CN109811582A - A kind of cultural product aramid paper and its preparation method and application - Google Patents
A kind of cultural product aramid paper and its preparation method and application Download PDFInfo
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- CN109811582A CN109811582A CN201910053041.XA CN201910053041A CN109811582A CN 109811582 A CN109811582 A CN 109811582A CN 201910053041 A CN201910053041 A CN 201910053041A CN 109811582 A CN109811582 A CN 109811582A
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Abstract
The invention discloses a kind of cultural product aramid papers and its preparation method and application, the aramid paper is obtained using the coated sizing of aramid fiber body paper, it is with a thickness of 0.06-0.28mm, quantification of 22-80g/ ㎡, whiteness >=80%, mean tensile strength >=2N/cm in length and breadth, in length and breadth averagely tear strength >=1.5N, in length and breadth mean water absorption height >=2.5cm/180s.The preparation method includes the following steps: that drying, rewinding cut and produce qualified cultural product aramid paper using roll-type, air-blade type, scraper type coating by chemical industry synthesis glue or natural plant coating sizing on aramid fiber body paper.The aramid paper can be stored permanently, is non-aging.
Description
Technical field
The invention belongs to synthetic fibers paper technical fields, in particular it relates to a kind of cultural product aramid paper
And its preparation method and application.
Background technique
For many years, since plain paper main ingredient is plant fiber, inevitably understand insect bite, go rotten, natural aging, people are very
Difficulty sees the books before a century, calligraphy and painting.Though the paper storage days that fiber crops, cotton, bark fiber are done are a little long, but can not resistance to height
It is temperature, acid and alkali-resistance, radiation hardness, ageing-resistant, therefore, how to invent a kind of high temperature resistant, acid and alkali-resistance, radiation hardness, ageing-resistant cultural product
With paper be there is an urgent need to.
Aramid fiber satellite solar cell plate realizes that satellite sun energy photovoltaic battery panel is researched and developed with paper is the twentieth century U.S.
World's high-tech product；Aramid fiber industrial products are in recent years since aramid fiber has high-intensitive, high insulation, resistance to spoke with paper
It penetrates, superperformance resistant to high temperature, is used widely in electric power, electronics field, one is especially more won in terms of insulating materials
It raises.But due to the technical disadvantages of itself, following problems can be generated if being directly used in Writing-painting printing: being existed for a long time
Body paper whiteness declines under the influence of ultraviolet light, prints image difference and obscures, as shown in Figure 1, being used as dry and astringent not smooth when Writing-painting.
Summary of the invention
The object of the present invention is to provide a kind of cultural product paper made of aramid fiber, which can permanently be deposited
It puts, is non-aging.
In order to achieve the above objectives, present invention employs the following technical solutions:
A kind of cultural product aramid paper, the aramid paper are obtained using the coated sizing of aramid fiber body paper, with a thickness of
0.06-0.28mm, quantification of 22-80g/ ㎡, whiteness >=80%, mean tensile strength >=2N/cm, average anti-tear strong in length and breadth in length and breadth
Degree >=1.5N, in length and breadth mean water absorption height >=2.5cm/180s.
In the present invention, the aramid fiber body paper with a thickness of 0.06-0.28mm, quantification of 22-80g/ ㎡, whiteness >=82%,
Mean tensile strength >=2N/cm in length and breadth, in length and breadth averagely tear strength >=1.5N, mean water absorption height >=3.5cm/180s in length and breadth,
There is no dust.
Preferably, the coating sizing are as follows: by chemical industry synthesis glue or natural plant coating sizing on aramid fiber body paper,
Coating increases every square metre 3-5 grams of solid content.
It is further preferred that the chemical industry synthesis glue is selected from formaldehydeless modifying agent (color fixing Mldifier
Fomaldehyde-Free), alkyl ketene dimer (alkyl letene dimer, AKD), polyamideepichlorohydrin PPE,
One of aqueous silica sol liquid and Nano titanium dioxide antiultraviolet aqueous solvent are a variety of.
Rubber polymer used in the present invention is commercially available to be obtained, for example, formaldehydeless modifying agent is purchased from Shanghai seat base,
Deng.
It is further preferred that the natural plant is obtained using following methods: carambola rattan, willow rhizome crust and elm
One of rhizome crust or a variety of impregnate through water squeeze mucus or cryogenic vacuum water extraction mucus, and gained mucus is natural plant
Object glue.
The present invention also provides the preparation method of above-mentioned cultural product aramid paper, the preparation method includes following step
It is rapid:
Using roll-type, air-blade type, scraper type coating by chemical industry synthesis glue or natural plant coating sizing in aramid fiber body paper
On, drying, rewinding cut and produce qualified cultural product aramid paper.
Invention still further provides application of the above-mentioned cultural product paper in writing, drawing, printing.
Preferably, the printing is using aqueous pigment ink jet printing.
The present invention utilizes aramid fiber manufacturer production aramid fiber body paper, permanently stores by coating sizing production, is non-aging
Aramid fiber cultural product paper.
Aramid fiber body paper is glued its performance by coating and obviously changes, and calligraphy font is smooth, drawing printed pattern is good
It is good.
Because of aramid fiber molecule parallel layers structure, aramid fiber paper performance prepared by the present invention is sufficiently stable, aramid fiber
Cultural product is the ideal cultural product paper of people for a certainty with paper.
The appearance of aramid fiber cultural product paper of the present invention is achieved the hope for a long time dream of " paper Shou Qiannian " of people,
Also fundamentally solve National archives, technical literature, national treasure calligraphy and painting, ancient writings duplication, the long-range storage of humanity history data
Big problem, Social benefit and economic benefit can be further obvious in the future as the development of society.
Detailed description of the invention
Fig. 1 is aramid fiber body paper printing figure；
Fig. 2 is the hand-written calligraphy figure of writing brush using aramid paper of the present invention；
Fig. 3 is the handwritten drawings figure using aramid paper of the present invention；
Fig. 4 is the ink jet printing figure using aramid paper of the present invention；
Fig. 5 is to print figure one using aramid paper of the present invention；
Fig. 6 is to print figure two using aramid paper of the present invention；
Fig. 7 is degradation result figure of the present invention.
Specific embodiment
Any feature is disclosed to obtain in this specification, it unless specifically stated, can be equivalent or with similar purpose by other
Alternative features are replaced.Unless specifically stated, each feature is an example in a series of equivalent or similar characteristics
?.It is described to understand the present invention just for the sake of help, it should not be considered as to concrete restriction of the invention.
With the drawings and specific embodiments, the present invention is described in further detail below.
Chemical industry synthesis glue and natural plant used by embodiment are as follows:
1, chemical industry synthesis glue:
1) formaldehydeless modifying agent (color fixing Mldifier Fomaldehyde-Free)；
2) alkyl ketene dimer (alkyl letene dimer AKD)；
3) polyamideepichlorohydrin PPE；
4) aqueous silica sol liquid；
5) Nano titanium dioxide antiultraviolet aqueous solvent.
Above-mentioned chemical industry synthesis glue can dilute 2-3 times when in use.
2, natural plant:
1) carambola rattan, which is soaked in water, squeezes mucus or cryogenic vacuum water extraction mucus；
2) willow rhizome crust and elm rhizome crust, which are soaked in water, squeezes mucus or cryogenic vacuum water extraction mucus；
3) willow rhizome crust, which is soaked in water, squeezes mucus or cryogenic vacuum water extraction mucus；
4) elm rhizome crust, which is soaked in water, squeezes mucus or cryogenic vacuum water extraction mucus；
5) carambola rattan, willow rhizome crust and elm rhizome crust be soaked in water squeeze mucus or cryogenic vacuum water extract it is viscous
Liquid.
Embodiment 1 is using formaldehydeless modifying agent as coating glue, and embodiment 2 is using alkyl ketene dimer as coating
Glue, for embodiment 3 using polyamideepichlorohydrin PPE as coating glue, embodiment 4 is used as coating glue using aqueous silica sol liquid,
For embodiment 5 using Nano titanium dioxide antiultraviolet aqueous solvent as coating glue, embodiment 6 uses formaldehydeless modifying agent
With alkyl ketene dimer as coating glue, embodiment 7 uses alkyl ketene dimer and polyamideepichlorohydrin PPE conduct
It is coated with glue, embodiment 8 is using polyamideepichlorohydrin PPE and aqueous silica sol liquid as coating glue, and embodiment 9 is using formaldehydeless
Modifying agent and Nano titanium dioxide antiultraviolet aqueous solvent as coating glue, embodiment 10 use alkyl ketene dimer
With aqueous silica sol liquid as coating glue, embodiment 11 is using 1 in natural plant) as coating glue, embodiment 12 uses day
2 in right natural plant gum) as coating glue, embodiment 13 is using 3 in natural plant) as coating glue, embodiment 14 uses
4 in natural plant) as coating glue, embodiment 15 is using 5 in natural plant) as coating glue, embodiment 16 is adopted
Use formaldehydeless modifying agent and aqueous silica sol liquid as coating glue.
Aramid fiber body paper used in embodiment 1-16 with a thickness of 0.06-0.28mm, quantification of 22-80g/ ㎡, whiteness >=82%,
Mean tensile strength >=2N/cm in length and breadth, in length and breadth averagely tear strength >=1.5N, mean water absorption height >=3.5cm/180s in length and breadth,
There is no dust (buying is reached from Yantai celebrated scholar).
Embodiment 1-16
Using roll-type, air-blade type, scraper type coating by above-mentioned chemical industry synthesis glue or natural plant coating sizing in virtue
On synthetic fibre body paper, drying, rewinding cut and produce qualified cultural product aramid paper, and coating increases every square metre of solid content
3-5 grams.Gained cultural product is as shown in table 1 below with the technical indicator of paper aramid paper；
Table 1: aramid fiber cultural product paper technical indicator
Cultural product paper obtained by 1-16 of the embodiment of the present invention, equal ink jet printing image clearly print the books word being made into
Mark rectify, Portable durable, choose it is therein it is several as an example, as shown in Fig. 2-Fig. 6.Aramid fiber body paper is glued its property by coating
It can obviously change, calligraphy font smoothness (see Fig. 2)；It is good using same printing process drawing figure compared to Fig. 1
(see Fig. 3)；Ink jet printing image clearly (see Fig. 4)；It prints the books writing being made into rectify, Portable durable (see Fig. 5-6).
Degradation:
After 6 hours of 180 DEG C of high temperature ovens, newspaper, the books of plant fiber have turned yellow, have become fragile, mutually without leading
Power, such as the a-c in Fig. 7；Aramid fiber cultural product paper physical strength does not have much variations, moreover it is possible to which tension is anti-tear, and only whiteness is omited
Having reduces 3-5 degree, such as the d in Fig. 7.
From above-described embodiment as can be seen that aramid fiber cultural product paper excellent effect, can reach and permanently store, be not easy always
Change, can painting and calligraphy, the whole of printing (including Digital ink jet printing) require.
Technological parameter (such as temperature, time) section bound value of the invention and interval value can realize this law,
Embodiment numerous to list herein.
Ordinary skill in the art knowledge can be used in the unspecified content of the present invention.
It should be noted last that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting.Although ginseng
It is described the invention in detail according to embodiment, it will be apparent to an ordinarily skilled person in the art that technical side of the invention
Case is modified or replaced equivalently, and without departure from the spirit and scope of technical solution of the present invention, should all be covered in the present invention
Scope of the claims in.
Claims (8)
1. a kind of cultural product aramid paper, which is characterized in that the aramid paper is obtained using the coated sizing of aramid fiber body paper,
With a thickness of 0.06-0.28mm, quantification of 22-80g/ ㎡, whiteness >=80%, mean tensile strength >=2N/cm, average in length and breadth in length and breadth
Tear strength >=1.5N, in length and breadth mean water absorption height >=2.5cm/180s.
2. cultural product aramid paper according to claim 1, which is characterized in that the aramid fiber body paper with a thickness of
0.06-0.28mm, quantification of 22-80g/ ㎡, whiteness >=82%, mean tensile strength >=2N/cm, average anti-tear strong in length and breadth in length and breadth
Degree >=1.5N, in length and breadth mean water absorption height >=3.5cm/180s.
3. cultural product aramid paper according to claim 1, which is characterized in that the coating sizing are as follows: close chemical industry
On aramid fiber body paper, coating increases every square metre 3-5 grams of solid content for plastic or natural plant coating sizing.
4. cultural product aramid paper according to claim 3, which is characterized in that the chemical industry synthesis glue is selected from formaldehydeless
Modifying agent, alkyl ketene dimer, polyamideepichlorohydrin PPE, aqueous silica sol liquid and Nano titanium dioxide UV resistance
One of line aqueous solvent is a variety of.
5. cultural product aramid paper according to claim 3, which is characterized in that the natural plant is used with lower section
Method obtains: one of carambola rattan, willow rhizome crust and elm rhizome crust or a variety of impregnate through water squeeze mucus or low temperature
Vacuum water extracts mucus, and gained mucus is natural plant.
6. the preparation method of any one of the claim 1-5 cultural product aramid paper, the preparation method includes following step
It is rapid:
Chemical industry synthesis glue or natural plant coating sizing on aramid fiber body paper, are passed through using roll-type, air-blade type, scraper type coating
Drying, rewinding cut and produce qualified cultural product aramid paper.
7. application of any one of the claim 1-5 cultural product paper in writing, drawing, printing.
8. application according to claim 7, which is characterized in that the printing is using aqueous pigment ink jet printing.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910053041.XA CN109811582A (en) | 2019-01-21 | 2019-01-21 | A kind of cultural product aramid paper and its preparation method and application |
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| CN201910053041.XA CN109811582A (en) | 2019-01-21 | 2019-01-21 | A kind of cultural product aramid paper and its preparation method and application |
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Citations (5)
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|---|---|---|---|---|
| US20090214818A1 (en) * | 2008-02-26 | 2009-08-27 | E. I. Du Pont De Nemours And Company | Core having a high shear strength and articles made from same |
| CN101644013A (en) * | 2009-09-01 | 2010-02-10 | 金东纸业（江苏）股份有限公司 | Printing rice paper and manufacture method thereof |
| CN104594107A (en) * | 2014-12-29 | 2015-05-06 | 圣欧芳纶（江苏）股份有限公司 | Preparation method of meta-position aramid fiber synthetic fiber paper of imitated rice paper |
| CN104968858A (en) * | 2013-02-08 | 2015-10-07 | 杜邦帝人先进纸（日本）有限公司 | Colored aramid paper and process for producing same |
| CN106283888A (en) * | 2016-08-19 | 2017-01-04 | 张玉环 | A kind of high tenacity art painting paper using and preparation method thereof |
-
2019
- 2019-01-21 CN CN201910053041.XA patent/CN109811582A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090214818A1 (en) * | 2008-02-26 | 2009-08-27 | E. I. Du Pont De Nemours And Company | Core having a high shear strength and articles made from same |
| CN101644013A (en) * | 2009-09-01 | 2010-02-10 | 金东纸业（江苏）股份有限公司 | Printing rice paper and manufacture method thereof |
| CN104968858A (en) * | 2013-02-08 | 2015-10-07 | 杜邦帝人先进纸（日本）有限公司 | Colored aramid paper and process for producing same |
| CN104594107A (en) * | 2014-12-29 | 2015-05-06 | 圣欧芳纶（江苏）股份有限公司 | Preparation method of meta-position aramid fiber synthetic fiber paper of imitated rice paper |
| CN106283888A (en) * | 2016-08-19 | 2017-01-04 | 张玉环 | A kind of high tenacity art painting paper using and preparation method thereof |
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Application publication date: 20190528 |