CN109761237A - A kind of efficient inside and outside dual-heating mode revolution retort - Google Patents

A kind of efficient inside and outside dual-heating mode revolution retort Download PDF

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Publication number
CN109761237A
CN109761237A CN201910020398.8A CN201910020398A CN109761237A CN 109761237 A CN109761237 A CN 109761237A CN 201910020398 A CN201910020398 A CN 201910020398A CN 109761237 A CN109761237 A CN 109761237A
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section
heating mode
charing
combustion chamber
outside dual
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李俊华
刘俊
李怀株
张利兵
陈建军
彭悦
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Tsinghua University
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Tsinghua University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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Abstract

The invention discloses a kind of efficient inside and outside dual-heating mode revolution retorts for belonging to active carbon carbonized material production equipment field.The inside and outside dual-heating mode revolution retort is composed in series by waste heat boiler and the second combustion chamber, feed hopper, feed screw, material guiding section, solidification section, lifting charing section, discharging section, the first combustion chamber, fuel gas inlet;Wherein the first combustion chamber is placed on pedestal, and discharging equipment is fixed on discharging section in the following, revolution charing furnace interior is filled using refractory casting material;Expansion chamber is mounted on feed screw in the following, and being connected to detritus tank.The retort can guarantee that carbonizing raw material and adverse current hot fume carries out fast pyrogenation solidification, not only avoid charing coal charge in rotary furnace building up inside, but also can quickly increase the intensity of its cold burden, thus effectively loss late of the lower coal grain in lifting charing section;Gained carbonized material has preferable wear-resistant pressure-resistant intensity, also can increase production capacity, provides enough raw material guarantees for subsequent activation section.

