CN109723742A - A kind of non-metallic automotive brake block and preparation method thereof - Google Patents

A kind of non-metallic automotive brake block and preparation method thereof Download PDF

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Publication number
CN109723742A
CN109723742A CN201910110451.3A CN201910110451A CN109723742A CN 109723742 A CN109723742 A CN 109723742A CN 201910110451 A CN201910110451 A CN 201910110451A CN 109723742 A CN109723742 A CN 109723742A
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China
Prior art keywords
carbon fiber
waste product
fibre
particle
composite material
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CN201910110451.3A
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Chinese (zh)
Inventor
柴昌盛
高国亮
陈翔
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Lanzhou City University
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Lanzhou City University
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Priority to CN201910110451.3A priority Critical patent/CN109723742A/en
Publication of CN109723742A publication Critical patent/CN109723742A/en
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Abstract

The present invention provides a kind of non-metallic automotive brake block, weight percentages of components are as follows: epoxy base carbon fiber composite material waste product regenerates particle 15-20WT%;Phenolic aldehyde base carbon fiber composite material waste product regenerates particle 20-45WT%;Glass carbon dust 5-15WT%;Glass fibre 5-15WT%;Silica gray fibers 5-10WT%;Molybdenum disulphide powder 10-20WT%;Alumina fibre 5-15WT%, vermiculite power 5-10WT%.The present invention furthermore provides the preparation method of the non-metallic automotive brake block.A kind of non-metallic automotive brake block provided by the invention regenerates particle using carbon fibre composite waste product, solves waste disposal problems, reduce production cost;By the confounding effect of carbon fiber and mineral fibres, the advantage of prominent fiber respectively, performance complement, the advantages of highlighting various reinforcing materials;Inorganic non-metallic filler is selected, coefficient of friction is enhanced, reduces brake noise, has reached the requirement of braking comfort.

Description

A kind of non-metallic automotive brake block and preparation method thereof
Technical field
The invention belongs to brake system of car technical fields, and in particular to a kind of non-metallic automotive brake block and its preparation side Method.
Background technique
Brake block directly affects car steering performance as one of link important in entire braking system, braking ability And concerning life security, especially some heavy-duty freight cars and car are when mountain highway is run at high speed, since brake is frequent Braking causes brake block heat fading, causes brake efficiency to weaken or fail and particularly serious traffic accident occurs, give people's life wealth Production brings huge loss.Traditional one, two generation brake blocks are easy to happen hot ceremonial dress for royalty and move back, wear away fast, braking stationarity when forcing dynamic The outstanding problems such as difference and noise are big, can not adapt to the new demand of the modern means of communication.It studies and is suitble to higher speed, more may be used By stabilization, good heat resistanceheat resistant Decay Rate, more environmentally-friendly and great replicability high performance brake material, meet the friendship of China's modern times The demand of logical tool.
The brake block of fibre reinforced is the new hot spot of domestic and international new brake investigation of materials, has heat-resist, weight Gently, the advantages that coefficient of expansion is small, wear-resistant and good heat resistanceheat resistant Decay Rate.Fibre reinforced brake material is broadly divided into carbon fiber Dimension enhancing two classifications of carbon/carborundum based material and carbon fiber enhancement resin base composite material.Lot of documents is to domestic and international 9 Kind C/C composite airplane brake disc thermodynamics and friction and wear behavior are tested, the results showed that carbon matrix brake disc is every It has excellent performance.It was found that bond vitrified and deformation also do not occur for 2000 DEG C of carbon/carbon compound material disc surface temperature, absorb heat function Can, wearability and antifading is good and wear rate is low.Brake pad material is from carbon fiber skeleton structure, thickening technology, component Etc. C/SiC brake material studied find that its average friction coefficient reaches 0.23, friction stability reaches 0.43, linear to grind Loss rate is 9.3 μm/secondary face, and quality wear rate is 2.6mg/ face, and coefficient of friction is to braking number and surface temperature is unwise Sense, there is no heat fading trend;The rubbing surface of sample worn surface formation continuous-stable.Carbon fiber can reduce compound after being added The coefficient of friction of material, carbon fiber adding manner is different, also different to the influence of coefficient of friction;Detect the examination of different resins base The frictional behaviour of sample, the results showed that its frictional behaviour is main related with temperature, and wear rate and coefficient of friction vary with temperature and become Change, but correspond to different matrix, degree of susceptibility is different.
