CN109699677A - A kind of quick mildew removing agent and preparation method thereof - Google Patents
A kind of quick mildew removing agent and preparation method thereof Download PDFInfo
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- CN109699677A CN109699677A CN201811581088.5A CN201811581088A CN109699677A CN 109699677 A CN109699677 A CN 109699677A CN 201811581088 A CN201811581088 A CN 201811581088A CN 109699677 A CN109699677 A CN 109699677A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 38
- 239000002253 acid Substances 0.000 claims abstract description 35
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000460 chlorine Substances 0.000 claims abstract description 28
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 28
- 239000000843 powder Substances 0.000 claims abstract description 25
- 239000007844 bleaching agent Substances 0.000 claims abstract description 23
- 235000019441 ethanol Nutrition 0.000 claims abstract description 22
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical class OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims abstract description 18
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011149 active material Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims description 46
- 239000007788 liquid Substances 0.000 claims description 42
- 238000000605 extraction Methods 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 239000008367 deionised water Substances 0.000 claims description 28
- 229910021641 deionized water Inorganic materials 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 25
- 239000006228 supernatant Substances 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 17
- 238000005119 centrifugation Methods 0.000 claims description 14
- 239000013049 sediment Substances 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 8
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 8
- UETNIIAIRMUTSM-UHFFFAOYSA-N Jacareubin Natural products CC1(C)OC2=CC3Oc4c(O)c(O)ccc4C(=O)C3C(=C2C=C1)O UETNIIAIRMUTSM-UHFFFAOYSA-N 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- NCEXYHBECQHGNR-QZQOTICOSA-N sulfasalazine Chemical compound C1=C(O)C(C(=O)O)=CC(\N=N\C=2C=CC(=CC=2)S(=O)(=O)NC=2N=CC=CC=2)=C1 NCEXYHBECQHGNR-QZQOTICOSA-N 0.000 claims description 5
- 229960001940 sulfasalazine Drugs 0.000 claims description 5
- NCEXYHBECQHGNR-UHFFFAOYSA-N sulfasalazine Natural products C1=C(O)C(C(=O)O)=CC(N=NC=2C=CC(=CC=2)S(=O)(=O)NC=2N=CC=CC=2)=C1 NCEXYHBECQHGNR-UHFFFAOYSA-N 0.000 claims description 5
- 238000012360 testing method Methods 0.000 claims description 5
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- 239000001508 potassium citrate Substances 0.000 claims description 3
- 229960002635 potassium citrate Drugs 0.000 claims description 3
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 3
- 235000011082 potassium citrates Nutrition 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical group C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 claims description 2
- 239000004310 lactic acid Substances 0.000 claims description 2
- 235000014655 lactic acid Nutrition 0.000 claims description 2
- LWXVCCOAQYNXNX-UHFFFAOYSA-N lithium hypochlorite Chemical compound [Li+].Cl[O-] LWXVCCOAQYNXNX-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 2
- 238000002137 ultrasound extraction Methods 0.000 claims 2
- 241000675108 Citrus tangerina Species 0.000 claims 1
- 238000006356 dehydrogenation reaction Methods 0.000 claims 1
- IOCHDYUJEBGIKB-UHFFFAOYSA-M ethyl-[(3-methoxyphenyl)methyl]-dimethylazanium;4-methylbenzenesulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1.CC[N+](C)(C)CC1=CC=CC(OC)=C1 IOCHDYUJEBGIKB-UHFFFAOYSA-M 0.000 claims 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 9
- 230000000149 penetrating effect Effects 0.000 abstract description 8
- 239000003112 inhibitor Substances 0.000 abstract description 7
- 125000003118 aryl group Chemical group 0.000 abstract description 6
- 239000003513 alkali Substances 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 5
- 238000005260 corrosion Methods 0.000 abstract description 5
- 230000002401 inhibitory effect Effects 0.000 abstract description 5
- 230000002045 lasting effect Effects 0.000 abstract description 5
- 231100001231 less toxic Toxicity 0.000 abstract description 5
- 239000000645 desinfectant Substances 0.000 abstract description 4
- 230000002085 persistent effect Effects 0.000 abstract description 3
- 241000233866 Fungi Species 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- IEDVJHCEMCRBQM-UHFFFAOYSA-N trimethoprim Chemical compound COC1=C(OC)C(OC)=CC(CC=2C(=NC(N)=NC=2)N)=C1 IEDVJHCEMCRBQM-UHFFFAOYSA-N 0.000 description 7
