CN109747105A - Shell and preparation method thereof and electronic product - Google Patents
Shell and preparation method thereof and electronic product Download PDFInfo
- Publication number
- CN109747105A CN109747105A CN201711064013.5A CN201711064013A CN109747105A CN 109747105 A CN109747105 A CN 109747105A CN 201711064013 A CN201711064013 A CN 201711064013A CN 109747105 A CN109747105 A CN 109747105A
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- Prior art keywords
- layer
- shell
- ink
- glass
- metal base
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- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000010410 layer Substances 0.000 claims abstract description 135
- 239000011521 glass Substances 0.000 claims abstract description 116
- 238000000034 method Methods 0.000 claims abstract description 83
- 229910052751 metal Inorganic materials 0.000 claims abstract description 78
- 239000002184 metal Substances 0.000 claims abstract description 78
- 239000011248 coating agent Substances 0.000 claims abstract description 65
- 238000000576 coating method Methods 0.000 claims abstract description 65
- 239000002131 composite material Substances 0.000 claims abstract description 39
- 239000011241 protective layer Substances 0.000 claims abstract description 33
- 238000009413 insulation Methods 0.000 claims abstract description 30
- 229920003023 plastic Polymers 0.000 claims abstract description 30
- 239000004033 plastic Substances 0.000 claims abstract description 30
- 238000005034 decoration Methods 0.000 claims abstract description 23
- 229920002799 BoPET Polymers 0.000 claims abstract description 22
- 238000001746 injection moulding Methods 0.000 claims description 41
- 239000012190 activator Substances 0.000 claims description 38
- 239000000463 material Substances 0.000 claims description 38
- 229910000838 Al alloy Inorganic materials 0.000 claims description 31
- 239000004952 Polyamide Substances 0.000 claims description 31
- 229920002647 polyamide Polymers 0.000 claims description 31
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 30
- 239000000758 substrate Substances 0.000 claims description 28
- 239000003365 glass fiber Substances 0.000 claims description 26
- 238000012545 processing Methods 0.000 claims description 26
- 239000004417 polycarbonate Substances 0.000 claims description 24
- 229920000515 polycarbonate Polymers 0.000 claims description 24
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 23
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 23
- 239000012778 molding material Substances 0.000 claims description 19
- 238000005498 polishing Methods 0.000 claims description 18
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 17
- 229920002635 polyurethane Polymers 0.000 claims description 16
- 239000004814 polyurethane Substances 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 208000003443 Unconsciousness Diseases 0.000 claims description 11
- 239000003085 diluting agent Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 229920000058 polyacrylate Polymers 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
- 238000005422 blasting Methods 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 230000003213 activating effect Effects 0.000 claims description 9
- 238000007493 shaping process Methods 0.000 claims description 9
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 229920001187 thermosetting polymer Polymers 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 239000010935 stainless steel Substances 0.000 claims description 6
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical class NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 5
- 239000004642 Polyimide Substances 0.000 claims description 5
- 230000008859 change Effects 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 229920001721 polyimide Polymers 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 229910001220 stainless steel Inorganic materials 0.000 claims description 4
- 239000012790 adhesive layer Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 239000000976 ink Substances 0.000 description 92
- 239000002585 base Substances 0.000 description 75
- 239000000047 product Substances 0.000 description 40
- 238000004519 manufacturing process Methods 0.000 description 22
- 239000000243 solution Substances 0.000 description 16
- 238000001035 drying Methods 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 238000000465 moulding Methods 0.000 description 13
- 239000002002 slurry Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 239000007788 liquid Substances 0.000 description 12
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 11
- 229910052709 silver Inorganic materials 0.000 description 11
- 239000004332 silver Substances 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 239000003292 glue Substances 0.000 description 8
- 239000005341 toughened glass Substances 0.000 description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 230000004087 circulation Effects 0.000 description 7
- 238000005530 etching Methods 0.000 description 6
- 229910052738 indium Inorganic materials 0.000 description 6
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 6
- 235000019353 potassium silicate Nutrition 0.000 description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000011435 rock Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical compound [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 4
- 238000005065 mining Methods 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- -1 polyethylene terephthalate Polymers 0.000 description 3
- 238000012797 qualification Methods 0.000 description 3
- 238000005488 sandblasting Methods 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000208818 Helianthus Species 0.000 description 2
- 235000003222 Helianthus annuus Nutrition 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 230000003139 buffering effect Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000012776 electronic material Substances 0.000 description 2
- 210000004905 finger nail Anatomy 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000013003 hot bending Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 2
- 235000019799 monosodium phosphate Nutrition 0.000 description 2
- 229920006389 polyphenyl polymer Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000007788 roughening Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229910001256 stainless steel alloy Inorganic materials 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000002459 sustained effect Effects 0.000 description 2
- 208000011580 syndromic disease Diseases 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
- 240000006409 Acacia auriculiformis Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- ZRBROGSAUIUIJE-UHFFFAOYSA-N azanium;azane;chloride Chemical compound N.[NH4+].[Cl-] ZRBROGSAUIUIJE-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000005439 thermosphere Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/06—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions for securing layers together; for attaching the product to another member, e.g. to a support, or to another product, e.g. groove/tongue, interlocking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to technical field of electronic products, disclose a kind of shell and preparation method thereof and electronic product, the shell includes glass cover-plate, plastic frame body and metal base frame, and the glass cover-plate, plastic frame body and metal base frame are successively combined without step；Composite coating is formed on one side surface of the glass cover-plate, the composite coating successively includes thermal insulation layer, optional surface decoration layer, PET film, explosion-proof layer and protective layer by the glass cover plate surfaces outward direction.In shell of the invention glass cover-plate with it is seamless between metal base frame, combined without step, binding force between glass and metal base is high, broken screen is nearly low, waterproof ability is strong.And method of the invention can form surface texture appearance effect abundant convenient for shell.
Description
Technical field
The present invention relates to technical field of electronic products, and in particular, to a kind of shell and preparation method thereof and electronic product.
Background technique
In the prior art, shield before glass and the combination of metal base frame is substantially and directly fits group with glue
Dress, for example, Mobile phone screen is mostly to put a plastic washers (soft) between glass and metal base frame, by glass and gold
Belong to glue coating on substrate frame, is assembled.Therefore, the combination of glass and metal base frame determines metal base
With the binding force size of glass.There are following several big disadvantages for the shell being prepared by this method: (1) between glass and metal base
Binding force it is smaller, in conjunction with not close, have the gap, be non-watertight, is easy to fall off；(2) no platform is not all accomplished in substantially all of fitting
Rank combines, and causes glass prominent, not only increases the thickness of shell, while also increasing broken screen danger；(3) preparation section compared with
It is more, production cost is increased, while also improving fraction defective.
Summary of the invention
The purpose of the invention is to overcome drawbacks described above in the prior art, provide a kind of shell and preparation method thereof and
Electronic product, in the shell glass cover-plate with it is seamless between metal base frame, combined without step, between glass and metal base
Binding force it is high, broken screen is nearly low, waterproof ability is strong.
To achieve the goals above, in a first aspect, the present invention provides a kind of shell, the shell include glass cover-plate,
Plastic frame body and metal base frame, the glass cover-plate, plastic frame body and metal base frame are successively combined without step；Institute
State and be formed with composite coating on a side surface of glass cover-plate, the composite coating by the glass cover plate surfaces outward direction according to
Secondary includes thermal insulation layer, surface decoration layer, PET film, explosion-proof layer and protective layer.
Second aspect, the present invention provides a kind of preparation methods of shell, which comprises
(1) composite coating is prepared, the composite coating includes the thermal insulation layer set gradually, surface decoration layer, PET film, prevents
Quick-fried layer and protective layer；
(2) composite coating is fitted in by the composite coating in such a way that thermal insulation layer is towards the glass substrate
On one side surface of the glass substrate；
(3) it is coated with activator on the edge of glass cover-plate, dries；
(4) glass cover-plate that step (3) obtains is combined with metal base frame by way of injection molding.
