -1, 8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [3- (4- chloro- 2, 6- 3,5-dimethylphenyl) -8- methoxyl group -2- oxo -1, 8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [3- (4- chloro- 2, 6- Dimethvl-phenyl) -1, 8- bis- Methoxyl group -2- oxo -1, 8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [3- (4- chloro- 2, 6- Dimethvl-phenyl) -1- ethyoxyl -8- methoxyl group -2- oxo -1, 8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [1- ethyoxyl -8- methoxyl group -2- oxo -3- (2, 4, 6- trimethylphenyl) -1, 8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [1, 8- dimethoxy -2- oxo -3- (2, 4, 6- trimethylphenyl) -1, 8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [8- methoxyl group -1- methyl -2- oxo -3- (2, 4, 6- trimethyl Phenyl) -1, 8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [8- methoxyl group -2- oxo -3- (2, 4, 6- trimethylphenyl) -1, 8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, 2- (3- ethylsulfonyl -2- pyridyl group) -3- methyl -6- (trifluoromethyl) imidazo [4, 5-b] pyridine, 2- [3- ethylsulfonyl -5- (trifluoromethyl) -2- pyridyl group] -3- methyl -6- (trifluoromethyl) imidazo [4, 5-b] pyridine, 4- [5- (3, 5- dichlorophenyl) -5- (trifluoromethyl) -4H- is differentAzoles -3- base]-N- [(4R) -2- ethyl -3- oxo-differentOxazolidine -4- base] -2- methyl-benzamide, [5- (3,5- bis- chloro- 4- fluoro-phenyl) -5- (trifluoromethyl) -4H- is different by 4-Azoles -3- base]-N- [(4R) -2- ethyl -3- oxo-different

Description

Pesticide combination

Description

The present invention relates to include following pesticide combination:

1) as the 1- of compound I [2- [[1- (4- chlorphenyl) pyrazole-3-yl] oxygen methyl] -3- methylphenyl] -4- first Base-tetrazolium -5- ketone；With

2) a kind of Pesticidal compound II, wherein compound II is selected from the group by forming as follows: N- [4- chloro- 3- [[(phenyl first Base) amino] carbonyl] phenyl] -1- methyl -3- (1,1,2,2,2- pentafluoroethyl group) -4- (trifluoromethyl) -1H- pyrazoles -5- formyl Amine, [3- (the chloro- 2,6- 3,5-dimethylphenyl of 4-) -8- methoxyl group -1- methyl -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene - 4- yl] carbonic acid ethyl ester, [3- (the chloro- 2,6- 3,5-dimethylphenyl of 4-) -8- methoxyl group -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [3- (the chloro- 2,6- Dimethvl-phenyl of 4-) -1,8- dimethoxy -2- oxo -1,8- diaza Spiral shell [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [3- (the chloro- 2,6- Dimethvl-phenyl of 4-) -1- ethyoxyl -8- methoxyl group -2- Oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [1- ethyoxyl -8- methoxyl group -2- oxo -3- (2, 4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [1,8- dimethoxy -2- oxygen Generation -3- (2,4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [8- methoxyl group -1- Methyl -2- oxo -3- (2,4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [8- Methoxyl group -2- oxo -3- (2,4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, 2- (3- ethylsulfonyl -2- pyridyl group) -3- methyl -6- (trifluoromethyl) imidazo [4,5-b] pyridine, 2- [3- ethyl sulphonyl Base -5- (trifluoromethyl) -2- pyridyl group] -3- methyl -6- (trifluoromethyl) imidazo [4,5-b] pyridine, 4- [5- (3,5- dichloro Phenyl) -5- (trifluoromethyl) -4H- is differentAzoles -3- base]-N- [(4R) -2- ethyl -3- oxo-differentOxazolidine -4- base] -2- [5- (the chloro- 4- fluoro-phenyl of 3,5- bis-) -5- (trifluoromethyl) -4H- is different by methyl-benzamide, 4-Azoles -3- base]-N- [(4R) -2- ethyl -3- oxo-differentOxazolidine -4- base] -2- methyl-benzamide.

Said mixture is hereinafter also known as " inventive mixture ".

In addition, this is related to including that animal has the present invention relates to a kind of method using inventive mixture prevention and treatment nuisance Evil object and harmful fungoid, and be related to compound I and compound II and preparing the purposes in such mixture, and is mixed comprising such Close the composition of object.

In addition, the present invention relates to a kind of method of inventive mixture prevention and treatment harmful fungoid using compound I and II, with And compound I and one or two compound II are preparing the purposes in such mixture as defined above, and include this The composition of class mixture.

Extraly, the invention also includes a kind of protection plant propagation materials (preferred seed) to prevent harmful nuisance such as fungi Or the method for animal pests (insect, spider or nematode), including have the plant propagation material (preferred seed) with pesticide The inventive mixture of effect amount contacts.

Term " plant propagation material " is understood to mean that all reproductive parts such as seed of plant, and can be used for numerous Grow asexual the vegetable material such as cutting and stem tuber (such as potato) of plant.This includes seed, root, fruit, stem tuber, bulb, underground Stem, branch, bud and other plant part, including the rice shoot and seedling after sprouting or after emergence by soil transferring.These seedling are also It can be protected and via dipping or the complete or partial treatment poured before the transplant.In a particularly preferred embodiment party In case, term propagation material indicates seed.

Extraly, the invention also includes it is a kind of protection plant propagation material (preferred seed) to prevent harmful fungoid method, Including contacting the plant propagation material (preferred seed) with a effective amount of inventive mixture of pesticide.

In addition, the present invention relates to a kind of methods and inventive mixture using inventive mixture prevention and treatment harmful fungoid Present in compound preparing purposes in such mixture and comprising the composition of such mixture.

It is mixed that the invention further relates to the plant protective active constituents with the chemiluminescence for improving plant health The method closed object and inventive mixture is applied to plant.

Compound I and analog and its action of agricultural chemicals and its method is prepared for example as known to WO 2013162072.Change It closes object II and its action of agricultural chemicals and prepares its method usually by WO2015132140, WO2013050302, WO2015190316 Known to WO 2014/191271.

The typical problem occurred in nuisance prevention and control field be need to reduce the dosage rate of active constituent to reduce or Unfavorable environment or toxicological effects are avoided, while remaining to that effective nuisance is allowed to prevent and treat.

For the present invention, term nuisance includes harmful fungoid and animal pests.

Another problem met with involves a need to effectively antagonize wide scope harmful fungoid and harmful animal nuisance Available nuisance control agent.

There is also needing to knock down activity in conjunction with long control, i.e., nuisance of the snap action in conjunction with long dauer effect is anti- Control agent.

Repetition that another difficulty relevant to pesticide is used is various agricultural chemical compounds and single administration are in many cases Lead to the quick selection of nuisance, nuisance means animal pests and harmful fungoid, nuisance to the reactive compound With drug resistance that is natural or adapting to.Therefore, it is necessary to help to prevent or overcome the nuisance control agent of drug resistance.

The present invention faced another problem is that need to be improved the composition of plant, it is a kind of usually and hereinafter referred to as " to plant The method of object health ".

Term plant health includes preventing and treating unrelated various plants with nuisance to improve.For example, there may be mentioned benefit It can be improved crop characteristic, including emergence, crop yield, protein content, oil content, content of starch, the more root system developed (improved root growth), improved stress tolerance (such as arid, heat, salt, UV, water, cold), the ethylene reduced (drop Low generation and/or received inhibition), it is tiller increase, plant height increase, bigger blade, less dead base leaf, stronger Tiller, greener leaf color, pigment content, photosynthetic activity, need less supply (such as fertilizer or water), the less seed of needs, More voluminous tiller, blooming earlier, early stage grain maturity, less plant section (lodging), the growth of increased spray, raising Plant vigor, increased associations and early stage and preferably sprout；Or it is well known to those skilled in the art any other Advantage.

Therefore, it is an object of the present invention to provide solve described problem reduction dosage rate and/or enhancing activity profile and/or knock down Activity combined with long control and/or drug resistance management and/or promotion plant health pesticide combination.

It has been found that the purpose is realized by the mixture comprising reactive compound defined in beginning partially or completely.

Particularly, it has been found that compared with the control rate for using individual compounds may cause, such as start defined mixing Object shows the effect significantly increase to nuisance and/or worked as and is applied to plant, plant part, seed or applies in its growth place Used time is suitable for improving plant health.

It has been found that the effect of the inventive mixture comprising compound I and compound II is far more than living present in mixture Property compound individually antifungal and/or desinsection and/or plant health improvement result (synergistic function).

Moreover, it has been discovered that compared with the control rate for using individual compounds may cause, meanwhile, that is, combine or applies respectively Compound I and compound II or continuous administration compound I and compound II allows the enhancing to harmful fungoid to prevent and treat, and (collaboration increases Imitate mixture).

Moreover, it has been discovered that compared with the control rate for using individual compounds may cause, meanwhile, that is, combine or applies respectively Compound I and compound II or continuous administration compound I and compound II allows the enhancing to harmful animal nuisance to prevent and treat (synergistic mixture).

Moreover, it has been discovered that compared with the plant health effect for using individual compounds may cause, meanwhile, that is, combine or divides Not Shi Yong compound I and compound II or continuous administration compound I and compound II allow enhance plant health effect.

The weight ratio of compound I and compound II in binary mixture be 20000:1-1:20000,500:1-1:500, It is preferred that 100:1-1:100, more preferable 50:1-1:50, most preferably 20:1-1:20, including weight ratio are 10:1-1:10,1:5-5:1 Or 1:1.

In the mixture of three kinds of ingredients, in each combination of two kinds of ingredients, the weight ratio of compound I and II are 20000: 1-1:20000,500:1-1:500, preferably 100:1-1:100, more preferable 50:1-1:50, most preferably 20:1-1:20, including weight Amount is than being 10:1-1:10,1:5-5:1 or 1:1.

As described above, the present invention is more particularly directed to inventive mixtures as defined above, that is, it include following pestsides synthesis Object:

1) as the 1- of compound I [2- [[1- (4- chlorphenyl) pyrazole-3-yl] oxygen methyl] -3- methylphenyl] -4- first Base-tetrazolium -5- ketone；With

2) a kind of Pesticidal compound II, wherein compound II is selected from the group by forming as follows: N- [4- chloro- 3- [[(phenyl first Base) amino] carbonyl] phenyl] -1- methyl -3- (1,1,2,2,2- pentafluoroethyl group) -4- (trifluoromethyl) -1H- pyrazoles -5- formyl Amine, [3- (the chloro- 2,6- 3,5-dimethylphenyl of 4-) -8- methoxyl group -1- methyl -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene - 4- yl] carbonic acid ethyl ester, [3- (the chloro- 2,6- 3,5-dimethylphenyl of 4-) -8- methoxyl group -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [3- (the chloro- 2,6- Dimethvl-phenyl of 4-) -1,8- dimethoxy -2- oxo -1,8- diaza Spiral shell [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [3- (the chloro- 2,6- Dimethvl-phenyl of 4-) -1- ethyoxyl -8- methoxyl group -2- Oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [1- ethyoxyl -8- methoxyl group -2- oxo -3- (2, 4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [1,8- dimethoxy -2- oxygen Generation -3- (2,4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [8- methoxyl group -1- Methyl -2- oxo -3- (2,4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [8- Methoxyl group -2- oxo -3- (2,4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, 2- (3- ethylsulfonyl -2- pyridyl group) -3- methyl -6- (trifluoromethyl) imidazo [4,5-b] pyridine, 2- [3- ethyl sulphonyl Base -5- (trifluoromethyl) -2- pyridyl group] -3- methyl -6- (trifluoromethyl) imidazo [4,5-b] pyridine, 4- [5- (3,5- dichloro Phenyl) -5- (trifluoromethyl) -4H- is differentAzoles -3- base]-N- [(4R) -2- ethyl -3- oxo-differentOxazolidine -4- base] -2- [5- (the chloro- 4- fluoro-phenyl of 3,5- bis-) -5- (trifluoromethyl) -4H- is different by methyl-benzamide, 4-Azoles -3- base]-N- [(4R) -2- ethyl -3- oxo-differentOxazolidine -4- base] -2- methyl-benzamide.

Preferred mixture is to include following mixture:

1) as the 1- of compound I [2- [[1- (4- chlorphenyl) pyrazole-3-yl] oxygen methyl] -3- methylphenyl] -4- first Base-tetrazolium -5- ketone；With

2) a kind of Pesticidal compound II, wherein compound II is selected from the group by forming as follows: 4- [5- (3,5- dichloro-benzenes Base) -5- (trifluoromethyl) -4H- is differentAzoles -3- base]-N- [(4R) -2- ethyl -3- oxo-differentOxazolidine -4- base] -2- first [5- (the chloro- 4- fluoro-phenyl of 3,5- bis-) -5- (trifluoromethyl) -4H- is different by base-benzamide and 4-Azoles -3- base]-N- [(4R) - 2- ethyl -3- oxo-differentOxazolidine -4- base] -2- methyl-benzamide.

In another preferred embodiment of the present, the present invention relates to include following mixture:

1) as the 1- of compound I [2- [[1- (4- chlorphenyl) pyrazole-3-yl] oxygen methyl] -3- methylphenyl] -4- first Base-tetrazolium -5- ketone；With

2) a kind of Pesticidal compound II, wherein compound II is selected from the group by forming as follows: [3- (chloro- 2, the 6- dimethyl of 4- Phenyl) -8- methoxyl group -1- methyl -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [3- (4- Chloro- 2,6- 3,5-dimethylphenyl) -8- methoxyl group -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [3- (the chloro- 2,6- Dimethvl-phenyl of 4-) -1,8- dimethoxy -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] Carbonic acid ethyl ester, [3- (the chloro- 2,6- Dimethvl-phenyl of 4-) -1- ethyoxyl -8- methoxyl group -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [1- ethyoxyl -8- methoxyl group -2- oxo -3- (2,4,6- trimethylphenyl) - 1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [1,8- dimethoxy -2- oxo -3- (2,4,6- trimethyl Phenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [8- methoxyl group -1- methyl -2- oxo -3- (2, 4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester and [8- methoxyl group -2- oxo -3- (2,4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester.

In another preferred embodiment of the present, the present invention relates to include following mixture:

1) as the 1- of compound I [2- [[1- (4- chlorphenyl) pyrazole-3-yl] oxygen methyl] -3- methylphenyl] -4- first Base-tetrazolium -5- ketone；With

2) a kind of Pesticidal compound II, wherein compound II is selected from the group by forming as follows: 2- (3- ethylsulfonyl -2- Pyridyl group) -3- methyl -6- (trifluoromethyl) imidazo [4,5-b] pyridine and 2- [3- ethylsulfonyl -5- (trifluoromethyl) -2- Pyridyl group] -3- methyl -6- (trifluoromethyl) imidazo [4,5-b] pyridine.

In a further preferred embodiment, the present invention relates to include following mixture:

1) as the 1- of compound I [2- [[1- (4- chlorphenyl) pyrazole-3-yl] oxygen methyl] -3- methylphenyl] -4- first Base-tetrazolium -5- ketone；With

2) a kind of Pesticidal compound II, wherein compound II is selected from the group by forming as follows: 4- [5- (3,5- dichloro-benzenes Base) -5- (trifluoromethyl) -4H- is differentAzoles -3- base]-N- [(4R) -2- ethyl -3- oxo-differentOxazolidine -4- base] -2- first [5- (the chloro- 4- fluoro-phenyl of 3,5- bis-) -5- (trifluoromethyl) -4H- is different by base-benzamide and 4-Azoles -3- base]-N- [(4R) - 2- ethyl -3- oxo-differentOxazolidine -4- base] -2- methyl-benzamide.

In another more preferred, the present invention relates to include following mixture:

1) as the 1- of compound I [2- [[1- (4- chlorphenyl) pyrazole-3-yl] oxygen methyl] -3- methylphenyl] -4- first Base-tetrazolium -5- ketone；With

2) a kind of Pesticidal compound II, wherein compound II is 2- (3- ethylsulfonyl -2- pyridyl group) -3- methyl -6- (trifluoromethyl) imidazo [4,5-b] pyridine.

Inventive mixture can further contain one or more insecticides, fungicide, herbicide.

Inventive mixture can be converted to the agrochemical composition of common type, for example, solution, lotion, suspension, Pulvis, powder, paste, particle, mould, capsule and its mixture.The example of types of compositions be suspension (such as SC, OD, FS), emulsifiable concentrate (such as EC), lotion (such as EW, EO, ES, ME), capsule (such as CS, ZC), paste, pastille, wettable Powder or pulvis (such as WP, SP, WS, DP, DS), mould (such as BR, TB, DT), particle (such as WG, SG, GR, FG, GG, MG), the gel formulation (such as GF) of insect killing product (such as LN) and processing plant propagation material such as seed.These and other Types of compositions is in " Catalogue of pesticide formulation types and international Coding system ", Technical Monograph, the 2nd phase, May the 6th edition in 2008, CropLife It is defined in International.

