CN109728217A - With fire-retardant, explosion prevention function high-energy, high power density lithium battery system - Google Patents

With fire-retardant, explosion prevention function high-energy, high power density lithium battery system Download PDF

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Publication number
CN109728217A
CN109728217A CN201811605427.9A CN201811605427A CN109728217A CN 109728217 A CN109728217 A CN 109728217A CN 201811605427 A CN201811605427 A CN 201811605427A CN 109728217 A CN109728217 A CN 109728217A
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China
Prior art keywords
partition
energy
retardant
battery system
fire
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CN201811605427.9A
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Chinese (zh)
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CN109728217B (en
Inventor
李军
谭晓军
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Sun Yat Sen University
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Sun Yat Sen University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Secondary Cells (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

The invention discloses with fire-retardant, explosion prevention function high-energy, high power density lithium battery system, including several battery modules, each battery module is mounted in partition, battery module in partition is connect by disconnect switch with external electrical, is separated for sealing structure and is connected to nonconducting cooling medium by liquid valve.This system can prevent injures and deaths caused by thermal runaway or risk of explosion from occurring, to ensure work that entire battery system can be safer, more reliable.

Description

With fire-retardant, explosion prevention function high-energy, high power density lithium battery system
Technical field
It is especially a kind of close with fire-retardant, explosion prevention function high-energy, high power the present invention relates to a kind of lithium battery system Spend lithium battery system.
Background technique
As the concepts such as the enhancing of people's environmental consciousness, Green Travel are universal, new-energy automobile is gradually accepted.In order to Eliminate people to the anxiety of electric automobile during traveling mileage, meet the needs of people's electric vehicle rapid charging, have high-energy close The lithium ion battery of the features such as degree, charge rate, high power density developed by producer.But due to lithium ion battery Own material properties, high-energy density, high power density battery system have higher thermal runaway, risk of explosion.
Summary of the invention
Above-mentioned to overcome the problems, such as, the present invention provides a kind of with fire-retardant, explosion prevention function high-energy, high power Density lithium battery system prevents injures and deaths caused by thermal runaway or risk of explosion from occurring, to ensure that entire battery system can more pacify Entirely, more reliable work.
The present invention is realized in that above-mentioned purpose:
With fire-retardant, explosion prevention function high-energy, high power density lithium battery system, including several battery modules, each Battery module is all mounted in partition, and the battery module in partition is connect by disconnect switch with external electrical, is separated for sealing Structure is simultaneously connected to nonconducting cooling medium by liquid valve.
Wherein, the partition is communicated with vent valve.
Wherein, the partition is closely joined together one by one, cooling medium of the inside full of insulation.
Wherein, the partition is divided into shell, absorbing energy layer and flame-retardant layer, and middle layer is absorbing energy layer, using spraying or coating Energy-absorbing material addition is in partition inner surface;Innermost layer is flame-retardant layer, is added using spraying or coating fire proofing in absorbing energy layer Surface.
The beneficial effects of the present invention are: battery system mechanical structure is using sealing partition design, entire space is divided At many individually small-sized partitions;Storage has a battery module in each partition, and it is quick-fried can to effectively reduce battery in this way Fried or burning the condition of a disaster diffusion or sprawling, play the purpose of explosion-proof flame-retardant.In addition, being opened in each partition comprising an open circuit Close, this switch can disconnect the battery module in partition from entire battery system, and with battery module in adjacent partition It disconnects, prevents single battery from damaging and cause the damage of entire battery system;In addition, containing nonconducting cooling medium in partition Or solution, the heat that battery generates can be absorbed by nonconducting solution, guaranteed that battery is in normal operating temperature, prevented battery The generation of overheat or explosion, it is ensured that the work that entire battery system can be safer, more reliable.
Detailed description of the invention
Present invention will be further explained below with reference to the attached drawings and examples:
Fig. 1 is schematic diagram of the invention;
Fig. 2 is schematic structural view of the invention.
Specific embodiment
Referring to Fig.1, have fire-retardant, explosion prevention function, the lithium battery system suitable for high-energy density, high power density be On the basis of existing battery system, increase the following contents: the fire-retardant of battery system, Explosion-proof Design and battery system are fire-retardant, explosion-proof Control strategy.