In terms of application achievements, patent CN104405804A and CN105156526A etc. provide various forms of carbon fibers and increase Strong brake pad material and preparation method thereof, the carbon fiber introduced in improves the friction and wear behavior of brake block, but brakes Appoint in piece component and so contain a large amount of metal materials, such as copper powder and metallic fiber material, these components are to improvement brake block Require no any effect using modern automobile industries such as low noise comforts, instead exactly the origin cause of formation of brake block brake noise because Element.Therefore, the new demand that high-performance and low-cost brake pad material is China's Modern Traffic transportation development is prepared.
A kind of epoxy base carbon fiber composite material waste product of summary of the invention recycles granulating technique (epoxy and phenolic aldehyde)
It is multiple to solve carbon fiber using the carbon fiber in carbon fibre composite waste product or leftover pieces as main raw material(s) by the present invention The problem of condensation material waste disposal hardly possible reduces production cost from raw material end;All select high molecular material and inorganic non-metallic Component, optimization preparation process realize low-consumption high-efficiency preparation, and strict control cost is prepared inexpensive, highly resistance character of heat-fading energy Nonmetallic brake pad material.
To achieve the above object, the present invention provides a kind of non-metallic automotive brake block, component content by weight percentage As follows: epoxy base carbon fiber composite material waste product regenerates particle 15-20WT%;The regeneration of phenolic aldehyde base carbon fiber composite material waste product Grain 30-45WT%;Glass carbon dust 5-15WT%;Glass fibre 5-15WT%;Silica gray fibers 5-10WT%;Molybdenum disulphide powder 10-20WT%;Alumina fibre 5-15WT%, vermiculite power 5-10WT%.
Specifically, the epoxy base carbon fiber composite material waste product regeneration particle and phenolic aldehyde base carbon fiber composite material are useless Product regenerate particle, are regenerated and are processed by carbon fibre composite waste product, diameter 1-3mm, and carbon fiber content is in 60-75%, tool There is cementability.The glass fibre length is 0.5-2mm;Alumina fibre and wollastonite fibre length are 1-2mm;Glass carbon dust For 200-400 mesh;Molybdenum disulphide powder and vermiculite power are 600-800 mesh.
A kind of preparation method of non-metallic automotive brake block of the invention, is realized using following steps:
Step 1 weighs each component in parts by weight, and epoxy base carbon fiber composite material waste product is first regenerated particle and phenol Aldehyde radical carbon fibre composite waste product regenerates particle and 5-8min is blended;Then 2- is stirred after glass carbon dust being added while stirring 5min;2-3min is stirred after glass fibre is added while stirring again;2-3min is stirred after molybdenum disulfide is added while stirring again;Again 2-3min is stirred after alumina fibre and silica gray fibers is added while stirring;2- is stirred after vermiculite power is added while stirring again 3min。
Blend components in step 1 are added mold, mold are put into hot press and is pressed and molded, then by step 2 Demoulding, rear processing polishing obtain non-metallic automotive brake block.
Above-mentioned mould pressing process are as follows:
1,60-80 DEG C of molding temperature, molding pressure 5-7MPA, dwell time 10-15min;
2, constant temperature, pressure relief 1-2min;
3,80-100 DEG C of molding temperature, molding pressure 10-12MPA, dwell time 30-40min;
4, constant temperature, pressure relief 2-4min;
5,110-130 DEG C of molding temperature, molding pressure 15-18MPA, dwell time 50-60min;
6, constant temperature, pressure relief 4-5min;
7,130-180 DEG C of molding temperature, molding pressure 26-29MPA, dwell time 120-180min;
8, pressure maintaining demoulds after being cooled to room temperature.