Composition such as Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001；Or Knowles, New developments in crop protection product formulation, Agrow It is prepared in a known way described in Reports DS243, T&F Informa, London, 2005.

Suitable auxiliary agent is solvent, liquid-carrier, solid carrier or filler, surfactant, dispersing agent, emulsifier, profit Humectant, adjuvant, solubilizer, penetration enhancer, protective colloid, adhesive, thickener, moisturizer, expellent, attractant, Feeding stimulants, compatilizer, fungicide, antifreezing agent, defoaming agent, colorant, tackifier and adhesive.

Suitable solvent and liquid-carrier are water and organic solvent, arrive high boiling mineral oil fractions as in, such as kerosene, Diesel oil；The oil of plant or animal origin；Aliphatic series, cyclic annular and aromatic hydrocarbons, such as toluene, paraffin, naphthane, alkylated naphthalene；Alcohol Class, such as ethyl alcohol, propyl alcohol, butanol, benzylalcohol, cyclohexanol；Glycols；DMSO；Ketone, such as cyclohexanone；Esters, such as lactate, Carbonic ester, aliphatic ester, gamma-butyrolacton；Fatty acid；Phosphonate ester；Amine；Amides, such as N-Methyl pyrrolidone, fatty acid Dimethylformamide；And their mixture.

Suitable solid carrier or filler are mine soil, such as silicate, silica gel, talcum, kaolin, lime stone, lime, white Chalk, clay, dolomite, diatomite, bentonite, calcium sulfate, magnesium sulfate, magnesia；Polysaccharide, such as cellulose, starch；Fertilizer, Such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas；The product of plant origin, for example, flour, bark powder, wood powder, shuck powder and Their mixture.

Suitable surfactant is surface active cpd, such as anion, cation, nonionic and amophoteric surface active Agent, block polymer, polyelectrolyte and their mixture.Such surfactant may be used as emulsifier, dispersing agent, Solubilizer, wetting agent, penetration enhancer, protective colloid or adjuvant.The example of surfactant is listed in McCutcheon ' s, Volume 1: Emulsifiers&Detergents, McCutcheon ' s Directories, Glen Rock, USA, 2008 In (International Ed. or North American Ed.).

Suitable anionic surfactant be sulfonic acid, sulfuric acid, phosphoric acid, the alkali metal of carboxylic acid, alkaline-earth metal or ammonium salt with And their mixture.The example of sulfonate is alkylaryl sulfonates, diphenyl sulfonate, alpha-alkene sulfonate, lignin sulphur Hydrochlorate, the sulfonate of fatty acid and oil, the sulfonate of ethoxylated alkylphenol, the sulfonate of alkoxylate aryl phenol, condensation naphthalene Sulfonate, the sulfonate of dodecyl-and tridane, the sulfonate of naphthalene and alkylnaphthalene, sulfosuccinate or sulfo group Succinamate.The example of sulfate is the sulfuric acid of the sulfate of fatty acid and oil, the sulfate of ethoxylated alkylphenol, alcohol The sulfate of salt, the sulfate of ethoxylated alcohol or aliphatic ester.Phosphatic example is phosphate ester.The example of carboxylate is Alkyl carboxylate and carboxylation alcohol or alkylphenol ethoxylate.

Suitable nonionic surfactant is alcoxylates, the fatty acid amide that N- replaces, amine oxide, esters, Glycosyl surfactant active, polymeric surfactant and its mixture.The example of alcoxylates is that all 1-50 as has already been work as Measure the compound of alkoxylated alcohol, alkyl phenol, amine, amide, aryl phenol, fatty acid or aliphatic ester.It can be by ethylene oxide And/or propylene oxide is used for alkoxylate, preferably ethylene oxide.The example for the fatty acid amide that N- replaces is fatty acid glucose acyl Amine or Marlamid.The example of esters is aliphatic ester, glyceride or monoglyceride.The reality of glycosyl surfactant active Example is anhydro sorbitol, ethoxylated sorbitan, sucrose and glucose ester or alkyl polyglucoside.Polymer surfactants The example of agent is the homopolymer or copolymer of vinyl pyrrolidone, vinyl alcohol or vinyl acetate.

Suitable cationic surfactant is season type surfactant, such as the quaternary ammonium with 1 or 2 hydrophobic group The salt of compound or long chain primary amines.Suitable amphoteric surfactant is alkyl betaine and imidazolines.Suitable block is poly- It closes A-B the or A-B-A type block polymer that object is the block comprising polyoxyethylene and polyoxypropylene, or includes alkanol, poly- The A-B-C type block polymer of ethylene oxide and polyoxypropylene.Suitable polyelectrolyte is polyacids or polybases.The example of polyacids is The alkali metal salt or polyacids comb-shaped polymer of polyacrylic acid.The example of polybases is polyvinylamine or polyvinylamine.

Suitable adjuvant is that itself have insignificant pesticide activity or in itself even without pesticide activity and improvement Compound of the inventive mixture to the biology performance of object.Example be surfactant, mineral oil or vegetable oil and Other auxiliary agents.Other examples are by Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa UK, the 2006, the 5th chapter are listed.

Suitable thickener is that polysaccharide (such as xanthan gum, carboxymethyl cellulose), inorganic clay are (organically-modified or unmodified ), polycarboxylate and silicate.

Suitable fungicide be bronopol (bronopol) and isothiazolinone derivatives such as alkyl isothiazole quinoline ketone with Benzoisothiazolinone class.

Suitable antifreezing agent is ethylene glycol, propylene glycol, urea and glycerol.

Suitable defoaming agent is polysiloxanes, long-chain alcohol and fatty acid salt.

Suitable colorant (such as red coloration, blue or green) is low aqueous solubility pigment and water-soluble dye.Example is Inorganic colourant (such as iron oxide, titanium oxide, Hexacyanoferrate iron) and toner (such as alizarin colouring agent, azo Toner and phthalocyanine colorant).

Suitable tackifier or adhesive are polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylic acid Ester, biowax or synthetic wax and cellulose ether.

Types of compositions and its example of preparation are as follows:

I) water-soluble concentrate (SL, LS)

10-60 weight % inventive mixture and 5-15 weight % wetting agent (such as alcohol alkoxylates) are dissolved in and being added to In the water and/or water-soluble solvent (such as alcohol) of 100 weight %.Active material dissolution when being diluted with water.

Ii) dispersed concentrate (DC)

5-25 weight % inventive mixture and 1-10 weight % dispersing agent (such as polyvinylpyrrolidone) are dissolved in and added Into the organic solvent (such as cyclohexanone) of 100 weight %.It is diluted with water to obtain dispersion.

Iii) emulsifiable concentrate (EC)

By 15-70 weight % inventive mixture and 5-10 weight % emulsifier (such as calcium dodecyl benzene sulfonate and castor Sesame oil ethoxylate) it is dissolved in the water-insoluble organic solvents (such as aromatic hydrocarbon) for adding to 100 weight %.It is diluted with water to obtain Lotion.

Iv) lotion (EW, EO, ES)

By 5-40 weight % inventive mixture and 1-10 weight % emulsifier (such as calcium dodecyl benzene sulfonate and castor-oil plant Oily ethoxylate) it is dissolved in 20-40 weight % water-insoluble organic solvents (such as aromatic hydrocarbon).By mulser by the mixing Object is introduced into the water for adding to 100 weight % and equal phase emulsion is made.It is diluted with water to obtain lotion.

V) suspension (SC, OD, FS)

2-10 weight % dispersing agent and wetting is being added in 20-60 weight % inventive mixture in the ball mill of stirring Agent (such as sodium lignosulfonate and alcohol ethoxylate), 0.1-2 weight % thickener (such as xanthan gum) and add to 100 weight % Underwater crushing, obtain active material suspension fine crushing.It is diluted with water to obtain stable active material suspension.For FS type At most 40 weight % adhesives (such as polyvinyl alcohol) are added in composition.

Vi) water-dispersible granule and water-soluble granular (WG, SG)

It is smart under the dispersing agent and wetting agent (such as sodium lignosulfonate and alcohol ethoxylate) for adding to 100 weight % Fine lapping 50-80 weight % inventive mixture is simultaneously made by commercial plant (such as extruder, spray tower, fluidized bed) Water dispersible or water-soluble granular.It is diluted with water to obtain stable active substance dispersion or solution.

Vii) water dispersible pow-ders and water-soluble powder (WP, SP, WS)

1-5 weight % dispersing agent (such as sodium lignosulfonate), 1-3 weight is being added in 50-80 weight % inventive mixture It amount % wetting agent (such as alcohol ethoxylate) and adds under the solid carrier (such as silica gel) of 100 weight % in rotor-stator It is ground in grinding machine.It is diluted with water to obtain stable active substance dispersion or solution.

Viii) gel (GW, GF)

3-10 weight % dispersing agent (such as sodium lignosulfonate), 1-5 weight % thickening is being added in the ball mill of stirring Agent (such as carboxymethyl cellulose) and the underwater crushing 5-25 weight % inventive mixture for adding to 100 weight %, obtain activity The delicate suspensions of substance.It is diluted with water to obtain stable active material suspension.

Ix) microemulsion (ME)

5-30 weight % organic solvent blend (such as myristalkonium is added in 5-20 weight % inventive mixture Amide and cyclohexanone), 10-25 weight % surfactant blend (such as alcohol ethoxylate and aryl phenol ethoxylate) With add in the water of 100 weight %.The mixture is stirred 1 hour, with the thermodynamically stable microemulsion of spontaneous generation.

X) microcapsules (CS)

Will comprising 5-50 weight % inventive mixture, 0-40 weight % water-insoluble organic solvents (such as aromatic hydrocarbon), The oily phase of 2-15 weight % acrylic monomer (such as methyl methacrylate, methacrylic acid and two-or triacrylate) It is distributed in the aqueous solution of protective colloid (such as polyvinyl alcohol).Shape is led to by the free radical polymerization that radical initiator causes At poly- (methyl) acrylate microcapsules.It or will include 5-50 weight % inventive mixture, 0-40 weight % water-insoluble Organic solvent (such as aromatic hydrocarbon) mutually disperses with the oil of isocyanate-monomer (such as diphenyl methane -4,4 '-diisocyanate) Into the aqueous solution of protective colloid (such as polyvinyl alcohol).It is micro- that addition polyamines (such as hexamethylene diamine) results in polyureas Capsule.Amount of monomer is 1-10 weight %.Weight % is related to entire CS composition.

It xi) can dusting powder (DP, DS)

By the grinding fine crushing of 1-10 weight % inventive mixture and with the solid carrier that adds to 100 weight % it is (such as fine crushing Kaolin) it is sufficiently mixed.

Xii) particle (GR, FG)

By 0.5-30 weight % inventive mixture it is fine crushing grinding and combine add to 100 weight % solid carrier (such as Silicate).It is realized and is granulated by extrusion, spray drying or fluidized bed.

Xiii) ultra low volume liquids (UL)

1-50 weight % inventive mixture is dissolved in the organic solvent (such as aromatic hydrocarbon) for adding to 100 weight %.

Types of compositions i)-xi) it can optionally include other auxiliary agents, such as 0.1-1 weight % fungicide, 5-15 weight % is anti- Freeze agent, 0.1-1 weight % defoaming agent and 0.1-1 weight % colorant.

Gained agrochemical composition generally comprises 0.01-95 weight %, preferably 0.1-90 weight %, especially 0.5-75 Weight % active material.Active material is used with 90-100%, the preferably purity of 95-100% (according to NMR spectra).

In order to handle plant propagation material, especially seed, usually using seed treatment solution (LS), suspension emulsion (SE), flowable concentrate (FS), dry-cure powder (DS), the water-dispersible property powder (WS) of slurry treatment, water-soluble powder (SS), lotion (ES), emulsifiable concentrate (EC) and gel (GF).The composition is after 2-10 times of dilution shortly in preparation Provide 0.01-60 weight %, the preferably active material concentration of 0.1-40 weight %.Application can before planting or period into Row.The method of administration on plant propagation material, especially seed includes breeding material to inventive mixture and combinations thereof respectively Method of administration in seed dressing, coating, granulation, dusting and the immersion of material and ditch dug with a plow.It is preferred that the method by not inducing sprouting, such as Inventive mixture or combinations thereof object is applied on plant propagation material respectively by seed dressing, granulation, coating and dusting.

When in plant protection, the type that the amount of application of active material depends on required effect is 0.001-2kg/ Ha, preferably 0.005-2kg/ha, more preferable 0.01-1.0kg/ha, especially 0.05-0.75kg/ha.

In plant propagation material such as seed for example by usually requiring that activity in dusting, the processing for being coated or being impregnated with seed The amount of substance is 0.01-10kg/100kg, preferably 0.1-1000g/100kg, more preferable 1-100g/100kg plant propagation material (preferred seed).

When being used in protection materials or storage product, the amount of application of active material depends on type and the institute in application region Need effect.Common amount of application is, for example, 0.001g-2kg in material protection, preferably 0.005g-1kg active material/cubic meter Processed material.

It can be to active material or comprising being used as pre-composition to be added or properly make being close in their compositions With (such as the weeding of the various types of oil of preceding addition (bucket mixing), wetting agent, adjuvant, fertilizer or trace nutrient and other pesticides Agent, insecticide, fungicide, growth regulator, safener).These reagents can be with 1:100-100:1, preferably 1:10-10:1 Weight ratio mixed with the present composition.

The present composition is usually used for predose device, musette bag sprayer, aerosol can, spraying airplane or filling by user Irrigate system.Agrochemical composition water, buffer and/or other auxiliary agents are usually formulated into required application concentration, thus It obtains i.e. with spray liquid or agrochemical composition of the present invention.Per hectare agricultural use area usually applies 20-2000 liter, preferably 50-400, which rises, uses spray liquid.

According to an embodiment, user oneself can be used for the container (example of application in aerosol can or any other type Such as seed treatment rotary drum, pellet seeds machine, musette bag sprayer) in mix each component of the present composition, such as complete packet Each section of dress or each section of binary mixture and other auxiliary agents can properly be added.

Therefore, one embodiment of the invention is a kind of packaging kit for preparing useful composition pesticide, the complete packet Dress comprising a) include component 1 as defined herein) and at least one auxiliary agent composition；It and b) include component as defined herein And the composition of at least one auxiliary agent 2)；And it is optional c) comprising at least one auxiliary agent and optional another activity as defined herein Component 3) composition.

As described above, the present invention includes a kind of method for preventing and treating nuisance, wherein being mixed with a effective amount of present invention of pesticide Object processing nuisance, its habitat, breeding spot, its place or plant, soil or the plant to be protected to prevent and treat nuisance invasion Propagation material (preferred seed).

In a preferred embodiment, the present invention includes the method for preventing and treating nuisance, wherein with a effective amount of, pesticide Invention mixture handles plant propagation material (preferred seed).

Of the invention particularly including a kind of method for preventing and treating harmful fungoid, wherein at a effective amount of inventive mixture of pesticide Reason nuisance, its habitat, breeding spot, its place or plant, soil or the plant propagation material to be protected to prevent and treat fungi invasion Expect (preferred seed).

Advantageously, inventive mixture is suitble to prevent and treat following Mycophyta disease: ornamental plant, vegetables (such as white rust And the Albugo (Albugo) on sunflower (such as salsify white rust (A.tragopogonis)) (A.candida)) (white blister)；Vegetables, rape (rape raw rod method (A.brassicola) or alternaria brassica (A.brassicae)), sugar are used Beet (A.tenuis), fruit, rice, soybean, potato (such as early epidemic rod method (A.solani) or rod method (A.alternata)), the Alternaria (Alternaria) on tomato (such as early epidemic rod method or rod method) and wheat (rod method leaf spot)；Aphanomyces (Aphanomyces) on sugar beet and vegetables；Two spore of shell on Cereal and vegetables Belong to (Ascochyta), such as the A.tritici (anthracnose) on wheat and two spore of big wheat husk (A.hordei) on barley；It is flat Navel Helminthosporium (Bipolaris) and Drechslera (Drechslera) (epigamous: cochliobolus category (Cochliobolus)), Such as helminthosporium maydis (Bipolaris maydis (D.maydis)) or leaf blight (Bipolaris zeicola on corn (B.zeicola)) spot blight (wheat root-rot Bipolaris (B.sorokiniana) and, for example, rice and grass, such as on Cereal Rice Bipolaris (B.oryzae) on level ground；(Blumeria is (old for wheat powdery mildew on Cereal (such as wheat or barley) Name: Erysiphe) graminis) (powdery mildew)；Fruit and berry (such as strawberry), vegetables (such as lettuce, carrot, rooted celery Dish and cabbage), rape, flowers, grapevine, the Botrytis cinerea (Botrytis cinerea) on forest plants and wheat (have Property type: Botrytis cinerea (Botryotinia fuckeliana): gray mold)；Lettuce disk on lettuce obstructs mould (Bremia Lactucae) (downy mildew)；Long beak shell category (Ceratocystis) (synonym line mouth shell category on broad leaf tree and evergreen tree (Ophiostoma)) (rot disease or wilt disease), such as the elm wilt (C.ulmi) (Dutch elm disease) on elm；Corn (such as gray leaf spot: corn tail spore bacterium (C.zeae-maydis)), rice, sugar beet (such as the raw tail spore of beet (C.beticola)), sugarcane, vegetables, coffee, soybean (such as Germ To Soybean Frogeye Leaf Spot (C.sojina) or Cercospora kikuchii (C.kikuchii)) Cercospora (Cercospora) (tail spore leaf spot) and on rice；Tomato (such as Cladosporium fulvum ) and the branch spore on Cereal (such as careless bud branch spore (C.herbarum) (ear rot) on wheat) (C.fulvum): leaf mold Belong to (Cladosporium)；Ergot (Claviceps purpurea) (ergot) on Cereal；Corn (the long compacted spore of grey (C.carbonum)), Cereal (such as standing grain cochliobolus (C.sativus), phorozoon: wheat root-rot Bipolaris) and rice (example Such as palace portion cochliobolus (C.miyabeanus), phorozoon: the long compacted spore (H.oryzae) of rice) on cochliobolus category it is (asexual Type: Helminthosporium (Helminthosporium) or Bipolaris) (leaf spot)；Cotton (such as cotton anthracnose bacterium (C.gossypii)), corn (such as standing grain is raw anthrax bacteria (C.graminicola): anthrax stem rot), berry, potato (such as Watermelon anthrax bacteria (C.coccodes): diplostomiasis), Kidney bean (such as bean anthrax bacteria (C.lindemuthianum)) and big Perverse disk spore category on beans (such as Colletotrichum truncatum (C.truncatum) or colletotrichum gloeosporioides Penz (C.gloeosporioides)) (Colletotrichum) (epigamous: GLOMERFLLA CINGULATA Pseudomonas (Glomerella)) (anthracnose)；Corticium Such as rice Shang Bamboo grass wood photovoltaicing leather bacteria (C.sasakii) (banded sclerotial blight) (Corticium),；Cucumber on soybean and ornamental plant is brown Pinta bacterium (Corynespora cassiicola) (leaf spot)；Rust staining germ category (Cycloconium), such as on Chinese olive tree C.oleaginum；Fruit tree, grapevine (such as C.liriodendri, epigamous: Neonectria liriodendri: black foot Disease) and ornamental plant on ginseng give birth to Ramularia (Cylindrocarpon) (such as fruit tree putrefaction disease or grapevine Blackfoot Disease, Epigamous: Nectria (Nectria) or lady's slipper mycorhiza Pseudomonas (Neonectria))；Lineae ablicantes plumage bacterium on soybean (Dematophora (epigamous: Rosellinia) necatrix) (root rot/stem rot)；Northern stem canker Pseudomonas (Diaporthe), the soybean north stem canker (D.phaseolorum) (founding withered ulcer) such as on soybean；Corn, Cereal are such as Barley (such as compacted spore of navel (D.teres) in barley filigree, net blotch) and wheat (such as D.tritici-repentis: foxiness Disease), the Drechslera (synonym Helminthosporium, epigamous: Pyrenophora (Pyrenophora)) on rice and lawn；By spot Brown pore fungi (Formitiporia (synonym Phellinus) punctata), F.mediterranea, Phaeomoniella Chlamydospora (old entitled Phaeoacremonium chlamydosporum), Phaeoacremonium Eschka (Esca) on grapevine caused by aleophilum and/or grape seat chamber bacterium (Botryosphaeria obtusa) (grapevine wilt disease, die back disease)；A kind of fruit, such as apple, pear, etc. (E.pyri), berry (raspberry Elsinochrome (E.veneta): anthracnose) and Portugal Elsinoe (Elsinoe) on grape rattan (grape Elsinochrome (E.ampelina): anthracnose)；Rice leaf smut on rice (Entyloma oryzae) (leaf smut)；Epicoccum (Epicoccum) (smut) on wheat；Sugar beet (beet Powdery mildew (E.betae)), vegetables (such as pea powdery mildew (E.pisi)) such as cucurbitaceous plant (such as two spore powdery mildews (E.cichoracearum)), cabbage, Erysiphe (Erysiphe) (white powder on rape (such as E.cruciferarum) Disease)；In fruit tree, grapevine and ornamental tree side Curvularia lunata (Eutypa lata) (Eutypa canker or wilt disease, phorozoon: Cytosporina lata, synonym Libertella blepharis)；Corn (such as Exserohilum turcicum (E.turcicum)) the prominent navel Helminthosporium (Exserohilum) (synonym Helminthosporium) on；Fusarium on various plants (Fusarium) (epigamous: Gibberella (Gibberella)) (wilt disease, root rot or stem rot), such as Cereal (such as Wheat or barley) on fusarium graminaria (F.graminearum) or machete fusarium (F.culmorum) (root rot, scab Or silver point disease), the sharp fusarium (F.oxysporum) on tomato, the eggplant fusarium (F.solani) on soybean (f.sp.glycines, present synonym are Fusarium virguliforme (F.virguliforme) and respectively cause Wheel on the Fusarium tucumaniae (F.tucumaniae) and F.brasiliense and corn of syndrome of dying suddenly Branch fusarium (F.verticillioides)；Gaeumannomyce on Cereal (such as wheat or barley) and corn (Gaeumannomyces graminis) (full rot)；Cereal (such as Gibberella zeae (G.zeae)) and rice (such as Teng Cang Red mould (G.fujikuroi):Seedling diseases) on Gibberella；Apple anthrax bacteria on grapevine, a kind of fruit, such as apple, pear, etc. and other plant Cotton anthracnose bacterium (G.gossypii) on (Glomerella cingulata) and cotton；Grainstaining on rice complex；Black rot of grape bacterium (Guignardia bidwellii) (black rot) on grapevine；Rosaceous plant and Chinese juniper On Rust (Gymnosporangium), such as the G.sabinae (rust) on pears；Length on corn, Cereal and rice is compacted Spore category (synonym Drechslera, epigamous: cochliobolus category)；Camel spore rest fungus category (Hemileia), such as the coffee on coffee Coffee camel spore rest fungus (H.vastatrix) (coffee leaf rust)；Foxiness on grapevine intends Isaria (Isariopsis Clavispora) (synonym Cladosporium vitis)；Kidney bean shell ball spore (Macrophomina on soybean and cotton Phaseolina (synonym phaseoli)) (root rot/stem rot)；The mould leaf of snow on Cereal (such as wheat or barley) is withered Bacterium (Microdochium (synonym Fusarium) nivale (snow mold)；Diffusion cross hair shell on soybean (Microsphaeradiffusa) (powdery mildew)；On Monilia (Monilinia), such as drupe and other rosaceous plants Drupe chain sclerotinia sclerotiorum (M.laxa), peach brown rot fungus (M.fructicola) and M.fructigena (blossom rot and branch maize ear rot, it is brown Maize ear rot)；Mycosphaerella (Mycosphaerella) on Cereal, banana, berry and peanut, such as the standing grain green-ball chamber on wheat On bacterium (M.graminicola) (phorozoon: wheat septoria (Septoria tritici), septoria musiva leaf spot) or banana Fijian spherical cavity bacterium (M.fijiensis) (Sigatoka black spot)；Cabbage (such as rape downy mildew (P.brassicae)), oil Dish (such as Peronospora parasitic (P.parasitica)), onion (such as shallot downy mildew (P.destructor)), tobacco (Peronospora tabacina (P.tabacina)) Peronospora (the Peronospora) (frost and on soybean (such as downy mildew bacterium (P.manshurica)) Mildew)；Phakopsora pachyrhizi (Phakopsora pachyrhizi) and mountain horseleech layer rest fungus (P.meibomiae) on soybean is (big Soybean rust)；Such as grapevine (such as P.tracheiphila and P.tetraspora) and soybean (such as brown stem rot bacterium (P.gregata): stem rot the Phialophora (Phialophora) on)；Balck shank (Phoma on rape and cabbage Lingam) (root rot, leaf spot and vertical of the beet Phoma sp (P.betae) on (root rot and stem rot) and sugar beet Blight)；Sunflower, grapevine (such as black rot of grape bacterium (P.viticola): dead arm and leaf spot) and soybean (such as stem Maize ear rot: P.phaseoli, epigamous: soybean north stem canker (Diaporthe phaseolorum)) on Phomopsis (Phomopsis)；Maize brown spot bacterium (Physoderma maydis) (brown spot) on corn；Various plants such as green pepper With cucurbitaceous plant (such as Phytophthora capsici (P.capsici)), soybean (such as soybean phytophthora (P.megasperma), synonym P.sojae), potato and tomato (such as phytophthora infestans (P.infestans): late blight) and broad leaf tree (such as robur sudden death Germ (P.ramorum): the anxious dead disease of Oak Tree) on Phytophthora (Phytophthora) (wilt disease, root rot, leaf rot, stem rot Disease and fruit tree putrefaction disease)；Plasmodiophora brassica bacteria (Plasmodiophora on cabbage, rape, radish and other plant Brassicae) (clubroot)；Peronospora (Plasmopara), such as the grape on grapevine are raw uniaxial mould (P.viticola) Plasmopara Halstedll (P.halstedii) in (grapevine downy mildew) and sunflower；Rosaceous plant, hops, a kind of fruit, such as apple, pear, etc. and Podosphaera (Podosphaera) (powdery mildew) on berry, such as the apple mildew bacterium on apple (P.leucotricha)；Such as Cereal such as barley and wheat (Polymyxa Graminis (P.graminis)) and sugar beet (sweet tea The more Acarasiales of dish (P.betae)) on more virus diseases Acarasiales category (Polymyxa) and thus propagated；Cereal such as wheat or On barley wheat Phyllostachys pubescens (Pseudocercosporella herpotrichoides) (eye spot, epigamous: Tapesia yallundae)；Pseudoperonospora (Pseudoperonospora) (downy mildew) on various plants, such as Curcurbitaceae Pseudoperonospora cubensis (P.cubensis) on plant or the humulus grass on hops are false white (P.humili)；On grapevine Pseudopezicula tracheiphila (grape angle variegated leaf coke germ or ' rotbrenner ', phorozoon: Saksenaea (Phialophora))；Puccinia (Puccinia) (rust) on various plants, such as Cereal such as wheat, barley or black Wheat handle rest fungus (P.triticina) (leaf rust or leaf rust) on wheat, bar shaped handle rust (P.striiformis) (striped Disease or yellow rust), barley handle rust (P.hordei) (barley yellow dwarf leaf rust), puccinia graminis (P.graminis) (stem rot Or stalk rust) or puccinia triticinia (P.recondita) (leaf rust or leaf rust), the Puccinia kuehnii on sugarcane (P.kuehnii) the Asparagus handle rust (P.asparagi) in (orange rust) and asparagus；Wheat Yellow variegated leaf on wheat is withered Barley net on germ (Pyrenophora (phorozoon: Drechslera) tritici-repentis) (maculopathy) or barley The compacted spore of navel (P.teres) (net blotch) in spot；Pyricularia Sacc. (Pyricularia), such as the Pyricularia oryzae (P.oryzae) on rice Piricularia oryzae (P.grisea) on (epigamous: Magnaporthe grisea, rice blast) and lawn and Cereal；Grass Level ground, rice, corn, wheat, cotton, rape, sunflower, soybean, sugar beet, (such as the ultimate corruption of vegetables and various other plants Mould (P.ultimum) or melon and fruit corruption are mould (P.aphanidermatum)) on pythium (Pythium) (damping-off)；Column every Spore category (Ramularia), such as R.collo-cygni (pseudomonas sp, physiology leaf spot) and sugar beet on barley On beet leaf spot fungi (R.beticola)；Cotton, rice, potato, lawn, corn, rape, potato, sugar beet, vegetables and Rhizoctonia (Rhizoctonia) on various other plants, such as Rhizoctonia solani Kuhn (R.solani) (root-rot on soybean Disease/stem rot), the R.solani (banded sclerotial blight) on rice or Rhizoctonia cerealis (R.cerealis) (wheat on wheat or barley Banded sclerotial blight)；Rhizopus stolonifer (Rhizopus stolonifer) on strawberry, carrot, cabbage, grapevine and tomato is (black Mildew, soft rot)；Rye beak spore (Rhynchosporium secalis) (moire disease) on barley, rye and triticale；Rice On rice broom branch mould (Sarocladium oryzae) and S.attenuatum (sheath rot disease)；Vegetables and field crop such as oil Dish, sunflower (such as sclerotinite (S.sclerotiorum)) and soybean (such as S.rolfsii or soybean sclerotinia crown rot (S.sclerotiorum)) Sclerotinia (Sclerotinia) (stem rot or southern blight) on；Septoria musiva on various plants Belong to (Septoria), such as the soybean septoria musiva (S.glycines) (brown spot) on soybean, the wheat septoria on wheat (S.tritici) many spores of clever withered shell (S. (synonym Stagonospora) in (septoria musiva leaf spot) and Cereal Nodorum) (spot blight)；Grape snag shell (Uncinula (synonym Erysiphe) necator) (white powder on grapevine Disease, phorozoon: Oidium tuckeri)；Corn (such as Exserohilum turcicum (S.turcicum), the convex navel of the big spot of synonym are compacted Spore (Helminthosporium turcicum)) and lawn on leaf blight Pseudomonas (Setospaeria) (leaf blight)；Corn Axis Ustilago (Sphacelotheca) on (such as silk axis smut (S.reiliana): head smut), millet and sugarcane (smut)；Monofilament shell powdery mildew (Sphaerotheca fuliginea) (powdery mildew) on cucurbitaceous plant；On potato Virus disease powder scab bacterium (Spongospora subterranea) (powdery scab) and thus propagated；Shell on Cereal is more Spore category (Stagonospora), such as many spores of clever withered shell (S.nodorum) (spot blight, epigamous: the withered spherical cavity bacterium of grain husk on wheat (Leptosphaeria [synonym Phaeosphaeria] nodorum))；Synchytrium endobioticum percival on potato (Synchytrium endobioticum) (potato canker)；Exoascus (Taphrina), such as the lopsided external capsule on peach Lee's external capsule bacterium (T.pruni) (cystocarp Lee) on bacterium (T.deformans) (leaf-curl) and Lee；Tobacco, benevolence fruits and vegetables, soybean With the Thiclaviopsis (Thielaviopsis) (black root rot) on cotton, such as black root rot bacterium (T.basicola) (synonym Chalara elegans)；Tilletia (Tilletia) (bunt or the bunt smut of wheat) on Cereal, Such as T.tritici (synonym T.caries, the bunt of wheat) and T.controversa (short bunt on wheat Disease)；Meat spore core coral bacterium (Typhula incarnata) (grey snow mold) on barley or wheat；Ustilago (Urocystis), hidden smut (U.occulta) (smut) such as on rye；Vegetables such as Kidney bean (such as wart top is single Born of the same parents rest fungus (U.appendiculatus), synonym U.phaseoli) and sugar beet (such as rust of beet (U.betae)) On monospore rust belong to (Uromyces) (rust)；Cereal (such as wheat loose smut (U.nuda) and U.avaenae), corn Ustilago (Ustilago) (smut) on (such as Ustilago maydis (U.maydis): smut of maize) and sugarcane； Venturia (Venturia) (scab) on apple (such as scab of apple (V.inaequalis)) and pears；And it is various Verticillium (Verticillium) on plant if tree and ornamental plant, grapevine, slurry fruits and vegetables and field crop is (withered Wither disease), such as the Verticillium wilt (V.dahliae) on strawberry, rape, potato and tomato.

Inventive mixture is also suitable in the protection of storage product or harvest product respectively and prevents in material protection Control harmful fungoid.

Term " material protection " is understood to mean that safeguard industries and nonliving material, such as adhesive, glue, timber, paper With cardboard, textile, leather, paint dispersion, plastics, cooling lubricant, fiber or fabric to prevent harmful microorganism such as fungi and Bacterial invasion and destruction.Protection for timber and other materials, especially it should be noted that following harmful fungoid: Ascomycetes fungi (Ascomycetes), such as line mouth shell category, long beak shell category, Aureobasidium pullulans, Sclerophoma spp., Chaetomium (Chaetomium spp.), Humicola (Humicola spp.), Peter's shell category (Petriella spp.), the mould category of pieces (Trichurus spp.)；Basidiomycetes fungi (Basidiomycetes), such as cellar fungus category (Coniophora Spp.), Coriolus Qu61 (Coriolus spp.) glues gill fungus category (Gloeophyllum spp.), Lentinus (Lentinus Spp.), Pleurotus (Pleurotus spp.), hole of crouching belong to (Poria spp.), Merulius (Serpula spp.) and cheese Pseudomonas (Tyromyces spp.), deuteromycetes fungi (Deuteromycetes), such as aspergillus (Aspergillus Spp.), Cladosporium, Penicillium (Penicillium spp.), trichoderma (Trichorma spp.), Alternaria, Paecilomyces varioti Belong to (Paecilomyces spp.) and Zygomycetes (Zygomycetes) fungi, such as mucor (Mucor spp.), furthermore It should be noted that following yeast fungus in the protection of storage product and harvest product: candida (Candida spp.) and wine brewing Yeast (Saccharomyces cerevisae).

