CN109825205A - A kind of black one-faced tapes and preparation method thereof with heat insulating function - Google Patents
A kind of black one-faced tapes and preparation method thereof with heat insulating function Download PDFInfo
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- CN109825205A CN109825205A CN201910040220.XA CN201910040220A CN109825205A CN 109825205 A CN109825205 A CN 109825205A CN 201910040220 A CN201910040220 A CN 201910040220A CN 109825205 A CN109825205 A CN 109825205A
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Abstract
A kind of black one-faced tapes with heat insulating function the invention discloses adiabatic gum with technical field, including the release layer successively contacted, heat-insulated acrylic acid glue-line, heat-insulated PET base membrane layer and insulating moulding coating layer, the release layer with a thickness of 23~75 microns, and release layer is preferably PET release film, the heat-insulated acrylic acid glue-line with a thickness of 5~15 microns, the heat-insulated acrylic acid glue-line includes rutile titanium dioxide, one of eakleite and hollow glass micropearl are a variety of, the insulating moulding coating layer includes acrylic emulsion 35-50wt%, rutile type titanium white 10-25wt%, sericite 1-8wt%, heat-reflecting heat-insulating powder 2.5-15wt%, hollow glass micropearl 5-20wt%, water 10-15wt%, auxiliary agent 2-20wt%, it is described Heat-insulated PET basement membrane with a thickness of 1.9~30 microns, the invention enables black one-faced tapes have preferable heat insulating function, can effectively improve heat-proof quality, stability, dispersion performance and the reflecting properties of adhesive tape entirety, strengthen the whole service performance of adhesive tape.
Description
Technical field
The present invention relates to adiabatic gum band technical field, specially a kind of black one-faced tapes and its system with heat insulating function
Preparation Method.
Background technique
In daily use process, black belt is easy to absorb light during use existing black one-faced tapes
Heat, and the appliance and electronic fastened by black belt is easy directly to conduct by adhesive tape to the outside of casing in adstante febre, it is existing
Some black one-faced tapes do not have excellent heat-proof quality, in order to reinforce the whole service performance of adhesive tape.For this purpose, it is proposed that
A kind of black one-faced tapes and preparation method thereof with heat insulating function.
Summary of the invention
The purpose of the present invention is to provide a kind of black one-faced tapes and preparation method thereof with heat insulating function, to solve
The problems mentioned above in the background art.
To achieve the above object, the invention provides the following technical scheme: a kind of black one-faced tapes with heat insulating function,
Including release layer, heat-insulated acrylic acid glue-line, heat-insulated PET base membrane layer and the insulating moulding coating layer successively contacted.
Further, the release layer with a thickness of 23~75 microns, and release layer is preferably PET release film.
Further, the heat-insulated acrylic acid glue-line with a thickness of 5~15 microns, the heat-insulated acrylic acid glue-line include gold
One of red stone-type titanium dioxide, eakleite and hollow glass micropearl are a variety of.
Further, the insulating moulding coating layer includes acrylic emulsion 35-50wt%, rutile type titanium white 10-
25wt%, sericite 1-8wt%, heat-reflecting heat-insulating powder 2.5-15wt%, hollow glass micropearl 5-20wt%, water 10-15wt%,
Auxiliary agent 2-20wt%.
Further, the heat-insulated PET basement membrane with a thickness of 1.9~30 microns.