Referring to Fig. 2, having fire-retardant, explosion prevention function high-energy, high power density lithium battery system includes several batteries Module, each battery module are mounted in partition, and the battery module in partition is connect by disconnect switch with external electrical, Partition is sealing structure and is connected to nonconducting cooling medium by liquid valve.Battery system mechanical structure is using sealing partition Design, entire space are divided into many individually small-sized partitions;Storage has a battery module in each partition, this Sample can effectively reduce the diffusion or sprawling of battery explosion or the condition of a disaster of burning, play the purpose of explosion-proof flame-retardant.In addition, each separates In all include a disconnect switch, this switch can disconnect the battery module in partition from entire battery system, and with phase Battery module also disconnects in neighbour's partition, prevents single battery from damaging and causes the damage of entire battery system;In addition, partition includes There are nonconducting cooling medium or solution, the heat that battery generates can be absorbed by nonconducting solution, guarantee that battery is in normal Operating temperature, prevent battery from overheating or the generation of explosion, it is ensured that the work that entire battery system can be safer, more reliable.
Wherein, the partition is communicated with vent valve.When gas pressure is greater than the set value in partition, exhaust valve is opened, High pressure gas in release partition prevents explosion to reduce partition internal gas pressure.
Wherein, the partition is closely joined together one by one, forms an organic close entirety;And it is nonconducting The cooling medium that insulate is internal full of partition, so that guaranteeing that battery in cover is full and uniform is quickly obtained cooling, is guaranteeing battery just Often work, effectively prevent the generation of thermal explosion.
In addition, it is described partition be divided into shell 1, absorbing energy layer 2 and flame-retardant layer 3, absorbing energy layer 2 is middle layer, using spraying or Energy-absorbing material addition is coated in partition inner surface;Innermost layer is flame-retardant layer 3, is being inhaled using spraying or coating fire proofing addition It can layer surface.Absorbing energy layer can absorb the impact energy generated when battery explosion, and flame-retardant layer can prevent to separate interior cells burst the condition of a disaster Sprawling, achieve the effect that fire-retardant.Flame retardant plastics, flame-retarded resin or the metal-back manufacture of hard can be used in the shell.
It is designed based on fire-retardant, anti-explosion battery service system, battery system is divided into air pressure in battery system using control strategy Burning occurs for high, battery system, explosion occurs for battery system and situations such as exploding and burning occurs for battery system, specifically controls plan Slightly it is described as follows:
Situation I: air pressure is high in battery system
When gas pressure is higher in partition in battery system, system control strategy is as follows:
(1) when the interior gas pressure of partition is higher than setting value I(high-voltage value) when, battery system opens exhaust valve in failure partition;Row Except interior high pressure gas is separated, gas pressure in separating is reduced;
(2) when gas pressure is reduced to setting value (recovery value is less than high-voltage value) in partition, the partition of battery system closing fault Middle exhaust valve.
Situation II: battery system burns
When burning the condition of a disaster occurs for battery system, system control strategy is as follows:
(1) battery system supplying power for outside route (physics disconnection) is closed;
(2) disconnect switch acts in failure partition, and cutting separates battery in interior battery module and entire battery system, surrounding partition The electrical connection of module;
(3) liquid valve in burning partition is opened, injects cooling medium, into partition for reducing fuel cell module temperature;
(4) in the case where the condition of a disaster is extinguished, ensures personal safety, according to relevant operation regulation handling failure battery system.
Situation III: battery system explodes
When explosion the condition of a disaster occurs for battery system, system control strategy is as follows:
(1) battery system supplying power for outside route (physics disconnection) is closed;
(2) disconnect switch acts in failure partition, and cutting separates battery in interior battery module and entire battery system, surrounding partition The electrical connection of module;
(3) vent valve in failure partition is opened, explosion gases is discharged, reduces gas pressure in failure partition;
(4) liquid valve in burning partition is opened, injects cooling medium, into partition for reducing battery module temperature in partition;
(5) in the case where the condition of a disaster is extinguished, ensures personal safety, according to relevant operation regulation handling failure system.
Situation IV: battery system occurs to explode and burn
When explosion, burning occur for battery system, system control strategy is as follows:
(1) battery system supplying power for outside route (physics disconnection) is closed;
(2) disconnect switch acts in failure partition, and cutting separates battery in interior battery module and entire battery system, surrounding partition The electrical connection of module;
(3) liquid valve in burning partition is opened, injects cooling medium, into partition for reducing battery module temperature in partition;
(4) after the temperature that failure partition and fail battery is effectively reduced in cooling medium, vent valve in failure partition, release are opened Explosion gases reduces gas pressure in failure partition;
(5) in the case where the condition of a disaster is extinguished, ensures personal safety, according to relevant operation regulation handling failure system.