They are in various cultivated plants, such as banana, cotton, greengrocery (such as cucumber, Kidney bean and cucurbit), cereal Class, such as wheat, rye, barley, rice, oat；Dogstail, coffee, potato, corn, fruit, soybean, tomato, grapevine are seen Plant is appreciated, it is especially important to prevent and treat a large amount of fungies in sugarcane and a large amount of seeds.In a preferred embodiment, the present invention mixes Object is used for soybean, Cereal and corn.

As described above, the present invention includes a kind of method for preventing and treating harmful animal nuisance, wherein with a effective amount of, pesticide Invention mixture processing nuisance, its habitat, breeding spot, its place or plant, the soil to be protected to prevent and treat nuisance invasion Earth or plant propagation material (preferred seed).

As described above, inventive mixture also shows the excellent effect for preventing and treating following purpose animal pests:

Lepidoptera (Lepidoptera) insect, such as lesser wax-moth (Achroia grisella), Acleris spp category (Acleris spp.), such as A.fimbriana, western blackhead Acleris spp (A.gloverana), blackhead Acleris spp (A.variana)；Acrolepiopsis assectella, Sang Jian Autographa spp (Acronicta major), Adoxophyessp (Adoxophyes spp.), such as Adoxophyes cyrtosema (A.cyrtosema), smaller apple leafrol- ler (A.orana)；Tired noctuid (Aedia leucomelas), ground Noctua (Agrotis spp.), such as alert line cutworm (A.exclamationis), Yan Qing Cutworm (A.fucosa), black cutworm (A.ipsilon), A.orthogoma, yellow cutworm (A.segetum), A.subterranea；Cotton leaf ripple noctuid (Alabama argillacea), Aleurodicus dispersus (Aleurodicus Dispersus), wave woods geometrid moth (Alsophila pometaria), vine hawk moth (Ampelophaga rubiginosa), Amyelois transitella, Anacampsis sarcitella, Anagasta kuehniella, anarsialineatella (Anarsia lineatella), oak Huang Io moth (Anisota senatoria), tussah (Antheraea pernyi), Dry evil spirit's Noctua (Anticarsia (=Thermesia) spp.), such as Anticarsia (A.gemmatalis)；Apamea spp., Aproaerema modicella, Archips spp (Archips spp.), if tree Huang rolls up moth (A.argyrospila), apricot yellow It rolls up moth (A.fuscocupreanus), rose yellow rolls up moth (A.rosana), A.xyloseanus；Apple silver moth (Argyresthia Conjugella), steinernema category (Argyroploce spp.), Argyrotaenia spp category (Argyrotaenia spp.), such as jack pine Argyrotaenia spp (A.velutinana)；Athetis mindara, Austroasca viridigrisea, gamma (Autographa gamma), stain gamma (Autographa nigrisigna), lopper worm (Barathra Brassicae), Bedellia spp., Bonagota salubricola, Xian hesperid (Borbo cinnara), the cotton shot hole of leaf Lyonetid (Bucculatrix thurberiella), loose looper (Bupalus piniarius), Busseola spp., leaf roller Belong to (Cacoecia spp.), such as fir leaf roller (C.murinana), yellow tail leaf roller (C.podana)；Perforation snout moth's larva (Cactoblastis cactorum), amyloid plaque snout moth (Cadra cautella), Calingo braziliensis, Caloptilis theivora, Capua reticulana, Carposina spp., such as peach fruit moth (C.niponensis), Small heart-eating peach worm (C.sasakii)；Stem bee category (Cephus spp.), Mai Jing great flea beetle (Chaetocnema aridula), winter Geometrid moth (Cheimatobia brumata), straw borer spp (Chilo spp.), such as C.indicus, striped rice borer (C.suppressalis),C.partellus；Choreutis pariana, Choristoneura spp category (Choristoneura spp.), Such as willow Choristoneura spp (C.conflictana), dragon spruce Choristoneura spp (C.fumiferana), the big leaf roller of apple (C.longicellana), European spruce leaf roller (C.murinana), western dragon spruce Choristoneura spp (C.occidentalis), C.rosaceana；Noctua (Chrysodeixis (=Pseudoplusia) spp.), southern three-spotted plusia is such as (C.eriosoma), soybean looper (C.includens)；Mythimna separata (Cirphis unipuncta), grape codling moth (Clysia ambiguella) (Clysia Ambiguella), Cnaphalocerus spp., cnaphalocrocis medinalls guenee (Cnaphalocrocis medinalis), cloud roll up moth Belong to (Cnephasia spp.), sunflower moth (Cochylis hospes), casebearer moth (Coleophora spp.), Colias Eurytheme, the tapering moth category of tea branch (Conopomorpha spp.), Conotrachelus spp., Copitarsia spp., Rice snout moth's larva (Corcyra cephalonica), corn root web spinner (Crambus caliginosellus), annual bluegrass crambid (Crambus teterrellus), Crocidosema (=Epinotia) aporema, Cydalima (=Diaphania) Perspectalis, steinernema category (Cydia (=Carpocapsa) spp.), such as codling moth (C.pomonella), nut Leaf roller (C.latiferreana)；Dalaca noctuides, walnut match piece boat moth (Datana integerrima), Dasychira pinicola, Dendrolimus (Dendrolimus spp.), such as dendrolimus pini (D.pini), dendrolimus spectabilis (D.spectabilis), dendrolimus sibiricus (D.sibiricus)；Grape small leaf open country snout moth's larva (Desmia funeralis), Diaphania spp., such as yellow Diaphania indica (D.nitidalis), sweet tea Diaphania indica (D.hyalinata)；Southwest Maize bar grass Snout moth's larva (Diatraea grandiosella), small sugarcane borer (Diatraea saccharalis), Diphthera festiva, Buddha's warrior attendant It bores and belongs to (Earias spp.), such as Egyptian to bore noctuid (E.insulana), earias fabia (E.vittella)；Ecdytolopha Aurantianu, Egira (=Xylomyges) curialis, South America maize seedling phycitid (Elasmopalpus Lignosellus), sugarcane borer (Eldana saccharina), grape-berry moth (Endopiza viteana), elm Autumn Huang geometrid moth (Ennomos subsignaria), Mexico's rice borer (Eoreuma loftini), meal moth category (Ephestia Spp.), such as dry fruit meal moth (E.cautella), tobacco powder sp (E.elutella), Anagasta kuehniella (E.kuehniella)；Night steinernema (Epinotia aporema), the brown volume moth of apple (Epiphyas postvittana), Bodhisattva It mentions loose geometrid moth (Erannis tiliaria), any of several broadleaf plants is hesperided (Erionota thrax), snout moth category (Etiella spp.), Eulia Spp., ligustrum fine tortricidae (Eupoecilia ambiguella), pornography and drug moth (Euproctis chrysorrhoea), cuts noctuid Belong to (Euxoa spp.), Evetria bouliana, Faronta albilinea, Noctua (Feltia spp.), such as grain skin Ground tiger (F.Subterranean)；Galleria mellonella waxmoth (Galleria mellonella), Gracillaria spp., heart-eating worm category (Grapholita spp.), such as Lee's Grapholita spp (G.funebrana), oriental fruit months (G.molesta), the small food heart of apple Worm (G.inopinata)；Halysidota spp., black quasi- sandfly moth (Harrisina americana), Hedylepta spp., Genus heliothis (Helicoverpa spp.), such as bollworm (H.armigera (=Heliothis armigera)), America cotton Earworm (H.zea (=Heliothis zea))；Heliothis (Heliothis spp.), such as Heliothis assulta (H.assulta)), H.subflexa, tobacco budworm (H.virescens)；Hellula spp., such as Hellula undalis (H.undalis), Oeobia undalis (H.rogatalis)；Helocoverpa gelotopoeon, Hemileuca oliviae, Herpetogramma Licarsisalis, Hibernia defoliaria, it is brown to knit moth (Hofmannophila pseudospretella), sunflower Same phycitid (Homoeosoma electellum), Homonamagnanima (Homona magnanima), Hypena scabra, the U.S. are white Moth (Hyphantria cunea), cherry ermine moth (Hyponomeuta padella), apple ermine moth (Hyponomeuta Malinellus), persimmon fruit moth (Kakivoria flavofasciata), tomato worm moth (Keiferia Lycopersicella), hemlock looper moth (Lambdina fiscellaria fiscellaria), western hemlock geometer (Lambdina fiscellaria lugubrosa), bean pyralid (Lamprosema indicata), moth-eaten heart-eating worm (Laspeyresia molesta), eating-core bean worm (Leguminivora glycinivorella), Lerodea eufala, Leucinodes orbonalis is avenged poison moth (Leucoma salicis), leaf miner category (Leucoptera spp.), such as coffee Leaf miner (L.coffeella), pear leaf blister moth (L.scitella)；Leuminivora lycinivorella, apple spot curtain are latent Leaf moth (Lithocolletis blancardella), green fruit winter noctuid (Lithophane antennata), Llattia Octo (=Amyna axis), grape berry steinernema (Lobesia botrana), Lophocampa spp., beans Bai Longqiegen Worm (Loxagrotis albicosta), Loxostege spp., such as beet webworm (L.sticticalis), L.cereralis；Euproctis (Lymantria spp.), such as gypsymoth (L.dispar), lymantria monacha (L.monacha)；Peach is latent Moth (Lyonetia clerkella), Lyonetia prunifoliella, Malacosoma (Malacosoma spp.), such as Apple tent caterpillar (M.americanum), grassland tent caterpillar (M.californicum), forest tent caterpillar (M.constrictum), malacosoma neustria (M.neustria)；Lopper worm category (Mamestra spp.), such as lopper worm (M.brassicae), bud band noctuid (M.configurata)；Mamstra brassicae, Manduca spp., such as tomato day Moth (M.quinquemaculata), maduca sexta (M.sexta)；The wild snout moth's larva category (Marasmia spp) of brush palpus, Marmara Spp., beans open country snout moth's larva (Maruca testulalis), Megalopyge lanata, Melanchra picta, declining satyrid (Melanitis leda), Mocis spp., such as M.lapites, rice hair shin noctuid (M.repanda)；Mocis latipes, Monochroa fragariae, mythimna separata (Mythimna separata), Nemapogon cloacella, Neoleucinodes Elegantalis, pseudo- geometrid moth category (Nepytia spp.), Nymphula spp., Oiketicus spp., beans nibble leaf open country snout moth's larva (Omiodes indicata), Sweet Potato snout moth's larva (Omphisa anastomosalis), winter geometer (Operophtera Brumata), Douglas fir closes poison moth (Orgyia pseudotsugata), Oria spp., Orthaga thyrisalis, stalk open country snout moth's larva Belong to (Ostrinia spp.), such as European corn borer (O.nubilalis)；Rice leaf beetles (Oulema oryzae), apple geometrid moth (Paleacrita vernata), small noctuid (Panolis flammea), Parnara (Parnara spp.) are common to eat into Stem noctuid (Papaipema nebris), big swallowtail butterfly (Papilio cresphontes), navel orange snout moth (Paramyelois Transitella), grape clearwing moth (Paranthrene regalis), no palm butterfly moth (Paysandisia archon), Corn earworm category (Pectinophora spp.), such as colored corn earworm (P.gossypiella)；Boundary noctuid (Peridroma saucia), Leaf miner category (Perileucoptera spp.), such as coffee leafminer (P.coffeella)；Circle palm boat moth (Phalera Bucephala), Phryganidia californica, cigarette geometrid moth category (Phthorimaea spp.), such as potato tuberworm (P.operculella)；Citrus leaf-miner (Phyllocnistis citrella), leaf miner category (Phyllonorycter Spp.), such as spot curtain leaf miner (P.blancardella), hawthorn leaf miner (P.crataegella), P.issikii, Jin Wenxi Moth (P.ringoniella)；Pieris spp (Pieris spp.), such as Pieris brassicae (P.brassicae), cabbage butterfly (P.rapae), green arteries and veins cabbage butterfly (P.napi)；Pilocrocis tripunctata, the green noctuid (Plathypena of clover Scabra), Platynota spp., such as P.flavedana, P.idaeusalis, P.stultana；Carnation steinernema (Platyptilia carduidactyla), beans hairstreak (Plebejus argus), Indian meal moth (Plodia Interpunctella), Plusia spp, diamond-back moth (Plutella maculipennis), diamondback moth (Plutella Xylostella), Pontia protodica, Prays spp., spodoptera (Prodenia spp.), 2 committee noctuid insect (Proxenus lepigone), mythimna separata category (Pseudaletia spp.), such as P.sequax, a star mythimna separata (P.unipuncta)；Corn borer (Pyrausta nubilalis), Rachiplusia nu, Richia albicosta, Rhizobius ventralis, Rhyacionia frustrana, Sabulodes aegrotata, Schizura Concinna, Schoenobius spp., Schreckensteinia festaliella, white standing grain snout moth's larva category (Scirpophaga Spp.), such as yellow rice borer (S.incertulas), S.innotata；Scotia segetum, pink rice borer category (Sesamia spp.), Such as Rice ragged stunt virus (S.inferens), grape repairs tiger moth (Seudyra subflava), gelechiid (Sitotroga Cerealella), grape berry moth (Sparganothis pilleriana), Spilonota lechriaspis, apple are small It rolls up moth (S.ocellana), Spodoptera (Spodoptera (=Lamphygma) spp.), such as S.cosmoides, S.eridania, beet armyworm (S.exigua), fall army worm (S.frugiperda), S.latisfascia, extra large spodoptera (S.littoralis), prodenia litura (S.litura), yellow mythimna separata (S.omithogalli)；Stigmella spp., Stomopteryx subsecivella, Strymon bazochii, Notarchaderogata (Sylepta derogata), Synanthedon spp., such as small peach wing moth (S.exitiosa), Tecia solanivora, Telehin licus, Thaumatopoea pityocampa, Thaumatotibia (=Cryptophlebia) leucotreta, Song Yizhou moth (Thaumetopoea pityocampa), Thecla spp., Theresimima ampelophaga, Thyrinteina Spp, Tildenia inconspicuella, Tinea spp., such as T.cloacella, bag rain moth (T.pellionella)；Curtain Rain moth (Tineola bisselliella), Tortrix spp., such as the green volume moth (T.viridana) of oak；Hair quivers moth (Trichophaga tapetzella), Trichoplusiaspp (Trichoplusia spp.), such as cabbage looper (T.ni)；Tuta (= Scrobipalpula) absoluta, (Udea spp., such as the wild snout moth's larva (U.rubigalis) of greenhouse netting, the wild snout moth's larva of greenhouse netting (U.rubigalis)；Virachola spp., apple ermine moth (Yponomeuta padella) and Zeiraphera canadensis；