Description

A kind of efficient inside and outside dual-heating mode revolution retort
Technical field
The invention belongs to active carbon carbonized material production equipment field, in particular to a kind of efficient inside and outside dual-heating mode turns round charcoal Change furnace.
Background technique
Activated carbon product is many kinds of, is widely used in military chemical defence, space flight and aviation, air cleaning, water body purification, change The wide fields such as work synthesis, solution are recycled, medicine purifies, food decolourizes, Industrial " three Waste " is administered, using active carbon as carrier manufacture Catalyst be military " coring raw " protective equipment core material.Since its is acidproof, alkaline-resisting, heat-resisting, and after adsorption saturation Regeneration can be facilitated, play increasingly important role in protection environment for human survival.Active carbon is according to raw material difference, activity Charcoal can be divided into wooden active carbon, shell class active carbon, active carbon from coal and petroleum coke active carbon etc..Coal base or wooden carbon containing original Material carries out carbonization process, usually Low Temperature Pyrolysis Process (500~600 DEG C), be before activation be primarily intended for and basis, by charcoal The carbonized material of change process has a great impact to the quality of final products active carbon.
Equipment used is revolution retort when charing, and revolution retort is divided into internal heat type and two kinds of external-heat.Interior heat Formula revolution retort then has simple structure, technology controlling and process and easy to operate easy, thermal efficiency height, makes material by rotating mixing Be evenly heated, heating rate rationally, uniform quality, furnace atmosphere is easily controllable, product yield is high, product strength is high, yield is big, The advantages that continuous production is stable, therefore active carbon from coal manufacturing enterprise is widely used that internal heat type revolution charing at present Furnace.The working principle of internal-heated rotary furnace is that heat medium and the material carbonized continuously directly connect within the scope of certain temperature Touching, mutual reverse flow.Material is mobile from low-temperature space to high-temperature region, and reverse and next heat medium is constantly by heat aliment Material, temperature of charge steps up, so that the processes such as dehydration, degassing, drying, thermal decomposition, thermal polycondensation are completed, finally from high-temperature region Discharge port discharge;Heat medium is mobile from high-temperature region to low-temperature space, and since heat is constantly supplied material, own temperature gradually drops A large amount of volatile matters that are low and carrying material generation in carbonization process, are finally exported by furnace exit gas and are discharged.Traditional external-heat returns Turn retort due to structure is relative complex, cost is higher, the thermal efficiency is low etc., has been rarely employed now.Traditional outer heat Formula turns round retort due to structure is relative complex, cost is higher, the thermal efficiency is low etc., has been rarely employed now.It is novel outer Traditional mode of the heating revolving retort due to breaching revolution retort in process and structure, production capacity and the thermal efficiency Significantly larger than traditional inside and outside heating revolving retort.
The patent document that number of patent application is CN103787306A discloses a kind of external heat and turns round retort, in the patent Active carbon charing raw material be not directly contacted with flue gas, the combustion gas as caused by activation furnace through combustion chambers burn generation 500~600 DEG C flue gas retort is entered by burner, external-heat returns inside retort using stainless-steel pipe conveying charing raw coal, stainless steel Length of steel pipe is equal with rotary furnace entire length, and active carbon charing raw material is not directly contacted with flue gas, so can effectively avoid Material is accumulated higher in furnace tube under equal production volume in internal heat type retort, and ejection height is larger, and material uneven heating is even and grinds It is higher to damage and beat percentage of damage, carbonizes the problems such as finished product yield is low.But in operation process inside the external-heating revolving retort In there are tar in furnace in raw material blockage, furnace tail sealing material is not up to standard, and production capacity is not up to standard, brings inconvenience to next step activation The disadvantages of;When production capacity increases, the volatile matter of active carbon raw coal is largely precipitated, and can largely be blocked up in stainless-steel pipe furnace tail region domain Plug causes part obstructed, seriously limits the production capacity of complete equipment, while causing the quality of activated carbon of production not up to standard.
Summary of the invention
The object of the present invention is to provide a kind of efficient inside and outside dual-heating modes to turn round retort, which is characterized in that described inside and outside Dual-heating mode continuous rotary retort include waste heat boiler, the second combustion chamber, feed hopper, feed screw, material guiding section, solidification section, Lifting carbonizes section, discharging section, the first combustion chamber, fuel gas inlet, pedestal, discharging equipment, detritus tank and expansion chamber;The inside and outside mixed heat Formula is turned round retort and is carbonized by waste heat boiler and the second combustion chamber, feed hopper, feed screw, material guiding section, solidification section, lifting Section, discharging section, the first combustion chamber, fuel gas inlet are composed in series;Wherein the first combustion chamber is placed on pedestal, and discharging equipment is fixed on Discharging section is in the following, revolution charing furnace interior is filled using refractory material casting;Expansion chamber is mounted on feed screw in the following, simultaneously It is connected to detritus tank.
The revolution retort outer surface is provided with insulating layer.
The beginning of the feed screw is connect with feed hopper, and feed hopper front end is pelletizer, the end of feed screw It is connected to the beginning of retort.
The material guiding section is by mullite Al2O3-SiO2Refractory casting forms, the wear-resistant strength that has had and it is corrosion-resistant and High-temperature stability, long service life;
Eight stainless-steel pipes are used in the solidification section, the charing raw material entered from material guiding section enters eight stainless steel steel Inside pipe, charing raw material can be effectively avoided to accumulate in furnace tube higher, ejection height is larger, and material uneven heating is even and wears Higher with percentage of damage is beaten, charing finished product yield is low;It can make to carbonize raw material fast eliminating outside water, rapid curing;
The lifting carbonizes section, internal to use refractory material casting at effective length is 12~14 meters, using zigzag Internal structure can guarantee that carbonized material is sufficiently shed in inside in carrying out carbonization process, hot fume and material counter current contacting, The contact area of charing raw material and flue gas is increased in this way, guarantees the efficient fast pyrogenation of carbonized material.
The discharging section, it is internal to use refractory material casting at inner surface is smooth, and bottom end is connected with discharging equipment It connects;
Second combustion chamber and waste heat boiler are mainly by the volatilization for the raw coke oven gas and coalite tar for carbonizing section generation Divided combustion, waste heat boiler generate steam used in activation section using the heat of the second combustion chamber.
The pedestal, top are provided with rotary furnace slewing and the first combustion chamber, the combustion material of the first combustion chamber Predominantly outer combustion gas or activation section generate CO+H2Combustion gas, the first combustion chamber generate flue gas, enter discharging section when temperature Degree can reach 600-800 DEG C.
The expansion chamber and detritus tank, are set to the second combustion chamber right end, and main function is to collect charing raw material to exist The tar that pyrolytic process generates prevents it from blocking flue gas pipeline.
The beneficial effects of the invention are as follows being turned round in retort in efficient inside and outside dual-heating mode, by solidifying section using special Internal structure, guarantee that charing raw material and adverse current hot fume carry out rapid heat and exchange, on the one hand, this inside and outside to mix hot mode Heat transfer mode, the moisture fast eliminating that can be effectively shortened in coal intragranular portion and coal tar, internal temperature is quickly Just reach 400 DEG C, on the other hand ensure that gel and binder quickly can be acted on adequately, it can by the processing of this section It avoids charing coal charge in rotary furnace building up inside, and the intensity of its cold burden can be quicklyd increase, so that charing coal grain effectively be avoided to exist The greater loss rate of lifting charing section;Compared with individual external-heat or internal heat type retort, carbonized material obtained by the retort With preferable wear-resistant pressure-resistant intensity, while the production capacity of carbonized material can be increased, provide raw material guarantee for later period activation section.
Detailed description of the invention
Fig. 1 is the side view that efficient inside and outside dual-heating mode turns round retort;
Fig. 2 is the sectional view that inside and outside dual-heating mode turns round material guiding section inside retort;
Fig. 3 is the sectional view that inside and outside dual-heating mode turns round retort internal curing section;
Fig. 4 is the sectional view that inside and outside dual-heating mode turns round that lifting inside retort carbonizes section;
Fig. 5 is the sectional view that inside and outside dual-heating mode turns round discharging section inside retort;
Label declaration:
1, waste heat boiler;2, the second combustion chamber;3, feed hopper;4, feed screw;5, material guiding section;6, solidify section;7, resistance to Fiery castable;8, lifting carbonizes section;9, discharging section;10, the first combustion chamber;11, fuel gas entrance;12, pedestal;13, it discharges Equipment;14, detritus tank;15, expansion chamber;16, spiral shape deflector chute (refractory matter mullite Al2O3-SiO2Casting);17. stainless steel Steel pipe (06Cr25Ni20 (GB/T20878-2007);18,304 stainless steels weldering nail.
Specific embodiment
The present invention provides a kind of efficient inside and outside dual-heating mode revolution retort, is said below in conjunction with drawings and examples It is bright.
As shown in Figure 1, Figure 2, Fig. 3, Fig. 4 and efficient inside and outside dual-heating mode revolution retort shown in fig. 5, including waste heat boiler 1, Second combustion chamber 2, feed hopper 3, feed screw 4, material guiding section 5, solidification section 6, lifting charing section 8, discharging section 9, first burn Room 10, fuel gas inlet 11, pedestal 12, discharging equipment 13, detritus tank 14, expansion chamber 15, spiral shape deflector chute (refractory matter mullite Al2O3-SiO2Casting) 16, the stainless steel of the stainless-steel pipe 17 and 304 weldering nail 18 that material is 0Cr25Ni20;It turns round in retort Portion mainly uses refractory casting material 7, stainless-steel pipe 17 (06Cr25Ni20) and 304 stainless steels weldering nail 18;Wherein, waste heat pot Furnace 1 and the second combustion chamber 2, feed hopper 3, feed screw 4, material guiding section 5, solidification section 6, lifting carbonize section 8, discharging section 9, first Combustion chamber 10, fuel gas inlet 11 are composed in series;Wherein the first combustion chamber 10 is placed on pedestal 12, and discharging equipment 13 is fixed on discharging Section 9 is in the following, revolution charing furnace interior is filled using refractory casting material 7;Expansion chamber 15 be mounted on feed screw 4 in the following, And (as shown in Figure 1) is connected to detritus tank 14.
The revolution retort outer surface is provided with insulating layer.
Charing raw material and hot fume counter current contacting in entirely revolution furnace system, the column activity being prepared through pelletizer Charcoal first passes around feed hopper 3, is then entered inside revolving activation furnace by feed screw 4 again, then passes sequentially through guide Section 5 (material guiding section construction as shown in Figure 2) solidifies section 6 (solidification section construction as shown in Figure 3) and lifting charing 8 (such as Fig. 4 of section Shown in lifting charing section construction), discharging section 9 (as shown in Figure 5 discharging section construction) is eventually arrived at, in the vertical of discharging section 9 Direction bottom enters activation workshop section by discharging equipment 13, then through guide equipment;Burner part region is the first burning Room 10, in the part, outer combustion gas 11 is generally CO+H produced by coke-stove gas or activation section2Synthesis gas in the combustion chamber After burning, generate the flue gas that temperature is about 800 DEG C, hot fume first passes around discharging section 9, then pass sequentially through lifting charing section 8, Solidify section 6, material guiding section 5, inside rotary furnace, charing coal grain releases a large amount of volatile matter in low temperature distillation process, mainly For raw coke oven gas and coalite tar, after the volatile matter released is mixed with the flue gas that the first combustion chamber 10 generates, furnace is first passed around The expansion chamber 15 of tail, the tar in flue gas are deposited to detritus tank 14 inside expansion chamber 15, and next step flue gas enters the second combustion Room 2 is burnt, the hot fume that the second combustion chamber 2 generates generates vapor and use for activation section into waste heat boiler 1.In this way can Guarantee that rotary furnace internal structure is stablized, and can guarantee that equipment has longer service life
In the specific implementation, the column-shaped active carbon being prepared through pelletizer first passes around feed hopper 3, then passes through spiral Charger 4 enters inside revolving activation furnace, then passes sequentially through material guiding section 5;By material guiding section 5, original coal grain is carbonized successively Into inside 8 stainless-steel pipes, inside these stainless-steel pipes, hot cigarette caused by raw coal and the first combustion chamber 10 is carbonized Gas countercurrent contact carries out inside and outside dual-heating mode rapid draing pyrolysis, removes its internal moisture, at the same internal gel and coal tar into Row sufficiently effect, compared with raw coal intensity after cold pressing, the charing raw coal anti-pressure and abrasion-proof intensity by solidifying the processing of section 6 is obviously mentioned It rises;Then charing raw coal sequentially enters lifting charing section 8, carries out extensive pyrolysis, pyrolysis temperature is about 600 DEG C, is eventually entered into out Expect section 9, using discharging equipment 13, transports activation workshop section to by web feed machine.

Claims (10)

1. a kind of efficient inside and outside dual-heating mode turns round retort, which is characterized in that the efficient inside and outside dual-heating mode continuous rotary Retort includes waste heat boiler, the second combustion chamber, feed hopper, feed screw, material guiding section, solidification section, lifting charing section, discharging Section, the first combustion chamber, fuel gas inlet, pedestal, discharging equipment, detritus tank and expansion chamber;Inside and outside dual-heating mode revolution retort by Waste heat boiler and the second combustion chamber, feed hopper, feed screw, material guiding section, solidification section, lifting charing section, discharging section, the first combustion Burn room, fuel gas inlet is composed in series;Wherein the first combustion chamber is placed on pedestal, and discharging equipment is fixed on discharging section in the following, revolution Furnace interior is carbonized to fill using refractory casting material;Expansion chamber is mounted on feed screw in the following, and being connected to detritus tank.
2. a kind of efficient inside and outside dual-heating mode turns round retort according to claim 1, which is characterized in that the revolution charing Furnace outer surface is provided with insulating layer.
3. a kind of efficient inside and outside dual-heating mode turns round retort according to claim 1, which is characterized in that the spiral charging The beginning of machine is connect with feed hopper, and feed hopper front end is pelletizer, and the end of feed screw is connected to the beginning of retort.
4. a kind of efficient inside and outside dual-heating mode turns round retort according to claim 1, which is characterized in that the material guiding section by Mullite Al2O3-SiO2Refractory material casting at, the wear-resistant strength having had and corrosion-resistant and high-temperature stability, service life It is long.
5. a kind of efficient inside and outside dual-heating mode turns round retort according to claim 1, which is characterized in that in the solidification section Use eight root timber matter for 06Cr25Ni20 stainless-steel pipe, the charing raw material entered from material guiding section enters in eight stainless-steel pipes Portion can effectively avoid charing raw material from accumulating in furnace tube higher, and ejection height is larger, and material uneven heating is even and wears and falls The problems such as percentage of damage is higher, and charing finished product yield is low is beaten, can make to carbonize raw material fast eliminating outside water, rapid curing.
6. a kind of efficient inside and outside dual-heating mode turns round retort according to claim 1, which is characterized in that the lifting charing Section, internal to be filled using refractory material casting, effective length is 12~14 meters, using zigzag internal structure, is carrying out charcoal During change, it can guarantee that carbonized material is sufficiently shed in inside, hot fume and material counter current contacting increase charing raw material in this way With the contact area of flue gas, guarantee the efficient fast pyrogenation of carbonized material.
7. a kind of efficient inside and outside dual-heating mode turns round retort according to claim 1, which is characterized in that the discharging section, Its inside is using refractory material casting at inner surface is smooth, and bottom end is connected with discharging equipment.
8. a kind of efficient inside and outside dual-heating mode turns round retort according to claim 1, which is characterized in that second burning Room and waste heat boiler are mainly the volatile combustion that will carbonize raw coke oven gas and coalite tar that section generates, and waste heat boiler utilizes the The heat of two combustion chambers generates steam used in activation section.
9. a kind of efficient inside and outside dual-heating mode turns round retort according to claim 1, which is characterized in that the pedestal, Top is provided with rotary furnace slewing and the first combustion chamber, and the combustion material of the first combustion chamber is mainly outer combustion gas or work Change section and generates CO+H2Synthesis gas, the first combustion chamber generate flue gas, enter discharging section when temperature can reach 600-800 ℃。
10. a kind of efficient inside and outside dual-heating mode turns round retort according to claim 1, which is characterized in that the expansion chamber And detritus tank, it is set to the second combustion chamber right end, main function is the tar collecting charing raw material and generating in pyrolytic process, Prevent it from blocking flue gas pipeline.
CN201910020398.8A 2019-01-09 2019-01-09 A kind of efficient inside and outside dual-heating mode revolution retort Pending CN109761237A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110921664A (en) * 2019-11-15 2020-03-27 太原理工大学 High-yield and energy-saving production system of activated carbon carbonization furnace
CN110921663A (en) * 2019-11-15 2020-03-27 太原理工大学 High-yield curing machine for producing activated carbon
CN111056553A (en) * 2019-11-15 2020-04-24 太原理工大学 High-yield rotary carbonization furnace for producing activated carbon
CN111204763A (en) * 2019-11-15 2020-05-29 太原理工大学 Efficient internal and external mixed heating type rotary carbonization furnace for producing activated carbon
CN112340733A (en) * 2019-08-06 2021-02-09 中冶长天国际工程有限责任公司 Production system of active carbon carbonization material

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112340733A (en) * 2019-08-06 2021-02-09 中冶长天国际工程有限责任公司 Production system of active carbon carbonization material
CN112340733B (en) * 2019-08-06 2022-08-16 中冶长天国际工程有限责任公司 Production system of active carbon carbonization material
CN110921664A (en) * 2019-11-15 2020-03-27 太原理工大学 High-yield and energy-saving production system of activated carbon carbonization furnace
CN110921663A (en) * 2019-11-15 2020-03-27 太原理工大学 High-yield curing machine for producing activated carbon
CN111056553A (en) * 2019-11-15 2020-04-24 太原理工大学 High-yield rotary carbonization furnace for producing activated carbon
CN111204763A (en) * 2019-11-15 2020-05-29 太原理工大学 Efficient internal and external mixed heating type rotary carbonization furnace for producing activated carbon
CN110921663B (en) * 2019-11-15 2024-01-30 太原理工大学 A high yield solidification machine for producing active carbon

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