CN109836975A - A kind of corrosion-resistant conductive coating and its preparation method and application - Google Patents
A kind of corrosion-resistant conductive coating and its preparation method and application Download PDFInfo
- Publication number
- CN109836975A CN109836975A CN201711195070.7A CN201711195070A CN109836975A CN 109836975 A CN109836975 A CN 109836975A CN 201711195070 A CN201711195070 A CN 201711195070A CN 109836975 A CN109836975 A CN 109836975A
- Authority
- CN
- China
- Prior art keywords
- parts
- corrosion
- preparation
- coating
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of corrosion-resistant conductive coatings and its preparation method and application to obtain coating by the way that resin, solvent, conductive filler to be uniformly mixed after grinding.By selecting the ketone-grouped resin splendid to the extreme environments tolerance such as strong acid and strong base high temperature, realize adaptation of the coating to extreme use environment, select suitable conductive filler that can also maintain good electric conductivity simultaneously, to guarantee that coating still has good conductive property in extreme environments such as strong acid and strong bases, the usage scenario of conductive coating has been expanded significantly.It is strong to can be widely used in corrosivity, and easily on the surface of the object of surface stored charge, such as, aerospace, petrochemical industry etc., wherein, aerospace field mainly includes the positions such as special Aviation Fuel tank and warehouse, aircraft fuel tank surfaces externally and internally, and petrochemical industry mainly includes speciality chemical holding vessel, transport pipeline, the surfaces externally and internally of petroleum storage equipment etc..
Description
Technical field
The present invention relates to paint fields, specifically, a kind of corrosion-resistant conductive coating and its preparation method and application.
Background technique
Conductive coating mainly realizes electric conductivity, the electric conductivity meeting of coating by loading conductive filler inside resin
As external environment declines the corrosion of coating.Anticorrosive paint is generally divided into conventional anticorrosive paint and anticorrosive paint, prevents again
For rotten coating refers to relatively conventional anticorrosive paint, can be applied in relatively harsh corrosive environment, and have can reach than routine
A kind of anticorrosive paint of anticorrosive paint longer protection period.Therefore, how the two to be combined, increases preserver in conductive coating
Matter, to increase the service life of coating, is exactly always so that the electric conductivity of coating will not be reduced because of extraneous corrosion
The problem of industry urgent need to resolve, but there is presently no the conductive coating for the extreme environments such as strong acid and strong base high temperature, this is also
Limit the usage scenario of conductive coating.
Summary of the invention
For the problems in the relevant technologies, the present invention has studied a kind of preparation method of corrosion-resistant conductive coating, to provide one
Kind of electric conductivity is good and corrosion-resistant strong coating.
The preparation method of corrosion-resistant conductive coating provided by the invention, comprising: in parts by weight, by 33~50 parts of resins, 30
~40 parts of solvents, 17~25 parts of conductive fillers, 1~3 part of auxiliary agent mixing, are sufficiently stirred, grind, obtain the anti-corrosion conduction and apply
Material.
In the above preparation method, the resin include epoxy resin, polyester resin, amino resins, in polyurethane resin
One or more combinations and ketone-grouped resin.
In the above preparation method, the solvent includes 25~35 parts of N-Methyl pyrrolidones, 25 according to parts by weight
~35 parts of dimethyl acetamides, 15~25 parts of dimethylbenzene, 15~20 parts of dichloroethanes, 1~3 part of butyl.
In the above preparation method, the conductive filler be carbon nanotube, metal fine powder, conductive titanium dioxide, conductive black,
One of carbon fiber, graphene or a variety of combinations.
In the above preparation method, the auxiliary agent includes dispersing agent, defoaming agent and levelling agent.
In the above preparation method, the dispersing agent is polyvinyl pyrrolidone, in vinyl bis-stearamides, polyethylene glycol
One or more combinations.
In the above preparation method, the defoaming agent is dimethyl silicone polymer, polyoxyethylene polyoxy propyl alcohol amidogen ether, emulsification
One of silicone oil, polyoxypropylene, polypropylene glycerol aether or a variety of combinations.
In the above preparation method, the levelling agent is diphenylpolysiloxane, polymethylphenylsiloxane, poly dimethyl
One of siloxanes or a variety of combinations.