The third aspect, the present invention provides the shells that method of the present invention is prepared.
Fourth aspect, the present invention provides a kind of electronic product, the electronic product includes shell of the present invention.
In shell of the invention, the binding force between glass cover-plate and metal base may be up to 700N or more (speed 10mm/
Min), and glass cover-plate with it is seamless by plastic frame body between metal base frame, combine (by the side of injection molding without step
Formula, especially normal temperature molding are intermediate metal substrate combining and glass cover-plate using plastic cement, substantially increase knot between the two
With joint efforts, and glass cover-plate, plastic frame body and metal base frame are in same plane, three be in sustained height and successively without
Step combines), binding force is good, broken screen is nearly low, waterproof ability is strong, it is frivolous, beautiful, can be used as practical cover board dress
With shell, and preparation method reduces patch screen process, reduces production cost, improves product yield.
In method of the invention, by being coated with activator on the edge of glass cover-plate, so that the activating component of activator
It crosslinks and reacts with injection molding plastic cement, plastic frame body and glass cover-plate, plastic frame body and metal base can be dramatically increased
Binding force between frame reduces broken screen danger.
It is high when advantageously reducing high temperature plastic-injection by increasing thermal insulation layer in composite coating in method of the invention
Temperature easily shrinks into ridges to the high wind-warm syndrome of rupture pressure disc (including explosion-proof layer and PET film) etc. when so as to improve rupture pressure disc injection molding
The problem of, so that glass surface can have texture appearance effect abundant.
Other features and advantages of the present invention will the following detailed description will be given in the detailed implementation section.
Specific embodiment
Detailed description of the preferred embodiments below.It should be understood that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
The endpoint of disclosed range and any value are not limited to the accurate range or value herein, these ranges or
Value should be understood as comprising the value close to these ranges or value.For numberical range, between the endpoint value of each range, respectively
It can be combined with each other between the endpoint value of a range and individual point value, and individually between point value and obtain one or more
New numberical range, these numberical ranges should be considered as specific open herein.
In order to solve mentioned in background technique " binding force between glass and metal base is smaller, in conjunction with not close, has
It is gap, non-watertight, easy to fall off " the problem of, the present inventor proposes glass cover-plate and metal by way of injection molding
The method that substrate frame combines.However, in actual operation, inventor has found new problem again, i.e., for shell,
It usually requires to form the surface coverings such as surface decoration layer, PET film, explosion-proof layer in glass cover plate surfaces shape in glass cover plate surfaces
At texture appearance effect abundant；However the process for being combined glass cover-plate with metal base frame by way of injection molding
In, the high wind-warm syndrome of injection temperature is likely to result in rupture pressure disc (including explosion-proof layer and PET film) etc. and shrinks into ridges, and then influences
The problem of shell appearance.In order to solve this problem, a kind of new shell and preparation method thereof is provided in the present invention.
In a first aspect, the shell includes glass cover-plate, plastic frame body and metal base the present invention provides a kind of shell
Frame, the glass cover-plate, plastic frame body and metal base frame are successively combined without step；The side table of the glass cover-plate
Composite coating is formed on face, the composite coating successively includes thermal insulation layer, surface by the glass cover plate surfaces outward direction
Decorative layer, PET film, explosion-proof layer and protective layer.
In shell of the invention, the surface decoration layer with a thickness of 10-50 μm, the rupture pressure disc (including PET film and anti-
Quick-fried layer) with a thickness of 5-70 μm, the protective layer with a thickness of 50-100 μm.
In shell of the invention, the surface decoration layer includes that the inside being formed in thermal insulation layer surface has hollowed out area
Decorative ink layer, the metallic mirror surface filled layer that is filled in the hollowed out area of the decorative ink layer and be formed in described
Black-out ink layer on decorative ink layer and metallic mirror surface filling layer surface；It is preferred that the decorative ink layer with a thickness of 5-
15 μm, metallic mirror surface filled layer with a thickness of 200nm-600nm and black-out ink layer with a thickness of being higher by the decorative ink
2-4 μm of layer.
In shell of the invention, raw material used by surface decoration layer, PET film, explosion-proof layer and protective layer is referring to ability
The conventional material in domain, preparation method is as shown in following method part.
In shell of the invention, thermal insulation layer can include polyethylene-acrylate, polyacrylate water glass for main component
The coating of one or more of glass and silica solution, is also possible to adiabatic gum band.The commercial goods that can wherein use include
But it is not limited to be commercially available from the polyethylene-acrylate type insulating moulding coating of Rui Peimu company, the U.S., or is commercially available from Japanese ippon company
The heat-insulating slurry of the polyacrylate waterglass of production, or it is commercially available from the bonding adiabatic gum band of Minnesota Mining and Manufacturing Company's production.It should
Description of the specific preparation method of thermal insulation layer referring to lower noodle producing method part.
In shell of the invention, it will be understood by those skilled in the art that between glass cover-plate and metal base frame
It is seamless by plastic frame body, combined without step, specifically, plastic frame body be cured, hard plastic frame body, glass cover-plate,
Plastic frame body and metal base frame are in same plane, and three is in sustained height and successively combines without step.
In shell of the invention, in order to significantly improve the binding force between glass cover-plate and metal base, and it is substantially reduced broken
Screen is dangerous, and under preferable case, the material of plastic frame body is polyamide (PA), glass fibre (GF), polycarbonate (PC) and polyphenyl
At least one of thioether (PPS), further preferably at least one of polyamide, polycarbonate and polyphenylene sulfide and glass
The mixture of fiber, the still more preferably mixture for polyamide and glass fibre.
Wherein it is preferred in plastic frame body, the total weight of at least one of polyamide, polycarbonate and polyphenylene sulfide
Ratio with the weight of glass fibre is (0.5-5): 1, further preferably (1-3): 1.Those skilled in the art should understand that
, when in plastic frame body containing one of polyamide, polycarbonate and polyphenylene sulfide, polyamide, polycarbonate and polyphenyl
The total weight of at least one of thioether is the weight of the one kind, contains polyamide, polycarbonate and polyphenylene sulfide in plastic frame body
When two or more in ether, the total weight of at least one of polyamide, polycarbonate and polyphenylene sulfide is that this is two or more
Weight and.In the present invention, polyamide, glass fibre, polycarbonate and polyphenylene sulfide are respectively common various polyamide, glass
Fiber, polycarbonate and polyphenylene sulfide can be commercially available.
In shell of the invention, for metal base, there is no particular limitation, can be various metals commonly used in the art
Substrate, under preferable case, metal base is stainless steel substrate or aluminum alloy base material.
In shell of the invention, in order to further increase the binding force between glass cover-plate and metal base, and it is substantially reduced
Broken screen is dangerous, and under preferable case, metal base is aluminum alloy base material, and the surface of aluminum alloy base material frame is formed with anode oxide film
Layer, and micropore is formed in the extexine of the anode oxidation membrane.Aforementioned metal substrate frame can be by including following processing
The method of step is prepared: stainless steel or aluminium alloy are successively carried out machine-shaping, polishing, chemical polishing, blasting treatment, can
Anodized, micropore processing and the pad pasting processing of choosing.Specific step is detailed in aftermentioned corresponding contents.
In shell of the invention, the size of glass cover-plate, plastic frame body and metal base frame is not limited particularly
It is fixed, it can accordingly be designed, be specifically designed and sized to as it is known to those skilled in the art that herein no longer according to actual needs
It repeats.
Second aspect, the present invention provides a kind of preparation methods of shell, which comprises
(1) composite coating is prepared, the composite coating includes the thermal insulation layer set gradually, surface decoration layer, PET film, prevents
Quick-fried layer and protective layer；
(2) composite coating is fitted in by the composite coating in such a way that thermal insulation layer is towards the glass substrate
On one side surface of the glass substrate；
(3) it is coated with activator on the edge of glass cover-plate, dries；
(4) glass cover-plate that step (3) obtains is combined with metal base frame by way of injection molding.
