CN109775854A - The multiple continuous bioreactor of ring and sewage treatment process - Google Patents

The multiple continuous bioreactor of ring and sewage treatment process Download PDF

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CN109775854A
CN109775854A CN201910102794.5A CN201910102794A CN109775854A CN 109775854 A CN109775854 A CN 109775854A CN 201910102794 A CN201910102794 A CN 201910102794A CN 109775854 A CN109775854 A CN 109775854A
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mixed liquor
reactor
ring
water
lattice
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吴永刚
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Abstract

The invention belongs to sewage treatment fields, and in particular to a kind of continuous bioreactor of ring and sewage treatment process again.Reactor of the invention includes more lattice bioreactors of filler built in concatenated partial region and aerator, it is multiple can be from the stripping tube and a set of reflux canal of each reaction grid device water outlet bottom backflow mixed liquor, when pending water passes through the reactor, form continuous ring type water flow and mixed liquor reflux all linked with one another, answer ring continuous flow, in turn, the multiple-microorganism systematic collaboration formed in reactor is completed to pollutant, the removal of ammonia nitrogen etc., it is strong with anti impulsion load ability, influent ammonia nitrogen content is allowed to improve to 500mg/l, characteristics of compact layout, land occupation is few, process flow is simple, convenient operation and management, it is able to achieve adjustable and Relative steady-state nitrification-denitrification process, under the low water temperature condition under 15 DEG C of temperature or so, it can also complete nitrification-denitrification process.