- 239000003814 drug Substances 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 229960001082 trimethoprim Drugs 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- OVBPIULPVIDEAO-LBPRGKRZSA-N folic acid Chemical compound C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-LBPRGKRZSA-N 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 235000019795 sodium metasilicate Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 description 1
- OVBPIULPVIDEAO-UHFFFAOYSA-N N-Pteroyl-L-glutaminsaeure Natural products C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)NC(CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 239000005839 Tebuconazole Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 125000003963 dichloro group Chemical group Cl* 0.000 description 1
- VOPQXYCIRQXBGE-UHFFFAOYSA-M dimethyl-bis(sulfanyl)azanium chloride Chemical compound [Cl-].S[N+](C)(C)S VOPQXYCIRQXBGE-UHFFFAOYSA-M 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229960000304 folic acid Drugs 0.000 description 1
- 235000019152 folic acid Nutrition 0.000 description 1
- 239000011724 folic acid Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- -1 propyl lycine Chemical compound 0.000 description 1
- FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical compound [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 description 1
- 229960002026 pyrithione Drugs 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 1
- 229960002218 sodium chlorite Drugs 0.000 description 1
- MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to remove mould field, specially a kind of quick mildew removing agent and preparation method thereof, is grouped as by the group of following parts by weight: 20 ~ 35 parts of chlorine bleach, 8 ~ 10 parts of dehydroactic acid, 5 ~ 8 parts of Kathon CG, 4 ~ 6 parts of paraben esters, 1 ~ 3 part of synergist, 20 ~ 30 parts of orange peel powder, 10 ~ 20 parts of ethyl alcohol；Quick mildew removing agent prepared by the present invention, penetrating odor is smaller, by the active material for extracting orange peel powder, it can make the present invention that there is aromatic odor, by dissolving dehydroactic acid with ethyl alcohol, penetrating odor can be mitigated with ethyl alcohol, dehydroactic acid is a kind of less toxic efficient corrosion resisting simultaneously, mould inhibitor, and it is adaptable, in acid, there is certain antibacterial action under the conditions of alkali, it is especially most strong to the inhibiting effect of mould, it is a kind of effective, lasting disinfectant, by adding Kathon CG, with the use of parabens, the present invention can be made to have persistent except mould, anti-mold effect.
Description
Technical field
The present invention relates to remove mould field, specially a kind of quick mildew removing agent and preparation method thereof.
Background technique
Wall is easy mouldy, mouldy wall by the time of tide for a long time not only influences appearance, but also goes down can also seriously endanger for a long time
Victimize health.
A kind of existing mildew removing agent of Chinese patent and preparation method thereof (CN201810427815.6), the mildew removing agent, by weight
Percentages, including the following raw material: oxidant 1~10%, surfactant 0.05~5%, mould inhibitor 0.3~1%, bleeding agent
0.02~0.5%, adjuvant 0.02~2%, deionized water water surplus；Wherein, it is different to be selected from sodium chlorite, dichloro for the oxidant
At least one of NaDCC, sodium benzoate, hydrogen peroxide；The surfactant is selected from neopelex, 12
At least one of alkyl azochlorosulfonate propyl lycine, quaternary ammonium salt；The mould inhibitor be selected from Tebuconazole, dimercaptodimethyl ammonium chloride,
At least one of dioctadecyl dimethyl ammonium chloride, pyrithione urea.The mildew removing agent have the effect of it is mould proof, except mould, and
And persistent, it is harmful to human health, to no skin irritation, is applicable to various domestic environments, and easy to use, it is raw
The processing is simple for production, and energy consumption is few.
A kind of another existing wall mildew removing agent of Chinese patent and preparation method thereof (CN201610841435.8), this method include
Following step: first adding water in material-compound tank, stirring is opened, sodium hydroxide, sodium cetanesulfonate and/or amino front three
Pitch four sodium of phosphonic acids, sodium bromide, EDTA-4Na, dodecyldimethylamine oxide and/or tetradecyldimethylamine oxide, alkyl
Material-compound tank is added in dimethyl benzyl ammonium chloride, sodium metasilicate and/or sodium metasilicate, and material-compound tank finally is added in sodium hypochlorite, stirs
It filters within sedimentation 24 hours after uniformly.The present invention can quickly kill mould dedicated for the detergent of removing mould mildew, remove mould
Spot, and mould is inhibited to breed again.