In method of the invention, the protective layer is release film protective layer, prepares the side of composite coating in step (1) at this time
Method includes: that rupture pressure disc is formed on the release film protective layer, and the rupture pressure disc includes PET film and formed on a pet film
Explosion-proof layer, wherein explosion-proof layer is arranged towards the release film protective layer；In the rupture pressure disc backwards to the release film protective layer
Surface decoration layer is formed on one side surface (i.e. on pet sheet face)；Thermal insulation layer is formed on the surface decoration layer.
In method of the invention, the release film protective layer can use commercially available material, such as E.I.Du Pont Company production it is light
Release release film, in another example the gum-free release film of Best Co., Ltd's production.
In method of the invention, the material that the rupture pressure disc can be used using row industry routine, is by will be explosion-proof
Glue is sprayed on PET film (polyethylene terephthalate) and is formed, and used rupture pressure disc can be commercially available in the present invention
OCA rupture pressure disc, can be specifically the OCA rupture pressure disc of SKC company production, in another example the OCA of Japanese prince company production is anti-
Quick-fried film, the rupture pressure disc can (preferable temperature be 30-50 DEG C, and pressure is 80 × 10 by roll-in3-180×103Pa method shape)
At on the release film protective layer.
In method of the invention, thermal insulation layer can include polyethylene-acrylate, polyacrylate water glass for main component
The coating of one or more of glass and silica solution is also possible to bond adiabatic gum band.The commercial goods that can wherein use
It include but is not limited to be commercially available from the polyethylene-acrylate type insulating moulding coating of Rui Peimu company, the U.S., or be commercially available from Japanese ippon
The heat-insulating slurry of the polyacrylate waterglass of company's production, or it is commercially available from the bonding adiabatic gum of Minnesota Mining and Manufacturing Company's production
Band.Wherein, when thermal insulation layer can include polyethylene-acrylate, polyacrylate waterglass and silica solution for main component
One or more of coating when, which can pass through silk-screen, spraying insulating moulding coating, the bonding modes shape such as adiabatic gum band
At；It, can be using the poly- second of U.S. Rui Peimu company production when forming thermal insulation layer using silk-screen, spraying insulating moulding coating mode
Alkene-acrylic ester type insulating moulding coating, or the production of Japanese ippon company polyacrylate waterglass heat-insulating slurry or U.S. Du
Company, nation silica solution type insulating moulding coating, preparation method are that heat-insulating slurry addition is formulated as the slurry that solid content is 80-90wt%
Then material silk-screen or is sprayed on the surface decoration layer；It, can when forming thermal insulation layer by the way of bonding adiabatic gum band
To use method specifically will to bond after bonding adiabatic gum band heating using the bonding adiabatic gum band of Minnesota Mining and Manufacturing Company's production
On the surface decoration layer.
In method of the invention, for aforementioned composite coating, material layer is more, can complete in different workshop sections different
Work, such as be initially formed the partial coating including rupture pressure disc and protective layer, then other workshop section complete subsequent thermal insulation layer and
The preparation of surface decoration layer can be in PET film under preferable case at this time in order to protect to PET film exposed in rupture pressure disc
Upper formation protective film (such as ultra-thin electrostatic protection film) removes the protective film when preparing and forming surface decoration layer again.
In method of the invention, in the rupture pressure disc on a side surface of the release film protective layer (i.e. pet sheet face
On) the step of forming surface decoration layer includes: to be formed internal to have vacancy section (i.e. on pet sheet face) in the explosion-proof film surface
The decorative ink layer in domain；The ink raw materials for being wherein used to form the decorative ink layer can be modification acrylate, such as South Korea
The MC-JQ00 type ink of LSNJ company production, in another example the 8031-4 type ink of Swiss Franc company production.The decorative ink layer can be with
It is formed in such a way that UV is transferred；
Hollowed out area forms metallic mirror surface filled layer in the decorative ink layer；The metallic mirror surface filled layer can pass through
The mode of spraying mirror-like silver ink or electroplating metal material is formed；The mirror-like silver ink that wherein can be used can be arbitrarily
Commercial product, as long as adhesive force and color use.Such as it is commercially available from Shenzhen and consolidates the GM-911 mirror-like silver of Xingda's ink, quotient
JMY-9200 mirror-like silver ink purchased from sunflower Electronic Materials Corp, Shenzhen or the SP-8580 for being commercially available from Seiko ink
Mirror-like silver ink；At this time preferably the metallic mirror surface filled layer with a thickness of 2.5-6 μm, more preferably 4-6 μm.And in order to by institute
The film thickness monitoring of metallic mirror surface is stated in 4-6 μ m.The electroplated metal layer that can wherein use can be indium or tin coating.Its
The technique that middle indium plating or tin can be plated using vacuum evaporation coating or ion sputtering, plating raw material can be selected from metallic tin, metal
Indium, TiN or TiO are preferably formed by indium or tin coating thickness between 200nm-600nm.
Black-out ink layer is formed by being screen printed on the decorative ink layer and the metallic mirror surface filled layer.Wherein
MRX-912 (black), the EG-911C of the black black out ink that the black black-out ink layer can use such as empire's Printing ink producing
(dense black), Seiko ink 1000-710 (black), 1000-710C (dense black) etc..
In method of the invention, step forms adhesive layer in the thermal insulation layer surface in (2), and the composite coating is glued
It closes on a side surface of the glass substrate, then the precuring 80-100min at 80-100 DEG C.Wherein adhesive layer can be adopted
Material includes but is not limited to polyurethane and/or acrylate.It specifically can be using the 1300HK type of Seiko company production
Binder or the IBM002 type binder of company, empire production.
In the case of process of the present invention it is preferred, this method further include: in step (3), before being coated with activator, until
It is few that ink is coated on the edge of glass cover-plate, solidify.Wherein it is possible to be determined according to the applicable cases of shell in glass cover-plate
Which position on be coated with ink, for example, if shell be used as before screen cover board shell when, only on the edge of glass cover-plate
It is coated with ink, mainly plays a part of to cover ITO circuit；If shell shields cover board shell after being used as, in glass cover-plate
Surface is coated with ink on (edge including inner surface), shields cover board color of shell after mainly playing display.
In method of the invention, in step (3), in order to improve the binding force between glass cover-plate and metal base, and reduce
Broken screen is dangerous, and under preferable case, glass cover-plate is that edge has carried out the glass cover-plate of roughening treatment, to increase its rough surface
Degree.Roughening treatment is well known to those skilled in the art, and details are not described herein.
In method of the invention, in step (3), for ink, there is no particular limitation, can be commonly used in the art each
Kind of ink, under preferable case, ink is UV ink or thermosetting ink.
Wherein, in step (3), for the mode of coating, there is no particular limitation, can be any mode that can be coated with,
In order to facilitate production, under preferable case, the mode for being coated with ink is silk-screen, the ink of silk-screen with a thickness of 5-15 μm.Specific silk
The method of print is well known to those skilled in the art, and details are not described herein.
In method of the invention, in step (3), in order to significantly improve the binding force between glass cover-plate and metal base, and
It is dangerous to be substantially reduced broken screen, under preferable case, activator includes activating component, diluent and curing agent, with the activator
On the basis of weight, the content of the activating component is 80-94 weight %, further preferably 85-91 weight %；The diluent
Content be 5-19 weight %, further preferably 6-10 weight %；The content of the curing agent is 1-10 weight %, further
Preferably 3-5 weight %.
Preferably, the activating component is at least one in polyurethane, epoxy resin, polyimides and polyacrylate
Kind.
Preferably, the diluent is at least one of acetone, ethyl acetate and ethyl acetate.
Preferably, the curing agent is at least one of ethylenediamine, ethylene glycol, glycerine and diethylenetriamines.