Coleoptera (Coleoptera) insect, such as Acalymma vittatum, acanthoscelides obtectus (Acanthoscehdes Obtectus), beak rutelian category (Adoretus spp.), poplar firefly is chrysomelid (Agelastica alni), Agrilus spp., Such as A.anxius, A.planipennis, the narrow lucky fourth (A.sinuatus) of pears；Click beetle category (Agriotes spp.), such as thin chest are kowtowed Cephalont (A.fuscicollis), click beetle (A.lineatus), dark-coloured click beetle (A.obscurus)；Alphitobius Rutelian (Anisoplia fills in diaperinus, Amphimallus solstitialis, Anisandrus dispar, state difficult to understand Austriaca), furniture death watch beetle (Anobium punctatum), verdigris different beetle (Anomala corpulenta), red metal Rutelian (Anomala rufocuprea), Genus Anoplophora Hope (Anoplophora spp.), such as anoplophora glabripennis (A.glabripennis)；Anthonomus spp category (Anthonomus spp.), such as pepper flea beetle (A.eugenii), anthonomus grandis (A.grandis), apple flower is as (A.pomorum)；Anthrenus (Anthrenus spp.), Aphthona euphoridae, pears As category (Apion spp.), Ah gill cockchafer category (Apogonia spp.), Athous haemorrhoidalis, hidden wing first category (Atomaria spp.), such as Atomaria linearis (A.linearis)；Fur moth category (Attagenus spp.), aulacophora femoralis (Aulacophora femoralis), vertical pit cutting pin small moth (Blastophagus piniperda), Blitophaga Undata, Bruchidius obtectus, bean weevil category (Bruchus spp.), such as European Lens culinaris is as (B.lentis), pea weevil (B.pisorum), broad bean weevil (B.rufimanus)；Apple is rolled up as (Byctiscus betulae), Callidiellum Rufipenne, Callopistria floridensis, Callosobruchus chinensis (Callosobruchus chinensis), Cameraria Ohridella, Cassida nebulosa (Cassida nebulosa), beans are chrysomelid (Cerotoma trifurcata), golden flower cockchafer (Cetonia aurata), ceutorhynchus (Ceuthorhynchus spp.), if Chinese cabbage seed tortoise is as (C.assimilis), blister beetle tortoise As (C.napi)；Beet shin flea beetle (Chaetocnema tibialis), Cleonus mendicus, wide chest Agriotes spp (Conoderus spp.), such as tobacco wireworm (C.vespertinus)；Conotrachelus nenuphar, rootstock is as belonging to (Cosmopolites spp.), New Zealand meadow grub (Costelytra zealandica), asparagus scotellaris (Crioceris asparagi), positive rusty grain beetle (Cryptolestes ferrugineus), Yang Ganyin beak as (Cryptorhynchus lapathi), Ctenicera spp., such as C.destructor；Curculio (Curculio spp.), Cylindrocopturus spp., Cyclocephala spp., corn dicladispa armigera (Dactylispa balyi), stem borer (Dectes texanus), khapra beetle category (Dermestes spp.), chrysomelid category (Diabrotica spp.), such as to star ladybug (D.undecimpunctata), South America is chrysomelid (D.speciosa), northern corn root-worm (D.longicornis), D.semipunctata, diabroticavirgifera (D.virgifera)；Mandarin orange Ju weevil (Diaprepes abbreviates), surname Wild snout moth's larva category (Dichocrocis spp.), rice dicladispa armigera (Dicladispa armigera), Argentinian pocket worm (Diloboderus Abderus), Diocalandra frumenti (Diocalandra stigmaticollis), Enaphalodes Rufulus, epilachna genus (Epilachna spp.), such as mexican bean ladybird (E.varivestis), potato bug (E.vigintioctomaculata)；Hair phyllotreta (Epitrix spp.), as tobacco flea beetle (E.hirtipennis), E.similaris；Eutheola humilis, cotton ash are covered as mutation (Eutinobothrus brasiliensis), and tobacco is bored Hole worm (Faustinus cubae), Gibbium psylloides, Gnathocerus cornutus, Oeobia undalis (Hellula Undalis), African xylotrupes dichotomus (Heteronychus arator), Hylamorpha elegans, European hylobius abietis (Hylobius abietis), house longhorn beetle (Hylotrupes bajulus), Hypera spp., such as Egyptian cloverleaf as (H.brunneipennis), alfalfa leaf is as (H.postica)；Green squama weevil (Hypomeces squamosus), fruit bark beetle Belong to (Hypothenemus spp.), ips typographus (Ips typographus), Lachnosterna Consanguinea, lasioderma serricorne (Lasioderma serricorne), Latheticus oryzae, Lathridius spp., Lema spp., such as tobacco scotellaris (L.bilineata), black angle scotellaris (L.melanopus)；Colorado potato beetles category (Leptinotarsa spp.), such as colorado potato beetles (L.decemlineata)；Leptispa pygmaea, beet click beetle (Limonius californicus), rice water weevil (Lissorhoptrus oryzophilus), cylinder beak is as category (Lixus Spp.), Luperodes spp., powder moth category (Lyctus spp.), such as Lyctus brunneus Stephens (L.bruneus)；Liogenys fuscus, Hallux toe category (Macrodactylus spp.), such as M.subspinosus；Ma thin,tough silk cockchafer (Maladera matrida), Megaplatypus mutates, Megascelis spp., Melanotus communis, cauliflower nitidulid category (Meligethes spp.), such as rape nitidulid (M.aeneus)；Melolontha spp., such as great Li gill cockchafer (M.hippocastani), the gill in May cockchafer (M.melolontha)；Western India sugarcane borer (Metamasius hemipterus), Microtheca spp., Migdolus spp., such as M.fryanus, black day Bos (Monochamus spp.), such as Song Motian Ox (M.alternatus)；Naupactus xanthographus, golden spider beetle (Niptus hololeucus), Oberia Brevis, Oemona hirta, coconut palm eat into rhinoceros cockchafer (Oryctes rhinoceros), saw-toothed grain beetle (Oryzaephilus Surinamensis), Oryzaphagus oryzae, black grape ear image (Otiorrhynchus sulcatus), strawberry root as First (Otiorrhynchus ovatus), black grape ear image (Otiorrhynchus sulcatus), Oulema melanopus, Oulema oryzae (Oulema oryzae), small blue and white cockchafer (Oxycetonia jucunda), Phaedon spp., such as apelet Leaf worm (P.brassicae), horseradish ape are chrysomelid (P.cochleariae)；Phoracantha recurva, leaf of pear tree as Rutelian (Phyllopertha horticola) is sent out in (Phyllobius pyri), flower garden, eats phyllobranchia cockchafer category (Phyllophaga spp.), such as P.helleri；Phyllotreta (Phyllotreta spp.), as P.chrysocephala, The light sufficient flea beetle (P.nemorum) of soybean, Phyllotreta striolata (P.striolata), yellow slat flea beetle (P.vittula)；Flower garden It sends out rutelian (Phyllopertha horticola), Japanese beetle (Popillia japonica), Cylas (Premnotrypes spp.), Psacothea hilaris, rape blue flea beetle (Psylliodes chrysocephala), greatly Lesser grain borer (Prostephanus truncates), Psylliodes spp., Ptinus (Ptinus spp.), Pulga Saltona, lesser grain borer (Rhizopertha dominica), it is reddish brown belong to (Rhynchophorus spp., such as R.billineatus, Red plam weevil (R.ferrugineus), palm weevil (R.palmarum), R.phoenicis, R.vulneratus；Saperda Candida, Scolytus schevyrewi, Scyphophorus acupunctatus, pea leaf is as (Sitona Lineatus), grain weevil category (Sitophilus spp.), grain weevil (S.granaria), rice weevil (S.oryzae), sitophilus zea-mais (S.zeamais)；Sharp Rhynchophorus (Sphenophorus spp.), such as S.levis；Stegobium paniceum, stem as Belong to (Sternechus spp.), such as S.subsignatus；Strophomorphus ctenotus, Symphyletes spp., Tanymecus spp., yellow meal worm (Tenebrio molitor), Tenebrioides mauretanicus；Tribolium (Tribolium spp.), such as red flour beetle (T.castaneum)；Spot khapra beetle category (Trogoderma spp.), seed are as belonging to (Tychius spp.), Xylotrechus Chevrolat (Xylotrechus spp.), such as X.pyrrhoderus；And zabrus category (Zabrus spp.), such as Z.Tenebrioides)；

Diptera (Diptera) insect, such as Aedes spp., such as Aedes aegypti (A.aegypti), aedes albopictus (A.albopictus), perverse to disturb yellow-fever mosquito (A.vexans)；Mexfly (Anastrepha ludens)；Anopheles (Anopheles spp.), such as white sufficient anopheles (A.albimanus), anopheles crucians (A.crucians), Fei Shi anopheles (A.freeborni), anopheles costalis (A.gambiae), anopheles leucosphyrus leucosphyrus (A.leucosphyrus), anopheles maculipennis (A.maculipennis), anopheles minius (A.minimus), anopheles quadrimaculatus (A.quadrimaculatus), Anopheles sinensis (A.sinensis)；Bactrocera invadens, garden march fly (Bibio hortulanus), bluebottle (Calliphora Erythrocephala), calliphora erythrocephala (Calliphora vicina), Mediterranean fruitfly (Ceratitis capitata), gold Fly category (Chrysomyia spp.), such as chrysomyabezziana (C.bezziana), C.hominivorax, chrysomyia macellaria (C.macellaria)；Chrysops atlanticus, deerfly (Chrysops discalis), chrysops silacea (Chrysops Silacea), Callitroga (Cochliomyia spp.), such as screwfly (C.hominivorax)；Cecidomyiia category (Contarinia Spp.), such as sorghum cecidomyiia (C.sorghicola)；Cordylobia anthropophaga maggot (Cordylobia anthropophaga), Culex (Culex spp.), such as spot mosquito (C.nigripalpus), northern house (C.pipiens), Culex quinquefasciatus (C.quinquefasciatus), matchmaker's spot mosquito (C.tarsalis), Culex tritaeniorhynchus (C.tritaeniorhynchus)；It is furious Storehouse midge (Culicoides furens), no decorations arteries and veins march fly (Culiseta inornata), culiseta melanura (Culiseta Melanura), Cuterebra (Cuterebra spp.), melon fly (Dacus cucurbitae), dacus oleae (Dacus Oleae), rape leave cecidomyiia (Dasineura brassicae), Dasineura oxycoccana, Delia (Delia Spp.), such as onion fly (D.antique), wheat field Hylemyia Platura Meigen (D.coarctata), delia platura (D.platura), wild cabbage ground Hylemyia Platura Meigen (D.radicum)；Dermatobia hominis (Dermatobia hominis), Drosophila (Drosophila spp.), such as spotted wing drosophila (D.suzukii), Fannia (Fannia spp.), such as small Mao latrine fly (F.canicularis)；Gasterophilus (Gastraphilus Spp.), such as horse botfly (G.intestinalis)；Geomyza tipunctata, Glossina spp., such as G.fuscipes, thorn Tsetse fly (G.morsitans), glossina palpalis (G.palpalis), glue tsetse fly (G.tachinoides), Haematobia irritans (Haematobia Irritans), Haplodiplosis equestris, Hippelates (Hippelates spp.), Hylemyia (Hylemyia Spp.), such as Peanut Fields delia platura (H.platura)；Hypoderma (Hypoderma spp.), such as heel fly (H.lineata)； Hyppobosca spp., rice phenanthrene island hair eye ephydrid (Hydrellia philippina), Leptoconops torrens, Liriomyza spp., such as Americal rice leaf miner (L.sativae), U.S. Liriomyza (L.trifolii)；Lucilia spp., such as L.caprina, lucilia cuprina (L.cuprina), lucilia sericata (L.sericata)；Lycoria pectoralis, Mansonia Titillanus, Mayetiola spp., such as wheat cecidomyiia (M.destructor)；Musca spp., such as face fly (M.autumnalis), housefly (M.domestica)；False stable fly (Muscina stabulans)；Oestrus spp., such as sheep Botfly (O.ovis)；Opomyza florum, Oscinella spp., such as Oscinella frit (O.frit)；Pachydiplosis oryzae (Orseolia oryzae), henbane seed spring fly (Pegomya hysocyami), phlebotomus argentipes (Phlebotomus Argentipes), Phorbia (Phorbia spp.), such as onion fly (P.antiqua), radish fly (P.brassicae), wheat field Hylemyia Platura Meigen (P.coarctata)；Phytomyza gymnostoma, Prosimulium mixtum, carrot fly (Psila Rosae), Psorophora columbiae (Psorophora columbiae), Psorophora discolor, Rhagoletis Spp., such as cherry fruit fly (R.cerasi), R.cingulate, R.indifferens, R.mendax, Rhagoletis pomonella (R.pomonella)；Rivellia quadrifasciata, Sarcophaga (Sarcophaga spp.), such as Sarcophaga haemorrhoidalis (S.haemorrhoidalis)；Band buffalo gnat (Simulium vittatum), Sitodiplosis mosellana, Genus Stomoxys (Stomoxys spp.), such as tatukira (S.calcitrans)；Gadfly (Tabanus spp.), such as tabanus atratus (T.atratus), the gadfly (T.bovinus), red former horsefly (T.lineola), two caterpillars (T.similis)；Tannia Spp., Thecodiplosis japonensis, Tipula oleracea, European daddy-longlegs (Tipula paludosa) and dirty fly Belong to (Wohlfahrtia spp.)；

Thysanoptera (Thysanoptera) insect, such as rice thrips (Baliothrips biformis), orchid thrips (Dichromothrips corbetti), Dichromothrips ssp., Echinothrips americanus, Enneothrips flavens, flower thrips category (Frankliniella spp.), such as cigarette brown thrip (F.fusca), honeysuckle Ji Horse (F.occidentalis), east flower thrips (F.tritici)；Heliothrips (Heliothrips spp.), greenhouse thrips (Hercinothrips femoralis), card Thrips (Kakothrips spp.), Microcephalothrips Abdominalis, Neohydatothrips samayunkur, Pezothrips kellyanus, the prominent wrinkle needle thrips of abdomen (Rhipiphorothrips cruentatus), hard Thrips (Scirtothrips spp.), such as the hard thrips of tangerine (S.citri), S.dorsalis, S.perseae；Stenchaetothrips spp, Taeniothrips cardamoni, Taeniothrips inconsequens；Thrips (Thrips spp.), such as T.imagines, T.hawaiiensis, rice Ji Horse (T.oryzae), palm thrips (T.palmi), T.parvispinus, onion thrips (T.tabaci)；