Further, a kind of preparation method of the black one-faced tapes with heat insulating function:
1) the carbon black black color paste 6% that polyurethane resin 89% and solid content are 20% is stirred at 1000rpm
20min is added epoxide resin type curing additive 1%, 20min is stirred at 1000rpm, with two layers of 400 mesh metal filter screens
Filtering, obtaining black non-sticky can print printing ink paint, by acrylic acid adhesive 76%, the carbon black black color that solid content is 20%
Slurry 6%, ethyl acetate 14% and hexamethylene diisocyanate 4% mix, and the heat-insulated acrylic acid sizing material of black are obtained, then black
Color acrylic acid sizing material adds heat insulating function auxiliary agent, and 2~7 parts of heat insulating function selection of auxiliary of rutile titanium dioxide, hard silicon
One of calcium stone and hollow glass micropearl are a variety of, to obtain the heat-insulated acrylic acid glue-line of black；
2) by acrylic emulsion 35-50wt%, rutile type titanium white 10-25wt%, sericite 1-8wt%, heat reflection
Heat-insulating powder 2.5-15wt%, hollow glass micropearl 5-20wt%, water 10-15wt%, auxiliary agent 2-20wt% be mixed from
And prepare insulating moulding coating layer；
3) acrylic acid ester emulsion of phosphate ester-containing group is used, and the acrylic acid ester emulsion of phosphate ester-containing group passes through first
Acrylic monomers is obtained with the second acrylic monomers emulsion polymerization；Wherein the first acrylic monomers is phosphoester acrylic ester, the
Diacrylate monomer is selected from acrylic acid, butyl methacrylate, methyl methacrylate, butyl acrylate, acrylic acid-2-ethyl
One of own ester is a variety of.
4) one side of heat-insulated PET basement membrane is coated into the heat-insulated acrylic acid sizing material of black, solidification forms heat-insulated acrylic acid glue-line；
In the another side coating thermal insulating of heat-insulated PET basement membrane, solidification forms insulating moulding coating layer, then on heat-insulated acrylic acid glue-line
Release layer is covered, black one-faced tapes are obtained.
Compared with prior art, the beneficial effects of the present invention are: the present invention passes through heat-insulated acrylic acid glue-line, heat-insulated PET base
The setting of film layer and insulating moulding coating layer so that black one-faced tapes have preferable heat insulating function, while preparing heat-insulated painting
When the bed of material, heat-proof quality, the stability of adhesive tape entirety can be effectively improved using the acrylic acid ester emulsion of phosphate ester-containing group
Energy, dispersion performance and reflecting properties, strengthen the whole service performance of adhesive tape.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention.
In figure: 1 release layer, 2 heat-insulated acrylic acid glue-lines, 3 heat-insulated PET base membrane layers, 4 insulating moulding coating layers.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
Referring to Fig. 1, the present invention provides a kind of technical solution: a kind of black one-faced tapes with heat insulating function, including
Release layer 1, heat-insulated acrylic acid glue-line 2, heat-insulated PET base membrane layer 3 and the insulating moulding coating layer 4 successively contacted.
As shown in Figure 1, release layer 1 with a thickness of 23~75 microns, and release layer 1 be preferably PET release film；
As shown in Figure 1, heat-insulated acrylic acid glue-line 2 with a thickness of 5~15 microns, heat-insulated acrylic acid glue-line 2 include rutile
One of type titanium dioxide, eakleite and hollow glass micropearl are a variety of；
As shown in Figure 1, insulating moulding coating layer 4 includes acrylic emulsion 35-50wt%, rutile type titanium white 10-25wt%,
Sericite 1-8wt%, heat-reflecting heat-insulating powder 2.5-15wt%, hollow glass micropearl 5-20wt%, water 10-15wt%, auxiliary agent 2-
20wt%；
As shown in Figure 1, using the acrylic acid ester emulsion of phosphate ester-containing group, and the acrylic acid ester emulsion of phosphate ester-containing group
It is obtained by the first acrylic monomers and the second acrylic monomers emulsion polymerization；Wherein the first acrylic monomers is phosphate propylene
Acid esters, the second acrylic monomers are selected from acrylic acid, butyl methacrylate, methyl methacrylate, butyl acrylate, propylene
One of acid -2- ethylhexyl is a variety of；
As shown in Figure 1, heat-insulated PET basement membrane 3 with a thickness of 1.9~30 microns.
