CN109772238A - A kind of aeroge preparation system and method - Google Patents
A kind of aeroge preparation system and method Download PDFInfo
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- CN109772238A CN109772238A CN201910188713.8A CN201910188713A CN109772238A CN 109772238 A CN109772238 A CN 109772238A CN 201910188713 A CN201910188713 A CN 201910188713A CN 109772238 A CN109772238 A CN 109772238A
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- working space
- activation
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- 238000000034 method Methods 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 32
- 238000001035 drying Methods 0.000 claims abstract description 77
- 230000004913 activation Effects 0.000 claims abstract description 53
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000460 chlorine Substances 0.000 claims abstract description 12
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 12
- 239000000499 gel Substances 0.000 claims description 88
- 230000005855 radiation Effects 0.000 claims description 45
- 230000032683 aging Effects 0.000 claims description 31
- 238000012546 transfer Methods 0.000 claims description 29
- 238000012986 modification Methods 0.000 claims description 24
- 230000004048 modification Effects 0.000 claims description 24
- 239000002699 waste material Substances 0.000 claims description 23
- 238000011084 recovery Methods 0.000 claims description 20
- 238000007711 solidification Methods 0.000 claims description 18
- 230000008023 solidification Effects 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 13
- 230000008859 change Effects 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 10
- 238000004806 packaging method and process Methods 0.000 claims description 9
- 238000012805 post-processing Methods 0.000 claims description 9
- 238000002407 reforming Methods 0.000 claims description 8
- 238000013459 approach Methods 0.000 claims description 6
- 239000011240 wet gel Substances 0.000 claims description 5
- 125000000524 functional group Chemical group 0.000 claims description 4
- 230000009257 reactivity Effects 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000004904 shortening Methods 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 30
- 238000005516 engineering process Methods 0.000 abstract description 12
- 235000019441 ethanol Nutrition 0.000 description 16
- 239000007789 gas Substances 0.000 description 16
- 239000004964 aerogel Substances 0.000 description 12
- 238000003860 storage Methods 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 8
- 238000012545 processing Methods 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 235000019353 potassium silicate Nutrition 0.000 description 6
- 238000004064 recycling Methods 0.000 description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229910001868 water Inorganic materials 0.000 description 6
- 238000013461 design Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 238000010924 continuous production Methods 0.000 description 4
- 238000012216 screening Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 229910002012 Aerosil® Inorganic materials 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- 230000001133 acceleration Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 229910052913 potassium silicate Inorganic materials 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 235000019795 sodium metasilicate Nutrition 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 238000000352 supercritical drying Methods 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 239000004111 Potassium silicate Substances 0.000 description 2
- 239000004965 Silica aerogel Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007596 consolidation process Methods 0.000 description 2
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- 238000006073 displacement reaction Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 description 2
- 229910052912 lithium silicate Inorganic materials 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000003032 molecular docking Methods 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000012745 toughening agent Substances 0.000 description 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- AEMOLEFTQBMNLQ-YMDCURPLSA-N D-galactopyranuronic acid Chemical compound OC1O[C@H](C(O)=O)[C@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-YMDCURPLSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 1
- 229910003953 H3PO2 Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 229920002230 Pectic acid Polymers 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 239000004110 Zinc silicate Substances 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- PNNNRSAQSRJVSB-BXKVDMCESA-N aldehydo-L-rhamnose Chemical compound C[C@H](O)[C@H](O)[C@@H](O)[C@@H](O)C=O PNNNRSAQSRJVSB-BXKVDMCESA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001345 alkine derivatives Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 229920001276 ammonium polyphosphate Polymers 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011953 bioanalysis Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 235000012241 calcium silicate Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 1
- 229940005991 chloric acid Drugs 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- ZOIVSVWBENBHNT-UHFFFAOYSA-N dizinc;silicate Chemical compound [Zn+2].[Zn+2].[O-][Si]([O-])([O-])[O-] ZOIVSVWBENBHNT-UHFFFAOYSA-N 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 229940009493 gel-one Drugs 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002608 ionic liquid Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 239000005078 molybdenum compound Substances 0.000 description 1
- 150000002752 molybdenum compounds Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000010318 polygalacturonic acid Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000002444 silanisation Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000000194 supercritical-fluid extraction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- XTIIITNXEHRMQL-UHFFFAOYSA-N tripotassium methoxy(trioxido)silane Chemical compound [K+].[K+].[K+].CO[Si]([O-])([O-])[O-] XTIIITNXEHRMQL-UHFFFAOYSA-N 0.000 description 1
- XYRAEZLPSATLHH-UHFFFAOYSA-N trisodium methoxy(trioxido)silane Chemical compound [Na+].[Na+].[Na+].CO[Si]([O-])([O-])[O-] XYRAEZLPSATLHH-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000019352 zinc silicate Nutrition 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Colloid Chemistry (AREA)
Abstract
The present invention relates to a kind of aeroge preparation system and methods, including at least supplementary material system (1), gel systems (2), modified and drying system (4), still alternatively increase setting gel activation system (3) in gel systems (2), modified and drying system (4)；The hollow tubular or tunnel-like cavity that gel systems (2), gel activation system (3), modified and drying system (4) respective shell are directly formed are working space, each working space is mutually indepedent and can form the tunnel-like that be mutually communicated by opening and closing device and continues through space, and the conveying device (11) docked with supplementary material system (1) is arranged in each working space.The present invention is designed for no chlorine without alcohol production technique, can be realized the highly effective continuous preparation of aeroge, solves the problems, such as the drawbacks described above of aeroge normal pressure technology continous way production.
