CN109776025B - Composite environment-friendly washing stone material and preparation method thereof - Google Patents
Composite environment-friendly washing stone material and preparation method thereof Download PDFInfo
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- CN109776025B CN109776025B CN201910049990.0A CN201910049990A CN109776025B CN 109776025 B CN109776025 B CN 109776025B CN 201910049990 A CN201910049990 A CN 201910049990A CN 109776025 B CN109776025 B CN 109776025B
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- 239000004575 stone Substances 0.000 title claims abstract description 68
- 238000005406 washing Methods 0.000 title claims abstract description 45
- 239000002131 composite material Substances 0.000 title claims abstract description 42
- 239000000463 material Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000002245 particle Substances 0.000 claims abstract description 63
- 239000004033 plastic Substances 0.000 claims abstract description 57
- 229920003023 plastic Polymers 0.000 claims abstract description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000011347 resin Substances 0.000 claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 26
- 239000011435 rock Substances 0.000 claims abstract description 23
- 239000002994 raw material Substances 0.000 claims abstract description 22
- 239000002699 waste material Substances 0.000 claims abstract description 20
- 238000005187 foaming Methods 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 17
- 238000007493 shaping process Methods 0.000 claims description 21
- 238000007710 freezing Methods 0.000 claims description 14
- 230000008014 freezing Effects 0.000 claims description 14
- 238000001746 injection moulding Methods 0.000 claims description 14
- 238000005303 weighing Methods 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000003431 cross linking reagent Substances 0.000 claims description 9
- 239000003242 anti bacterial agent Substances 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 238000004806 packaging method and process Methods 0.000 claims description 7
- 239000012257 stirred material Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 239000002893 slag Substances 0.000 claims description 2
- 238000012545 processing Methods 0.000 abstract description 10
- 239000002351 wastewater Substances 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000002347 injection Methods 0.000 abstract description 2
- 239000007924 injection Substances 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 25
- 238000003912 environmental pollution Methods 0.000 description 8
- 230000008569 process Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000013461 design Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/10—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Filtering Materials (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a novel composite environment-friendly water stone washing material which comprises the following raw materials in parts by weight: 15-30 parts of environment-friendly resin particles, 15-30 parts of plastic particles, 10-20 parts of foaming powder and 10-20 parts of natural volcanic rock ballast, wherein the plastic particles are waste recyclable plastic raw materials. The invention also discloses a preparation method of the composite environment-friendly water stone new material, the processing technology is simple, the raw material source is wide, the product is generated through an injection mold, the stability is high, the raw material does not need to be imported, and the wastewater pollution is not caused.
Description
Technical Field
The invention relates to the technical field of clothes washing industry, in particular to a novel composite environment-friendly washing stone material and a preparation method thereof.
Background
The cloth is dyed and needs washing water through a process, so that the cloth is not easy to fade, the process needs to use a stone, namely the washing stone, the washing stone special for environment-friendly washing water of clothes, is the latest product washing stone used for grinding and washing in the textile washing water industry, and can wash out clothes with different effects by products of different types, particularly the washing water industry of jeans, the effect is more obvious, the production technology is easy to master, the cost of the washing stone is saved due to the strong wear resistance of the environment-friendly washing stone and the consumption of the volcanic stone, the washing time is shortened, water is greatly saved, a plurality of production links using the natural volcanic stone are invisibly reduced, but most of the prior art adopts the natural volcanic stone as the washing stone, and the cost of import is relatively high due to the fact that the natural volcanic stone completely depends on the import, so that the cost of how to design is relatively low, the artificial absorbent stone can reduce the generation of sewage and sludge in a large proportion, has good stability and ensures environmental protection, and is particularly important.
Disclosure of Invention
The invention aims to solve the defects of the prior art and provide a novel composite environment-friendly water stone washing material and a preparation method thereof. The invention adopts environment-friendly resin, various waste plastics and natural volcanic rock slag to form an environment-friendly product through a series of processing, has obvious effects on saving the material cost of enterprises and protecting the environment, has simple operation of the product, can be recycled, ensures that the finished product of the enterprise is more stable in production, does not generate a large amount of waste water and waste residue, and is more environment-friendly in final processing.