As described above, a kind of non-metallic automotive brake block and preparation method thereof of the invention, utilizes carbon fibre composite Waste product regenerates particle, solves waste disposal problems, reduces production cost;By the confounding effect of carbon fiber and mineral fibres, The advantage of prominent fiber respectively, performance complement, the advantages of highlighting various reinforcing materials;Select inorganic non-metallic filler, enhancing Coefficient of friction reduces brake noise, has reached the requirement of braking comfort.
Specific embodiment
The present invention is furture elucidated combined with specific embodiments below, these embodiments are only limitted to illustrate the present invention and mend and be used for It limits the scope of the invention.
Illustrate embodiments of the present invention below by way of specific specific example, those skilled in the art can be by this specification Other advantages and efficacy of the present invention can be easily understood for disclosed content.The present invention can also pass through in addition different specific realities The mode of applying is embodied or practiced, the various details in this specification can also based on different viewpoints and application, without departing from Various modifications or alterations are carried out under spirit of the invention.
Embodiment 1
A kind of non-metallic automotive brake block and preparation method thereof chooses epoxy base carbon fiber composite material waste product by its component Regenerate particle 15g;Phenolic aldehyde base carbon fiber composite material waste product regenerates particle 30g;Glass carbon dust 10g;Glass fibre 5g;Wollastonite Fiber 5g;Molybdenum disulphide powder 15g;Alumina fibre 10g, vermiculite power 10g.
Specifically, the epoxy base carbon fiber composite material waste product regeneration particle and phenolic aldehyde base carbon fiber composite material are useless Product regenerate particle, are regenerated and are processed by carbon fibre composite waste product, and carbon fiber content has cementability 65%.The glass Glass fibre length is 0.5-2mm;Alumina fibre and wollastonite fibre length are 1-2mm;Glass carbon dust is 200 mesh;Curing Molybdenum powder and vermiculite power are 600 mesh.
It is realized using following steps:
Step 1 weighs each component in parts by weight, and epoxy base carbon fiber composite material waste product is first regenerated particle and phenol Aldehyde radical carbon fibre composite waste product regenerates particle and 5min is blended;Then 2min is stirred after glass carbon dust being added while stirring;Again 2min is stirred after glass fibre is added while stirring;2min is stirred after molybdenum disulfide is added while stirring again;Add while stirring again 2min is stirred after entering alumina fibre and silica gray fibers;2min is stirred after vermiculite power is added while stirring again.
Blend components in step 1 are added mold, mold are put into hot press and is pressed and molded, then by step 2 Demoulding, rear processing polishing obtain non-metallic automotive brake block.
Above-mentioned mould pressing process are as follows:
1,60 DEG C of molding temperature, molding pressure 5MPA, dwell time 10min;
2, constant temperature, pressure relief 1min;
3,90 DEG C of molding temperature, molding pressure 10MPA, dwell time 30min;
4, constant temperature, pressure relief 2-4min;
5,120 DEG C of molding temperature, molding pressure 18MPA, dwell time 60min;
6, constant temperature, pressure relief 4min;
7,1130 DEG C of molding temperature, molding pressure 29MPA, dwell time 120min;
8, pressure maintaining demoulds after being cooled to room temperature.
Embodiment 2
A kind of non-metallic automotive brake block and preparation method thereof, it is as follows by its component content by weight percentage: epoxy group Carbon fibre composite waste product regenerates particle 20g;Phenolic aldehyde base carbon fiber composite material waste product regenerates particle 30g;Glass carbon dust 10g;Glass fibre 10g;Silica gray fibers 5g;Molybdenum disulphide powder 15g;Alumina fibre 5g, vermiculite power 5g.