With the development of science and technology the product except mould aspect achieves certain progress, but still there is more disadvantage, for example,
Except penetrating odor is big during mould, usage experience is poor, and mildew removing agent effect is not ideal enough, once except vice-minister again soon after mould
Mould, anti-mold effect is not lasting.
Summary of the invention
In view of this, the present invention provides a kind of quick mildew removing agent and preparation method thereof, penetrating odor is smaller, passes through extraction
The active material of orange peel powder can make the present invention have aromatic odor, by dissolving dehydroactic acid with ethyl alcohol, can be subtracted with ethyl alcohol
Subexcite smell, while dehydroactic acid is a kind of less toxic efficient corrosion resisting, mould inhibitor, and adaptable, under the conditions of acid, alkali
There is certain antibacterial action, it is especially most strong to the inhibiting effect of mould, it is a kind of effective, lasting disinfectant.
To achieve the goals above, the invention adopts the following technical scheme:
According to the first aspect of the invention, a kind of quick mildew removing agent is provided, is grouped as by the group of following parts by weight: chlorine bleach
20 ~ 35 parts, 8 ~ 10 parts of dehydroactic acid, 5 ~ 8 parts of Kathon CG, 4 ~ 6 parts of paraben esters, 1 ~ 3 part of synergist, 20 ~ 30 parts of orange peel powder, ethyl alcohol
10 ~ 20 parts.
Preferably, a kind of quick mildew removing agent, is grouped as by the group of following parts by weight: 25 parts of chlorine bleach, dehydroactic acid 9
Part, 6 parts of Kathon CG, 5 parts of paraben esters, 1.5 parts of synergist, 25 parts of orange peel powder, 15 parts of ethyl alcohol.
Preferably, the chlorine bleach is one of sodium hypochlorite, postassium hypochlorite, lithium hypochlorite and calcium hypochlorite, sheet
Better embodiment is sodium hypochlorite in invention.
Preferably, available chlorine content is 10 ~ 15% in the chlorine bleach.
Preferably, the synergist is the mixing that trimethoprim, sulfasalazine are 3 ~ 5:2 ~ 4 according to weight ratio.
According to the second aspect of the invention, a kind of preparation method of quick mildew removing agent is provided comprising:
Orange peel powder and deionized water are mixed, using ultrasonic wave extraction active material, are centrifuged impurity after extraction, take supernatant by S1
Above-mentioned deionized water is added in liquid in sediment, repeats to extract once, be centrifuged after extraction, takes supernatant, what merging was extracted twice
Supernatant；
Dehydroactic acid is poured slowly into ethyl alcohol by S2, and side bevelling stirring, mixing speed is 100 ~ 300 revs/min, by dehydroactic acid
After being finished down, it is kept stirring at least 1 ~ 3min, until dehydroactic acid is completely dissolved, is sealed after the completion of stirring and reserve liquid A is made；
S3 mixes paraben esters and deionized water, and chlorine bleach and synergist is added after dissolving it all in moderate-speed mixer, slowly
Speed stirs evenly obtained reserve liquid B；
S4 is stirred evenly after mixing supernatant made from S1 with reserve liquid A, reserve liquid B, mixing speed be 200 ~ 400 turns/
Point, mixing time is 3 ~ 8min, tests pH；
S5, addition regulator are added Kathon CG after so that pH is in OK range, the present invention are made after mixing evenly.
Specifically, in S1, solid-liquid ratio is 1:30 ~ 50 when orange peel powder and deionized water mix, and mixture is put into ultrasound
In wave extractor, control Extracting temperature be 30 ~ 55 DEG C, frequency be 10 ~ 25kHz, intensity be 200 ~ 500W, extraction time be 40 ~
Extract after the completion of extraction, is put into centrifuge by 60min, and centrifuging temperature is 5 ~ 10 DEG C, and revolving speed is 5000 ~ 7500 revs/min, from
The heart time is 10 ~ 30min, and supernatant is stayed after centrifugation, removes sediment.