In order to achieve the purpose, the invention designs a novel composite environment-friendly water stone washing material and a preparation method thereof, wherein the composite environment-friendly water stone washing material comprises the following raw materials in parts by weight: 15-30 parts of environment-friendly resin particles, 15-30 parts of plastic particles, 10-20 parts of foaming powder and 10-20 parts of natural volcanic rock ballast, wherein the plastic particles are waste recyclable plastic raw materials.
Furthermore, the composite environment-friendly water washing stone also comprises 5-10 parts of an antibacterial agent.
Furthermore, the composite environment-friendly water washing stone also comprises 3-5 parts of a cross-linking agent.
Further, the composite environment-friendly water stone also comprises 1-5 parts of a wear-resisting agent.
Further, the composite environment-friendly water washing stone comprises the following raw materials in parts by weight: 20 parts of environment-friendly resin particles, 28 parts of plastic particles, 15 parts of foaming powder and 18 parts of natural volcanic rock residues.
The invention also discloses a preparation method of the composite environment-friendly new water stone washing material, which specifically comprises the following steps:
1) crushing the environment-friendly resin into particles, and weighing the environment-friendly resin particles with determined parts for later use;
2) grinding plastic into powdery plastic particles and weighing the plastic particles in a determined part for later use;
3) putting the particles obtained in the step (1) and the step (2) into a stirrer, adding foaming powder and natural volcanic rock ballast, and uniformly stirring;
4) and then obtaining models of various nature-imitated volcanic stone molds with different shapes, putting the uniformly stirred materials into an injection molding machine for shaping, then quickly taking down the products from the nature-imitated volcanic stone molds corresponding to the injection molding machine, putting the products into a refrigerator in time for quick freezing and shaping, and packaging the products after freezing and shaping to obtain the novel composite environment-friendly washable stone.
Further, an antibacterial agent is also added in step 3.
Further, a crosslinking agent is also added in step 3.
Further, an anti-wear agent is added in step 3.
The novel composite environment-friendly water stone washing material and the preparation method thereof have the advantages that the processing technology is simple, the raw material source is wide, the product is generated through an injection mold, the stability is high, the raw material does not need to be imported, and the wastewater pollution is avoided.
Detailed Description
The invention will be further described with reference to the following examples.
Example 1:
the embodiment provides a new composite environment-friendly water stone washing material, which comprises the following raw materials in parts by weight: 15-30 parts of environment-friendly resin particles, 15-30 parts of plastic particles, 10-20 parts of foaming powder and 10-20 parts of natural volcanic rock ballast, wherein the plastic particles are waste recyclable plastic raw materials.
Further, the composite environment-friendly water washing stone comprises the following raw materials in parts by weight: 20 parts of environment-friendly resin particles, 28 parts of plastic particles, 15 parts of foaming powder and 18 parts of natural volcanic rock residues.
The embodiment also discloses a preparation method of the composite environment-friendly new water stone washing material, which specifically comprises the following steps:
1) crushing the environment-friendly resin into particles, and weighing the environment-friendly resin particles with determined parts for later use;
2) grinding plastic into powdery plastic particles and weighing the plastic particles in a determined part for later use;
3) putting the particles obtained in the step (1) and the step (2) into a stirrer, adding foaming powder and natural volcanic rock ballast, and uniformly stirring;
4) and then obtaining models of various nature-imitated volcanic stone molds with different shapes, putting the uniformly stirred materials into an injection molding machine for shaping, then quickly taking down the products from the nature-imitated volcanic stone molds corresponding to the injection molding machine, putting the products into a refrigerator in time for quick freezing and shaping, and packaging the products after freezing and shaping to obtain the novel composite environment-friendly washable stone.
The technical effect of the embodiment is as follows: the environment-friendly product is formed by processing environment-friendly resin, various waste plastics and natural volcanic rock residues in a series of ways, has obvious effects on saving the material cost of enterprises and protecting the environment, is simple to operate, can be recycled, enables the finished products of the enterprises to be more stable in production, does not produce a large amount of waste water and waste residues, and is more environment-friendly in final processing.
The invention and test data show that the link pollution is more than 80% under the condition that the waste plastics are not recycled, the environmental pollution of the waste plastics in the processing process is reduced to be less than 50% by the invention, and the environmental pollution is less when the composite environment-friendly water washing stone is prepared, and the cost of the volcanic rock ballast is increased by the invention and is reduced by 30% compared with the existing cost.