Specifically, the epoxy base carbon fiber composite material waste product regeneration particle and phenolic aldehyde base carbon fiber composite material are useless Product regenerate particle, are regenerated and are processed by carbon fibre composite waste product, and carbon fiber content has cementability 75%.The glass Glass fibre length is 0.5-2mm;Alumina fibre and wollastonite fibre length are 1-2mm;Glass carbon dust is 400 mesh;Curing Molybdenum powder and vermiculite power are 800 mesh.
A kind of preparation method of non-metallic automotive brake block of the invention, is realized using following steps:
Step 1 weighs each component in parts by weight, and epoxy base carbon fiber composite material waste product is first regenerated particle and phenol Aldehyde radical carbon fibre composite waste product regenerates particle and 8min is blended;Then 5min is stirred after glass carbon dust being added while stirring;Again 3min is stirred after glass fibre is added while stirring;3min is stirred after molybdenum disulfide is added while stirring again;Add while stirring again 3min is stirred after entering alumina fibre and silica gray fibers;3min is stirred after vermiculite power is added while stirring again.
Blend components in step 1 are added mold, mold are put into hot press and is pressed and molded, then by step 2 Demoulding, rear processing polishing obtain non-metallic automotive brake block.
Above-mentioned mould pressing process are as follows:
1,80 DEG C of molding temperature, molding pressure 5MPA, dwell time 15min;
2, constant temperature, pressure relief 1min;
3,100 DEG C of molding temperature, molding pressure 12MPA, dwell time 40min;
4, constant temperature, pressure relief 3min;
5,130 DEG C of molding temperature, molding pressure 18MPA, dwell time 50min;
6, constant temperature, pressure relief 4-5min;
7,160 DEG C of molding temperature, molding pressure 29MPA, dwell time 180min;
8, pressure maintaining demoulds after being cooled to room temperature.
Embodiment 3
A kind of non-metallic automotive brake block and preparation method thereof, it is as follows by its component content by weight percentage: epoxy group Carbon fibre composite waste product regenerates particle 15g;Phenolic aldehyde base carbon fiber composite material waste product regenerates particle 35g;Glass carbon dust 5g; Glass fibre 5g;Silica gray fibers 10g;Molybdenum disulphide powder 15g;Alumina fibre 10g, vermiculite power 5g.
Specifically, the epoxy base carbon fiber composite material waste product regeneration particle and phenolic aldehyde base carbon fiber composite material are useless Product regenerate particle, are regenerated and are processed by carbon fibre composite waste product, and carbon fiber content has cementability in 60-75%.It is described Glass fibre length is 0.5-2mm;Alumina fibre and wollastonite fibre length are 1-2mm;Glass carbon dust is 200 mesh;Two sulphur Change molybdenum powder and vermiculite power is 800 mesh.
A kind of preparation method of non-metallic automotive brake block of the invention, is realized using following steps:
Step 1 weighs each component in parts by weight, and epoxy base carbon fiber composite material waste product is first regenerated particle and phenol Aldehyde radical carbon fibre composite waste product regenerates particle and 6min is blended;Then 3min is stirred after glass carbon dust being added while stirring;Again 3min is stirred after glass fibre is added while stirring;3min is stirred after molybdenum disulfide is added while stirring again;Add while stirring again 2min is stirred after entering alumina fibre and silica gray fibers;2min is stirred after vermiculite power is added while stirring again.
Blend components in step 1 are added mold, mold are put into hot press and is pressed and molded, then by step 2 Demoulding, rear processing polishing obtain non-metallic automotive brake block.
Above-mentioned mould pressing process are as follows:
1,60 DEG C of molding temperature, molding pressure 5MPA, dwell time 10min;
2, constant temperature, pressure relief 1min;
3,100 DEG C of molding temperature, molding pressure 10MPA, dwell time 30min;
4, constant temperature, pressure relief 3min;
5,130 DEG C of molding temperature, molding pressure 18MPA, dwell time 50min;
6, constant temperature, pressure relief 5min;
7,180 DEG C of molding temperature, molding pressure 29MPA, dwell time 180min;
8, pressure maintaining demoulds after being cooled to room temperature.