Description

The multiple continuous bioreactor of ring and sewage treatment process
Technical field
The invention belongs to sewage treatment fields, and in particular to a kind of continuous bioreactor of ring and sewage treatment process again.
Background technique
Cost-effectively controlling high concentration high ammonia-nitrogen wastewater or high concentration nitrogen-containing waste water pollution is that current environmental worker grinds One of important topic studied carefully, has obtained the great attention of insider, and high concentration high ammonia-nitrogen wastewater or high concentration nitrogen-containing waste water, Such as fertilizer industrial wastewater, Petrochemical Industry Waste Water, coal chemical industrial waste water, landfill leachate generally have complicated component, biodegradability The features such as difference and pollutant concentration are high, when handling these waste water with traditional biological facture, vulnerable to temperature and basicity, dissolved oxygen, COD、 NH3-N、NO2The influence of-N equal size, impact resistance is weaker, especially biological denitrificaion method, the fluctuation warp of relevant parameter Often result in that treatment effeciency is low, in addition, it is some with lavatory drain based on small-sized sanitary sewage, there is also water quality, waters to change Greatly, carbon-nitrogen ratio is too low, can not achieve stably reaching standard, and using traditional handicraft, water outlet is only capable of substantially meeting " urban wastewater treatment firm dirt Contaminating object discharge standard " secondary discharge standard of (GB18918-2002) wants and as country is to the increasingly strict of nitrogen discharged standard Reaching level-one emission standard A just must be using measures such as conditioning tank, the online supplementary carbon sources of volume super large.
The inventors have recognized that development effectiveness is preferably suitble to high concentration high ammonia-nitrogen wastewater, high concentration nitrogen-containing waste water Greatly with water quality, water variation, the importance of low ratio of carbon to ammonium sanitary sewage disposal technology improves pollutant emission index to meet It is real urgent.
Summary of the invention
The present invention provides a kind of multiple continuous bioreactor of ring and sewage treatment process, break traditional bioreactor with Existing single creature processing technique is the general practice to design a model, in conjunction with the biological treatments skill such as activated sludge process, biofilm The respective spy of the reactors such as art and A-B method reactor, AO method reactor, sbr reactor device, biological contact oxidation pond, oxidation ditch Point, reasonable construction is at composite type bioreactor.The cycle alternation between anoxic section and aerobic section is strengthened in segmentation, to realize multistage Nitration denitrification, especially for high ammonia-nitrogen wastewater, influent ammonium concentration is close to 500mg/L, and denitrification percent improves significant.
The invention is realized by the following technical scheme:
A kind of multiple continuous bioreactor of ring, it is anti-including more lattice of filler built in concatenated partial region and aerator biology Answer device, multiple canals that can flow back from the stripping tube of each reaction grid device water outlet bottom backflow mixed liquor and a set of mixed liquor.It is special Sign is: the adjacent lattice top connection of the reactor, sets partition, partition bottom opening among each lattice, institute is arranged in partition both sides State filler, aerator described in the filler following settings;
It is characterized by: the fluidised form of partition two sides water is substantially the type that is thoroughly mixed, wherein opposite in the reactor It is flowed in water inlet, the water flow of partition water inlet side is flowed in left-hand circular, and the water flow that partition is discharged side is in right-hand circular Flowing.
It is characterized by: pending water flows into each lattice of the reactor from top, in the mixed of left-hand circular flowing Diffusion dilution in liquid is closed, under plug-flow effect, partition aperture is flowed through from lower part with the comparable mixed liquor of inflow, continues in up time In the mixed liquor that needle circulates diffusion dilution and from top flow out, on the whole, pending water can be with continuous ring type water flow rail Mark passes through the reactor.
It is characterized by: the multiple stripping tube can promote the mixed liquor of reactor water outlet bottom, pass through institute It states mixed liquor reflux canal and is back to the first reaction grid device of the reactor, and form the multiple ring of mixed liquor reflux to connect with one another closely, The quantity of the stripping tube is calculated according to backflow mixed liquor amount and is determined, and can be returned by adjusting air lift gas consumption to adjust mixed liquor Flow;
It is characterized by: the lattice of the reactor, which is arranged, can be achieved pollutant removal load decrescence, mixed liquor regurgitant volume Several times increase and the stripping tube lays advantages of simple.The reactor lattice quantity requires to calculate according to pollutant removal It determines;
It is characterized by: the backflow mixed liquor is able to achieve suitable hydraulic flow state and multiple ring continuous flow track, in this way, working as When dissolved oxygen reduces in the mixed liquor of circulation farther out, the high mixed liquor of the closer dissolved oxygen content just through air lift is incorporated to again, It connects with one another closely.Air lift amount is increased, guarantees that backflow mixed liquor is back to the first reaction grid device of the reactor with aerobic state, suitably Air lift amount is reduced, and backflow mixed liquor can be made to be back to the first reaction grid device of the reactor with aerobic-anaerobic alternant.
The sewage treatment process of the multiple continuous bioreactor of ring successively includes water inlet, multiple stage circulation reacts, multiple spot mixes Close liquid reflux, it is characterised in that steps are as follows:
(1) necessary pretreatment is carried out, influent COD≤1600mg/l, NH are made3- N≤500mg/l, if influent COD amount is C (similarly hereinafter), if influent ammonia nitrogen amount is N (similarly hereinafter), reflux ratio R takes in C/500 and two ratios of N/50 biggish one.Adjust gas Drawings tolerance, after mixing the mixed liquor of reflux with the ratio of R:1 with the sewage being newly passed through, the first lattice into the reactor are anti- Answer device;
It (2) is in reply immediately ring fastly continuously to flow shape by mixed liquor in maximum aeration quantity agitation reactor when C/N is less than 20 State, for the dissolved oxygen of water in 1.5mg/l~3.5mg/l, i.e. reactor presses aerobic mode operation in each reaction grid device, In, activated sludge area dissolved oxygen exists in 2.5mg/l~3.5mg/l, reactor in 1.5~2.5mg/l, packing area dissolved oxygen Adhere to aerobic, the attachment microfloras such as facultative type and suspension aerobic.When C/N is greater than 20, stirred by smaller aeration quantity Mixed liquor is in answering at a slow speed the continuous flow regime of ring in reactor, in each reaction grid device the dissolved oxygen of water 0mg/l~ 3.0mg/l, i.e. reactor press anaerobic-aerobic mode operation, wherein activated sludge area top dissolved oxygen 0.5mg/l~ 2.0mg/l, activated sludge area lower part dissolved oxygen is in 0.5mg/l hereinafter, packing area dissolved oxygen is in 2.0mg/l~3.0mg/l, instead Answer in device there are suspension oxygen-starved, attachment aerobic, attachment the microfloras such as facultative type and suspension aerobic.Two kinds of operation moulds Under formula, the dominant bacteria that breathing, nutrition, mobility etc. differ from one another will form in respective specific microenvironment, it is each It will form the dynamic equilibrium system for the multiple-microorganism for not only cooperating but also restricting in reaction grid device, moreover, being constantly proliferated, being fitted It answers, eliminate, the processes such as preferably.With circulating for water flow, completed by the collaboration of each microflora to organic pollutant, ammonia nitrogen Deng removal, wherein anaerobic-aerobic operational mode can realize the nitrification-denitrification technique of stable state, not only can use nitrate In oxygen meet certain oxygen demand, and the basicity consumed during denitrification additional nitration can be passed through, be especially suitable for height The removal of ammonia nitrogen waste water;
(3) the bottom mixed liquor reflux of the previous lattice water outlet of each reaction grid device, can both be reduced into thereafter The inflow of one lattice can also be oxygenated the mixed liquor promoted, and therefore, water flow is by multiple reactors and with air lift side Formula reflux bottom mixed liquor, can carry out multiple macrocyclic Anoxybiotic-aerobic biologic processing cycle process.In stepwise disposal and water Under conditions of measuring decrescence, the latter lattice load of each reaction grid device is than its reduction, it is ensured that goes out the processing requirement of water quality;
Further, when carrying out engineering design, if reactor total number of divisions is n, then n >=Log2(pollutant abatement amount/pollution Object discharge amount), and the COD amount for taking immediate integer in 2~6, and entering first reaction grid device is (C+ ∑1 n(C/2n·n))/ (n+1), it is (N+ ∑ into the ammonia nitrogen amount of first reaction grid device1 n(N/2n·n))/(n+1);
Further, when carrying out engineering design, each microflora can be regarded as independent, can clearly divided Activated sludge process design theory can be used in existing treatment process, suspension oxygen-starved and suspension aerobic region and relevant calculation is public Formula, adheres to aerobic and biological contact oxidation process design theory and relevant calculation formula can be used in attachment facultative type region, mixes Oxidation ditch design theory and relevant calculation formula can be used in liquid reflux canal.
The present invention answers having the beneficial effect that for the continuous bioreactor of ring and sewage treatment process:
(1) compared with traditional activated sludge process, biofilm, reactor of the invention have the stage be thoroughly mixed and by Stage load reduce double grading, not only have stronger anti impulsion load ability, also allow influent ammonia nitrogen content improve to 500mg/l, and ensure that stable water outlet is up to standard;
(2) compared with conventional activated sludge method, averagely equivalent sludge concentration is up to 10000mg/L in reactor of the invention More than, compared with the oxidation ditch of conventional activated sludge, there is characteristics of compact layout, take up an area few advantage, save land occupation about 30~ 50%;
(3) compared with the AO method reactor of conventional activated sludge, reactor internal reflux ratio of the invention reduces 40~ 50%;
(4) compared with the sbr reactor device of conventional activated sludge, reactor of the invention does not need water decanter and automatic control system System, can continuum micromeehanics, water outlet uniformly, process flow is simple, convenient operation and management;
(5) compared with the biological contact oxidation pond of standard biologic embrane method, reactor of the invention be able to achieve it is adjustable, and And the nitrification-denitrification process of Relative steady-state;
(6) reactor hydraulic detention time (HRT) of the invention shortens, and sludge retention time (SRT) extends, and is SRT Therefore extended aeration in meaning under the low water temperature condition under 15 DEG C of temperature or so, can also complete nitrification-denitrification mistake Journey.
Detailed description of the invention
Fig. 1 is the organigram of the multiple continuous bioreactor of ring of the present invention, is 1. filler in Fig. 1, is 2. aerator, 3. It is 4. air lift regulating valve for air stripper, is 5. aerating regulation valve, reaction grid device headed by A, F is last reaction grid device, and B-E is centre Reaction grid device, quantity is according to water quality and requires to calculate determination, and G is mixed liquor reflux canal.
Fig. 2 is the track of stream schematic diagram of the multiple continuous bioreactor of ring of the present invention.

Claims (9)

1. a kind of multiple continuous bioreactor of ring, more lattice biological respinses including filler built in concatenated partial region and aerator Device, multiple canals that can flow back from the stripping tube of each reaction grid device water outlet bottom backflow mixed liquor and a set of mixed liquor.Its feature Be: the adjacent lattice top connection of the reactor sets partition among each lattice, partition bottom opening, described in the setting of partition both sides Filler, aerator described in the filler following settings.
2. the multiple continuous bioreactor of ring according to claim 1, it is characterised in that: in the reactor, partition two sides The fluidised form of water is substantially the type that is thoroughly mixed, wherein is flowed to relative to water inlet, the water flow of partition water inlet side is in left-hand circular Flowing, the water flow that partition is discharged side are flowed in right-hand circular.
3. the multiple continuous bioreactor of ring according to claim 1, it is characterised in that: pending water flows into described from top Each lattice of reactor, the diffusion dilution in the mixed liquor of left-hand circular flowing are comparable with inflow under plug-flow effect Mixed liquor flows through partition aperture from lower part, continues the diffusion dilution in the mixed liquor that right-hand circular flows and flows out from top, On the whole, pending water can pass through the reactor with continuous ring type track of stream.
4. the multiple continuous bioreactor of ring according to claim 1, it is characterised in that: the multiple stripping tube can will be described The mixed liquor of reactor water outlet bottom is promoted, and the first reaction grid of the reactor is back to by mixed liquor reflux canal Device, and the multiple ring of mixed liquor reflux to connect with one another closely is formed, the quantity of the stripping tube is calculated according to backflow mixed liquor amount to be determined, And mixed liquor regurgitant volume can be adjusted by adjusting air lift gas consumption.
5. the multiple continuous bioreactor of ring according to claim 1, it is characterised in that: the lattice setting of the reactor can Realize pollutant removal load decrescence, mixed liquor regurgitant volume several times increase and the stripping tube lays advantages of simple;It is described anti- It answers device lattice quantity to be calculated according to pollutant removal requirement to determine.
6. the multiple continuous bioreactor of ring according to claim 1, it is characterised in that: the backflow mixed liquor is able to achieve conjunction Suitable hydraulic flow state and multiple ring continuous flow track, in this way, when dissolved oxygen reduces in the mixed liquor of circulation farther out, closer rigid warp The high mixed liquor of dissolved oxygen content for crossing air lift is incorporated to again, is connected with one another closely.Air lift amount is increased, guarantees backflow mixed liquor with aerobic State is back to the first reaction grid device of the reactor, appropriate to reduce air lift amount, and backflow mixed liquor can be made to replace with aerobic-anaerobic Form is back to the first reaction grid device of the reactor.
7. a kind of sewage treatment process of any one of the claim 1~6 multiple continuous bioreactor of ring, successively include into Water, multiple stage circulation reaction, the reflux of multiple spot mixed liquor, it is characterised in that steps are as follows:
(1) necessary pretreatment is carried out, influent COD≤1600mg/l, NH are made3- N≤500mg/l, if influent COD amount be C (under Together), if influent ammonia nitrogen amount is N (similarly hereinafter), reflux ratio R takes in C/500 and two ratios of N/50 biggish one.Air lift is adjusted to use Tolerance, after mixing the mixed liquor of reflux with the ratio of R:1 with the sewage being newly passed through, into the first lattice of the reactor;
It (2) is in reply immediately the continuous flow regime of ring, institute fastly by mixed liquor in maximum aeration quantity agitation reactor when C/N is less than 20 The dissolved oxygen of water in each reaction grid device is stated in 1.5mg/l~3.5mg/l, i.e. reactor presses aerobic mode operation, wherein living Property sludge area dissolved oxygen in 1.5~2.5mg/l, there is attachment in 2.5mg/l~3.5mg/l, reactor in packing area dissolved oxygen Aerobic, the attachment microfloras such as facultative type and suspension aerobic.When C/N is greater than 20, by the agitation reaction of smaller aeration quantity Mixed liquor is in the continuous flow regime of ring is answered at a slow speed in device, and the dissolved oxygen of water is in 0mg/l~3.0mg/ in each reaction grid device L, i.e. reactor press anaerobic-aerobic mode operation, wherein activated sludge area top dissolved oxygen is lived in 0.5mg/l~2.0mg/l Property sludge area lower part dissolved oxygen in 0.5mg/l hereinafter, packing area dissolved oxygen exist in 2.0mg/l~3.0mg/l, reactor it is outstanding Floating oxygen-starved, attachment aerobic, the attachment microfloras such as facultative type and suspension aerobic.Under two kinds of operation modes, respective It will form the dominant bacteria that breathing, nutrition, mobility etc. differ from one another, meeting in each reaction grid device in specific microenvironment The dynamic equilibrium system of multiple-microorganism for not only having cooperated but also having restricted is formed, moreover, being constantly proliferated, being adapted to, eliminated, preferably etc. Process.With circulating for water flow, the removal to organic pollutant, ammonia nitrogen etc. is completed by the collaboration of each microflora, wherein Anaerobic-aerobic operational mode can realize the nitrification-denitrification technique of stable state, and the oxygen that not only can use in nitrate meets centainly Oxygen demand, and can pass through denitrification additional nitration during consume basicity, be especially suitable for high ammonia-nitrogen wastewater removal;
(3) the bottom mixed liquor reflux of the previous lattice water outlet of each reaction grid device, can both have been reduced into its latter lattice Inflow, the mixed liquor promoted can also be oxygenated, therefore, water flow by multiple reactors and with stripping regime return Bottom mixed liquor is flowed, multiple macrocyclic biological treatment cyclic process can be carried out.In the condition of stepwise disposal and water decrescence Under, the latter lattice load of each reaction grid device is than its reduction, it is ensured that goes out the processing requirement of water quality.
8. a kind of sewage treatment process of any one of claim 1~6 multiple continuous bioreactor of ring, it is characterised in that: When carrying out engineering design, if reactor total number of divisions is n, then n >=Log2(pollutant abatement amount/pollutant discharge amount), and 2~ Immediate integer is taken in 6, and the COD amount for entering first reaction grid device is (C+ ∑1 n(C/2nN))/(n+1) is anti-into first lattice The ammonia nitrogen amount for answering device is (N+ ∑1 n(N/2n·n))/(n+1)。
9. a kind of sewage treatment process of any one of claim 1~6 multiple continuous bioreactor of ring, it is characterised in that: When carrying out engineering design, the existing treatment process that can be regarded each microflora as independent, can clearly divide suspends Activated sludge process design theory and relevant calculation formula can be used in oxygen-starved and suspension aerobic region, adheres to aerobic and attachment Biological contact oxidation process design theory and relevant calculation formula can be used in facultative type region, and oxidation ditch can be used in mixed liquor reflux canal Design theory and relevant calculation formula.
CN201910102794.5A 2019-02-02 2019-02-02 The multiple continuous bioreactor of ring and sewage treatment process Pending CN109775854A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1463932A (en) * 2002-06-27 2003-12-31 王建民 Sewage treatment bioreactor
US20080110828A1 (en) * 2004-10-12 2008-05-15 Biocast Systems Inc. Integrated Multi-Zone Wastewater Treatment System And Method
CN101450830A (en) * 2007-11-30 2009-06-10 孟广祯 Multi-stage aerobic and anoxic coupling bioreactor and sewage disposal method
CN201793455U (en) * 2010-06-11 2011-04-13 北京坎普尔环保技术有限公司 Multi-coupling bioreactor
CN102115296A (en) * 2011-01-14 2011-07-06 中国环境科学研究院 Novel multi-cell denitrifying membrane bioreactor
CN105776770A (en) * 2016-05-06 2016-07-20 云南大学 Sewage deep purifying device with high adaptivity and method thereof
CN106365314A (en) * 2015-07-23 2017-02-01 中国石油化工股份有限公司 Method and system for carrying out biological denitrification on waste water, and applications of system
CN108408883A (en) * 2017-02-10 2018-08-17 大连安能杰科技有限公司 A kind of MBBR integrated reactors gas lift and the air lift circulatory system

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1463932A (en) * 2002-06-27 2003-12-31 王建民 Sewage treatment bioreactor
US20080110828A1 (en) * 2004-10-12 2008-05-15 Biocast Systems Inc. Integrated Multi-Zone Wastewater Treatment System And Method
CN101450830A (en) * 2007-11-30 2009-06-10 孟广祯 Multi-stage aerobic and anoxic coupling bioreactor and sewage disposal method
CN201793455U (en) * 2010-06-11 2011-04-13 北京坎普尔环保技术有限公司 Multi-coupling bioreactor
CN102115296A (en) * 2011-01-14 2011-07-06 中国环境科学研究院 Novel multi-cell denitrifying membrane bioreactor
CN106365314A (en) * 2015-07-23 2017-02-01 中国石油化工股份有限公司 Method and system for carrying out biological denitrification on waste water, and applications of system
CN105776770A (en) * 2016-05-06 2016-07-20 云南大学 Sewage deep purifying device with high adaptivity and method thereof
CN108408883A (en) * 2017-02-10 2018-08-17 大连安能杰科技有限公司 A kind of MBBR integrated reactors gas lift and the air lift circulatory system

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