Example 2:
the embodiment provides a new composite environment-friendly water stone washing material, which comprises the following raw materials in parts by weight: 25 parts of environment-friendly resin particles, 28 parts of plastic particles, 18 parts of foaming powder and 15 parts of natural volcanic rock residues, wherein the plastic particles are waste recyclable plastic raw materials.
Furthermore, the composite environment-friendly water washing stone also comprises 5-10 parts of an antibacterial agent. In the present embodiment, the antimicrobial agent is 8 parts.
The embodiment also discloses a preparation method of the composite environment-friendly new water stone washing material, which specifically comprises the following steps:
1) crushing the environment-friendly resin into particles, and weighing the environment-friendly resin particles with determined parts for later use;
2) grinding plastic into powdery plastic particles and weighing the plastic particles in a determined part for later use;
3) putting the particles obtained in the step (1) and the step (2) into a stirrer, adding foaming powder, an antibacterial agent and natural volcanic rock ballast, and uniformly stirring;
4) and then obtaining models of various nature-imitated volcanic stone molds with different shapes, putting the uniformly stirred materials into an injection molding machine for shaping, then quickly taking down the products from the nature-imitated volcanic stone molds corresponding to the injection molding machine, putting the products into a refrigerator in time for quick freezing and shaping, and packaging the products after freezing and shaping to obtain the novel composite environment-friendly washable stone.
The invention and test data show that the link pollution is more than 80% under the condition that the waste plastics are not recycled, the environmental pollution of the waste plastics in the processing process is reduced to be less than 50% by the invention, and the environmental pollution is less when the composite environment-friendly water washing stone is prepared, and the cost of the volcanic rock ballast is increased by the invention and is reduced by 20% compared with the existing cost.
Example 3:
the embodiment provides a new composite environment-friendly water stone washing material, which comprises the following raw materials in parts by weight: 16 parts of environment-friendly resin particles, 17 parts of plastic particles, 17 parts of foaming powder and 14 parts of natural volcanic rock residues, wherein the plastic particles are waste recyclable plastic raw materials.
Furthermore, the composite environment-friendly water washing stone also comprises 3-5 parts of a cross-linking agent. In this example, the crosslinking agent is 4 parts.
The embodiment also discloses a preparation method of the composite environment-friendly new water stone washing material, which specifically comprises the following steps:
1) crushing the environment-friendly resin into particles, and weighing the environment-friendly resin particles with determined parts for later use;
2) grinding plastic into powdery plastic particles and weighing the plastic particles in a determined part for later use;
3) putting the particles obtained in the step (1) and the step (2) into a stirrer, adding foaming powder, a cross-linking agent and natural volcanic rock ballast, and uniformly stirring;
4) and then obtaining models of various nature-imitated volcanic stone molds with different shapes, putting the uniformly stirred materials into an injection molding machine for shaping, then quickly taking down the products from the nature-imitated volcanic stone molds corresponding to the injection molding machine, putting the products into a refrigerator in time for quick freezing and shaping, and packaging the products after freezing and shaping to obtain the novel composite environment-friendly washable stone.
The invention and test data show that the link pollution is more than 80% under the condition that the waste plastics are not recycled, the environmental pollution of the waste plastics in the processing process is reduced to be less than 60% by the invention, and the environmental pollution is less when the composite environment-friendly water washing stone is prepared, and the cost of the volcanic rock ballast is increased by the invention and is reduced by 25% compared with the existing cost.
Example 4:
the embodiment provides a new composite environment-friendly water stone washing material, which comprises the following raw materials in parts by weight: 18 parts of environment-friendly resin particles, 29 parts of plastic particles, 19 parts of foaming powder and 19 parts of natural volcanic rock residues, wherein the plastic particles are waste recyclable plastic raw materials.
Further, the composite environment-friendly water stone also comprises 1-5 parts of a wear-resisting agent. In this example, the anti-wear agent is 3 parts.
The embodiment also discloses a preparation method of the composite environment-friendly new water stone washing material, which specifically comprises the following steps:
1) crushing the environment-friendly resin into particles, and weighing the environment-friendly resin particles with determined parts for later use;
2) grinding plastic into powdery plastic particles and weighing the plastic particles in a determined part for later use;
3) putting the particles obtained in the step (1) and the step (2) into a stirrer, adding foaming powder, a wear-resisting agent and natural volcanic rock ballast, and uniformly stirring;
4) and then obtaining models of various nature-imitated volcanic stone molds with different shapes, putting the uniformly stirred materials into an injection molding machine for shaping, then quickly taking down the products from the nature-imitated volcanic stone molds corresponding to the injection molding machine, putting the products into a refrigerator in time for quick freezing and shaping, and packaging the products after freezing and shaping to obtain the novel composite environment-friendly washable stone.
After verification: the invention and test data show that the link pollution is more than 80% under the condition that the waste plastics are not recycled, the environmental pollution of the waste plastics in the processing process is reduced to be less than 70% by the invention, and the environmental pollution is less when the composite environment-friendly water washing stone is prepared, and the cost of the volcanic rock ballast is increased by the invention and is reduced by 35% compared with the existing cost.
Example 5:
the embodiment provides a new composite environment-friendly water stone washing material, which comprises the following raw materials in parts by weight: 29 parts of environment-friendly resin particles, 16 parts of plastic particles, 18 parts of foaming powder and 19 parts of natural volcanic rock residues, wherein the plastic particles are waste recyclable plastic raw materials.
Further, the composite environment-friendly water washing stone also comprises 9 parts of an antibacterial agent, 3.5 parts of a cross-linking agent and 2 parts of a wear-resisting agent.
The embodiment also discloses a preparation method of the composite environment-friendly new water stone washing material, which specifically comprises the following steps:
1) crushing the environment-friendly resin into particles, and weighing the environment-friendly resin particles with determined parts for later use;
2) grinding plastic into powdery plastic particles and weighing the plastic particles in a determined part for later use;
3) putting the particles obtained in the step (1) and the step (2) into a stirrer, adding foaming powder and natural volcanic rock ballast, and uniformly stirring;
4) and then obtaining models of various nature-imitated volcanic stone molds with different shapes, putting the uniformly stirred materials into an injection molding machine for shaping, then quickly taking down the products from the nature-imitated volcanic stone molds corresponding to the injection molding machine, putting the products into a refrigerator in time for quick freezing and shaping, and packaging the products after freezing and shaping to obtain the novel composite environment-friendly washable stone.
Further, an antibacterial agent is also added in step 3.
Further, a crosslinking agent is also added in step 3.
Further, an anti-wear agent is added in step 3.
While there have been shown and described what are at present considered the fundamental principles and essential features of the invention and its advantages, it will be apparent to those skilled in the art that the invention is not limited to the details of the foregoing exemplary embodiments, but is capable of other specific forms without departing from the spirit or essential characteristics thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (1)
1. A method for preparing a composite environment-friendly water-washing stone material,it is characterized in that the composite environment-friendly water washing stone comprises The raw materials are prepared by the following parts: 15-30 parts of environment-friendly resin particles, 15-30 parts of plastic particles, 10-20 parts of foaming powder and 10-20 parts of volcanic rock slag, 5-10 parts of antibacterial agent, 3-5 parts of cross-linking agent and 1-5 parts of wear-resisting agent, and the plastic particles Is a waste recyclable plastic raw material;
the preparation method specifically comprises the following steps:
1) crushing the environment-friendly resin into particles, and weighing the environment-friendly resin particles with determined parts for later use;
2) grinding plastic into powdery plastic particles and weighing the plastic particles in a determined part for later use;
3) putting the particles obtained in the step (1) and the step (2) into a stirrer, adding foaming powder, an antibacterial agent, a cross-linking agent, an anti-wear agent and natural volcanic rock ballast, and uniformly stirring;
4) and then obtaining models of various nature-imitated volcanic stone molds with different shapes, putting the uniformly stirred materials into an injection molding machine for shaping, then quickly taking down the products from the nature-imitated volcanic stone molds corresponding to the injection molding machine, putting the products into a refrigerator in time for quick freezing and shaping, and packaging the products after freezing and shaping to obtain the composite environment-friendly washable stone.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910049990.0A CN109776025B (en) | 2019-01-18 | 2019-01-18 | Composite environment-friendly washing stone material and preparation method thereof |
| PCT/CN2019/089820 WO2020147247A1 (en) | 2019-01-18 | 2019-06-03 | Composite environmentally friendly washed stone material and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910049990.0A CN109776025B (en) | 2019-01-18 | 2019-01-18 | Composite environment-friendly washing stone material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN109776025A CN109776025A (en) | 2019-05-21 |
| CN109776025B true CN109776025B (en) | 2020-06-23 |
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| CN201910049990.0A Active CN109776025B (en) | 2019-01-18 | 2019-01-18 | Composite environment-friendly washing stone material and preparation method thereof |
Country Status (2)
| Country | Link |
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| CN (1) | CN109776025B (en) |
| WO (1) | WO2020147247A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109776025B (en) * | 2019-01-18 | 2020-06-23 | 中山市粤漳科技有限公司 | Composite environment-friendly washing stone material and preparation method thereof |
| CN110819003B (en) * | 2019-11-13 | 2020-08-07 | 佛山市敬展纺织材料有限公司 | Washing material replacing pumice and preparation method thereof |
| CN110819002B (en) * | 2019-11-13 | 2020-07-28 | 佛山市敬展纺织材料有限公司 | Environment-friendly nontoxic jeans garment washing material |
| CN113698227A (en) * | 2021-09-07 | 2021-11-26 | 中山市诚力通通信科技有限公司 | Water washing stone and processing method for water washing stone |
| CN114276048A (en) * | 2022-01-04 | 2022-04-05 | 奇磊环保材料科技(云浮)有限公司 | Artificial plastic pumice and preparation method thereof |
| CN114752174B (en) * | 2022-04-28 | 2023-05-23 | 益科能(中山)新材料科技有限公司 | Artificial composite environment-friendly stone for ready-made clothes washing process and preparation method thereof |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US3948294A (en) * | 1972-03-01 | 1976-04-06 | Ameron, Inc. | Impact-protective coating for plastic pipe |
| US5367734A (en) * | 1991-11-04 | 1994-11-29 | Terry; Raymond | Pliable abrasive pellet for abrading fabrics |
| JPH0911134A (en) * | 1995-06-29 | 1997-01-14 | Kosaka Boole Sangyo Kk | Abrasive |
| KR20000054071A (en) * | 2000-05-04 | 2000-09-05 | 서동진 | Wing Bat and Double Labrador |
| CN2594288Y (en) * | 2002-11-26 | 2003-12-24 | 王鸿涓 | Environmental protection washing float stone |
| CN1583662A (en) * | 2004-06-04 | 2005-02-23 | 林柄楠 | Water washing stone for ceramic products and producing method thereof |
| CN2730875Y (en) * | 2004-06-04 | 2005-10-05 | 林柄楠 | Ceramic washed-granolithic |
| CN101386499A (en) * | 2007-09-13 | 2009-03-18 | 江苏通州四建集团有限公司 | Light building material and manufacturing method thereof |
| CN101230144A (en) * | 2007-12-28 | 2008-07-30 | 刘俊松 | All-natural moisture-retention dust-proof insulation weeding multifunctional environmental material |
| CN101245156A (en) * | 2008-02-28 | 2008-08-20 | 戴福寿 | Bamboo-plastic composite material |
| CN101429008B (en) * | 2008-11-26 | 2011-11-23 | 惠州市恒晖环保洗水石有限公司 | Waste ceramic produced environment friendly filter water stone n. and method for producing the same |
| CN201376940Y (en) * | 2009-04-15 | 2010-01-06 | 谢林杰 | Environment-friendly washing stone produced by ceramic waste regeneration |
| CN202029052U (en) * | 2010-12-27 | 2011-11-09 | 于泽洋 | A pumice rubbing block |
| CN109776025B (en) * | 2019-01-18 | 2020-06-23 | 中山市粤漳科技有限公司 | Composite environment-friendly washing stone material and preparation method thereof |
-
2019
- 2019-01-18 CN CN201910049990.0A patent/CN109776025B/en active Active
- 2019-06-03 WO PCT/CN2019/089820 patent/WO2020147247A1/en active Application Filing
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| CN109776025A (en) | 2019-05-21 |
| WO2020147247A1 (en) | 2020-07-23 |
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