Embodiment 4
A kind of non-metallic automotive brake block and preparation method thereof, it is as follows by its component content by weight percentage: epoxy group Carbon fibre composite waste product regenerates particle 15g;Phenolic aldehyde base carbon fiber composite material waste product regenerates particle 40g;Glass carbon dust 5g; Glass fibre 10g;Silica gray fibers 10g;Molybdenum disulphide powder 5g;Alumina fibre 5g, vermiculite power 10g.
Specifically, the epoxy base carbon fiber composite material waste product regeneration particle and phenolic aldehyde base carbon fiber composite material are useless Product regenerate particle, are regenerated and are processed by carbon fibre composite waste product, and carbon fiber content has cementability in 60-75%.It is described Glass fibre length is 0.5-2mm;Alumina fibre and wollastonite fibre length are 1-2mm;Glass carbon dust is 400 mesh;Two sulphur Change molybdenum powder and vermiculite power is 600 mesh.
A kind of preparation method of non-metallic automotive brake block of the invention, is realized using following steps:
Step 1 weighs each component in parts by weight, and epoxy base carbon fiber composite material waste product is first regenerated particle and phenol Aldehyde radical carbon fibre composite waste product regenerates particle and 6min is blended;Then 3min is stirred after glass carbon dust being added while stirring;Again 3min is stirred after glass fibre is added while stirring;3min is stirred after molybdenum disulfide is added while stirring again;Add while stirring again 2min is stirred after entering alumina fibre and silica gray fibers;2min is stirred after vermiculite power is added while stirring again.
Blend components in step 1 are added mold, mold are put into hot press and is pressed and molded, then by step 2 Demoulding, rear processing polishing obtain non-metallic automotive brake block.
Above-mentioned mould pressing process are as follows:
1,70 DEG C of molding temperature, molding pressure 5MPA, dwell time 12min;
2, constant temperature, pressure relief 1min;
3,110 DEG C of molding temperature, molding pressure 10MPA, dwell time 30min;
4, constant temperature, pressure relief 3min;
5,120 DEG C of molding temperature, molding pressure 17MPA, dwell time 50min;
6, constant temperature, pressure relief 4min;
7,160 DEG C of molding temperature, molding pressure 26MPA, dwell time 160min;
8, pressure maintaining demoulds after being cooled to room temperature.
9, sample obtained by embodiment 1-4 is tested for the property, mainly tests shear strength;Friction and wear behavior, antithesis Part is No. 45 steel.

Claims (3)

1. a kind of non-metallic automotive brake block, component is by weight percentage are as follows: the regeneration of epoxy base carbon fiber composite material waste product Particle 15-20WT%;Phenolic aldehyde base carbon fiber composite material waste product regenerates particle 20-45WT%;Glass carbon dust 5-15WT%;Glass Fiber 5-15WT%;Silica gray fibers 5-10WT%;Molybdenum disulphide powder 10-20WT%;Alumina fibre 5-15WT%, vermiculite power 5-10WT%.
2. a kind of non-metallic automotive brake block according to claim 1, it is characterised in that the epoxy base carbon fibre is compound Material waste product regenerates particle and phenolic aldehyde base carbon fiber composite material waste product regenerates particle, and for carbon fiber content in 60-75%, diameter is small In 1-3mm, there is cementability;The glass fibre length is 0.5-2mm;Alumina fibre and wollastonite fibre length are 1- 2mm;Glass carbon dust is 200-400 mesh;Molybdenum disulphide powder and vermiculite power are 600-800 mesh.
3. a kind of preparation method of non-metallic automotive brake block according to claim 1-2, is realized using following steps:
1) epoxy base carbon fiber composite material waste product is first regenerated into particle and phenolic aldehyde base carbon fiber composite material waste product regenerates particle 5-8min is blended;Then 2-5min is stirred after glass carbon dust being added while stirring;It is stirred after glass fibre is added while stirring again 2-3min;2-3min is stirred after molybdenum disulfide is added while stirring again;Alumina fibre is added while stirring again and wollastonite is fine 2-3min is stirred after dimension;2-3min is stirred after vermiculite power is added while stirring again.
2) mould pressing process are as follows:
A. 60-80 DEG C of molding temperature, molding pressure 5-7MPA, dwell time 10-15min;
B. constant temperature, pressure relief 1-2min;
C. 80-100 DEG C of molding temperature, molding pressure 10-12MPA, dwell time 30-40min;
D. constant temperature, pressure relief 2-4min;
E. 110-130 DEG C of molding temperature, molding pressure 15-18MPA, dwell time 50-60min;
F. constant temperature, pressure relief 4-5min;
G. 130-180 DEG C of molding temperature, molding pressure 26-29MPA, dwell time 120-180min;After pressure maintaining is cooled to room temperature Demoulding.
CN201910110451.3A 2019-02-11 2019-02-11 A kind of non-metallic automotive brake block and preparation method thereof Pending CN109723742A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112178091A (en) * 2020-09-30 2021-01-05 兰州城市学院 Carbon/carbon fiber friction material and preparation method and application thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1109830A (en) * 1994-01-24 1995-10-11 纽摩爱伯克斯公司 Hybrid brake assembly
EP0987461A1 (en) * 1997-05-09 2000-03-22 DaimlerChrysler AG Brake unit with a non-metallic ceramic brake disc and a hub made from a different material
CN1628015A (en) * 2002-05-20 2005-06-15 杜邦-东丽株式会社 Shreds for reinforcement, fiber-reinforced product using shreds, and method of mfg. shreds and product
JP2007186591A (en) * 2006-01-13 2007-07-26 Advics:Kk Friction material
CN101457798A (en) * 2007-12-12 2009-06-17 赫尔比格驱动技术有限公司 Non-metallic friction lining
CN205202333U (en) * 2015-11-04 2016-05-04 宜兴市中碳科技有限公司 Direct plastic combines epoxy base carbon fiber board
CN106402217A (en) * 2016-11-13 2017-02-15 徐州乐泰机电科技有限公司 Nanoscale compound wear-resisting brake pad
CN106907414A (en) * 2017-02-27 2017-06-30 李通 Automotive disc brake non-metallic friction materials and its preparation method and application

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1109830A (en) * 1994-01-24 1995-10-11 纽摩爱伯克斯公司 Hybrid brake assembly
EP0987461A1 (en) * 1997-05-09 2000-03-22 DaimlerChrysler AG Brake unit with a non-metallic ceramic brake disc and a hub made from a different material
CN1628015A (en) * 2002-05-20 2005-06-15 杜邦-东丽株式会社 Shreds for reinforcement, fiber-reinforced product using shreds, and method of mfg. shreds and product
JP2007186591A (en) * 2006-01-13 2007-07-26 Advics:Kk Friction material
CN101457798A (en) * 2007-12-12 2009-06-17 赫尔比格驱动技术有限公司 Non-metallic friction lining
CN205202333U (en) * 2015-11-04 2016-05-04 宜兴市中碳科技有限公司 Direct plastic combines epoxy base carbon fiber board
CN106402217A (en) * 2016-11-13 2017-02-15 徐州乐泰机电科技有限公司 Nanoscale compound wear-resisting brake pad
CN106907414A (en) * 2017-02-27 2017-06-30 李通 Automotive disc brake non-metallic friction materials and its preparation method and application

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112178091A (en) * 2020-09-30 2021-01-05 兰州城市学院 Carbon/carbon fiber friction material and preparation method and application thereof

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Application publication date: 20190507