In order to further increase the binding force between glass cover-plate and metal base, and broken screen danger is further decreased, preferably
Ground, in step (3), the activator of coating with a thickness of 5-15 μm.Wherein, the mode of coating can be silk-screen.The method of silk-screen
It may include: using 300-380 mesh halftone, toward two layers of duplicating, specific operating method is well known to those skilled in the art,
Details are not described herein.
In method of the invention, in step (3), the cured condition carried out after coating ink is not limited particularly
It is fixed, it can be selected according to the type of ink, be various conditions commonly used in the art, wherein when ink is UV ink, Gu
The mode of change is exposure, it is preferable that conditions of exposure includes: that power is 500-1200kW, time 1-5min；Ink is thermosetting oil
Mo Shi, cured mode are drying, it is preferable that the condition of drying includes: that temperature is 80-90 DEG C, time 50-100min.
In method of the invention, in step (3), the condition of the drying for carrying out after coating activator is not limited particularly
It is fixed, it can be various conditions commonly used in the art, under preferable case, the condition of drying includes: that temperature is 75-90 DEG C, and the time is
40-120min.Wherein, in order to reach optimum efficiency, after drying, should be molded as early as possible, if Storage period is longer, it is desirable that injection molding temperature
It spends higher.
In method of the invention, in step (4), for metal base, there is no particular limitation, can be commonly used in the art
Various metal bases, under preferable case, metal base is stainless steel substrate or aluminum alloy base material.
Wherein, the metal base frame of the prior art is generally by including that the method for following processing step is prepared: will
Stainless steel or aluminium alloy successively carry out machine-shaping, polishing, chemical polishing, blasting treatment and pad pasting processing, in order to further mention
Binding force between high glass cover-plate and metal base, and further decrease broken screen danger, it is preferable that metal base frame is aluminium conjunction
Auri edge frame, the aluminum alloy base material frame by include following processing step method be prepared: by aluminum alloy base material according to
Secondary progress machine-shaping, polishing, chemical polishing, blasting treatment, anodized, micropore processing and pad pasting processing are (in metal
Pad pasting is that anode oxide film is scratched in order to prevent on frame).Wherein, it handles, makes before increasing micropore after anodized
The extexine for obtaining anode oxidation membrane forms micron-sized big etch pit, by this corrosion pore-creating again, in subsequent molding
In the process, plastic material can be easier to be directly entered in substrate surface hole in injection moulding process, thus after forming plastic frame body
Good combination is formed with substrate, the binding force between glass cover-plate and metal base can be further increased.
Preferably, the mode of micropore processing are as follows: the substrate for obtaining anodized is dipped into etching liquid, in anode
Oxidation film layer extexine forms the etch pit that aperture is 200nm-2000nm.Wherein, etching liquid can be by anode oxide film film
The solution of layer corrosion, for example, general adjust concentration with the solution that can dissolve aluminium oxide, it can be acid/base etching liquid, such as
The solution that can be 10-13 selected from pH.It can be that single alkaline solution that pH is 10-13 or composite buffering are molten under preferable case
Liquid, the single alkaline solution that pH is 10-13 can be Na2CO3、NaHCO3、NaOH、K2CO3、KHCO3, KOH etc. aqueous solution, into
One step is preferably Na2CO3And/or NaHCO3Aqueous solution can be such that etch pit is uniformly distributed in substrate surface, and uniform pore diameter,
It can make the binding performance of glass cover-plate and substrate more preferably.The solid content of above-mentioned etching liquid can be 0.1-15 weight %.It is compound
Buffer solution can be the mixed solution of soluble phosphoric acid hydrogen salt and water soluble alkali, such as the water of sodium dihydrogen phosphate and sodium hydroxide
The solid content of the aqueous solution of solution, sodium dihydrogen phosphate and sodium hydroxide can be 0.1-15 weight %, or K3PO4With
K2HPO4Aqueous solution, composite buffering solution can also be ammonia spirit, hydrazine aqueous solution, hydrazine derivate aqueous solution, water-soluble amine system
Compound water solution, NH3-NH4Cl aqueous solution etc..It includes by base that the substrate that anodized is obtained, which is dipped into etching liquid,
In the repeated multiple times immersion etching liquid of material, the time impregnated every time can be 1-60min, be washed with deionized water after dipping every time,
The number of immersion can be 2 to 10 times.Cleaning, which can be to be put into rinsing bowl, cleans 1 to 5min, or is put into rinsing bowl and puts
Set 1 to 5min.
Wherein, for the method for machine-shaping, polishing, chemical polishing, blasting treatment, anodized and pad pasting processing
It is not particularly limited, can be various methods commonly used in the art, this is well known to the skilled person, for example, sandblasting
The condition of processing may include: that sandblasting pressure is 0.23-0.25MPa, 2-4 times reciprocal, walking speed 12-22Hz, wherein can make
With 205 ceramic sands, wobble frequency can be 33Hz (board fixed frequency).The condition of anodized may include: electrolysis
Sulfuric acid concentration is 10-30 weight %, aluminium ion concentration 10-30g/L in liquid；Temperature is 15-25 DEG C, current density 0.6-
3A/dm2, voltage 10-20V, oxidization time 30min-50min.
In method of the invention, in order to further increase the binding force between glass cover-plate and metal base, and further drop
Low broken screen is dangerous, under preferable case, this method further include: before injection molding, be coated with and live on the inward flange of metal base frame
Agent, drying.
Wherein, in order to significantly improve the binding force between glass cover-plate and metal base, and it is substantially reduced broken screen danger, preferably
In the case of, the activator being coated on the inward flange of metal base frame includes activating component, diluent and curing agent, with described
On the basis of the weight of activator, the content of the activating component is 80-94 weight %, further preferably 85-91 weight %；Institute
The content for stating diluent is 5-19 weight %, further preferably 6-10 weight %；The content of the curing agent is 1-10 weight
Measure %, further preferably 3-5 weight %.
Preferably, the activating component is at least one in polyurethane, epoxy resin, polyimides and polyacrylate
Kind.
Preferably, the diluent is at least one of acetone, ethyl acetate and ethyl acetate.
Preferably, the curing agent is at least one of ethylenediamine, ethylene glycol, glycerine and diethylenetriamines.
In order to further increase the binding force between glass cover-plate and metal base, and broken screen danger is further decreased, preferably
Ground, the activator being coated on the edge of metal base frame with a thickness of 5-15 μm.
Wherein, not special for being coated with the condition of the drying carried out after activator on the edge of metal base frame
It limits, can be various conditions commonly used in the art, under preferable case, the condition of drying includes: that temperature is 75-90 DEG C, the time
For 40-120min.
In the case of process of the present invention it is preferred, in step (4), the mode of injection molding is normal temperature molding, further preferably
Ground, the condition of injection molding include: that injection molding width is 0.5-1mm, and mold temperature is 15-35 DEG C, and injection molding material temperature is 200-300 DEG C.
In method of the invention, in order to significantly improve the binding force between glass cover-plate and metal base, and it is substantially reduced broken
Screen is dangerous, and under preferable case, injection molding material is at least one of polyamide, glass fibre, polycarbonate and polyphenylene sulfide, into one
Step is preferably the mixture of at least one of polyamide, polycarbonate and polyphenylene sulfide with glass fibre, still more preferably
For the mixture of polyamide and glass fibre.
Wherein it is preferred to the total weight and glass fibre of at least one of polyamide, polycarbonate and polyphenylene sulfide
The ratio of weight is (0.5-5): 1, further preferably (1-3): 1.It will be understood by those skilled in the art that in injection molding material
When containing one of polyamide, polycarbonate and polyphenylene sulfide, at least one of polyamide, polycarbonate and polyphenylene sulfide
Total weight be one kind weight, it is poly- when in injection molding material containing two or more in polyamide, polycarbonate and polyphenylene sulfide
The total weight of at least one of amide, polycarbonate and polyphenylene sulfide be the two or more weight and.
In method of the invention, as previously mentioned, according to a preferred embodiment of the present invention, by the side of glass cover-plate
Edge is roughened, while metal base frame is carried out micropore processing, its surface is made to form countless nanometer micropores；Locating
Silk-screen activator on glass cover-plate and metal base frame after reason, then glass cover-plate is placed in gold by way of normal temperature molding
Belong in substrate frame, realizes that metal base, plastic cement, glass cover-plate are combined without step.
Wherein, under preferable case, glass cover-plate (especially shell is as preceding screen cover board shell) is OGS (One Glass
Solution touch panel of the same name, one block of glass play a dual role of protecting glass and touch sensor simultaneously) touch screen tempered glass,
Product thickness is reduced, the barrier that injection temperature influences touch screen is breached, makes glass cover-plate and metal base frame one
Chemical conversion type can reduce product sequence, reduce cost, improve product performance and decorative product appearance, make product it is more frivolous,
It is practical.
In method of the invention, this method further include: after the injection-moulding remove extra peak.
The third aspect, the present invention provides the shells that preceding method of the present invention is prepared.
Fourth aspect, the present invention provides a kind of electronic product, the electronic product includes shell of the present invention.
For electronic product, there is no particular limitation, as long as having glass cover-plate and metal base frame in the electronic product i.e.
It can, it is preferable that the electronic product is mobile phone, tablet computer, game machine, wrist-watch, notebook, desktop computer, TV or instrument
Display.
Preferably, the shell is the preceding screen cover board shell, rear screen cover board shell or water-tight watch case of electronic product.Further
Preferably, the shell can be applied to the preceding screen of 2.5D and 3D, to improve the decorative effect of product, when shell is applied to
It further include that aforementioned composite coating is placed in film before composite coating is bonded on glass cover-plate when the preceding screen of 2.5D and 3D
Hot bending is formed and the matched curved-surface structure of 2.5D or 3D covering plate structure in piece hot-bending machine.
Embodiment
The present invention will be described in detail by way of examples below.It is unless otherwise instructed, used in following embodiment
Reagent material can be commercially available, and method used is the conventional method of this field.
Polyurethane is purchased from E.I.Du Pont Company, trade mark PA66HTN501.
Epoxy resin is purchased from E.I.Du Pont Company, trade mark PKHH.
Polyimides is purchased from E.I.Du Pont Company, trade mark 200H.
Polyacrylate is purchased from Guangzhou Ke Tai Chemical Co., Ltd., trade mark 7732-18-5.
Polyamide is purchased from E.I.Du Pont Company, trade mark 73G20L.
Glass fibre is purchased from E.I.Du Pont Company, trade mark FR530NC010.
Polycarbonate is purchased from E.I.Du Pont Company, trade mark CG943.
Polyphenylene sulfide is purchased from E.I.Du Pont Company, trade mark HTN52G35HSL.
Release film protective layer is purchased from E.I.Du Pont Company, and the trade mark is transparent QL-03, with a thickness of 3 μm.
OCA rupture pressure disc (including PET film and explosion-proof layer) is purchased from SKC company, trade mark SH50, with a thickness of 50 μm.
UV transfer ink is purchased from LSNJ company, trade mark MC-JQ00.
Metallic mirror surface silver ink is purchased from Shenzhen sunflower Electronic Materials Corp, and the trade mark is JMY-9200 mirror-like silver ink.
Black-out ink layer is purchased from empire, and the trade mark is ink MRX-912 (black)；
Polyethylene-acrylate type heat-insulating slurry is purchased from U.S. Rui Peimu company, trade mark RPM705.
It bonds adiabatic gum band and is purchased from Minnesota Mining and Manufacturing Company, trade mark 3M5433.
Binder is purchased from Seiko company, trade mark 1300-HK.
The condition of blasting treatment includes: using 205 ceramic sands, and sandblasting pressure is 0.24MPa, and reciprocal 3 times, walking speed is
18Hz, wobble frequency 33Hz.
Embodiment 1
(1) release film protective layer is taken, (temperature is 30 DEG C, and pressure is 100 × 10 by roll-in3Pa mode) prevents OCA
Quick-fried film is compounded on release film protective layer in a manner of outwardly by pet layer；The ink slurry for preparing decorative ink layer, is transferred by UV
Mode in OCA rupture pressure disc on pet layer surface formed inside with hollowed out area decorative ink layer (with a thickness of 12 μm)；It takes
Aforementioned metal mirror-like silver ink, and by the ink under conditions of 2# glasss, 25 DEG C of rock field adjustment viscosity to 12s；Then described
Aforementioned mirror-like silver ink is sprayed in the hollowed out area of decorative ink layer, then dry solidification (drying 30min at 150 DEG C) formation is filled out
Fill the metallic mirror surface filled layer in the hollowed out area in the decorative ink layer (with a thickness of 4 μm)；Aforementioned black black out ink is taken,
And the hollow out ink decor surface is sprayed on after the ink adjusted viscosity to 12s under conditions of 2# glasss, 25 DEG C of rock field
Upper formation black black-out ink layer (with a thickness of 6 μm)；Take polyethylene-acrylate type heat-insulating slurry, addition diluent to slurry
Solid content be 85wt%, after then being handled by way of stirring, be screen printed onto the black-out ink layer formed it is heat-insulated
Layer (with a thickness of 6 μm), and then form composite coating.
(2) foregoing adhesives are coated on the surface of the thermal insulation layer by mode for dispensing glue, then by vacuum abutted
Equipment fits the inner surface of aforementioned composite coating and OGS touch screen tempered glass, then spare through 90 DEG C of pretreatment 90min；
(3) will treated that OGS touch screen tempered glass edge is roughened through aforementioned, with the halftone of 70T in glass
The edge screen printing UV inks of glass, the silk-screen of UV ink is with a thickness of 10 μm, then under the exposure machine of 900kW, exposes 3min；With
For the halftone of 380 mesh by activator silk-screen on UV ink, then glass is put into 90 DEG C with a thickness of 10 μm by the silk-screen of activator
Dry 90min in tunnel dryer；Wherein, activator is polyurethane system, including polyurethane, acetone and ethylenediamine, with described
On the basis of the weight of activator, the content of polyurethane, acetone and ethylenediamine is respectively 88 weight %, 8 weight % and 4 weight %.
(4) aluminium alloy is successively subjected to machine-shaping, polishing, chemical polishing, blasting treatment, anodized, micropore
Processing and pad pasting processing, obtain aluminum alloy base material frame, then will be coated on aluminum alloy base material by identical activator with step (3)
On the inward flange of frame, coating thickness is 10 μm, in 80 DEG C of drying 90min；Wherein, the condition of anodized includes: electricity
Solving sulfuric acid concentration in liquid is 20 weight %, and aluminium ion concentration 20g/L, temperature is 20 DEG C, current density 1.5A/dm2, voltage
For 15V, oxidization time 40min；The condition of micropore processing includes: that substrate is immersed in the sodium carbonate that pH is 12,10 weight %
It in solution, is drawn off after 5min, is put into the beaker equipped with water and impregnates 1min, so circulation 5 times, be soaked in water for the last time
Afterwards, it dries；
(5) injection molding material (polyamide and glass fibre according to weight ratio 2:1 mix) is put into baking oven and is preheated to 250
DEG C, the aluminum alloy base material frame that the glass cover-plate that step (3) obtains is obtained with step (4) is mutually tied by way of normal temperature molding
It closes, wherein injection molding width is 0.8mm, and mold temperature is 30 DEG C, and injection molding material temperature is 250 DEG C.
(6) extra peak is removed, obtains shell product A1.
Embodiment 2
(1) release film protective layer is taken, (temperature is 30 DEG C, and pressure is 100 × 10 by roll-in3Pa mode) prevents OCA
Quick-fried film is compounded on release film protective layer in a manner of outwardly by PET film；The ink slurry for preparing decorative ink layer, is transferred by UV
Method formed on PET film surface inside with hollowed out area decorative ink layer (with a thickness of 12 μm)；It then will be aforementioned multiple
Film is closed to be placed in vacuum coating equipment, so that hollowed out area is exposed outside in decorative ink layer, using indium metal as plating raw material,
It the evaporation plating 20min time under the conditions of vacuum degree 0.4Pa, is formed indium coating (with a thickness of 20nm)；Then aforementioned black shading oil is taken
Ink, and the hollow out ink decorative layer table is sprayed on after the ink is adjusted viscosity to 12s under conditions of 2# glasss, 25 DEG C of rock field
Form black black-out ink layer on face (with a thickness of 6 μm)；Take polyethylene-acrylate type heat-insulating slurry, addition diluent to slurry
The solid content of material be 85wt%, after then being handled by way of stirring, be screen printed onto the black-out ink layer formed every
Thermosphere (with a thickness of 6 μm), and then form composite coating.
(2) foregoing adhesives are coated on the surface of the thermal insulation layer by mode for dispensing glue, then by vacuum abutted
Equipment fits the inner surface of aforementioned composite coating and OGS touch screen tempered glass, then spare through 90 DEG C of pretreatment 90min；
(3) OGS touch screen tempered glass edge is roughened, it is hot in the edge silk-screen of glass with the halftone of 70T
Gu ink, then the silk-screen of thermosetting ink dries 90min with a thickness of 15 μm in 80 DEG C of baking oven；It will be lived with the halftone of 300 mesh
In on thermosetting ink, then glass is put into 80 DEG C of tunnel dryer agent silk-screen by the silk-screen of activator with a thickness of 15 μm
Dry 110min；Wherein, activator is polyurethane system, including polyurethane, ethyl acetate and ethylene glycol, with the activator
On the basis of weight, the content of polyurethane, ethyl acetate and ethylene glycol is respectively 85 weight %, 10 weight % and 5 weight %.
(4) aluminium alloy is successively subjected to machine-shaping, polishing, chemical polishing, blasting treatment, anodized, micropore
Processing and pad pasting processing, obtain aluminum alloy base material frame, then will be coated on aluminum alloy base material by identical activator with step (3)
On the inward flange of frame, coating thickness is 15 μm, in 75 DEG C of drying 110min；Wherein, the condition of anodized includes: electricity
Solving sulfuric acid concentration in liquid is 15 weight %, and aluminium ion concentration 28g/L, temperature is 15 DEG C, current density 1A/dm2, voltage is
10V, oxidization time 50min；The condition of micropore processing includes: that substrate is immersed in the sodium bicarbonate that pH is 10,15 weight %
It in solution, is drawn off after 5min, is put into the beaker equipped with water and impregnates 1min, so circulation 5 times, be soaked in water for the last time
Afterwards, it dries；
(5) injection molding material (polyamide and glass fibre according to weight ratio 1:1 mix) is put into baking oven and is preheated to 300
DEG C, the aluminum alloy base material frame that the glass cover-plate that step (3) obtains is obtained with step (4) is mutually tied by way of normal temperature molding
It closes, wherein injection molding width is 1mm, and mold temperature is 15 DEG C, and injection molding material temperature is 300 DEG C.
(6) extra peak is removed, obtains shell product A2.
Embodiment 3
(1) release film protective layer is taken, (temperature is 30 DEG C, and pressure is 100 × 10 by roll-in3Pa mode) prevents OCA
Quick-fried film is compounded on release film protective layer in a manner of outwardly by PET film；The ink slurry for preparing decorative ink layer, is transferred by UV
Mode formed on pet layer inside with hollowed out area decorative ink layer (with a thickness of 12 μm)；Take aforementioned metal mirror-like silver
Ink, and by the ink under conditions of 2# glasss, 25 DEG C of rock field adjustment viscosity to 12s；Then engraving in the decorative ink layer
Aforementioned mirror-like silver ink is sprayed in empty region, then dry solidification (drying 30min at 150 DEG C) formation is filled in the decoration oil
Metallic mirror surface filled layer in the hollowed out area of layer of ink (with a thickness of 4 μm)；Aforementioned black black out ink is taken, and by the ink in rock
Formation black shading on the hollow out ink decor surface is sprayed on after adjusting viscosity to 12s under conditions of field 2# glasss, 25 DEG C
Ink layer (with a thickness of 6 μm)；Aforementioned bonding adiabatic gum band is taken, after handling by way of heating, is bonded in the black out ink
It is formed thermal insulation layer (with a thickness of 5 μm) on layer, and then forms composite coating.
(2) foregoing adhesives are coated on the surface of the thermal insulation layer by mode for dispensing glue, then by vacuum abutted
Equipment fits the inner surface of aforementioned composite coating and OGS touch screen tempered glass, then spare through 90 DEG C of pretreatment 90min；
(3) OGS touch screen tempered glass edge is roughened, it is hot in the edge silk-screen of glass with the halftone of 70T
Gu ink, then the silk-screen of thermosetting ink dries 60min with a thickness of 5 μm in 90 DEG C of baking oven；It will be lived with the halftone of 300 mesh
In on thermosetting ink, then glass is put into 80 DEG C of tunnel dryer and does with a thickness of 8 μm agent silk-screen by the silk-screen of activator
Dry 50min；Wherein, activator is polyurethane system, including polyurethane, ethyl acetate and diethylenetriamines, with the activation
On the basis of the weight of agent, the content of polyurethane, ethyl acetate and diethylenetriamines is respectively 91 weight %, 6 weight % and 3 weights
Measure %.
(4) aluminium alloy is successively subjected to machine-shaping, polishing, chemical polishing, blasting treatment, anodized, micropore
Processing and pad pasting processing, obtain aluminum alloy base material frame, then will be coated on aluminum alloy base material by identical activator with step (3)
On the inward flange of frame, coating thickness is 5 μm, in 90 DEG C of drying 60min；Wherein, the condition of anodized includes: electrolysis
Sulfuric acid concentration is 25 weight % in liquid, and aluminium ion concentration 15g/L, temperature is 25 DEG C, current density 2.5A/dm2, voltage is
20V, oxidization time 30min；The condition of micropore processing includes: that substrate is immersed in the sodium bicarbonate that pH is 10,15 weight %
It in solution, is drawn off after 5min, is put into the beaker equipped with water and impregnates 1min, so circulation 5 times, be soaked in water for the last time
Afterwards, it dries；
(5) injection molding material (polyamide and glass fibre according to weight ratio 3:1 mix) is put into baking oven and is preheated to 200
DEG C, the aluminum alloy base material frame that the glass cover-plate that step (3) obtains is obtained with step (4) is mutually tied by way of normal temperature molding
It closes, wherein injection molding width is 0.5mm, and mold temperature is 35 DEG C, and injection molding material temperature is 200 DEG C.
(6) extra peak is removed, obtains shell product A3.
Embodiment 4
Shell product A4 is prepared according to the method for embodiment 1, unlike, activator is polyurethane system, including poly- ammonia
Ester, acetone and ethylenediamine, on the basis of the weight of the activator, the content of polyurethane, acetone and ethylenediamine is respectively 80 weights
Measure %, 10 weight % and 10 weight %.
Embodiment 5
Shell product A5 is prepared according to the method for embodiment 1, unlike, poly- ammonia is replaced with epoxy resin in activator
Ester.
Embodiment 6
Shell product A6 is prepared according to the method for embodiment 1, unlike, poly- ammonia is replaced with polyimides in activator
Ester.
Embodiment 7
Shell product A7 is prepared according to the method for embodiment 1, unlike, poly- ammonia is replaced with polyacrylate in activator
Ester.
Embodiment 8
Shell product A8 is prepared according to the method for embodiment 1, unlike, in step (4), before injection molding, do not exist
Activator is coated on the inward flange of aluminum alloy base material frame.
Embodiment 9
Shell product A9 is prepared according to the method for embodiment 1, unlike, it prepares during aluminum alloy base material frame simultaneously
Without micropore processing.
Embodiment 10
Shell product A10 is prepared according to the method for embodiment 1, unlike, injection molding material is polycarbonate and glass fibre
It is mixed according to weight ratio 2:1.
Embodiment 11
Shell product A11 is prepared according to the method for embodiment 1, unlike, injection molding material is polyphenylene sulfide and glass fibre
It is mixed according to weight ratio 2:1.
Embodiment 12
Shell product A12 is prepared according to the method for embodiment 1, unlike, injection molding material is that polyamide and glass fibre are pressed
It is mixed according to weight ratio 0.5:1.
Embodiment 13
Shell product A13 is prepared according to the method for embodiment 1, unlike, injection molding material is polyphenylene sulfide.
Embodiment 14
Shell product A14 is prepared according to the method for embodiment 1, unlike, injection molding material is polyamide.
Embodiment 15
Shell product A15 is prepared according to the method for embodiment 1, unlike, injection molding material is polycarbonate.
Embodiment 16
Shell product A16 is prepared according to the method for embodiment 1, unlike, injection molding material is glass fibre.
Comparative example 1
According to the method for embodiment 1, unlike, the method comprising the steps of (1)-(3), wherein
Step (1) are as follows: be roughened OGS touch screen tempered glass edge, with the halftone of 70T at the edge of glass
Screen printing UV inks, the silk-screen of UV ink is with a thickness of 10 μm, then under the exposure machine of 900kW, exposes 3min；
Step (2) are as follows: aluminium alloy is successively carried out machine-shaping, polishing, chemical polishing, blasting treatment, at anodic oxidation
Reason and pad pasting processing, obtain aluminum alloy base material frame；
Step (3) are as follows: put between the aluminum alloy base material sheet frame that step (1) obtained glass cover-plate and step (2) obtain
One plastic washers, the glue coating on glass cover-plate and aluminum alloy base material sheet frame, are placed in aluminum alloy base material plate for glass cover-plate
In frame, it is then placed in 90 DEG C of drying boxes and dries 30min.Obtain shell D1.
Comparative example 2
According to the method for embodiment 2, the difference is that, it does not include thermal insulation layer in composite coating.Obtain shell D2.
Test example
Following properties test is carried out to shell A1-A16 and D1-D2 respectively.
1, flatness is tested: with three coordinate measuring machine (being purchased from Hai Kesikang, model Global classic050705)
Measure the flatness of the glass cover plate surfaces of each shell.It the results are shown in Table 1.
2, mirror surface thrust is tested: (being purchased from INSTRON, model 3369, fltting speed is with universal material mechanics machine
The binding force between the glass cover-plate and metal base frame of each shell 10mm/min) is tested, metal base frame is fixed, is pushed
Glass cover-plate is until glass breaking or glass fall off.30 parallel repetitions are done, are averaged.It the results are shown in Table 1.
3, each shell is assembled into complete machine, carries out drop test: non-loaded drop test, height 1m.After fall-down test,
Record product does not occur the maximum times of deformation, impression and damage.It the results are shown in Table 1.
4, temperature shock is tested: each shell is respectively put into temperature shock test machine (purchased from KSON Qing Sheng company, model
KSKC-415TBS in), -40 DEG C of placements 2h, 85 DEG C of placement 2h, this is 1 circulation, does 5 circulations altogether, then 25 DEG C of placement 4h,
Test front/rear corrosion-free, spot, fade, change colour, crackle, blistering, distortion etc. is bad and cannot have finger nail to scratch phenomenon,
It is as qualified.It the results are shown in Table 1.
5, moisture and hot ageing is tested: each shell being put in 50 DEG C, 72h in the climatic chamber of humidity 95%.Test front/rear nothing
Burn into spot, fade, change colour, crackle, blistering, distortion etc. is bad and cannot have finger nail to scratch phenomenon, as qualified.Knot
Fruit is shown in Table 1.
6, salt spray test: each shell is placed into salt spray chamber, under the conditions of temperature is 35 DEG C, humidity is 90%, uses pH
The NaCl solution that value is 6.8,5 weight % is continuously 2 hours spraying to product surface, and each product is then placed in 50 DEG C, humidity
22 hours in 95% climatic chamber, this is a circulation, is 3 circulation 72h altogether.Then it is carried out using 38 DEG C of warm water soft
Flushing, and with non-dust cloth wiped clean, room temperature checks sample after 2 hours, film layer appearance is without exception, appearance becomes without obvious
Change and (such as corrodes, changes colour and blister), it is as qualified.It the results are shown in Table 1.
7, chemical resistance is tested: respectively uniformly applying edible oil, sunblock lotion, lipstick, foundation emulsion, mosquito repellent liquid, hand lotion etc.
It smears after on each shell, being put in the climatic chamber that temperature is 70 DEG C, humidity is 90% for 24 hours, in 25 DEG C of placement 4h, uses alcohol
Wipe product is as qualified without obvious remaining trace.It the results are shown in Table 1.
8, waterproof performance is tested: carrying out IPX7 submerging test in short-term, assembled complete machine is immersed in the water 30min, workpiece
Top water be deep to few 150mm, the hydraulic pressure of 1m is at least born at nethermost position.After taking out the water surface, surface drying workpiece is placed
After 30min, it can work normally as qualification.It the results are shown in Table 1.
9, composite coating binding force is tested: small in 10*10 (100) 1mm*1mm of test sample surface stroke with cross-cut tester
Grid, each depth of score answer the bottom of depth and coating, are cleaned down the fragment of test zone with hairbrush, with 3M600 glue
Paper firmly clings tested small grid, and firmly wipes adhesive tape with erasing rubber, holds adhesive tape one end, fast in vertical direction
Speed shuts down adhesive tape, and same position carries out 2 identical experiments；The tilting of its floating coat is considered as unqualified, and coating is unchanged to be considered as qualification.
10, composite coating shrinks into ridges test: optical microscopy amplifies 50 times of observations, and wherein composite coating has not shunk Zou
Be considered as qualification, appearance shunk Zou be considered as it is unqualified.
Table 1
As can be seen from Table 1, method of the invention can greatly improve the glass cover-plate and metal of the shell being prepared
Binding force between substrate sheet frame greatly reduces glass and falls off and risk and drop rear broken screen danger, significantly improves product
Energy.And method of the invention is used, by the way that thermal insulation layer is arranged between glass substrate and surface covering, can be applied to surface
Layer is protected, avoid the surface covering in the preparation process of shell from shrinking into ridges, and then abundant convenient for shell formation surface
Texture appearance effect.
In addition, can be seen that 3D glass metal prepared by 1-16 according to embodiments of the present invention by Visual Ispection method
The bound fraction size matching of complex is more complete, is not present between glass and metal and there is assembly step, gap problem, and adopts
There are have significantly assembly seam between glass and metal for the bound fraction of 3D glass metal complex prepared by documents 1
The problem of gap, step.
The preferred embodiment of the present invention has been described above in detail, and still, the present invention is not limited thereto.In skill of the invention
In art conception range, can with various simple variants of the technical solution of the present invention are made, including each technical characteristic with it is any its
Its suitable method is combined, and it should also be regarded as the disclosure of the present invention for these simple variants and combination, is belonged to
Protection scope of the present invention.
Claims (17)
1. a kind of shell, which is characterized in that the shell includes glass cover-plate, plastic frame body and metal base frame, the glass
Glass cover board, plastic frame body and metal base frame are successively combined without step；It is formed on one side surface of the glass cover-plate
Composite coating, the composite coating successively include thermal insulation layer, optional incrustation by the glass cover plate surfaces outward direction
Layer, PET film, explosion-proof layer and protective layer.
2. shell according to claim 1, wherein the surface decoration layer includes the inside being formed in thermal insulation layer surface
Decorative ink layer with hollowed out area, the metallic mirror surface filled layer being filled in the hollowed out area of the decorative ink layer, with
And it is formed in the black-out ink layer on the decorative ink layer and metallic mirror surface filling layer surface.
3. shell according to claim 1, wherein the overall thickness of the surface decoration layer is 10-50 μm, the PET film
Be 5-70 μm with the overall thickness of explosion-proof layer, the protective layer with a thickness of 50-100 μm.
4. shell according to claim 1, wherein the material of the plastic frame body is polyamide, glass fibre, poly- carbonic acid
At least one of at least one of ester and polyphenylene sulfide, preferably polyamide, polycarbonate and polyphenylene sulfide and glass fibers
The mixture of the mixture of dimension, further preferably polyamide and glass fibre, it is further preferred that gathering in plastic frame body
The ratio of the weight of the total weight and glass fibre of at least one of amide, polycarbonate and polyphenylene sulfide is 0.5-5:1, then
Further preferably 1-3:1.
5. shell according to claim 1, wherein the metal base is stainless steel substrate or aluminum alloy base material.
6. according to claim 1, shell described in 4 or 5, wherein the metal base frame is aluminum alloy base material frame, described
The surface of aluminum alloy base material frame is formed with anode oxidation membrane, and is formed with micropore in the extexine of the anode oxidation membrane.
7. a kind of preparation method of shell, which is characterized in that the described method comprises the following steps:
(1) composite coating is prepared, the composite coating includes the thermal insulation layer set gradually, surface decoration layer, PET film, explosion-proof layer,
And protective layer；
(2) by the composite coating in such a way that thermal insulation layer is towards the glass substrate, the composite coating is fitted in described
On one side surface of glass substrate；
(3) it is coated with activator on the edge of glass cover-plate, dries；
(4) glass cover-plate that step (3) obtains is combined with metal base frame by way of injection molding.
8. being prepared in step (1) compound according to the method described in claim 7, wherein, the protective layer is release film protective layer
The method of coating includes:
Form rupture pressure disc on the release film protective layer, the rupture pressure disc includes PET film and forms on a pet film explosion-proof
Layer, wherein explosion-proof layer is arranged towards the release film protective layer；
Surface decoration layer is formed on a side surface of the release film protective layer in the rupture pressure disc；
Thermal insulation layer is formed on the surface decoration layer.
9. according to the method described in claim 8, wherein, in the rupture pressure disc backwards to a side surface of the release film protective layer
The step of upper formation surface decoration layer includes:
Decoration oil inside the rupture pressure disc is formed on a side surface of the release film protective layer with hollowed out area
Layer of ink；
Hollowed out area forms metallic mirror surface filled layer in the decorative ink layer；
Black-out ink layer is formed on the decorative ink layer and the metallic mirror surface filled layer.
10. being incited somebody to action according to the method described in claim 7, wherein, forming adhesive layer in step (2) in the thermal insulation layer surface
The composite coating is bonded on a side surface of the glass substrate, then the precuring 80-100min at 80-100 DEG C.
11. according to the method described in claim 7, wherein, this method further include: before injection molding, in metal base frame
It is coated with activator on inward flange, dries.
12. according to the method described in claim 7, wherein, this method further include: in step (3), before being coated with activator,
It is at least coated with ink on the edge of glass cover-plate, solidifies；
Preferably, the ink is UV ink or thermosetting ink；
Preferably, be coated with ink mode be silk-screen, the ink of silk-screen with a thickness of 5-15 μm.
13. the method according to any one of claim 7 to 12, wherein in step (3), the activator includes living
Change component, diluent and curing agent, on the basis of the weight of the activator, the content of the activating component is 80-94 weight
Measure %, preferably 85-91 weight %；The content of the diluent is 5-19 weight %, preferably 6-10 weight %；The solidification
The content of agent is 1-10 weight %, preferably 3-5 weight %；
Preferably, the activating component is at least one of polyurethane, epoxy resin, polyimides and polyacrylate；
Preferably, the diluent is at least one of acetone, ethyl acetate and ethyl acetate；
Preferably, the curing agent is at least one of ethylenediamine, ethylene glycol, glycerine and diethylenetriamines；
Preferably, in step (3), the activator of coating with a thickness of 5-15 μm.
14. the method according to any one of claim 7 to 12, wherein in step (4), the metal base is aluminium
Alloy base material,
Preferably, the metal base frame is by including that the method for following processing step is prepared: stainless steel or aluminium are closed
Gold successively carries out machine-shaping, polishing, chemical polishing, blasting treatment, anodized, micropore processing and pad pasting processing.
15. the method according to any one of claim 7 to 12, wherein in step (4), the condition packet of the injection molding
Include: injection molding width is 0.5-1mm, and mold temperature is 15-35 DEG C, and injection molding material temperature is 200-300 DEG C；
Preferably, the injection molding material is at least one of polyamide, glass fibre, polycarbonate and polyphenylene sulfide, more preferably
For the mixture of at least one of polyamide, polycarbonate and polyphenylene sulfide and glass fibre, further preferably polyamide
With the mixture of glass fibre, it is further preferred that the gross weight of at least one of polyamide, polycarbonate and polyphenylene sulfide
The ratio of amount and the weight of glass fibre is 0.5-5:1, much further preferably from 1-3:1.
16. the shell that any one of claim 7 to 15 the method is prepared.
17. a kind of electronic product, which is characterized in that the electronic product includes described in any one of claim 1-6 and 16
Shell；
Preferably, the electronic product is mobile phone, tablet computer, game machine, wrist-watch, notebook, desktop computer, TV or instrument
Display；
Preferably, the shell is the preceding screen cover board shell, rear screen cover board shell or water-tight watch case of electronic product.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711064013.5A CN109747105A (en) | 2017-11-02 | 2017-11-02 | Shell and preparation method thereof and electronic product |
| PCT/CN2018/112471 WO2019085866A1 (en) | 2017-11-02 | 2018-10-29 | Outer casing, manufacturing method thereof, and electronic product |
| TW107138426A TW201918374A (en) | 2017-11-02 | 2018-10-30 | Housing, preparation method thereof and electronic product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201711064013.5A CN109747105A (en) | 2017-11-02 | 2017-11-02 | Shell and preparation method thereof and electronic product |
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| CN109747105A true CN109747105A (en) | 2019-05-14 |
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| CN201711064013.5A Pending CN109747105A (en) | 2017-11-02 | 2017-11-02 | Shell and preparation method thereof and electronic product |
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| CN (1) | CN109747105A (en) |
| TW (1) | TW201918374A (en) |
| WO (1) | WO2019085866A1 (en) |
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| CN110293380A (en) * | 2019-07-30 | 2019-10-01 | 深圳市百骏胜科技有限公司 | A kind of processing method of aluminium extruded type lampshade |
| CN110446380A (en) * | 2019-07-30 | 2019-11-12 | 惠州Tcl移动通信有限公司 | Production method, shell and the intelligent terminal of diaphragm |
| CN114292602A (en) * | 2021-12-27 | 2022-04-08 | 苏州普耀光电材料有限公司 | Explosion-proof membrane and method for reducing raindrops on membrane surface of explosion-proof membrane |
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| CN113618602B (en) * | 2021-08-18 | 2024-04-12 | 重庆达硕实业有限公司 | Notebook shell production device and technology |
| CN115716356A (en) * | 2021-08-25 | 2023-02-28 | 比亚迪股份有限公司 | Ceramic plastic composite, preparation method thereof and electronic equipment |
| CN115967759B (en) * | 2021-10-09 | 2024-07-09 | 荣耀终端有限公司 | Shell assembly, preparation method thereof and terminal |
| CN114012954A (en) * | 2021-11-02 | 2022-02-08 | 东莞正广精密科技有限公司 | Double-layer texture process |
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Also Published As
| Publication number | Publication date |
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| TW201918374A (en) | 2019-05-16 |
| WO2019085866A1 (en) | 2019-05-09 |
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Application publication date: 20190514 |
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