CN1097015A - Flash coloured minute surface sheet decorative pigment and manufacturing process thereof - Google Patents
Flash coloured minute surface sheet decorative pigment and manufacturing process thereof Download PDFInfo
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- CN1097015A CN1097015A CN 93112472 CN93112472A CN1097015A CN 1097015 A CN1097015 A CN 1097015A CN 93112472 CN93112472 CN 93112472 CN 93112472 A CN93112472 A CN 93112472A CN 1097015 A CN1097015 A CN 1097015A
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- minute surface
- surface sheet
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Abstract
A kind of adopt vacuum aluminum-coated rete to coat the transparent color cold coating and make one deck on its surface have the strong transparent color resin molding of minute surface reflective, through solidifying it is fragmented into the minute surface platelets, derive from 0.5 millimeter-3.0 millimeters even lamellar pigment through screening, each platelet-shaped pigments body becomes one to be handled through Al metallizing Fool and to have strong reflective dyeing specular surface body, under the irradiation of light, can reflect flash coloured reflected light, can be used for the decoration field, to prepare flash coloured decoration spray material, decorative glass board, the usefulness of glass reinforced plastic decoration and advertisement art artwork decoration is a kind of novel product in the pigment field.
Description
The present invention relates to a kind of novel pigment and preparation method thereof, specifically, it is a kind of flash coloured minute surface sheet decorative pigment and manufacturing process thereof.
Have in the used pigment of the strong coating of reflective function, tradition adopts metallic pigment at present, promptly so-called: bronze, silver powder, all have the metal polish degree, when being mixed, this kind pigment is prepared into coating, paint with varnish, slightly have the gold and silver glistening intensity, also have new organic fluorescent pigment under the ultraviolet light irradiation, to have the gloss of fluorescence color in addition, but water-based that these existing pigment are made or oil paint or paint are at flash coloured aspect of performance, always feel also that gloss is bright-coloured inadequately colorful, when especially they being used as the decoration field, lack the gorgeous degree of multicoloured color.Disclose a kind of panchromatic paint with circular ultramicrorasters at Chinese patent publication number 87103922, equally also had shortcomings such as lacking garish color directly perceived and multicoloured gorgeous degree.
For this reason, the invention provides a kind of flash coloured minute surface sheet decorative pigment and manufacturing process thereof.
Above-mentioned purpose of the present invention realizes in the following manner:
A kind of preparation method of flash coloured minute surface sheet decorative pigment, its feature are included in and coat the transparent color cold coating on the vacuum aluminum-coated rete, should describedly film through curing, cracked, screening.
It is characterized in that described transparent color cold coating is mixed and made into by phenol resin solution, epoxy resin solution and dyestuff alcoholic solution.
It is characterized in that described phenol resin solution comprises the tertiary butyl phenol urea formaldehyde is dissolved in lacquer thinner or the ethyl acetate makes 1: the solution 1(weight ratio); It is to add 6-8 gram quadrol solidifying agent and described dyestuff alcoholic solution in Resins, epoxy 100 gram of E-44 to comprise that 30-60 is restrained pure dissolubility light-resistant dye to be dissolved in the methyl alcohol of 1000C.C or the ethanol and to make that described epoxy resin solution comprises the trade mark; Then, the dye solution that adding 50-200 restrains described phenol resin solution and 10-20C.C in described epoxy resin solution is coated on the vacuum aluminum-coated rete after mixing, and after solidifying under the room temperature, is fragmented into 0.5mm-3.0mm.
It is characterized in that described dyestuff is selected from one or more among 411 pure molten organic yellow CGG, 410 Spirit Fast Yellow GRs, 401 pure molten everbright fast red B, 402 pure molten sun-proof fluoresceins, the scarlet GG of pure molten sun-proof, the 406 green HL of pure molten sun-proof and/or the blue HL of 409 pure molten sun-prooves.
The flash coloured minute surface sheet decorative pigment that a kind of production method as described above is produced.