Description
Technical field
The present invention relates to aeroge preparation technical fields, and in particular to a kind of normal pressure continous way prepare aeroge method and
Equipment.
Background technique
Aeroge is the novel nanometer of one kind, porous, low-density, amorphous material, has continuous three-dimensional net structure.
Aeroge has many unique properties, as high porosity, high-specific surface area, low-density, low heat conductivity, sound insulation value are excellent
Deng, have Magic Characteristics in numerous areas such as calorifics, optics, electricity, chemistry, have boundless application prospect.
Supercritical Drying Technology is that earliest realize prepares aeroge technology in batches, be have been relatively mature, and domestic at present
Outer aeroge enterprise uses more technology.But because supercritical pressure and temperature are all very high, as the super critical point of methanol exists
239.4 DEG C and 81 atm highers, in addition, supercritical autoclave cannot achieve full-automatic continuous production, it is necessary to make kettle
It opens, by hoisting material, aerogel products cannot achieve serialization conveying, therefore there are high-voltage high-temperature equipments to hold high for supercritical technology
The disadvantages of expensive, security risk is big, low efficiency, at high cost, complex process.Constant pressure and dry is a kind of novel aeroge preparation work
Skill is that current research is most active, the maximum aeroge of development potentiality batch production technology, for normal pressure technology is with respect to supercritical technology,
It is low with equipment investment, production cost is low, excellent product performance, it is safer, easy, be able to achieve the advantages such as continuous production, be
The trend of aeroge research and development and production.There are document and patent report constant pressure and dry to prepare aerogel products, but its method
Gel time is long, a large amount of organic solutions are introduced in colloidal sol, and modifying agent loss is caused to increase, and the cost recovery of alcohols also compared with
The disadvantages of height, it is cumbersome that there are methods, and the production cycle is long, low efficiency, increase the airtightness to equipment, explosion-proof, prevent it is quiet
The requirement such as electricity, increases cost and also reduces the safety of production.
Meanwhile comprehensive existing patented technology and document report, existing aerosil production method mostly use
Organosilicon (ethyl orthosilicate, methyl orthosilicate, multi-polysiloxane) is raw material, with supercritical drying or constant pressure and dry method system
It is standby.Supercritical process can be divided into ethanol supercritical drying again and carbon dioxide supercritical extraction is dry, and the two raw material is organic
The problems such as estersil, that there are raw materials is very expensive for these methods, and has toxicity, complex process, safety is low seriously constrains two
The large-scale production and application of silica aerogel.It can be using waterglass as waste using non-pressure process production aeroge
Aerosil, hence it is evident that reduce the cost of raw material and the complexity of equipment, but silica gas is produced using waterglass
Gel so that silicate solution be made, then adds a kind of basic catalyst and makes its Cheng Ning often by means of a kind of ion exchange resin
Glue.Then it washs resulting gel repeatedly with hot water, then passes through normal pressure after organic solvent displacement and surface methyl groups Silanization reaction
Aerosil is made.It discloses in the patent application document that patent application publication number is CN102167337A with alkalinity
Silicate (sodium metasilicate, potassium silicate) is silicon source, and water and ethylene glycol dilution is added, and inorganic acid is then added and sufficiently reacts 1-5 hours
Adjustment pH is 2-4 afterwards, is repeatedly 0.1% hereinafter, finally existing with or mixtures thereof water or alcohol washing to sodium ion or potassium content
Quick dewatering drying is carried out at 100-400 DEG C.Such method is cumbersome, and the production cycle is long, low efficiency, and meeting in preparation process
Generate a large amount of brine waste.In addition after gel-forming by the way of solvent displacement, it is direct that ethyl alcohol is added in silica solution
Alcogel is made, gel obtained by the alcohol solution dipping with various concentration is still needed to after gel.Since technical process is band alcohol band
Chlorine, so equipment durability and requirement to equipment liner are very high.
The reaction unit used for the most of existing aeroge of alcohol-containing containing chlorine production, in order to guarantee production security needs
Liner is set in the shell of device, and has limitation requirement for accelerated mode, is similar to this acceleration side of radio-frequency radiation
Formula will generate sparking burning or even explosion when using, have biggish production hidden danger.
Summary of the invention
The technical problem to be solved by the present invention is to prepare the method and system of aeroge, needle using a kind of normal pressure continous way
The highly effective continuous preparation of aeroge is realized without alcohol production technique to no chlorine, solves the production of aeroge normal pressure technology continous way
Drawbacks described above problem.
In order to solve the above-mentioned technical problem, the present invention adopts the following technical scheme:
A kind of aeroge preparation system includes at least supplementary material system (1), gel systems (2), modified and drying system (4),
Still alternatively increase setting gel activation system (3) in gel systems (2), modified and drying system (4)；It is characterized by:
Hollow tubular that gel systems (2), gel activation system (3), modified and drying system (4) respective shell are directly formed or
Tunnel-like cavity is working space, and each working space is mutually indepedent and can form the tunnel-like being mutually communicated by opening and closing device
Space is continued through, the conveying device (11) docked with supplementary material system (1) is set in each working space；In gel systems
(2), the Cooling and Heat Source being connected to inside each working space is respectively provided on gel activation system (3), modification and drying system (4) to convey
Pipeline, gas passage, recovery approach and discharge-channel, Cooling and Heat Source conveyance conduit are connected to cold and heat source system (7), gas passage with
Air supply system (8) connection, recovery approach are connected to recovery system (6), and discharge-channel is connected to waste treatment system (5).
According to the above technical scheme, the setting solidification aging accelerator in the working space of gel systems (2), the solidification are old
The accelerated mode for changing accelerator is one or more of radio-frequency radiation, sound wave, infra-red radiation, vibration, heat transfer；It is living in gel
One or more of setting heat transfer, infra-red radiation, vibration, radio-frequency radiation, sound wave activation in the working space of change system (3)
Accelerator；Modified accelerator, the accelerated mode of the modified accelerator are set in modified and drying system (4) working space
It is one or more of sound wave, infra-red radiation, vibration, heat transfer.
According to the above technical scheme, each accelerator is arranged at the top or lower part of each working space, or in working space
Inboard wall of tube body is circumferentially around setting.
According to the above technical scheme, modified and drying system (4) are by the modified device being separately provided and the drying being separately provided
The modification and dry run-though space that equipment is connected in series or is wholely set；Modified and drying system (4) are integrated setting
When modified and dry run-though space, gel activation system must also be set in gel systems (2), modified and drying system (4)
(3).
According to the above technical scheme, product post-processing system (9) and product packaging system are also set up after modified and drying system (4)
It unites (10).
Using the aeroge preparation method of above-mentioned aeroge preparation system, it is characterised in that include the following steps:
S1: supplementary material is added in supplementary material system (1)；Conveying device (11) starting later is started to work；
S2: supplementary material enters gel systems (2), by adjusting pH, heat transfer, radio-frequency radiation, infra-red radiation, sound in the section
One of wave, vibration or various ways promote solidification and aging, and shortening solidifies and the time of aging；
S3: solidify through gel systems (2) and enter gel activation system through conveying device (11) drive with the gel after aging
(3), the activation for realizing chemical functional group in wet gel improves its reactivity, accelerates the modified speed of back segment；
S4: the gel after activation drives through conveying device (11) and enters modified and drying system (4), passes through sound in modified section
One or more of wave, infra-red radiation, vibration, heat transfer mode accelerate to be modified, and improve modification efficiency；Enter drying later
Section by one of hot wind, infra-red radiation, heat transfer or several is dried；
S5: in above steps, cold and heat source system (7) is connected to Cooling and Heat Source conveyance conduit to each working space and supplementary material system
(1) heating and cooling is carried out；Air supply system (8) supplies each working space and supplementary material system (1)；What entire workshop section generated
The three wastes enter waste treatment system (5)；The material that recovery system (6) is collected in reaction process is recycled.
According to the above technical scheme, the method is applicable in aeroge without chlorine without alcohol technique.
According to the above technical scheme, solidification and 0 DEG C -300 DEG C of aging temperature in step s 2, solidification is completed in 10S-5h,
Aging is completed in 1min-48h；Preferred 0-300 DEG C of activation temperature in step S3,10S-168h is interior to complete activation；Step S4 is modified
0-150 DEG C of module operating temperature, modified 30s-5h are completed；0-250 DEG C of irradiation modules drying temperature, dry 10s-2.5h are completed.
According to the above technical scheme, when reforming system in modified and drying system (4) and drying system are discontinuous independent
When the reaction compartment of connection, S4 step is substituted by S4a step, at this point, the gel after S2 step is directly or through S3 step
After enter step S4a；
The step S4a are as follows: gel drives through conveying device (11) and enters modified and drying system (4), and gel is by being modified
System simultaneously enters drying system after modification, and modifying process and drying process are respectively independent.
According to the above technical scheme, the reaction time in reforming system is 1min-2h；2h-10h；10h-24h;24h-48h；
Any duration or unlimited duration in 48h-168h.
We have invented the method and system that a kind of normal pressure continous way prepares aeroge for no chlorine without alcohol technique as a result,
It is able to achieve the highly effective continuous preparation of aeroge, solves the predicament of aeroge normal pressure technology continous way production.The present invention is with continuous
Formula tunnel oven-like reaction compartment realizes continuous modification and the drying of gel rubber material, and the preparation efficiency of aeroge is substantially improved.With
Most of existing aeroge production line is compared with production method, the invention has the following beneficial effects:
The present invention using no chlorine without alcohol technique, thus when equipment body or reaction compartment are not provided with liner, even if using radio frequency
Radiation mode accelerates reaction that will not have the security risks such as sparking.
Secondly, gel systems solidify aging, gel activation system can use radio-frequency radiation, sound wave, infra-red radiation, heat
One or more accelerated modes such as conduction, vibration, modified and dryer section can be using sound wave, infra-red radiation, heat transfer, vibrations etc.
One or more accelerated modes, device fabrication are more flexible.
Again, no inner-tube structure avoids polymer liner using temperature is low, ceramic and glass inner bag is easily broken, it is difficult to add
The disadvantage of work.
Finally, compared to the double-layer structure for being equipped with liner, when the equipment that the box house of reaction compartment is installed breaks down
When, convenient for checking the source of failure, and it is easy to maintain.
Detailed description of the invention
Fig. 1 is the structure chart for the one of embodiment of system for preparing aeroge implemented according to the present invention.
Fig. 2 is the structure chart for second embodiment of system for preparing aeroge implemented according to the present invention.
Fig. 3 is the independent modified device structure chart in second embodiment implemented according to the present invention.
Fig. 4 is the independent drying equipment structure figure in second embodiment implemented according to the present invention.
Fig. 5 is the system third example structure figure for preparing aeroge implemented according to the present invention.
Fig. 6 is the structure chart with gel systems 2 of the invention.
Fig. 7 is the structure chart with gel activation system 3 of the invention.
Specific embodiment
The system for preparing aeroge implemented according to the present invention is as shown in Figure 1, mainly include supplementary material system 1, gel system
System 2, gel activation system 3, modified and drying system 4, waste treatment system 5, recovery system 6, cold and heat source system 7, gas supply system
System 8.All devices, accessory, auxiliary facility meet explosion-proof and safety requirements.It can be produced by the device of the invention with high-efficiency and continuous
A variety of aerogel products, including but not limited to aerogel powder, aerogel blanket, aerogel plate, airsetting adhesive plaster.
After gel systems 2, gel activation system 3, modified and drying system 4 are successively set on supplementary material system 1: its feature
It is that the tube body cavity that gel systems 2, gel activation system 3, the modified and respective shell of drying system 4 are directly formed is work
Make space, each working space is configured to be mutually communicated or close respectively, setting and supplementary material system 1 in each working space
The conveying device 11 of docking；Namely without another in gel systems 2, gel activation system 3, the modified and respective shell of drying system 4
Outer bladder layer namely shell is single hull, and innermost inner and outer wall is integrated, and is not independently of the liner of outer wall.
The Cooling and Heat Source conveying being connected to each working space is respectively provided on gel systems 2, gel activation system 3, modified and drying system 4
Pipeline, gas passage, recovery approach and discharge-channel, Cooling and Heat Source conveyance conduit are connected to cold and heat source system 7, gas passage and confession
Gas system 8 is connected to, and recovery approach is connected to recovery system 6, and discharge-channel is connected to waste treatment system 5.In supplementary material system 1
Also the conventional plants such as recycling, waste processing, Cooling and Heat Source have been set as needed.
The conveying device 11 docked with supplementary material system 1 is set in each working space for transmitting supplementary material, conveying dress
11 are set as such as caterpillar conveying device or the common mode of movement of pipeline.
Setting solidification aging accelerator, the acceleration side for solidifying aging accelerator in the working space of gel systems 2
Formula is one or more of radio-frequency radiation, sound wave, infra-red radiation, vibration, heat transfer；It is empty in the work of gel activation system 3
One or more of interior setting heat transfer, infra-red radiation, vibration, radio-frequency radiation, sound wave activate accelerator；Modified and dry
Modified accelerator is set in the working space of drying system 4, and the accelerated mode of the modified accelerator is sound wave, infra-red radiation, vibration
One or more of dynamic, heat transfer.
The present invention is directed to aeroge without chlorine without alcohol production technique, is not provided with liner in each working space, thus especially suitable
With aeroge without chlorine without alcohol production technique, aeroge is detailed in the Chinese public patent application of the applicant without chlorine without alcohol production method
CN 108314411A, the method that silicon dioxide silica aerogel composite material is prepared without alcohol technique using no chlorine, wherein water-soluble silicon source
For waterglass, water silica sol, methane-siliconic acid lithium, sodium methyl silicate, potassium methyl silicate, lithium metasilicate, lithium metasilicate, sodium metasilicate,
The combination of one or more of sodium metasilicate, potassium silicate or potassium metasilicate；No chloric acid is H2SO4、HNO3、HF、HBr、HI、H2SO3、
HNO3、H3PO4、H3PO2、H3BO3One or more of combination.Desalination process uses ion exchange resin, freezing and crystallizing, evaporation
The combination of one or more of condensing crystallizing, film process.Additive can be the one of infrared light screening agent, fire retardant or toughener
Kind or several combinations；Infrared light screening agent can be ferrous oxide, carbon black, titanium dioxide, crystal whisker of hexa potassium titanate, zinc oxide, oxygen
Change zirconium, aluminium oxide, magnesia, alumina silicate, magnesium silicate, calcium silicates, zinc silicate, zinc borate, magnesium hydroxide, aluminium hydroxide, hydrogen-oxygen
Change one of iron or a variety of mixtures；Fire retardant can be magnesium hydroxide, aluminium hydroxide, zinc borate, ammonium polyphosphate, red
One or more mixtures of phosphorus, antimony oxide or molybdenum compound；Toughener can be polyethylene, polypropylene, polystyrene, gather
Vinyl alcohol, polyvinylpyrrolidone, polyacrylamide, polyacrylonitrile, polycarbonate, polyether sulfone, polyformaldehyde, polymethylacrylic acid
One of methyl esters, polygalacturonic acid, poly- L- rhamnose galacturonic acid and polyimides or a variety of mixtures；Fiber increases
Strong material is inorfil or organic fiber.
The specific method is as follows for specific Each part and technique:
(1) supplementary material system 1 may be implemented supplementary material storage, the preparation of substrate, the preparation of specified mix colloidal sol and colloidal sol and
Substrate it is compound；The preparation module 1A of the supplementary material system 1 including specified mix colloidal sol, the preparation module 1B of substrate, it is molten
Gum base materials compound preparation module 1C, supplementary material storage module 1D.Supplementary material system can be any combination of 1A, 1B, 1C, 1D,
Any separate modular being also possible in 1A, 1B, 1C, 1D.The aerogel products of diversified forms may be implemented in the supplementary material system 1
Conversion production, for example, if be added substrate can then produce the products such as aerogel blanket, can be direct if being added without substrate
Produce aerogel powder.All modules of equipment can increase or amplify, and can also realize raw while different shape product
It produces.
Further, the substrate of the investment in supplementary material system 1 can be fibrous material (organic fibrous material, inorganic fibre
Tie up material), granular materials, crystal whisker materials, metal material, porous material, one or more of polymer material.The original is auxiliary
Material system 1 can realize the functions such as production, storage, preparation and the conveying of material, supply subsequent production.Collection function can be designed simultaneously
Can and recyclable device, enable production, storage, the substance for dripping or being poured out in transmission process effectively to collect and recycle.It is former
The settable control system of adjuvant systems 1 is realized intelligent.Raw material mainly include but is not limited to Jiao Yuan, additive, activator,
One or more of infrared light screening agent, modifying agent, substrate, auxiliary material include but is not limited to mainly water, catalyst, diluent, set
Change one or more of agent, packaging material, post-processing material, acid, alkali, moisturizer, polymerization inhibitor, smoke suppressant, crosslinking agent.
(2) conveying device 11 is such as caterpillar conveying device or the common mode of movement of pipeline.At least through solidifying
Colloid system 2, gel activation system 3, modified and drying system 4, the material of conveying device 11 itself can be polymer, ceramics,
One or more of glass, metal.Conveying device 11, which is continuously integrally formed or is segmented docking in each working space and formed, to be connected
Continuous conveying device.
(3) gel activation system 3 is mainly used for realizing the activation of chemical functional group in wet gel, improves its reactivity,
Accelerate the modified speed of back segment.Gel activation system 3 is provided with the storage device and collection device being connected to itself working space, storage
Cryopreservation device for storing or transfer supplementary material, collection device effectively collects with the substance that drips or be poured out in processing system, it is defeated
Device 11 is sent, without passing through in liner working space, to supply subsequent production from gel activation system 3.
Activator can be surfactant, salt, acid, alkali, alcohol, ether, ester, phenol, benzene, enol, hydrocarbon, alkane, alkynes, sulfide,
One or more of heterocyclic compound, amine, ionic liquid, water, metal, metal ion, metal oxide, complexing agent, enzyme.It is living
Change preferred 0-300 DEG C of temperature, completes activation in 10S-168h.The settable control system of gel activation system is realized intelligent.
Setting solidification aging accelerator, the acceleration side for solidifying aging accelerator in the working space of gel systems 2
Formula is one or more of radio-frequency radiation, sound wave, infra-red radiation, vibration, heat transfer；It is empty in the work of gel activation system 3
One or more of interior setting heat transfer, infra-red radiation, vibration, radio-frequency radiation, sound wave activate accelerator, for promoting work
Change efficiency, shortens activation time.Modified accelerator is set in modified and drying system 4 working space, and the modification accelerates
The accelerated mode of device is one or more of sound wave, infra-red radiation, vibration, heat transfer.
(4) modification as shown in Figure 1 and drying system 4, the continous way that wet gel may be implemented are modified and dry；Including changing
Property module 4A and irradiation modules 4B.Only when modified speed and rate of drying fast quickly, it will just be modified according to the present invention
It is designed into together with drying section, forms modified and drying system 4, realize high efficiency continuously production, gel activation system is to change
Critical step before property.
In such as Fig. 2, modified and drying system 4 in Fig. 1 can be replaced with individual modification as shown in Figure 3 respectively and set
Standby and as shown in Figure 4 independent drying equipment.It is substituted after the two (4C modified device, 4D are drying equipment) series connection modified and dry
The function of system 4.
As shown in figure 3, modified device 4C mainly by shell 12, gas device 4-1, modified accelerator 4-2, reagent storage and
Supplementary device 4-3 composition.Waste treatment system 5, recovery system 6, cold and heat source system 7 with the nothing in modified device 4C shell 12
The connection of liner working space.What 12 inner wall of modified device 4C shell was directly formed seals without liner working space, ensures air tight
And safety.Air supply system 8 is connected to the working space in shell 12 by gas device 4-1.
The accelerated mode of modified accelerator 4-2 is one or more of sound wave, infra-red radiation, vibration, heat transfer.By changing
Property accelerator 4-2 improve modification efficiency, preferably 0-300 DEG C of modification temperature, modified 1min~10h is completed.
As shown in figure 4, drying equipment 4D mainly impregnated by drying box 13, dry accelerator 4-4, wash mill 4-5(or
Spray etc. common mode of washing), dust-extraction unit 4-6 composition.Waste treatment system 5, recovery system 6, cold and heat source system 7 with it is dry
The working space connection that dry 13 inner wall of cabinet is directly formed.13 inner wall of drying box is directly formed close without liner working space
Envelope ensures air tight and safe.Air supply system 8 is connected to working space in drying box 13 by gas device 4-1.It is dry to accelerate
The drying accelerated mode of device 4-4 can be one of hot wind, infra-red radiation, heat transfer or several, and drying time is quick, excellent
Dry 10S~5h is selected to complete, 30-500 DEG C of drying temperature.Modified and dry settable control system, is realized intelligent.
Process modification and drying after corresponding series connection can also change, and be followed successively by solidifying through supplementary material system-gel systems-
Glue activation system-reforming system-drying system.Corresponding temperature and processing time have carried out minor change.In Fig. 2,4C is modified
Module, 4D are irradiation modules, and the two is discontinuous independent connection, can thus be lengthened with modification time to endless
(including but not limited to 1min-2h；2h-10h；10h-24h；24h-48h；Any duration in 48h-168h), to modified side
The technology of method and efficiency is without so high request, and furthermore the activation system 3 of front can not be enabled or not assembled, Mei Gegong
Section can be prepared according to the actual situation, advantage be preparation process require it is low, flexibly prepared convenient for each workshop section；The disadvantage is that
Production is discontinuous, preparation efficiency is low.
(5) recovery processing of the three wastes may be implemented in waste treatment system 5；The waste treatment system is for handling entire life
The three wastes that can not be recycled generated during producing (waste liquid, gives up admittedly at exhaust gas).Waste treatment system 5 can design control
System is realized intelligent.
(6) recycling, regeneration and recycling of material in entire process units may be implemented in recovery system 6；The recycling
The way of recycling of system 6 can be one or more of chemical method, physical method, bioanalysis, including but not limited to directly receive
One of collection, extraction, condensation, liquid separation, evaporation and concentration, filtering, acid-base neutralization, rectifying, screening, adsorption/desorption, centrifugation are several
Kind.The settable control system of recovery system 6 is realized intelligent.
(7) cold and heat source system 7 provides heat source and cold source to entire process units；The cold and heat source system 7 can design control
System is realized intelligent.
(8) air supply system 8 provides gas to entire process units.The air supply system is used to supply to production line.Gas supply
System can design control system, realize intelligent.
(9) gel systems 2 may be implemented colloidal sol and solidify and the aging of gel rubber material.
As shown in fig. 6, the solidification aging cabinet 15(of the gel systems 2 is without liner) directly formed without liner working space
One of middle setting heat transfer, radio-frequency radiation, infra-red radiation, sound wave, vibration or a variety of solidification aging accelerator 2-2, pass through
Solidify aging accelerator 2-2 and promote solidification and ageing time, preferred consolidation and aging temperature are -50 DEG C -300 DEG C, in 10S-5h
Solidification is completed, completes aging in 1min-48h.Waste treatment system 5, recovery system 6, cold and heat source system 7 with solidification ageing oven
Working space is connected in body 15.Air supply system 8 is by gas device 4-1 connection gel systems 2 without liner working space.
Conveying device 11, without passing through in liner working space, realizes the conveying of gel products, after supply from gel systems 2
Continuous production, collection device are effectively collected and the substance that drips or be poured out in processing system.The settable control system of gel systems,
It realizes intelligent.
As shown in fig. 7, the activation cabinet 14(of the gel activation system 3 is without liner) it is arranged in the working space that is directly formed
One of heat transfer, radio-frequency radiation, infra-red radiation, sound wave, vibration or a variety of activation accelerator 4-8 promote activation.Gel is living
Change system 3 is provided with the reagent storage being connected to itself working space inner cavity and supplementary device 4-7；Waste treatment system 5, recycling
System 6, cold and heat source system 7 are connected to the working space in activation cabinet 14.Air supply system 8 is connected to by gas device 4-1
Gel activation system 3 without liner working space.
The inventive gel time is short, modified high-efficient, drying is quick, simple process, with short production cycle, reaction process is controllable,
Equipment automatization and aerogel products continuous production may be implemented in low cost product.
Correspondingly, the method for preparing aeroge implemented according to the present invention includes the following steps:
S1: supplementary material is added in supplementary material system 1；The starting of conveying device 11 later is started to work；
S2: supplementary material enters gel systems 2, in the section by adjust pH, heat transfer, radio-frequency radiation, infra-red radiation, sound wave,
One of vibration or various ways promote solidification and aging, and shortening solidifies and the time of aging, preferred consolidation and aging temperature 0
DEG C -300 DEG C, solidification is completed in 10S-5h, completes aging in 1min-48h；
S3: solidify through gel systems 2 and driven through conveying device 11 with the gel after aging into gel activation system 3, realized
The activation of chemical functional group in wet gel, improves its reactivity, accelerates the modified speed of back segment, and preferred 0-300 DEG C of activation temperature,
Activation is completed in 10S-168h；
S4: gel after activation drives through conveying device 11 and enters modified and drying system 4, passes through sound wave, red in modified section
One or more of external radiation, vibration, heat transfer mode accelerate to be modified, and improve modification efficiency, preferably modification module work temperature
0-150 DEG C of degree, modified 30s-5h are completed；Enter dryer section later, by one of hot wind, infra-red radiation, heat transfer or
Several dryings, preferably 0-250 DEG C of irradiation modules drying temperature, dry 10s-2.5h are completed.
S5: in above steps, cold and heat source system 7 is connected to Cooling and Heat Source conveyance conduit to each working space and supplementary material system
System 1 carries out heating and cooling；Air supply system 8 supplies each working space and supplementary material system 1；The three wastes that entire workshop section generates
It is handled into waste treatment system 5；The material that recovery system 6 is collected in reaction process is recycled.
Further, corresponding with second embodiment of the invention, when reforming system in modified and drying system (4) and do
Drying system be it is discontinuous be separately provided and when the reaction compartment of selectable connection, S4 step is substituted by S4a step, at this point,
Gel after S2 step is directly or through entering step S4a after S3 step；Step S4a are as follows: gel is through 11 band of conveying device
It moves and enters modified and drying system 4, gel passes through reforming system and after modification into drying system, modified and dry
It is separately provided, modifying process and drying process are respectively independent.
Accelerate to be modified by one or more of sound wave, infra-red radiation, vibration, heat transfer mode in reforming apparatus,
Improve modification efficiency；It is preferred that 0-300 DEG C of reforming apparatus operating temperature, modification time 1min-2h, 2h-10h, 10h-24h, for 24 hours-
Any duration or unlimited duration in 48h, 48h-168h；Enter drying device later, passes through hot wind, infra-red radiation, heat transfer
One of or several, 30-500 DEG C of drying device operating temperature, dry 10s-5h complete.
Further, product post-processing system 9 and product packaging systems 10 are also set up after step s 5；Successively realize gas
The post-processing and packaging of gel products.
In the embodiment of such as Fig. 5, it is shown that increase product post-processing system 9 and product packaging systems 10；Add after product
The post-processing of aerogel products may be implemented in work system 9；Including but not limited to molding, performance regulation are handled, suppress, encapsulate, are filled
One or more of dress, dispersion, grinding, sorting.Product post-processing system 9 includes storage device, conveying device, collects dress
It sets, realizes the conveying and storage of product, the substance effectively generated in collection and processing system.Product post-processing system 9 can design
Control system is realized intelligent.
Product packaging systems 10 are used for the collection and packaging of aerogel products final finished.Product packaging systems 10 include storage
Cryopreservation device, conveying device realize the storage and conveying of product, the substance effectively generated in collection and processing system.Product packaging
System can design control system, realize intelligent.
Claims (10)
1. a kind of aeroge preparation system includes at least supplementary material system (1), gel systems (2), modified and drying system (4),
Still alternatively increase setting gel activation system (3) in gel systems (2), modified and drying system (4)；Its feature exists
In: the hollow tube that gel systems (2), gel activation system (3), modified and drying system (4) respective shell are directly formed
Shape or tunnel-like cavity are working space, and each working space is mutually indepedent and can form the tunnel being mutually communicated by opening and closing device
Road shape continues through space, and the conveying device (11) docked with supplementary material system (1) is arranged in each working space；In gel system
It is defeated that the Cooling and Heat Source being connected to inside each working space is respectively provided on system (2), gel activation system (3), modification and drying system (4)
Pipeline, gas passage, recovery approach and discharge-channel are sent, Cooling and Heat Source conveyance conduit is connected to cold and heat source system (7), gas passage
It is connected to air supply system (8), recovery approach is connected to recovery system (6), and discharge-channel is connected to waste treatment system (5).
2. aeroge preparation system according to claim 1, it is characterised in that: in the working space of gel systems (2)
Setting solidification aging accelerator, the accelerated mode for solidifying aging accelerator be radio-frequency radiation, sound wave, infra-red radiation, vibration,
One or more of heat transfer；Heat transfer is set in the working space of gel activation system (3), infra-red radiation, vibrates, penetrate
One or more of radio-frequency radiation, sound wave activate accelerator；Setting is modified in the working space of modification and drying system (4) adds
Fast device, the accelerated mode of the modified accelerator are one or more of sound wave, infra-red radiation, vibration, heat transfer.
3. aeroge preparation system according to claim 1, it is characterised in that: each accelerator is arranged at each working space
Top or lower part, or working space inboard wall of tube body circumferentially around setting.
4. aeroge preparation system according to claim 1, it is characterised in that: modified and drying system (4) are by individually setting
The modification and dry run-though space that the modified device set and the drying equipment being separately provided are connected in series or are wholely set；Change
Property and drying system (4) be integrated the modification of setting and when dry run-though space, in gel systems (2), modified and drying system
(4) gel activation system (3) must also be set in.
5. aeroge preparation system according to claim 1, it is characterised in that: also set up after modified and drying system (4)
Product post-processing system (9) and product packaging systems (10).
6. using the aeroge preparation method of any one of claim 1-5 aeroge preparation system, it is characterised in that including as follows
Step:
S1: supplementary material is added in supplementary material system (1)；Conveying device (11) starting later is started to work；
S2: supplementary material enters gel systems (2), by adjusting pH, heat transfer, radio-frequency radiation, infra-red radiation, sound in the section
One of wave, vibration or various ways promote solidification and aging, and shortening solidifies and the time of aging；
S3: solidify through gel systems (2) and enter gel activation system through conveying device (11) drive with the gel after aging
(3), the activation for realizing chemical functional group in wet gel improves its reactivity, accelerates the modified speed of back segment；
S4: the gel after activation drives through conveying device (11) and enters modified and drying system (4), passes through sound in modified section
One or more of wave, infra-red radiation, vibration, heat transfer mode accelerate to be modified, and improve modification efficiency；Enter drying later
Section by one of hot wind, infra-red radiation, heat transfer or several is dried；
S5: in above steps, cold and heat source system (7) is connected to Cooling and Heat Source conveyance conduit to each working space and supplementary material system
(1) heating and cooling is carried out；Air supply system (8) supplies each working space and supplementary material system (1)；What entire workshop section generated
The three wastes enter waste treatment system (5)；The material that recovery system (6) is collected in reaction process is recycled.
7. aeroge preparation method according to claim 6, it is characterised in that the method is applicable in aeroge without chlorine without alcohol
Technique.
8. aeroge preparation method according to claim 6, it is characterised in that solidification and aging temperature 0 in step s 2
DEG C -300 DEG C, solidification is completed in 10S-5h, completes aging in 1min-48h；Preferred 0-300 DEG C of activation temperature, 10S- in step S3
Activation is completed in 168h；0-150 DEG C of operating temperature of step S4 modification module, modified 30s-5h are completed；Irradiation modules drying temperature
0-250 DEG C, dry 10s-2.5h is completed.
9. aeroge preparation method according to claim 6, it is characterized in that: when system modified in modified and drying system (4)
When system and drying system are the discontinuous reaction compartment individually connected, S4 step is substituted by S4a step, at this point, S2 step is complete
Gel after finishing is directly or through entering step S4a after S3 step；
The step S4a are as follows: gel drives through conveying device (11) and enters modified and drying system (4), and gel is by being modified
System simultaneously enters drying system after modification, and modifying process and drying process are respectively independent.
10. aeroge preparation method according to claim 9, it is characterized in that: the reaction time in reforming system is 1min-
2h；2h-10h；10h-24h;24h-48h；Any duration or unlimited duration in 48h-168h.
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Application publication date: 20190521 |