Specifically, in S1, solid-liquid ratio is 1:30 when orange peel powder and deionized water mix, and mixture is put into ultrasonic wave and is mentioned
It taking in tank, control Extracting temperature is 35 DEG C, frequency 15kHz, intensity 400W, extraction time 55min, after the completion of extraction,
Extract is put into centrifuge, centrifuging temperature is 7 DEG C, and revolving speed is 6000 revs/min, and centrifugation time 15min stays supernatant after centrifugation
Liquid removes sediment.
Specifically, in S3, solid-liquid ratio is 1:10 ~ 20 when paraben esters and deionized water mix, and moderate-speed mixer speed is
300 ~ 500 revs/min, mixing time is 2 ~ 5min, and mixing slowly speed is 100 ~ 300 revs/min, and mixing time is 4 ~ 8min.
Specifically, in S5, regulator is acid regulator, concretely citric acid, potassium citrate, lactic acid, tartaric acid
One of, it when adjusting pH value, stirs in Plus acidic regulator, stops when pH value is between 5 ~ 9.5.
Be to advantageous effect of the invention: quick mildew removing agent prepared by the present invention, penetrating odor is smaller, by extracting orange peel
The active material of powder can make the present invention have aromatic odor, by dissolving dehydroactic acid with ethyl alcohol, can be mitigated with ethyl alcohol and be pierced
Swash property smell, while dehydroactic acid is a kind of less toxic efficient corrosion resisting, mould inhibitor, and adaptable, is had under the conditions of acid, alkali
Certain antibacterial action, it is especially most strong to the inhibiting effect of mould, it is a kind of effective, lasting disinfectant, by adding Kathon CG,
With the use of parabens, the present invention can be made to have persistent except mould, anti-mold effect.
Specific embodiment
The technical solution in the present invention is clearly and completely described below in conjunction with embodiment, it is clear that described
Embodiment is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field
Those of ordinary skill's all other embodiment obtained without creative efforts, belongs to protection of the present invention
Range.
Embodiment 1
A kind of quick mildew removing agent, is grouped as by the group of following parts by weight: 25 parts of chlorine bleach, 9 parts of dehydroactic acid, 6 parts of Kathon CG,
5 parts of paraben esters, 1.5 parts of synergist, 25 parts of orange peel powder, 15 parts of ethyl alcohol.
In embodiment 1, the chlorine bleach is sodium hypochlorite；Available chlorine content is 13% in the chlorine bleach；The increasing
Imitate agent be trimethoprim, the mixing that sulfasalazine is 3:2 according to weight ratio.
A kind of preparation method of quick mildew removing agent comprising:
Orange peel powder and deionized water are mixed, using ultrasonic wave extraction active material, are centrifuged impurity after extraction, take supernatant by S1
Above-mentioned deionized water is added in liquid in sediment, repeats to extract once, be centrifuged after extraction, takes supernatant, what merging was extracted twice
Supernatant, by ultrasonic wave extraction can by orange peel aromatic substance and effective active matter extract, product can be made to have
There is certain aromatic odor, and orange peel powder itself has certain bactericidal effect, kills two birds with one stone；
Dehydroactic acid is poured slowly into ethyl alcohol by S2, and side bevelling stirring, mixing speed is 100 ~ 300 revs/min, by dehydroactic acid
After being finished down, it is kept stirring at least 1 ~ 3min, until dehydroactic acid is completely dissolved, is sealed after the completion of stirring and reserve liquid A is made,
Dehydroactic acid is a kind of less toxic efficient corrosion resisting, mould inhibitor.There is certain antibacterial action under the conditions of acid, alkali, especially to mould
Inhibiting effect it is most strong, by dissolving with ethyl alcohol, the peculiar smell in the present invention can be watered down with ethyl alcohol；
S3 mixes paraben esters and deionized water, and chlorine bleach and synergist is added after dissolving it all in moderate-speed mixer, slowly
Speed stirs evenly obtained reserve liquid B；
S4 is stirred evenly after mixing supernatant made from S1 with reserve liquid A, reserve liquid B, mixing speed be 200 ~ 400 turns/
Point, mixing time is 3 ~ 8min, tests pH；
S5, addition regulator are added Kathon CG after so that pH is in OK range, the present invention are made after mixing evenly.