Semiptera (Hemiptera) insect, such as silk tree wood louse (Acizzia jamatonica), Acrosternum Spp., such as quasi- acrosternumhilare (A.hilare)；Without net long tube Aphis (Acyrthosipon spp.), such as A.onobrychis, acyrthosiphum pisim (A.pisum)；Adelge laricis (Adelges laricis), Adelges tsugae, Adelphocoris spp., such as A.rapidus, A.superbus；Foam bee category (Aeneolamia spp.), Aphalaridae (Agonoscena spp.), eggplant without Net aphid (Aulacorthum solani), Aleurocanthus woglumi, white powder Pediculus (Aleurodes spp.), Aleurodicus disperses, sugarcane cave aleyrodid (Aleurolobus barodensis), velvet Aleyrodes (Aleurothrixus spp.) , Mango leafhopper category (Amrasca spp.), squash bug (Anasa tristis), intends beautiful stinkbug Belong to (Antestiopsis spp.), Anuraphis cardui, kidney Aspidiotus category (Aonidiella spp.), pears tumor aphid (Aphanostigma piri), Aphidula nasturtii, Aphis (Aphis spp.), such as A.craccivora, aphis fabae (A.fabae), strawberry root aphid (A.forbesi), cotten aphid (A.gossypii), North America currant aphid (A.grossulariae), A.maidiradicis, apple aphid (A.pomi), elder aphid (A.sambuci), Xi Naide aphid (A.schneideri), leaf roll Aphid (A.spiraecola)；Grape Ah jassids (Arboridia apicalis), wheel bug (Arilus critatus), Roundlet armored scale category (Aspidiella spp.), Aspidiotus category (Aspidiotus spp.), Atanus spp., Aulacaspis Yasumatsui, eggplant is without net aphid (Aulacorthum solani), Bactericera cockerelli (Paratrioza Cockerelli), Aleyrodes (Bemisia spp.), such as Bemisia argentifolii (B.argentifolii), Bemisia tabaci (B.tabaci (Aleurodes tabaci))；Native chinch bug category (Blissus spp.), such as chinch bug (B.leucopterus)； Brachycaudus spp., such as welted thistle short-tail aphid (B.cardui), Lee's short-tail aphid (B.helichrysi), peach short-tail aphid (B.persicae), B.prunicola；Micro-pipe Aphis (Brachycolus spp.), Brachycorynella asparagi, Brevicoryne brassicae (Brevicoryne brassicae), Cacopsylla spp., such as C.fulguralis, C.pyricola (pear wood Lice (Psylla piri))；Small brown back rice plant hopper (Calligypona marginata), pretty fleahopper category (Calocoris spp.), spot Leg aculea fleahopper (Campylomma livida), Capitophorus horni, Carneocephala fulgida, different back are long Stinkbug category (Cavelerius spp.), Ceraplastes spp., Ceratovacuna lanigera, Ceroplastes Ceriferus, Cerosipha gossypii, Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Cimex spp., such as cimex hemipterus (C.hemipterus), bed bug (C.lectularius)；Coccomytilus Halli, soft a red-spotted lizard category (Coccus spp.), such as C.hesperidum, C.pseudomagnoliarum；Corythucha Arcuata, Creontiades dilutus, the hidden tumor aphid of currant (Cryptomyzus ribis), Chrysomphalus Aonidum, the hidden tumor aphid of tea Fischer (Cryptomyzus ribis), Ctenarytaina spatulata, blackspot cigarette fleahopper (Cyrtopeltis notatus), Dalbulus spp., pepper coried (Dasynus piperis), aleyrodid (Dialeurades spp.), such as D.citrifolii；Dalbulus maidis, Psylla spp (Diaphorina spp.), such as D.citri；White back armored scale category (Diaspis spp.), such as D.bromeliae；Dichelops furcatus, Hou Shi long stick net Stinkbug (Diconocoris hewetti), Doralis spp., abies nordmanniana vertebra adelgid (Dreyfusia Nordmannianae), dragon spruce vertebra adelgid (Dreyfusia piceae) is carried out giant coccid category (Drosicha spp.)；Western rounded tail aphid Belong to (Dysaphis spp.), such as Chinese herbaceous peony rounded tail aphid (D.plantaginea), the western rounded tail aphid (D.pyri) of pears, Ju Genxi rounded tail aphid (D.radicola)；Dysaulacorthum pseudosolani；Red cotton bug category (Dysdercus spp.), such as red cotton bug (D.cingulatus),D.intermedius；Grey mealybug category (Dysmicoccus spp.), Edessa spp., Geocoris Spp., Empoasca flavescens (Empoasca spp.), such as semen viciae fabae Empoasca spp (E.fabae), the small greenery butterfly of Suo Lana (E.solana)；Epidiaspis leperii, woolly aphid category (Eriosoma spp.), such as E.lanigerum, E.pyricola； Erythroneura spp category (Erythroneura spp.)；Eurygasterspp category (Eurygaster spp.), such as wheat Eurygasterspp (E.integriceps)；Blunt nose leaf cicada (Euscelis bilobatus), America stinkbug category (Euschistus spp.), such as soybean Brown Chinese toon (E.heros), tobacco stinkbug (E.impictiventris), brown smelly stinkbug (E.servus)；Fiorinia theae, coffee Mealybug (Geococcus coffeae), Glycaspis brimblecombei；Eating attraction category (Halyomorpha spp.), such as Eating attraction (H.halys)；The blind Chinese toon in angle (Heliopeltis spp.), glass leafhopper (Homalodisca vitripennis (= H.coagulata)), Horcias nobilellus, the big tail aphid of Lee (Hyalopterus pruni), the super tumor aphid of tea Fischer Chinese Ixeris (Hyperomyzus lactucae), icerya purchasi category (Icerya spp.), such as I.purchase；Piece angle leafhopper category (Idiocerus spp.), flat beak leafhopper category (Idioscopus spp.), small brown rice planthopper (Laodelphax striatellus), Lecanium category (Lecanium spp.), Lecanoideus floccissimus, lepidosaphes shimer (Lepidosaphes spp.), such as L.ulmi；Leptocorisa spp category (Leptocorisa spp.), the red bell beak coried of cotton (Leptoglossus phyllopus), radish aphid (Lipaphis erysimi), Lygus Hahn (Lygus spp.), such as lygus bug (L.hesperus), America tarnished plant bug (L.lineolaris), tarnished plant bug (L.pratensis)；Maconellicoccus hirsutus, Marchalina Hellenica, the black chinch bug of sugarcane (Macropes excavatus), long tube Aphis (Macrosiphum spp.), such as rose long tube Aphid (M.rosae), grain aphid (M.avenae), root of Beijing euphorbia Macrosiphus spp (M.euphorbiae)；Macrosteles Quadrilineatus, Mahanarva fimbriolata are sieved beans tortoise stinkbug (Megacopta cribraria), and nest Lay repairs tail aphid (Megoura viciae), Melanaphis pyrarius, kaoliang aphid (Melanaphis sacchari)；Melanocallis (=Tinocallis) caryaefoliae, Metcafiella spp., wheat without net aphid (Metopolophium dirhodum), The black flat wing spot aphid of edge (Monellia costalis), Monelliopsis pecanis；Myzocallis coryli, Murgantia spp., tumor aphid genus (Myzus spp.), as shallot aphid (M.ascalonicus), Lee's tumor aphid (M.cerasi), M.nicotianae, black peach aphid (M.persicae), airpotato yam tumor aphid (M.varians)；Blackcurrant patches up Macrosiphus spp (Nasonovia ribis-nigri), Neotoxoptera formosana, Neomegalotomus spp, rice green leafhopper category (Nephotettix spp.), as Malaya rice green leafhopper (N.malayanus), two rice green leafhoppers (N.nigropictus), Tiny rice green leafhopper (N.parvus), nephotettix bipunctatus (N.virescens)；Bemisia spp (Nezara spp.), such as green rice bug (N.viridula)；Brown paddy plant hopper (Nilaparvata lugens), Nysius huttoni, rice stinkbug category (Oebalus spp.), Such as O.pugnax；Oncometopia spp., Orthezia praelonga, Oxycaraenus hyalinipennis, red bayberry Aleyrodid (Parabemisia myricae), Parlatoria (Parlatoria spp.), Parthenolecanium spp., such as P.corni,P.persicae；Pemphigus (Pemphigus spp.), as suspensor goitre woolly aphid (P.bursarius), P.populivenae；Com planthopper (Peregrinus maidis), sugarcane plant hopper (Perkinsiella saccharicida), Phenacoccus (Phenacoccus spp.), such as P.aceris, P.gossypii；Yang Ping wing woolly aphid (Phloeomyzus Passerinii), phorodon aphid (Phorodon humuli), grape phylloxera category (Phylloxera spp.), such as P.devastatrix；Beet is intended lace bug (Piesma quadrata), wall stinkbug category (Piezodorus spp.), such as P.guildinii；The brown point of sago cycas and armored scale (Pinnaspis aspidistrae), stern line mealybug category (Planococcus Spp.), such as P.citri, P.ficus；Prosapia bicincta, pyriform original giant coccid (Protopulvinaria Pyriformis), cotton puppet spot leg fleahopper (Psallus seriatus), Pseudacysta persea, Pseudaulacaspis pentagona (Pseudaulacaspis pentagona), mealybug category (Pseudococcus spp.), such as Kang Shi mealybug (P.comstocki)；Psylla spp (Psylla spp.), such as apple sucker (P.mali)；Tiny golden wasp category (Pteromalus spp.), Pulvinaria amygdali, Pyrilla spp., large bamboo hat with a conical crown and broad brim Aspidiotus category (Quadraspidiotus spp.), such as Q.perniciosus；Quesada gigas puts down and pierces mealybug category (Rastrococcus spp.), Reduvius senilis, Rhizoecus americanus, Rhodnius (Rhodnius spp.), shallot tumor moth aphid (Rhopalomyzus ascalonicus)；Rhopalosiphum (Rhopalosiphum spp.), as radish aphid (R.pseudobrassicas), apple grass are hung Pipe aphid (R.insertum), corn leaf aphids (R.maidis), rhopalosiphum padi (R.padi)；Sagatodes spp., cocoa are brown blind Stinkbug (Sahlbergella singularis), black bourch category (Saissetia spp.), Sappaphis mala, Sappaphis Mali, Scaptocoris spp., Scaphoideus titanus (Scaphoides titanus), green bugs (Schizaphis Graminum), Schizoneura lanuginosa, scotinophora lurida category (Scotinophora spp.) pierce armored scale (Selenaspidus articulatus), cereal net aphid (Sitobion avenae), long clypeus plant hopper category (Sogata Spp.), white backed planthopper (Sogatella furcifera), Solubea insularis, Spissistilus festinus (=Stictocephala festina), pear crown network pentatomidae (Stephanitis nashi), Stephanitis pyrioides, Stephanitis takeyai, Tenalaphara malayensis, Tetraleurodes perseae, Therioaphis Maculate, Thyanta spp., such as T.accerra, T.perditor；Tibraca spp., wide chest froghopper category (Tomaspis Spp.), sound Aphis (Toxoptera spp.), such as black citrus aphid (T.aurantii)；White powder Pediculus (Trialeurodes Spp.), such as T.abutilonea, T.ricini, trialeurodes vaporariorum (T.vaporariorum)；Triatoma (Triatoma spp.), A Psylla spp (Trioza spp.), jassids category (Typhlocyba spp.), sharp armored scale category (Unaspis spp.), such as U.Citri, arrowhead scales (U.yanonensis)；And grape phylloxera (Viteus vitifolii)；

Hymenoptera (Hymenoptera) insect, such as Acanthomyops interjectus, Athaliarosae (Athalia rosae), Atta spp., such as A.capiguara, leaf cutting ant (A.cephalotes), leaf cutting ant (A.cephalotes), A.laevigata, A.robusta, A.sexdens, A.texana, bombus (Bombus spp.), Brachymyrmex spp., Camponotus spp., as Florida back of a bow ant (C.floridanus), C.pennsylvanicus,C.modoc；Cardiocondyla nuda, Chalibion sp lifts abdomen ant category (Crematogaster spp.), velvet ant (Dasymutilla occidentalis), Diprion (Diprion Spp.), Ji wasp (Dolichovespula maculata), Dorymyrmex spp., Dryocosmus kuriphilus, Formica spp., real bee category (Hoplocampa spp.), such as H.minuta, apple sawfly (H.testudinea)； Iridomyrmex humilis, hair ant category (Lasius spp.), such as black wool ant (L.niger), Argentine ant (Linepithema humile), Liometopum spp., Leptocybe invasa, Monomorium spp., such as little Huang Family ant (M.pharaonis), Monomorium, Nylandria fulva, Pachycondyla chinensis, Paratrechina longicornis, Paravespula spp., as P.germanica, P.pennsylvanica, P.vulgaris；Pheidole spp., such as brown major part ant (P.megacephala)；Pogonomyrmex spp., such as red ant (P.barbatus), harvester ant (P.californicus), wasp (Polistes rubiginosa), Prenolepis Impairs, Pseudomyrmex gracilis, Schelipron spp., Sirex cyaneus, Solenopsis spp., Such as Solenopsis geminata (S.geminata), red fire ant (S.invicta), S.molesta, black fiery ant (S.richteri), south fire Ant (S.xyloni)；Sphecius speciosus, Sphex spp., Tapinoma spp., as T.melanocephalum, T.sessile；Tetramorium spp., such as T.caespitum, T.bicarinatum, Hornet category (Vespa spp.), Such as yellow side wasp (V.crabro)；Vespula spp., such as hornet (V.squamosa)；Wasmannia Auropunctata, Xylocopa sp；

Orthoptera (Orthoptera) insect, such as Achroia grisella (Acheta domestica), Italian locust (Calliptamus italicus), Australia grass are dwelt locust (Chortoicetes terminifera), Ceuthophilus Spp., Diastrammena asynamora, Morocco halberd line locust (Dociostaurus maroccanus), Gryllotalpa Spp., such as African mole cricket (G.africana), mole cricket (G.gryllotalpa)；Gryllus spp., African sugarcane locust (Hieroglyphus daganensis), sissoo locust (Kraussaria angulifera), Locusta spp. are like flying Locust (L.migratoria), brown intend migratory locusts (L.pardalina；Melanoplus spp., such as the black locust of double cut (M.bivittatus), the black locust of red foot (M.femurrubrum), the black locust of Mexico (M.mexicanus), migrate black locust (M.sanguinipes), stone dwells black locust (M.spretus)；The red locust of striped (Nomadacris septemfasciata), Sai Na Jar (unit of capacitance) trolley locust (Oedaleus senegalensis), Scapteriscus spp., Schistocerca spp., such as America Desert locust (S.americana), desert locust (S.gregaria), Stemopelmatus spp., front yard disease stove Zhong (Tachycines ) and Zonozerus variegatus asynamorus；

Spider guiding principle (Arachnida) nuisance, such as Acarina (Acari), such as Argasidae (Argasidae), Ying Pi section (Ixodidae) and Sarcoptidae (Sarcoptidae), such as Amblyomma (Amblyomma spp.) (such as long star tick (A.americanum), the torrid zone flower tick (A.variegatum), amblyomma maculatum (A.maculatum)), Argas (Argas Spp.), such as adobe tick (A.persicu), Boophilus (Boophilus spp.) such as ox tick (B.annulatus), disappears Color ox tick (B.decoloratus), boophilus microplus (B.microplus), Dermacentor spp., such as dermacentor silvarum (D.silvarum), Dermacentor andersoni (D.andersoni), the big leather tick (D.variabilis) in America, Hyalomma (Hyalomma Spp.), such as proboscis (H.truncatum), Isodesspp (Ixodes spp.), such as castor bean tick (I.ricinus), shallow Red hard tick (I.rubicundus), Blacklegged tick (I.scapularis), ixodes holocyclus (I.holocyclus), ixodes pacificus (I.pacificus), Rhipicephalus sanguineus, Ornithodoros (Ornithodorus spp.), such as the white blunt edge of hair Tick (O.moubata, He Shi turicata (O.hermsi), relapsing fever tick (O.turicata), ornithonyssus bacoti (Ornithonyssus bacoti), ear-piercing tick (Otobius megnini), Dermanyssus gallinae (Dermanyssus Gallinae), Psoroptes (Psoroptes spp.), if sheep scabies is sick (P.ovis), Rhinpicephalus (Rhipicephalus Spp.), such as brown dog tick (R.sanguineus), Rhipicephalus appendicularis (R.appendiculatus), rhipicephalus evertsi (Rhipicephalus evertsi), root mite category (Rhizoglyphus spp.), Sarcoptesspp (Sarcoptes spp.), such as people Itch mite (S.scabiei)；And Eriophyidae (Eriophyidae), including Aceria spp., as A.sheldoni, A.anthocoptes, Acallitus spp., peronium section tick category (Aculops spp.), such as A.lycopersici, tangerine rust mite (A.pelekassi)；Aculus (Aculus spp.), such as thorn apple rust mite (A.schlechtendali)；Colomerus Vitis, Epitrimerus pyri (Epitrimerus pyri), tangerine wrinkle leaf Aculus (Phyllocoptruta oleivora； Eriophytes ribis and Eriophyes (Eriophyes spp.), such as citrus reticulata pediculus (Eriophyes sheldoni)；Instep suede Mite section (Tarsonemidae), including half Tarsonemus (Hemitarsonemus spp.), Phytonemus pallidus and Polyphagotarsonemus latus Banks (Polyphagotarsonemus latus), Steneotarsonemus (Stenotarsonemus spp.), Steneotarsonemus spinki；Tenuipalpidae (Tenuipalpidae), including short whisker Acarapis (Brevipalpus Spp.), such as purplish red short hairs mite (B.phoenicis)；Tetranychidae (Tetranychidae), including Eotetranychus (Eotetranychus spp.), true Tetranychus (Eutetranychus spp.), Oligonychus (Oligonychus spp.), Petrobia latens, Tetranychus spp., such as Tetranychus cinnabarinus (T.cinnabarinus), T.evansi, kamisawa tetranychus (T.kanzawai), Pacific Ocean tetranychid (T.pacificus), T.phaseulus, cotton spider mites (T.telarius) and T.urticae Koch (T.urticae)；Bryobia praetiosa (Bryobia praetiosa)；Panonychus citri category (Panonychus spp.), such as apple tetranychus (P.ulmi), citrus red mite (P.citri)；Metatetranychus spp. and Oligonychus (Oligonychus spp.), Such as meadow unguiculus mite (O.pratensis), O.perseae, Vasates lycopersici；Raoiella indica, fruit mite Section (Carpoglyphidae), including Carpoglyphus spp.；Penthaleidae spp., such as Halotydeus destructor；Demodicidae (Demodicidae) is several, such as Demodex spp.；Trombicidea, including Trombicula spp.；Opposing needling mite section (Macronyssidae), including Ornothonyssus spp.；Pyemotidae Including Pyemotes tritici (Pyemotidae),；Tyrophagus putrescentiae；Mite section (Acaridae), packet Include Acarus siro；Araneida (Araneida), such as tarantula (Latrodectus mactans), Tegenaria Agrestis, Chiracanthium sp, Lycosa sp, Achaearanea tepidariorum and brown silk spider (Loxosceles reclusa)；

Nemathelminthes (Phylum Nematoda) nuisance, such as plant parasitic nematodes, such as root-knot nematode, root knot Turbatrix (Meloidogyne spp.), such as M hapla (M.hapla), Meloidogyne incognita (M.incognita), pawl Root-knot nematode (M.javanica)；Cyst nematode, ball Heterodera (Globodera spp.), such as globodera rostochiensis (G.rostochiensis)；Heterodera (Heterodera spp.), such as Polymyxa graminis (H.avenae), soybean born of the same parents Capsule nematode (H.glycines), the nematode worm of beet (H.schachtii), clover cyst nematode (H.trifolii)；Seed Swollen goitre nematode, grain Turbatrix (Anguina spp.)；Cauline leaf nematode, Aphelenchoides (Aphelenchoides spp.), such as water Aphelenchoides oryzae Yokoo (A.besseyi)；Nematode is pierced, needle pierces Turbatrix (Belonolaimus spp.), as weeds pierce nematode (B.longicaudatus)；Loose ends worm, Bursaphelenchus (Bursaphelenchus spp.), such as Bursaphelenchus xylophilus (B.lignicolus), Bursaphelenchus xylophilus (B.xylophilus)；Annular nematode, ring grain Turbatrix (Criconema spp.) are small Loop wire Eimeria (Criconemella spp.), such as C.xenoplax and C.ornata and Criconemoides (Criconemoides Spp.), such as Criconemoides informis, middle ring Turbatrix (Mesocriconema spp.)；Bulb eelworm, Ditylenchus dipsaci Belong to (Ditylenchus spp.), such as rot stem nematodes (D.destructor), sweet potato stem nematode (D.dipsaci)；Nematode is bored, It bores Turbatrix (Dolichodorus spp.)；Spiral shape nematode, mostly band spiral (Heliocotylenchus multicinctus)；Sheath nematode and sheath shape nematode, sheath Turbatrix (Hemicycliophora spp.) and Hemicriconemoides belongs to；Hirshmanniella belongs to；It is preced with nematode, tie nematode (Hoplolaimus) belongs to；Rhizoid tie lines Worm, natural pearls Turbatrix (Nacobbus spp.)；Needlework worm, minute hand Turbatrix (Longidorus spp.) such as stretching, extension minute hand nematode (L.elongatus)；Pratylenchus, Pratylenchus (Pratylenchus spp.), such as the shortest tail of a nematode (P.brachyurus), neglect Pratylenchidae (P.neglectus), Cobb root (P.penetrans), P.curvitatus, ancient enlightening Pratylenchidae (P.goodeyi)；Similes thorne, perforation line Eimeria (Radopholus spp.), such as Radopholus similes thorne (R.similis)；Rhadopholus spp.；Rhodopholus spp.；Kidney worm, reniform nematode category (Rotylenchulus spp.), the nematode (R.robustus) that such as spirals, kidney shape kidney nematode (R.reniformis)；Shield nematode (Scutellonema) belong to；Undesirable root nematode, burr Turbatrix (Trichodorus spp.), such as T.obtusus, original burr line Worm (T.primitivus)；Class burr category (Paratrichodorus spp.), such as P.minor；Hinder long nematode, Tylenchorhynchus (Tylenchorhynchus spp.), such as Clayton's species of Tylenchorhynchus Nematodes (T.claytoni), indefinite species of Tylenchorhynchus Nematodes (T.dubius)； Citrus nematode, small Tylenchida (Tylenchulus) belongs to, such as citrus Tylenchulus Semipenetrans (T.semipenetrans)；Sword nematode, Xiphinema (Xiphinema spp.)；And other plant parasitic nematode kind；

Isoptera (Isoptera) insect, such as kalotermes flavicollis (Calotermes flavicollis), Coptotermes spp., such as Workers of Coptotermes formosanus Shiraki (C.formosanus), C.gestroi, C.acinaciformis； Cornitermes cumulans, Cryptotermes spp., such as C.brevis, C.cavifrons；Globitermes It is sulfureus, Heterotermes spp., such as golden yellow different termite (H.aureus), long-headed istermites (H.longiceps), sweet Sugarcane termite (H.tenuis)；Leucotermes flavipes, odontotermes (Odontotermes spp.), Incisitermes spp., such as I.minor, I.Snyder；Marginitermes hubbardi, Mastotermes spp., Such as M.darwiniensis, Neocapritermes spp., such as N.opacus, N.parvus；Neotermes spp., Procornitermes spp., Zootermopsis spp., such as Z.angusticollis, Z.nevadensis, Reticulitermes (Reticulitermes spp.), as R.hesperus, R.tibialis, eastern subterranean termite (R.speratus), yellow limb dissipate it is white Ant (R.flavipes), R.grassei, European reticulitermes flavipe (R.lucifugus), R.santonensis, the small black reticulitermes flavipe of U.S. (R.virginicus)；Termes natalensis；

Blattaria (Blattaria) insect, such as Blatta spp., as oriental cockroach (B.orientalis), B.lateralis；Blattella spp., such as B.asahinae, Groton bug (B.germanica)；Leucophaea maderae (Leucophaea maderae), Panchlora nivea, Periplaneta spp., such as American cockroach (P.americana), Australia blattaria (P.australasiae), brown blattaria (P.brunnea), Peroplaneta fluligginosa (P.fuligginosa), the big Lian (P.japonica) of Japan；Supella longipalpa, Parcoblatta Pennsylvanica, Eurycotis floridana, Pycnoscelus surinamensis,

Siphonaptera (Siphonoptera) insect, such as Cediopsylla simples, Ceratophyllus (Ceratophyllus Spp.), Ctenocephalides spp., such as cat flea (C.felis), dog flea (C.canis), Xanthopsyllacheopis (Xenopsylla cheopis), Pulex irritans (Pulex irritans), Trichodectes canis, chigo (Tunga ) and ceratophyllus fasciatus (Nosopsyllus fasciatus) penetrans；

Thysanoptera (Thysanura) insect, such as silverfiss (Lepisma saccharina), Ctenolepisma Urbana and spot silverfish (Thermobia domestica)；

Chilopoda (Chilopoda) nuisance, for example, Scolopendra (Geophilus spp.), common house centipede belong to (Scutigera Spp.), such as Scutigera coleoptrata；

Diplopoda (Diplopoda) nuisance, such as Blaniulus guttulatus, Julus spp., Narceus spp.；

Symphyla (Symphyla) nuisance, such as Scutigerella immaculata,

Dermaptera (Dermaptera) insect, such as European earwig (Forficula auricularia),

Collembola (Collembola) insect, such as Onychiurus arcticus category (Onychiurus ssp.) such as equip with arms Onychiurus arcticus (Onychiurus armatus),

Isopoda (Isopoda) nuisance, such as pillworm (Armadillidium vulgare), comb beach louse (Oniscus Asellus), ball pillworm (Porcellio scaber)；

Hair Anoplura (Phthiraptera) insect, such as Damalinia (Damalinia spp.)；Pediculus (Pediculus Spp.), such as pediculus humanus capitis (Pediculus humanus capitis), pediculus humanus corporis (Pediculus humanus corporis), Pediculus humanus humanus；Crab louse (Pthirus pubis)；Haematopinus (Haematopinus spp.), such as ox Blood lice (Haematopinus eurysternus), haematopinus suis (Haematopinus suis)；Linognathusspp (Linognathus Spp.), such as calf jaw lice (Linognathus vituli)；Ox louse (Bovicola bovis), chicken lice (Menopon Gallinae), big chicken lice (Menacanthus stramineus) and solenoptes capillatus (Solenopotes capillatus), chew Pediculus (Trichodectes spp.).

The example for other nuisance kinds that can be prevented and treated by formula (I) compound includes: Mollusca (Phylum Mollusca), Bivalvia (Bivalvia), such as decorations shellfish category (Dreissena spp.)；Gastropoda (Gastropoda), such as A Yong Limax (Arion spp.), Biomphalaria (Biomphalaria spp.), small Bulinus (Bulinus spp.), Deroceras spp., native snail category (Galba spp.), Lymnaea (Lymnaeas pp.), Katayama (Oncomelania Spp.), Pomacea canaliculata (Pomacea canaliclata), amber spiro spp (Succinea spp.)；Worm guiding principle (helminths), Such as Ancylostoma duodenale (Ancylostoma duodenale), Sri Lanka hook worm (Ancylostoma Ceylanicum), ancylostoma braziliense (Acylostoma braziliensis), Ancylostoma (Ancylostoma Spp.), seemingly draw ascarid nematode (Ascaris lubricoides), Ascaris (Ascaris spp.), cloth Shandong, Malaysia nematode (Brugia malayi), cloth Shandong, Timor nematode (Brugia timori), Bunostomum (Bunostomum spp.), Xia Bai Special Turbatrix (Chabertia spp.), branch testis fluke category (Clonorchis spp.), Cooperia (Cooperia Spp.), Dicrocoelium (Dicrocoelium spp.), dictyocaulus filaria (Dictyocaulus filaria), broad-leaved are split Head tapeworm (Diphyllobothrium latum), Guinea worm (Dracunculus medinensis), particulate spine ball Tapeworm (Echinococcus granulosus), Echinococcus multilocularis (Echinococcus multilocularis), compacted shape Firmly intestines pinworm (Enterobius vermicularis), piece fluke category (Faciola spp.), Haemonchus (Haemonchus spp.) such as haemonchus contortus (Haemonchus contortus)；Heterakis (Heterakis Spp.), short and small to nibble shell tapeworm (Hymenolepis nana), Metastrongylus apri category (Hyostrongulus spp.), Luo Aluoa Nematode (Loa Loa), Nematodirus (Nematodirus spp.), oesophagostomum (Oesophagostomum spp.), Opisthorchis (Opisthorchis spp.), Onchocerca caecutiens (Onchocerca volvulus), this off-line Eimeria difficult to understand (Ostertagia spp.), Paragonimus (Paragonimus spp.), Schistosoma (Schistosomen spp.), richness Family name's quasi-colubriformis (Strongyloides fuelleborni), strongyloides intestinalis (Strongyloides stercora lis), Excrement Strongylus (Stronyloides spp.), taeniarhynchus saginatus (Taenia saginata), taeniasis suis (Taenia Solium), trichina(Trichinella spiralis) (Trichinella spiralis), Trichinella nativa (Trichinella nativa), strain Trichinella britovi (Trichinella britovi), southern trichina (Trichinella nelsoni), puppet Fang Dingmao shape line Worm (Trichinella pseudopsiralis), Trichostrongylus (Trichostrongulus spp.), ascaris trichiurus (Trichuris trichuria), wuchereria bancrofti (Wuchereria bancrofti).

Inventive mixture can be applied to any and all stages of development of nuisance, for example, ovum, larva, pupa and at Worm.Nuisance can be by keeping objective pests, its food supply, habitat, breeding spot or its place and pesticide a effective amount of Inventive mixture or comprising the mixture composition contact and prevent and treat.

" place " refers to plant, plant propagation material (seed), soil, region, material or in which unwanted growth or can The environment that can be grown.

Typically, " pesticide effective quantity " refers to observable effect is obtained to growth needed for inventive mixture or The amount of composition comprising the mixture, the effect include necrosis, dead, retardance, prevention and removal effect, execution or Reduce the appearance and movable effect of target organism.For the various mixtures/combinations being used in the present invention, pesticide has Effect amount can change.The pesticide effective quantity of mixtures/combinations also can according to for example required pesticidal effects of essential condition and it is lasting when Between, weather, target species, place, method of application etc. and change.

As described above, the present invention includes a kind of method for improving plant health, wherein by plant, wherein plant growth or pre- The place of phase growth is handled by plant propagation material a effective amount of inventive mixture of plant of its growing plant.

Term " plant health effective quantity " indicates the present invention mixing for being enough to realize plant health effects as defined below Object amount.More exemplary information in relation to amount, method of application and proper ratio ready for use is provided below.Anyway, skillfully Technical staff sufficiently know the amount can change in a wide range and depend on various factors, such as processed cultivated plant or The fact that material and weather conditions.

When preparing the mixture, it is preferable to use pure reactive compound, can be added other reactive compounds to it on demand To prevent nuisance, such as Insecticides (tech) & Herbicides (tech), fungicide or weeding or growth regulating-activity compound or fertilizer are as other Active component.

Inventive mixture by with a effective amount of reactive compound of pesticide handle fungi, animal pests or it is to be protected with Anti-fungal invasion plant, plant propagation material (preferred seed), material or soil treatment and use.Application can be in material, plant Object or plant propagation material (preferred seed), which infect front and back by nuisance, to carry out.

For the present invention, term plant refers to the propagation material of entire plant, a part of plant or plant.

Inventive mixture and combinations thereof in various cultivated plants such as Cereal, such as wheat, rye, barley, Triticale, oat or rice；Beet, such as sugar beet or fodder beet；Fruit, such as a kind of fruit, such as apple, pear, etc., drupe or berry, such as apple, Pears, Lee, peach, almond, cherry, strawberry, raspberry, blackberry, blueberry or dayberry；Leguminous plant, such as hyacinth bean, pea, clover or soybean； Oilseed plant, such as rape, leaf mustard, olive, sunflower, coconut, cocoa bean, castor oil plant, oil palm, peanut or soybean；Calabash Lu Ke plant, such as pumpkin, cucumber or muskmelon；Fibre plant, such as cotton, flax, hemp or jute；Cedra fruits, example Such as orange, lemon, grape fruit or tangerine；Vegetables, such as spinach, lettuce, asparagus, cabbage, carrot, onion, tomato, soil Beans, cucurbit or green pepper；Laurel class plant, such as avocado, cortex cinnamomi or camphor；Energy and material plant, such as corn and soybean, Rape, sugarcane or oil palm；Corn；Tobacco；Nut；Coffee；Tea；Banana；Grapevine (table grapes and wine Wine grape)；Beer Flower；Lawn；STEVIA REBAUDIANA (also referred to as stevia rebaudianum (Stevia))；Natural rubber plant or ornamental and forest plants, for example, flowers, shrub, Prevention and treatment is big in broad leaf tree or evergreen tree, such as coniferous tree and plant propagation material such as seed and the crop material of these plants It is especially important to measure plant pathogenic fungi.

It is preferred that being respectively used to inventive mixture and combinations thereof in field crop, such as potato, sugar beet, cigarette Grass, wheat, rye, barley, oat, rice, corn, cotton, soybean, rape, leguminous plant, sunflower, coffee or sugarcane；Water Fruit；Grapevine；Ornamental plant；Or a large amount of fungies are prevented and treated on vegetables such as cucumber, tomato, Kidney bean or pumpkin.

It is preferred that inventive mixture and combinations thereof is used for the processing of plant propagation material respectively for example small in Cereal Wheat, rye, barley and oat；A large amount of fungies are prevented and treated on potato, tomato, grapevine, rice, corn, cotton and soybean.

Term " cultivated plant " is understood to include the plant for having passed through breeding, mutagenesis or genetic engineering modification, including But the agricultural biotechnologies product for being not limited to list marketing or exploitation (referring to http://cera-gmc.org, is shown in that GM therein makees Object database).Genetically modified plant is its genetic material by using not easily passing through hybridization, mutation or nature under field conditions (factors) Recombinate the plant of obtained recombinant DNA technology modification.Usually by the heredity of one or more gene integrations to genetically modified plant Improve certain performances of plant in material.This kind of gene modification further includes but is not limited to the targeting of protein, oligopeptides or polypeptide Posttranslational modification, for example, by glycosylation or polymer addition such as isoprenylation, acetylation or farnesylation structure division or PEG structure division.

The plant modified by breeding, mutagenesis or genetic engineering is for example because conventional breeding or gene engineering method are resistant to spy The application of different classification herbicide, these herbicides such as auxin herbicide such as dicamba (dicamba) or 2,4-D；Bleaching Agent herbicide such as medical midbodies of para (ortho)-hydroxybenzoic acetone acid dioxygenase enzyme (HPPD) inhibitor or phytoene desaturase (PDS) inhibit Agent；Acetolactate synthestase (ALS) inhibitor, such as sulfonylurea or imidazolone type；Enol pyruvylshikimate 3- phosphoric acid Synzyme (EPSPS) inhibitor, such as glyphosate (glyphosate)；Glutamine synthelase (GS) inhibitor, such as careless ammonium Phosphine (glufosinate)；Protoporphyrinogen-IX oxidase inhibitor；Lipid biosynthesis inhibitors such as acetyl group CoA carboxylase (ACCase) inhibitor；Or oxynil (i.e. Brominal (bromoxynil) or ioxynil (ioxynil)) herbicide.In addition, planting Object is resistant to plurality of classes herbicide by multiple gene modification, is such as resistant to both glyphosate and glufosinate-ammonium or tolerance grass is sweet Phosphine and another category herbicide two selected from ALS inhibitor, HPPD inhibitor, auximone inhibitor or ACCase inhibitor Person.These herbicide tolerant technologies are for example described in Pest ManageM.A.Sci.61,2005,246；61,2005,258； 61,2005,277；61,2005,269；61,2005,286；64,2008,326；64,2008,332；Weed Sci.57,2009, 108；Austral.J.Agricult.Res.58,2007,708；Science 316,2007,1185；And text cited therein In offering.Several cultivated plants have passed through conventional breeding methods (gene mutation) herbicide-tolerant, such as imidazolinone resistance Such as imazamox (imazamox)Summer sowing rape (Canola, German BASF SE) or tolerance sulfonylurea, Such as tribenuron-methyl (tribenuron)Sunflower (DuPont, USA).Gene engineering method is used Cultivated plant such as soybean, cotton, corn, beet and rape are assigned to the tolerance of herbicide such as glyphosate and glufosinate-ammonium, it In it is some can be with trade (brand) name(tolerance glyphosate, Monsanto, U.S.A.),(tolerance imidazolone, German BASF SE) and(tolerance glufosinate-ammonium, German Bayer CropScience) commercially available.