A kind of preparation method of the black one-faced tapes with heat insulating function:
1) the carbon black black color paste 6% that polyurethane resin 89% and solid content are 20% is stirred at 1000rpm
20min is added epoxide resin type curing additive 1%, 20min is stirred at 1000rpm, with two layers of 400 mesh metal filter screens
Filtering, obtaining black non-sticky can print printing ink paint, by acrylic acid adhesive 76%, the carbon black black color that solid content is 20%
Slurry 6%, ethyl acetate 14% and hexamethylene diisocyanate 4% mix, and the heat-insulated acrylic acid sizing material of black are obtained, then black
Color acrylic acid sizing material adds heat insulating function auxiliary agent, and 2~7 parts of heat insulating function selection of auxiliary of rutile titanium dioxide, hard silicon
One of calcium stone and hollow glass micropearl are a variety of, to obtain the heat-insulated acrylic acid glue-line 2 of black；
2) by acrylic emulsion 35-50wt%, rutile type titanium white 10-25wt%, sericite 1-8wt%, heat reflection
Heat-insulating powder 2.5-15wt%, hollow glass micropearl 5-20wt%, water 10-15wt%, auxiliary agent 2-20wt% be mixed from
And prepare insulating moulding coating layer 4；
3) one side of heat-insulated PET basement membrane 3 is coated into the heat-insulated acrylic acid sizing material of black, solidification forms heat-insulated acrylic acid glue-line
2；In the another side coating thermal insulating of heat-insulated PET basement membrane 3, solidification forms insulating moulding coating layer 4, then in heat-insulated acrylate glue
Release layer 1 is covered on layer 2, obtains black one-faced tapes.
Embodiment 1: 3 parts by weight Emulsifier (SDBS and OP-10 mass ratio is 2:1), 20 parts by weight of deionized water are added
In there-necked flask, pre-emulsification 15min.Then 7 the first acrylic monomers of parts by weight and 45 weight are added dropwise into reaction flask while stirring
The second acrylic monomers of part (20 parts by weight of butyl methacrylate, 5 parts by weight of methyl methacrylate, 2 parts by weight of acrylic acid,
15 parts by weight of butyl acrylate, 3 parts by weight of acrylic acid-2-ethyl caproite), 0.4 parts by weight initiator KPS, 3 parts by weight buffers
NaHCO3 and 20 parts by weight of deionized water.Rear high-speed stirred 1h is dripped, monomer pre-emulsion is obtained, it is spare.Take the pre- cream of monomer
Change liquid 1/3 is added in the four-hole bottle equipped with reflux condenser, blender and constant pressure funnel, and stirring is warming up to 82 DEG C.
Start that remaining 2/3 monomer pre-emulsion is slowly added dropwise when obvious blue light occurs in system, temperature control is added dropwise in 83 DEG C, 2h
It finishes.40 DEG C or so are cooled to after heat preservation 2h, 1.6 parts by weight neutralizer ammonium hydroxide are added, regulation system pH value is 8, filtering and discharging,
Obtain the acrylic emulsion for the phosphate ester-containing group that solid content is 42-48%, the acrylate glue for being 88:7:5 according to quality proportioning
Glutinous agent, rutile titanium dioxide and hexamethylene diisocyanate curing agent mix in the acrylic emulsion of phosphate ester-containing group
It closes, stirs 20min, obtain heat-insulated acrylic acid sizing material.
Embodiment 2: 3 parts by weight Emulsifier (SDBS and OP-10 mass ratio is 2:1), 20 parts by weight of deionized water are added
In there-necked flask, pre-emulsification 20min.Then 10 the first acrylic monomers of parts by weight and 42 weight are added dropwise into reaction flask while stirring
The second acrylic monomers of part (20 parts by weight of butyl methacrylate, 2 parts by weight of methyl methacrylate, 2 parts by weight of acrylic acid,
15 parts by weight of butyl acrylate, 3 parts by weight of acrylic acid-2-ethyl caproite), 0.4 parts by weight initiator KPS, 3 parts by weight buffers
NaHCO3 and 20 parts by weight of deionized water.Rear high-speed stirred 1h is dripped, monomer pre-emulsion is obtained, it is spare.Take the pre- cream of monomer
Change liquid 1/3 is added in the four-hole bottle equipped with reflux condenser, blender and constant pressure funnel, and stirring is warming up to 82 DEG C.