Advantage of the present invention is tangible:
Coat the colourful transparent cold coating and each unitary lamellar pigment body of flash coloured minute surface sheet decorative pigment of making is a tiny transparent color eyeglass by Al metallizing Fool, it is reflective to have the intensive minute surface, be equipped with the dyeing of various colourful transparent resins, can make the tens of kinds of colour mirrorlike surface bodies that color is different, through different color cooperation and mixed mutually, can obtain flash coloured pigment, a kind ofly utilize vacuum aluminum-coated membrane technique and make pigment thereby make to have increased in the pigment manufacturing field, broken the technology of in the past traditional production pigment with minute surface refractive body.Flash coloured pigment has reflective to be mixed by force with Clear paint liquid as inner wall decorative coating, and it is peculiar that its coating has quartzy jewel luster effect.Also can be used for preparing the glass fibre steel work, decorate and the washboard decoration as indoor terrace.Flash coloured pigment mat tackiness agent is sprayed at glass pane surface can become decorative glass board, substitutes the usefulness that partial color is made ad decoration equally in advertisement art decoration field, and purposes is very extensive, increases a new kind in the common pigments field.
The present invention is described in further detail below with reference to specific embodiment.
Embodiment:
Step 1:
Tertiary butyl phenol urea formaldehyde (trade mark E-44) and lacquer thinner or ethyl acetate are mixed with 1: the solution 1(weight ratio).With 100 gram E-44 Resins, epoxy and 6 to 8 gram quadrols (solidifying agent) through fully stir mixed after, add above-mentioned phenol resin solution 50-200 gram again, in the stirring evenly adding 20-30 restrain lacquer thinner or ethyl acetate (thinner) is made resin mixture liquor.
Step 2:
Be selected from 401 pure molten everbright fast red B, the green HL of the scarlet CG.406 molten sun-prooves of alcohol of the molten sun-proof of 402 pure molten sun-proof fluorescein GG.404 alcohol, the blue HL of 409 pure molten sun-prooves, 410 Spirit Fast Yellow GRs or 411 pure molten organic yellow CGG one or more (for example: the green that Huang+indigo plant can be combined into different tones; And for example yellow+as redly can be combined into the orange etc. of different tones) be mixed with the solution of following concentration with methyl alcohol or ethanol:
Table 1
| Title | Methyl alcohol 98% | Alcohol 95 % |
| 401 pure molten everbright fast red B | 45 gram/1000CC | 50 gram/1000CC |
| 402 pure molten sun-proof fluoresceins | 53 grams | 53 grams |
| The scarlet CG of 404 pure molten sun-prooves | 64 grams | 19 grams |
| The green HL of 406 pure molten sun-prooves | 55 grams | 30 grams |
| 410 Spirit Fast Yellow GRs | 100 grams | 120 grams |
| 411 pure molten organic yellow CGG | 15 grams | 11 grams |
Step 3: the 10-20C.C dye solution of preparation in the step 2 is added in the resin mixture liquor of preparation in the step 1, and thorough mixing is even, is mixed with the colouring resin mixed solution.
Step 4. is passed through spraying or manual the brushing on the electrochemical aluminum foil layer with the colouring resin mixed solution of preparation in the step 3, general consumption is a 25-50 gram/square metre scope, adopt normal temperature or heating cure resin, the electrochemical aluminum foil layer is after coating transparent colo(u)r coating, be solidified into doctor blade holder that the hardened tunic makes by steel disc roll over gently broken after, color resin film just comes off from washing the human relations substrate, again the fragment that will come off by separation sieve sieve obtain required size (for example: the 0.5-3.0mm) finished product of different size.
Above-mentioned most preferred embodiment can have multiple variation, and for example the Resins, epoxy in the step 1 can adopt the E-51 trade mark; Coating in the step 2 (for example: alkaline bright blue etc.) also can be selected basic dyestuff for use; Electrochemical aluminum foil in the step 4 can be the electrochemical aluminum foil of recycling that had partly printed, and can reach the purpose that reduces cost, fully utilizes thus.
By the present invention prepared " flash coloured minute surface sheet decorative pigment ", can develop following a series of product:
One. adopt the high-quality exterior wall to mix and can prepare quartzy flash coloured inner wall decorative coating with pigment of the present invention with phenylpropyl water-soluble coating, it is coated with rete and has quartzy colour jewel particulate and be embedded in top sensation on the metope in being sprayed at, style is very luxurious, and the increase people give in the decoration field the enjoyment of U.S. and increase fresh content.
But two. adopt the abrasion resistant polyurethane resin to mix to make glass fibre enhanced glass reinforced plastic sheet stock floor file level ground to have special decorative effect, also can be used as decorated wall surface and make washboard with this flash coloured minute surface sheet decorative pigment.
Three. mixed being sprayed on the sheet glass with resin adhesive of flash coloured minute surface sheet decorative pigment of the present invention can be done decorative glass plate.