The corrosion-resistant conductive coating prepared by the above method.
Application of the above-mentioned corrosion-resistant conductive coating in aerospace field and/or petrochemical industry.
The preparation method of corrosion-resistant conductive coating provided by the invention, by the way that resin, solvent, conductive filler are uniformly mixed,
Corrosion-resistant conductive coating is obtained after grinding.The present invention uses the resin for having strong corrosion resistant to extreme environments such as strong acid and strong base high temperature
As matrix resin, guarantee that it can be in the extreme environments normal use such as strong acid and strong base, and by addition conductive filler come real
Existing electric conductivity, has expanded the usage scenario of coating significantly.
Coating prepared by the present invention can be widely used in that corrosivity is strong, and easily in the table of the object of surface stored charge
Face, for example, aerospace, petrochemical industry etc., wherein aerospace field mainly includes special Aviation Fuel tank and warehouse, boat
The positions such as pocket fuel tank surfaces externally and internally, petrochemical industry mainly include speciality chemical holding vessel surfaces externally and internally, transport pipeline
Surfaces externally and internally, petroleum storage equipment surfaces externally and internally etc..
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched
It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention
In embodiment, those of ordinary skill in the art's every other embodiment obtained shall fall within the protection scope of the present invention.
The preparation method of corrosion-resistant conductive coating provided by the invention, comprising:
Prepare solvent, by according to parts by weight 25~35 parts of N-Methyl pyrrolidones, 25~35 parts of dimethyl acetamides,
15~25 parts of dimethylbenzene, 15~20 parts of dichloroethanes, 1~3 part of butyl are uniformly mixed, and solvent is made, it is preferable that will
30 parts of N-Methyl pyrrolidone parts, 30 parts of dimethyl acetamides, 20 parts of dimethylbenzene, 18 parts of dichloroethanes, 2 parts of butyls
Solvent is made in mixing.In this step, because the corrosive resin of strong alkali-acid resistance, especially polyarylether resin are almost insoluble
Solution is in most solvents, and therefore, it is necessary to select suitable composite solvent system, and in strict control system, each component contains
Amount guarantees that the components such as resin can sufficiently dissolve in a solvent, and plays its effect, to guarantee the basic of corrosion-resistant conductive coating
Mechanical property.
Corrosion-resistant conductive coating is prepared, in parts by weight, by 33~50 parts of resins, 30~40 parts of solvents, 17~25 parts of conductions
Filler, 1~3 part of auxiliary agent mixing, are sufficiently stirred, grind, obtain corrosion-resistant conductive coating.In this step, the time of grinding is 25
~35min, if milling time is inadequate, will lead to gained corrosion-resistant conductive coating quality it is not uniform enough, led to influence anti-corrosion
The mechanical property of coating coated by electrocoating paint and the smoothness of appearance, and the fineness of corrosion-resistant conductive coating is 20~30 micro-
Rice, sufficiently fine corrosion-resistant conductive coating just can guarantee the smoothness of coating prepared by corrosion-resistant conductive coating.Resin includes epoxy
One of resin, polyester resin, amino resins, polyurethane resin or a variety of combinations and ketone-grouped resin, Huo Zheshu
Rouge is ketone-grouped resin.Conductive filler is carbon nanotube, metal fine powder, conductive titanium dioxide, conductive black, carbon fiber, graphite
One of alkene or a variety of combinations, wherein metal fine powder includes copper metal micro mist, silver metal micro mist, in aluminum metal micro mist
One or more combinations, conductive black include acetylene carbon black, conductive channel black, conductive furnace blacks, superconduct furnace blacks, spy
One of conductive furnace blacks or a variety of combinations, carbon fiber can be carbon nano-fiber.In this step, auxiliary agent includes point
Powder, defoaming agent and levelling agent, wherein dispersing agent is polyvinyl pyrrolidone, vinyl bis-stearamides, one in polyethylene glycol
Kind or a variety of combinations, dispersing agent be used for so that the solid matters such as resin, conductive filler are in the state of dispersion in a solvent, from