Start that remaining 2/3 monomer pre-emulsion is slowly added dropwise when obvious blue light occurs in system, temperature control is added dropwise in 84 DEG C, 3h
It finishes.40 DEG C or so are cooled to after heat preservation 2h, 1.6 parts by weight neutralizer ammonium hydroxide are added, regulation system pH value is 8, filtering and discharging,
Obtain the acrylic emulsion for the phosphate ester-containing group that solid content is 42-48%, the acrylate glue for being 85:4:2 according to quality proportioning
Glutinous agent, rutile titanium dioxide and hexamethylene diisocyanate curing agent mix in the acrylic emulsion of phosphate ester-containing group
It closes, stirs 20min, obtain heat-insulated acrylic acid sizing material.
Embodiment 3: according to following proportion carry out ingredient: HD-3268 polyurethane resin, styrene-maleic anhydride copolymer,
Distearyl acid ethylenediamine, propandiol butyl ether, toluene di-isocyanate(TDI) and rutile titanium dioxide mass ratio be 89:2:3:1:
Model HD-3268 polyurethane resin and styrene-maleic anhydride copolymer are stirred 20min at 1000rpm, added by 3:2
Distearyl acid ethylenediamine stirs 10min, stirs 10min after propandiol butyl ether and toluene di-isocyanate(TDI) is added, is eventually adding gold
Red stone-type titanium dioxide stirs 20min, obtains insulating moulding coating.
Embodiment 4: polyurethane resin, polycarboxylate sodium, the 2-Ethylhexyl Alcohol, propylene glycol fourth for the A-601 that refines model big day
The mass ratio of ether, hexamethylene diisocyanate and eakleite is 91:2:2:1:1:3, by the A-601 that refines above-mentioned model big day
Polyurethane resin and polycarboxylate sodium stir 20min at 1000rpm, add 2-Ethylhexyl Alcohol stirring 10min, be added two
Stir 10min after propylene glycol monomethyl ether and hexamethylene diisocyanate, be eventually adding eakleite stirring 20min, obtain every
Hot coating.
Table 1
| Performance ratio | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Heat-proof quality | It is excellent | It is excellent | It is good | It is good |
| Dispersion performance | It is excellent | It is excellent | It is excellent | It is good |
| Stability | It is excellent | It is excellent | It is good | It is excellent |
| Reflecting properties | It is excellent | It is excellent | It is good | It is good |
To sum up by the setting of heat-insulated acrylic acid glue-line, heat-insulated PET base membrane layer and insulating moulding coating layer described in table 1, so that black
Color one-faced tapes have preferable heat insulating function, while when preparing insulating moulding coating layer, using the propylene of phosphate ester-containing group
Acid esters lotion can effectively improve heat-proof quality, stability, dispersion performance and the reflecting properties of adhesive tape entirety.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (6)
1. a kind of black one-faced tapes with heat insulating function, including release layer (1), the heat-insulated acrylic acid glue-line successively contacted
(2), heat-insulated PET base membrane layer (3) and insulating moulding coating layer (4).
2. a kind of black one-faced tapes with heat insulating function according to claim 1, it is characterised in that: the release layer
(1) with a thickness of 23~75 microns, and release layer (1) is preferably PET release film.
3. a kind of black one-faced tapes with heat insulating function according to claim 1, it is characterised in that: described heat-insulated third
Olefin(e) acid glue-line (2) with a thickness of 5~15 microns, the heat-insulated acrylic acid glue-line (2) includes rutile titanium dioxide, hard silico-calcium
One of stone and hollow glass micropearl are a variety of.
4. a kind of black one-faced tapes with heat insulating function according to claim 1, it is characterised in that: the heat-insulated painting
The bed of material (4) includes acrylic emulsion 35-50wt%, rutile type titanium white 10-25wt%, sericite 1-8wt%, heat reflection every
Hot powder 2.5-15wt%, hollow glass micropearl 5-20wt%, water 10-15wt%, auxiliary agent 2-20wt%.
5. a kind of black one-faced tapes with heat insulating function according to claim 1, it is characterised in that: described heat-insulated
PET basement membrane (3) with a thickness of 1.9~30 microns.
6. a kind of preparation method of the black one-faced tapes with heat insulating function, it is characterised in that:
1) the carbon black black color paste 6% that polyurethane resin 89% and solid content are 20% is stirred into 20min at 1000rpm, added
Enter epoxide resin type curing additive 1%, stir 20min at 1000rpm, with two layers of 400 mesh metal filtration net filtrations, obtains
Black non-sticky can print printing ink paint, by acrylic acid adhesive 76%, the carbon black black color paste 6% that solid content is 20%, second
Acetoacetic ester 14% and hexamethylene diisocyanate 4% mix, and the heat-insulated acrylic acid sizing material of black are obtained, then in black acrylic
Sizing material adds heat insulating function auxiliary agent, and 2~7 parts of heat insulating function selection of auxiliary of rutile titanium dioxide, eakleite and sky
One of heart glass microballoon is a variety of, to obtain the heat-insulated acrylic acid glue-line (2) of black；
2) by acrylic emulsion 35-50wt%, rutile type titanium white 10-25wt%, sericite 1-8wt%, heat-reflecting heat-insulating
Powder 2.5-15wt%, hollow glass micropearl 5-20wt%, water 10-15wt%, auxiliary agent 2-20wt% be mixed making
Standby insulating moulding coating layer (4)；
3) acrylic acid ester emulsion of phosphate ester-containing group is used, and the acrylic acid ester emulsion of phosphate ester-containing group passes through the first propylene
Acid monomers are obtained with the second acrylic monomers emulsion polymerization；Wherein the first acrylic monomers is phosphoester acrylic ester, the two the third
Acrylic monomer is selected from acrylic acid, butyl methacrylate, methyl methacrylate, butyl acrylate, acrylic acid-2-ethyl caproite
One of or it is a variety of；
4) one side of heat-insulated PET basement membrane (3) is coated into the heat-insulated acrylic acid sizing material of black, solidification forms heat-insulated acrylic acid glue-line
(2)；In the another side coating thermal insulating of heat-insulated PET basement membrane (3), solidification is formed insulating moulding coating layer (4), then heat-insulated third
Release layer (1) is covered on olefin(e) acid glue-line (2), obtains black one-faced tapes.
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| CN201910040220.XA CN109825205A (en) | 2019-01-16 | 2019-01-16 | A kind of black one-faced tapes and preparation method thereof with heat insulating function |
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| CN201910040220.XA CN109825205A (en) | 2019-01-16 | 2019-01-16 | A kind of black one-faced tapes and preparation method thereof with heat insulating function |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112374259A (en) * | 2020-10-28 | 2021-02-19 | 南京尚达电子绝缘材料有限公司 | Black single-sided adhesive tape with heat insulation function and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073963A (en) * | 2011-10-26 | 2013-05-01 | 比亚迪股份有限公司 | Flame-retardant reflection insulation paint and preparation method thereof |
| CN206591069U (en) * | 2017-02-27 | 2017-10-27 | 东莞市吉晨胶粘制品有限公司 | A kind of ultra-thin black PET two-sided tapes |
| CN108424729A (en) * | 2018-05-11 | 2018-08-21 | 东莞市古川胶带有限公司 | A kind of black one-faced tapes and preparation method thereof with heat insulating function |
-
2019
- 2019-01-16 CN CN201910040220.XA patent/CN109825205A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073963A (en) * | 2011-10-26 | 2013-05-01 | 比亚迪股份有限公司 | Flame-retardant reflection insulation paint and preparation method thereof |
| CN206591069U (en) * | 2017-02-27 | 2017-10-27 | 东莞市吉晨胶粘制品有限公司 | A kind of ultra-thin black PET two-sided tapes |
| CN108424729A (en) * | 2018-05-11 | 2018-08-21 | 东莞市古川胶带有限公司 | A kind of black one-faced tapes and preparation method thereof with heat insulating function |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112374259A (en) * | 2020-10-28 | 2021-02-19 | 南京尚达电子绝缘材料有限公司 | Black single-sided adhesive tape with heat insulation function and preparation method thereof |
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Application publication date: 20190531 |