Four. plot printed words or pattern with general tackiness agent at body surface, again thereon with the spray of the flash coloured minute surface sheet of the present invention decorative pigment, cling securely after the curing and form flash coloured font and pattern on the surface, can be used for that advertisement art make to be gone up and artwork is made and had the bright-coloured color of flash of light, very noticeable.
Above-mentioned example only is for illustrative purposes, and protection scope of the present invention will embody in claims.
Claims (8)
1, a kind of preparation method of flash coloured minute surface sheet decorative pigment, its feature are included in and coat the transparent color cold coating on the vacuum aluminum-coated rete, with described curing of coating, cracked, screening.
2, the method for claim 1 is characterized in that described transparent color cold coating is mixed and made into by phenol resin solution, epoxy resin solution and dyestuff alcoholic solution.
3, method as claimed in claim 1 or 2 is characterized in that described phenol resin solution comprises the tertiary butyl phenol urea formaldehyde is dissolved in lacquer thinner or the ethyl acetate to make 1: the solution 1(weight ratio); It is to add 6-8 gram quadrol solidifying agent and described dyestuff alcoholic solution in Resins, epoxy 100 gram of E-44 to comprise that 30-60 is restrained pure dissolubility light-resistant dye to be dissolved in the methyl alcohol of 1000C.C or the ethanol and to make that described epoxy resin solution comprises the trade mark; Then, the dye solution that adding 50-200 restrains described phenol resin solution and 10-20C.C in described epoxy resin solution is coated on the vacuum aluminum-coated rete after mixing, and after solidifying under the room temperature, is fragmented into 0.5mm-3.0mm.
4, method as claimed in claim 3 is characterized in that described dyestuff is selected from one or more among 411 pure molten organic yellow CGG, 410 Spirit Fast Yellow GRs, 401 pure molten everbright fast red B, 402 pure molten sun-proof fluorescent reds, the scarlet GG of pure molten sun-proof, the 406 green HL of pure molten sun-proof and/or the blue HL of 409 pure molten sun-prooves.
5, a kind of flash coloured minute surface sheet decorative pigment of production method production as claimed in claim 1.
6, a kind of flash coloured minute surface sheet decorative pigment of production method production as claimed in claim 2.
7, a kind of flash coloured minute surface sheet decorative pigment of production method production as claimed in claim 3.
8, a kind of flash coloured minute surface sheet decorative pigment of production method production as claimed in claim 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93112472 CN1097015A (en) | 1993-06-29 | 1993-06-29 | Flash coloured minute surface sheet decorative pigment and manufacturing process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93112472 CN1097015A (en) | 1993-06-29 | 1993-06-29 | Flash coloured minute surface sheet decorative pigment and manufacturing process thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1097015A true CN1097015A (en) | 1995-01-04 |
Family
ID=4990080
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93112472 Pending CN1097015A (en) | 1993-06-29 | 1993-06-29 | Flash coloured minute surface sheet decorative pigment and manufacturing process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1097015A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1310773C (en) * | 2005-01-11 | 2007-04-18 | 王建雄 | Golden foil material in use for various tablets, business cards, album, mural painting and deocration |
| CN101812249A (en) * | 2010-05-11 | 2010-08-25 | 长沙族兴金属颜料有限公司 | Resin-coated aluminum pigment and preparation method thereof |
| CN107935387A (en) * | 2017-11-15 | 2018-04-20 | 蒙娜丽莎集团股份有限公司 | Colorful sheet dry granular glaze, sheet dry granular glaze cloth ashlar brick and preparation method thereof |
-
1993
- 1993-06-29 CN CN 93112472 patent/CN1097015A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1310773C (en) * | 2005-01-11 | 2007-04-18 | 王建雄 | Golden foil material in use for various tablets, business cards, album, mural painting and deocration |
| CN101812249A (en) * | 2010-05-11 | 2010-08-25 | 长沙族兴金属颜料有限公司 | Resin-coated aluminum pigment and preparation method thereof |
| CN107935387A (en) * | 2017-11-15 | 2018-04-20 | 蒙娜丽莎集团股份有限公司 | Colorful sheet dry granular glaze, sheet dry granular glaze cloth ashlar brick and preparation method thereof |
| CN107935387B (en) * | 2017-11-15 | 2021-06-11 | 蒙娜丽莎集团股份有限公司 | Colorful flaky dry particle glaze, flaky dry particle glaze cloth stone-like brick and preparation method thereof |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |