CN109758380A - A kind of hair-dyeing agent of pigment containing biomass or pigment precursor - Google Patents
A kind of hair-dyeing agent of pigment containing biomass or pigment precursor Download PDFInfo
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- CN109758380A CN109758380A CN201910234428.5A CN201910234428A CN109758380A CN 109758380 A CN109758380 A CN 109758380A CN 201910234428 A CN201910234428 A CN 201910234428A CN 109758380 A CN109758380 A CN 109758380A
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Abstract
The present invention provides the hair-dyeing agent of a kind of pigment containing biomass or pigment precursor, is made of pretreating agent, coloring agent, and wherein dyestuff is the pigment or pigment precursor of biomass type, and pretreating agent, coloring agent contain reducing agent, oxidant respectively.Hair-dyeing agent to the sequence of operation of hair in two steps: pretreating agent ingredient and coloring agent ingredient.The present invention is by way of respectively adding reducing agent, oxidant in pretreating agent and coloring agent, realization is applied in combination, it can make hair surface layer that microstructure adjustment occur, be obviously improved the porosity of its surface structure temporarily, so that biomass pigment is penetrated into hair body interior and finally colour developing creation necessary condition for dyeing phase.Meanwhile selecting Geniposide is biomass pigment/pigment precursor, when being free of niacin, niacinamide or derivatives thereof in adjuvant, coloration result is black-and-blue；If niacin, niacinamide or derivatives thereof are added in adjuvant, hair can be made to obtain the black hair dyeing effect of nature.
Description
Technical field
The invention belongs to hair care hair care art, it is related to the hair-dyeing agent of a kind of pigment containing biomass type or pigment precursor.
Background technique
Various non-transitories (containing the permanent and semipermanent) hair dye product that can be found on Vehicles Collected from Market, mainly
It is formulated by abiotic matter type pigment or pigment precursor.They have various either large or small health concerns, and there is certain
Health risk.So for a long time, people are seeking always the smaller product of health risk.
Natural or biomass type pigment/pigment precursor is the object of numerous trials of health type hair dye.But due to
The characteristics of their own, such as molecular structure, molecular dimension size, chemical property and application conditions and to be dyed right
As --- hair surface layer has natural stability and stronger shielding in microstructure and chemical property, so as to them
Popularization and using being difficult to realize always.
Summary of the invention
The object of the present invention is to provide the hair-dyeing agent of a kind of pigment containing biomass or pigment precursor, by pretreating agent,
Coloring agent forms, and contains reducing agent in pretreating agent component, oxidant, the dye in coloring agent of the present invention are contained in coloring agent component
Material is the pigment or pigment precursor of biomass type；Hair-dyeing agent to the sequence of operation of hair in two steps, it is respectively step 1: pre-
Inorganic agent ingredient, step 2: coloring agent ingredient, in which:
A. pretreating agent is made of reducing agent and adjuvant, specifically by following proportion at being grouped as: (following unit is
Part)
1. reducing agent: 0.5~1.5
2. adjuvant:
B. coloring agent is made of biomass pigment or pigment precursor, oxidant and adjuvant, specifically by following proportion at
It is grouped as: (following unit is part)
1. biomass pigment or pigment precursor: 0.2~1.0
2. oxidant: 0.1~0.4
3. adjuvant:
The biomass pigment or pigment precursor that the present invention selects, including but not limited to following kind: Geniposide, turmeric, height
Fine strain of millet is red, Monascus color, natural indigo, juglone, hematoxylin, alkermes, extra large Na pigment.
The reducing agent that the present invention selects includes but is not limited to following kind: cysteine or its esters, cysteine derivatives
Object (such as its esters), cystine or its esters, cystine derivatives (such as its esters), thioacetic acid.
The oxidant that the present invention selects includes but is not limited to following kind: hydrogen peroxide, percarbonate (such as SODIUM PERCARBONATE,
Potassium percarbonate), persulfate (such as ammonium persulfate, sodium peroxydisulfate), perborate (such as potassium perborate, sodium perborate), oxygen
Gas.
The adjuvant that the present invention selects includes but is not limited to following kind:
(1) bleeding agent: ethanol amine, acetic acid, bisabolol；
(2) conditioner: bisabolol；
(3) develop the color adjusting/nutritional agents: arginine, Nicotinic Acid/Nicotinamide or their derivative；
(4) color stabilizer: sodium phytate or sodium tripolyphosphate；
(5) acidity-basicity regulator: potassium carbonate, sodium hydroxide, potassium hydroxide, ethanol amine, acetic acid；
(6) thickener/emulsifier: SEPIPLUSTM400 (polyacrylate -13, poly- isobutanol, sorbitol ester 20 compounds)；
(7) solvent: water, propylene glycol.
The hair colouring methods of hair-dyeing agent of the present invention, by choosing any one kind of them reality from following two kinds upper dye operating processes
It is existing.
Upper dye operating process 1: the pretreating agent of reproducibility is uniformly applied to hair, pretreating agent composition:
Pretreating agent composition can also be selected:
Hair grooming far infrared or steam heating method are handled 30 minutes at 40~42 DEG C, removed with scraper plate and blotting paper
Pretreating agent is removed, the coloring agent of oxidisability is uniformly applied on hair, coloring agent composition:
Coloring agent composition can also be selected:
It is handled 30 minutes at 40~45 DEG C with far infrared or steam heating method, the medicine on hair is washed away with clear water
Hair dyeing is completed in agent.
Upper dye operating process 2: the pretreating agent of reproducibility is applied to hair, pretreating agent composition
The above dye identical heating method of operating process 1 one stops 30 minutes at 40~42 DEG C after smearing uniformly, above-mentioned pre-
Inorganic agent need not remove, and oxidant, biomass dyestuff are added directly on hair:
0.2~1.0 hydrogen peroxide 0.2~0.5 of Geniposide
Pretreating agent and the oxidant added below, biomass dyestuff collective effect are above after smearing uniformly to contaminate in hair
The identical heating method of operating process 1 stops 30 minutes at a temperature of 40~45 DEG C, washes away the medicament on hair with clear water, has had hair dyed
At.
The present invention has the advantages that following main:
(1) any artificial dye-stuff is free of as unique pigment composition using the biomass pigment of natural source, thus
By security risk control to close to minimum.
(2) nutrition contained by, conditioner ingredient, it can be ensured that use safety and health.
(3) without multiple dyeing operation, it can once dye and be satisfied with color and depth, save time and cost.
(4) after the completion of dyeing, hair quality is submissive, smooth, without other side effects.
(5) it is lasting to protect color there are many selection, color yield height, good color fastness for color.
(6) more convenient in dye operation on, also not excessive taboo.
Problems solved by the invention is --- it is so that biomass pigment/pigment precursor is needed to contaminating on hair to hair
It is suitably adjusted in the microstructure on surface layer, the porosity of its surface structure is enable temporarily to keep in the dying operation stage
Enough levels infiltrate into inside hair for following biomass pigment and stablize colour developing and create necessary condition；Another problem
It is to need that hair is further made to obtain nature black pool or the color yield of coloring hairs to be obviously improved.
The basic principle of hair colouring methods of the present invention: by respectively adding reducing agent, oxidation in pretreating agent and coloring agent
Reducing agent, oxidant is applied in combination in the mode of agent, realization, can make hair surface layer that the appropriate adjustment in microstructure occur, make it
The porosity of surface structure, which is temporarily got, to be obviously improved.For next second stage, that is, dyeing phase, biomass pigment seeps
It penetrates into the inside into hair main body and finally develops the color, create necessary condition.In addition, adding niacin, cigarette in the adjuvant
Amide or their derivative can make hair generate form and aspect transformation on the basis of original dyeing effect or significantly improve color yield.
When biomass pigment/pigment precursor of the selected Geniposide as this hair dye, when selected adjuvant (such as the auxiliary in example 1
Agent) in without niacin, niacinamide or their derivative when, coloration result is black-and-blue；If being added in above-mentioned adjuvant suitable
Niacin, niacinamide or their derivative of amount can then make hair obtain the black hair dyeing effect of nature.
Specific embodiment
The present invention is further described in conjunction with the embodiments.In the examples below, the reagent, which is only indicated in, faces dye behaviour
The constituent for needing allotment to reach before work, rather than actual commercialization existing forms.
Embodiment 1
This example completes operation using two steps, and the first step is pretreatment, second step is dyeing；1 step is pressed according to process flow
Rapid operation.
1. pretreating agent forms:
2. coloring agent forms:
Effect after hair dyeing: hair is in blue-black color.
Embodiment 2
This example completes operation using two steps, and the first step is pretreatment, second step is dyeing；The step of according to process flow 1
Operation.
1. pretreating agent forms:
2. coloring agent forms:
Hair dyeing effect: hair is in nature black pool.
Embodiment 3
This example completes operation using two steps, and the first step is pretreatment, second step is that midway is blended into oxidant and biomass dye
Material is to dye；It is operated according to the step of process flow 3.
1. pretreating agent forms:
2. midway is successively blended into following components (first mixing with a small amount of solvent) respectively, and smears uniform:
0.2~1.0 hydrogen peroxide 0.2~0.5 of Geniposide.
2. note: above-mentioned 1. pretreating agent and being blended into medicament halfway, the form that microencapsulation can also be respectively adopted mixes in advance
1. in pretreating agent, then this step operating procedure and previous step pretreating agent operating procedure can be combined into one.
Hair dyeing effect: hair is in nature black pool.
Claims (9)
1. the hair-dyeing agent of a kind of pigment containing biomass or pigment precursor, is made of pretreating agent, coloring agent, wherein pre- place
Contain adjuvant in reason agent, contains dyestuff, adjuvant in coloring agent；Hair-dyeing agent to the sequence of operation of hair in two steps, point
It is not step 1: pretreating agent ingredient, step 2: coloring agent ingredient, it is characterised in that: the dyestuff in coloring agent is biomass type
Pigment or pigment precursor, contain reducing agent in pretreating agent component, and contain oxidant in coloring agent component.
2. the hair-dyeing agent of a kind of pigment containing biomass according to claim 1 or pigment precursor, which is characterized in that oxygen
Agent selects one or more of following ingredients: hydrogen peroxide, percarbonate, persulfate, perborate, oxygen, described to cross carbon
Hydrochlorate selects SODIUM PERCARBONATE, potassium percarbonate, and the persulfate selects ammonium persulfate, sodium peroxydisulfate, and the perborate is selected
Potassium perborate, sodium perborate.
3. the hair-dyeing agent of a kind of pigment containing biomass according to claim 1 or pigment precursor, which is characterized in that institute
The reducing agent stated selects one or more of following ingredients: cysteine or its esters, cysteine derivative, cystine
Or its esters, cystine derivatives, thioacetic acid.
4. the hair-dyeing agent of a kind of pigment containing biomass according to claim 1 or pigment precursor, which is characterized in that institute
Biomass pigment or pigment precursor selection one or more of the following ingredients stated: Geniposide, turmeric, chrysanthemum, Monascus color,
Natural indigo, juglone, hematoxylin, alkermes, extra large Na pigment.
5. the hair-dyeing agent of a kind of pigment containing biomass according to claim 1 or pigment precursor, the adjuvant packet
Containing bleeding agent, conditioner, colour developing adjusting/nutritional agents, color stabilizer, acidity-basicity regulator, solvent, thickener/emulsifier, feature exists
In wherein bleeding agent selects one or more of ethanol amine, acetic acid, bisabolol；Conditioner selects bisabolol；Colour developing is adjusted
Section/nutritional agents selects one or more of Nicotinic Acid/Nicotinamide or their derivative, arginine；Color stabilizer selection sodium phytate,
One of sodium tripolyphosphate or two kinds.
6. the hair-dyeing agent of a kind of pigment containing biomass according to claim 1 or pigment precursor, it is characterised in that:
Niacin, niacinamide or their derivative are added in the adjuvant, and hair can be made to generate on the basis of original dyeing effect
Form and aspect turn.
7. the hair-dyeing agent of a kind of pigment containing biomass according to claim 1 or pigment precursor, which is characterized in that
Niacin, niacinamide or their derivative, and the selected biomass using Geniposide as hair dye are added in the adjuvant
When pigment/pigment precursor, hair can be made to generate form and aspect transformation on the basis of original dyeing effect and realize the black hair dyeing effect of nature.
8. the hair-dyeing agent of a kind of pigment containing biomass according to claim 1 or pigment precursor, which is characterized in that pre-
Inorganic agent is by following proportion at being grouped as:
9. the hair-dyeing agent of a kind of pigment containing biomass type according to claim 1 or pigment precursor, which is characterized in that
Coloring agent is by following proportion at being grouped as:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910234428.5A CN109758380B (en) | 2019-03-26 | 2019-03-26 | Hair coloring agent containing biomass pigment or pigment precursor |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910234428.5A CN109758380B (en) | 2019-03-26 | 2019-03-26 | Hair coloring agent containing biomass pigment or pigment precursor |
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| CN109758380A true CN109758380A (en) | 2019-05-17 |
| CN109758380B CN109758380B (en) | 2022-02-11 |
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| CN201910234428.5A Active CN109758380B (en) | 2019-03-26 | 2019-03-26 | Hair coloring agent containing biomass pigment or pigment precursor |
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Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02200617A (en) * | 1989-01-31 | 1990-08-08 | Tomiyuki Komiyama | Hair dyeing agent and hair dyeing agent used together for hair dyeing and cold permanent wave |
| CN1054716A (en) * | 1990-02-02 | 1991-09-25 | 株式会社常绿汉方制药 | With iridoid glycoside and the hair dyeing of glycoside unit thereof |
| JP2000302653A (en) * | 1999-04-27 | 2000-10-31 | Hoyu Co Ltd | Oxidative hair dye composition and hair treating agent composition for hair dyeing |
| DE19955914A1 (en) * | 1999-11-20 | 2001-06-13 | Wella Ag | Synthesis of indigo and 2,2'-bis(3-oxo-pyrrolo(2,3-b)pyridylidene) compounds, used for coloring keratinous fibers, e.g. human hair, involves enzymatic conversion and oxidation of tryptophan derivative with tryptophanase then oxidase |
| CN1462184A (en) * | 2001-04-27 | 2003-12-17 | 株式会社科思美 | Hair dye composition for dressing hair |
| DE102006060944A1 (en) * | 2006-02-21 | 2007-08-30 | Henkel Kgaa | Use of a cosmetic product comprising a selected active ingredient, e.g. a N-acyl tryrosine-arginine dipeptide ester, to sooth the skin during or immediately after oxidative hair treatment |
| WO2012060522A1 (en) * | 2010-11-03 | 2012-05-10 | Bae Young-Ae | Dyeing method, blue-dye production method, and a kit therefor |
| JP2013133320A (en) * | 2011-12-27 | 2013-07-08 | Milbon Co Ltd | Hair dye |
| CN103505379A (en) * | 2012-06-29 | 2014-01-15 | 西南民族大学 | Natural hair dye prepared from iridoid and amino acid and hair dyeing method |
| CN105687520A (en) * | 2016-02-22 | 2016-06-22 | 霸州市巨隆生物科技有限公司 | Hair nurturing liquid for inhibiting hair loss and white hair and promoting hair growth and preparation method |
-
2019
- 2019-03-26 CN CN201910234428.5A patent/CN109758380B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02200617A (en) * | 1989-01-31 | 1990-08-08 | Tomiyuki Komiyama | Hair dyeing agent and hair dyeing agent used together for hair dyeing and cold permanent wave |
| CN1054716A (en) * | 1990-02-02 | 1991-09-25 | 株式会社常绿汉方制药 | With iridoid glycoside and the hair dyeing of glycoside unit thereof |
| JP2000302653A (en) * | 1999-04-27 | 2000-10-31 | Hoyu Co Ltd | Oxidative hair dye composition and hair treating agent composition for hair dyeing |
| DE19955914A1 (en) * | 1999-11-20 | 2001-06-13 | Wella Ag | Synthesis of indigo and 2,2'-bis(3-oxo-pyrrolo(2,3-b)pyridylidene) compounds, used for coloring keratinous fibers, e.g. human hair, involves enzymatic conversion and oxidation of tryptophan derivative with tryptophanase then oxidase |
| CN1462184A (en) * | 2001-04-27 | 2003-12-17 | 株式会社科思美 | Hair dye composition for dressing hair |
| DE102006060944A1 (en) * | 2006-02-21 | 2007-08-30 | Henkel Kgaa | Use of a cosmetic product comprising a selected active ingredient, e.g. a N-acyl tryrosine-arginine dipeptide ester, to sooth the skin during or immediately after oxidative hair treatment |
| WO2012060522A1 (en) * | 2010-11-03 | 2012-05-10 | Bae Young-Ae | Dyeing method, blue-dye production method, and a kit therefor |
| JP2013133320A (en) * | 2011-12-27 | 2013-07-08 | Milbon Co Ltd | Hair dye |
| CN103505379A (en) * | 2012-06-29 | 2014-01-15 | 西南民族大学 | Natural hair dye prepared from iridoid and amino acid and hair dyeing method |
| CN105687520A (en) * | 2016-02-22 | 2016-06-22 | 霸州市巨隆生物科技有限公司 | Hair nurturing liquid for inhibiting hair loss and white hair and promoting hair growth and preparation method |
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| CN109758380B (en) | 2022-02-11 |
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