Specifically, in S1, solid-liquid ratio is 1:30 when orange peel powder and deionized water mix, and mixture is put into ultrasonic wave and is mentioned
It taking in tank, control Extracting temperature is 35 DEG C, frequency 15kHz, intensity 400W, extraction time 55min, after the completion of extraction,
Extract is put into centrifuge, centrifuging temperature is 7 DEG C, and revolving speed is 6000 revs/min, and centrifugation time 15min stays supernatant after centrifugation
Liquid removes sediment.
Specifically, in S3, solid-liquid ratio is 1:10 when paraben esters and deionized water mix, and moderate-speed mixer speed is 400
Rev/min, mixing time 3min, mixing slowly speed is 200 revs/min, mixing time 5min.
Specifically, in S5, regulator is citric acid, when adjusting pH value, is stirred in Plus acidic regulator, at pH value
Stop when (± 0.5) 8.0.
Embodiment 2
A kind of quick mildew removing agent, is grouped as by the group of following parts by weight: 30 parts of chlorine bleach, 8 parts of dehydroactic acid, 5 parts of Kathon CG,
4 parts of paraben esters, 2 parts of synergist, 20 parts of orange peel powder, 18 parts of ethyl alcohol.
In embodiment 2, the chlorine bleach is sodium hypochlorite；Available chlorine content is 12% in the chlorine bleach；The increasing
Imitate agent be trimethoprim, the mixing that sulfasalazine is 3:4 according to weight ratio.
A kind of preparation method of quick mildew removing agent comprising:
Orange peel powder and deionized water are mixed, using ultrasonic wave extraction active material, are centrifuged impurity after extraction, take supernatant by S1
Above-mentioned deionized water is added in liquid in sediment, repeats to extract once, be centrifuged after extraction, takes supernatant, what merging was extracted twice
Supernatant；
Dehydroactic acid is poured slowly into ethyl alcohol by S2, and side bevelling stirring, mixing speed is 100 ~ 300 revs/min, by dehydroactic acid
After being finished down, it is kept stirring at least 1 ~ 3min, until dehydroactic acid is completely dissolved, is sealed after the completion of stirring and reserve liquid A is made；
S3 mixes paraben esters and deionized water, and chlorine bleach and synergist is added after dissolving it all in moderate-speed mixer, slowly
Speed stirs evenly obtained reserve liquid B；
S4 is stirred evenly after mixing supernatant made from S1 with reserve liquid A, reserve liquid B, mixing speed be 200 ~ 400 turns/
Point, mixing time is 3 ~ 8min, tests pH；
S5, addition regulator are added Kathon CG after so that pH is in OK range, the present invention are made after mixing evenly.
Specifically, in S1, solid-liquid ratio is 1:35 when orange peel powder and deionized water mix, and mixture is put into ultrasonic wave and is mentioned
It taking in tank, control Extracting temperature is 40 DEG C, frequency 18kHz, intensity 350W, extraction time 45min, after the completion of extraction,
Extract is put into centrifuge, centrifuging temperature is 10 DEG C, and revolving speed is 5500 revs/min, and centrifugation time 20min is stayed after centrifugation
Clear liquid removes sediment.
Specifically, in S3, solid-liquid ratio is 1:15 when paraben esters and deionized water mix, and moderate-speed mixer speed is 350
Rev/min, mixing time 4min, mixing slowly speed is 150 revs/min, mixing time 6min.
Specifically, in S5, regulator is potassium citrate, when adjusting pH value, stirs in Plus acidic regulator, works as pH value
Stop when in (± 0.5) 9.0.
Embodiment 3
A kind of quick mildew removing agent, is grouped as by the group of following parts by weight: 35 parts of chlorine bleach, 10 parts of dehydroactic acid, Kathon CG 5
Part, 4 parts of paraben esters, 2 parts of synergist, 30 parts of orange peel powder, 15 parts of ethyl alcohol.
In embodiment 3, the chlorine bleach is sodium hypochlorite；Available chlorine content is 15% in the chlorine bleach；The increasing
Imitate agent be trimethoprim, the mixing that sulfasalazine is 5:4 according to weight ratio.
A kind of preparation method of quick mildew removing agent comprising:
Orange peel powder and deionized water are mixed, using ultrasonic wave extraction active material, are centrifuged impurity after extraction, take supernatant by S1
Above-mentioned deionized water is added in liquid in sediment, repeats to extract once, be centrifuged after extraction, takes supernatant, what merging was extracted twice
Supernatant；
Dehydroactic acid is poured slowly into ethyl alcohol by S2, and side bevelling stirring, mixing speed is 100 ~ 300 revs/min, by dehydroactic acid
After being finished down, it is kept stirring at least 1 ~ 3min, until dehydroactic acid is completely dissolved, is sealed after the completion of stirring and reserve liquid A is made；
S3 mixes paraben esters and deionized water, and chlorine bleach and synergist is added after dissolving it all in moderate-speed mixer, slowly
Speed stirs evenly obtained reserve liquid B；
S4 is stirred evenly after mixing supernatant made from S1 with reserve liquid A, reserve liquid B, mixing speed be 200 ~ 400 turns/
Point, mixing time is 3 ~ 8min, tests pH；
S5, addition regulator are added Kathon CG after so that pH is in OK range, the present invention are made after mixing evenly.
Specifically, in S1, solid-liquid ratio is 1:45 when orange peel powder and deionized water mix, and mixture is put into ultrasonic wave and is mentioned
It taking in tank, control Extracting temperature is 50 DEG C, frequency 25kHz, intensity 500W, extraction time 55min, after the completion of extraction,
Extract is put into centrifuge, centrifuging temperature is 10 DEG C, and revolving speed is 7000 revs/min, and centrifugation time 20min is stayed after centrifugation
Clear liquid removes sediment.
Specifically, in S3, solid-liquid ratio is 1:15 when paraben esters and deionized water mix, and moderate-speed mixer speed is 400
Rev/min, mixing time 2min, mixing slowly speed is 200 revs/min, mixing time 5min.
Specifically, in S5, regulator is tartaric acid, when adjusting pH value, is stirred in Plus acidic regulator, at pH value
Stop when (± 0.5) 6.
The characteristic and principle of each ingredient of the present invention are as follows:
Dehydroactic acid in the present invention is a kind of less toxic efficient corrosion resisting, mould inhibitor.There is certain antibacterial to make under the conditions of acid, alkali
With, it is especially most strong to the inhibiting effect of mould, it is a kind of effective disinfectant.
Trimethoprim in the present invention plays Trimethoprim, and the medicine itself has certain antibacterial action, later
Research, which confirms that the medicine and disulfonamide object share, can make sulfa drugs obtain antibacterial efficacy raising decades of times, or even make sulfanilamide (SN)
Class drug obtains bacteriostasis and becomes bactericidal effect.The reason is that bacterium can be made to obtain folic acid generation after the medicine and sulfa drugs share
It thanks and is acted on by double blocking.Therefore, which is referred to as " trimethoprim (TMP) " again.
Kathon CG in the present invention is a kind of liquid, is added in material directly below at 80 DEG C of temperature, Kathon CG have efficiently,
The long feature of nontoxic, restraining and sterilizing bacteria wide spectrum, lasting effect, it is good with other reagent intermiscibilities, effect is used cooperatively with parabens
More preferably, it is applicable in the range of pH value 3-9.5.