And it prevents from reuniting；Defoaming agent is dimethyl silicone polymer, polyoxyethylene polyoxy propyl alcohol amidogen ether, silicone emulsion, polyoxypropylene, polyoxy
One of propylene glycerin ether or a variety of combinations, defoaming agent are mainly used for inhibiting the generation of bubble in corrosion-resistant conductive coating, and
Accelerate vanishing for the bubble generated, keeps corrosion-resistant conductive coating more uniform；Levelling agent is diphenylpolysiloxane, polymethyl-benzene
One of radical siloxane, dimethyl silicone polymer or a variety of combinations, levelling agent are mainly used for increasing corrosion-resistant conductive coating
Permeability and mobility reduce a possibility that corrosion-resistant conductive coating generates spot and spot when brushing, increase spreadability, so that
Coating is more uniform, natural.In this step, resin loads conductive filler primarily as matrix, and the content of resin is direct
The acid-proof alkaline and weatherability of the antiseptic property such as coating of corrosion-resistant conductive coating can be arrived, while also directly affecting the painting of anti-corrosion conduction
The basic performance of material such as adhesive force, hardness etc..Conductive filler main function be in corrosion-resistant conductive coating Internal architecture conductive network,
Realize electric conductivity, the dosage and exterior appearance of conductive filler directly affect the electric conductivity of corrosion-resistant conductive coating, therefore, it is necessary to
The content of each component of strict control also has excellent to prepare while having good conductive property with antiseptic property
Good mechanical property, and homogeneous corrosion-resistant conductive coating.
Performance test:
(1) test of hardness
Hardness of paint film pencil measuring method reference " hardness of paint film pencil measuring method " (GB/T6739-1996), 50 × 120 ×
0.2~0.3mm3Paint film is prepared on the tinplate or aluminium sheet of specification, after paint film is done solid work, with Portable pencil scratch tester
Measurement.
Test equipment: HQ-A type Portable pencil scratch tester, Tianjin Jingke.
(2) measurement of paint film adhesion
Referring to " measuring method of paint film adhesion " (GB5210-85), in 3 pieces of 50 × 100 × 0.2~0.3mm3The horse of specification
Paint film is prepared on mouth iron plate or aluminium sheet, after paint film is done solid work, is measured under the conditions of constant temperature and humidity with adherometer.
Test equipment: II type Coating adhesion test instrument of QFI-, Tianjin Jingke.
(3) insulated paint paint film corrosion resistance measurement
" GB/T 1727-79 paint film is typically prepared method " prepares paint film on tinplate according to national standards.To paint film reality
After dry, by the paraffin and rosin blend edge sealing of paint film template 1:1.Then the 2/3 area immersion for template of painting is prepared
In corrosive liquid, the compartment time is taken out, and observes whether its surface has phenomena such as falling off, blister, get rusty and changing colour.
(4) paint film electrical property measures
Corrosion-resistant conductive coating is coated in factory 75mm, width is the substrate of 25mm, is hindered after solidification using ZC36 type 1017Q superelevation
Test resistance on 10-11A Micrometer of current.
Test equipment: ZC36 type Micrometer of current.
(5) measurement of coating layer thickness
After coating is completely dried, according to national standards GB1764-89 (79) measure thickness of dry film, template specification 50 ×
100 × 0.2~0.3mm3
Test equipment: CM10FH coating thickness detector, pioneer's detecting instrument Co., Ltd when the space of Shenyang.
Embodiment 1
Prepare solvent: by 30 parts of N-Methyl pyrrolidone parts, 30 parts of dimethyl acetamides, 20 parts of dimethylbenzene, 18 2 chloroethenes
Alkane, 2 parts of butyls are uniformly mixed, and prepare solvent.
It prepares corrosion-resistant conductive coating: 39 parts of resins (35 parts of ketone-grouped resins, 4 parts of epoxy resin), 18 parts of conductions is filled out
Expect (5 parts of graphenes, 5 parts of carbon nanotubes, 8 parts of conductive channel blacks), 40 parts of above-mentioned solvents, 1 part of auxiliary agent (0.5 part of polyvinyl pyrrolidone,
0.2 part of dimethyl silicone polymer, 0.3 part of diphenylpolysiloxane) mixing, after stirring, 25min is ground, test is thin
30 microns of degree.
Performance test: the corrosion-resistant conductive coating prepared through the invention is sprayed on substrate, and 400 DEG C are toasted 2 hours, is surveyed
Coating with a thickness of 200 microns, appearance is smooth, adhesion 1 grade, the concentrated sulfuric acid impregnate appearance it is unchanged, 50% sodium hydroxide is molten
2 hours appearances of liquid immersion are unchanged, and centimetre resistance is 0.27.
Embodiment 2
Prepare solvent: by 25 parts of N-Methyl pyrrolidone parts, 25 parts of dimethyl acetamides, 15 parts of dimethylbenzene, 15 parts of dichloros
Ethane, 1 part of butyl are uniformly mixed, and prepare solvent.
Prepare corrosion-resistant conductive coating: by 35 parts of resins (30 parts of ketone-grouped resin, 3 parts of epoxy resin, polyester resin 2
Part), 23 parts of conductive fillers (8 parts of copper metal micro mists, 5 parts superconduct furnace blacks, 10 parts of conductive titanium dioxides), 40 parts it is above-mentioned molten
Agent, 2 parts of auxiliary agents (1 part of vinyl bis-stearamides, 0.5 part of polyoxyethylene polyoxy propyl alcohol amidogen ether, 0.5 part of polymethyl-benzene base silicon oxygen
Alkane) mixing, stir after, grind 35min, test 20 microns of fineness.
Then the corrosion-resistant conductive coating prepared through the invention is sprayed on substrate, 400 DEG C are toasted 2 hours, and painting is measured
Layer with a thickness of 250 microns, appearance is smooth, adhesion 1 grade, the concentrated sulfuric acid impregnate appearance it is unchanged, 50% sodium hydroxide solution leaching
It is unchanged to steep 2 hours appearances, centimetre resistance is 0.34.
Embodiment 3
Prepare solvent: by 35 parts of N-Methyl pyrrolidone parts, 35 parts of dimethyl acetamides, 25 parts of dimethylbenzene, 20 parts of dichloros
Ethane, 3 parts of butyls are uniformly mixed, and prepare solvent.
Prepare corrosion-resistant conductive coating: 50 parts of resins (45 parts of ketone-grouped resins, 3 parts of epoxy resin, 2 parts of polyester resin),
17 parts of conductive fillers (5 parts of silver metal micro mists, 10 parts of conductive titanium dioxides, 2 parts of carbon nano-fibers), 30 parts of above-mentioned solvents, 3 parts of auxiliary agents
(1 part of polyethylene glycol, 1 part of silicone emulsion, 1 part of dimethyl silicone polymer) mixing after stirring, grinds 30min, test
25 microns of fineness.
Then the corrosion-resistant conductive coating prepared through the invention is sprayed on substrate, 400 DEG C are toasted 2 hours, and painting is measured
Layer with a thickness of 250 microns, appearance is smooth, adhesion 1 grade, the concentrated sulfuric acid impregnate appearance it is unchanged, 50% sodium hydroxide solution leaching
It is unchanged to steep 2 hours appearances, centimetre resistance is 0.29.
Embodiment 4
Prepare solvent: by 28 parts of N-Methyl pyrrolidone parts, 27 parts of dimethyl acetamides, 16 parts of dimethylbenzene, 16 parts of dichloros
Ethane, 1.5 parts of butyls are uniformly mixed, and prepare solvent.
Prepare corrosion-resistant conductive coating: 33 parts of resins (30 parts of ketone-grouped resins, 3 parts of amino resins), 25 parts of conductive fillers
(10 parts of high electric conductivity furnace blacks, 5 parts of aluminum metal micro mists, 10 parts of conductive titanium dioxides), 35 parts of above-mentioned solvents, 1.5 parts of auxiliary agents (0.5
Part polyvinyl pyrrolidone, 0.5 part of polyoxypropylene, 0.5 part of dimethyl silicone polymer) mixing, after stirring, grinding
33min tests 23 microns of fineness.
Then the corrosion-resistant conductive coating prepared through the invention is sprayed on substrate, 400 DEG C are toasted 2 hours, and painting is measured
Layer with a thickness of 180 microns, appearance is smooth, adhesion 1 grade, the concentrated sulfuric acid impregnate appearance it is unchanged, 50% sodium hydroxide solution leaching
It is unchanged to steep 2 hours appearances, centimetre resistance is 0.30.
Embodiment 5
Prepare solvent: by 32 parts of N-Methyl pyrrolidone parts, 32 parts of dimethyl acetamides, 23 parts of dimethylbenzene, 19 parts of dichloros
Ethane, 2.5 parts of butyls are uniformly mixed, and prepare solvent.
Prepare corrosion-resistant conductive coating: 40 parts of resins (35 parts of ketone-grouped resins, 2 parts of polyester resin, 3 parts of polyurethane trees
Rouge), 20 parts of conductive fillers (5 parts of conductive furnace blacks, 10 parts of carbon fibers, 5 parts of graphenes), 36 parts of above-mentioned solvents, 2 parts of auxiliary agents (1
Part polyethylene glycol, 0.5 part of polypropylene glycerol aether, 0.5 part of dimethyl silicone polymer) mixing, after stirring, grinding
28min tests 26 microns of fineness.
Then the corrosion-resistant conductive coating prepared through the invention is sprayed on substrate, 400 DEG C are toasted 2 hours, and painting is measured
Layer with a thickness of 250 microns, appearance is smooth, adhesion 1 grade, the concentrated sulfuric acid impregnate appearance it is unchanged, 50% sodium hydroxide solution leaching
It is unchanged to steep 2 hours appearances, centimetre resistance is 0.25.
Embodiment 6
Prepare solvent: by 30 parts of N-Methyl pyrrolidone parts, 29 parts of dimethyl acetamides, 18 parts of dimethylbenzene, 16 parts of dichloros
Ethane, 2 parts of butyls are uniformly mixed, and prepare solvent.
Prepare corrosion-resistant conductive coating: 45 parts of resins (45 parts of ketone-grouped resins), 22 parts of conductive filler (10 parts of conductive titanium whites
Powder, 7 parts of acetylene carbon blacks, 5 parts of carbon fibers), 38 parts of above-mentioned solvents, 2.5 parts of auxiliary agents (1 part of polyethylene glycol, 1 part of polyoxypropylene glyceryl
Ether, 0.5 part of dimethyl silicone polymer) mixing, after stirring, 26min is ground, tests 29 microns of fineness.
Then the corrosion-resistant conductive coating prepared through the invention is sprayed on substrate, 400 DEG C are toasted 2 hours, and painting is measured
Layer with a thickness of 200 microns, appearance is smooth, adhesion 1 grade, the concentrated sulfuric acid impregnate appearance it is unchanged, 50% sodium hydroxide solution leaching
It is unchanged to steep 2 hours appearances, centimetre resistance is 0.35.
Test result through the foregoing embodiment is it is found that coating prepared by corrosion-resistant conductive coating provided by the invention has
Good mechanical property, adhesive force is strong, and because corrosion-resistant conductive coating is homogeneous, fineness is small, so the appearance of coating is flat
It is sliding, and all there is good corrosion resistance to strong acid and highly basic, and resistance is small, conducts electricity very well.
The preparation method of corrosion-resistant conductive coating provided by the invention, by the way that resin, solvent, conductive filler are uniformly mixed,
Corrosion-resistant conductive coating is obtained after grinding.By selecting the poly(aryl ether ketone) tree splendid to the extreme environments tolerance such as strong acid and strong base high temperature
Rouge realizes adaptation of the corrosion-resistant conductive coating to extreme use environment, while selecting suitable conductive filler that can also remain good
Electric conductivity expanded significantly to guarantee that coating still has good conductive property in extreme environments such as strong acid and strong bases
The usage scenario of coating.It can be widely used in that corrosivity is strong, and easily on the surface of the object of surface stored charge, for example, boat
Empty space flight, petrochemical industry etc., wherein aerospace field mainly includes in special Aviation Fuel tank and warehouse, aircraft fuel tank
The positions such as outer surface, petrochemical industry mainly include speciality chemical holding vessel surfaces externally and internally, transport pipeline surfaces externally and internally, stone
Oil storage equipment surfaces externally and internally etc..