In addition, further including that can synthesize one or more insecticidal proteins by using recombinant DNA technology, especially by bud Those of known to spore Bacillus (Bacillus) bacterium, especially bacillus thuringiensis (Bacillus thuringiensis) Plant, the insecticidal proteins such as delta-endotoxin, such as CryIA (b), CryIA (c), CryIF, CryIF (a2), CryIIA (b), CryIIIA, CryIIIB (b1) or Cry9c；Asexual insecticidal proteins (VIP), such as VIP1, VIP2, VIP3 or VIP3A；Line The insecticidal proteins of worm colonizing bacteria, such as Photobacterium (Photorhabdus) or Xenorhabdus (Xenorhabdus)；It is dynamic Toxin such as scorpion toxin, spider toxin, wasp toxin or other insect-specific neurotoxins that object generates；Mycetogenetic poison Element, such as streptomyces (Streptomycetes) toxin；Phytolectin, such as pea or barley lectin element；Agglutinin；Egg White enzyme inhibitor, such as trypsin inhibitor, serpin, stem tuber storage protein (patatin), half Guang ammonia Pepsin inhibitor or antipain；Ribosome inactivating protein (RIP), such as ricin, corn-RIP, phase Think beans toxalbumin, Seeds of Luffa cylindrica albumen, saporin or different strain diarrhea toxalbumin (bryodin)；Steroid metabolism enzyme, such as 3- hydroxyl Steroids oxidizing ferment, ecdysteroids-IDP glycosyl transferase, cholesterol oxidase, moulting hormone inhibitor or HMG-CoA reduction Enzyme；Ion channel blocking agent, such as sodium channel or calcium channel blocker；JH esterase；Diuretic hormone receptor (helicokinin receptor)；Stilbene synzyme, bibenzyl synthases, chitinase or dextranase.In the context of the present invention, this A little insecticidal proteins or toxin are also specifically interpreted as preceding toxin, hybrid protein, the albumen that truncated or other aspects are modified.Heterozygosis egg White feature is the novel compositions (for example, see WO 02/015701) in albumen domain.The toxoid can synthesize these toxin Genetically modified plant other examples e.g., as disclosed in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427529, in EP-A 451 878, WO 03/18810 and WO 03/52073.The method for producing these genetically modified plants is usual It is known by those of ordinary skill in the art and is for example described in above-mentioned publication.These are contained in genetically modified plant Insecticidal proteins assign the plant for generating these albumen to the nuisance on all taxology for arthropod, especially beetle (coleoptera (Coeleropta)), dipteral insect (Diptera (Diptera)) and moth (Lepidoptera (Lepidoptera)) and The tolerance of nematode (Nematoda (Nematoda)).The genetically modified plant that one or more insecticidal proteins can be synthesized for example is retouched It is set forth in above-mentioned publication, some of which is commercially available, such as(generate the corn product of toxin Cry1Ab Kind),Plus (corn variety for generating toxin Cry1Ab and Cry3Bb1),(generate toxin The corn variety of Cry9c),RW (generates Cry34Ab1, Cry35Ab1 and the transfer of enzyme phosphinothricin-N- acetyl The corn variety of enzyme [PAT])；33B (cotton variety for generating toxin Cry1Ac),I (is produced The cotton variety of raw toxin Cry1Ac),II (cotton variety for generating toxin Cry1Ac and Cry2Ab2)；(cotton variety for generating VIP toxin)；(the potato kind for generating toxin Cry3A)；Bt11 (such asCB) and the Bt176 of France Syngenta Seeds SAS (generates the corn product of toxin Cry1Ab and PAT enzymes Kind), the MIR604 of French Syngenta Seeds SAS (generates the corn variety of the modification translation of toxin Cry3A, referring to WO 03/018810), the MON 863 (corn variety for generating toxin Cry3Bb1) of Belgian Monsanto Europe S.A., than The IPC 531 (cotton variety for generating the modification translation of toxin Cry1Ac) of Monsanto Europe S.A. and Belgium when sharp 1507 (corn varieties for generating toxin Cry1F and PAT enzymes) of Pioneer Overseas Corporation.

In addition, further including that can synthesize one or more pairs of bacteriums, virus or fungal pathogen by using recombinant DNA technology The plant of the protein of resistance or the tolerance enhancing of body.The example of the albuminoid is so-called " egg relevant to pathogenesis It is white " (PR albumen, 225) for example, see EP-A 0 392, Plant Genes Conferring Resistance To Pathogens (such as expression is for wild from Mexico The resistant gene that the phytophthora infestans (Phytophthora infestans) of raw potato Solanum bulbocastanum work Potato kind) or T4 Lysozyme (such as can synthesize to bacterium such as erwinia amylovora (Erwinia amylvora) have increase The potato kind of these albumen of strong resistance).The method of these genetically modified plants is produced usually to this field knack Personnel are known and are for example described in above-mentioned publication.

In addition, further including that can to synthesize one or more albumen by using recombinant DNA technology (such as raw to improve yield Substance generation, Grain Yield, content of starch, oil content or protein content), to arid, salt or other growth restrictive circumstances The plant of the tolerance of factor or the tolerance to nuisance and fungi, bacterium or viral pathogen.

In addition, further include by using recombinant DNA technology and the content of material containing knots modification or novel substance content are with outstanding Its plant for improving mankind or animal nutrition, such as generate sanatory long-chain omega-fatty acid or unsaturation ω -9 fatty acid Oil crops (such asRape, Canadian DOW Agro Sciences).

In addition, further include by using recombinant DNA technology and the content of material containing knots modification or novel substance content are with outstanding Its improve raw material production plant, such as generate incrementss amylopectin potato (such asPotato, Germany BASF SE)。

The difference of each compound of inventive mixture is administered in combination by before or after plant seeding or plant Spraying or dusting seed, rice shoot, plant or soil carry out before or after emergence.

Inventive mixture and it can be used for protecting wood materials such as trees, guardrail, sleeper etc. comprising their compositions, And building such as house, auxiliary building, factory, there are also construction material, furniture, leather, fiber, vinyl products, electric wire and Cable etc. to prevent ant and/or termite, and prevent ant and termite damage crop or the mankind (such as when nuisance intrusion house and When communal facility).

Conventional rate of application in material protection is, for example, 0.01-1000g reactive compound/m²Processed material, it is ideal Be 0.1-50g/m²。

For the use in spray composite, the content of mixture of active principles is 0.001-80 weight %, preferably 0.01-50 weight %, most preferably 0.01-15 weight %.

In a more preferable situation, particularly, the present invention includes a kind of method for preventing and treating harmful fungoid, wherein using pesticide A effective amount of inventive mixture processing fungi, its habitat, breeding spot, its place will protect the plant invaded with anti-fungal Object, soil or plant propagation material (preferred seed).

Herein, the present invention includes a kind of method for preventing and treating harmful fungoid, wherein mixed with a effective amount of present invention of pesticide Close object processing plant propagation material (preferred seed).

The present invention is further illustrated by following examples, but is not limited to following examples:

Reactive compound the compounds of this invention I (=compound I) and 2- (3- ethylsulfonyl -2- pyridyl group) -3- methyl - 6- (trifluoromethyl) imidazo [4,5-b] pyridine (=compound IIa) and 4- [5- (3,5- dichlorophenyl) -5- (trifluoromethyl) - 4H- is differentAzoles -3- base]-N- [(4R) -2- ethyl -3- oxo-differentOxazolidine -4- base] -2- methyl-benzamide (=chemical combination Object IIb) stock solution that concentration is 10000ppm is configured in dimethyl sulfoxide respectively.

Activity of the embodiment 1. to late blight encephalapthy agent phytophthora infestans

Stock solution is mixed according to ratio, be pipetted on titer plate (MTP) and is diluted with water to the concentration.Then The spore suspension of the phytophthora infestans containing the aqueous nutrient medium of pea juice base or DDC culture medium is added.Each plate is placed in temperature Degree is in 18 DEG C of steam-laden room.MTP is measured at 405nm using absorption spectrophotometry after inoculation 7 days.

By the parameter of measurement with the growth (100%) for compareing scheme without reactive compound and without fungi and activity The blank value of compound compares, to determine relative growth percentage of the pathogen in each reactive compound.

These percentages are converted to effect.

Using Colby formula, [R.S.Colby " calculates the association of combinations of herbicides to the expection effect of active compound combinations Responded with synergy and antagonism ", Weeds 15,20-22 (1967)] it determines and compared with the effect observed.

These are as the result is shown in table 1.

Table 1

Embodiment 2. is on wheat to the activity of the leaf spot as caused by wheat septoria

Stock solution is mixed according to ratio, be pipetted into titer plate and is diluted with water to the concentration.Then it is added Spore suspension of the QOI tolerance isolate of wheat septoria in biological malt or yeast-bacteria peptone-glycerine water solution Liquid.Each plate is placed in the steam-laden room that temperature is 18 DEG C.It is measured at 405nm after inoculation 7 days using absorption spectrophotometry MTP。

By the parameter of measurement with the growth (100%) for compareing scheme without reactive compound and without fungi and activity The blank value of compound compares, to determine relative growth percentage of the pathogen in each reactive compound.

These percentages are converted to effect.

Using Colby formula, [R.S.Colby " calculates the association of combinations of herbicides to the expection effect of active compound combinations Responded with synergy and antagonism ", Weeds 15,20-22 (1967)] it determines and compared with the effect observed.

These are as the result is shown in table 2.

Table 2

Activity of the embodiment 3. to rice blast Pyricularia oryzae

Stock solution is mixed according to ratio, be pipetted into titer plate and is diluted with water to the concentration.Then it is added Spore suspension of the QOI tolerance isolate of Pyricularia oryzae in biological malt or yeast-bacteria peptone-glycerine water solution. Each plate is placed in the steam-laden room that temperature is 18 DEG C.MTP is measured at 405nm using absorption spectrophotometry after inoculation 7 days.

By the parameter of measurement with the growth (100%) for compareing scheme without reactive compound and without fungi and activity The blank value of compound compares, to determine relative growth percentage of the pathogen in each reactive compound.

These percentages are converted to effect.

Using Colby formula, [R.S.Colby " calculates the association of combinations of herbicides to the expection effect of active compound combinations Responded with synergy and antagonism ", Weeds 15,20-22 (1967)] it determines and compared with the effect observed.

These are as the result is shown in table 3.

Table 3

Activity of the embodiment 4. to the early blight as caused by early epidemic rod method

Stock solution is mixed according to ratio, be pipetted into titer plate and is diluted with water to the concentration.Then it is added Spore suspension of the QOI tolerance isolate of early epidemic rod method in biological malt or yeast-bacteria peptone-glycerine water solution Liquid.Each plate is placed in the steam-laden room that temperature is 18 DEG C.It is measured at 405nm after inoculation 7 days using absorption spectrophotometry MTP。

By the parameter of measurement with the growth (100%) for compareing scheme without reactive compound and without fungi and activity The blank value of compound compares, to determine relative growth percentage of the pathogen in each reactive compound.

These percentages are converted to effect.

Using Colby formula, [R.S.Colby " calculates the association of combinations of herbicides to the expection effect of active compound combinations Responded with synergy and antagonism ", Weeds 15,20-22 (1967)] it determines and compared with the effect observed.

As the result is shown in table 4.

Table 4

Claims (13)

1. including the following pesticide combination as active component:

1) as the 1- of compound I [2- [[1- (4- chlorphenyl) pyrazole-3-yl] oxygen methyl] -3- methylphenyl] -4- methyl - Tetrazolium -5- ketone；With

2) a kind of Pesticidal compound II, wherein compound II is selected from the group by forming as follows: N- [the chloro- 3- of 4- [[(phenyl methyl) Amino] carbonyl] phenyl] -1- methyl -3- (1,1,2,2,2- pentafluoroethyl group) -4- (trifluoromethyl) -1H- pyrazoles -5- formamide, [3- (the chloro- 2,6- 3,5-dimethylphenyl of 4-) -8- methoxyl group -1- methyl -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- Base] carbonic acid ethyl ester, [3- (chloro- 2, the 6- 3,5-dimethylphenyl of 4-) -8- methoxyl group -2- oxo -1,8- diaza spiro [4.5] decyl- 3- Alkene -4- base] carbonic acid ethyl ester, [3- (chloro- 2, the 6- Dimethvl-phenyl of 4-) -1,8- dimethoxy -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [3- (chloro- 2, the 6- Dimethvl-phenyl of 4-) -1- ethyoxyl -8- methoxyl group -2- oxygen Generation -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [1- ethyoxyl -8- methoxyl group -2- oxo -3- (2,4, 6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [1,8- dimethoxy -2- oxo - 3- (2,4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [8- methoxyl group -1- first Base -2- oxo -3- (2,4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [8- first Oxygroup -2- oxo -3- (2,4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, 2- (3- ethylsulfonyl -2- pyridyl group) -3- methyl -6- (trifluoromethyl) imidazo [4,5-b] pyridine, 2- [3- ethylsulfonyl - 5- (trifluoromethyl) -2- pyridyl group] -3- methyl -6- (trifluoromethyl) imidazo [4,5-b] pyridine, 4- [5- (3,5- dichloro-benzenes Base) -5- (trifluoromethyl) -4H- is differentAzoles -3- base]-N- [(4R) -2- ethyl -3- oxo-differentOxazolidine -4- base] -2- first Base-benzamide, [5- (3,5- bis- chloro- 4- fluoro-phenyl) -5- (trifluoromethyl) -4H- is different by 4-Azoles -3- base]-N- [(4R) - 2- ethyl -3- oxo-differentOxazolidine -4- base] -2- methyl-benzamide.

2. mixture according to claim 1, wherein compound II is selected from the group by forming as follows: 4- [5- (3,5- dichloro-benzenes Base) -5- (trifluoromethyl) -4H- is differentAzoles -3- base]-N- [(4R) -2- ethyl -3- oxo-differentOxazolidine -4- base] -2- first [5- (the chloro- 4- fluoro-phenyl of 3,5- bis-) -5- (trifluoromethyl) -4H- is different by base-benzamide and 4-Azoles -3- base]-N- [(4R) - 2- ethyl -3- oxo-differentOxazolidine -4- base] -2- methyl-benzamide.

3. mixture according to claim 1, wherein compound II is selected from the group by forming as follows: [3- (chloro- 2, the 6- diformazan of 4- Base phenyl) -8- methoxyl group -1- methyl -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [3- (the chloro- 2,6- 3,5-dimethylphenyl of 4-) -8- methoxyl group -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl Ester, [3- (chloro- 2, the 6- Dimethvl-phenyl of 4-) -1,8- dimethoxy -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- Base] carbonic acid ethyl ester, [3- (chloro- 2, the 6- Dimethvl-phenyl of 4-) -1- ethyoxyl -8- methoxyl group -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [1- ethyoxyl -8- methoxyl group -2- oxo -3- (2,4,6- trimethylphenyl) - 1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [1,8- dimethoxy -2- oxo -3- (2,4,6- trimethyls Phenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester, [8- methoxyl group -1- methyl -2- oxo -3- (2, 4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester and [8- methoxyl group -2- oxo -3- (2,4,6- trimethylphenyl) -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base] carbonic acid ethyl ester.

4. mixture according to claim 1, wherein compound II is selected from the group by forming as follows: 2- (3- ethylsulfonyl -2- Pyridyl group) -3- methyl -6- (trifluoromethyl) imidazo [4,5-b] pyridine and 2- [3- ethylsulfonyl -5- (trifluoromethyl) -2- Pyridyl group] -3- methyl -6- (trifluoromethyl) imidazo [4,5-b] pyridine.

5. mixture as claimed in one of claims 1-4, wherein the weight ratio of compound I and compound II is 500:1-1: 500。

6. mixture as claimed in one of claims 1-4, wherein the weight ratio of compound I and compound II is 100:1-1: 100。

7. a kind of composition pesticide, comprising liquid or solid carrier and such as the mixture of any one of claim 1-6.

8. a kind of method for preventing and treating phytopathogenic harmful object, wherein with a effective amount of as any one of claim 1-6 determines The mixture of justice handles nuisance, its habitat, breeding spot, its place or to protect the plant to prevent nuisance invasion, soil Or plant propagation material.

9. a kind of method for improving plant health, wherein being mixed as defined in any one of claim 1-6 with a effective amount of Object handles the place of plant, wherein plant growth or expected growth or the plant propagation material by its growing plant.

10. a kind of protection plant propagation material is to prevent the method for nuisance, including keeps the plant propagation material and pesticide effective The contact of the mixture as defined in any one of claim 1-6 of amount.

11. method according to claim 10, wherein the mixture as defined in any one of claim 1-5 with 0.01g extremely The amount of 10kg/100kg plant propagation material is applied.

12. according to the method for any one of claim 8-11, wherein the mixture as defined in any one of claim 1-4 Meanwhile that is, combine respectively or continuous administration.

13. plant propagation material, comprising 0.01g to 10kg/100kg plant propagation material such as any one of claim 1-6 Defined mixture.