Claims (4)

1. there is fire-retardant, explosion prevention function high-energy, high power density lithium battery system, including several battery modules, it is special Sign is: each battery module is mounted in partition, and the battery module in partition is connected by disconnect switch and external electrical It connects, separate for sealing structure and nonconducting cooling medium is connected to by liquid valve.
2. according to claim 1 have fire-retardant, explosion prevention function high-energy, high power density lithium battery system, spy Sign is: the partition is communicated with vent valve.
3. according to claim 1 have fire-retardant, explosion prevention function high-energy, high power density lithium battery system, spy Sign is: the partition is closely joined together one by one, cooling medium of the inside full of insulation.
4. according to claim 1,2 or 3 have fire-retardant, explosion prevention function high-energy, high power density lithium battery system, It is characterized by: to be divided into shell (1), absorbing energy layer (2) and flame-retardant layer (3), middle layer be absorbing energy layer for the partition, using spraying or Person coats energy-absorbing material addition in partition inner surface;Innermost layer is flame-retardant layer, is existed using spraying or coating fire proofing addition Energy-absorbing layer surface.
CN201811605427.9A 2018-12-26 2018-12-26 High-energy and high-power-density lithium battery system with flame-retardant and explosion-proof functions Active CN109728217B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112331817A (en) * 2020-08-14 2021-02-05 安徽德亚电池有限公司 Preparation method of high-conductivity electrode material

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CN201194338Y (en) * 2008-07-31 2009-02-11 张红彬 Explosion preventing lithium ion electric power supply system for mining electric locomotive
CN101369643A (en) * 2007-08-17 2009-02-18 深圳市比克电池有限公司 Memory method and apparatus for isolating lithium battery chain explosion
CN102195334A (en) * 2011-05-20 2011-09-21 中国广东核电集团有限公司 Method and system for improving reliability of emergency power supplies of nuclear power plant
CN102832424A (en) * 2012-08-27 2012-12-19 华南理工大学 Temperature control system for battery packs
CN205882029U (en) * 2016-08-11 2017-01-11 苏州安尚新能源科技有限公司 Flame -retardant explosion -proof type battery
CN205882034U (en) * 2016-08-15 2017-01-11 泉州潮策贸易有限公司 Explosion -proof fire -retardant device of lithium cell
CN107180934A (en) * 2017-04-07 2017-09-19 中国电力科学研究院 A kind of battery thermal runaway protector and preparation method thereof and mould
CN207425974U (en) * 2017-11-08 2018-05-29 河南爱彼爱和新材料有限公司 A kind of battery case thermal runaway blocks protective sheet
CN108123076A (en) * 2016-11-28 2018-06-05 德阳九鼎智远知识产权运营有限公司 A kind of anticollision battery

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101369643A (en) * 2007-08-17 2009-02-18 深圳市比克电池有限公司 Memory method and apparatus for isolating lithium battery chain explosion
CN201194338Y (en) * 2008-07-31 2009-02-11 张红彬 Explosion preventing lithium ion electric power supply system for mining electric locomotive
CN102195334A (en) * 2011-05-20 2011-09-21 中国广东核电集团有限公司 Method and system for improving reliability of emergency power supplies of nuclear power plant
CN102832424A (en) * 2012-08-27 2012-12-19 华南理工大学 Temperature control system for battery packs
CN205882029U (en) * 2016-08-11 2017-01-11 苏州安尚新能源科技有限公司 Flame -retardant explosion -proof type battery
CN205882034U (en) * 2016-08-15 2017-01-11 泉州潮策贸易有限公司 Explosion -proof fire -retardant device of lithium cell
CN108123076A (en) * 2016-11-28 2018-06-05 德阳九鼎智远知识产权运营有限公司 A kind of anticollision battery
CN107180934A (en) * 2017-04-07 2017-09-19 中国电力科学研究院 A kind of battery thermal runaway protector and preparation method thereof and mould
CN207425974U (en) * 2017-11-08 2018-05-29 河南爱彼爱和新材料有限公司 A kind of battery case thermal runaway blocks protective sheet

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112331817A (en) * 2020-08-14 2021-02-05 安徽德亚电池有限公司 Preparation method of high-conductivity electrode material

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