Experimental example
By the mildew removing agent (as a comparison case) of mildew removing agent made from above-described embodiment 1 ~ 3 and the three kinds of different brands bought in the market
Experimental comparison；
Experiment method: will uniformly cultivate mould on white wall, six regions be classified as after mould grows up to, respectively with above-mentioned six kinds
Mildew removing agent, which record respectively except mould experiment, thoroughly decomposes mould the number for needing to repeat spraying and dosage, records in spraying
Whether irritant smell, and to penetrating odor classification (according to thorn taste concentration be successively denoted as without, it is small, in, it is big), observe respectively
Except mould six months and 12 months secondary mouldy situations, experimental result such as table 1:
| Spray number | Spray dosage | Smell rank | Six months | 12 months | |
| Embodiment 1 | 1 | (± 5) 100ml | It is small | Without fungus growth | Without fungus growth |
| Embodiment 2 | 1 | (± 5) 100ml | It is small | Without fungus growth | Without fungus growth |
| Embodiment 3 | 1 | (± 5) 100ml | It is small | Without fungus growth | Without fungus growth |
| Comparative example 1 | 2 | (± 5) 160ml | Greatly | Without fungus growth | A small amount of mould |
| Comparative example 2 | 1 | (± 5) 130ml | In | Without fungus growth | Without fungus growth |
| Comparative example 3 | 3 | (± 5) 150ml | Greatly | Without fungus growth | A small amount of mould |
Table 1
The experimental result of analytical table 1 it is found that embodiment 1 ~ 3 and comparative example 2 except mould effect it is best, it is only necessary to mould surface again
Spraying can once thoroughly remove mould, and it is mould that comparative example 1 and comparative example 3 averagely need spraying that can just thoroughly remove more than twice
Bacterium observes the dosage of mildew removing agent, can also verify except mould effect, and the average dose of embodiment 1 ~ 3 only has 100ml or so, comparison
Although the spraying of example 2 once can also thoroughly remove mould, its dosage is about 130ml, and comparative example 1 and comparative example 3 are whole
Whole to need 150ml or more, dosage is larger, and business efficiency is not high, and the penetrating odor of embodiment 1 ~ 3 is also minimum in spraying
, this is because part penetrating odor has been watered down with ethyl alcohol first in the present invention, aromatic substance in the orange peel powder in next invention
Matter and active material can cover thorn taste, except making discovery from observation after the completion of mould, without fungus growth after six months, and 12
Embodiment 1 ~ 3 and comparative example 2 are without fungus growth after month, and comparative example 1 and comparative example 3 have been tied and begun with a small amount of fungus growth,
This illustrates that the anti-mold effect of embodiment 1 ~ 3 and comparative example 2 is more longlasting, and comprehensive integral experiment is as a result, effect of the invention is preferable.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means
Particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one implementation of the invention
In example or example.In the present specification, schematic expression of the above terms may not refer to the same embodiment or example.
Moreover, particular features, structures, materials, or characteristics described can be in any one or more of the embodiments or examples to close
Suitable mode combines.
Finally, it should be noted that present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.It is excellent
The details that embodiment is all there is no detailed descriptionthe is selected, is not limited the invention to the specific embodiments described.Obviously, root
According to the content of this specification, can make many modifications and variations.These embodiments are chosen and specifically described to this specification, be in order to
The principle of the present invention and practical application are preferably explained, so that skilled artisan be enable to better understand and utilize
The present invention.The invention is limited only by the claims and the full scope thereof and equivalents thereof.
Claims (10)
1. a kind of quick mildew removing agent, which is characterized in that it is grouped as by the group of following parts by weight: 20 ~ 35 parts of chlorine bleach, dehydrogenation
8 ~ 10 parts of acetic acid, 5 ~ 8 parts of Kathon CG, 4 ~ 6 parts of paraben esters, 1 ~ 3 part of synergist, 20 ~ 30 parts of orange peel powder, 10 ~ 20 parts of ethyl alcohol.
2. a kind of quick mildew removing agent according to claim 1, which is characterized in that it is grouped as by the group of following parts by weight:
25 parts of chlorine bleach, 9 parts of dehydroactic acid, 6 parts of Kathon CG, 5 parts of paraben esters, 1.5 parts of synergist, 25 parts of orange peel powder, 15 parts of ethyl alcohol.
3. a kind of quick mildew removing agent according to claim 1 or 2, which is characterized in that the chlorine bleach be sodium hypochlorite,
One of postassium hypochlorite, lithium hypochlorite and calcium hypochlorite, the present invention in better embodiment be sodium hypochlorite.
4. a kind of quick mildew removing agent according to claim 1 or 2, which is characterized in that effective chlorine contains in the chlorine bleach
Amount is 10 ~ 15%.
5. a kind of quick mildew removing agent according to claim 1 or 2, which is characterized in that the synergist is that emilium tosylate is phonetic
Pyridine, sulfasalazine are the mixing of 3 ~ 5:2 ~ 4 according to weight ratio.
6. a kind of preparation method of quick mildew removing agent, characterized in that it comprises:
Orange peel powder and deionized water are mixed, using ultrasonic wave extraction active material, are centrifuged impurity after extraction, take supernatant by S1
Above-mentioned deionized water is added in liquid in sediment, repeats to extract once, be centrifuged after extraction, takes supernatant, what merging was extracted twice
Supernatant；
Dehydroactic acid is poured slowly into ethyl alcohol by S2, and side bevelling stirring, mixing speed is 100 ~ 300 revs/min, by dehydroactic acid
After being finished down, it is kept stirring at least 1 ~ 3min, until dehydroactic acid is completely dissolved, is sealed after the completion of stirring and reserve liquid A is made；
S3 mixes paraben esters and deionized water, and chlorine bleach and synergist is added after dissolving it all in moderate-speed mixer, slowly
Speed stirs evenly obtained reserve liquid B；
S4 is stirred evenly after mixing supernatant made from S1 with reserve liquid A, reserve liquid B, mixing speed be 200 ~ 400 turns/
Point, mixing time is 3 ~ 8min, tests pH；
S5, addition regulator are added Kathon CG after so that pH is in OK range, the present invention are made after mixing evenly.
7. a kind of preparation method of quick mildew removing agent according to claim 6, which is characterized in that in S1, orange peel powder and
Solid-liquid ratio is 1:30 ~ 50 when deionized water mixes, and mixture is put into ultrasonic extraction tank, and control Extracting temperature is 30 ~ 55
DEG C, frequency be 10 ~ 25kHz, intensity be 200 ~ 500W, extraction time be 40 ~ 60min, after the completion of extraction, by extract be put into from
Scheming, centrifuging temperature are 5 ~ 10 DEG C, and revolving speed is 5000 ~ 7500 revs/min, and centrifugation time is 10 ~ 30min, stay supernatant after centrifugation,
Remove sediment.
8. a kind of preparation method of quick mildew removing agent according to claim 7, which is characterized in that specifically, in S1, tangerine
Solid-liquid ratio is 1:30 when skin powder and deionized water mix, and mixture is put into ultrasonic extraction tank, and control Extracting temperature is 35
DEG C, extract after the completion of extraction, is put into centrifuge by frequency 15kHz, intensity 400W, extraction time 55min, centrifugation
Temperature is 7 DEG C, and revolving speed is 6000 revs/min, centrifugation time 15min, and supernatant is stayed after centrifugation, removes sediment.
9. a kind of preparation method of quick mildew removing agent according to claim 6, which is characterized in that in S3, paraben esters
It is 1:10 ~ 20 with solid-liquid ratio when deionized water mixing, moderate-speed mixer speed is 300 ~ 500 revs/min, and mixing time is 2 ~ 5min,
Mixing slowly speed is 100 ~ 300 revs/min, and mixing time is 4 ~ 8min.
10. a kind of preparation method of quick mildew removing agent according to claim 6, which is characterized in that in S5, regulator
For acid regulator, concretely one of citric acid, potassium citrate, lactic acid, tartaric acid, when adjusting pH value, side is Plus acidic
The stirring of regulator side, stops when pH value is between 5 ~ 9.5.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112320968A (en) * | 2020-09-22 | 2021-02-05 | 甘肃鹏发环保节能科技有限公司 | Odor inhibitor for sewage treatment plant |
| CN113265212A (en) * | 2021-05-28 | 2021-08-17 | 陕西省石油化工研究设计院 | Anti-corrosion and anti-mildew agent for cigarette glue and preparation method and application thereof |
| CN113480885A (en) * | 2021-06-09 | 2021-10-08 | 湖北恒沁环保科技有限责任公司 | Efficient mildew removing and preventing agent for treating mildew stains of wall |
| CN116807210A (en) * | 2023-04-11 | 2023-09-29 | 瑞年科技(广东)有限公司 | Multifunctional mildew-proof tablecloth |
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2018
- 2018-12-24 CN CN201811581088.5A patent/CN109699677A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112320968A (en) * | 2020-09-22 | 2021-02-05 | 甘肃鹏发环保节能科技有限公司 | Odor inhibitor for sewage treatment plant |
| CN113265212A (en) * | 2021-05-28 | 2021-08-17 | 陕西省石油化工研究设计院 | Anti-corrosion and anti-mildew agent for cigarette glue and preparation method and application thereof |
| CN113480885A (en) * | 2021-06-09 | 2021-10-08 | 湖北恒沁环保科技有限责任公司 | Efficient mildew removing and preventing agent for treating mildew stains of wall |
| CN116807210A (en) * | 2023-04-11 | 2023-09-29 | 瑞年科技(广东)有限公司 | Multifunctional mildew-proof tablecloth |
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