The above is merely preferred embodiments of the present invention, be not intended to limit the invention, it is all in spirit of the invention and
Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of preparation method of corrosion-resistant conductive coating, comprising:
In parts by weight, 33~50 parts of resins, 30~40 parts of solvents, 17~25 parts of conductive fillers, 1~3 part of auxiliary agent are mixed, is filled
Divide stirring, grinding obtains the corrosion-resistant conductive coating.
2. preparation method according to claim 1, which is characterized in that the resin includes epoxy resin, polyester resin, ammonia
One of base resin, polyurethane resin or a variety of combinations and ketone-grouped resin.
3. preparation method according to claim 1, which is characterized in that the solvent includes 25~35 according to parts by weight
Part N-Methyl pyrrolidone, 25~35 parts of dimethyl acetamides, 15~25 parts of dimethylbenzene, 15~20 parts of dichloroethanes, 1~3 part
Butyl.
4. preparation method according to claim 1, which is characterized in that the conductive filler be carbon nanotube, metal fine powder,
One of conductive titanium dioxide, conductive black, carbon fiber, graphene or a variety of combinations.
5. preparation method according to claim 1, which is characterized in that the auxiliary agent includes dispersing agent, defoaming agent and levelling
Agent.
6. preparation method according to claim 5, which is characterized in that the dispersing agent is polyvinyl pyrrolidone, vinyl
One of bis-stearamides, polyethylene glycol or a variety of combinations.
7. preparation method according to claim 5, which is characterized in that the defoaming agent is dimethyl silicone polymer, polyoxy
One of ethylene polyoxy propyl alcohol amidogen ether, silicone emulsion, polyoxypropylene, polypropylene glycerol aether or a variety of combinations.
8. preparation method according to claim 5, which is characterized in that the levelling agent is diphenylpolysiloxane, poly- first
One of base phenyl siloxane, dimethyl silicone polymer or a variety of combinations.
9. a kind of corrosion-resistant conductive coating of preparation method preparations described in any item according to claim 1~8.
10. corrosion-resistant conductive coating according to claim 9 is in the application of aerospace field and/or petrochemical industry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711195070.7A CN109836975A (en) | 2017-11-24 | 2017-11-24 | A kind of corrosion-resistant conductive coating and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711195070.7A CN109836975A (en) | 2017-11-24 | 2017-11-24 | A kind of corrosion-resistant conductive coating and its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109836975A true CN109836975A (en) | 2019-06-04 |
Family
ID=66878048
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711195070.7A Pending CN109836975A (en) | 2017-11-24 | 2017-11-24 | A kind of corrosion-resistant conductive coating and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109836975A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112094569A (en) * | 2020-08-26 | 2020-12-18 | 华东师范大学 | Corrosion-resistant anti-static high-infrared-emissivity coating and preparation method and application thereof |
| CN112646489A (en) * | 2020-12-22 | 2021-04-13 | 松山湖材料实验室 | Conductive coating and preparation method thereof |
| CN113004762A (en) * | 2019-12-19 | 2021-06-22 | 洛阳尖端技术研究院 | Electromagnetic shielding coating |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003011984A2 (en) * | 2001-07-31 | 2003-02-13 | Ppg Industries Ohio, Inc. | Weldable coating compositions having improved intercoat adhesion |
| KR20080101830A (en) * | 2008-09-30 | 2008-11-21 | 광 석 서 | Ultra-violet curable antistatic coating composition |
| CN103194142A (en) * | 2013-04-28 | 2013-07-10 | 吉林大学 | Antistatic high-temperature-resistant poly(ether-ether-ketone) coating and preparation method of antistatic high-temperature-resistant coating |
| CN105038446A (en) * | 2015-06-04 | 2015-11-11 | 上海电力学院 | Water-based anticorrosive conducting paint and preparation method thereof |
| CN106433084A (en) * | 2016-06-21 | 2017-02-22 | 江苏金陵特种涂料有限公司 | Graphene modified polyaryletherketone polymer material and preparation method thereof |
-
2017
- 2017-11-24 CN CN201711195070.7A patent/CN109836975A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003011984A2 (en) * | 2001-07-31 | 2003-02-13 | Ppg Industries Ohio, Inc. | Weldable coating compositions having improved intercoat adhesion |
| KR20080101830A (en) * | 2008-09-30 | 2008-11-21 | 광 석 서 | Ultra-violet curable antistatic coating composition |
| CN103194142A (en) * | 2013-04-28 | 2013-07-10 | 吉林大学 | Antistatic high-temperature-resistant poly(ether-ether-ketone) coating and preparation method of antistatic high-temperature-resistant coating |
| CN105038446A (en) * | 2015-06-04 | 2015-11-11 | 上海电力学院 | Water-based anticorrosive conducting paint and preparation method thereof |
| CN106433084A (en) * | 2016-06-21 | 2017-02-22 | 江苏金陵特种涂料有限公司 | Graphene modified polyaryletherketone polymer material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113004762A (en) * | 2019-12-19 | 2021-06-22 | 洛阳尖端技术研究院 | Electromagnetic shielding coating |
| CN112094569A (en) * | 2020-08-26 | 2020-12-18 | 华东师范大学 | Corrosion-resistant anti-static high-infrared-emissivity coating and preparation method and application thereof |
| CN112094569B (en) * | 2020-08-26 | 2022-03-25 | 华东师范大学 | Corrosion-resistant anti-static high-infrared-emissivity coating and preparation method and application thereof |
| CN112646489A (en) * | 2020-12-22 | 2021-04-13 | 松山湖材料实验室 | Conductive coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109836975A (en) | A kind of corrosion-resistant conductive coating and its preparation method and application | |
| CN107868567B (en) | Epoxy zinc powder primer, paint matching composition and application | |
| CN109762446A (en) | Water-base epoxy graphene zinc anticorrosive paint, preparation method and application | |
| CN107629593A (en) | Electrical equipment water-soluble multifunctional coating and preparation method thereof | |
| CN106519838B (en) | Weather-proof water soluble acrylic acid terrace paint coating and preparation method thereof | |
| CN110157296A (en) | One type graphite phase carbon nitride/epoxy resin corrosion resistant coating and its preparation method and application | |
| CN109749569A (en) | Two-component graphene anticorrosive paint and preparation method thereof | |
| CN103232786A (en) | Solvent-free nanometer epoxy anticorrosive paint and preparation method thereof | |
| CN109233551A (en) | A kind of wear-resistant ceramic antiseptin paint vehicle and preparation method thereof and coating method | |
| CN107556886A (en) | A kind of graphite-epoxy alkene zinc powder coating | |
| CN106243311A (en) | A kind of aqueous epoxy resin emulsion and preparation method thereof, cathode electrophoresis dope | |
| CN110128910A (en) | Anticorrosive paint and preparation method thereof | |
| CN105925138B (en) | A kind of anticorrosive paint and preparation method thereof for metal rusty scale | |
| CN111253827A (en) | Flake-type epoxy alkene-zinc primer and preparation method thereof | |
| CN110330865A (en) | Modified anti-corrosion primer of a kind of graphene and preparation method thereof | |
| CN104629619A (en) | Anti-scaling and drag-reducing coating for oil pipeline inner walls and preparation method thereof | |
| CN109608983A (en) | A kind of anticorrosive coating and preparation method thereof for underground petroleum storage tank | |
| CN110183882B (en) | Hydrophobic alcohol-soluble inorganic zinc silicate shop primer and preparation method thereof | |
| CN105585913A (en) | Transparent anti-rust paint for electrical equipment and preparation method of paint | |
| CN102408816A (en) | Epoxy ballast tank paint and preparation method thereof | |
| CN109321126A (en) | A kind of solvent-free anticorrosive paint and preparation method thereof | |
| CN108117816A (en) | A kind of nanometer modified epoxy zinc-rich paint | |
| CN109836976A (en) | Anti-corrosion self-cleaning coating and preparation method thereof | |
| CN104031496B (en) | A kind of electrostatic dura mater antirust paint and preparation method thereof | |
| CN110437715A (en) | A kind of water paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |