CN109768294A - A kind of high security prevents high temperature lithium Asia cylindrical battery passivation system - Google Patents
A kind of high security prevents high temperature lithium Asia cylindrical battery passivation system Download PDFInfo
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- CN109768294A CN109768294A CN201711097667.8A CN201711097667A CN109768294A CN 109768294 A CN109768294 A CN 109768294A CN 201711097667 A CN201711097667 A CN 201711097667A CN 109768294 A CN109768294 A CN 109768294A
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- power supply
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- lithium asia
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Abstract
The present invention relates to a kind of high securities to prevent high temperature lithium Asia cylindrical battery passivation system, it includes power supply, single-chip microcontroller, arteries and veins adjustment circuit and temperature sensing circuit, detection circuit, intelligent control switch, activation intelligent control switch, is large current discharge circuit, electricity system;The power supply includes the first power supply and second source lithium Asia battery, and first power supply is the single-chip microcontroller, the pulse width regulating circuit and temperature sensing circuit power supply;When the first supply voltage is lower than setting value V1, by activating intelligent control switch to make lithium Asia battery and heavy-current discharge circuit conducting, and timing;When the first supply voltage is higher than setting value V2, lithium Asia cell channel is closed;The intelligent control switch is to select the first power supply or second source to power to electricity system;The activation intelligent control switch is to turn-on and turn-off second source and heavy-current discharge circuit.It can be relieved or avoid the generation of passivating film, thus the phenomenon that having avoided electricity from can not putting;It is significant to production cost is reduced simultaneously.
Description
Technical field
The present invention relates to a kind of high temperature lithium Asia cylindrical batteries;Especially a kind of high security prevents high temperature lithium Asia cylindrical battery
Passivation system.
Background technique
Lithium Asia battery is as modern intelligence instrument (referring mainly to intelligent water, electricity, gas, hotlist meter) mainstream power supply.The sub- electricity of lithium
The no unique advantage of other intrinsic electrochmical power sources of pond;Such as high and stable operating voltage;Temperature use scope is wide;High-energy is close
Degree;Long shelf-life;It is pollution-free.But lithium thionyl chloride cell the shortcomings that there are voltage delay.
The reason of influencing voltage delay is to form densification in its positive electrode surface after being in contact due to lithium metal with thionyl chloride
Lithium chloride film.This tunic slows down the continuation fast chemical reaction between lithium and thionyl chloride to a certain extent, due to electricity
Pond generates the residue deposition of trace impurity and single sulphur on the surface of carbon pores in electric discharge, to lead to the conclusion that " storage
Time is longer, and storage temperature is higher, this tunic is thicker." since lithium chloride film is ion conductor, non-conducting electronics, then storing
Battery afterwards could must normally export biggish electric current after eliminating this tunic when high current uses again, guarantee compared with senior engineer
Make voltage.Internal resistance value is larger during abolishing passivating film, connect between occurring as soon as voltage transient after electrical appliance or resistance decline compared with
It is low.Voltage is being gradually increasing after several seconds.Whether this is normal good phenomenon, do not worry battery without electricity.This is the sub- electricity of lithium
The characteristic in pond.Electrochemical educational circles be referred to as " voltage delay ", battery lag degree and Battery storage time length, storage temperature and
There is this close relationship using the size of electric current and water content, the electro-hydraulic purity of battery.The battery storage time is longer, storage
Temperature is higher, and electric current is bigger, and battery more lags, and load voltage is lower.Battery lag can be solved fundamentally.In electricity
Some higher additives of activity are added in pond, battery passivation film is without battery is in high activity state for a long time.Electricity
The self discharge in pond just becomes larger.The use and storage service life of battery just reduces.The passivating film of battery has dual character in a word, only
The more communication and discussion of user and producer are wanted, are not unconquerable problems.
In using power supply system of the disposable lithium Asia battery as backup power source.Such as in wireless gas meter, electricity is done
Pond is as main power supply, and disposable lithium Asia battery is as backup power source, when dry cell power supply is normal, uses the electricity of dry cell
Amount;When dry cell is without electricity, in order to guarantee being normally carried out for wireless telecommunications, powered using lithium Asia battery.Due to lithium Asia battery
It is pre- in gas meter, flow meter, in order to guarantee the service life of lithium Asia battery, the very small lithium Asia battery of self discharge need to be selected.
Generally conventional long-life batteries will receive the influence of lithium Asia battery (lithium/thinly chloride) distinctive passivating film,
It is long-term place (or not working) after, unexpected use, which will appear voltage, to be reduced, can not discharging current the case where, cause battery to seem
It is no longer valid.
Patent of invention content
The purpose of the present invention is to provide a kind of methods for protecting high temperature lithium Asia cylindrical battery overcharge and overdischarge.
To achieve the above object, high temperature lithium Asia cylindrical battery passivation system is prevented using a kind of high security at present, it is wrapped
Include power supply, single-chip microcontroller, arteries and veins adjustment circuit and temperature sensing circuit, detection circuit, intelligent control switch, activation intelligent control
Switch is large current discharge circuit, electricity system;The power supply include the first power supply and second source lithium Asia battery, described first
Power supply is the single-chip microcontroller, the pulse width regulating circuit and temperature sensing circuit power supply;The pulse width modulation
Circuit includes switching diode, the first and second capacitors, the first and second biswitch diodes and first to 3rd resistor;
Lithium Asia battery is electricity system power supply as second source;Power supply for electricity system power supply further includes the first electricity
Source;Voltage of the detection circuit to detect the first power supply, when the first supply voltage is lower than setting value V1, by activating intelligence
Can control switch makes lithium Asia battery and heavy-current discharge circuit conducting, and timing;When the first supply voltage is higher than setting value V2,
Close lithium Asia cell channel;The intelligent control switch is to select the first power supply or second source to power to electricity system;Institute
Activation intelligent control switch is stated to turn-on and turn-off second source and heavy-current discharge circuit.
First power supply is connect with the anode of the switching diode, and the cathode of the switching diode passes through described
First capacitor ground connection, the cathode of the switching diode connect with the first anode of the first biswitch diode, and described the
The cathode of a pair of switching diode passes through second capacity earth;The second plate of the first biswitch diode and institute
State the anode connection of lithium Asia battery, the cathode ground connection of lithium Asia battery;
The second plate of the first biswitch diode pass through the first resistor and the second biswitch diode the
The connection of one anode, the second plate of the second biswitch diode is connect with the pin BAT-V of the single-chip microcontroller, and is passed through
The second resistance is connect with the VCC, the cathode of the second biswitch diode and the pin IRVC1 of the single-chip microcontroller
Connection, and connect by the 3rd resistor with the pin IRVC2 of the single-chip microcontroller;The voltage of lithium Asia battery passes through institute
It states pin BAT-V and is transmitted to the single-chip microcontroller, the single-chip microcontroller carries out the electric discharge of different modes to lithium Asia battery.
The degree of battery heatproof -40 is to 165 degree.
Loading method loads 150 Ω resistor loaded electric current 190mA of 25W with detection box, loads one minute, and on-load voltage >=
It loads and completes when 26V.
Specific embodiment
The lithium Asia battery that the present invention selects is electricity system power supply as second source, is powered for the electricity system
Power supply further include the first power supply;Lithium Asia battery is electricity system when the first power supply does not work as backup power source
Power supply.
The present invention prevent lithium Asia battery passivation system it include power supply, single-chip microcontroller, arteries and veins adjustment circuit and temperature inspection
Slowdown monitoring circuit, detection circuit, intelligent control switch, activation intelligent control switch, are large current discharge circuit, electricity system;The electricity
Source includes the first power supply and second source lithium Asia battery, and first power supply is the single-chip microcontroller, pulse width modulation electricity
Road and temperature sensing circuit power supply.
In conclusion the method proposed by the present invention for preventing lithium Asia battery passivation, through control circuit, within every time
Lithium Asia battery work a period of time is allowed, lithium Asia battery just has continuous discharge when working, has the function that activation type lithium primary cell.
It is regularly discharged by lithium Asia battery, can be relieved or avoid the generation of passivating film, thus the phenomenon that having avoided electricity from can not putting.
The preferred embodiment of the present invention has been described above in detail, still, during present invention is not limited to the embodiments described above
Detail within the scope of the technical concept of the present invention can be with various simple variants of the technical solution of the present invention are made, this
A little simple variants all belong to the scope of protection of the present invention.
It is further to note that specific technical features described in the above specific embodiments, in not lance
In the case where shield, can be combined in any appropriate way, in order to avoid unnecessary repetition, the present invention to it is various can
No further explanation will be given for the combination of energy.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should also be regarded as the disclosure of the present invention.
Claims (3)
1. a kind of high security prevents high temperature lithium Asia cylindrical battery passivation system, it is characterised in that: it include power supply, single-chip microcontroller,
Arteries and veins adjustment circuit and temperature sensing circuit, detection circuit, intelligent control switch, activation intelligent control switch, high current are put
Circuit, electricity system;The power supply includes the first power supply and second source lithium Asia battery, and first power supply is the monolithic
Machine, the pulse width regulating circuit and temperature sensing circuit power supply;The pulse width regulating circuit includes switch two
Pole pipe, the first and second capacitors, the first and second biswitch diodes and first are to 3rd resistor;Lithium Asia battery is made
It is electricity system power supply for second source;Power supply for electricity system power supply further includes the first power supply;The detection circuit
To detect the voltage of the first power supply, when the first supply voltage is lower than setting value V1, by activating intelligent control switch to make lithium
Sub- battery and heavy-current discharge circuit conducting, and timing;When the first supply voltage is higher than setting value V2, it is logical to close lithium Asia battery
Road;The intelligent control switch is to select the first power supply or second source to power to electricity system;The activation intelligent control
Switch is to turn-on and turn-off second source and heavy-current discharge circuit;
First power supply is connect with the anode of the switching diode, and the cathode of the switching diode passes through described first
Capacity earth, the cathode of the switching diode are connect with the first anode of the first biswitch diode, and described first pair
The cathode of switching diode passes through second capacity earth;The second plate and the lithium of the first biswitch diode
The anode connection of sub- battery, the cathode ground connection of lithium Asia battery;
The second plate of the first biswitch diode pass through the first resistor and the second biswitch diode the
The connection of one anode, the second plate of the second biswitch diode is connect with the pin BAT-V of the single-chip microcontroller, and is passed through
The second resistance is connect with the VCC, the cathode of the second biswitch diode and the pin IRVC1 of the single-chip microcontroller
Connection, and connect by the 3rd resistor with the pin IRVC2 of the single-chip microcontroller;The voltage of lithium Asia battery passes through institute
It states pin BAT-V and is transmitted to the single-chip microcontroller, the single-chip microcontroller carries out the electric discharge of different modes to lithium Asia battery.
2. a kind of system for preventing lithium Asia battery passivation as described in claim 1, it is characterised in that: the battery heatproof -40
Degree is to 165 degree.
3. a kind of high security according to claim 1 prevents high temperature lithium Asia cylindrical battery passivation system, it is characterised in that:
Loading method loads 150 Ω resistor loaded electric current 190mA of 25W with detection box, loads one minute, and when on-load voltage >=26V loads
It completes.
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CN201711097667.8A CN109768294A (en) | 2017-11-09 | 2017-11-09 | A kind of high security prevents high temperature lithium Asia cylindrical battery passivation system |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111736495A (en) * | 2020-02-25 | 2020-10-02 | 济南沛华信息科技有限公司 | Intelligent instrument control method and device |
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CN102097664A (en) * | 2010-11-26 | 2011-06-15 | 上海复展照明科技有限公司 | Method and system for preventing lithium secondary battery from passivation |
CN102097663A (en) * | 2010-11-26 | 2011-06-15 | 上海复展照明科技有限公司 | Method and system for preventing passivation of lithium thionyl chloride battery |
CN103828120A (en) * | 2011-05-05 | 2014-05-28 | 申舒斯美国有限公司 | Method and apparatus for reducing battery passivation in a meter-reading module |
CN204287442U (en) * | 2014-12-15 | 2015-04-22 | 石家庄科林电气股份有限公司 | Circuit is eliminated in a kind of electric energy meter pond passivation detection and passivation |
CN105140576A (en) * | 2015-07-22 | 2015-12-09 | 北京嘉捷恒信能源技术有限责任公司 | System and method for preventing lithium thionyl chloride battery from being passivated |
RU158210U1 (en) * | 2014-12-12 | 2015-12-27 | Федеральное государственное унитарное предприятие "18 Центральный научно-исследовательский институт" Министерства обороны Российской Федерации | DEVICE FOR RESTORING PERFORMANCE OF PASSIVATED LITHIUM-THIONYL CHLORIDE BATTERY |
CN106165166A (en) * | 2014-04-03 | 2016-11-23 | Msa欧洲有限责任公司 | The method of depassivation, apparatus for carrying out the process and battery apparatus for lithium thionyl battery |
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Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS63187555A (en) * | 1987-01-27 | 1988-08-03 | Shin Kobe Electric Mach Co Ltd | Lithium-thionyl chloride battery |
CN102097664A (en) * | 2010-11-26 | 2011-06-15 | 上海复展照明科技有限公司 | Method and system for preventing lithium secondary battery from passivation |
CN102097663A (en) * | 2010-11-26 | 2011-06-15 | 上海复展照明科技有限公司 | Method and system for preventing passivation of lithium thionyl chloride battery |
CN103828120A (en) * | 2011-05-05 | 2014-05-28 | 申舒斯美国有限公司 | Method and apparatus for reducing battery passivation in a meter-reading module |
CN106165166A (en) * | 2014-04-03 | 2016-11-23 | Msa欧洲有限责任公司 | The method of depassivation, apparatus for carrying out the process and battery apparatus for lithium thionyl battery |
RU158210U1 (en) * | 2014-12-12 | 2015-12-27 | Федеральное государственное унитарное предприятие "18 Центральный научно-исследовательский институт" Министерства обороны Российской Федерации | DEVICE FOR RESTORING PERFORMANCE OF PASSIVATED LITHIUM-THIONYL CHLORIDE BATTERY |
CN204287442U (en) * | 2014-12-15 | 2015-04-22 | 石家庄科林电气股份有限公司 | Circuit is eliminated in a kind of electric energy meter pond passivation detection and passivation |
CN105140576A (en) * | 2015-07-22 | 2015-12-09 | 北京嘉捷恒信能源技术有限责任公司 | System and method for preventing lithium thionyl chloride battery from being passivated |
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CN111736495A (en) * | 2020-02-25 | 2020-10-02 | 济南沛华信息科技有限公司 | Intelligent instrument control method and device |
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