CN109778091A - A kind of high-strength titanium alloy pipes case hardening process - Google Patents

A kind of high-strength titanium alloy pipes case hardening process Download PDF

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Publication number
CN109778091A
CN109778091A CN201711112604.5A CN201711112604A CN109778091A CN 109778091 A CN109778091 A CN 109778091A CN 201711112604 A CN201711112604 A CN 201711112604A CN 109778091 A CN109778091 A CN 109778091A
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China
Prior art keywords
titanium alloy
ultrasonic
processing
lathe
ultrasonic wave
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CN201711112604.5A
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Chinese (zh)
Inventor
吕淑敏
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Qingdao Sea Through Department Of Science And Technology Consulting Co Ltd
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Qingdao Sea Through Department Of Science And Technology Consulting Co Ltd
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Priority to CN201711112604.5A priority Critical patent/CN109778091A/en
Publication of CN109778091A publication Critical patent/CN109778091A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of outer surface method for curing for the high-strength titanium alloy pipes for belonging to materials processing technology field.Specifically ultrasonic wave processing dedicated tool is mounted on the knife rest of lathe;Frequency of use is that 30KHz supersonic generator carries out ultrasonic impact hardening processing to the outer surface of titanium alloy pipe, adjust lathe revolving speed, the wire velocity control for rotating titanium alloy pipe outer surface is in 10~20m/min, and the long feed speed control of ultrasonic wave dedicated tool is in 0.15~0.3mm;After completion of processing, ultrasonic equipment current value is transferred to 0.5A hereinafter, closing ultrasonic equipment.The present invention provides the technological parameters for using ultrasonic wave processing mode that high-strength titanium alloy pipes are carried out with Surface hardened layer processing on lathe high-strength titanium alloy pipes outer surface can be made to obtain optimal ultrasonic wave hardening effect by this technological operation.The technique can effectively improve the appearance surface hardness and wearability of titanium alloy pipe, reduce surface roughness.

Description

A kind of high-strength titanium alloy pipes case hardening process
Technical field
The invention belongs to materials processing technology field, in particular to the outer surface hardening side of a kind of high-strength titanium alloy pipes Method.Processing technology is hardened more particularly to a kind of outer surface ultrasonic impact of titanium alloy pipe, which can effectively improve titanium conjunction The appearance surface hardness and wearability of golden tubing reduce surface roughness.
Background technique
High-strength titanium alloy pipes have the characteristics that intensity is high, density is low, corrosion resistance and heat-resist, are Aeronautics and Astronautics, stone The ideal material of the fields such as oil, chemical industry, ship key position.But since the hardness of titanium alloy is lower, coefficient of friction is big, wear-resisting The disadvantages of property is poor, affects its service life and application range to a certain extent.Using suitable Case hardening techniques, do not dropping Under the premise of low matrix mechanical property, the surface hardness of titanium alloy pipe is improved, is to improve its surface abrasion resistance and service life Effective way, the application range of high-strength titanium alloy pipes can be expanded.Therefore, correlation engineering technical staff is to titanium alloy surface Hardening technique has carried out extensive research.
Metallic surface method for curing almost all is applied in the surface treatment of titanium alloy at present, open report can The surface-hardening treatment method for titanium alloy seen includes thermo-chemical treatment (gas nitriding, ionic nitriding), at shot blasting on surface Reason, ion implanting, surface anodization processing, surface-coating technology, vapor deposition film technology, electrical discharge machining, laser add Work etc..
The method of gas nitriding or ionic nitriding, although can be improved titanium alloy surface hardness, due to being seeped to improve Nitrogen efficiency, nitriding medium need to contain ammonia or nitrogen-hydrogen mixed gas, and nitridation process must carry out under higher high temperature, nitriding Hydrogen in these penetration enhancers easily causes titanium alloy to generate hydrogen embrittlement because inhaling hydrogen.Therefore, in nitriding process, it is not allow for the atmosphere of hydrogen In the presence of causing efficiency of nitridation extremely low, nitride layer depth and hardness are difficult to reach requirement.
Bead achievees the purpose that surface peening and making titanium alloy surface generate plastic deformation, but shot-peening can make The bright and clean surface roughness of the titanium alloy pipe of rolling increases, although improving the wearability of itself in this way, is easy to cause The other parts matched with the titanium alloy member generate abrasion.
The major advantage of ion implantation is that film layer is combined with matrix, and anti-strip ability is strong, and injection process does not require Substrate temperature is increased, so as to keep workpiece geometric accuracy.But ion implantation low efficiency, and existing ion implantation device Be not suitable for being surface-treated 3 meters of length or more of tubing.
Surface anodization processing is the common approach of raising titanium alloy corrosion resistance and wearability, but due to titanium alloy tube For material in processing and heat treatment process, surface easily forms dense oxidation film, must effectively remove in anodic oxidation, otherwise serious shadow Anodic oxidation film quality is rung, however its cleaning difficulty is larger.In addition, either removing original oxide layer or anodic oxidation Process requires to employ a large amount of acid, alkali and a variety of chemical reagent, considerably increases subsequent wastewater treatment cost, but also difficult To reach increasingly harsher environmental protection standard.
Surface-coating technology is to improve the antioxidative effective ways of titanium alloy, if but hard for improving titanium alloy surface Degree and wearability, this hard coat and being easy to happen for titanium alloy substrate crack and flake off.
Vapour deposition process prepares DLC film in titanium alloy surface, and the surface hardness and rub resistance of titanium alloy can be improved Property.But when Ti content is more than 9% in film, the hardness of film will decline, and film and basal body binding force are limited.
Laser melting coating processing is that the alloy powders such as CoCrW are formed cladding figure layer in titanium alloy surface, to improve titanium conjunction Golden watch surface hardness and wearability, but the uniformity of film layer, compactness and crack problem not yet solve, and this method is difficult to Realize all standing in long length titanium alloy pipe surface.
Differential arc oxidation (MAO) technology is that parent metal is directly become oxygen by micro-arc discharge area instantaneous high-temperature high-pressure sinter Compound ceramics, and thicker oxidation film is obtained, the hardness Gao Bingyu metallic matrix of film is well combined, and improves titanium alloy surface The performances such as wear-resistant, anticorrosive, heat shock resistance, with good application prospect.
Ultrasonic impact processing is to push percussion tool to rush with 10,000 times per second or more frequencies using powerful ultrasonic wave Metal object surface is hit, so that metal surface is generated biggish compactibility deformation, ultrasonic impact position is strengthened, to make metal The intensity and hardness of superficial layer all increase significantly, while reducing workpiece surface roughness.Chinese patent CN101503755, CN101502881 etc. provides only ultrasonic metallic surface processing device, does not provide specific processing technology.Chinese patent CN1013111972A, CN103072049A, CN103084648A, CN103084634A, CN103084608A are each provided Lathe, cylindrical grinder, planer, milling machine, boring machine are using Ultrasonic Machining to 5 kinds of materials such as carbon steel, stainless steel, cast iron, copper, aluminium Matter metallic surface processing technology.
So far, the related processing technology report that titanium alloy surface hardness is improved using ultrasonic impact processing method is had no Road.
Summary of the invention
The object of the present invention is to provide a kind of high-strength titanium alloy pipes case hardening process, specifically used lathe, frequency are 30KHz supersonic generator, ultrasonic surface processing unit (plant) and ultrasonic wave processing dedicated tool, adopt high-strength titanium alloy pipes surface It is hardened with ultrasonic impact processing technology, which comprises the steps of:
1) ultrasonic wave processing dedicated tool is mounted on the knife rest of lathe;
2) cable for connecting supersonic generator, ultrasonic surface processing unit (plant) and ultrasonic wave processing dedicated tool is connected;
3) high-strength titanium alloy pipes are clamped in lathe spindle, high-strength titanium alloy pipes are carrying out ultrasonic surface hardening processing Before need to meet following requirement:
A) straightness :≤1mm/m
B) external diameter circularity :≤0.05mm
C) outer diameter tolerance :≤0.1mm
D) surface roughness: Ra0.8~3.2 μm
E) ultrasonic wave processing surplus: 0.005~0.06mm;
4) tool position is adjusted, center and the tubing centre-height deviation≤± 0.5mm of cutter, and center cutter and tubing table are made Face contact and the pressure for applying 30~300kg to tubing;
5) ultrasonic equipment, adjustment ultrasonic device current value to 0.8A~1.2A are opened;
6) start lathe, adjust lathe revolving speed, the wire velocity control for rotating titanium alloy pipe outer surface in 10~20m/min, The long feed speed control of ultrasonic wave dedicated tool is in 0.15~0.3mm;
7) ultrasonic equipment current value is transferred to 0.5A hereinafter, closing ultrasonic equipment switch by completion of processing.
8) high-strength titanium alloy pipes surface is tested, the surface roughness value of tubing reaches Ra0.4 hereinafter, hardness mentions High by 25% or more, wearability significantly improves;Or automatic testing equipment is installed on lathe, hardness or roughness test are shown on the spot As a result.
The beneficial effects of the invention are as follows provide on lathe using ultrasonic wave processing mode to high-strength titanium alloy pipes into The technological parameter of row Surface hardened layer processing can make high-strength titanium alloy pipes outer surface obtain rough surface by this technological operation Angle value reaches Ra0.4 hereinafter, hardness improves 25% or more ultrasonic wave hardening effect.
Specific embodiment
The present invention provides a kind of high-strength titanium alloy pipes case hardening process, and specifically used lathe, frequency are 30KHz ultrasound Wave producer, ultrasonic surface processing unit (plant) and ultrasonic wave processing dedicated tool use ultrasonic wave to high-strength titanium alloy pipes surface Impact processing technology is hardened ,~by taking TC10 titanium alloy pipe as an example, it is specific as follows that ultrasonic surface impacts processing technology:
(1) equipment that the ultrasonic impact processing technology is used include lathe, output frequency be 30KHz supersonic generator, Ultrasonic surface processing unit (plant) and ultrasonic wave processing dedicated tool;
(2) ultrasonic wave processing dedicated tool is mounted on the knife rest of lathe;
(3) cable for connecting supersonic generator, ultrasonic surface processing unit (plant) and ultrasonic wave processing dedicated tool is connected;
(4) the TC10 titanium alloy pipe of 52 × Φ of Φ, 40 × 3000mm is clamped in lathe spindle, the mode that is loaded and turnery processing When it is consistent.Tubing bending deformation under tool pressure in order to prevent should install and use follow-rest.TC10 titanium alloy pipe is carrying out It needs to meet following requirement before ultrasonic surface hardening processing:
F) straightness :≤1mm/m
G) external diameter circularity :≤0.05mm
H) outer diameter tolerance :≤0.1mm
I) surface roughness: Ra0.8~1.6 μm
J) ultrasonic wave processing surplus: 0.01~0.03mm
(5) tool position is adjusted, center and the tubing centre-height deviation≤± 0.5mm of cutter, and center cutter and tubing are made Surface contact and the pressure for applying 30~300kg to tubing;
(6) ultrasonic equipment, adjustment ultrasonic device current value to 1.2A are opened;
(7) start lathe, adjust lathe revolving speed, the wire velocity control for rotating titanium alloy pipe outer surface is in 15m/min, ultrasound The long feed speed control of wave dedicated tool is in 0.2mm;
(8) after completion of processing, ultrasonic equipment current value is transferred to 0.5A hereinafter, closing ultrasonic equipment switch.

Claims (1)

1. a kind of high-strength titanium alloy pipes case hardening process, specifically used lathe, frequency are 30KHz supersonic generator, surpass Sound surface processing device and ultrasonic wave processing dedicated tool use ultrasonic impact processing technology to high-strength titanium alloy pipes surface It is hardened, which comprises the steps of:
1) ultrasonic wave processing dedicated tool is mounted on the knife rest of lathe;
2) cable for connecting supersonic generator, ultrasonic surface processing unit (plant) and ultrasonic wave processing dedicated tool is connected;
3) high-strength titanium alloy pipes are clamped in lathe spindle, high-strength titanium alloy pipes are carrying out ultrasonic surface hardening processing Before need to meet following requirement:
A) straightness :≤1mm/m
B) external diameter circularity :≤0.05mm
C) outer diameter tolerance :≤0.1mm
D) surface roughness: Ra0.8~3.2 μm
E) ultrasonic wave processing surplus: 0.005~0.06mm;
4) tool position is adjusted, center and the tubing centre-height deviation≤0.5mm of cutter, and center cutter and tube surfaces are made Contact and apply to tubing the pressure of 30~300kg;
5) ultrasonic equipment, adjustment ultrasonic device current value to 0.8A~1.2A are opened;
6) start lathe, adjust lathe revolving speed, the wire velocity control for rotating titanium alloy pipe outer surface in 10~20m/min, The long feed speed control of ultrasonic wave dedicated tool is in 0.15~0.3mm;
7) ultrasonic equipment current value is transferred to 0.5A hereinafter, closing ultrasonic equipment switch by completion of processing;
8) high-strength titanium alloy pipes surface is tested, the surface roughness value of tubing reaches Ra0.4 hereinafter, hardness improves 25% or more, wearability significantly improves;Or automatic testing equipment is installed on lathe, hardness or roughness test knot are shown on the spot Fruit.
CN201711112604.5A 2017-11-13 2017-11-13 A kind of high-strength titanium alloy pipes case hardening process Pending CN109778091A (en)

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Application Number Priority Date Filing Date Title
CN201711112604.5A CN109778091A (en) 2017-11-13 2017-11-13 A kind of high-strength titanium alloy pipes case hardening process

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Application Number Priority Date Filing Date Title
CN201711112604.5A CN109778091A (en) 2017-11-13 2017-11-13 A kind of high-strength titanium alloy pipes case hardening process

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CN109778091A true CN109778091A (en) 2019-05-21

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110666454A (en) * 2019-09-29 2020-01-10 江苏纽麦托钛业有限公司 High-strength small-diameter titanium alloy pipe for orthopedics department

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110666454A (en) * 2019-09-29 2020-01-10 江苏纽麦托钛业有限公司 High-strength small-diameter titanium alloy pipe for orthopedics department

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Application publication date: 20190521